EP2494877A2 - Multi-component filter for a smoking article - Google Patents

Multi-component filter for a smoking article Download PDF

Info

Publication number
EP2494877A2
EP2494877A2 EP12168428A EP12168428A EP2494877A2 EP 2494877 A2 EP2494877 A2 EP 2494877A2 EP 12168428 A EP12168428 A EP 12168428A EP 12168428 A EP12168428 A EP 12168428A EP 2494877 A2 EP2494877 A2 EP 2494877A2
Authority
EP
European Patent Office
Prior art keywords
filter
segment
flavour release
end segment
component filter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP12168428A
Other languages
German (de)
French (fr)
Other versions
EP2494877B2 (en
EP2494877B1 (en
EP2494877A3 (en
Inventor
Clement Besso
Yves Jordil
Charles Kuersteiner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Philip Morris Products SA
Original Assignee
Philip Morris Products SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=38922805&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP2494877(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Philip Morris Products SA filed Critical Philip Morris Products SA
Priority to EP12168428.6A priority Critical patent/EP2494877B2/en
Publication of EP2494877A2 publication Critical patent/EP2494877A2/en
Publication of EP2494877A3 publication Critical patent/EP2494877A3/en
Application granted granted Critical
Publication of EP2494877B1 publication Critical patent/EP2494877B1/en
Publication of EP2494877B2 publication Critical patent/EP2494877B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure
    • A24D3/048Tobacco smoke filters characterised by their shape or structure containing additives
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/302Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
    • A24B15/303Plant extracts other than tobacco
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/002Cigars; Cigarettes with additives, e.g. for flavouring
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02Manufacture of tobacco smoke filters
    • A24D3/0204Preliminary operations before the filter rod forming process, e.g. crimping, blooming
    • A24D3/0212Applying additives to filter materials
    • A24D3/022Applying additives to filter materials with liquid additives, e.g. application of plasticisers
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/061Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/062Use of materials for tobacco smoke filters characterised by structural features
    • A24D3/063Use of materials for tobacco smoke filters characterised by structural features of the fibers
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/14Use of materials for tobacco smoke filters of organic materials as additive

