EP2492456B1 - Système de turbine à vapeur et procédé pour contrôler le débit de vapeur d'un système de turbine à vapeur - Google Patents
Système de turbine à vapeur et procédé pour contrôler le débit de vapeur d'un système de turbine à vapeur Download PDFInfo
- Publication number
- EP2492456B1 EP2492456B1 EP11155946.4A EP11155946A EP2492456B1 EP 2492456 B1 EP2492456 B1 EP 2492456B1 EP 11155946 A EP11155946 A EP 11155946A EP 2492456 B1 EP2492456 B1 EP 2492456B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- steam
- preheating
- main
- turbine
- nozzle box
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K13/00—General layout or general methods of operation of complete plants
- F01K13/02—Controlling, e.g. stopping or starting
Definitions
- the present invention relates to a steam turbine system as well as a method for controlling the steam flow of a steam turbine system.
- Steam turbine systems are already known for generating power and usually comprise a steam system which provides steam to a steam turbine.
- One problem of already existing steam turbine systems is the fact that during the start phase of the steam turbine extensive thermal stress results in the turbine casing of the steam turbine as well as the nozzle box within the steam turbine.
- the thermal stress in such elements of the steam turbine system further results in the risk of material failure over time, in particular weakening of the material over time and multiple start phases.
- One high risk coming together with that problem is the fact that such thermal stress can introduce micro cracks into the material of the turbine casing as well as the nozzle box. Such micro cracks would lead to a dramatic material failure and the breakdown of the whole steam turbine during usage without any pre-warning.
- Afore-mentioned object is achieved by a steam turbine system comprising features of independent claim 1 as well as a method for controlling the steam flow of a steam turbine system with features of independent claim 8.
- Further embodiments of the present invention comprise for example the respective dependent claims.
- a steam turbine system for generating power comprises a steam turbine with turbine blades surrounding a rotor and being arranged inside a turbine casing.
- a steam turbine is meant for generating the power by rotation of the rotor, which is driven by steam running over the turbine blades and forcing the rotor to rotate within the turbine casing.
- Steam turbines are well known and therefore such a steam turbine has not to be described in more detail at this place.
- the inventive steam turbine system further comprises a nozzle box which is provided inside the turbine casing with nozzles, directing steam to the turbine blades of the steam turbine.
- a nozzle box is used to direct the steam in the predefined direction, in particular in the direction of the turbine blades.
- the nozzle box improves the efficiency of the steam turbine due to the fact that the steam is introduced into the turbine casing in an adapted direction corresponding with the necessary direction of the steam to result in a more efficient rotation of the turbine blades and the rotor of the steam turbine.
- a main steam system is provided within the steam turbine system.
- the main steam system comprises a main input port, a main valve, located downstream of the main input port, at least one control valve, located downstream the main valve and upstream the nozzle box, and steam lines connecting the main input port, the main valve, the at least one control valve and the nozzle box.
- the main steam system is used to provide steam from any kind of steam generator or steam source to the steam turbine.
- the main steam system therefore uses the main input port as a technical interface to be connected to any kind of steam source, such as for example a solar steam source, a boiler or any other technical kind of steam generator.
- the rest of the main steam system is necessary to transport the steam from the steam source, in particular from the main input port, to the steam turbine.
- the main valve within such transport steam part is used to fully open or fully close the path for the steam. If the main valve is closed, no steam can arrive at the steam turbine and therefore the turbine blades as well as the rotor are not forced to rotate. In other words a closed main valve results in a stop of the steam turbine as well as in a stop of generating power. On the other hand, if the main valve is opened, steam can flow to the steam turbine and results in a rotation of the turbine blades and the rotor. Thus, the steam turbine generates power when the main valve has been opened.
- At least one control valve Downstream of the main input port as well as downstream of the main valve, at least one control valve is positioned.
- the control valve is a valve, which has the possibility to vary the possible amount of steam, which can flow through the control valve. Therefore, between a fully open and a fully closed position, further positions with different levels of openness of the at least one control valve exist.
- the control valve of is used to control the explicit amount of steam which flows into the steam turbine and therefore it is used to control indirectly the amount of power which is generated by the steam turbine.
