EP2501459A1 - Verfahren zur reinigung eines gasstroms durch implementierung eines schützes mit parallelen passagen bei gleichzeitiger erhaltung der leistung - Google Patents
Verfahren zur reinigung eines gasstroms durch implementierung eines schützes mit parallelen passagen bei gleichzeitiger erhaltung der leistungInfo
- Publication number
- EP2501459A1 EP2501459A1 EP10779271A EP10779271A EP2501459A1 EP 2501459 A1 EP2501459 A1 EP 2501459A1 EP 10779271 A EP10779271 A EP 10779271A EP 10779271 A EP10779271 A EP 10779271A EP 2501459 A1 EP2501459 A1 EP 2501459A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- compound
- main adsorber
- hydrogen
- contactor
- adsorption
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
- B01D53/0473—Rapid pressure swing adsorption
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0423—Beds in columns
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/16—Hydrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/102—Nitrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/204—Inorganic halogen compounds
- B01D2257/2045—Hydrochloric acid
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/304—Hydrogen sulfide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/406—Ammonia
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/502—Carbon monoxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/80—Water
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40001—Methods relating to additional, e.g. intermediate, treatment of process gas
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40077—Direction of flow
- B01D2259/40081—Counter-current
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/41—Further details for adsorption processes and devices using plural beds of the same adsorbent in series
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
- C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/048—Composition of the impurity the impurity being an organic compound
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0495—Composition of the impurity the impurity being water
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Definitions
- the invention relates to a method for purifying a gas flow comprising at least a first compound chosen from the compounds of the first group formed by water, ammonia, aromatics, hydrocarbons of alkane, alkene or C5 + alkyne type, that is to say having at least 5 carbon atoms, aldehydes, ketones, halogenated hydrocarbons, hydrogen sulphide, hydrogen chloride and at least a second and a third compound selected from the compounds of the second group formed by helium, hydrogen, nitrogen, oxygen, argon, monoxide of carbon, carbon dioxide, hydrocarbons less than C5, by variable pressure adsorption (PSA), using at least one main adsorber comprising at least one contactor with parallel passages.
- PSA variable pressure adsorption
- Adsorption is a physical phenomenon that is increasingly used industrially to separate or purify gas flows.
- adsorption is conventionally used to dry various gas streams, in particular air, natural gas, for the production of hydrogen, for the production of oxygen and / or nitrogen from air atmospheric, to capture many components of various effluents before their use in a downstream process or venting such as VOC, nitrogen oxides, mercury ...
- VSA vacuum swing adsorption
- PSA and TSA to describe all these adsorption processes comprising an in situ regeneration step depending on whether the predominant effect used to regenerate the adsorbent is pressure or temperature.
- the adsorbent used is generally in the form of particles filled with an adsorber. These particles can be in the form of granules, rods, balls, crushed. The characteristic dimensions of these particles generally range from 0.5 mm to 5 mm.
- adsorbers having a large fluid passage section are used, such as cylindrical adsorbers with a horizontal axis or radial adsorbers.
- a disadvantage to this gain is an increased pollution risk for the adsorbent.
- the document FR 2 800 297 deals with this aspect by referring to the humidity inputs which concern increasingly smaller quantities of sieves as the cycles improve.
- Removing moisture inputs helps to maintain efficiency over time as water-sensitive adsorbents are used.
- the solutions are conventional and range from strengthening seals, using dry barrier gas, controlled leakage outwards to prevent any entry of water into the system. If the unit is shut down, a slight pressurization of the unit is also foreseen, with a possible slight leakage, for the same purpose and possibly to avoid the migration of impurities from the inlet to the contactor output. .
- a conventional unit that is to say a unit which does not comprise a contactor with parallel passages and having a step time greater than 30 seconds generally, it is common to frame the duration of a step by a value minimum and a maximum value and calculate the duration of the current step depending on the operating conditions, in particular the flow.
- many regulations and / or security can intervene to correct the defect or to put the unit in security.
