EP2511194B1 - Film cartridge and method for producing a film cartridge - Google Patents

Film cartridge and method for producing a film cartridge Download PDF

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Publication number
EP2511194B1
EP2511194B1 EP12158339.7A EP12158339A EP2511194B1 EP 2511194 B1 EP2511194 B1 EP 2511194B1 EP 12158339 A EP12158339 A EP 12158339A EP 2511194 B1 EP2511194 B1 EP 2511194B1
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EP
European Patent Office
Prior art keywords
opening
filling
film
chamber
tube
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP12158339.7A
Other languages
German (de)
French (fr)
Other versions
EP2511194A3 (en
EP2511194A2 (en
Inventor
Ralf Willner
Gottfried Kleinhans
Armin Bässler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hilti AG
Original Assignee
Hilti AG
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Filing date
Publication date
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Publication of EP2511194A2 publication Critical patent/EP2511194A2/en
Publication of EP2511194A3 publication Critical patent/EP2511194A3/en
Application granted granted Critical
Publication of EP2511194B1 publication Critical patent/EP2511194B1/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D35/00Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor
    • B65D35/02Body construction
    • B65D35/10Body construction made by uniting or interconnecting two or more components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B3/00Packaging plastic material, semiliquids, liquids or mixed solids and liquids, in individual containers or receptacles, e.g. bags, sacks, boxes, cartons, cans, or jars
    • B65B3/04Methods of, or means for, filling the material into the containers or receptacles
    • B65B3/16Methods of, or means for, filling the material into the containers or receptacles for filling collapsible tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B39/00Nozzles, funnels or guides for introducing articles or materials into containers or wrappers
    • B65B39/12Nozzles, funnels or guides for introducing articles or materials into containers or wrappers movable towards or away from container or wrapper during filling or depositing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B43/00Forming, feeding, opening or setting-up containers or receptacles in association with packaging
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D35/00Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor
    • B65D35/22Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor with two or more compartments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/32Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging two or more different materials which must be maintained separate prior to use in admixture
    • B65D81/3261Flexible containers having several compartments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/32Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging two or more different materials which must be maintained separate prior to use in admixture
    • B65D81/3261Flexible containers having several compartments
    • B65D81/3272Flexible containers having several compartments formed by arranging one flexible container within another
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/0055Containers or packages provided with a flexible bag or a deformable membrane or diaphragm for expelling the contents
    • B65D83/0072Containers or packages provided with a flexible bag or a deformable membrane or diaphragm for expelling the contents the contents of a flexible bag being expelled by a piston or a movable bottom or partition provided in the container or the package
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B2230/00Aspects of the final package
    • B65B2230/02Containers having separate compartments isolated from one another

