EP2498974A1 - Gekrümmtes kunststoffsegment mit mehrschichtigerwand zur montage von rohren - Google Patents
Gekrümmtes kunststoffsegment mit mehrschichtigerwand zur montage von rohrenInfo
- Publication number
- EP2498974A1 EP2498974A1 EP10773356A EP10773356A EP2498974A1 EP 2498974 A1 EP2498974 A1 EP 2498974A1 EP 10773356 A EP10773356 A EP 10773356A EP 10773356 A EP10773356 A EP 10773356A EP 2498974 A1 EP2498974 A1 EP 2498974A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- curved segment
- polymer
- central layer
- layer
- pipes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
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- 239000004800 polyvinyl chloride Substances 0.000 description 16
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- 229920000491 Polyphenylsulfone Polymers 0.000 description 4
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- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
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- 229910001141 Ductile iron Inorganic materials 0.000 description 2
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- 229920000098 polyolefin Polymers 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 239000005033 polyvinylidene chloride Substances 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- LUTSRLYCMSCGCS-BWOMAWGNSA-N [(3s,8r,9s,10r,13s)-10,13-dimethyl-17-oxo-1,2,3,4,7,8,9,11,12,16-decahydrocyclopenta[a]phenanthren-3-yl] acetate Chemical compound C([C@@H]12)C[C@]3(C)C(=O)CC=C3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)C)C1 LUTSRLYCMSCGCS-BWOMAWGNSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
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- 229920005570 flexible polymer Polymers 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
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- 229920000578 graft copolymer Polymers 0.000 description 1
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- 238000002347 injection Methods 0.000 description 1
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- 239000011810 insulating material Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
- B32B1/08—Tubular products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
- B29C53/02—Bending or folding
- B29C53/04—Bending or folding of plates or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
- B29C53/80—Component parts, details or accessories; Auxiliary operations
- B29C53/84—Heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D99/00—Subject matter not provided for in other groups of this subclass
- B29D99/001—Producing wall or panel-like structures, e.g. for hulls, fuselages, or buildings
- B29D99/0021—Producing wall or panel-like structures, e.g. for hulls, fuselages, or buildings provided with plain or filled structures, e.g. cores, placed between two or more plates or sheets, e.g. in a matrix
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/12—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/146—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers whereby one or more of the layers is a honeycomb structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/18—Handling of layers or the laminate
- B32B38/1866—Handling of layers or the laminate conforming the layers or laminate to a convex or concave profile
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/12—Rigid pipes of plastics with or without reinforcement
- F16L9/121—Rigid pipes of plastics with or without reinforcement with three layers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/22—Pipes composed of a plurality of segments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2009/00—Layered products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/60—Multitubular or multicompartmented articles, e.g. honeycomb
- B29L2031/608—Honeycomb structures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/22—Fibres of short length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2327/00—Polyvinylhalogenides
- B32B2327/06—PVC, i.e. polyvinylchloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2375/00—Polyureas; Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
- B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
Definitions
- the present invention relates to a plastic multilayer-wall curved segment for assembling pipes. It also relates to a method for manufacturing this segment. It also relates to a method for assembling pipes from same segments and also to the pipes thus assembled.
- Pipes intended for transporting fluids (pressurized or unpressurized fluids) and, in particular, the pipes for underground rainwater or wastewater drainage, water supply systems, etc., can be economically produced from ductile cast iron, ceramic or concrete.
- plastic pipes are preferred, in a number of cases, to cast iron, ceramic or concrete as they are much lighter and exhibit remarkable corrosion resistance .
- coextruded pipes comprising three PVC-based layers and more particularly: pipes of ABA type where A is rigid PVC and B rigid foamed PVC;
- ⁇ pipes comprising two layers produced by in-line laminating of an inner pipe, covered during passage in a forming block with a corrugated pipe; this configuration is generally based on PP;
- the French patent application published under the number 2 745 746 describes a structured wall material for lining pipes comprising two outer laminated layers and an intermediate layer having a honeycomb structure comprising cells that have the shape of contiguous symmetrical prisms (the cross sections of which have a circular envelope).
- This intermediate layer has the advantage of increasing the mechanical strength of the whole low-weight and low-cost assembly.
