EP2545195A2 - Verfahren zur beschichtung zumindest der innenfläche eines kolbenrings sowie kolbenring - Google Patents
Verfahren zur beschichtung zumindest der innenfläche eines kolbenrings sowie kolbenringInfo
- Publication number
- EP2545195A2 EP2545195A2 EP11704068A EP11704068A EP2545195A2 EP 2545195 A2 EP2545195 A2 EP 2545195A2 EP 11704068 A EP11704068 A EP 11704068A EP 11704068 A EP11704068 A EP 11704068A EP 2545195 A2 EP2545195 A2 EP 2545195A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- piston ring
- coating
- doing
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000011248 coating agent Substances 0.000 title claims abstract description 20
- 238000000576 coating method Methods 0.000 title claims abstract description 20
- 238000005240 physical vapour deposition Methods 0.000 claims abstract description 9
- 238000000168 high power impulse magnetron sputter deposition Methods 0.000 claims abstract description 5
- 229910001018 Cast iron Inorganic materials 0.000 claims abstract description 3
- 229910001208 Crucible steel Inorganic materials 0.000 claims abstract description 3
- 239000010959 steel Substances 0.000 claims abstract description 3
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052721 tungsten Inorganic materials 0.000 claims description 4
- 239000010937 tungsten Substances 0.000 claims description 4
- 150000001247 metal acetylides Chemical class 0.000 claims description 3
- 150000004767 nitrides Chemical class 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical group FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 239000011737 fluorine Chemical group 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Chemical group 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000002244 precipitate Substances 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 239000010410 layer Substances 0.000 description 19
- 230000006835 compression Effects 0.000 description 5
- 238000007906 compression Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910021385 hard carbon Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000000752 ionisation method Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/02—Pretreatment of the material to be coated
- C23C16/0272—Deposition of sub-layers, e.g. to promote the adhesion of the main coating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16J—PISTONS; CYLINDERS; SEALINGS
- F16J9/00—Piston-rings, e.g. non-metallic piston-rings, seats therefor; Ring sealings of similar construction
- F16J9/26—Piston-rings, e.g. non-metallic piston-rings, seats therefor; Ring sealings of similar construction characterised by the use of particular materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/34—Gas-filled discharge tubes operating with cathodic sputtering
- H01J37/3464—Operating strategies
- H01J37/3467—Pulsed operation, e.g. HIPIMS
Definitions
- the invention relates to a method for coating
- the invention to be coated piston ring is
- Oil scraper ring provided in a piston of an internal combustion engine.
- the actual piston ring which is in sliding contact with a cylinder or a cylinder liner, pressed by an internal helical compression spring against the cylinder wall.
- On the inner surface of the piston ring it is thus due to the dynamic stress during operation of the motor relative movements between the
- DE 196 51 112 AI relates to a completely provided with a coating ⁇ labstreifring on a
- JP2006349019 (A) discloses a piston ring with an amorphous hard carbon coating.
- the invention is based on the object, a method for coating a piston ring and a coated
- PA-CVD plasma enhanced chemical vapor deposition
- glow discharge or high ionization processes, such as a piston ring, preferably made of cast iron or steel, is used.
- the piston ring on its cylindrical inner surface and is preferably coated at least in those areas, for example in the region of a hose spring groove, which are in contact with the hose spring.
- other surfaces such as the flanks and / or the tread, may be provided with the coating described herein.
- the described layers have been found to have very low coefficients of friction. Consequently, in addition advantageously low wear on the hose spring is to be expected. Finally, the layers described are chemically comparatively highly resistant, so that deposits are prevented, and advantageously a further improvement in the mobility of the entire oil ring system is achieved.
- the DLC layer can be called
- Hydrogen-free layer in particular in the form a-C or ta-C present.
- a hydrogen-containing, but metal-free layer for example in the form a-C: H or ta-C: H is conceivable.
- Nitrides and / or carbides at least one of the metals
- Deposition of the nitrides and carbides can take place alternately or simultaneously.
- a structure which has at least one of the following layers and to the base material of the piston ring first an adhesion layer of chromium and / or titanium with a layer thickness of 1.0 ⁇ or smaller. This is followed by a metal or semiconductor-containing intermediate layer, ie an aC: H: Me with tungsten, titanium or chromium as metal or aC: H: X with
- X silicon and / or germanium as semiconductors and / or one or more of the constituents fluorine, boron, oxygen and nitrogen.
- the thickness of this intermediate layer is preferably 0.1 ⁇ m to 5 ⁇ m.