- the response times are of the order of one second, that is to say a few percent of the step time. This can result in the fact that we enter for example 3% more gas than expected in the design, that is to say also 3% more impurities.
- an impurity corresponds to at least one adsorbent.
- the impurity will not leave its adsorption zone or at worst will spill over the next zone.
- the impurity will be adsorbed at least in the next layer and most likely in many of the following layers.
- a problem that arises is to provide a process for purifying a gas stream using a PSA comprising at least one contactor with parallel passages and the integrity of the initial performance is preserved.
- the subject of the invention is a process for purifying a gaseous flow comprising at least a first compound chosen from the compounds of the first group formed by water, ammonia, aromatics and alkane-type hydrocarbons. , alkenes or alkynes containing at least 5 carbon atoms, aldehydes, ketones, halogenated hydrocarbons, hydrogen sulphide, hydrogen chloride and at least a second and a third compound chosen from the compounds of the second group formed by helium, hydrogen, nitrogen, oxygen, argon, carbon monoxide, carbon dioxide, hydrocarbons below C5, by variable pressure adsorption (PSA), using at least one main adsorber (17-2) comprising at least one parallel passage contactor, characterized in that:
- PSA variable pressure adsorption
- the first compound is at least partially stopped by a TSA unit (17-1) placed upstream of said main adsorber (17-2), and
- the main adsorber follows a pressure cycle comprising an adsorption phase of less than 15 seconds, and a regeneration phase in which the waste gas is withdrawn from the main adsorber.
- At least a portion of the waste gas is compressed for later use.
- the waste gas is enriched in CO2
- its compression requires that it be dry in order to avoid corrosion problems.
- the upstream TSA solves this problem.
- Figure 15 schematically shows a device for carrying out the purification process according to the invention.
- the main adsorber is also shown in references 16-2, 17-2 and 18-2.
- FIGS 1 to 7 show schematically, but not limited to, the different types of contactors with parallel passages. Indeed, the contactors may comprise channels of different shapes and sizes. We then distinguish:
- the fluid can also circulate in the free space left by solid walls presented in the form of cylinders or fibers (Figure 6).
- the solid walls may also have the configuration "packing" as used in distillation ( Figure 7). In the latter case, it is possible to use all the geometric possibilities relating to said packings by playing on the bending angles, the orientation of the passages relative to the vertical (supposed vertical contactor), the dimensions of the channels ...
- the fluid which is preferably a gaseous flow, circulates in channels presenting little (or no) obstacle to flow. and the adsorbent is located or constitutes the wall of said channels.
- the documents EP 1 413 348, EP 1 121 981 and WO 2005/094987 describe contactors with parallel passages
- the parallel-channel contactors are preferred to the conventional solution of particle beds when the effects of a decrease in the pressure drop become preponderant and make it possible to compensate for the probable overcost linked to the adoption of the new type. adsorber.
- the embodiment of the contactor itself, and more particularly of the support-wall assembly, is done according to various techniques which can for example be classified according to the way the adsorbent is integrated into the wall.
- the adsorbent in the case of “monolith”, constitutes directly the wall of the channels (FIG. 8).
- the adsorbent (110) is fixed on a support (1 1 1), for example a metal foil.
- the adhesion to the wall can be done via the binder.
- adsorbent (whose role is then double: agglomeration of adsorbent micro particles between them and attachment to the wall) as shown in Figure 9 or via a specific glue (120) ( Figure 10).
- the support will generally have been treated to facilitate the adhesion, it can be porous by nature (membrane, tissue ...); many materials can be used such as polymers, ceramics, metals, paper ...
- the support of the adsorbent may be folded (before or after deposition of the adsorbent layer) and this folded sheet itself wound around a central axis.
- Figure 3 of US 5,771,707 shows such an arrangement. In the case of folds substantially triangular shape, the height of the triangle and its base will generally be between 0.5 and 5 mm.
- the adsorbent can also be trapped.