- its contiguous symmetrical prism structure gives it such a high stiffness that it is necessary to provide rupture lines in order to be able to produce the desired curves, which is relatively complicated from an implementation point of view and leads to poor mechanical strength (acceptable, it is true, in lining, but not for solid piping).
- Document WO 2009/115521 discloses, in particular, a process for producing a structured wall plastic pipe according to which at least one plastic sheet having a honeycomb structure with asymmetric cells (i.e. cells that have a cross section for which the envelope has a shape factor (ratio of its largest dimension to its smallest dimension) greater than 1) is wound around a tubular plastic mandrel, and firmly attached to the latter, so that these cells are arranged radially to the surface of the mandrel.
- the assembly is covered with at least one top layer which must be attached to the honeycomb sheet on the side opposite the one to which the tubular mandrel is attached.
- the self-supporting structured wall pipe has, for a given diameter, a high ring stiffness for a low weight.
- One subject of the present invention is especially to provide elements with structured walls, which elements are much less bulky and lighter than the pipe described in document WO 2009/115521, and can be easily transported due to their subsequent assembly into pipes at the work site.
- the invention relates to a plastic multilayer-wall curved segment for assembling pipes, said segment comprising at least one central layer (P) based on a thermoplastic polymer (PI) and said central layer having a honeycomb cellular structure, each of the outer faces of this central layer (P) being covered with at least one sheet (F) of solid structure based on a thermoplastic polymer (P2).
- curved segment is understood to define, in the present description, a solid three-dimensional structure, rounded in its circumferential direction and substantially flat in its longitudinal direction, i.e. a panel that is curved in such a way that two of its parallel edges describe arcs of a circle, the other two parallel sides being rectilinear.
- the curved segment according to the invention is advantageously present as an element (a fraction) of a wall of cylindrical cross section. This curved segment constitutes a portion of the final pipe to be assembled. Thus, if this curved segment represents 1/n of the circumference of the final pipe (or of a length thereof), the latter will be obtained by assembling n elements.
- n is greater than or equal to 2.
- n is less than or equal to 8, preferably less than or equal to 4.
- plastic is understood to mean any amorphous or semicrystalline thermoplastic polymer, including thermoplastic elastomers, and also blends thereof.
- polymer is understood to mean both homopolymers and copolymers (especially binary or ternary copolymers). Examples of such copolymers are, non-limitingly: random copolymers, linear block copolymers, other block copolymers and graft copolymers.
- amorphous polymer is understood to mean any thermoplastic polymer predominantly having a disordered arrangement of the macromolecules that form it.
- this term is understood to mean any thermoplastic polymer that contains less than 30% by weight, preferably less than 10% by weight, of crystalline phase (that is to say, the phase characterized by a melting endotherm during differential thermal analysis (DSC) measurements).
- DSC differential thermal analysis
- thermoplastic polymer is understood to mean any thermoplastic polymer having, in a large proportion, a chemically and geometrically regular arrangement of the macromolecules that form it.
- this expression is understood to mean any thermoplastic polymer that contains more than 30% by weight, preferably more than 50% by weight, of crystalline phase (that is to say the phase characterized by a melting endotherm during differential thermal analysis (DSC) measurements).
- DSC differential thermal analysis
- thermoplastic polymers they are the glass transition temperature (T g ) and the melting temperature or temperature of fusion (T f ).
- T g is the temperature below which a polymer mass has several properties of inorganic glass, including hardness and rigidity. Above the T g , the polymer mass has plastic or elastic properties and it is said to be in the rubbery or elastomeric state.
- T f is also called the flow temperature in the case of amorphous polymers and the straightforward melting point when it is a question of semicrystalline polymers. At the T f (which is rather, in practice, a temperature zone or range of temperatures), it is more a case of a viscous liquid.
- thermoplastic polymer or copolymer the working temperature of which is below the decomposition temperature, is suitable for producing the multilayer-wall curved segment according to the invention.
- Synthetic thermoplastics having a working range spread over at least 10 degrees Celsius are particularly suitable. Examples of such materials include those that exhibit polydispersity of their molecular weight.