- the construction described is completed by a metal-free top layer of the type a ⁇ C: H having a thickness of preferably 0.1 ⁇ m to 5 ⁇ m.
- metal-containing DLC interlayer containing nanocrystalline metal or metal carbide precipitates e.g. WC, CrC, Sic, GeC or TiC.
- sputtering and in particular hollow cathode glow discharge methods can also be used for the DLC layer.
- piston ring coated in particular coated on the inner surface, described herein, may advantageously have the same name as the application filed in the same day
- Helical compression spring for an oil scraper ring of a piston in an internal combustion engine and method for coating a helical compression spring described helical compression spring can be combined in one of the embodiments given there.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Plasma & Fusion (AREA)
- Chemical Vapour Deposition (AREA)
- Pistons, Piston Rings, And Cylinders (AREA)
- Physical Vapour Deposition (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102010002687.5A DE102010002687C5 (de) | 2010-03-09 | 2010-03-09 | Verfahren zur Beschichtung zumindest der Innenfläche eines Kolbenrings sowie Kolbenring |
| PCT/EP2011/052342 WO2011110411A2 (de) | 2010-03-09 | 2011-02-17 | Verfahren zur beschichtung zumindest der innenfläche eines kolbenrings sowie kolbenring |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2545195A2 true EP2545195A2 (de) | 2013-01-16 |
Family
ID=44022914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP11704068A Withdrawn EP2545195A2 (de) | 2010-03-09 | 2011-02-17 | Verfahren zur beschichtung zumindest der innenfläche eines kolbenrings sowie kolbenring |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20130136861A1 (enExample) |
| EP (1) | EP2545195A2 (enExample) |
| JP (1) | JP5855026B2 (enExample) |
| KR (1) | KR101781618B1 (enExample) |
| CN (1) | CN103620085B (enExample) |
| BR (1) | BR112012022013B1 (enExample) |
| DE (1) | DE102010002687C5 (enExample) |
| WO (1) | WO2011110411A2 (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102011003254A1 (de) * | 2011-01-27 | 2012-08-02 | Federal-Mogul Burscheid Gmbh | Gleitelement, insbesondere Kolbenring, mit einer Beschichtung sowie Verfahren zur Herstellung eines Gleitelements |
| BRPI1105714B1 (pt) * | 2011-12-07 | 2021-01-05 | Mahle Metal Leve S/A | componente deslizante para uso em motores de combustão interna |
| BR102012003607A2 (pt) * | 2012-02-16 | 2013-10-29 | Mahle Metal Leve Sa | Componente deslizante para uso em motores de combustão interna |
| CN103374697B (zh) * | 2012-04-20 | 2017-09-29 | 深圳富泰宏精密工业有限公司 | 类金刚石膜层的表面处理方法及制品 |
| JP5564099B2 (ja) * | 2012-12-28 | 2014-07-30 | 株式会社リケン | シリンダとピストンリングの組合せ |
| EP2963145B1 (en) * | 2014-06-30 | 2018-01-31 | IHI Hauzer Techno Coating B.V. | Coating and method for its deposition to operate in boundary lubrication conditions and at elevated temperatures |
| CN107532717B (zh) * | 2015-07-31 | 2019-05-28 | 日本活塞环株式会社 | 活塞环 |
| CN107923532B (zh) * | 2015-08-10 | 2020-06-23 | 日本Itf株式会社 | 活塞环及发动机 |
| BR102016007169B1 (pt) * | 2016-03-31 | 2023-01-10 | Mahle International Gmbh | Anel de pistão para motores de combustão interna, processo para obtenção de anel de pistão e motor de combustão interna |
| CN105839058B (zh) * | 2016-04-05 | 2019-05-14 | 中国建筑材料科学研究总院 | 硫化锌基体表面镀制类金刚石膜的方法及具有类金刚石膜的硫化锌板 |
| DE102016107874A1 (de) | 2016-04-28 | 2017-11-16 | Federal-Mogul Burscheid Gmbh | Gleitelement, insbesondere Kolbenring |