- "imprisonment” can be homogeneous, that is to say that the adsorbent particles (130) are immobilized by a network of fibers (131) thin and dense which occupy the entire volume of the wall ( Figure 11).
- An adhesive may be added to strengthen the attachment.
- the entrapment of adsorbent particles in fiber networks has been used in the manufacture of gas masks. Note, however, that in this In the latter case, the air flowing through the adsorbent medium while in the case considered here, the gas flow along the wall containing the adsorbent.
- the adsorbent particles (140) are held between two walls (141, 142) porous to the fluid ( Figure 12).
- a binder and / or an adhesive may be added to improve if necessary the maintenance of the particles between the porous walls.
- These walls may be of metal type, polymers ... They are chosen so that they can simultaneously contain the adsorbent particles and not create significant resistance to the diffusion of the molecules.
- Figure 13 shows the base cell, i.e. the smallest element that can be used to describe the geometry of a parallel-pass contactor.
- the channel (20) in which circulates the gaseous flow, of total thickness 2 epf, the porous membrane maintaining the adsorbent (21) of epm thickness, the adsorbent layer (22) thick epads, an adhesive layer (23) of epc thickness and the support sheet (24) of total thickness 2 eps.
- the base cell is epf + epm + epads + epc + eps.
- the orders of magnitude of these thicknesses are for example:
- the basic cell would therefore have in the example a thickness of 210 microns (75 + 25 + 50 + 10 + 50)
- the support sheet by its density, its heat capacity, its thermal conductivity, possibly its porosity;
- the adhesive layer by its density, its heat capacity, its thermal conductivity, possibly its porosity
- the adsorbent layer by its total porosity, by the average size of the macro pores, by the density of the adsorbent particles, possibly their size, their internal porosity, their heat capacity, their thermal conductivity as well as by the isotherms of adsorption and co-adsorption binding the adsorbent and the molecules present in the gas stream;
- the membrane by its total porosity, the average pore diameter, the heat capacity, the density, the thermal conductivity, the fluid side wall roughness.
- FIG. 14 represents an example of an adsorber comprising a contactor with parallel passages.
- the cylindrical contactor (1) is housed in a metal casing (2) comprising a bottom bottom and an upper bottom with openings for the passage of the gas stream.
- the contactor rests on the bottom bottom of the envelope (4).
- Diffusers (3) at the top and bottom the good distribution of the incoming and outgoing gas flows.
- Sealing at the inner wall of the casing (4), to avoid a preferential passage of the gas stream at this location, is achieved by simply pressing the contactor previously rolled on the wall of the casing. If necessary, this seal can be improved by any of the known means (seals, welding, gluing ...)
- a parallel passage contactor means a device in which the fluid passes through channels whose walls contain adsorbent.
- the fluid circulates in essentially obstacle free channels, these channels allowing the fluid to flow from an input to an output of the contactor.
- These channels can be rectilinear connecting directly the input to the output of the contactor or present changes of direction.
- the fluid is in contact with at least one adsorbent present at said walls.
- the adsorber according to the invention may comprise one or more of the following characteristics:
- a stream enriched in the second compound and depleted in the third compound is recovered at the outlet of the main adsorber;
- the main adsorber follows a pressure cycle whose adsorption time is less than 30 seconds, preferably between 2 and 15 seconds; we will speak in this case of PS A fast.
- the main adsorber follows a pressure cycle comprising an adsorption phase of less than 5 seconds duration, and a regeneration phase in which the waste gas is withdrawn from the main adsorber, and a variable portion of said waste gas is recycled to the supply side of the main adsorber.
- adsorption phase can be significantly shorter than the time required to obtain the maximum efficiency that can be expected from this type of unit.
- the adsorption time is generally between 0.1 to 5 seconds.