Definitions

  • the present invention relates to a multi-component filter for a smoking article and to a smoking article comprising such a multi-component filter.
  • Filter cigarettes typically comprise a rod of tobacco cut filler surrounded by a paper wrapper and a cylindrical filter aligned in end-to-end relationship with the wrapped tobacco rod and attached thereto by tipping paper. Ventilation in the form of circumferential perforations is commonly provided at a location along the filter, to mix the mainstream smoke produced during combustion of the wrapped tobacco rod with ambient air.
  • the filter In conventional filter cigarettes, the filter usually consists of a plug of cellulose acetate tow wrapped in porous plug wrap.
  • filter cigarettes with multi-component filters that comprise two or more segments of filtration material for the removal of particulate and gaseous components of the mainstream smoke are also known.
  • filters that include flavourants In particular, it has been proposed to include flavourants in the form of plant material, such as leaves, seeds or roots, from one or more aromatic plants.
  • a filter cigarette is proposed with a multi-component filter having a flavour release segment containing a mixture of plant materials, including liquorice plant material, ginger root and shredded peppermint leaf.
  • a multi-component filter for a smoking article that, in use, provides improved flavour enhancement, and in particular improved mint and menthol flavour delivery to mainstream smoke as it is drawn from a rod of smokable material through the filter by a consumer. Furthermore, it would be desirable to provide a multi-component filter for a smoking article comprising a flavour release segment that minimises loss of flavour during storage.
  • a multi-component filter for a smoking article comprising: a mouth end segment; and a flavour release segment upstream of the mouth end segment, wherein the flavour release segment comprises plant leaf and a filter plasticiser.
  • a smoking article comprising a wrapped rod of smokable material and a multi-component filter according to the present invention attached to the rod of smokable material, preferably by tipping paper.
  • the smoking article is a filter cigarette.
  • upstream and downstream are used to describe the relative positions of segments of the multi-component filter of the invention in relation to the direction of the mainstream smoke drawn from a rod of smokable material through the multi-component filter during use.
  • the flavour release segment is upstream of the mouth end segment, which means that mainstream smoke is drawn first through the flavour release segment and then through the mouth end segment.
  • filter plasticiser refers to any compound suitable for use as a plasticiser in a conventional fibrous cigarette filter plug.
  • the plasticiser is typically a solvent for the fibre material and acts by softening the outer surfaces of the fibres such that they adhere to each other.
  • Glycerol triacetate is commonly used as the filter plasticiser for a cellulose acetate tow.
  • the filter plasticiser used in the present invention is glycerol triacetate.
  • plant leaf is used to denote a material consisting of the leaves of a plant, which have preferably been cut or shredded to provide a particulate material.
  • the flavour release segment may include any plant leaf that is capable of releasing flavour into mainstream smoke drawn through the multi-component filter.
  • the plant leaf is non-tobacco plant leaf.
  • the flavour release segment may include leaf from one or more plants.
  • the flavour released from the plant leaf is provided by volatile compounds, such as oils, contained therein, which are volatilised during smoking.
  • the mainstream smoke enriched with the volatile oils from the plant leaf flows downstream through the mouth end segment of the multi-component filter into the consumer's mouth.
  • the volatile oils Prior to smoking, the volatile oils remain trapped within the plant leaf. This advantageously ensures that loss of flavour during storage of multi-component filters and smoking articles according to the present invention is minimised, and so maximises flavour release into the mainstream smoke during smoking.
  • the plant leaf in the flavour release segment is shredded, cut or otherwise reduced in size. More preferably, the plant leaf has a cut width of between about 0.25 mm and about 3 mm. Most preferably, the plant leaf has a cut width of between about 1 mm and about 2 mm.
  • the plant leaf is dried to a moisture content of between about 8 % and about 10 %.
  • the plant leaf in the flavour release segment comprises herb leaf.
  • the term “herb leaf” is used to denote leaves from an herbaceous plant.
  • An “herbaceous plant” is an aromatic plant without woody tissue, the leaves of which are used for medicinal, culinary or aromatic purposes and are capable of releasing flavour into mainstream smoke drawn through the multi-component filter.
  • the flavour release segment may comprise herb leaf from one or more perennial or annual herbaceous plants.
  • the flavour release segment may comprise herb leaf from herbaceous plants including, but not limited to, peppermint, lemon balm, basil cinnamon, lemon basil, chive, coriander, basil, lavender, sage, tea, thyme and carvi.
  • the plant leaf in the flavour release segment comprises peppermint leaf.
  • the oil content of the peppermint leaf is at least about 0.6 % by weight.
  • the inclusion of peppermint leaf in the flavour release segment of multi-component filters according to the present invention advantageously provides an improved way of imparting mint and menthol flavours to the mainstream smoke of a smoking article.
  • Smoking articles according to the present invention with multi-component filters comprising peppermint leaf advantageously provide enhanced mint and menthol flavours compared to conventional menthol cigarettes.
  • the plant leaf in the flavour release segment is peppermint leaf and the filter plasticiser is glycerol triacetate. It has surprisingly been found that the inclusion of peppermint leaf and glycerol triacetate in the flavour release segment of multi-component filters and smoking articles according to the present invention advantageously enhances the mint and menthol flavour provided by the release of menthol and other volatile oils from the peppermint leaf. This is illustrated, for example, by the results shown in Table 1, below.
  • Table 1 shows the quantities of particular flavour compounds released into the mainstream smoke from peppermint leaf in the flavour release segment of filter cigarettes (Samples 1 and 3) according to the invention having the general construction shown in Figure 1 .
  • the flavour release segment consists of a plug of cellulose acetate tow with peppermint leaf and glycerol triacetate distributed therein.
  • Table 1 also shows the quantities of the flavour compounds released from peppermint leaf in the flavour release segment of filter cigarettes (Samples 2 and 4) not according to the invention having the same construction as Samples 1 and 3, but in which the flavour release segment does not contain glycerol triacetate.
  • Each of the samples contains 40 mg of peppermint leaf. Not all of the compounds released from the peppermint leaf are measured.
  • Each of the samples is smoked under ISO conditions and the smoke extracts obtained are analysed using a GC-MS single ion monitoring method in order to determine the levels of the volatile compounds in the smoke.
  • a full scan analysis with a scan range from 30 to 400 m/z (anion mass to charge ratio) is performed.
  • the combination of glycerol triacetate and peppermint leaf in the flavour release segment of the filter cigarettes according to the present invention results in increased levels of flavour compounds being released from the peppermint leaf into the mainstream smoke during smoking compared to the filter cigarettes not according to the invention, in which the flavour release segment does not contain glycerol triacetate.
  • acetic acid and glycerine are released in the flavour release segment of the filter as a result of hydrolysis of the glycerol triacetate. Accordingly, the levels of acetic acid released in the filter during smoking are significantly higher than for a smoking article not according to the invention, as illustrated by the results shown in Table 2, below.
  • Table 2 gives the dimensions and properties of a filter cigarette (Sample 5) according to the present invention having the general construction shown in Figure 1 .
  • the mouth end segment of the filter cigarette consists of a plug of cellulose acetate tow and the flavour release segment consists of a plug of cellulose acetate tow with peppermint leaf and glycerol triacetate distributed therein.
  • Table 2 also gives the dimensions and properties of a filter cigarette (Sample 6) not according to the present invention having the same construction as Sample 5, but in which the flavour release segment does not contain glycerol triacetate.
  • the overall length of smoking articles according to the present invention is between about 70 mm and about 128 mm, more preferably about 84 mm.
  • the external diameter of multi-component filters and smoking articles according to the present invention is between about 5 mm and 8.5 mm, more preferably about 7.9 mm.
  • the overall length of multi-component filters according to the present invention is between about 18 mm and about 36 mm, more preferably about 27 mm.
  • the length of each individual segment of multi-component filters according to the present invention is between about 5 mm and about 22 mm.
  • the mouth end segment of multi-component filters according to the present invention may, in some embodiments, advantageously prevent plant leaf from the flavour release segment reaching the mouth of the consumer during smoking.
  • the mouth end segment comprises filtration material. More preferably, the mouth end segment comprises filtration material that has substantially no particulate phase filtration efficiency or very low particulate phase filtration efficiency.
  • the mouth end segment may, for example, comprise cellulosic material, such as cellulose acetate tow, or other suitable fibrous filtration material of low filtration efficiency.
  • the length of the mouth end segment is preferably between about 3 mm and about 12 mm, more preferably between about 6 mm and about 8 mm.
  • Multi-component filters according to the present invention may further comprise a rod end segment upstream of the flavour release segment.
  • the rod end segment comprises fibrous filtration material.
  • the rod end segment may, for example, comprise cellulosic material, such as cellulose acetate tow, or other suitable fibrous filtration materials such as paper.
  • cellulosic material such as cellulose acetate tow
  • fibrous filtration materials such as paper.
  • the rod end segment may comprise at least one sorbent capable of removing at least one gas phase constituent from mainstream smoke drawn through the filter.
  • the at least one sorbent is selected from the group consisting of activated carbon, active aluminium, zeolites, sepiolites, molecular sieves and silica gel.
  • the rod end segment may include one or more flavourants, preferably one or more liquid flavourants, to further enhance flavour delivery to the consumer during smoking.
  • the rod end segment may comprise a plug of filtration material including one or more threads impregnated with liquid flavourant.
  • the one or more threads may be made from cellulose acetate yarn, rayon, cotton, or any other hydrophilic textile or non-textile material capable of absorbing or adsorbing the liquid flavourant.
  • the threads may be coloured, for example, to indicate the type of flavourant impregnated therein. If more than one thread is provided, the threads may be the same or different colours and may be impregnated with the same or different liquid flavourants.
  • the threads are between about 0.6 mm and about 2.0 mm in diameter, more preferably about 0.8 mm in diameter.
  • Filter plugs comprising flavourant bearing threads suitable for use in rod end segments of multi-component filters according to the present invention, and methods and apparatuses for producing such plugs, are described in US Patents Nos. 4,281,671 and 7,074,170 and are available from the American Filtrona Company, Richmond, Virginia, USA.
  • the rod end segment may include a plurality of beads impregnated with liquid flavourant.
  • the beads may be formed from, for example, a cellulosic material bonded with a polyvinyl acetate binder, or from tobacco powder bonded with microcrystalline cellulose.
  • Beads suitable for use in rod end segments of multi-component filters according to the present invention are manufactured and sold under the brand Viscopearls® by Rengo Co. Ltd., Japan. Methods and apparatuses for producing such beads are also described in Japanese Patent Application No. 10182842 .
  • the beads may be of the same or different diameters and colours.
  • the colour of the beads may, for example, indicate the type of flavourant with which they are impregnated.
  • the beads are between about 0.2 mm and about 2 mm in diameter.
  • Liquid flavourants for use in the rod end segments of multi-component filters according to the present invention may include one or more flavour ingredients to create a certain flavour type and may be natural extracts, synthetic flavours, or a combination thereof.
  • Liquid flavourants and flavour types that may be included in the rod end segment of multi-component filters according to the present invention include, but are not limited to, menthol, peppermint, spearmint, coffee, tea, spices (such as cinnamon, clove and ginger), cocoa, vanilla and fruit flavourants.
  • the rod end segment of the multi-component filter preferably comprises a liquid menthol flavourant.
  • the provision of a menthol flavourant in the rod end segment advantageously enhances the flavour released into mainstream smoke drawn through the filter during smoking and compliments the menthol and mint flavours released downstream into the mainstream smoke by the peppermint leaf in the flavour release segment.
  • the mouth end segment may comprise at least one flavourant, such as those previously described above for the rod end segment.
  • a flavourant such as those previously described above for the rod end segment.
  • the mouth end segment includes one or more threads impregnated with liquid flavourant.