- the steam can be introduced into the steam turbine at different positions.
- three different control valves are used, three outlets are provided within the turbine casing, in particular within the nozzle box such that the amount of steam can be separated over the three control valves and the amount of distribution can be shifted between the three lines of the three control valves. Therefore the efficiency of the generation of power by the steam turbine can be further increased.
- the whole system, in particular the nozzle box as well as the turbine casing, are cold respectively comprise a temperature close to the ambient temperature.
- the steam which is provided to the steam turbine is relatively hot. Therefore the provision of steam to the steam turbine results in heating up the material surrounding the main steam system, namely the steam lines as well as the turbine casing and the nozzle box.
- the increase of temperature of such components of the steam turbine system results in thermal expansion of the respective materials. Due to the fact that the nozzle box and the steam turbine comprise a lot more material than for example that main steam system, in particular steam lines, the velocity of heating up is different from component to component. Differences in the velocity of heating up result in differences of the temperature between different components. Furthermore, the differences in temperature result in different geometrical dimensions based on the respective temperature and therefore resulted in thermal stress.
- a preheating steam system comprises a preheating input port, at least one preheating control valve, located downstream of the preheating input port and upstream of the nozzle box, and steam lines connecting the preheating input port, the at least one preheating control valve and the nozzle box.
- the preheating steam system can be understood as some kind of a bypass to the main steam system, providing steam in particular to the nozzle box and also, directly or indirectly to the turbine casing.
- the main valve is still closed, a preheating before the start phase of the steam turbine takes place of the material of the nozzle box as well as the turbine casing.
- the main valve is opened and the start of the steam turbine can take place. Due to the fact that the nozzle box as well as the turbine casing already have a relatively high temperature, the difference in temperature between the different components of the steam turbine system are a lot lower than compared to known systems according to the state of the art. The decrease in temperature difference results in the decrease of thermal stress and therefore decreases the risk of the possibility of micro cracks within the material of the different components.
- the material of the nozzle box is heated up directly by the steam flowing through the preheating steam system.
- the material of the turbine casing can be heated up directly or indirectly.
- An indirect heating up would take place if the nozzle box is provided with steam by the preheating steam system and the steam within the nozzle box also influences, namely heats up, the material of the turbine casing.
- the preheating steam system comprises steam lines which proceed through the turbine casing. In such a construction, the preheating of the turbine casing takes place directly, namely due to direct contact between the heated steam of the preheating steam system as well as the material of the turbine casing.
- the steam lines of the main steam system as well as of the preheating steam system can be pipes, in particular pipelines made of any kind of material which can stand the temperature and pressure of the steam.
- pipes, made of enforced plastics are used.
- the input ports are formed integrally namely as one combined input port forming the main input port and the preheating input port.
- a preheating control valve can be located, providing two functionalities, namely first to separate the steam between the main steam system and the preheating steam system as well as closing/opening both systems by comprising the functionality of the main valve as well as of the preheating control valve.
- the use of such preheating control valve and one combined input port as inter face for steam sources reduces the complexity of the present invention thereby reduces costs of such an inventive steam turbine system.
- the steam lines of the preheating systems from the at least one preheating control valve are connected to the steam lines of the main steam system between the at least one control valve and the nozzle box.
- both systems namely the main steam system and the preheating steam system only need one connection to the nozzle box.
- the connection between the steam lines of the preheating system and the main heating system are placed upstream of such connection to the nozzle box.
- lines for the steam within the steam turbine casing can reduce complexity of such a way of construction.
- the steam turbine system according to the invention is characterized in that the connection between the steam lines of the preheating system and the steam lines of the main steam system is located within the material of the turbine casing. That leads to a very efficient way of direct heating up of the material of the turbine casing.
- the steam, flowing through the preheating steam system flows to such connection and thereby gets into direct contact with the material of the turbine casing.
- Such direct contact leads to transition of heat from the steam to the material of the turbine casing and thereby heats up the respective material directly.
- the steam arrives in the nozzle box and gets also into direct contact with the respective material to heat up the nozzle box.