Definitions

  • the invention relates to a film cartridge and a method for producing a film cartridge.
  • Foil cartridges with one or more chambers containing chemical masses such as putties, sealants or adhesive compounds are known. Such a film cartridge is used in a cartridge holder of a Auspress réelles over which the application of the chemical masses takes place at the desired location.
  • WO 91/07333 A1 describes a film cartridge of highly tear-resistant plastic with a glued or welded spray nozzle with a cap.
  • Out EP 0 992 438 A1 is a cartridge cylinder with a rigid wall, a cartridge outlet with an outlet pipe known.
  • EP 1 331 174 A1 describes a flexible container having a cylindrical element of flexible film, a bottom plate member and a dispensing opening.
  • the object of the invention is to provide a simple and inexpensive to produce film cartridge that is reliable and reproducible to open.
  • a film cartridge comprising a film tube enclosing at least one chamber in the circumferential direction and a cover which is separate from the film tube and terminating an axial end of the film tube, and by forming a plurality of openings, wherein in the cover for each chamber at least one first opening, via which the chamber can be filled with a filling material, and a discharge opening separate from the first opening is formed, wherein a head part is provided, which is fixedly connected to the lid and the one provided on a receptacle for a mixer pipe for dispensing the filling material discharge opening, a A closure which closes the dispensing opening and, for each chamber, has a filling opening which is separate from the dispensing opening and in each case aligned with the first opening in the lid, each filling opening of the head part being closed by a closure.
  • the advantages of the film tube namely fast and cost-effective production and space-saving storage after emptying, are retained.
  • the use of the separate lid allows to provide defined and possibly dimensionally stable openings, which can be released by removing or destroying the closure targeted in a defined diameter.
  • the opening is preferably carried out when the film cartridge is inserted into the Auspress réelle.
  • the film cartridge first to produce and then to fill, since the first opening is easy to close even after a separate filling.
  • since the foil bag was firmly closed at both ends and thus has no opening through which a filling could take place.
  • the second axial end of the film tube may be closed by a separate from the film tube, connected to this bottom. In this way, it is easy to form a cylindrical chamber of defined volume.
  • the bottom can for example consist of the material of the lid or the film tube and correspond in size and dimensions forth at least approximately the lid.
  • the lid is preferably formed of a stiffer material than the film tube, e.g. polyethylene, polypropylene, polybutylene terephthalate or acrylonitrile-butadiene-styrene.
  • the film cartridge may be formed as a multi-chamber cartridge, wherein the various chambers can accommodate different filling materials, which are mixed together only when the material is dispensed.
  • chambers can be filled with different filling materials.
  • the filling materials can form, for example, components of sealants, mortars, coating compositions, paints, foam precursors, adhesives or lubricants. But it is also possible to fill at least two chambers with the same filler material to realize high mixing ratios.
  • Several chambers may be formed, for example, by dividing the film tube by a division in the axial direction into a plurality of chambers, which extend in the axial direction parallel to one another.
  • one or more foil sections which extend in the axial direction parallel to the film tube, can be introduced into the latter and adhesively bonded or welded to the walls of the film tube as well as to each other.
  • the individual chambers are completely separated from each other as long as the film cartridge is closed.
  • a plurality of chambers may also be formed by providing a further film tube which is arranged in the first film tube, so that the first film tube is parallel to the second Foil tube extends.
  • a large volume difference between the chambers can be achieved.
  • a thin second film tube lying within the first film tube can accommodate a component that is needed in a much smaller volume fraction in the final mixture than the component in the large outer chamber.
  • the chambers may be arranged coaxially, but the inner film tube may also be offset from the axis.
  • All chambers preferably extend to the lid, where each chamber has its own first opening. Preferably, all the chambers extend to the bottom.
  • a head part which is firmly connected to the cover and which has a discharge opening provided on a receptacle for a mixer tube for dispensing the filling material.
  • the head part is advantageously made of a relatively rigid material, so that the dispensing opening is not deformed during the dispensing of the filling material.
  • the dispensing opening is closed by a closure (prior to use of the film cartridge).
  • At least one channel for guiding the filling material to the dispensing opening can be formed.
  • one channel per chamber is preferably formed, which advantageously runs separately up to the dispensing opening, in order to prevent mixing of the filling materials of the individual chambers within the film cartridge. Through the channels, the individual components and filling materials are completely separated even before the emergence of the discharge opening even when the film cartridge is opened.
  • connection between the film tube and the lid or bottom and between the lid and the head part can be done by gluing or welding, in particular ultrasonic, laser or thermal welding.
  • Headboard and lid can also be connected by latching or caulking. Of course, a combination of these measures can be used. All compounds are preferably designed so that the chambers are hermetically sealed.
  • a separate from the first opening emptying opening is provided per chamber.
  • This offers various advantages when filling the foil cartridges. For example, it is possible to fill the chamber via the first opening so far that the channel is completely filled up to the dispensing opening with the filling material. This means that the flow can be minimized, since the mixing ratio in multi-component cartridges corresponds directly from the beginning of the desired mixing ratio.
  • one or more foils are preferably provided, such as a composite or monofilm.
  • the films may e.g. consist of one or more layers of polypropylene, polyethylene, polyethylene terephthalate, ethylene vinyl copolymer and / or aluminum.
  • the film is preferably welded or glued to the edge of the opening. For easier removal, it can have a tear-off tab.
  • a metal plate or an injection molded part may be provided, in particular for the filling openings in the head part. These closures are closed with the edge of the opening preferably by gluing or welding.
  • the closure can be placed directly on the respective opening.
  • a film may be designed so that it is removable as a whole and after removal of the film, the discharge opening or the discharge opening completely exposes.
  • a film can also have one or more weakening zones, along which the film tears open in a controlled manner by means of overpressure applied via the dispensing device and defines the dispensing opening or emptying opening in a defined manner.
  • the weakening zone can be produced, for example, very reproducibly by laser ablation.
  • the closure in particular that for the first openings, can be provided, for example, with the material details of the components of the filling material, a batch number or else the expiry date. This can optionally be done by the labeling of the film cartridge.
  • the edge of the first opening and / or the discharge opening may have a conical taper.
  • the taper serves to center a filling lance and thus provide a closer seal between the filling lance and the edge of the opening.
  • At least one lip is formed at the edge of the first opening and / or the discharge opening.
  • the advantageously circumferentially circumferential lip, or a corresponding ridge serves to strip the filler material from the filling lance when retracting the filling lance so that no filling material is introduced into the filling device. It can also be arranged axially behind one another several lips or ridges in order to strip off the largest possible proportion of the filling material.
  • Coarse or comparatively large fillers can also be used in the individual components of the fillers, since the first opening can be made large enough without problems that such components can be filled in without problems. Also, the size of the channels can be easily chosen so that coarser filler can be used in the filling materials.
  • the outer geometry of the film cartridge can be made the same regardless of the number of components used. In this way, a Auspressêt for different types of filling materials can be used.
  • the discharge opening may be closed by a closure provided with a weakening zone, and when applying the squeezing force when inserting a still closed new film cartridge into the squeezing device, the internal pressure exceeds the force necessary to open the weakening zone. In this way, the newly inserted film cartridge is opened automatically and controlled.
  • the foil cartridge is completely finished before it is filled. Any existing floor is already used, so that the chamber with the exception of the first opening and possibly another discharge opening are completely closed.
  • the filling material is then filled into the chamber, which can be done in a different machine than the production of the empty film cartridge. After filling, the first opening is closed, hermetically sealing the foil cartridge.
  • An above-described head portion with the receptacle for the mixer tube for dispensing the filling material is firmly connected to the lid before filling or after filling.
  • the channels between the cover and the head part are filled with the filling material.
  • the filling takes place via the first opening, and this is closed after filling and before attaching the head part.
  • the first opening and / or the emptying opening may remain open, and only the openings (filling opening and dispensing opening) in the head part are closed.
  • the lid Since the lid has an additional discharge opening per chamber, a further filling opening is provided in alignment with the first opening in the head part.
  • the filling is advantageously carried out via a filling lance, which is introduced through the first opening into the chamber, wherein a UnterLiteab colllung is made. As the filling level increases, the filling lance is continually pulled back while it is being filled. So a bubble-free filling of the chambers is possible.
  • the filling process can be supported by vacuum or back pressure. This is particularly useful if the channels are to be filled to the dispensing opening.
  • the air in the chambers may escape through the discharge openings (if provided). It is also possible to form the filling opening in the head part with a smaller cross-section than the first opening during filling when the head part is attached, so that the filling lance lies close to the filling opening, but air can escape from the chamber due to the excess of the first opening during filling ,
  • the film cartridge is easy to open because the film used as a closure can be easily peeled off without tools or, with certain force applied to the film cartridge, tears open from outside through the extrusion tool. Since a defined opening always arises, the forces necessary for the application process are constant during the opening and during the pressing out of the filling material.
  • FIG. 1 shows a film cartridge 100 according to the invention in this case, the film cartridge 100 comprises two film containers 102 and a head portion 104 (see FIG. 3 ).
  • the head portion 104 is connected at an upper axial end to each of two juxtaposed film containers 102.
  • FIG. 2 one of the film containers 102 is shown in more detail.
  • a first, outer film tube 106 is defined by a partition 108 (see FIGS. 6 and 7 ) are subdivided into two parallel chambers 110, 112 separated from one another in the axial direction A.
  • the two chambers 110, 112 may be formed the same size or different sizes, which is achieved by the arrangement of the partition 108.
  • a single subdivision 108 could also be several subdivisions 108 may be provided, which can extend arbitrarily through the cross section of the film tube 106.
  • the film tube 106 and the partition 108 are made of a single piece of film.
  • a closed-tube film tube such as manufactured by extrusion, and insert a partition 108 into the interior.
  • the attachment of the partition 108 to the film tube 106 is done here by gluing or welding by any suitable method.
  • the head portion 104 facing away from the axial end of the film tube 106 is closed by a bottom 114 not shown here.
  • the bottom 114 is a piece of foil bonded to the axial end of the film tube 106 and subdivision 108 by gluing or welding such that the chambers 110, 112 are hermetically sealed from the environment at that end.
  • the chambers 110, 112 are closed by a cover 116 which, like the bottom 114, is fixedly connected to the film tube 106 and the partition 108 by welding or gluing.
  • Foil tube 106, partition 108, bottom 114 and lid 116 define the chambers 110, 112 and enclose them completely.
  • the lid 116 a plurality of openings are formed, wherein per chamber 110, 112, a first opening 118 and a separate discharge opening 120.
  • the lid 116 consists here of a relatively strong film material. It may be stronger than the material used for the film tube 106.
  • the head portion 104 is here made of a stronger material than the lid 116 and causes a dimensional stability of the entire axial upper end of the film cartridge 100. In particular, the head portion 104 ensures that the diameter of the openings even when using the film cartridge 100 in a (not shown ) Pressing device remains constant.
  • openings are also formed, namely a central dispensing opening 122 and for each chamber 110, 112 a separate from the dispensing opening 122 filling opening 124, each aligned with the first openings 118 in the lid 116.
  • FIG. 3 the situation is only shown for one chamber 112 each of a film container 102.
  • the header 104 has only one common delivery opening 122 for all the chambers 110, 112 and all the film containers 102.
  • channels 126 are formed, each leading from one of the discharge openings 120 to the discharge opening 122.
  • the dispensing opening 122 is disposed at the end of a nozzle-like receptacle 128 which forms a receptacle for a mixer tube for dispensing the filling material received in the chambers 110, 112.
  • the partitions 130 which define the channels 126 in the interior between the walls of the head part 104 and the cover 116, extend right up to the discharge opening 122 so that it is effectively divided into as many channels 126 as chambers are provided.
  • the discharge port 122 is sealed by a shutter 132.
  • the closure 132 is a foil which has a weakening zone 134 for each chamber 110, 112, which is in each case arranged centrally above one of the channels 126 in the region of the dispensing opening 122 (see FIG FIG. 5 ).
  • All of the chambers 110, 112 are hermetically sealed from the environment prior to use of the film cartridge 100. A mixing of the different filling materials in the individual chambers 110, 112 does not take place in this state.
  • the filling openings 124 are also tightly closed by a closure 136.
  • the closure 136 is likewise a film which is printed with the product name, the filling materials contained in the individual chambers 110, 112, the batch number and the expiry date of the film cartridge and thus the labeling of the film cartridge 100 is used.
  • closure 136 It is also possible to use a metal plate or an injection-molded part as closure 136. In all cases, the closure 136 completely closes the filling openings 124 so that filling material can not escape from the chambers 110, 112.
  • the head part 104 here extends a filling channel 138 from the edge of the filling opening 124 directly to the first opening 118 in the lid 116.
  • the filling channel has in the region in which it forms the edge of the filling opening 124, a conical taper 140, in a circumferential Lip 142 ends.
  • the lip 142 defines the region of least cross-section of the fill channel 138.
  • the film container 102 is first produced.
  • a film tube 106 is produced from a flat film section or as a film tube with a closed circumference. Any subdivisions 108 are secured in the film tube 106.
  • At the lower axial end of the bottom 114 is inserted and glued or fixed by ultrasonic, laser or thermal welding.
  • the lid 116 is also attached. In this case, the subdivisions 108 are attached to the bottom 114 and lid 116 so that self-contained chambers 110, 112 are formed.
  • the first openings 118 and the emptying openings 120 are still open.
  • the head portion 104 is fixedly secured to the lid 116, such as by gluing or welding.
  • the foil cartridge 100 is now ready to be filled as a prefabricated product. This can be done in a different machine than the production.
  • a filling lance (not shown) is now introduced into the respective chamber 110, 112 and the specific filling material intended for the chamber 110, 112 is introduced.
  • the filling lance is pulled further and further back as the fill level rises, so that a bubble-free bottom-up filling takes place.
  • the conical taper 140 causes a centering of the filling lance in the filling opening 124 and ensures that the filling opening 124 is substantially sealed by the filling lance.
  • the escaping from the chamber 110, 112 air escapes through the discharge opening 120 and the discharge opening 122.
  • the filling lance is pulled back in the course of filling ever further, the lip 142 strips off excess filler from the filling lance, so this does not get into the filling. It could be provided a plurality of axially successively arranged lips 142 in the filling channel 138, wherein only one is shown here.
  • the filling takes place until the filling material emerges from the emptying openings 120 and also fills the channels 126 up to the outlet opening 122.
  • the filling may be assisted by applying a vacuum to the exit port 122 or establishing a backpressure.
  • the outlet opening 122 is sealed with the closure 132.
  • the individual channels 126 are completely separated from each other.
  • the filling openings 124 are sealed with the closures 136.
  • the first openings 118 and the discharge openings 120 remain unlocked in this example.
  • the finished film cartridge 100 may be inserted into a squeezing device in this form, the initially applied pressure causing the weakened zone 134 in the closure 132 of the dispensing opening 122 to rupture.
  • the filling material exits from all chambers 110, 112 in the desired mixing ratio.
  • the closure 132 could also be designed to be removed by the user prior to insertion into the dispenser.
  • the shape of the channels 126 and the size of the emptying openings 120 are selected depending on the filling material used in the chambers 110, 112 so that either openings and channels 126 are large enough to fill materials with larger packing can escape without obstruction or a throttling effect is realized for only a small volume required and / or low-viscosity filling materials.
  • Each of the channels 126 may be formed differently in this sense. The variation can be achieved by the shape of the header 104 and the dividing walls 130.
  • each of the chambers 110, 112 of the two film containers 102 contains a different filling material.
  • the filling materials come into contact with each other only on exiting the dispensing opening 122 and are mixed in the mixer tube placed there.