  • Multi-component filters according to the present invention may include mouth end segments comprising at least one flavourant or rod end segments comprising at least one flavourant or mouth end segments comprising at least one flavourant and rod end segments comprising at least one flavourant.
  • the mouth end segment and the rod end segment comprise at least one flavourant
  • the at least one flavourant in the mouth end segment may be the same as or different to the at least one flavourant in the rod end segment.
  • flavour is released into the mainstream smoke from the plant leaf in the flavour release segment.
  • flavour is also released upstream of the flavour release segment as previously described above.
  • flavour is also released downstream of the flavour release segment.
  • Multi-component filters according to the present invention may, therefore, provide dual or triple flavour enhancement to mainstream smoke drawn through the filter during smoking.
  • Multi-component filters according to the present invention may be produced by forming separate continuous rods comprising multiple units of each individual segment of the multi-component filter and then combining these separate rods in a known manner in one or more stages to form a continuous filter rod comprising multiple units of the multi-component filter.
  • the continuous filter rod may then be subsequently severed at regular intervals by a cutting mechanism to yield a succession of discrete multi-component filters according to the invention.
  • smoking articles according to the present invention comprise a wrapped rod of tobacco cut filler.
  • smoking articles according to the present invention have a total nicotine free dry particulate matter (NFDPM) or "tar" delivery of up to about 10 mg. More preferably, the "tar delivery” is between 1 mg and 10 mg and more preferably about 6 mg.
  • NFDPM nicotine free dry particulate matter
  • Smoking articles according to the present invention may be packaged in containers, for example in soft packs or hinge-lid packs, with an inner liner coated with one or more flavourants.
  • the plant leaf in the flavour release segment is distributed through a plug of fibrous filtration material, preferably a cellulose acetate tow.
  • the filter plasticiser is applied to the fibrous filtration material in a conventional manner, by spraying it onto the separated fibres, preferably before applying the plant leaf to the filtration material.
  • the plant leaf is substantially evenly distributed along the length the plug of fibrous filtration material.
  • the loading of peppermint leaf in the flavour release segment is preferably between about 1 mg and about 4 mg per mm of the flavour release segment for a multi-component filter having a diameter of between about 7.5 mm and about 7.8 mm.
  • the amount of filter plasticiser may be between 1% and 9% by weight of the plug of fibrous filter material, preferably 5% or less by weight of the plug of fibrous filter material. If glycerol triacetate is used as the filter plasticiser, the amount of glycerol triacetate is preferably about 5% by weight of the cellulose acetate tow or other fibrous filtration material. This level of glycerol triacetate has been found to provide an acceptable rigidity of the plug of fibrous filtration material of the flavour release segment without obstructing the release of flavour from the peppermint leaf. It is notably lower than the amount of glycerol triacetate in conventional cellulose acetate tow filter plugs, which is typically about 7% by weight.
  • the flavour segment is preferably between about 5 mm and about 22 mm in length, more preferably between about and 10 mm about 15 mm in length, most preferably about 12 mm in length.
  • the mouth end segment may comprise a hollow tube or recess.
  • the hollow tube or recess may be formed when the multi-component filter is attached to a rod of smokable material by, for example, tipping paper to form a smoking article according to the present invention.
  • the downstream end of the flavour release segment is visible at the mouth end of the multi-component filter through the hollow tube or recess, allowing the consumer to see the plant leaf distributed in the plug of fibrous filtration material.
  • the length of the mouth end segment is preferably between about 3 mm and about 4 mm.
  • the flavour release segment comprises a plug of plant leaf, preferably compressed plant leaf, coated with a filter plasticiser.
  • the plug preferably does not comprise any other materials.
  • the filter plasticiser may be applied to the plant leaf before, or after the plug is formed.
  • the amount of filter plasticiser is preferably between about 0.5 % and about 1.5 % by weight of the plant leaf. If the flavour release segment comprises a plug of peppermint leaf coated with glycerol triacetate, the amount of glycerol triacetate is preferably between about 0.5% and about 1.5% by weight of the peppermint leaf. In such smoking articles a much lower level of glycerol triacetate is required than in smoking articles in which the peppermint leaf is distributed in a plug of fibrous filtration material, since the glycerol triacetate is required only for flavour enhancement and not to stiffen the filter plug.
  • the mouth end segment preferably comprises fibrous filtration material, in order to prevent loss of the peppermint leaf from the filter.
  • the flavour release segment is preferably between about 3 mm and about 12 mm in length.
  • multi-component filters according to the present invention further comprises a second flavour release segment between the mouth end segment and the flavour release segment previously described.
  • the inclusion of a second flavour release segment further enhances flavour delivery to the consumer during smoking.
  • the second flavour release segment comprises tobacco leaf.
  • the tobacco leaf may be shredded, cut, or otherwise reduced in size.
  • the tobacco leaf is finely cut and more preferably, the tobacco leaf has a cut width of about 0.4 mm.
  • the tobacco leaf in the second flavour release segment is dried.
  • the moisture content of the tobacco leaf is about 15% or less by weight.
  • the length of the second flavour release segment is between about 6 mm and about 12 mm, more preferably between about 6 mm and about 10 mm.
  • the second flavour release segment may include tobacco leaf to which casing comprising, for example, sugars or humectants has been applied.
  • the filter cigarettes shown in Figures 1 to 9 have several components in common and these components have been given the same reference numerals. In each of the side views, portions have been broken away to illustrate interior details of the multi-component filter.
  • Each filter cigarette generally comprises an elongate, cylindrical wrapped tobacco rod 2 attached at one end to an axially aligned, elongate, cylindrical, multi-component filter 4.
  • the wrapped tobacco rod 2 and the multi-component filter 4 are joined in a conventional manner by tipping paper 6, which circumscribes the entire length of the multi-component filter and an adjacent portion of the wrapped tobacco rod 2.
  • tipping paper 6 which circumscribes the entire length of the multi-component filter and an adjacent portion of the wrapped tobacco rod 2.
  • a plurality of annular perforations 8 are provided through the tipping paper 6 at a location along the multi-component filter 4.
  • the multi-component filter 4 of the filter cigarette 10 includes two segments in abutting end-to-end relationship: a mouth end segment 12, distant from the wrapped tobacco rod 2; and a flavour release segment 14, located upstream of the mouth end segment 12 and adjacent to and abutting the wrapped tobacco rod 2.
  • the mouth end segment 12 comprises a plug of cellulose acetate tow of low filtration efficiency plasticised with glycerol triacetate.
  • the flavour release segment 14 comprises a plug of cellulose acetate tow with dried peppermint leaf having a cut width of between 1 mm and 2 mm substantially evenly distributed through it.
  • the plug of cellulose acetate tow includes 5 % by weight of glycerol triacetate plasticiser.
  • the mouth end segment 12 of the multi-component filter 4 shown in Figure 1 is replaced by a recess, which has substantially no filtration efficiency, formed by the tipping paper 6.
  • the multi-component filter 4 of the filter cigarette 20 shown in Figure 2 is of similar construction to the multi-component filter 4 of the filter cigarette 10 shown in Figure 1 and described above.
  • the mouth end segment 12 of the filter cigarette 20 shown in Figure 2 further comprises a central cotton thread 22 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of the filter cigarette 20.
  • the filter cigarette 30 shown in Figure 3 has a multi-component filter 4 that includes three segments in abutting end-to-end relationship: a mouth end segment 12, distant from the tobacco rod 2; a flavour release segment 14 located upstream of the mouth end segment; and a rod end segment 32, located upstream of the flavour release segment 14 and adjacent to and abutting the wrapped tobacco rod 2.
  • the mouth end segment 12 and the flavour release segment 14 are of the same construction as those previously described for the filter cigarette 10 shown in Figure 1 .
  • the rod end segment 32 comprises a plug of cellulose acetate tow of medium to high filtration efficiency which, in use, partially filters out particulate phase components of the mainstream smoke.
  • the multi-component filter 4 of the filter cigarette 40 shown in Figure 4 is of similar construction to the multi-component filter 4 of the filter cigarette 30 shown in Figure 3 and described above.
  • the mouth end segment 12 of the filter cigarette 40 shown in Figure 4 further comprises a central cotton thread 22 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of the filter cigarette 40.
  • the multi-component filter 4 of the filter cigarette 50 shown in Figure 5 is also of similar construction to the multi-component filter 4 of the filter cigarette 30 shown in Figure 3 and described above.
  • the rod end segment 32 of the multi-component filter 4 of the filter cigarette 50 shown in Figure 5 comprises a central cotton thread 52 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of the filter cigarette 50.
  • the multi-component filter 4 of the filter cigarette 60 shown in Figure 6 is once again of similar construction to the multi-component filter 4 of the filter cigarette 30 shown in Figure 3 and described above.
  • both the rod end segment 32 and the mouth end segment 12 of the multi-component filter 4 of the filter cigarette 60 shown in Figure 6 comprise a central cotton thread 22, 52 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of the filter cigarette 60.
  • the rod end segments 32 of the multi-component filters of the filter cigarettes, 40, 50, 60 shown in Figures 4, 5 and 6 may further comprise at least one sorbent capable of removing gas phase constituents from mainstream smoke drawn through the filters 4.
  • the at least one sorbent is, for example, activated carbon, activated aluminium, zeolites or sepiolites provided on the cellulose acetate tow.
  • the multi-component filter 4 of the filter cigarette 70 shown in Figure 7 is of similar construction to the multi-component filter 4 of the filter cigarette 50 shown in Figure 5 and described above.
  • the rod end segment 32 of the multi-component filter 4 of the filter cigarette 70 shown in Figure 7 comprises a plurality of Viscopearls® loaded with menthol, in place of the central cotton thread 52.
  • the mouth end segments 12 of the multi-component filters 4 of the filter cigarettes 30, 40, 50, 60, 70 shown in Figures 3 to 7 is replaced by a recess, which has substantially no filtration efficiency, formed by the tipping paper 6.
  • the filter cigarette 80 shown in Figure 8 has a multi-component filter 4 similar in construction to the multi-component filters 4 of the filter cigarettes 30, 40, 50, 60 shown in Figures 3 to 6 , which includes three segments in abutting end-to-end relationship: a mouth end segment 12, distant from the tobacco rod 2; a flavour release segment 14 located upstream of the mouth end segment; and a rod end segment 32, located upstream of the flavour release segment 14 and adjacent to and abutting the wrapped tobacco rod 2.
  • the mouth end segment 12 and the rod end segment 14 are of the same construction as those previously described for the filter cigarettes 30, 40, 50, 60 shown in Figures 3 to 6 .
  • the flavour release segment 14 comprises a plug of fine cut peppermint leaf, which is coated with glycerol triacetate and compressed, in place of the plug of cellulose acetate tow with peppermint distributed through it.
  • the amount of glycerol triacetate is between about 0.5 % and 1.5 % by weight of the peppermint leaf.
  • either or both of the mouth end segment 12 and the rod end segment 42 of the filter cigarette 80 shown in Figure 8 may include a flavourant, as previously described above for the filter cigarettes 30, 40, 50, 60 shown in Figures 3 to 6 .
  • the filter cigarette 90 shown in Figure 9 has a multi-component filter 4 that includes four segments in abutting end-to-end relationship: a mouth end segment 12, distant from the tobacco rod 2; a first flavour release segment 92 located upstream of the mouth end segment, a second flavour release segment 14 located upstream of the first flavour release segment; and a rod end segment 32, located upstream of the second flavour release segment 14 and adjacent to and abutting the wrapped tobacco rod 2.
  • the mouth end segment 12, the second flavour release segment 14 and the rod end segment 32 are of the same construction as the mouth end segment, the flavour release segment and the rod end segment previously described for the filter cigarettes 30, 40, 50, 60, 70 shown in Figures 3 to 7 .
  • the second flavour release segment 92 comprises a plug of densely packed fine cut tobacco.
  • the multi-component filters 4 are produced and then joined to the wrapped tobacco rods 2, which are produced in a conventional manner, by the tipping paper 6 using known filter cigarette making equipment.
  • each multi-component filter 4 separate continuous rods comprising multiple units of each segment 12, 14, 32, 92 of the multi-component filter 4 are produced in a known manner and then combined to form a continuous filter rod comprising multiple units of the multi-component filter 4.
  • the continuous filter rod is then severed at regular intervals by a cutting mechanism to yield a succession of discrete multi-component filters.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Botany (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