- Such way of construction therefore leads to a direct heating up of the material of the turbine casing as well as the material of the nozzle box.
- a steam turbine system of the present invention comprises an emergency stop valve which is provided within the main steam system, located downstream of the main valve and upstream of the at least one control valve.
- Such emergency stop valve can be used for emergency situations, in particular when any leakage within the steam turbine is detected.
- a steam turbine system comprises explicitly one or two or three or four control valves, which are provided in the main steam system.
- the provision of specifically one, two, three or four control valves typically results in a respective construction of the nozzle box.
- the nozzle box is constructed to surround the rotor of the steam turbine by 180 degrees, two or specifically three control valves for that main steam system can be of advantage.
- the nozzle box is bigger, for example fully surrounds the rotor of the steam turbine, four control valves and therefore four connections to the nozzle box from the main steam system can be of advantage.
- it is a very small steam turbine, and a very small nozzle box is used it could be of advantage if only one control valve is provided to reduce the complexity and the costs of the main steam system.
- the nozzle box and the turbine casing are positioned in surface contact, in particular are manufactured to be integrally connected.
- the use of such construction, namely the surface contact between nozzle box and turbine casing results in a better and faster heat transmission from the nozzle box to the turbine casing and the other way round.
- the temperature can flow fast between such two components and therefore thermal stress due to thermal differences between such two components is reduced.
- the steam turbine can be constructed such that the nozzle box at least partly surrounds the rotor of the steam turbine.
- the level of surrounding the rotor can depend on the size of the steam turbine, in particular the size of the turbine blades. Once more it has to be noted that the level of surrounding of the rotor also influences the number of control valves which are to be used for the main steam system.
- At least one temperature sensor is provided at a position to measure the temperature of the nozzle box and/or the turbine casing.
- the temperature sensor leads to possibility to include the real time temperature of the respective material into the control of the main steam system as well as the preheating steam system. This further increases the advantage of the preheating system due to the fact that the preheating step can be controlled specifically with respect to the material temperature. In particular it is possible to use the preheating system until the material of the turbine casing and the material of the nozzle box has exceeded over a predefined threshold of temperature.
- the steam lines of the preheating steam system downstream of the at least one preheating control valve are connected to the steam lines of the main steam system between the main valve or the emergency stop valve and the at least one control valve.
- the main valve and/or the emergency stop valve are closed during preheating operation. That way, not only the nozzle box and/or the casing of the steam turbine is preheated, but also the casing of the at least one preheating control valve.
- the differences between the temperature of the casing, the nozzle box and the casing for the at least one preheating control valve can be further reduced, thereby reducing the respective temperature stress within the material.
- a further object of the present invention is to provide a method for controlling the steam flow of a steam turbine system with the features of the present invention. Such method comprises the following steps:
- the steps of opening the main valve of the main steam system and/or closing the preheating control valve of the preheating system are carried out after a predetermined time period.
- a predetermined time period By using such a time period, during design of the steam turbine system, the size and geometry of the material of the nozzle box as well as the size and the geometry of the material of the turbine casing are used to calculate the necessary time to heat up the respective components that the steam provided by a steam source entering in the preheating input port. After such time period has passed by, the preheating will have resulted in the predefined material temperatures and therefore the main steam system can be opened to start the steam turbine to generate power.
- the steps of opening the main valve of the main steam system and/or closing the preheating control valve of the preheating system are carried out after the temperature of the material of the nozzle box and/or the material of the turbine casing have exceeded a predetermined threshold.
- the steam turbine system comprises a temperature sensor which informs a control system about the real temperature of the material of the nozzle box and7/or of the material of the turbine casing.
- FIG 1 one embodiment of an inventive steam turbine system 10 is disclosed.
- the steam turbine system 10 comprises a steam turbine 20, which is enclosed by a turbine casing 26. Within such turbine casing 26 a nozzle box 30 is located.
- a main steam system 40 is provided to provide the nozzle box 30 and thereby the steam turbine 20 with steam.