Description

Die Erfindung betrifft eine Folienkartusche sowie ein Verfahren zur Herstellung einer Folienkartusche.The invention relates to a film cartridge and a method for producing a film cartridge.

Folienkartuschen mit einer oder mehreren Kammern, die chemische Massen wie beispielsweise Spachtelmassen, Dichtmassen oder Klebermassen enthalten, sind bekannt. Eine solche Folienkartusche wird in einen Kartuschenhalter eines Auspressgeräts eingesetzt, über das die Applikation der chemischen Massen an der gewünschten Stelle erfolgt.Foil cartridges with one or more chambers containing chemical masses such as putties, sealants or adhesive compounds are known. Such a film cartridge is used in a cartridge holder of a Auspressgeräts over which the application of the chemical masses takes place at the desired location.

Die Verwendung von Folienkartuschen, bei denen die Kammer im Wesentlichen durch einen Folienschlauch gebildet wird, ist günstig, da leere Kartuschen ohne großen Aufwand und mit geringem Platzbedarf entsorgt werden können. Beispielsweise aus der DE 295 01 255 U1 ist bekannt, die Kammer dadurch zu schaffen, dass die beiden Enden des Folienbeutels zu einem Zopf zusammengefasst werden, der jeweils durch einen Metallclip verschlossen wird. Hier stellt sich jedoch nachteilig heraus, dass zum einen die axialen Enden der Kammer nicht hermetisch abgeschlossen sind, sodass immer eine gewisse Leckage besonders mobiler Flüssigkeitsanteile, teilweise durch Kapillarkräfte im Zopf, erfolgt. Zum anderen stellt sich das Problem des reproduzierbaren Öffnens des Folienbeutels. Hierzu wird in der DE 295 01 255 U1 eine Aufstecheinrichtung eingesetzt, mit zwei Aufstechspaten, die eine definierte Öffnung im Folienbeutel schaffen sollen. Dennoch ist die tatsächliche Form der Öffnung davon abhängig, wie das Folienmaterial im Einzelfall reißt.The use of film cartridges, in which the chamber is essentially formed by a film tube is favorable, since empty cartridges can be disposed of without great effort and with a small footprint. For example, from the DE 295 01 255 U1 It is known to provide the chamber in that the two ends of the film bag are combined into a braid, which is each closed by a metal clip. However, it turns out disadvantageously that on the one hand, the axial ends of the chamber are not hermetically sealed, so always a certain leakage particularly mobile liquid fractions, partially by capillary forces in the braid occurs. On the other hand, there is the problem of reproducible opening of the film bag. This is in the DE 295 01 255 U1 a Aufstecheinrichtung used, with two Aufstechspaten, which has a defined opening in the foil bag should create. Nevertheless, the actual shape of the opening depends on how the film material breaks in individual cases.

WO 91/07333 A1 beschreibt eine Folienkartusche aus hochreißfestem Kunststoff mit einer angeleimten oder angeschweißten Spritzdüse mit einer Verschlusskappe. Aus EP 0 992 438 A1 ist ein Kartuschenzylinder mit starrer Wand, einem Kartuschenauslass mit einem Auslassrohr bekannt. EP 1 331 174 A1 beschreibt einen flexiblen Behälter mit einem zylindrischen Element aus flexibler Folie, einem Bodenplattenelement und einer Ausgabeöffnung. WO 91/07333 A1 describes a film cartridge of highly tear-resistant plastic with a glued or welded spray nozzle with a cap. Out EP 0 992 438 A1 is a cartridge cylinder with a rigid wall, a cartridge outlet with an outlet pipe known. EP 1 331 174 A1 describes a flexible container having a cylindrical element of flexible film, a bottom plate member and a dispensing opening.

Aufgabe der Erfindung ist es, eine einfach und kostengünstig herzustellende Folienkartusche zu schaffen, die verlässlich und reproduzierbar zu öffnen ist.The object of the invention is to provide a simple and inexpensive to produce film cartridge that is reliable and reproducible to open.

Dies wird mit einer Folienkartusche erreicht mit einem wenigstens eine Kammer in Umfangsrichtung umschließenden Folienschlauch und einem vom Folienschlauch separaten Deckel, der ein axiales Ende des Folienschlauchs abschließt, und indem mehrere Öffnungen ausgebildet sind, wobei im Deckel für jede Kammer wenigstens eine erste Öffnung, über die die Kammer mit einem Füllmaterial befüllt werden kann, und eine von der ersten Öffnung separate Entleerungsöffnung ausgebildet ist, wobei ein Kopfteil vorgesehen ist, das fest mit dem Deckel verbunden ist und das eine an einer Aufnahme für ein Mischerrohr zur Ausgabe des Füllmaterials vorgesehene Ausgabeöffnung, einen Verschluss, der die Ausgabeöffnung verschließt, und für jede Kammer eine von der Ausgabeöffnung separate Befüllöffnung, die jeweils mit der ersten Öffnung im Deckel fluchtet, aufweist, wobei jede Befüllöffnung des Kopfteils mit einem Verschluss verschlossen ist. Die Vorteile des Folienschlauchs, nämlich schnelle und kostengünstige Fertigung sowie platzsparende Lagerung nach der Entleerung, bleiben erhalten. Die Verwendung des separaten Deckels erlaubt jedoch, definierte und gegebenenfalls formbeständige Öffnungen vorzusehen, die durch Entfernen oder Zerstören des Verschlusses gezielt in einem definierten Durchmesser freigegeben werden können. Das Öffnen erfolgt vorzugsweise, wenn die Folienkartusche in das Auspressgerät eingesetzt wird. Außerdem ist es aufgrund dieser Gestaltung möglich, die Folienkartusche erst herzustellen und anschließend zu befüllen, da die erste Öffnung auch nach einem separaten Befüllvorgang einfach zu verschließen ist. Bei bisherigen Folienkartuschen erfolgte das Herstellen und Befüllen in einem Arbeitsgang, da der Folienbeutel an beiden Enden fest verschlossen wurde und so keine Öffnung aufweist, durch die eine Befüllung erfolgen könnte.This is achieved with a film cartridge comprising a film tube enclosing at least one chamber in the circumferential direction and a cover which is separate from the film tube and terminating an axial end of the film tube, and by forming a plurality of openings, wherein in the cover for each chamber at least one first opening, via which the chamber can be filled with a filling material, and a discharge opening separate from the first opening is formed, wherein a head part is provided, which is fixedly connected to the lid and the one provided on a receptacle for a mixer pipe for dispensing the filling material discharge opening, a A closure which closes the dispensing opening and, for each chamber, has a filling opening which is separate from the dispensing opening and in each case aligned with the first opening in the lid, each filling opening of the head part being closed by a closure. The advantages of the film tube, namely fast and cost-effective production and space-saving storage after emptying, are retained. The use of the separate lid, however, allows to provide defined and possibly dimensionally stable openings, which can be released by removing or destroying the closure targeted in a defined diameter. The opening is preferably carried out when the film cartridge is inserted into the Auspressgerät. In addition, it is possible due to this design, the film cartridge first to produce and then to fill, since the first opening is easy to close even after a separate filling. In previous film cartridges manufacturing and Filling in one operation, since the foil bag was firmly closed at both ends and thus has no opening through which a filling could take place.

Das zweite axiale Ende des Folienschlauchs kann durch einen vom Folienschlauch separaten, mit diesem verbundenen Boden verschlossen sein. Auf diese Weise lässt sich einfach eine zylindrische Kammer mit definiertem Volumen ausbilden. Der Boden kann beispielsweise aus dem Material des Deckels oder dem des Folienschlauchs bestehen und von der Dimension und den Abmessungen her zumindest in etwa dem Deckel entsprechen.The second axial end of the film tube may be closed by a separate from the film tube, connected to this bottom. In this way, it is easy to form a cylindrical chamber of defined volume. The bottom can for example consist of the material of the lid or the film tube and correspond in size and dimensions forth at least approximately the lid.