- the first compound is at least partially stopped by an adsorption unit (17-1) or a permeation membrane (16-1) placed upstream of said main adsorber (FIGS. 16 and 17);
- the adsorption unit (17-1) is chosen from a renewable charge guard bed, a TSA unit, a PSA unit having an adsorption time greater than 15 seconds, or a PSA unit (18-1) comprising a parallel passage contactor combined with a guard bed (18-3) (Figs. 17 and 18);
- the adsorption unit is regenerated or the permeation membrane is eluted by a stream (17-3 or 16-3) coming from the main adsorber or by a flow outside the main adsorber;
- the main adsorber comprises at least two parallel passage switches arranged in series.
- the use of parallel-series contactors arranged in series makes it possible to treat large quantities of fluid, in particular gas flows of several hundred or several thousand Nm / h and / or to obtain products of very high purity (99.9% for example) ;
- the second compound is hydrogen or C0 2 ;
- the second compound is hydrogen
- the third compound is chosen from carbon dioxide, methane, carbon monoxide and nitrogen
- a hydrogen enriched and depleted stream is recovered at the outlet of the main adsorber; in third compound.
- the adsorbents that may be used in the parallel-passage contactors are those used in the conventional gas stream separation or purification units. The choice depends on the application. It is possible in the same contactor to use successively several different adsorbents. Mention may be made of silica gels, optionally doped activated alumina, activated carbons, various type zeolites (3A, 4A, 5A, type X, LSX, Y, etc., optionally exchanged, etc.), framing adsorbents. metal-organic (MOF .7) Zeolites are generally used in the form of microcrystals, even nano-crystals according to the synthetic methods. Other adsorbents, for example activated carbons, can be crushed to obtain micron-sized particles.
- an additional means for limiting the problem of decreasing the initial performance of the main adsorber is to choose adsorbents not having too much affinity for the constituents present.
- the PSA may not be regenerated by a simple pressure effect.
- Figure 19 illustrates in particular the arrangement of three contactors in series in an adsorber.
- the three contactors (10), (1 1) and (12) are superimposed in the same envelope (4) having a lower bottom and an upper bottom equipped with inlet / outlet openings of the gas flows.
- Deflectors or diffusers (15) allow in the lower and upper part the good distribution of the gas flow.
- Intermediate distributors (16) make it possible to recover the flows leaving one contactor and redistribute them homogeneously in the next.
- These distributors (16) can be special pieces of equipment making transition between two contactors and making sure not to plug the channels devolved to the fluids. It may especially be grating, metal grid, spider and more generally a spacer having no resistance to the flow of fluid.
- the ends of at least one contactor can be adapted to facilitate the flow of fluid between the contactors.
- This adaptation may consist of notching, for example, the last centimeter of the support in order to create a large passage zone for the fluid which can thus be redistributed more easily in the second contactor.
- Another solution may be to make each of the contactors solitary with the wall of the outer casing leaving for example a clearance (free space) between contactors.
- the three contactors may be identical or on the contrary, it is possible to use this invention to singularize at least one contactor and adapt it to the operating conditions at this level of the adsorber.