- the main steam system 40 comprises a main input port 42, which acts as an interface to a not depicted steam source. Steam, introduced into the main input port 42, follows the steam lines 48 and passes the main valve 44, the emergency valve 45 and the control valves 46. After passing the control valves 46, the three steam lines 48 enter the nozzle box 30 to let out the steam into the steam turbine 20.
- the steam turbine system 10 is provided with a preheating steam system 50.
- a preheating steam system 50 comprises a preheating input port 52, acting as an interface also to a steam source.
- Such steam source can be the identical steam source acting as a steam source for the main steam system 40.
- the steam entering the preheating input port 52 passes the preheating control valve 54 and is split into three parallel steam lines 58, to connect to the steam lines 48 of the main steam system 40 between the control valves 46 and the nozzle box 30. Therefore, the functionality of a steam turbine system 10 of the present embodiment can be described as followed.
- the main valve 44 of the main steam system 40 is closed.
- the preheating control valve 54 is opened such that steam coming from a steam source entering the preheating input port 52 can flow through the steam lines 58 of the preheating system 50.
- Such steam flows through the connections to the steam lines 48 of the main steam system 40 downstream of the in particular closed control valves 46 and enters the nozzle box 30.
- the nozzle box 30 is heated up.
- such steam also heats up the turbine casing 26 of the steam turbine.
- the preheating control valve 54 is closed and the main valve 44 of the main steam system 40 is opened.
- the regular work of the steam turbine 20 can begin, namely the steam from a steam source can flow through the nozzle box 30 into the turbine casing 26 and the steam turbine 20 can start to generate power.
- FIG. 1 an alternative embodiment is depicted in figure 2 . Same features comprise same reference signs and only differences between the two embodiments will be described below.
- the embodiment of figure 2 comprises one combined input port for the main input port 42 and the preheating input port 52.
- a three-port valve Located downstream of the combined input port a three-port valve is positioned, comprising the functionality of the main valve 44 of the main steam system 40 and the preheating control valve 54 of the preheating steam system 50.
- such three-port valve comprises the two functionalities of separating the steam from a steam source or steam generator from the combined input port as well as acting as the two necessary valves of the two steam systems 40 and 50.
- the rest of the functionality is identical between the embodiments of figure 1 and figure 2 .
- the main steam system 40 comprising the main valve 44 is also provided with three control valves 46.
- the steam lines 48 follow the way to the nozzle box 30 downstream of the control valves 46 through the material of the turbine casing 26.
- Within the material of the turbine casing 26 there is also the connection to the steam lines 58 of the preheating steam system 50.
- the steam flows through the preheating steam lines 58 and by passing said connection to the steam lines 48 of the main steam system 40. Downstream of that connection, the steam flows within the material of the turbine casing 26 and due to that direct contact between such material and the steam the turbine casing 26 is heated up.
- the nozzle box 30 comprises three nozzles 32, which are connected each to one steam line 48 of the main steam system 40. Thereby the nozzles 32 and the nozzle box 30 are connected to the main steam system 40 as well as to the preheating steam system 50 such that the nozzle box 30 is also preheated by the preheating steam system 50.
- the embodiment of figure 3 comprises a temperature sensor 60, which is located at least partly with its sensing part inside the material of the turbine casing 26.
- a temperature sensor 60 which is located at least partly with its sensing part inside the material of the turbine casing 26.
- Figure 4 shows in a schematic view the embodiment of figure 3 .
- the steam after leaving the nozzles 32 flows along a rotor 24 of the steam turbine 20 and forces the turbine blades 22 to rotate.
- the amount of steam following through the preheating steam system 50 is a lot less than the amount of steam which flows through the main steam system 40. Therefore, the steam which is used to heat up the turbine casing 26 as well as the nozzle box 30 also enters the interior of the turbine casing 26 but does not result in a start of generating power due to the fact that the amount of steam is too low to result in a rotation of the turbine blades 22.
- Fig. 5 shows the preheating operation.
- the emergency stop valve 45 as well as the control valves 46 are closed.
- the preheating control valve 54 is open and thereby the steam can flow though the steam lines 58 of the preheating steam system 50 for heating up the nozzle box 30, the casing 26 as well as the control valves 46, respectively their casing.