Der Deckel ist vorzugsweise aus einem steiferen Material als der Folienschlauch gebildet, z.B. aus Polyethylen, Polypropylen, Polybutylenterephthalat oder Acrylnitril-Butadien-Styrol.The lid is preferably formed of a stiffer material than the film tube, e.g. polyethylene, polypropylene, polybutylene terephthalate or acrylonitrile-butadiene-styrene.

Die Folienkartusche kann als Mehrkammerkartusche ausgebildet sein, wobei die verschiedenen Kammern verschiedene Füllmaterialien aufnehmen können, die erst bei der Ausgabe des Materials miteinander gemischt werden.The film cartridge may be formed as a multi-chamber cartridge, wherein the various chambers can accommodate different filling materials, which are mixed together only when the material is dispensed.

Wenn mehrere Kammern vorgesehen sind, können diese mit unterschiedlichen Füllmaterialien befüllt sein. Die Füllmaterialien können beispielsweise Komponenten von Dichtmassen, Mörteln, Beschichtungsmassen, Farben, Schaumvorprodukten, Klebstoffen oder Schmierstoffen bilden. Es ist aber auch möglich, wenigstens zwei Kammern mit demselben Füllmaterial zu befüllen, um hohe Mischungsverhältnisse zu realisieren. Mehrere Kammern können beispielsweise dadurch gebildet sein, dass der Folienschlauch durch eine Unterteilung in Axialrichtung in mehrere Kammern unterteilt ist, die sich in Axialrichtung parallel zueinander erstrecken. Hierzu können ein oder mehrere Folienabschnitte, die sich in Axialrichtung parallel zum Folienschlauch erstrecken, in diesen eingebracht werden und mit den Wänden des Folienschlauchs sowie untereinander verklebt oder verschweißt werden. Die einzelnen Kammern sind vollständig voneinander getrennt, solange die Folienkartusche verschlossen ist.If several chambers are provided, they can be filled with different filling materials. The filling materials can form, for example, components of sealants, mortars, coating compositions, paints, foam precursors, adhesives or lubricants. But it is also possible to fill at least two chambers with the same filler material to realize high mixing ratios. Several chambers may be formed, for example, by dividing the film tube by a division in the axial direction into a plurality of chambers, which extend in the axial direction parallel to one another. For this purpose, one or more foil sections, which extend in the axial direction parallel to the film tube, can be introduced into the latter and adhesively bonded or welded to the walls of the film tube as well as to each other. The individual chambers are completely separated from each other as long as the film cartridge is closed.

Alternativ, jedoch nicht von der Erfindung umfasst, können mehrere Kammern auch dadurch gebildet sein, dass ein weiterer Folienschlauch vorgesehen ist, der im ersten Folienschlauch angeordnet ist, sodass sich der erste Folienschlauch parallel zum zweiten Folienschlauch erstreckt. Mit dieser Gestaltung kann insbesondere ein großer Volumenunterschied zwischen den Kammern erreicht werden. Ein dünner, innerhalb des ersten Folienschlauchs liegender zweiter Folienschlauch kann eine Komponente aufnehmen, die in einem viel geringeren Volumenanteil in der fertigen Mischung benötigt wird als die Komponente in der großen außen liegenden Kammer. Die Kammern können koaxial angeordnet sein, der innere Folienschlauch kann aber auch von der Achse versetzt sein.Alternatively, but not covered by the invention, a plurality of chambers may also be formed by providing a further film tube which is arranged in the first film tube, so that the first film tube is parallel to the second Foil tube extends. With this design, in particular a large volume difference between the chambers can be achieved. A thin second film tube lying within the first film tube can accommodate a component that is needed in a much smaller volume fraction in the final mixture than the component in the large outer chamber. The chambers may be arranged coaxially, but the inner film tube may also be offset from the axis.

Alle Kammern erstrecken sich vorzugsweise bis zum Deckel, wo jeder Kammer eine eigene erste Öffnung zugeordnet ist. Vorzugsweise erstrecken sich auch sämtliche Kammern bis zum Boden.All chambers preferably extend to the lid, where each chamber has its own first opening. Preferably, all the chambers extend to the bottom.

Erfindungsgemäß ist ein Kopfteil vorgesehen, das fest mit dem Deckel verbunden ist und das eine an einer Aufnahme für ein Mischerrohr zur Ausgabe des Füllmaterials vorgesehene Ausgabeöffnung aufweist. Das Kopfteil ist vorteilhaft aus einem relativ starren Material gefertigt, sodass die Ausgabeöffnung während der Ausgabe des Füllmaterials nicht verformt wird.According to the invention, a head part is provided which is firmly connected to the cover and which has a discharge opening provided on a receptacle for a mixer tube for dispensing the filling material. The head part is advantageously made of a relatively rigid material, so that the dispensing opening is not deformed during the dispensing of the filling material.

Die Ausgabeöffnung ist (vor der Verwendung der Folienkartusche) durch einen Verschluss verschlossen.The dispensing opening is closed by a closure (prior to use of the film cartridge).

Zwischen Deckel und einer Innenwand des Kopfteils lässt sich wenigstens ein Kanal zur Führung des Füllmaterials zur Ausgabeöffnung ausbilden. Bei mehreren Kammern ist bevorzugt ein Kanal pro Kammer gebildet, die vorteilhaft bis zur Ausgabeöffnung getrennt verlaufen, um ein Vermischen der Füllmaterialien der einzelnen Kammern innerhalb der Folienkartusche zu verhindern. Durch die Kanäle sind die einzelnen Komponenten und Füllmaterialien auch bei angebrochener Folienkartusche vor dem Austreten aus der Ausgabeöffnung vollständig voneinander getrennt.Between the cover and an inner wall of the head part, at least one channel for guiding the filling material to the dispensing opening can be formed. In the case of a plurality of chambers, one channel per chamber is preferably formed, which advantageously runs separately up to the dispensing opening, in order to prevent mixing of the filling materials of the individual chambers within the film cartridge. Through the channels, the individual components and filling materials are completely separated even before the emergence of the discharge opening even when the film cartridge is opened.

Die Verbindung zwischen Folienschlauch und Deckel bzw. Boden sowie zwischen Deckel und Kopfteil kann durch Kleben oder Schweißen, insbesondere Ultraschall-, Laser- oder thermisches Schweißen, erfolgen.The connection between the film tube and the lid or bottom and between the lid and the head part can be done by gluing or welding, in particular ultrasonic, laser or thermal welding.

Kopfteil und Deckel können auch durch Verrasten oder durch Verstemmen verbunden werden. Natürlich kann auch eine Kombination dieser Maßnahmen eingesetzt werden. Alle Verbindungen sind vorzugsweise so ausgeführt, dass die Kammern hermetisch dicht verschlossen sind.Headboard and lid can also be connected by latching or caulking. Of course, a combination of these measures can be used. All compounds are preferably designed so that the chambers are hermetically sealed.

Erfindungsgemäß ist pro Kammer eine von der ersten Öffnung separate Entleerungsöffnung vorgesehen. Dies bietet diverse Vorteile bei der Befüllung der Folienkartuschen. Beispielsweise ist es möglich, über die erste Öffnung die Kammer so weit zu befüllen, dass der Kanal bis zur Ausgabeöffnung vollständig mit dem Füllmaterial befüllt ist. Dies führt dazu, dass der Vorlauf minimiert werden kann, da das Mischungsverhältnis bei Mehrkomponentenkartuschen direkt von Anfang an dem gewünschten Mischungsverhältnis entspricht.According to the invention, a separate from the first opening emptying opening is provided per chamber. This offers various advantages when filling the foil cartridges. For example, it is possible to fill the chamber via the first opening so far that the channel is completely filled up to the dispensing opening with the filling material. This means that the flow can be minimized, since the mixing ratio in multi-component cartridges corresponds directly from the beginning of the desired mixing ratio.

Es ist möglich, nebeneinanderliegende erste Öffnungen, Entleerungsöffnungen oder Befüllöffnungen mit gemeinsamen Verschlüssen zu verschließen.It is possible to close adjacent first openings, emptying openings or filling openings with common closures.

Als Verschluss sowohl der ersten Öffnungen, der Entleerungsöffnungen als auch der Ausgabeöffnung sind vorzugsweise eine oder mehrere Folien vorgesehen, etwa eine Verbund- oder Monofolie. Die Folien können z.B. aus einer oder mehreren Lagen Polypropylen, Polyethylen, Polyethylenterephtalat, Ethylenvinylcopolymer und/oder Aluminium bestehen.As a closure of both the first openings, the emptying openings and the discharge opening, one or more foils are preferably provided, such as a composite or monofilm. The films may e.g. consist of one or more layers of polypropylene, polyethylene, polyethylene terephthalate, ethylene vinyl copolymer and / or aluminum.