A multi-component filter (4) for a smoking article comprises: a mouth end segment (12); and a flavour release segment (14) upstream of the mouth end segment (12). The flavour release segment (14) comprises plant leaf and a filter plasticiser. The multi-component filter (4) preferably further comprises a rod end segment (32) comprising filtration material upstream of the flavour release segment. Preferably, one or both of the mouth end segment (12) and the rod end segment (32) comprises at least one liquid flavourant. The rod end segment (32) may include a sorbent.

Description

  • The present invention relates to a multi-component filter for a smoking article and to a smoking article comprising such a multi-component filter.
  • Filter cigarettes typically comprise a rod of tobacco cut filler surrounded by a paper wrapper and a cylindrical filter aligned in end-to-end relationship with the wrapped tobacco rod and attached thereto by tipping paper. Ventilation in the form of circumferential perforations is commonly provided at a location along the filter, to mix the mainstream smoke produced during combustion of the wrapped tobacco rod with ambient air.
  • In conventional filter cigarettes, the filter usually consists of a plug of cellulose acetate tow wrapped in porous plug wrap. However, filter cigarettes with multi-component filters that comprise two or more segments of filtration material for the removal of particulate and gaseous components of the mainstream smoke are also known. To enhance the flavour of the mainstream smoke, it is known to provide filter cigarettes with filters that include flavourants. In particular, it has been proposed to include flavourants in the form of plant material, such as leaves, seeds or roots, from one or more aromatic plants. In one known example, a filter cigarette is proposed with a multi-component filter having a flavour release segment containing a mixture of plant materials, including liquorice plant material, ginger root and shredded peppermint leaf.
  • It would be desirable to provide a multi-component filter for a smoking article that, in use, provides improved flavour enhancement, and in particular improved mint and menthol flavour delivery to mainstream smoke as it is drawn from a rod of smokable material through the filter by a consumer. Furthermore, it would be desirable to provide a multi-component filter for a smoking article comprising a flavour release segment that minimises loss of flavour during storage.
  • According to the present invention there is provided a multi-component filter for a smoking article comprising: a mouth end segment; and a flavour release segment upstream of the mouth end segment, wherein the flavour release segment comprises plant leaf and a filter plasticiser.
  • According to the invention there is also provided a smoking article comprising a wrapped rod of smokable material and a multi-component filter according to the present invention attached to the rod of smokable material, preferably by tipping paper. Preferably, the smoking article is a filter cigarette.
  • Throughout the specification, the terms "upstream" and "downstream" are used to describe the relative positions of segments of the multi-component filter of the invention in relation to the direction of the mainstream smoke drawn from a rod of smokable material through the multi-component filter during use. For example, in the filter of the present invention the flavour release segment is upstream of the mouth end segment, which means that mainstream smoke is drawn first through the flavour release segment and then through the mouth end segment.
  • The term "filter plasticiser" refers to any compound suitable for use as a plasticiser in a conventional fibrous cigarette filter plug. In conventional fibrous filter plugs, the role of a filter plasticiser is to bind together the fibres of the plug so that the rigidity of the plug, and therefore its resistance to compression, is increased. The plasticiser is typically a solvent for the fibre material and acts by softening the outer surfaces of the fibres such that they adhere to each other. Glycerol triacetate is commonly used as the filter plasticiser for a cellulose acetate tow.
  • Preferably, the filter plasticiser used in the present invention is glycerol triacetate.
  • The term "plant leaf" is used to denote a material consisting of the leaves of a plant, which have preferably been cut or shredded to provide a particulate material.
  • The flavour release segment may include any plant leaf that is capable of releasing flavour into mainstream smoke drawn through the multi-component filter. Preferably, the plant leaf is non-tobacco plant leaf. The flavour release segment may include leaf from one or more plants. In preferred embodiments, the flavour released from the plant leaf is provided by volatile compounds, such as oils, contained therein, which are volatilised during smoking. The mainstream smoke enriched with the volatile oils from the plant leaf flows downstream through the mouth end segment of the multi-component filter into the consumer's mouth.
  • Prior to smoking, the volatile oils remain trapped within the plant leaf. This advantageously ensures that loss of flavour during storage of multi-component filters and smoking articles according to the present invention is minimised, and so maximises flavour release into the mainstream smoke during smoking.
  • Preferably, the plant leaf in the flavour release segment is shredded, cut or otherwise reduced in size. More preferably, the plant leaf has a cut width of between about 0.25 mm and about 3 mm. Most preferably, the plant leaf has a cut width of between about 1 mm and about 2 mm.
  • Preferably, the plant leaf is dried to a moisture content of between about 8 % and about 10 %.
  • Preferably, the plant leaf in the flavour release segment comprises herb leaf.
  • The term "herb leaf" is used to denote leaves from an herbaceous plant. An "herbaceous plant" is an aromatic plant without woody tissue, the leaves of which are used for medicinal, culinary or aromatic purposes and are capable of releasing flavour into mainstream smoke drawn through the multi-component filter. The flavour release segment may comprise herb leaf from one or more perennial or annual herbaceous plants. For example, the flavour release segment may comprise herb leaf from herbaceous plants including, but not limited to, peppermint, lemon balm, basil cinnamon, lemon basil, chive, coriander, basil, lavender, sage, tea, thyme and carvi.
  • In particularly preferred embodiments of the present invention, the plant leaf in the flavour release segment comprises peppermint leaf. Preferably, the oil content of the peppermint leaf is at least about 0.6 % by weight. The inclusion of peppermint leaf in the flavour release segment of multi-component filters according to the present invention advantageously provides an improved way of imparting mint and menthol flavours to the mainstream smoke of a smoking article. Smoking articles according to the present invention with multi-component filters comprising peppermint leaf advantageously provide enhanced mint and menthol flavours compared to conventional menthol cigarettes.
  • In particularly preferred embodiments of the invention, the plant leaf in the flavour release segment is peppermint leaf and the filter plasticiser is glycerol triacetate. It has surprisingly been found that the inclusion of peppermint leaf and glycerol triacetate in the flavour release segment of multi-component filters and smoking articles according to the present invention advantageously enhances the mint and menthol flavour provided by the release of menthol and other volatile oils from the peppermint leaf. This is illustrated, for example, by the results shown in Table 1, below.
  • Table 1 shows the quantities of particular flavour compounds released into the mainstream smoke from peppermint leaf in the flavour release segment of filter cigarettes (Samples 1 and 3) according to the invention having the general construction shown in Figure 1. The flavour release segment consists of a plug of cellulose acetate tow with peppermint leaf and glycerol triacetate distributed therein. Table 1 also shows the quantities of the flavour compounds released from peppermint leaf in the flavour release segment of filter cigarettes (Samples 2 and 4) not according to the invention having the same construction as Samples 1 and 3, but in which the flavour release segment does not contain glycerol triacetate. Each of the samples contains 40 mg of peppermint leaf. Not all of the compounds released from the peppermint leaf are measured.
  • Each of the samples is smoked under ISO conditions and the smoke extracts obtained are analysed using a GC-MS single ion monitoring method in order to determine the levels of the volatile compounds in the smoke. A full scan analysis with a scan range from 30 to 400 m/z (anion mass to charge ratio) is performed.
  • As can be seen from Table 1, the combination of glycerol triacetate and peppermint leaf in the flavour release segment of the filter cigarettes according to the present invention results in increased levels of flavour compounds being released from the peppermint leaf into the mainstream smoke during smoking compared to the filter cigarettes not according to the invention, in which the flavour release segment does not contain glycerol triacetate. Table 1
    Sample 1 Sample 2 Sample 3 Sample 4
    Tar, mg/cigarette 1 1 6 6
    Glycerol triacetate content of flavour release segment, % 5 0 5 0
    Amount of menthol released into mainstream smoke during smoking, µg/cigarette 0.70 0.25 3.63 1.79
    Amount of menthone released into mainstream smoke during smoking, µg/cigarette 0.45 0.36 1.19 0.87
    Amount of menthyl acetate released into mainstream smoke during smoking, µg/cigarette nd nd 0.187 0.052
    Amount of neomenthol released into mainstream smoke during smoking, µg/cigarette 0.050 0.018 0.254 0.124
    Amount of α-pinene released into mainstream smoke during smoking, µg/cigarette nd nd 0.032 0.030
    Amount of β-pinene released into mainstream smoke during smoking, µg/cigarette nd nd 0.050 0.049
    (nd = not determined)
  • During smoking of a smoking article comprising a multi-component filter according to the invention in which the filter plasticiser is glycerol triacetate, acetic acid and glycerine are released in the flavour release segment of the filter as a result of hydrolysis of the glycerol triacetate. Accordingly, the levels of acetic acid released in the filter during smoking are significantly higher than for a smoking article not according to the invention, as illustrated by the results shown in Table 2, below. Table 2 gives the dimensions and properties of a filter cigarette (Sample 5) according to the present invention having the general construction shown in Figure 1. The mouth end segment of the filter cigarette consists of a plug of cellulose acetate tow and the flavour release segment consists of a plug of cellulose acetate tow with peppermint leaf and glycerol triacetate distributed therein. Table 2 also gives the dimensions and properties of a filter cigarette (Sample 6) not according to the present invention having the same construction as Sample 5, but in which the flavour release segment does not contain glycerol triacetate.
  • As can be seen from Table 2, the combination of glycerol triacetate and peppermint leaf in the flavour release segment of the multi-component filter of the filter cigarette according to the present invention (Sample 5) results in a significantly increased level of acetic acid being released in the filter compared to the filter cigarette not according to the present invention (Sample 6), in which only the mouth end segment contains glycerol triacetate. Table 2
    Sample 5 Sample 6
    Tar, mg/cigarette 6.1 6.2
    Total RTD, mmH2O 93 92
    Ventilation, % 35 36
    Length of cigarette, mm 84.0 84.0
    Length of mouth end segment, mm 15.0 15.0
    Length of flavour release segment, mm 12.0 12.0
    Filter RTD, mmH2O 92.7 91.2
    Glycerol triacetate content of mouth segment, % 7.0 7.0
    Glycerol triacetate content of flavour release segment, % 5.0 0.0
    Peppermint leaves content, mg 40.0 40.0
    Acetic acid concentration, ppm (based on cigarette weight = 920mg) 221 57
  • Preferably, the overall length of smoking articles according to the present invention is between about 70 mm and about 128 mm, more preferably about 84 mm.
  • Preferably, the external diameter of multi-component filters and smoking articles according to the present invention is between about 5 mm and 8.5 mm, more preferably about 7.9 mm.
  • Preferably, the overall length of multi-component filters according to the present invention is between about 18 mm and about 36 mm, more preferably about 27 mm.
  • Preferably, the length of each individual segment of multi-component filters according to the present invention is between about 5 mm and about 22 mm.
  • The mouth end segment of multi-component filters according to the present invention may, in some embodiments, advantageously prevent plant leaf from the flavour release segment reaching the mouth of the consumer during smoking. Preferably, the mouth end segment comprises filtration material. More preferably, the mouth end segment comprises filtration material that has substantially no particulate phase filtration efficiency or very low particulate phase filtration efficiency. The mouth end segment may, for example, comprise cellulosic material, such as cellulose acetate tow, or other suitable fibrous filtration material of low filtration efficiency.
  • Where the mouth end segment comprises filtration material, the length of the mouth end segment is preferably between about 3 mm and about 12 mm, more preferably between about 6 mm and about 8 mm.
  • Multi-component filters according to the present invention may further comprise a rod end segment upstream of the flavour release segment. Preferably, the rod end segment comprises fibrous filtration material. The rod end segment may, for example, comprise cellulosic material, such as cellulose acetate tow, or other suitable fibrous filtration materials such as paper. The inclusion of a rod end segment comprising filtration material advantageously provides additional filtration efficiency.
  • Alternatively or in addition, the rod end segment may comprise at least one sorbent capable of removing at least one gas phase constituent from mainstream smoke drawn through the filter. Preferably, the at least one sorbent is selected from the group consisting of activated carbon, active aluminium, zeolites, sepiolites, molecular sieves and silica gel.
  • The rod end segment may include one or more flavourants, preferably one or more liquid flavourants, to further enhance flavour delivery to the consumer during smoking.
  • For example, the rod end segment may comprise a plug of filtration material including one or more threads impregnated with liquid flavourant. The one or more threads may be made from cellulose acetate yarn, rayon, cotton, or any other hydrophilic textile or non-textile material capable of absorbing or adsorbing the liquid flavourant. The threads may be coloured, for example, to indicate the type of flavourant impregnated therein. If more than one thread is provided, the threads may be the same or different colours and may be impregnated with the same or different liquid flavourants. Preferably, the threads are between about 0.6 mm and about 2.0 mm in diameter, more preferably about 0.8 mm in diameter. Filter plugs comprising flavourant bearing threads suitable for use in rod end segments of multi-component filters according to the present invention, and methods and apparatuses for producing such plugs, are described in US Patents Nos. 4,281,671 and 7,074,170 and are available from the American Filtrona Company, Richmond, Virginia, USA.
  • Alternatively, the rod end segment may include a plurality of beads impregnated with liquid flavourant. The beads may be formed from, for example, a cellulosic material bonded with a polyvinyl acetate binder, or from tobacco powder bonded with microcrystalline cellulose. Beads suitable for use in rod end segments of multi-component filters according to the present invention are manufactured and sold under the brand Viscopearls® by Rengo Co. Ltd., Japan. Methods and apparatuses for producing such beads are also described in Japanese Patent Application No. 10182842 . The beads may be of the same or different diameters and colours. The colour of the beads may, for example, indicate the type of flavourant with which they are impregnated. Preferably, the beads are between about 0.2 mm and about 2 mm in diameter.
  • Liquid flavourants for use in the rod end segments of multi-component filters according to the present invention may include one or more flavour ingredients to create a certain flavour type and may be natural extracts, synthetic flavours, or a combination thereof. Liquid flavourants and flavour types that may be included in the rod end segment of multi-component filters according to the present invention include, but are not limited to, menthol, peppermint, spearmint, coffee, tea, spices (such as cinnamon, clove and ginger), cocoa, vanilla and fruit flavourants. In preferred embodiments of the present invention in which the plant leaf in flavour release segment is peppermint leaf, the rod end segment of the multi-component filter preferably comprises a liquid menthol flavourant. In such embodiments, the provision of a menthol flavourant in the rod end segment advantageously enhances the flavour released into mainstream smoke drawn through the filter during smoking and compliments the menthol and mint flavours released downstream into the mainstream smoke by the peppermint leaf in the flavour release segment.