- Use may especially be made of polyolefms, polyvinyl halides (such as
- PVC or polyvinyl chloride) or polyvinylidene halides such as PVDF or polyvinylidene fluoride, PVDC or polyvinylidene chloride
- thermoplastic polyesters such as PVDF or polyvinylidene fluoride, PVDC or polyvinylidene chloride
- polyarylethersulphones such as polyphenylsulphones (PPSUs), polyketones, polyamides (PAs) and copolymers thereof.
- PVC and polyolefms [and in particular polypropylene (PP) and polyethylene (PE)]
- polyarylethersulphones such as polyphenylsulphones (PPSUs), PAs and thermoplastic fluoropolymers have given good results.
- a blend of polymers or copolymers may also be used; similarly it is also possible to use a blend of polymeric materials with inorganic, organic and/or natural fillers (such as, for example but non-limitingly: carbon, salts and other inorganic derivatives, natural or polymeric fibres) and/or other additives (stabilizers, processing aids, etc.), which is generally referred to as a polymer composition.
- inorganic, organic and/or natural fillers such as, for example but non-limitingly: carbon, salts and other inorganic derivatives, natural or polymeric fibres
- additives stabilizers, processing aids, etc.
- Polymers (PI) advantageously used in the composition of the central layer (P) of the curved segment according to the invention are PVC and polyolefms [in particular polypropylene (PP) and high-density polyethylene (HDPE)].
- PVC is particularly preferred on account of the fact that it has a high stiffness/cost ratio.
- PVC polyvinymer
- PVC polymers that are very particularly preferred are vinyl chloride homopolymers.
- polymers may advantageously be used as polymer (P2) in the composition of the sheets (F) of the curved segment according to the invention.
- PVC containing a known reinforcing agent, such as glass fibres for example, in particular long, chopped and randomly distributed glass fibres, is particularly preferred for the composition of the sheets (F).
- a curved segment of particularly high ring stiffness is obtained when the polymer (PI) used in the composition of its central layer (P) is PVC and the polymer (P2) used in the composition of the sheets (F) is PVC to which glass fibres have been added.
- curved segments for which all the components (central layer(s) (P) and sheets (F)) are based on the same polymer, (i.e. mainly composed of the same polymer) or on compatible polymers, are preferred.
- the sheets (F) covering each outer face of the central layer (P) of the curved segment according to the invention are preferably identical in thickness and in composition. If this is not the case, their thicknesses are preferably chosen so that they have comparable flexural and tensile stiffness and similar coefficients of linear expansion in the transverse and longitudinal directions.
- Curved segments comprising several central layers (P) based on a thermoplastic polymer (PI), these layers (P) then being identical or different in thickness and in composition, also fall within the scope of the invention. Curved segments comprising more than one sheet (F) on each of the outer faces of the central layer (P) also fall within the scope of the invention.
- PI thermoplastic polymer
- honeycomb having a honeycomb cellular structure
- honeycomb is understood to mean, in the present description, a three-dimensional structure (plate/sheet) composed of a cohesive assembly of contiguous cellular cells (also referred to more simply as "cells").
- cells is understood to mean open or closed cells preferably having an asymmetric cross section (the envelope of which has a shape factor (defined as being the ratio of their largest dimension to their smallest dimension) other than 1, preferably at least equal to 1.5, even 2.5 and preferably 4) that is generally substantially oval, elliptical or hexagonal, with walls arranged in any manner, but preferably that are parallel from one cell to another.
- these cells are arranged radially, i.e. their vertical axis (the one which is perpendicular to the longitudinal axis of the curved segment) is radial (positioned substantially in the extension of a radius of the curved segment).
- the longest walls of the cells may form a non-zero angle with the longitudinal axis of the curved segment. In this case, this angle is advantageously less than 30° and, preferably, less than 15°.
- the longest walls of the cells are however preferably substantially parallel to the longitudinal axis of the curved segment (i.e. the angle formed by these walls with this axis is less than 5°, preferably zero).
- the honeycomb cellular structure that makes up the central layer of the multilayer-wall curved segment according to the invention may have been obtained by any known process. Preferably, it is obtained by extrusion of lamellae based on a molten thermoplastic polymer (PI) that are intermittently welded.