Die Folie wird vorzugsweise mit dem Rand der Öffnung verschweißt oder verklebt. Zur leichteren Entfernung kann sie eine Abreißlasche aufweisen.The film is preferably welded or glued to the edge of the opening. For easier removal, it can have a tear-off tab.

Als Verschluss kann auch ein Metallplättchen oder ein Spritzgussteil vorgesehen sein, insbesondere für die Befüllöffnungen im Kopfteil. Auch diese Verschlüsse werden mit dem Rand der Öffnung vorzugsweise durch Kleben oder Schweißen verschlossen.As a closure, a metal plate or an injection molded part may be provided, in particular for the filling openings in the head part. These closures are closed with the edge of the opening preferably by gluing or welding.

Der Verschluss kann unmittelbar auf die jeweilige Öffnung aufgesetzt sein.The closure can be placed directly on the respective opening.

Zur Öffnung bzw. Entfernung des Verschlusses sind mehrere Möglichkeiten denkbar. Beispielsweise kann eine Folie so gestaltet sein, dass sie als Ganzes abziehbar ist und nach Entfernen der Folie die Entleerungsöffnung oder die Ausgabeöffnung vollständig freilegt. Eine Folie kann aber auch eine oder mehrere Schwächungszonen aufweisen, entlang derer die Folie durch über das Auspressgerät aufgebrachten Überdruck kontrolliert aufreißt und definiert die Ausgabeöffnung oder Entleerungsöffnung freigibt. Die Schwächungszone lässt sich beispielsweise sehr reproduzierbar durch Laserabtrag herstellen.For opening or removal of the closure several possibilities are conceivable. For example, a film may be designed so that it is removable as a whole and after removal of the film, the discharge opening or the discharge opening completely exposes. However, a film can also have one or more weakening zones, along which the film tears open in a controlled manner by means of overpressure applied via the dispensing device and defines the dispensing opening or emptying opening in a defined manner. The weakening zone can be produced, for example, very reproducibly by laser ablation.

Der Verschluss, insbesondere der für die ersten Öffnungen, kann beispielsweise mit den Materialangaben der Komponenten des Füllmaterials, einer Chargennummer oder auch dem Verfallsdatum versehen sein. Hierüber kann gegebenenfalls auch die Etikettierung der Folienkartusche erfolgen.The closure, in particular that for the first openings, can be provided, for example, with the material details of the components of the filling material, a batch number or else the expiry date. This can optionally be done by the labeling of the film cartridge.

Um den Befüllvorgang zu verbessern, kann der Rand der ersten Öffnung und/oder der Ausgabeöffnung eine konische Verjüngung aufweisen. Die Verjüngung dient dazu, eine Fülllanze zu zentrieren und somit einen dichteren Abschluss zwischen der Fülllanze und dem Rand der Öffnung herzustellen.In order to improve the filling process, the edge of the first opening and / or the discharge opening may have a conical taper. The taper serves to center a filling lance and thus provide a closer seal between the filling lance and the edge of the opening.

Vorzugsweise ist am Rand der ersten Öffnung und/oder der Ausgabeöffnung wenigstens eine Lippe ausgebildet. Die vorteilhaft umfangsmäßig umlaufende Lippe, oder auch ein entsprechender Grat, dient zum Abstreifen des Füllmaterials von der Fülllanze beim Zurückziehen der Fülllanze, sodass kein Füllmaterial in die Befüllungsvorrichtung eingebracht wird. Es können auch mehrere Lippen oder Grate axial hintereinander angeordnet sein, um einen möglichst großen Anteil des Füllmaterials abzustreifen.Preferably, at least one lip is formed at the edge of the first opening and / or the discharge opening. The advantageously circumferentially circumferential lip, or a corresponding ridge, serves to strip the filler material from the filling lance when retracting the filling lance so that no filling material is introduced into the filling device. It can also be arranged axially behind one another several lips or ridges in order to strip off the largest possible proportion of the filling material.

In den einzelnen Komponenten der Füllmaterialien können auch grobe oder vergleichsweise große Füllkörper verwendet werden, da die erste Öffnung ohne Probleme so groß gestaltet werden kann, dass derartige Komponenten problemlos eingefüllt werden können. Auch die Größe der Kanäle kann einfach so gewählt werden, dass auch gröbere Füllkörper in den Füllmaterialien eingesetzt werden können.Coarse or comparatively large fillers can also be used in the individual components of the fillers, since the first opening can be made large enough without problems that such components can be filled in without problems. Also, the size of the channels can be easily chosen so that coarser filler can be used in the filling materials.

Da die Kammern hermetisch verschlossen und voneinander getrennt sind und die Leckagerate aufgrund der Gestalt der Kammern praktisch null ist, lassen sich lange Lagerdauern erreichen.Since the chambers are hermetically sealed and separated from each other and the leakage rate is virtually zero due to the shape of the chambers, long storage periods can be achieved.

Die Außengeometrie der Folienkartusche kann unabhängig von der Zahl der verwendeten Komponenten gleich gestaltet werden. Auf diese Weise ist ein Auspressgerät für verschiedene Arten von Füllmaterialien verwendbar.The outer geometry of the film cartridge can be made the same regardless of the number of components used. In this way, a Auspressgerät for different types of filling materials can be used.

Die Entleerungsöffnung kann durch einen mit einer Schwächungszone versehenen Verschluss verschlossen sein und beim Aufbringen der Auspresskraft beim Einlegen einer noch verschlossenen neuen Folienkartusche in das Auspressgerät übersteigt der Innendruck die Kraft, die notwendig ist, um die Schwächungszone zu öffnen. Auf diese Weise wird die neu eingelegte Folienkartusche automatisch und kontrolliert geöffnet.The discharge opening may be closed by a closure provided with a weakening zone, and when applying the squeezing force when inserting a still closed new film cartridge into the squeezing device, the internal pressure exceeds the force necessary to open the weakening zone. In this way, the newly inserted film cartridge is opened automatically and controlled.

Durch die Gestaltung des Querschnitts der Kanäle und/oder des Querschnitts der ersten Öffnungen bzw. Entleerungsöffnungen kann eine Drosselwirkung einzelner Füllmaterialien aus unterschiedlichen Kammern bewirkt werden, wodurch sich die Menge des jeweils ausgegebenen Füllmaterials sehr genau einstellen lässt. Auch Fließunterschiede bei unterschiedlichen Rheologien der einzelnen Füllmaterialien können so ausgeglichen werden.By designing the cross section of the channels and / or the cross section of the first openings or emptying openings, a throttling action of individual filling materials can be effected from different chambers, whereby the amount of each discharged filling material can be set very precisely. Even flow differences at different rheologies of the individual fillers can be compensated.

Bei einem Verfahren zur Herstellung einer Folienkartusche, wie sie oben beschrieben wurde, werden die folgenden Schritte ausgeführt:

  • Herstellen wenigstens einer Kammer durch Verbinden des Deckels mit dem Folienschlauch,
  • Befüllen der Kammer mit einem Füllmaterial durch die erste Öffnung im Deckel und
  • Verschließen der ersten Öffnung.
In a process for producing a film cartridge as described above, the following steps are carried out:
  • Producing at least one chamber by connecting the lid to the film tube,
  • Filling the chamber with a filling material through the first opening in the lid and
  • Closing the first opening.

Die Folienkartusche wird vollständig gefertigt, bevor sie befüllt wird. Auch ein eventuell vorhandener Boden wird bereits eingesetzt, sodass die Kammer mit Ausnahme der ersten Öffnung und eventuell einer weiteren Entleerungsöffnung vollständig geschlossen sind. Als zweiter Schritt wird dann das Füllmaterial in die Kammer eingefüllt, was in einer anderen Maschine erfolgen kann als die Fertigung der leeren Folienkartusche. Nach dem Befüllen wird die erste Öffnung verschlossen und so die Folienkartusche hermetisch verschlossen.The foil cartridge is completely finished before it is filled. Any existing floor is already used, so that the chamber with the exception of the first opening and possibly another discharge opening are completely closed. As a second step, the filling material is then filled into the chamber, which can be done in a different machine than the production of the empty film cartridge. After filling, the first opening is closed, hermetically sealing the foil cartridge.

Ein oben beschriebenes Kopfteil mit der Aufnahme für das Mischerrohr zur Ausgabe des Füllmaterials wird vor dem Befüllen oder nach dem Befüllen fest mit dem Deckel verbunden.An above-described head portion with the receptacle for the mixer tube for dispensing the filling material is firmly connected to the lid before filling or after filling.

Erfolgt das Befüllen nach dem Aufsetzen des Kopfteils, werden vorzugsweise auch die Kanäle zwischen Deckel und Kopfteil mit dem Füllmaterial befüllt.If filling takes place after placement of the head part, preferably also the channels between the cover and the head part are filled with the filling material.