  • The mouth end segment may comprise at least one flavourant, such as those previously described above for the rod end segment. Preferably, if a flavourant is provided, the mouth end segment includes one or more threads impregnated with liquid flavourant.
  • Multi-component filters according to the present invention may include mouth end segments comprising at least one flavourant or rod end segments comprising at least one flavourant or mouth end segments comprising at least one flavourant and rod end segments comprising at least one flavourant. Where the mouth end segment and the rod end segment comprise at least one flavourant, the at least one flavourant in the mouth end segment may be the same as or different to the at least one flavourant in the rod end segment.
  • In use, as mainstream smoke is drawn from a rod of smokable material through the multi-component filter, flavour is released into the mainstream smoke from the plant leaf in the flavour release segment. In embodiments of the present invention in which at least one flavourant is provided in the rod end segment, flavour is also released upstream of the flavour release segment as previously described above. In embodiments of the present invention in which at least one flavourant is alternatively or additionally provided in the mouth end segment, flavour is also released downstream of the flavour release segment. Multi-component filters according to the present invention may, therefore, provide dual or triple flavour enhancement to mainstream smoke drawn through the filter during smoking.
  • Multi-component filters according to the present invention may be produced by forming separate continuous rods comprising multiple units of each individual segment of the multi-component filter and then combining these separate rods in a known manner in one or more stages to form a continuous filter rod comprising multiple units of the multi-component filter. The continuous filter rod may then be subsequently severed at regular intervals by a cutting mechanism to yield a succession of discrete multi-component filters according to the invention.
  • Preferably, smoking articles according to the present invention comprise a wrapped rod of tobacco cut filler.
  • Preferably, smoking articles according to the present invention have a total nicotine free dry particulate matter (NFDPM) or "tar" delivery of up to about 10 mg. More preferably, the "tar delivery" is between 1 mg and 10 mg and more preferably about 6 mg.
  • Smoking articles according to the present invention may be packaged in containers, for example in soft packs or hinge-lid packs, with an inner liner coated with one or more flavourants.
  • In a first aspect of the present invention, the plant leaf in the flavour release segment is distributed through a plug of fibrous filtration material, preferably a cellulose acetate tow. The filter plasticiser is applied to the fibrous filtration material in a conventional manner, by spraying it onto the separated fibres, preferably before applying the plant leaf to the filtration material.
  • Preferably, the plant leaf is substantially evenly distributed along the length the plug of fibrous filtration material. The loading of peppermint leaf in the flavour release segment is preferably between about 1 mg and about 4 mg per mm of the flavour release segment for a multi-component filter having a diameter of between about 7.5 mm and about 7.8 mm.
  • The amount of filter plasticiser may be between 1% and 9% by weight of the plug of fibrous filter material, preferably 5% or less by weight of the plug of fibrous filter material. If glycerol triacetate is used as the filter plasticiser, the amount of glycerol triacetate is preferably about 5% by weight of the cellulose acetate tow or other fibrous filtration material. This level of glycerol triacetate has been found to provide an acceptable rigidity of the plug of fibrous filtration material of the flavour release segment without obstructing the release of flavour from the peppermint leaf. It is notably lower than the amount of glycerol triacetate in conventional cellulose acetate tow filter plugs, which is typically about 7% by weight.
  • In smoking articles according to the first aspect of the invention, the flavour segment is preferably between about 5 mm and about 22 mm in length, more preferably between about and 10 mm about 15 mm in length, most preferably about 12 mm in length.
  • In smoking articles according to the first aspect of the invention, the mouth end segment may comprise a hollow tube or recess. The hollow tube or recess may be formed when the multi-component filter is attached to a rod of smokable material by, for example, tipping paper to form a smoking article according to the present invention. In such smoking articles, the downstream end of the flavour release segment is visible at the mouth end of the multi-component filter through the hollow tube or recess, allowing the consumer to see the plant leaf distributed in the plug of fibrous filtration material. Where the mouth end segment comprises a hollow tube or recess, the length of the mouth end segment is preferably between about 3 mm and about 4 mm.
  • In a second aspect of the invention, the flavour release segment comprises a plug of plant leaf, preferably compressed plant leaf, coated with a filter plasticiser. The plug preferably does not comprise any other materials. The filter plasticiser may be applied to the plant leaf before, or after the plug is formed.
  • The amount of filter plasticiser is preferably between about 0.5 % and about 1.5 % by weight of the plant leaf. If the flavour release segment comprises a plug of peppermint leaf coated with glycerol triacetate, the amount of glycerol triacetate is preferably between about 0.5% and about 1.5% by weight of the peppermint leaf. In such smoking articles a much lower level of glycerol triacetate is required than in smoking articles in which the peppermint leaf is distributed in a plug of fibrous filtration material, since the glycerol triacetate is required only for flavour enhancement and not to stiffen the filter plug.
  • In smoking articles according to a second aspect of the invention, the mouth end segment preferably comprises fibrous filtration material, in order to prevent loss of the peppermint leaf from the filter.
  • In smoking articles according to the second aspect of the invention, the flavour release segment is preferably between about 3 mm and about 12 mm in length.
  • In a third aspect of the invention, multi-component filters according to the present invention further comprises a second flavour release segment between the mouth end segment and the flavour release segment previously described. The inclusion of a second flavour release segment further enhances flavour delivery to the consumer during smoking.
  • Preferably, the second flavour release segment comprises tobacco leaf. The tobacco leaf may be shredded, cut, or otherwise reduced in size. Preferably, the tobacco leaf is finely cut and more preferably, the tobacco leaf has a cut width of about 0.4 mm.
  • Preferably the tobacco leaf in the second flavour release segment is dried. Preferably the moisture content of the tobacco leaf is about 15% or less by weight.
  • Preferably, the length of the second flavour release segment is between about 6 mm and about 12 mm, more preferably between about 6 mm and about 10 mm.
  • The second flavour release segment may include tobacco leaf to which casing comprising, for example, sugars or humectants has been applied.
  • The invention will be further described, by way of example only, with reference to the accompanying drawings, in which:
    • Figures 1 to 3 show side views of three filter cigarettes comprising multi-component filters according to first, second and third embodiments, respectively, of the first aspect of the present invention;
    • Figures 4 to 7 show schematic longitudinal cross sections of four filter cigarettes comprising multi-component filters according to fourth to seventh embodiments, respectively, of the first aspect of the present invention;
    • Figure 8 shows a side view of a filter cigarette comprising a multi-component filter according to an embodiment of the second aspect of the present invention; and
    • Figure 9 shows a side view of a filter cigarette comprising a multi-component filter according to an embodiment of the third aspect of the present invention.
  • The filter cigarettes shown in Figures 1 to 9 have several components in common and these components have been given the same reference numerals. In each of the side views, portions have been broken away to illustrate interior details of the multi-component filter.
  • Each filter cigarette generally comprises an elongate, cylindrical wrapped tobacco rod 2 attached at one end to an axially aligned, elongate, cylindrical, multi-component filter 4. The wrapped tobacco rod 2 and the multi-component filter 4 are joined in a conventional manner by tipping paper 6, which circumscribes the entire length of the multi-component filter and an adjacent portion of the wrapped tobacco rod 2. To ventilate mainstream smoke produced during combustion of the wrapped tobacco rod 4 with ambient air, a plurality of annular perforations 8 are provided through the tipping paper 6 at a location along the multi-component filter 4.
  • The multi-component filter 4 of the filter cigarette 10 according to the first embodiment of the invention shown in Figure 1 includes two segments in abutting end-to-end relationship: a mouth end segment 12, distant from the wrapped tobacco rod 2; and a flavour release segment 14, located upstream of the mouth end segment 12 and adjacent to and abutting the wrapped tobacco rod 2. The mouth end segment 12 comprises a plug of cellulose acetate tow of low filtration efficiency plasticised with glycerol triacetate. The flavour release segment 14 comprises a plug of cellulose acetate tow with dried peppermint leaf having a cut width of between 1 mm and 2 mm substantially evenly distributed through it. The plug of cellulose acetate tow includes 5 % by weight of glycerol triacetate plasticiser.
  • In an alternative embodiment of the present invention (not shown), the mouth end segment 12 of the multi-component filter 4 shown in Figure 1 is replaced by a recess, which has substantially no filtration efficiency, formed by the tipping paper 6.
  • The multi-component filter 4 of the filter cigarette 20 shown in Figure 2 is of similar construction to the multi-component filter 4 of the filter cigarette 10 shown in Figure 1 and described above. However, the mouth end segment 12 of the filter cigarette 20 shown in Figure 2 further comprises a central cotton thread 22 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of the filter cigarette 20.
  • The filter cigarette 30 shown in Figure 3 has a multi-component filter 4 that includes three segments in abutting end-to-end relationship: a mouth end segment 12, distant from the tobacco rod 2; a flavour release segment 14 located upstream of the mouth end segment; and a rod end segment 32, located upstream of the flavour release segment 14 and adjacent to and abutting the wrapped tobacco rod 2. The mouth end segment 12 and the flavour release segment 14 are of the same construction as those previously described for the filter cigarette 10 shown in Figure 1.
  • The rod end segment 32 comprises a plug of cellulose acetate tow of medium to high filtration efficiency which, in use, partially filters out particulate phase components of the mainstream smoke.
  • The multi-component filter 4 of the filter cigarette 40 shown in Figure 4 is of similar construction to the multi-component filter 4 of the filter cigarette 30 shown in Figure 3 and described above. However, the mouth end segment 12 of the filter cigarette 40 shown in Figure 4 further comprises a central cotton thread 22 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of the filter cigarette 40.
  • The multi-component filter 4 of the filter cigarette 50 shown in Figure 5 is also of similar construction to the multi-component filter 4 of the filter cigarette 30 shown in Figure 3 and described above. However, the rod end segment 32 of the multi-component filter 4 of the filter cigarette 50 shown in Figure 5 comprises a central cotton thread 52 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of the filter cigarette 50.
  • The multi-component filter 4 of the filter cigarette 60 shown in Figure 6 is once again of similar construction to the multi-component filter 4 of the filter cigarette 30 shown in Figure 3 and described above. However, both the rod end segment 32 and the mouth end segment 12 of the multi-component filter 4 of the filter cigarette 60 shown in Figure 6 comprise a central cotton thread 22, 52 loaded with menthol that extends axially through the plug of cellulose acetate tow, parallel to the longitudinal axis of the filter cigarette 60.
  • In alternative embodiments of the present invention (not shown), the rod end segments 32 of the multi-component filters of the filter cigarettes, 40, 50, 60 shown in Figures 4, 5 and 6 may further comprise at least one sorbent capable of removing gas phase constituents from mainstream smoke drawn through the filters 4. The at least one sorbent is, for example, activated carbon, activated aluminium, zeolites or sepiolites provided on the cellulose acetate tow.
  • The multi-component filter 4 of the filter cigarette 70 shown in Figure 7 is of similar construction to the multi-component filter 4 of the filter cigarette 50 shown in Figure 5 and described above. However, the rod end segment 32 of the multi-component filter 4 of the filter cigarette 70 shown in Figure 7 comprises a plurality of Viscopearls® loaded with menthol, in place of the central cotton thread 52.
  • In alternative embodiments of the present invention (not shown), the mouth end segments 12 of the multi-component filters 4 of the filter cigarettes 30, 40, 50, 60, 70 shown in Figures 3 to 7 is replaced by a recess, which has substantially no filtration efficiency, formed by the tipping paper 6.
  • The filter cigarette 80 shown in Figure 8 has a multi-component filter 4 similar in construction to the multi-component filters 4 of the filter cigarettes 30, 40, 50, 60 shown in Figures 3 to 6, which includes three segments in abutting end-to-end relationship: a mouth end segment 12, distant from the tobacco rod 2; a flavour release segment 14 located upstream of the mouth end segment; and a rod end segment 32, located upstream of the flavour release segment 14 and adjacent to and abutting the wrapped tobacco rod 2. The mouth end segment 12 and the rod end segment 14 are of the same construction as those previously described for the filter cigarettes 30, 40, 50, 60 shown in Figures 3 to 6. The flavour release segment 14 comprises a plug of fine cut peppermint leaf, which is coated with glycerol triacetate and compressed, in place of the plug of cellulose acetate tow with peppermint distributed through it. The amount of glycerol triacetate is between about 0.5 % and 1.5 % by weight of the peppermint leaf.
  • It will be appreciated that either or both of the mouth end segment 12 and the rod end segment 42 of the filter cigarette 80 shown in Figure 8 may include a flavourant, as previously described above for the filter cigarettes 30, 40, 50, 60 shown in Figures 3 to 6.
  • The filter cigarette 90 shown in Figure 9 has a multi-component filter 4 that includes four segments in abutting end-to-end relationship: a mouth end segment 12, distant from the tobacco rod 2; a first flavour release segment 92 located upstream of the mouth end segment, a second flavour release segment 14 located upstream of the first flavour release segment; and a rod end segment 32, located upstream of the second flavour release segment 14 and adjacent to and abutting the wrapped tobacco rod 2. The mouth end segment 12, the second flavour release segment 14 and the rod end segment 32 are of the same construction as the mouth end segment, the flavour release segment and the rod end segment previously described for the filter cigarettes 30, 40, 50, 60, 70 shown in Figures 3 to 7. The second flavour release segment 92 comprises a plug of densely packed fine cut tobacco.
  • To form the filter cigarettes 10, 20, 30, 40, 50, 60, 70, 80, 90 according to the embodiments of the present invention shown in Figures 1 to 9, the multi-component filters 4 are produced and then joined to the wrapped tobacco rods 2, which are produced in a conventional manner, by the tipping paper 6 using known filter cigarette making equipment.
  • To produce each multi-component filter 4, separate continuous rods comprising multiple units of each segment 12, 14, 32, 92 of the multi-component filter 4 are produced in a known manner and then combined to form a continuous filter rod comprising multiple units of the multi-component filter 4. The continuous filter rod is then severed at regular intervals by a cutting mechanism to yield a succession of discrete multi-component filters.