- PI thermoplastic polymer
- the honeycomb is obtained by a process according to which:
- - parallel lamellae of a composition based on at least one thermoplastic polymer (PI) are continuously extruded, in an approximately horizontal direction, through a die having a front face provided with a plurality of parallel slots and with an insulating material, at least on the surface;
- the spaces lying between two adjacent lamellae are subjected, in successive alternations and between two sizing units whose length is short enough for the polymer composition to remain molten, to an injection of compressed gas or of a coolant and to a vacuum, the two sides of any one lamella being, in respect of one of them, subjected to the action of the compressed gas or coolant and, in respect of the other of them, subjected to the action of the vacuum, and vice versa during the next alternation, so as to deform the lamellae and weld them together in pairs, with formation, in a plane approximately parallel to the extrusion direction, of a cellular structure whose constituent cells extend perpendicular to the extrusion direction.
- honeycombs may advantageously be obtained by adding, to the lamella extrusion process described above, a step of stretching the honeycomb perpendicular to the extrusion direction and in line with said extrusion.
- a process is described in document WO 2007/110370, the content of which is incorporated by reference in the present description for everything that it discloses.
- the components (central layer(s) (P) and sheets (F)) of the curved segments according to the invention are advantageously attached (assembled) by any of the methods known for assembling together three-dimensional plastic structures.
- these methods advantageously applied to the flat panels that are precursors of the curved segments (see below), mention may be made of welding and adhesive bonding. Supplementary details regarding these methods are provided below within the context of the description of the subject of the invention relating to the process for manufacturing a plastic multilayer-wall curved segment.
- the layer P is thermoformed and a dynamic cold press is supplied with this layer and the layer(s) F that is (are) shaped in situ and that is (are) assembled with the layer P, preferably with the aid of highly reactive adhesives, or a laser beam;
- a dynamic cold press is supplied with a flexible honeycomb and the layer(s) F and they are all shaped and assembled preferably with the aid of highly reactive adhesives, or a laser beam.
- the first variant is preferred as flat structures are commercially available. Therefore, in particular, the invention also relates to a process for manufacturing a plastic multilayer-wall curved segment comprising at least one central layer (P) based on a thermoplastic polymer (PI), having a honeycomb cellular structure, each of the outer faces of this central layer (P) being covered with at least one sheet (F) of solid structure made of a thermoplastic polymer (P2).
- PI thermoplastic polymer
- F sheet of solid structure made of a thermoplastic polymer
- the process according to this aspect of the invention comprises the thermoforming and bending of a flat panel, the multilayer composition of which corresponds to the multilayer wall of the curved segment to be obtained. That is to say that this flat panel is composed, like the curved segment of which it is the precursor, of at least one central layer based on a thermoplastic polymer (PI), having a honeycomb cellular structure, each of the outer faces of this central layer being covered with at least one sheet of solid structure made of a thermoplastic polymer (P2).
- PI thermoplastic polymer
- P2 thermoplastic polymer
- central layer(s) (P) and sheets (F)) of the flat panel to be thermoformed are advantageously attached (assembled) by any of the methods known for assembling together three-dimensional plastic structures.
- One method of assembling the flat panel which has proved advantageous consists in covering the two outer faces of the central layer (P) and/or the inner faces of the sheets (F) with a surface layer that acts as an adhesive.
- This adhesive layer may be deposited by coating or by coextrusion.
- the adhesive layer is deposited by coextrusion, is adapted to the nature of the central layer (P) and of the inner faces of the sheets (F) and to the attachment (assembly) technology used (adhesive bonding, welding, in particular thermal welding, laser welding, UV welding, welding using electromagnetic radiation, etc.).
- the adhesive must advantageously have a sufficient temperature resistance to withstand the temperature prevailing during the subsequent thermoforming of the flat panel.
- the most widely used adhesive is generally a polymer adhesive, preferably that can be thermally activated (by heating). It may be a polyurethane, an acrylic polyester, an EVA/VAc copolymer (if the central layer is based on PVC) or a functionalized polyolefin (if the central layer is based on a polyolefm). Details on the functionalized polyolefins that can be used as a polymer adhesive can be found in the cited document WO 2009/115521.