- it may be another type of adsorbent, a change in the thickness of the adsorbent layer, the passage section, etc.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Separation Of Gases By Adsorption (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0958170A FR2952553B1 (fr) | 2009-11-19 | 2009-11-19 | Procede de purification d'un flux gazeux mettant en oeuvre un contacteur a passages paralleles presentant une conservation de ses performances |
PCT/EP2010/066770 WO2011061056A1 (fr) | 2009-11-19 | 2010-11-04 | Procede de purification d'un flux gazeux mettant en œuvre un contacteur a passages paralleles presentant une conservation de ses performances |
Publications (1)
Publication Number | Publication Date |
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EP2501459A1 true EP2501459A1 (de) | 2012-09-26 |
Family
ID=42244626
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP10779271A Ceased EP2501459A1 (de) | 2009-11-19 | 2010-11-04 | Verfahren zur reinigung eines gasstroms durch implementierung eines schützes mit parallelen passagen bei gleichzeitiger erhaltung der leistung |
Country Status (5)
Country | Link |
---|---|
US (1) | US20120227583A1 (de) |
EP (1) | EP2501459A1 (de) |
CN (1) | CN102665857B (de) |
FR (1) | FR2952553B1 (de) |
WO (1) | WO2011061056A1 (de) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2992573B1 (fr) | 2012-06-29 | 2017-10-20 | Air Liquide | Assemblage de modules d'adsorbants structures |
US9073001B2 (en) * | 2013-02-14 | 2015-07-07 | The Boeing Company | Monolithic contactor and associated system and method for collecting carbon dioxide |
CN104436992B (zh) * | 2014-10-15 | 2016-08-17 | 北京氢璞创能科技有限公司 | 具有前置气体成份分离装置的变压吸附气体提纯器组件 |
FR3029803B1 (fr) | 2014-12-11 | 2019-09-27 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Melange adsorbant a capacite thermique amelioree |
FR3034027B1 (fr) | 2015-03-26 | 2018-11-16 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede de production d'oxygene par vpsa comprenant 4 adsorbeurs |
EP3093550A1 (de) | 2015-05-11 | 2016-11-16 | Basf Se | Lagerbehälter mit mindestens einem formkörper eines porösen feststoffs |
US9795915B2 (en) * | 2016-01-29 | 2017-10-24 | Air Products And Chemicals, Inc. | Heater arrangement for TEPSA system |
AU2017320837B2 (en) | 2016-09-01 | 2020-07-23 | Exxonmobil Upstream Research Company | Swing adsorption processes for removing water using 3A zeolite structures |
JP7021227B2 (ja) | 2016-12-21 | 2022-02-16 | エクソンモービル アップストリーム リサーチ カンパニー | 活性材料を有する自己支持構造 |
RU2019120009A (ru) | 2016-12-21 | 2021-01-22 | Эксонмобил Апстрим Рисерч Компани | Самоподдерживающиеся структуры, имеющие структуры с геометрией пены и активные материалы |
WO2020131496A1 (en) | 2018-12-21 | 2020-06-25 | Exxonmobil Upstream Research Company | Flow modulation systems, apparatus, and methods for cyclical swing adsorption |
CN109647131B (zh) * | 2019-02-27 | 2022-02-11 | 大连大学 | 一种脉动射流变压吸附净化气体的装置 |
US11376545B2 (en) | 2019-04-30 | 2022-07-05 | Exxonmobil Upstream Research Company | Rapid cycle adsorbent bed |
WO2021071755A1 (en) | 2019-10-07 | 2021-04-15 | Exxonmobil Upstream Research Company | Adsorption processes and systems utilizing step lift control of hydraulically actuated poppet valves |
US11433346B2 (en) | 2019-10-16 | 2022-09-06 | Exxonmobil Upstream Research Company | Dehydration processes utilizing cationic zeolite RHO |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5531809A (en) * | 1994-09-14 | 1996-07-02 | Air Products And Chemicals, Inc. | Pretreatment layer for CO-VSA |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4329158A (en) * | 1980-06-13 | 1982-05-11 | Air Products And Chemicals, Inc. | Air fractionation by pressure swing adsorption |
US4472178A (en) * | 1983-07-05 | 1984-09-18 | Air Products And Chemicals, Inc. | Adsorptive process for the removal of carbon dioxide from a gas |