Claims (13)

  1. A multi-component filter (4) for a smoking article comprising:
    a mouth end segment (12); and
    a flavour release segment (14) upstream of the mouth end segment (12),
    wherein the flavour release segment (14) comprises plant leaf coated with a filter plasticiser.
  2. A multi-component filter (4) according to claim 1 wherein the amount of the filter plasticiser is between 0.5% and 1.5% by weight of the plant leaf.
  3. A multi-component filter (4) according to claim 1 or 2 wherein the plant leaf in the flavour release segment (14) is compressed plant leaf.
  4. A multi-component filter (4) according to any of claims 1 to 3 wherein the plant leaf in the flavour release segment (14) comprises herb leaf.
  5. A multi-component filter (4) according to claim 4 wherein the herb leaf (14) comprises peppermint leaf.
  6. A multi-component filter (4) according to any preceding claim wherein the filter plasticiser is glycerol triacetate.
  7. A multi-component filter (4) according to any preceding claim wherein the flavour release segment (14) comprises a plug of cellulose acetate tow with the plant leaf and filter plasticiser distributed therein.
  8. A multi-component filter (4) according to any preceding claim further comprising a rod end segment (32) upstream of the flavour release segment (14).
  9. A multi-component filter according to any preceding claim further comprising a second flavour release segment between the mouth end segment and the flavour release segment.
  10. A multi-component filter (4) according to any preceding claim wherein the mouth end segment (12) comprises filtration material.
  11. A multi-component filter (4) according to any preceding claim wherein the mouth end segment (12) comprises at least one liquid flavourant.
  12. A smoking article (10)(20)(30)(40)(50)(60)(70)(80) comprising:
    a wrapped rod of smokable material (2); and
    a multi-component filter (4) according to any preceding claim attached to the rod of smokable material (2) by tipping paper (6).
  13. A smoking article (10)(20)(30)(40)(50)(60)(70)(80) according to claim 12 wherein the mouth end segment (12) of the multi-component filter (4) is a hollow tube or recess.
EP12168428.6A 2007-08-17 2008-08-14 Multi-component filter for a smoking article Active EP2494877B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12168428.6A EP2494877B2 (en) 2007-08-17 2008-08-14 Multi-component filter for a smoking article