- the coextrusion according to the present invention aims to provide an adhesive layer on at least one of the faces of the central layer (P).
- the honeycomb cellular structure that makes up the central layer (P) is coextruded so that its cells comprise three sublayers: one, relatively thick, sublayer that forms the body of the honeycomb and two, relatively thinner, adhesive-based surface sublayers (the terms “thick” and “thin” being relative, that is to say by comparison from one layer to another), each of the surface sublayers being intended to firmly attach the central layer (P) to the sheets (F).
- the coextrusion of the central layer (P) and/or of the sheets (F) may prove particularly advantageous for assembling components of the flat panel by the laser welding technique (in particular described in the
- either the apexes of the cells of the central layer (P), or the inner faces of the sheets (F) may be covered by coextrusion of a layer of a plastic (as defined above) containing an agent having very high absorption of the IR radiation of the laser, preference being given to carbon black.
- the manufacture of the flat panel to be thermo formed may optionally be taken advantage of in order to fill at least one portion of the honeycomb cellular structure that makes up the central layer (P) with foam and thus render the resulting curved segment insulating and water-impermeable.
- foam is understood to mean an expanded material, the density of which has been reduced to less than 20% of its initial value (without blowing agents), and even to less than 10% of this value, for identical pressure and temperature conditions.
- the material expanded is a plastic.
- Polyurethanes (PURs) are examples of plastic that is very suitable as a constituent material of the foam.
- the flat panel is thermoformed and bent in order to convert it into a curved segment.
- the thermoforming of the flat panel in order to convert it into a curved segment can be carried out in-line with the manufacture of said panel or else at the work site prior to the assembly of the pipes from the curved segments.
- thermoforming is preferably carried out in a heating device, the heating technique, thermal profile and thermal cycle of which can be adjusted in order to bring the thermoplastic polymer (PI) to a temperature Ti close to T gl , T gl being the glass transition temperature of the polymer (PI) if this polymer is
- T f i being the melting point of the polymer (PI) (measured according to the ASTM D 3417 standard) if it is semicrystalline.
- close is preferably understood, in order to prevent crushing of the honeycomb cellular structure that makes up the central layer (P), to mean that Ti ⁇ T gi or ⁇ ⁇ T fl , preferably Ti ⁇ T gi - 20°C or ⁇ ⁇ T fl - 20°C.
- Ti ⁇ T gl - 30°C and ⁇ ⁇ T f i - 30°C it being understood that in order to allow the thermoforming, it is preferable that Ti > T g i - 50°C or T' i > T fl - 50°C.
- the heating technique, thermal profile and thermal cycle of the heating device are advantageously adjusted so as to bring the thermoplastic polymer (P2) contained in the sheets (F) of solid structure of the flat panel to a temperature T 2 such that T g2 ⁇ T 2 ⁇ T g2 + 50°C (preferably, T g2 ⁇ T 2 ⁇ T g2 + 30°C and very particularly preferably, T g2 ⁇ T 2 ⁇ T g2 + 10°C), T g2 being the glass transition temperature of the polymer (P2) if it is amorphous, or such that Tf2 ⁇ T 2 ⁇ Tf2 + 50°C (preferably, T G ⁇ T 2 ⁇ T G + 30°C and very particularly preferably, Te ⁇ T 2 ⁇ Te + 10°C), Te being the melting point of the polymer (P2) if it is semicrystalline. If the sheets F on the sky and ground side are of different polymer nature, the sky and ground side indexed temperatures in the heating device must consequently be
- the adjustable heating device for the thermoforming of the flat panel may be, for example, an electric oven, a liquid fuel oven or solid fuel oven, a pulsed- air oven, a pressurized heated mould, etc.
- the constituents of the flat panel can be heated by irradiation, by infrared radiation, etc.
- the hot flat panel After conveyance to and residence in the adjustable heating device, the hot flat panel is guided, for example, by a profiled cone, a calibration tunnel, etc. to a shaping means such as a mandrel, a cylinder, etc. advantageously divided into a heated first portion and a cooled second portion, on which the panel is held and cooled in order to be shaped into a curved segment, the uniformity of the thickness of which may advantageously be obtained by optional passage in a pulling machine.