| DE102016110131A1 (de) * | 2016-06-01 | 2017-12-07 | Federal-Mogul Burscheid Gmbh | Zweiteiliger Ölabstreifring mit Öldruckeffektstegen |
| DE102018131021A1 (de) | 2018-12-05 | 2020-06-10 | Schaeffler Technologies AG & Co. KG | Gelenklager |
| CN109536905B (zh) * | 2018-12-13 | 2020-09-22 | 西安工程大学 | 一种铜表面用TiC-Si固溶体导电涂层的制备方法 |
| DE102019131675A1 (de) | 2019-11-22 | 2021-05-27 | Leibniz-Institut Für Polymerforschung Dresden E.V. | Membranen für die flüssigkeitsaufbereitung |
| CN114318270B (zh) * | 2022-01-07 | 2023-12-15 | 仪征亚新科双环活塞环有限公司 | 一种提高活塞环外圆面硬质镀层磨合期摩擦学性能的磨合涂层及其制备方法 |
| US20240392444A1 (en) * | 2023-05-22 | 2024-11-28 | IBC Materials & Technologies, LLC | Coating compositions, methods to produce non-stick surfaces and non-stick surfaces made therefrom |
| EP4467700A1 (de) * | 2023-05-24 | 2024-11-27 | KARL MAYER STOLL R&D GmbH | Textilwerkzeug, textilwerkzeugverbund und textilmaschine zur herstellung eines textilen flächengebildes |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0988406A1 (en) * | 1997-06-19 | 2000-03-29 | N.V. Bekaert S.A. | Method for making a non-sticking diamond like nanocomposite |
| WO2006125683A1 (en) * | 2005-05-26 | 2006-11-30 | Nv Bekaert Sa | Piston ring having hard multi-layer coating |
| JP2008241032A (ja) * | 2007-02-28 | 2008-10-09 | Nippon Piston Ring Co Ltd | ピストンリング及びその製造方法 |
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| US6468642B1 (en) * | 1995-10-03 | 2002-10-22 | N.V. Bekaert S.A. | Fluorine-doped diamond-like coatings |
| JP3957778B2 (ja) | 1995-12-08 | 2007-08-15 | 株式会社リケン | ピストンロッド用シール装置 |
| JP2855419B2 (ja) * | 1995-12-19 | 1999-02-10 | 帝国ピストンリング株式会社 | 組合せオイルリングのスペーサエキスパンダおよび組合せオイルリング |
| EP1340835B1 (en) * | 1996-06-27 | 2006-10-04 | Nissin Electric Co., Ltd. | Object coated with carbon film and method of manufacturing the same |
| JP3885375B2 (ja) * | 1997-09-30 | 2007-02-21 | 帝国ピストンリング株式会社 | ピストンリング |
| US6726993B2 (en) * | 1997-12-02 | 2004-04-27 | Teer Coatings Limited | Carbon coatings, method and apparatus for applying them, and articles bearing such coatings |
| US6827976B2 (en) * | 1998-04-29 | 2004-12-07 | Unaxis Trading Ag | Method to increase wear resistance of a tool or other machine component |
| DE19825860A1 (de) * | 1998-06-10 | 1999-12-16 | Elgan Diamantwerkzeuge Gmbh & | Kolbenring und seine Verwendung |
| US20020017761A1 (en) * | 2000-03-23 | 2002-02-14 | Dubose G. Douglas | Seals for internal combustion engines |
| JP2002097573A (ja) * | 2000-09-19 | 2002-04-02 | Riken Corp | 摺動部材 |
| JP4615697B2 (ja) * | 2000-11-07 | 2011-01-19 | ティーア、コーティングズ、リミテッド | 炭素含有被覆を施した物品 |
| US6583048B2 (en) * | 2001-01-17 | 2003-06-24 | Air Products And Chemicals, Inc. | Organosilicon precursors for interlayer dielectric films with low dielectric constants |
| DE10117164A1 (de) * | 2001-04-06 | 2002-10-10 | Bayerische Motoren Werke Ag | Kolbenringanordnung für Kolben von Hubkolbenmaschinen, insbesondere Brennkrafmaschinen |
| JP4374153B2 (ja) * | 2001-06-29 | 2009-12-02 | 日本ピストンリング株式会社 | ピストンリング |
| JP4336203B2 (ja) * | 2001-11-27 | 2009-09-30 | 日本発條株式会社 | 不連続な支持構造を有する圧縮コイルばね装置 |
| US6835663B2 (en) * | 2002-06-28 | 2004-12-28 | Infineon Technologies Ag | Hardmask of amorphous carbon-hydrogen (a-C:H) layers with tunable etch resistivity |
| JP4184041B2 (ja) * | 2002-11-14 | 2008-11-19 | 帝国ピストンリング株式会社 | 組合せピストンリング |
| US20040150145A1 (en) * | 2003-01-31 | 2004-08-05 | Delphi Technologies Inc. | Bi-state rate dip hydraulic mount |