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP07253246A EP2025251A1 (en) 2007-08-17 2007-08-17 Multi-component filter for a smoking article
EP08827853A EP2175749B1 (en) 2007-08-17 2008-08-14 Multi-component filter for a smoking article
EP12168428.6A EP2494877B2 (en) 2007-08-17 2008-08-14 Multi-component filter for a smoking article

Related Parent Applications (2)

Application Number Title Priority Date Filing Date
EP08827853A Division EP2175749B1 (en) 2007-08-17 2008-08-14 Multi-component filter for a smoking article
EP08827853.6 Division 2008-08-14

Publications (4)

Publication Number Publication Date
EP2494877A2 true EP2494877A2 (en) 2012-09-05
EP2494877A3 EP2494877A3 (en) 2013-07-03
EP2494877B1 EP2494877B1 (en) 2014-07-02
EP2494877B2 EP2494877B2 (en) 2018-03-21

Family

ID=38922805

Family Applications (3)

Application Number Title Priority Date Filing Date
EP07253246A Ceased EP2025251A1 (en) 2007-08-17 2007-08-17 Multi-component filter for a smoking article
EP08827853A Active EP2175749B1 (en) 2007-08-17 2008-08-14 Multi-component filter for a smoking article
EP12168428.6A Active EP2494877B2 (en) 2007-08-17 2008-08-14 Multi-component filter for a smoking article

Family Applications Before (2)

Application Number Title Priority Date Filing Date
EP07253246A Ceased EP2025251A1 (en) 2007-08-17 2007-08-17 Multi-component filter for a smoking article
EP08827853A Active EP2175749B1 (en) 2007-08-17 2008-08-14 Multi-component filter for a smoking article

Country Status (24)

Country Link
US (1) US20090044817A1 (en)
EP (3) EP2025251A1 (en)
JP (2) JP5356386B2 (en)
KR (1) KR101514095B1 (en)
CN (2) CN105495685A (en)
AR (1) AR067942A1 (en)
AU (1) AU2008290277B2 (en)
BR (1) BRPI0813791B1 (en)
CO (1) CO6251217A2 (en)
DK (1) DK2175749T3 (en)
EA (2) EA024076B1 (en)
ES (2) ES2504098T5 (en)
HK (2) HK1138158A1 (en)
MX (1) MX2009013969A (en)
MY (1) MY165545A (en)
NZ (1) NZ582088A (en)
PL (1) PL2175749T3 (en)
PT (1) PT2175749E (en)
RS (1) RS52406B (en)
SG (1) SG183002A1 (en)
SI (1) SI2175749T1 (en)
TW (1) TWI446877B (en)
UA (1) UA98664C2 (en)
WO (1) WO2009024866A2 (en)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0820229D0 (en) * 2008-11-05 2008-12-10 British American Tobacco Co Filter for a smoking article
GB0911181D0 (en) * 2009-06-29 2009-08-12 British American Tobacco Co A filter for a smoking article
EP2324722A1 (en) * 2009-11-23 2011-05-25 Philip Morris Products S.A. Novel filter segment comprising a substrate loaded with a smoke-modifying agent
KR101320501B1 (en) * 2009-11-23 2013-10-23 엘지디스플레이 주식회사 Flexible display device and manufacturing method thereof
GB0922253D0 (en) * 2009-12-21 2010-02-03 British American Tobacco Co Sheet filter materials with additives
GB201004976D0 (en) * 2010-03-24 2010-05-12 Filtrona Int Ltd Tobacco smoke filter
GB201007946D0 (en) * 2010-05-12 2010-06-30 British American Tobacco Co Filter additive
EP2401929A1 (en) * 2010-06-30 2012-01-04 Philip Morris Products S.A. Filter for a smoking article
JP5766934B2 (en) 2010-11-01 2015-08-19 株式会社ダイセル Tobacco filter, method for producing the same, and tobacco
EP2462822A1 (en) * 2010-12-13 2012-06-13 Philip Morris Products S.A. Smoking article including flavour granules
CN103458718B (en) * 2011-02-03 2015-03-25 日本烟草产业株式会社 Filter for cigarette and cigarette with filter
GB201104788D0 (en) * 2011-03-22 2011-05-04 British American Tobacco Co Smoking article
CN102302220A (en) * 2011-08-28 2012-01-04 云南烟草科学研究院 Application of lemon balm to binary composite filter tips
CN102423133A (en) * 2011-08-28 2012-04-25 云南烟草科学研究院 Application of mint leaves in binary composite filter tip
UA112328C2 (en) * 2011-11-07 2016-08-25 Філіп Морріс Продактс С.А. MENTAL CONTINUOUS SMOKING PRODUCTS
WO2013098957A1 (en) * 2011-12-27 2013-07-04 日本たばこ産業株式会社 Filter assembly for cigarette, and cigarette
AR089602A1 (en) 2011-12-30 2014-09-03 Philip Morris Products Sa AEROSOL GENERATOR ARTICLE FOR USE WITH AN AEROSOL GENERATOR DEVICE
AU2012360831B2 (en) 2011-12-30 2017-02-16 Philip Morris Products S.A. Smoking article with front-plug and aerosol-forming substrate and method
LT2797450T (en) * 2011-12-30 2018-01-10 Philip Morris Products S.A. Smoking article with front-plug and method
EP2625975A1 (en) 2012-02-13 2013-08-14 Philip Morris Products S.A. Aerosol-generating article having an aerosol-cooling element
IN2014DN09464A (en) 2012-05-31 2015-07-17 Philip Morris Products Sa
AR091509A1 (en) 2012-06-21 2015-02-11 Philip Morris Products Sa ARTICLE TO SMOKE TO BE USED WITH AN INTERNAL HEATING ELEMENT
PL2879528T3 (en) * 2012-08-06 2018-10-31 Philip Morris Products S.A. Method of forming smoking articles with mouth end cavities
EP2712510B1 (en) * 2012-09-28 2016-03-02 Reemtsma Cigarettenfabriken GmbH Smoking article
RU2665672C2 (en) * 2012-12-13 2018-09-03 Джапан Тобакко Инк. Cigarette
US20140261486A1 (en) * 2013-03-12 2014-09-18 R.J. Reynolds Tobacco Company Electronic smoking article having a vapor-enhancing apparatus and associated method
TR201902078T4 (en) * 2013-03-28 2019-03-21 Philip Morris Products Sa Smoking product containing a flavor delivery element.
WO2015181949A1 (en) * 2014-05-30 2015-12-03 日本たばこ産業株式会社 Smoking article having filter attached thereto
GB201421799D0 (en) * 2014-12-08 2015-01-21 British American Tobacco Co A Smoking article , a smoking article filtersection and method of manufacturing a smoking article
TW201635927A (en) 2015-03-27 2016-10-16 菲利浦莫里斯製品股份有限公司 Smoking article with a mouth end cavity and ventilation
CN107846968B (en) * 2015-08-24 2021-04-20 菲利普莫里斯生产公司 Method for manufacturing a multi-component aerosol-forming article
EP3449739A4 (en) * 2016-04-28 2020-01-15 Japan Tobacco, Inc. Cigarette with filter
GB2549803A (en) * 2016-04-29 2017-11-01 British American Tobacco Investments Ltd A filter tube for a smoking article
GB201615601D0 (en) 2016-09-14 2016-10-26 British American Tobacco Investments Ltd Receptacle section
GB201615608D0 (en) * 2016-09-14 2016-10-26 British American Tobacco Investments Ltd A container
GB201615603D0 (en) 2016-09-14 2016-10-26 British American Tobacco Investments Ltd Receptacle section
WO2018154006A1 (en) * 2017-02-27 2018-08-30 Philip Morris Products S.A. Filter element and method for manufacturing thereof
JP2017136084A (en) * 2017-04-05 2017-08-10 日本たばこ産業株式会社 cigarette
GB201717567D0 (en) 2017-10-25 2017-12-06 British American Tobacco Investments Ltd A filter for a smoking article or an aerosol generating product
CN108308704A (en) * 2017-12-27 2018-07-24 广东中烟工业有限责任公司 A kind of composition containing natural extracts and its application in preparing function filter stick plasticizer
US10555558B2 (en) 2017-12-29 2020-02-11 Rai Strategic Holdings, Inc. Aerosol delivery device providing flavor control
CN109998164A (en) * 2019-04-03 2019-07-12 红云红河烟草(集团)有限责任公司 Cigarette filter stick flavor enhancing particle and cigarette filter stick
KR102022909B1 (en) * 2019-06-19 2019-09-19 주식회사 케이티앤지 A smoking article with technology modifying sidestream and a smoking article case including the same
CN111436652A (en) * 2020-03-13 2020-07-24 南通烟滤嘴有限责任公司 Firmware with flow channel corresponding to function and filter stick thereof
CN112493536B (en) * 2020-11-13 2022-11-04 云南养瑞科技集团有限公司 Heating non-combustion cigarette particle filter stick