- a shaping means such as a mandrel, a cylinder, etc.
- the invention also relates to a process for assembling pipes from the curved segments that constitute the main subject thereof.
- the assembly of the pipes advantageously takes place at the site of their installation, where the curved segments have previously been brought to, advantageously stacked one on top of another so as to fill as much as possible of the available volume in the means of transport (lorry, wagon, etc.) used.
- each curved segment constitutes a portion (circumferential fraction) of at least one portion of the final pipe to be assembled.
- n may range from 2 to 8, preferably from 2 to 4.
- the curved segments may advantageously be joined together, along their longitudinal edges, by clip-fastening or adhesive bonding.
- one of the sheets (F) may protrude beyond one of the longitudinal edges of the central layer (P) by a length ⁇ ( ⁇ advantageously being equal to less than a quarter, preferably less than an eighth of the arc of a circle formed by the circumferential edge of the layer (P)), the sheet (F) leaving uncovered, on the side of the opposite longitudinal edge of the layer (P), a surface of this layer (P) equivalent to the same length ⁇ .
- This configuration may be symmetrical or asymmetrical for each of the sheets (F) located on both sides of the central layer (P).
- each protruding part be complementary and actually be affixed to the corresponding uncovered part (as can be imagined with segments such as the one represented in the appended Figure 1).
- the protruding edge of the left panel covers the honeycomb of the right panel and vice versa for the latter so that the honeycombs of adjacent panels are contiguous and so that the protruding edge is firmly attached to the adjacent curved panel by welding, adhesive bonding or any other technique.
- the seam between the circumferential edges of adjacent curved segments may be strengthened by addition of a bonded strip or a filling seal (for example, silicone seal, etc.) to prevent a reduction in the impact strength.
- a filling seal for example, silicone seal, etc.
- the assembly of the curved segments into pipes may take place by use of extruded profiles; in this case the arc of each curved part must be calculated so as to take into account the thickness of the profiles.
- the flat panels may be belled during the thermoforming thereof.
- the term "belled” should be understood here in its conventional sense, which means that, at one of the circumferential edges (sections) of the thermoformed panel, a curved segment or a socket is formed which has the general shape of a fragment (lobe) of a bell into which the pipe to be joined is slid. This belling makes it possible to avoid the use of profiles or sleeves.
- the flat panel is sufficiently softened by the thermoforming, it is advantageously placed in another heating device which shapes the bell fragment on the panel.
- a groove, into which a rubber seal which ensures leaktightness may be placed may be hollowed out in this bell fragment which will enable the subsequent interlocking together, along their
- the belled part will describe an arc having a length equal to that of the arc of the main curved part of the panel.
- the inner sheet describes an arc about the outer circumference of the pipe, i.e. about a cylindrical surface having a greater diameter.
- the inner diameter of the pipe at the belling is equal to the outer diameter of the pipe outside of the belled zone.
- Another way is to adapt the belling process so that the belled part is slightly drawn, transversely, in order to increase the length of the arc of the belled part so that 2 adjacent belled parts are contiguous.
- Figure la represents a perspective view of a portion of a curved segment according to the invention.
- Figure lb represents an elevation view, along the cutting plane
- Figure la represents a perspective view of a portion of a curved segment according to the invention, composed of 2 sheets (Fi) and (F 2 ) based on PVC to which glass fibres have been added that are coextruded with a central layer (P) based on PVC.
- the assembly was thermo formed and bent after attachment of the constituents of the precursor flat panel by laser welding, via the apexes of the hexagonal cells (a), drawn in the longitudinal direction, of the central layer (P), which are covered by coextrusion of a layer (not represented) of a plastic, identical to or different from the matrix of the central layer and containing carbon black which absorbs the laser beam.
- the sheet (F 2 ) protrudes from the longitudinal edge of the central layer (P) by a length ⁇ , the sheet (Fi) leaving uncovered, on the side of the opposite
- Figure lb represents an elevation view, along the cutting plane A - A, of the left portion of the same curved segment as that represented in perspective in Figure la.