Wird das Kopfteil nach dem Befüllen aufgesetzt, erfolgt das Befüllen über die erste Öffnung, und diese wird nach dem Befüllen und vor Befestigen des Kopfteils verschlossen.If the head part is placed after filling, the filling takes place via the first opening, and this is closed after filling and before attaching the head part.

Erfolgt das Befüllen nach Aufsetzen des Kopfteils, kann die erste Öffnung und/oder die Entleerungsöffnung offen bleiben, und es werden nur die Öffnungen (Befüllöffnung und Ausgabeöffnung) im Kopfteil verschlossen.If the filling is carried out after placing the head part, the first opening and / or the emptying opening may remain open, and only the openings (filling opening and dispensing opening) in the head part are closed.

Da der Deckel eine zusätzliche Entleerungsöffnung pro Kammer aufweist, ist fluchtend mit der ersten Öffnung im Kopfteil eine weitere Befüllöffnung vorgesehen.Since the lid has an additional discharge opening per chamber, a further filling opening is provided in alignment with the first opening in the head part.

Das Befüllen erfolgt vorteilhaft über eine Fülllanze, die durch die erste Öffnung in die Kammer eingeführt wird, wobei eine Unterspiegelabfüllung vorgenommen wird. Mit zunehmendem Füllstand wird dabei während des Befüllens die Fülllanze immer weiter zurückgezogen. So ist eine luftblasenfreie Befüllung der Kammern möglich. Der Befüllvorgang kann durch Vakuum oder Gegendruck unterstützt werden. Dies ist insbesondere nützlich, wenn auch die Kanäle bis zur Ausgabeöffnung befüllt werden sollen.The filling is advantageously carried out via a filling lance, which is introduced through the first opening into the chamber, wherein a Unterspiegelabfüllung is made. As the filling level increases, the filling lance is continually pulled back while it is being filled. So a bubble-free filling of the chambers is possible. The filling process can be supported by vacuum or back pressure. This is particularly useful if the channels are to be filled to the dispensing opening.

Die Luft in den Kammern kann beispielsweise durch die Entleerungsöffnungen entweichen (wenn diese vorgesehen sind). Es ist auch möglich, bei der Befüllung bei aufgesetztem Kopfteil die Befüllöffnung im Kopfteil mit einem geringeren Querschnitt auszubilden als die erste Öffnung, sodass zwar die Fülllanze dicht an der Befüllöffnung anliegt, aber Luft durch das Übermaß der ersten Öffnung beim Befüllen aus der Kammer entweichen kann.For example, the air in the chambers may escape through the discharge openings (if provided). It is also possible to form the filling opening in the head part with a smaller cross-section than the first opening during filling when the head part is attached, so that the filling lance lies close to the filling opening, but air can escape from the chamber due to the excess of the first opening during filling ,

Die Folienkartusche ist einfach zu öffnen, da die Folie, die als Verschluss verwendet wird, einfach ohne Werkzeug abgezogen werden kann oder bei bestimmter Kraftausübung auf die Folienkartusche von außen durch das Auspresswerkzeug definiert aufreißt. Da immer eine definierte Öffnung entsteht, sind die für den Applikationsvorgang notwendigen Kräfte bei der Öffnung und beim Auspressen des Füllmaterials gleichbleibend.The film cartridge is easy to open because the film used as a closure can be easily peeled off without tools or, with certain force applied to the film cartridge, tears open from outside through the extrusion tool. Since a defined opening always arises, the forces necessary for the application process are constant during the opening and during the pressing out of the filling material.

Die Erfindung wird nachfolgend anhand mehrerer Ausführungsbeispiele mit Bezug auf die beigefügten Zeichnungen näher beschrieben. In den Zeichnungen zeigen:

FIG.1
eine schematische Draufsicht einer erfindungsgemäßen Folienkartusche gemäß einer ersten Ausführungsform;
FIG. 2
eine schematische perspektivische Ansicht eines Teils der Folienkartusche aus Figur 1;
FIG. 3
eine schematische Schnittansicht des oberen Teils der Folienkartusche aus Figur 1;
FIG. 4
eine schematische Detailansicht aus Figur 3;
FIG. 5
eine schematische Ansicht eines Verschlusses für eine erfindungsgemäße Folienkartusche;
FIG. 6 und 7
schematisch eine Unterteilung eines Folienschlauchs einer erfindungsgemäßen Folienkartusche;
The invention is described below with reference to several embodiments with reference to the accompanying drawings. In the drawings show:
FIG.1
a schematic plan view of a film cartridge according to the invention according to a first embodiment;
FIG. 2
a schematic perspective view of a portion of the film cartridge FIG. 1 ;
FIG. 3
a schematic sectional view of the upper part of the film cartridge FIG. 1 ;
FIG. 4
a schematic detail view FIG. 3 ;
FIG. 5
a schematic view of a closure for a film cartridge according to the invention;
FIG. 6 and 7
schematically a subdivision of a film tube of a film cartridge according to the invention;

Figur 1 zeigt eine erfindungsgemäße Folienkartusche 100. Die Folienkartusche 100 umfasst in diesem Fall zwei Folienbehälter 102 sowie ein Kopfteil 104 (siehe Figur 3). Das Kopfteil 104 ist an einem oberen axialen Ende mit jedem der beiden nebeneinander angeordneten Folienbehälter 102 verbunden. FIG. 1 shows a film cartridge 100 according to the invention in this case, the film cartridge 100 comprises two film containers 102 and a head portion 104 (see FIG. 3 ). The head portion 104 is connected at an upper axial end to each of two juxtaposed film containers 102.

In Figur 2 ist einer der Folienbehälter 102 näher dargestellt. Ein erster, äußerer Folienschlauch 106 ist durch eine Unterteilung 108 (siehe Figuren 6 und 7) in zwei in Axialrichtung A voneinander getrennte, parallele Kammern 110, 112 unterteilt. Wie die Figuren 6 und 7 zeigen, können die beiden Kammern 110, 112 gleich groß oder unterschiedlich groß ausgebildet sein, was durch die Anordnung der Unterteilung 108 erreicht wird. Anstatt einer einzigen Unterteilung 108 könnten auch mehrere Unterteilungen 108 vorgesehen sein, die sich beliebig durch den Querschnitt des Folienschlauchs 106 erstrecken können.In FIG. 2 one of the film containers 102 is shown in more detail. A first, outer film tube 106 is defined by a partition 108 (see FIGS. 6 and 7 ) are subdivided into two parallel chambers 110, 112 separated from one another in the axial direction A. As the FIGS. 6 and 7 show, the two chambers 110, 112 may be formed the same size or different sizes, which is achieved by the arrangement of the partition 108. Instead of a single subdivision 108 could also be several subdivisions 108 may be provided, which can extend arbitrarily through the cross section of the film tube 106.

In den Figuren 6 und 7 sind der Folienschlauch 106 und die Unterteilung 108 aus einem einzigen Folienstück gefertigt. Es wäre jedoch auch möglich, einen Folienschlauch mit geschlossenem Umfang, beispielsweise hergestellt durch Extrusion, zu verwenden, und eine Unterteilung 108 in das Innere einzubringen. Die Befestigung der Unterteilung 108 am Folienschlauch 106 erfolgt hier durch Kleben oder Schweißen nach einem beliebigen geeigneten Verfahren.In the FIGS. 6 and 7 For example, the film tube 106 and the partition 108 are made of a single piece of film. However, it would also be possible to use a closed-tube film tube, such as manufactured by extrusion, and insert a partition 108 into the interior. The attachment of the partition 108 to the film tube 106 is done here by gluing or welding by any suitable method.

Das dem Kopfteil 104 abgewandte axiale Ende des Folienschlauchs 106 ist durch einen hier nicht weiter dargestellten Boden 114 verschlossen. Der Boden 114 ist hier ein Stück Folie, das mit dem axialen Ende des Folienschlauchs 106 und der Unterteilung 108 durch Kleben oder Schweißen verbunden ist, sodass die Kammern 110, 112 an diesem Ende hermetisch gegenüber der Umgebung abgeschlossen sind.The head portion 104 facing away from the axial end of the film tube 106 is closed by a bottom 114 not shown here. Here, the bottom 114 is a piece of foil bonded to the axial end of the film tube 106 and subdivision 108 by gluing or welding such that the chambers 110, 112 are hermetically sealed from the environment at that end.

Am axial oberen Ende sind die Kammern 110, 112 durch einen Deckel 116 verschlossen, der wie der Boden 114 mit dem Folienschlauch 106 und der Unterteilung 108 fest verbunden ist, durch Schweißen oder Kleben. Folienschlauch 106, Unterteilung 108, Boden 114 und Deckel 116 begrenzen die Kammern 110, 112 und umschließen sie vollständig.At the axially upper end, the chambers 110, 112 are closed by a cover 116 which, like the bottom 114, is fixedly connected to the film tube 106 and the partition 108 by welding or gluing. Foil tube 106, partition 108, bottom 114 and lid 116 define the chambers 110, 112 and enclose them completely.