| JP4653964B2 (ja) * | 2003-04-08 | 2011-03-16 | 株式会社栗田製作所 | Ｄｌｃ膜の成膜方法およびｄｌｃ成膜物 |
| JP4973971B2 (ja) * | 2003-08-08 | 2012-07-11 | 日産自動車株式会社 | 摺動部材 |
| AU2003298338A1 (en) * | 2003-12-02 | 2005-06-24 | N.V. Bekaert S.A. | A layered structure |
| KR200370631Y1 (ko) | 2004-09-13 | 2004-12-17 | 장철년 | 스펀지 도장 |
| JP5013445B2 (ja) * | 2005-03-09 | 2012-08-29 | 株式会社豊田中央研究所 | ピストンリング、それを備えたピストンおよびそれらの使用方法 |
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| DE102005033769B4 (de) * | 2005-07-15 | 2009-10-22 | Systec System- Und Anlagentechnik Gmbh & Co.Kg | Verfahren und Vorrichtung zur Mehrkathoden-PVD-Beschichtung und Substrat mit PVD-Beschichtung |
| DE102005063123B3 (de) * | 2005-12-30 | 2007-05-31 | Federal-Mogul Burscheid Gmbh | Gleitelement, insbesondere Kolbenring, Verfahren zur Herstellung eines Gleitelements, Gleitsystem und Beschichtung für ein Gleitelement |
| JP4839120B2 (ja) * | 2006-04-03 | 2011-12-21 | 株式会社リケン | 積層皮膜を有するピストンリング |
| DE102006046917C5 (de) * | 2006-10-04 | 2014-03-20 | Federal-Mogul Burscheid Gmbh | Kolbenring für Verbrennungskraftmaschinen |
| DE102007011230A1 (de) * | 2007-03-06 | 2008-09-11 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Magnetronplasmaanlage |
| US8394197B2 (en) * | 2007-07-13 | 2013-03-12 | Sub-One Technology, Inc. | Corrosion-resistant internal coating method using a germanium-containing precursor and hollow cathode techniques |
| US20100255338A1 (en) * | 2007-09-19 | 2010-10-07 | Citizen Holdings Co., Ltd. | Decorative part |
| DE102008016864B3 (de) * | 2008-04-02 | 2009-10-22 | Federal-Mogul Burscheid Gmbh | Kolbenring |
| KR101405464B1 (ko) | 2011-02-24 | 2014-06-13 | 그래핀스퀘어 주식회사 | 플렉서블 태양전지 및 그의 제조방법 |
-
2010
- 2010-03-09 DE DE102010002687.5A patent/DE102010002687C5/de active Active
-
2011
- 2011-02-17 KR KR1020127026365A patent/KR101781618B1/ko not_active Expired - Fee Related
- 2011-02-17 WO PCT/EP2011/052342 patent/WO2011110411A2/de not_active Ceased
- 2011-02-17 BR BR112012022013A patent/BR112012022013B1/pt active IP Right Grant
- 2011-02-17 JP JP2012556430A patent/JP5855026B2/ja active Active
- 2011-02-17 US US13/583,715 patent/US20130136861A1/en not_active Abandoned
- 2011-02-17 CN CN201180012801.4A patent/CN103620085B/zh active Active
- 2011-02-17 EP EP11704068A patent/EP2545195A2/de not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0988406A1 (en) * | 1997-06-19 | 2000-03-29 | N.V. Bekaert S.A. | Method for making a non-sticking diamond like nanocomposite |
| WO2006125683A1 (en) * | 2005-05-26 | 2006-11-30 | Nv Bekaert Sa | Piston ring having hard multi-layer coating |
| JP2008241032A (ja) * | 2007-02-28 | 2008-10-09 | Nippon Piston Ring Co Ltd | ピストンリング及びその製造方法 |
Non-Patent Citations (1)
| Title |
|---|
| See also references of WO2011110411A2 * |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20130005282A (ko) | 2013-01-15 |
| CN103620085B (zh) | 2016-10-12 |
| US20130136861A1 (en) | 2013-05-30 |
| JP5855026B2 (ja) | 2016-02-09 |
| RU2012142814A (ru) | 2014-04-20 |
| DE102010002687C5 (de) | 2015-09-10 |
| KR101781618B1 (ko) | 2017-09-25 |
| CN103620085A (zh) | 2014-03-05 |
| JP2013529249A (ja) | 2013-07-18 |
| BR112012022013B1 (pt) | 2019-12-24 |
| WO2011110411A2 (de) | 2011-09-15 |
| DE102010002687A1 (de) | 2011-09-15 |
| DE102010002687B4 (de) | 2012-02-16 |
| BR112012022013A2 (pt) | 2017-02-07 |
| WO2011110411A3 (de) | 2015-06-25 |
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