- the multilayer- wall curved segments according to the invention may be used for the manufacture of pipes used in any application where high ring stiffness presents an advantage. These pipes make good, light and stiff, substitutes for concrete pipes. They are particularly suitable for the discharge of wastewater or rainwater.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0957961A FR2952323B1 (fr) | 2009-11-12 | 2009-11-12 | Segment incurve a paroi multicouche en matiere plastique pour l'assemblage de tubes |
PCT/EP2010/067071 WO2011057994A1 (en) | 2009-11-12 | 2010-11-09 | Plastic multilayer-wall curved segment for assembling pipes |
Publications (1)
Publication Number | Publication Date |
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EP2498974A1 true EP2498974A1 (de) | 2012-09-19 |
Family
ID=42262394
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP10773356A Withdrawn EP2498974A1 (de) | 2009-11-12 | 2010-11-09 | Gekrümmtes kunststoffsegment mit mehrschichtigerwand zur montage von rohren |
Country Status (5)
Country | Link |
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EP (1) | EP2498974A1 (de) |
BR (1) | BR112012011289A2 (de) |
FR (1) | FR2952323B1 (de) |
RU (1) | RU2012124025A (de) |
WO (1) | WO2011057994A1 (de) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US9956718B2 (en) * | 2012-09-18 | 2018-05-01 | The Boeing Company | Method of forming a tube from a thermoplastic sandwich sheet |
FI127375B (fi) * | 2016-06-07 | 2018-04-30 | Tuub Oy | Putki ja menetelmä putken valmistamiseksi |
CN106863874B (zh) * | 2017-03-06 | 2019-04-09 | 中国商用飞机有限责任公司北京民用飞机技术研究中心 | 一种复杂曲面蜂窝夹层结构的蜂窝定型方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PT80171B (pt) * | 1985-03-27 | 1987-08-19 | Oliveira Carlos Joaquim Costa Martins De | Colector pre-fabricado de juntas longitudinais |
FR2745746A1 (fr) | 1996-03-05 | 1997-09-12 | Sade Compagnie Generale De Tra | Materiau composite pour le chemisage de canalisations |
DE19882311T1 (de) * | 1997-04-08 | 2000-05-11 | Zardoz Pty Ltd | Verbessertes Rohrleitungssystem |
US20080268225A1 (en) | 2004-10-20 | 2008-10-30 | Solvay (Societe Anonyme) | Method for Manufacturing a Multilayer Insulating Panel |
WO2006084117A2 (en) * | 2005-02-02 | 2006-08-10 | Panterra Engineered Plastics, Inc. | Method for forming and bonding thermoformable composites |
FR2883791B1 (fr) | 2005-04-05 | 2007-06-01 | Solvay | Structure plane composee d'un assemblage cohesif de cellules alveolaires jointives |
BRPI0614862A2 (pt) | 2005-08-19 | 2012-12-04 | Solvay | processo para fabricar uma estrutura celular à base de plástico, e, dispositivo para implementar o processo |
FR2899145B1 (fr) * | 2006-03-29 | 2008-05-09 | Solvay | Procede pour la fabrication d'une structure alveolaire a base de matiere plastique |
FR2928712A1 (fr) | 2008-03-17 | 2009-09-18 | Solvay | Tube a paroi structuree en plastique, procede de fabrication dudit tube et utilisation particuliere de celui-ci. |
-
2009
- 2009-11-12 FR FR0957961A patent/FR2952323B1/fr not_active Expired - Fee Related
-
2010
- 2010-11-09 WO PCT/EP2010/067071 patent/WO2011057994A1/en active Application Filing
- 2010-11-09 BR BR112012011289A patent/BR112012011289A2/pt not_active IP Right Cessation
- 2010-11-09 EP EP10773356A patent/EP2498974A1/de not_active Withdrawn
- 2010-11-09 RU RU2012124025/05A patent/RU2012124025A/ru not_active Application Discontinuation
Non-Patent Citations (1)
Title |
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See references of WO2011057994A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2011057994A1 (en) | 2011-05-19 |
BR112012011289A2 (pt) | 2018-04-03 |
FR2952323B1 (fr) | 2011-12-09 |
RU2012124025A (ru) | 2013-12-20 |
FR2952323A1 (fr) | 2011-05-13 |
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