Im Deckel 116 sind jedoch mehrere Öffnungen ausgebildet, wobei pro Kammer 110, 112 eine erste Öffnung 118 sowie eine davon separate Entleerungsöffnung 120. Der Deckel 116 besteht hier aus einem relativ festen Folienmaterial. Es kann fester sein als das Material, das für den Folienschlauch 106 eingesetzt wird. Das Kopfteil 104 ist hier aus einem festeren Material als der Deckel 116 gefertigt und bewirkt eine Formstabilität des gesamten axialen oberen Endes der Folienkartusche 100. Insbesondere sorgt das Kopfteil 104 dafür, dass der Durchmesser der Öffnungen auch bei Verwendung der Folienkartusche 100 in einem (nicht dargestellten) Auspressgerät konstant bleibt.In the lid 116, however, a plurality of openings are formed, wherein per chamber 110, 112, a first opening 118 and a separate discharge opening 120. The lid 116 consists here of a relatively strong film material. It may be stronger than the material used for the film tube 106. The head portion 104 is here made of a stronger material than the lid 116 and causes a dimensional stability of the entire axial upper end of the film cartridge 100. In particular, the head portion 104 ensures that the diameter of the openings even when using the film cartridge 100 in a (not shown ) Pressing device remains constant.

Im Kopfteil 104 sind ebenfalls Öffnungen ausgebildet, nämlich eine zentrale Ausgabeöffnung 122 sowie für jede Kammer 110, 112 eine von der Ausgabeöffnung 122 separate Befüllöffnung 124, die jeweils mit den ersten Öffnungen 118 im Deckel 116 fluchten. In Figur 3 ist die Situation nur jeweils für eine Kammer 112 jeweils eines Folienbehälters 102 dargestellt. Jedoch weist das Kopfteil 104 nur eine gemeinsame Ausgabeöffnung 122 für sämtliche Kammern 110, 112 und alle Folienbehälter 102 auf.In the head part 104 openings are also formed, namely a central dispensing opening 122 and for each chamber 110, 112 a separate from the dispensing opening 122 filling opening 124, each aligned with the first openings 118 in the lid 116. In FIG. 3 the situation is only shown for one chamber 112 each of a film container 102. However, the header 104 has only one common delivery opening 122 for all the chambers 110, 112 and all the film containers 102.

Zwischen der Innenwand des Kopfteils 104 und der Oberseite des Deckels 116 sind Kanäle 126 ausgebildet, die jeweils von einer der Entleerungsöffnungen 120 bis zur Ausgabeöffnung 122 führen.Between the inner wall of the head portion 104 and the top of the lid 116 channels 126 are formed, each leading from one of the discharge openings 120 to the discharge opening 122.

Die Ausgabeöffnung 122 ist am Ende einer stutzenförmigen Aufnahme 128 angeordnet, der eine Aufnahme für ein Mischerrohr zur Ausgabe des in den Kammern 110, 112 aufgenommenen Füllmaterials bildet.The dispensing opening 122 is disposed at the end of a nozzle-like receptacle 128 which forms a receptacle for a mixer tube for dispensing the filling material received in the chambers 110, 112.

Die Trennwände 130, die die Kanäle 126 im Innenraum zwischen den Wandungen des Kopfteils 104 und dem Deckel 116 begrenzen, reichen bis unmittelbar zur Ausgabeöffnung 122, sodass diese effektiv in so viele Kanäle 126 unterteilt ist, wie Kammern vorgesehen sind.The partitions 130, which define the channels 126 in the interior between the walls of the head part 104 and the cover 116, extend right up to the discharge opening 122 so that it is effectively divided into as many channels 126 as chambers are provided.

Bevor die Folienkartusche 100 verwendet wird, ist die Ausgabeöffnung 122 durch einen Verschluss 132 dicht abgeschlossen. Im hier gezeigten Fall ist der Verschluss 132 eine Folie, die für jede Kammer 110, 112 eine Schwächungszone 134 aufweist, die jeweils mittig über einem der Kanäle 126 im Bereich der Ausgabeöffnung 122 angeordnet ist (siehe Figur 5).Before the film cartridge 100 is used, the discharge port 122 is sealed by a shutter 132. In the case shown here, the closure 132 is a foil which has a weakening zone 134 for each chamber 110, 112, which is in each case arranged centrally above one of the channels 126 in the region of the dispensing opening 122 (see FIG FIG. 5 ).

Sämtliche Kammern 110, 112 sind vor der Verwendung der Folienkartusche 100 hermetisch gegenüber der Umgebung abgeschlossen. Eine Vermischung der unterschiedlichen Füllmaterialien in den einzelnen Kammern 110, 112 findet in diesem Zustand nicht statt.All of the chambers 110, 112 are hermetically sealed from the environment prior to use of the film cartridge 100. A mixing of the different filling materials in the individual chambers 110, 112 does not take place in this state.

Die Befüllöffnungen 124 sind ebenfalls dicht verschlossen von einem Verschluss 136. Bei dem Verschluss 136 handelt es sich hier ebenfalls um eine Folie, die mit dem Produktnamen, den in den einzelnen Kammern 110, 112 enthaltenen Füllmaterialien, der Chargennummer sowie dem Verfallsdatum der Folienkartusche bedruckt ist und somit der Etikettierung der Folienkartusche 100 dient.The filling openings 124 are also tightly closed by a closure 136. The closure 136 is likewise a film which is printed with the product name, the filling materials contained in the individual chambers 110, 112, the batch number and the expiry date of the film cartridge and thus the labeling of the film cartridge 100 is used.

Es ist auch möglich, als Verschluss 136 ein Metallplättchen oder ein Spritzgussteil einzusetzen. In allen Fällen verschließt der Verschluss 136 die Befüllöffnungen 124 vollkommen dicht, sodass Füllmaterial nicht aus den Kammern 110, 112 austreten kann.It is also possible to use a metal plate or an injection-molded part as closure 136. In all cases, the closure 136 completely closes the filling openings 124 so that filling material can not escape from the chambers 110, 112.

Im Kopfteil 104 erstreckt sich hier ein Füllkanal 138 vom Rand der Befüllöffnung 124 bis direkt zur ersten Öffnung 118 im Deckel 116. Der Füllkanal hat in dem Bereich, in dem er den Rand der Befüllöffnung 124 bildet, eine konische Verjüngung 140, die in einer umlaufenden Lippe 142 endet. Die Lippe 142 definiert den Bereich mit geringstem Querschnitt des Füllkanals 138.In the head part 104 here extends a filling channel 138 from the edge of the filling opening 124 directly to the first opening 118 in the lid 116. The filling channel has in the region in which it forms the edge of the filling opening 124, a conical taper 140, in a circumferential Lip 142 ends. The lip 142 defines the region of least cross-section of the fill channel 138.

Bei der Herstellung der Folienkartusche 100 wird zunächst der Folienbehälter 102 hergestellt. Hierzu wird ein Folienschlauch 106 aus einem flachen Folienabschnitt oder als Folienschlauch mit geschlossenem Umfang hergestellt. Etwaige Unterteilungen 108 werden im den Folienschlauch 106 befestigt. An das untere axiale Ende wird der Boden 114 eingesetzt und verklebt oder durch Ultraschall-, Laser- oder thermisches Schweißen befestigt. Am entgegengesetzten axialen Ende wird der Deckel 116 ebenfalls befestigt. Dabei werden auch die Unterteilungen 108 am Boden 114 und Deckel 116 befestigt, sodass in sich abgeschlossene Kammern 110, 112 gebildet sind. Die ersten Öffnungen 118 und die Entleerungsöffnungen 120 sind noch geöffnet.In the production of the film cartridge 100, the film container 102 is first produced. For this purpose, a film tube 106 is produced from a flat film section or as a film tube with a closed circumference. Any subdivisions 108 are secured in the film tube 106. At the lower axial end of the bottom 114 is inserted and glued or fixed by ultrasonic, laser or thermal welding. At the opposite axial end of the lid 116 is also attached. In this case, the subdivisions 108 are attached to the bottom 114 and lid 116 so that self-contained chambers 110, 112 are formed. The first openings 118 and the emptying openings 120 are still open.

Als Nächstes wird das Kopfteil 104 mit dem Deckel 116 fest verbunden, beispielsweise durch Kleben oder Schweißen.Next, the head portion 104 is fixedly secured to the lid 116, such as by gluing or welding.

Jetzt sind auch die Kanäle 126 zwischen Deckel 116 und Kopfteil 104 ausgebildet. Die Ausgabeöffnung 122 ist ebenfalls noch geöffnet, genauso wie die Einfüllöffnungen 124. Die Folienkartusche 100 ist jetzt als vorgefertigtes Produkt zur Befüllung bereit. Diese kann in einer anderen Maschine erfolgen als die Herstellung.Now, the channels 126 between the lid 116 and head 104 are formed. The dispensing opening 122 is also still open, as are the fill openings 124. The foil cartridge 100 is now ready to be filled as a prefabricated product. This can be done in a different machine than the production.

