EP2545018A4 - Alkylated aromatics production - Google Patents

Alkylated aromatics production

Info

Publication number
EP2545018A4
EP2545018A4 EP10847601.1A EP10847601A EP2545018A4 EP 2545018 A4 EP2545018 A4 EP 2545018A4 EP 10847601 A EP10847601 A EP 10847601A EP 2545018 A4 EP2545018 A4 EP 2545018A4
Authority
EP
European Patent Office
Prior art keywords
alkylated aromatics
aromatics production
production
alkylated
aromatics
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP10847601.1A
Other languages
German (de)
French (fr)
Other versions
EP2545018A1 (en
Inventor
Matthew J Vincent
Vijay Nanda
Maruti Bhandarkar
Brian Maerz
Terry E Helton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
TEn Process Technology Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Stone and Webster Process Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc, Stone and Webster Process Technology Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of EP2545018A1 publication Critical patent/EP2545018A1/en
Publication of EP2545018A4 publication Critical patent/EP2545018A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/073—Ethylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/085—Isopropylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
EP10847601.1A 2010-03-10 2010-03-10 Alkylated aromatics production Withdrawn EP2545018A4 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2010/026844 WO2011112189A1 (en) 2010-03-10 2010-03-10 Alkylated aromatics production

Publications (2)

Publication Number Publication Date
EP2545018A1 EP2545018A1 (en) 2013-01-16
EP2545018A4 true EP2545018A4 (en) 2014-10-08

Family

ID=44563758

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10847601.1A Withdrawn EP2545018A4 (en) 2010-03-10 2010-03-10 Alkylated aromatics production

Country Status (8)

Country Link
EP (1) EP2545018A4 (en)
JP (1) JP5659247B2 (en)
KR (1) KR101533875B1 (en)
CN (1) CN102906054B (en)
BR (1) BR112012022691A2 (en)
RU (1) RU2528825C2 (en)
SG (1) SG183322A1 (en)
WO (1) WO2011112189A1 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102892731B (en) 2010-05-20 2015-12-02 埃克森美孚化学专利公司 The alkylation improved
WO2013175490A1 (en) * 2012-04-03 2013-11-28 Reliance Industries Limited An oxygenates-free c8-c12 aromatic hydrocarbon stream and a process for preparing the same
CN105339328B (en) * 2013-05-08 2020-08-25 巴杰许可有限责任公司 Aromatic alkylation process
US20160130196A1 (en) 2014-11-07 2016-05-12 Uop Llc Highly selective alkylation process with low zeolite catalyst composition
CN110337328B (en) * 2017-02-28 2022-05-06 埃克森美孚化学专利公司 Catalyst composition and its use in aromatic alkylation process
WO2018160327A1 (en) * 2017-02-28 2018-09-07 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in aromatic alkylation processes
EP3600653A1 (en) * 2017-03-29 2020-02-05 ExxonMobil Chemical Patents Inc. Catalyst compositions and their use in aromatic alkylation processes
CN111574318B (en) * 2020-06-04 2022-09-30 常州瑞华化工工程技术股份有限公司 Energy-saving reaction process for producing ethylbenzene from pure ethylene
RU2756954C1 (en) * 2020-12-09 2021-10-07 Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть-ОНПЗ") Method for obtaining alkyl derivatives of arenes
CN113333014A (en) * 2021-06-02 2021-09-03 辽宁师范大学 Solid catalyst for preparing diethylbenzene by ethyl benzene ethanol/ethylene alkylation and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6297417B1 (en) * 1996-08-20 2001-10-02 The Dow Chemical Company Alkylation/transalkylation process with pretreatment of the alkylation/transalkylation feedstock
US20080177120A1 (en) * 2007-01-19 2008-07-24 Clark Michael C Liquid phase alkylation with multiple catalysts

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8028A (en) * 1851-04-08 Hokse-poweb
US5030786A (en) * 1989-06-23 1991-07-09 Fina Technology, Inc. Liquid phase aromatic conversion process
JPH04346939A (en) * 1991-05-24 1992-12-02 Asahi Chem Ind Co Ltd Production of alkyl aromatic compound
US5777187A (en) * 1996-02-08 1998-07-07 Huntsman Petrochemical Corporation Two-step process for alkylation of benzene to form linear alkylbenzenes
US6617482B1 (en) * 2000-08-16 2003-09-09 Exxonmobil Chemical Patents Inc. Removable of polar contaminants from aromatic feedstocks
CN1639089A (en) * 2002-02-28 2005-07-13 斯东及韦伯斯特公司 Production of alkyl aromatic compounds
US6995295B2 (en) * 2002-09-23 2006-02-07 Exxonmobil Chemical Patents Inc. Alkylaromatics production
US7425659B2 (en) * 2006-01-31 2008-09-16 Exxonmobil Chemical Patents Inc. Alkylaromatics production

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6297417B1 (en) * 1996-08-20 2001-10-02 The Dow Chemical Company Alkylation/transalkylation process with pretreatment of the alkylation/transalkylation feedstock
US20080177120A1 (en) * 2007-01-19 2008-07-24 Clark Michael C Liquid phase alkylation with multiple catalysts

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2011112189A1 *

Also Published As

Publication number Publication date
SG183322A1 (en) 2012-09-27
JP2013521336A (en) 2013-06-10
RU2012141942A (en) 2014-04-10
CN102906054B (en) 2015-11-25
BR112012022691A2 (en) 2016-08-23
JP5659247B2 (en) 2015-01-28
KR101533875B1 (en) 2015-07-03
WO2011112189A1 (en) 2011-09-15
RU2528825C2 (en) 2014-09-20
KR20120136357A (en) 2012-12-18
EP2545018A1 (en) 2013-01-16
CN102906054A (en) 2013-01-30
WO2011112189A8 (en) 2012-03-08

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Legal Events

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Owner name: EXXONMOBIL CHEMICAL PATENTS INC.

Owner name: STONE & WEBSTER PROCESS TECHNOLOGY, INC.

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