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4281671A (en) 1978-04-21 1981-08-04 American Filtrona Corporation Production of tobacco smoke filters
JPH10182842A (en) 1996-12-26 1998-07-07 Rengo Co Ltd Production of cellulose microparticle
US7074170B2 (en) 2002-03-29 2006-07-11 Philip Morris Usa Inc. Method and apparatus for making cigarette filters with a centrally located flavored element

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2948282A (en) 1954-06-28 1960-08-09 Eastman Kodak Co Fibrous tobacco smoke filter elements
ZA804947B (en) 1979-08-28 1981-06-24 British American Tobacco Co Smoke filtration
US4924887A (en) 1986-02-03 1990-05-15 R. J. Reynolds Tobacco Company Tobacco rods and filters
US4763674A (en) * 1986-04-16 1988-08-16 Hercules Incorporated Method and device for controlling hydrogen cyanide and nitric oxide concentrations in cigarette smoke
GB8722309D0 (en) * 1987-09-22 1987-10-28 Imp Tobacco Ltd Smoking articles
JPH02127194U (en) 1989-03-29 1990-10-19
CA2015736A1 (en) * 1989-05-11 1990-11-11 Diane G. Schmidt Perfume particles for use in cleaning and conditioning compositions
US4971078A (en) * 1989-08-15 1990-11-20 Hoechst Celanese Corporation Filter for a smoking article containing a flavored hollow fiber
RU2040190C1 (en) * 1993-08-17 1995-07-25 Геннадий Николаевич Вакс Filtering cigarette holder
JPH08196258A (en) * 1995-01-25 1996-08-06 Seiichi Kitabayashi Filter of flavored filter cigarette, flavored filter pipe, etc., and flavored filter cigarette, flavored filter pipe and combined body of flavored filter cigarette or flavored cigarette with filter pipe
JP4209999B2 (en) 1998-05-19 2009-01-14 日本たばこ産業株式会社 Cigarette filter
CN2415620Y (en) * 1999-12-31 2001-01-24 陈慧刚 Hollow filter tips for cigarettes
MY138902A (en) * 2000-04-20 2009-08-28 Philip Morris Prod "cigarette filters of shaped micro cavity fibers impregnated with flavorant materials"
PL207339B1 (en) * 2001-02-22 2010-12-31 Philip Morris Products Cigarette and filter with downstream flavor addition
GEP20043350B (en) 2001-11-21 2004-01-12 Telavi State University Smoking Articles
KR200381466Y1 (en) * 2004-06-24 2005-04-14 김용호 Herb eddition tobacco
US20070000505A1 (en) * 2005-02-24 2007-01-04 Philip Morris Usa Inc. Smoking article with tobacco beads
CN100525662C (en) * 2005-04-19 2009-08-12 张鹰 Delayed releasing mint filter tip for cigarette and its production process
CN2852725Y (en) * 2005-12-26 2007-01-03 张家口卷烟厂 Cigarette with hollow filter tip
PL1889550T3 (en) * 2006-08-04 2010-01-29 Philip Morris Products Sa Multi-component filter providing multiple flavour enhancement

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4281671A (en) 1978-04-21 1981-08-04 American Filtrona Corporation Production of tobacco smoke filters
JPH10182842A (en) 1996-12-26 1998-07-07 Rengo Co Ltd Production of cellulose microparticle
US7074170B2 (en) 2002-03-29 2006-07-11 Philip Morris Usa Inc. Method and apparatus for making cigarette filters with a centrally located flavored element

Also Published As

Publication number Publication date
EP2175749B1 (en) 2012-06-27
JP2013255514A (en) 2013-12-26
CO6251217A2 (en) 2011-02-21
TW200913909A (en) 2009-04-01
MY165545A (en) 2018-04-03
EP2494877B2 (en) 2018-03-21
SI2175749T1 (en) 2012-08-31
DK2175749T3 (en) 2012-08-27
BRPI0813791A2 (en) 2014-12-30
KR20100045410A (en) 2010-05-03
SG183002A1 (en) 2012-08-30
JP2010536336A (en) 2010-12-02
MX2009013969A (en) 2010-03-09
TWI446877B (en) 2014-08-01
WO2009024866A2 (en) 2009-02-26
JP5674885B2 (en) 2015-02-25
AU2008290277A1 (en) 2009-02-26
CN101790329A (en) 2010-07-28
EA201070284A1 (en) 2010-06-30
KR101514095B1 (en) 2015-04-21
AR067942A1 (en) 2009-10-28
PL2175749T3 (en) 2012-11-30
ES2504098T5 (en) 2018-06-07
UA98664C2 (en) 2012-06-11
EP2494877B1 (en) 2014-07-02
PT2175749E (en) 2012-07-30
ES2504098T3 (en) 2014-10-08
EP2494877A3 (en) 2013-07-03
WO2009024866A3 (en) 2009-05-28
JP5356386B2 (en) 2013-12-04
ES2386187T3 (en) 2012-08-13
HK1138158A1 (en) 2010-08-20
US20090044817A1 (en) 2009-02-19
CN105495685A (en) 2016-04-20
EA201200576A1 (en) 2012-12-28
AU2008290277B2 (en) 2012-11-08
EA016920B1 (en) 2012-08-30
EP2175749A2 (en) 2010-04-21
NZ582088A (en) 2011-10-28
HK1176244A1 (en) 2013-07-26
BRPI0813791B1 (en) 2018-09-18
EP2025251A1 (en) 2009-02-18
EA024076B1 (en) 2016-08-31
RS52406B (en) 2013-02-28

Similar Documents

Publication Publication Date Title
EP2494877B1 (en) Multi-component filter for a smoking article
EP1889550B1 (en) Multi-component filter providing multiple flavour enhancement
EP2134201B1 (en) Multi-component filter providing improved flavour enhancement
EP2299854A1 (en) Filter for a smoking article
AU2012241110B2 (en) Multi-component filter for a smoking article

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20120612

AC Divisional application: reference to earlier application

Ref document number: 2175749

Country of ref document: EP

Kind code of ref document: P

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: RS

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: RS

RIC1 Information provided on ipc code assigned before grant

Ipc: A24D 3/14 20060101ALI20130527BHEP

Ipc: A24D 3/06 20060101ALI20130527BHEP

Ipc: A24D 3/04 20060101AFI20130527BHEP

REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1176244

Country of ref document: HK

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20140127

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AC Divisional application: reference to earlier application

Ref document number: 2175749

Country of ref document: EP

Kind code of ref document: P

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: RS

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

Ref country code: AT

Ref legal event code: REF

Ref document number: 675391

Country of ref document: AT

Kind code of ref document: T

Effective date: 20140715

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602008033165

Country of ref document: DE

Effective date: 20140814

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: BOVARD AG, CH

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2504098

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20141008

REG Reference to a national code

Ref country code: HK

Ref legal event code: GR

Ref document number: 1176244

Country of ref document: HK

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 675391

Country of ref document: AT

Kind code of ref document: T

Effective date: 20140702

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20140702

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20141002

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20141103

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20141002

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20141003

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20141102

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

REG Reference to a national code

Ref country code: DE

Ref legal event code: R026

Ref document number: 602008033165

Country of ref document: DE

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140831

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

26 Opposition filed

Opponent name: BRITISH-AMERICAN TOBACCO (INVESTMENTS) LIMITED

Effective date: 20150402

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

REG Reference to a national code

Ref country code: DE

Ref legal event code: R026

Ref document number: 602008033165

Country of ref document: DE

Effective date: 20150402

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140814

PLAF Information modified related to communication of a notice of opposition and request to file observations + time limit

Free format text: ORIGINAL CODE: EPIDOSCOBS2

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20080814

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140702

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140814

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 9

APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO

APBM Appeal reference recorded

Free format text: ORIGINAL CODE: EPIDOSNREFNO

APBP Date of receipt of notice of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA2O

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 10

APBU Appeal procedure closed

Free format text: ORIGINAL CODE: EPIDOSNNOA9O

PUAH Patent maintained in amended form

Free format text: ORIGINAL CODE: 0009272

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT MAINTAINED AS AMENDED

27A Patent maintained in amended form

Effective date: 20180321

AK Designated contracting states

Kind code of ref document: B2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: RS

REG Reference to a national code

Ref country code: DE

Ref legal event code: R102

Ref document number: 602008033165

Country of ref document: DE

REG Reference to a national code

Ref country code: ES

Ref legal event code: DC2A

Ref document number: 2504098

Country of ref document: ES

Kind code of ref document: T5

Effective date: 20180607

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 11

REG Reference to a national code

Ref country code: HK

Ref legal event code: AM43

Ref document number: 1176244

Country of ref document: HK

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: TR

Payment date: 20200813

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20201023

Year of fee payment: 13

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20221026

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210815

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230529

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20230822

Year of fee payment: 16

Ref country code: GB

Payment date: 20230822

Year of fee payment: 16

Ref country code: CH

Payment date: 20230902

Year of fee payment: 16

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20230824

Year of fee payment: 16

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210814

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20240821

Year of fee payment: 17