- the preheating control valve is closed and the emergency stop valve 45, the control valves 46 as well as the main valve 44 are all set into an open state as it is shown in fig. 6 .
- the preheating steam system 50 is closed and the normal operation mode of the steam turbine 20 can be started.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Control Of Turbines (AREA)
Claims (10)
- Système (10) de turbine à vapeur pour générer une énergie, comprenant :une turbine à vapeur (20) avec des aubes (22) de turbine entourant un rotor (24) et étant agencées à l'intérieur d'un corps (26) de turbine, une boîte (30) de buses prévue à l'intérieur du corps (26) de turbine avec des buses (32) dirigeant de la vapeur vers les aubes (22) de turbine de la turbine à vapeur (20),un système principal (40) de vapeur avec un orifice principal (42) d'entrée, une soupape principale (44), située en aval de l'orifice principal (42) d'entrée, au moins une soupape (46) de commande, située en aval de la soupape principale (44) eten amont de la boîte (30) de buses, et des lignes (48) de vapeur connectant l'orifice principal (42) d'entrée, la soupape principale (44), l'au moins une soupape (46) de commande et la boîte (30) de buses,un système (50) de vapeur de préchauffage avec un orifice (52) d'entrée de préchauffage, au moins une soupape (54) de commande de préchauffage, située en aval de l'orifice (52) d'entrée de préchauffage et en amont de la boîte (30) de buses, et des lignes (58) de vapeur connectant l'orifice (52) d'entrée de préchauffage, l'au moins une soupape (54) de commande de préchauffage et la boîte (30) de buses, dans lequelles lignes (58) de vapeur du système (50) de vapeur de préchauffage provenant de l'au moins une soupape (54) de commande de préchauffage sont connectées aux lignes (48) de vapeur du système principal (40) de vapeur entre l'au moins une soupape (46) de commande et la boîte (30) de buses,caractérisé en ce que la connexion entre les lignes (58) de vapeur du système (50) de vapeur de préchauffage et les lignes (48) de vapeur du système principal (40) de vapeur est située au sein du matériau du corps (26) de turbine.
- Système (10) de turbine à vapeur selon la revendication 1, caractérisé en ce qu'une soupape (45) d'arrêt d'urgence est prévue dans le système principal (40) de vapeur, située en aval de la soupape principale (44) et en amont de l'au moins une soupape (46) de commande.
- Système (10) de turbine à vapeur selon l'une quelconque des revendications 1 à 2, caractérisé en ce qu'une ou deux ou trois ou quatre soupape(s) (46) de commande est/sont prévue(s) dans le système principal (40) de vapeur.
- Système (10) de turbine à vapeur selon l'une quelconque des revendications 1 à 3, caractérisé en ce que la boîte (30) de buses et le corps (26) de turbine sont positionnés en contact de surface, en particulier sont fabriqués pour être connectés de façon intégrale.
- Système (10) de turbine à vapeur selon l'une quelconque des revendications 1 à 4, caractérisé en ce que la boîte (30) de buses entoure au moins partiellement le rotor (24) de la turbine à vapeur (20).
- Système (10) de turbine à vapeur selon l'une quelconque des revendications 1 à 5, caractérisé en ce qu'au moins un capteur (60) de température est prévu en une position pour mesurer la température de la boîte (30) de buses et/ou du corps (26) de turbine.
- Système (10) de turbine à vapeur selon l'une quelconque des revendications 1 à 6, caractérisé en ce que les lignes (58) de vapeur du système (50) de vapeur de préchauffage en aval de l'au moins une soupape (54) de commande de préchauffage sont connectées aux lignes (48) de vapeur du système principal (40) de vapeur entre la soupape principale (44) ou la soupape (45) d'arrêt d'urgence et l'au moins une soupape (46) de commande.