US4770676A (en) * | 1986-05-16 | 1988-09-13 | Air Products And Chemicals, Inc. | Recovery of methane from land fill gas |
US5120694A (en) | 1989-07-28 | 1992-06-09 | Uop | Method of coating aluminum substrates with solid adsorbent |
US5451248A (en) * | 1990-07-19 | 1995-09-19 | The Boc Group Plc | Storage and transportation of goods under controlled atmospheres |
CA2133302A1 (en) * | 1993-10-06 | 1995-04-07 | Ravi Kumar | Integrated process for purifying and liquefying a feed gas mixture with respect to its less strongly adsorbed component of lower volatility |
US5753010A (en) * | 1996-10-28 | 1998-05-19 | Air Products And Chemicals, Inc. | Hydrogen recovery by pressure swing adsorption integrated with adsorbent membranes |
CA2195282C (en) | 1997-01-16 | 2004-05-11 | Frederic Lagace | Unitary heat exchanger for the air-to-air transfer of water vapor and sensible heat |
US5914455A (en) * | 1997-09-30 | 1999-06-22 | The Boc Group, Inc. | Air purification process |
FR2788993B1 (fr) * | 1999-01-29 | 2001-02-23 | Air Liquide | Procede d'epuration d'un gaz par adsorption |
FR2800297B1 (fr) | 1999-10-28 | 2001-12-28 | Air Liquide | Installation de traitement cyclique de fluide par adsorption avec vannes a etancheite amelioree |
JP3489048B2 (ja) | 2000-02-01 | 2004-01-19 | 日産自動車株式会社 | 排気ガス浄化用触媒 |
CA2430184A1 (en) | 2001-01-05 | 2002-08-29 | Questair Technologies Inc. | Adsorbent coating compositions, laminates and adsorber elements comprising such compositions and methods for their manufacture and use |
US20030037672A1 (en) * | 2001-08-27 | 2003-02-27 | Shivaji Sircar | Rapid thermal swing adsorption |
US7077891B2 (en) | 2002-08-13 | 2006-07-18 | Air Products And Chemicals, Inc. | Adsorbent sheet material for parallel passage contactors |
US20050211100A1 (en) | 2004-03-23 | 2005-09-29 | Doughty David T | Shaped composite adsorbent material |
WO2006079028A1 (en) * | 2005-01-21 | 2006-07-27 | Exxonmobil Research And Engineering Company | Hydrocracking of heavy feedstocks with improved hydrogen management |
US20090214902A1 (en) * | 2005-06-15 | 2009-08-27 | Pelman Aaron M | Adsorptive Bulk Separation for Upgrading Gas Streams |
ES2510547T3 (es) * | 2007-01-24 | 2014-10-21 | Air Products And Chemicals, Inc. | Capas de protección para dispositivos de absorción con oscilación de presión de ciclo rápido |
US7959720B2 (en) * | 2007-05-18 | 2011-06-14 | Exxonmobil Research And Engineering Company | Low mesopore adsorbent contactors for use in swing adsorption processes |
US7909913B2 (en) * | 2008-07-17 | 2011-03-22 | Air Products And Chemicals, Inc. | Gas purification by adsorption of hydrogen sulfide |
-
2009
- 2009-11-19 FR FR0958170A patent/FR2952553B1/fr not_active Expired - Fee Related
-
2010
- 2010-11-04 EP EP10779271A patent/EP2501459A1/de not_active Ceased
- 2010-11-04 WO PCT/EP2010/066770 patent/WO2011061056A1/fr active Application Filing
- 2010-11-04 CN CN201080052030.7A patent/CN102665857B/zh not_active Expired - Fee Related
- 2010-11-04 US US13/510,404 patent/US20120227583A1/en not_active Abandoned
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5531809A (en) * | 1994-09-14 | 1996-07-02 | Air Products And Chemicals, Inc. | Pretreatment layer for CO-VSA |
Non-Patent Citations (2)
Title |
---|
BABICKI MATT; HALL ET AL: "PSA technology hits the Fast Lane", 1 August 2003 (2003-08-01), pages 6 PP, XP055175607, Retrieved from the Internet <URL:http://www.xebecinc.com/pdf/e_h2x_fast_lane.pdf> [retrieved on 20150311] * |
See also references of WO2011061056A1 * |
Also Published As
Publication number | Publication date |
---|---|
FR2952553A1 (fr) | 2011-05-20 |
US20120227583A1 (en) | 2012-09-13 |
CN102665857B (zh) | 2014-09-24 |
FR2952553B1 (fr) | 2012-06-01 |
WO2011061056A1 (fr) | 2011-05-26 |
CN102665857A (zh) | 2012-09-12 |
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