Über die Einfüllöffnungen 124 und die ersten Öffnungen 118 wird nun eine (nicht dargestellte) Fülllanze in die jeweilige Kammer 110, 112 eingeführt und das für die Kammer 110, 112 bestimmte spezifische Füllmaterial eingebracht. Die Fülllanze wird dabei beginnend vom Boden der Kammer 110, 112 mit steigendem Füllstand immer weiter zurückgezogen, sodass eine blasenfreie Unterspiegelbefüllung erfolgt. Die konische Verjüngung 140 bewirkt eine Zentrierung der Fülllanze in der Befüllöffnung 124 und sorgt dafür, dass die Befüllöffnung 124 durch die Fülllanze im Wesentlichen abgedichtet ist. Die aus der Kammer 110, 112 entweichende Luft entweicht durch die Entleerungsöffnung 120 und die Ausgabeöffnung 122. Die Fülllanze wird im Verlauf des Befüllens immer weiter zurückgezogen, wobei die Lippe 142 überschüssiges Füllmaterial von der Fülllanze abstreift, sodass dies nicht in die Befüllvorrichtung gelangt. Es könnten mehrere axial hintereinander angeordnete Lippen 142 im Füllkanal 138 vorgesehen sein, wobei hier nur eine dargestellt ist.Via the filling openings 124 and the first openings 118, a filling lance (not shown) is now introduced into the respective chamber 110, 112 and the specific filling material intended for the chamber 110, 112 is introduced. Starting from the bottom of the chamber 110, 112, the filling lance is pulled further and further back as the fill level rises, so that a bubble-free bottom-up filling takes place. The conical taper 140 causes a centering of the filling lance in the filling opening 124 and ensures that the filling opening 124 is substantially sealed by the filling lance. The escaping from the chamber 110, 112 air escapes through the discharge opening 120 and the discharge opening 122. The filling lance is pulled back in the course of filling ever further, the lip 142 strips off excess filler from the filling lance, so this does not get into the filling. It could be provided a plurality of axially successively arranged lips 142 in the filling channel 138, wherein only one is shown here.

Die Befüllung erfolgt so lange, bis das Füllmaterial aus den Entleerungsöffnungen 120 austritt und auch die Kanäle 126 bis zur Austrittsöffnung 122 auffüllt.The filling takes place until the filling material emerges from the emptying openings 120 and also fills the channels 126 up to the outlet opening 122.

Die Befüllung kann durch Anlegen eines Vakuums an die Austrittsöffnung 122 oder Aufbau eines Gegendrucks unterstützt werden.The filling may be assisted by applying a vacuum to the exit port 122 or establishing a backpressure.

Nachdem die Befüllung abgeschlossen ist, wird die Austrittsöffnung 122 mit dem Verschluss 132 dicht verschlossen. Dabei werden auch die einzelnen Kanäle 126 vollständig voneinander getrennt.After the filling is completed, the outlet opening 122 is sealed with the closure 132. In this case, the individual channels 126 are completely separated from each other.

Auch die Befüllöffnungen 124 werden mit den Verschlüssen 136 dicht verschlossen. Die ersten Öffnungen 118 und die Entleerungsöffnungen 120 bleiben in diesem Beispiel unverschlossen.The filling openings 124 are sealed with the closures 136. The first openings 118 and the discharge openings 120 remain unlocked in this example.

Die fertige Folienkartusche 100 kann in dieser Form in eine Auspressvorrichtung eingesetzt werden, wobei der anfänglich aufgebrachte Druck dafür sorgt, dass die Schwächungszone 134 im Verschluss 132 der Ausgabeöffnung 122 aufreißen. Bereits ab diesem Zeitpunkt tritt das Füllmaterial aus allen Kammern 110, 112 im gewünschten Mischungsverhältnis aus.The finished film cartridge 100 may be inserted into a squeezing device in this form, the initially applied pressure causing the weakened zone 134 in the closure 132 of the dispensing opening 122 to rupture. Already from this point on, the filling material exits from all chambers 110, 112 in the desired mixing ratio.

Der Verschluss 132 könnte auch so gestaltet sein, dass er vom Benutzer vor Einsetzen in das Auspressgerät abgezogen wird.The closure 132 could also be designed to be removed by the user prior to insertion into the dispenser.

Die Form der Kanäle 126 und die Größe der Entleerungsöffnungen 120 ist abhängig vom in den Kammern 110, 112 verwendeten Füllmaterial so gewählt, dass entweder Öffnungen und Kanäle 126 groß genug sind, um Füllmaterialien mit größeren Füllkörpern ohne Behinderung ausströmen können oder eine Drosselwirkung für nur in geringem Volumen benötigte und/oder dünnflüssige Füllmaterialien realisiert ist. Jeder der Kanäle 126 kann in diesem Sinn unterschiedlich ausgebildet sein. Die Variation kann durch die Form des Kopfteils 104 und die Trennwände 130 erreicht werden.The shape of the channels 126 and the size of the emptying openings 120 are selected depending on the filling material used in the chambers 110, 112 so that either openings and channels 126 are large enough to fill materials with larger packing can escape without obstruction or a throttling effect is realized for only a small volume required and / or low-viscosity filling materials. Each of the channels 126 may be formed differently in this sense. The variation can be achieved by the shape of the header 104 and the dividing walls 130.

Im gezeigten Fall ist eine Vierkomponentenkartusche realisiert, bei der jede der Kammern 110, 112 der beiden Folienbehälter 102 ein unterschiedliches Füllmaterial enthält. Die Füllmaterialien kommen erst beim Austritt aus der Ausgabeöffnung 122 miteinander in Kontakt und werden im dort aufgesetzten Mischerrohr vermischt.In the case shown, a four-component cartridge is realized in which each of the chambers 110, 112 of the two film containers 102 contains a different filling material. The filling materials come into contact with each other only on exiting the dispensing opening 122 and are mixed in the mixer tube placed there.

Claims (6)

  1. Film cartridge having a tube of film (106) which surrounds at least one chamber (110, 112, 113) in the circumferential direction and having a cap (116), separate from the tube of film (106), which terminates one axial end of the tube of film (106) and there being a plurality of openings formed, there being formed in the cap (116; 216; 316; 416), for each chamber (110, 112, 113), at least one first opening (118) via which the chamber (110, 112, 113) can be filled with a filling material, and at least one emptying opening (120) separate from the first opening (118), wherein a head part (104) is provided which is solidly connected to the cap (116) and which has a dispensing opening (122) provided at a receiving means (128) for a mixing tube intended for dispensing the filling material, which has a closure (132) which closes off the dispensing opening (122), and which has, for each chamber, a filling opening (124), separate from the dispensing opening (122), which is in line with the respective first opening (118) in the cap (116), each filling opening (124) in the head part being closed off with a closure (136).
  2. Film cartridge according to claim 1, characterised in that a plurality of chambers (110, 112, 113) are provided which are separated from one another by dividing up the tube of film (106) in the axial direction (A).
  3. Film cartridge according to claim 1 or 2, characterised in that there is formed between the cap (116) and an inner wall of the head part (104) at least one passage (126) for guiding the filling material to the dispensing opening (122).
  4. Film cartridge according to one of the preceding claims, characterised in that the closure (136) of each filling opening (124) in the head part (104) is a film.
  5. Method of producing a film cartridge according to one of claims 1 to 4 having a tube of film (106) and a cap (116) having at least one first opening (118), the method having the following steps:
    - production of at least one chamber (110, 112, 113) by connecting the cap (116) to the tube of film (106),
    - filling of the chamber (110, 112, 113) with a filling material through the first opening (118) in the cap (116), and
    - closing off of the first opening (118), characterised in that a head part (104) is provided which has a receiving means (128) for a mixing tube for dispensing the filling material and which is solidly connected to the cap (116) before or after the filling.
  6. Method according to claim 5, characterised in that the first opening (118) is closed off by a closure which is placed directly on the first opening (118).
EP12158339.7A 2011-04-15 2012-03-07 Film cartridge and method for producing a film cartridge Active EP2511194B1 (en)

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CN102730289B (en) 2015-12-02
EP2511194A3 (en) 2013-01-02
ES2601455T3 (en) 2017-02-15
CN102730289A (en) 2012-10-17
JP6147962B2 (en) 2017-06-14
RU2012114681A (en) 2013-10-20
JP2012224397A (en) 2012-11-15
AU2012202087A1 (en) 2012-11-01
US20130097968A1 (en) 2013-04-25
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EP2511194A2 (en) 2012-10-17
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