- Procédé de commande de l'écoulement de vapeur d'un système (10) de turbine à vapeur avec les caractéristiques de l'une quelconque des revendications 1 à 7, comprenant les étapes suivantes :- apport de vapeur jusqu'à l'orifice (52) d'entrée de préchauffage,- ouverture d'au moins une soupape (54) de commande de préchauffage tandis que la soupape principale (44) du système principal (40) de vapeur reste au moins partiellement fermée, permettant ainsi que de la vapeur passe par les lignes (58) de vapeur du système (50) de vapeur de préchauffage et pénètre dans la boîte (30) de buses pour chauffer la boîte (30) de buses et/ou le corps (26) de turbine,- ouverture de la soupape principale (44) du système principal (40) de vapeur et démarrage de la commande de l'au moins une soupape (46) de commande pour démarrer la génération d'énergie par la turbine à vapeur (20),- fermeture de l'au moins une soupape (54) de commande de préchauffage du système (50) de vapeur de préchauffage.
- Procédé selon la revendication 8, caractérisé en ce que les étapes d'ouverture de la soupape principale (44) du système principal (40) de vapeur et/ou de fermeture de la soupape (54) de commande de préchauffage du système (50) de vapeur de préchauffage sont mises en oeuvre après une période de temps prédéterminée.
- Procédé selon la revendication 8, caractérisé en ce que les étapes d'ouverture de la soupape principale (44) du système principal (40) de vapeur et/ou de fermeture de la soupape (54) de commande de préchauffage du système (50) de vapeur de préchauffage sont mises en oeuvre après que la température du matériau de la boîte (30) de buses et/ou du matériau du corps (26) de turbine a excédé un seuil prédéterminé.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL11155946.4T PL2492456T3 (pl) | 2011-02-25 | 2011-02-25 | System turbiny parowej oraz sposób sterowania przepływem pary w systemie turbiny parowej |
EP11155946.4A EP2492456B1 (fr) | 2011-02-25 | 2011-02-25 | Système de turbine à vapeur et procédé pour contrôler le débit de vapeur d'un système de turbine à vapeur |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11155946.4A EP2492456B1 (fr) | 2011-02-25 | 2011-02-25 | Système de turbine à vapeur et procédé pour contrôler le débit de vapeur d'un système de turbine à vapeur |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2492456A1 EP2492456A1 (fr) | 2012-08-29 |
EP2492456B1 true EP2492456B1 (fr) | 2016-04-13 |
Family
ID=44021999
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11155946.4A Not-in-force EP2492456B1 (fr) | 2011-02-25 | 2011-02-25 | Système de turbine à vapeur et procédé pour contrôler le débit de vapeur d'un système de turbine à vapeur |
Country Status (2)
Country | Link |
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EP (1) | EP2492456B1 (fr) |
PL (1) | PL2492456T3 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3029280B1 (fr) | 2014-12-04 | 2023-02-08 | General Electric Technology GmbH | Procédé de démarrage d'une turbine à vapeur |
US10577962B2 (en) | 2016-09-07 | 2020-03-03 | General Electric Company | Turbomachine temperature control system |
EP3460205A1 (fr) * | 2017-09-22 | 2019-03-27 | Siemens Aktiengesellschaft | Procédé de fonctionnement d'une turbine à vapeur |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3561216A (en) * | 1969-03-19 | 1971-02-09 | Gen Electric | Thermal stress controlled loading of steam turbine-generators |
US5042246A (en) * | 1989-11-06 | 1991-08-27 | General Electric Company | Control system for single shaft combined cycle gas and steam turbine unit |
JPH0486307A (ja) * | 1990-07-27 | 1992-03-18 | Toshiba Corp | ガスタービン起動装置 |
US5412936A (en) * | 1992-12-30 | 1995-05-09 | General Electric Co. | Method of effecting start-up of a cold steam turbine system in a combined cycle plant |
US7937928B2 (en) * | 2008-02-29 | 2011-05-10 | General Electric Company | Systems and methods for channeling steam into turbines |
-
2011
- 2011-02-25 PL PL11155946.4T patent/PL2492456T3/pl unknown
- 2011-02-25 EP EP11155946.4A patent/EP2492456B1/fr not_active Not-in-force
Also Published As
Publication number | Publication date |
---|---|
PL2492456T3 (pl) | 2016-10-31 |
EP2492456A1 (fr) | 2012-08-29 |
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