Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
  • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
  • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
  • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
  • C10J2300/00—Details of gasification processes
  • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
  • C10J2300/0903—Feed preparation
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
  • C10J2300/00—Details of gasification processes
  • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
  • C10J2300/0913—Carbonaceous raw material
  • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
  • C10J2300/00—Details of gasification processes
  • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
  • C10J2300/0953—Gasifying agents
  • C10J2300/0956—Air or oxygen enriched air
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
  • C10J2300/00—Details of gasification processes
  • C10J2300/12—Heating the gasifier
  • C10J2300/1284—Heating the gasifier by renewable energy, e.g. solar energy, photovoltaic cells, wind
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
  • C10J2300/00—Details of gasification processes
  • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
  • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
  • C10J2300/1606—Combustion processes
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
  • C10J2300/00—Details of gasification processes
  • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
  • C10J2300/1681—Integration of gasification processes with another plant or parts within the plant with biological plants, e.g. involving bacteria, algae, fungi
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
  • C10J2300/00—Details of gasification processes
  • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
  • C10J2300/1693—Integration of gasification processes with another plant or parts within the plant with storage facilities for intermediate, feed and/or product
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
  • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
  • F23G2201/00—Pretreatment
  • F23G2201/20—Dewatering by mechanical means
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
  • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
  • F23G2206/00—Waste heat recuperation
  • F23G2206/10—Waste heat recuperation reintroducing the heat in the same process, e.g. for predrying
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
  • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
  • F23G2209/00—Specific waste
  • F23G2209/26—Biowaste
  • F23G2209/262—Agricultural waste
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
  • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
  • F23G2900/00—Special features of, or arrangements for incinerators
  • F23G2900/50208—Biologic treatment before burning, e.g. biogas generation
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
  • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
  • F23G2900/00—Special features of, or arrangements for incinerators
  • F23G2900/50212—Extruding waste before combustion
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
  • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
  • F23G2900/00—Special features of, or arrangements for incinerators
  • F23G2900/50214—Separating non combustible matters
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E50/00—Technologies for the production of fuel of non-fossil origin
  • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

• the invention relates to a method of treating garbage or waste for their optimal recovery.
• garbage or waste has essentially raised the problem of their elimination or inerting. Part of the energy contained in the garbage or waste is eventually recovered during these operations. Nevertheless, the treatments applied until now on this garbage or waste have not really been optimized for the recovery of the energy they contain.
• biogas materials likely to undergo anaerobic fermentation and thus produce, by methanization, "biogas".
• materials include on the one hand putrescible materials of animal or vegetable origin, and, on the other hand, cellulosic materials (paper, cardboard, ).
• the separation steps of these materials are complex and expensive, and, moreover, that the internal energy of other materials from garbage or raw waste, for example non-recyclable polymeric synthetic materials, is not valued.
• EP 0563173 discloses a waste or waste treatment process in which, after extraction of the inert materials (materials neither fuels nor putrescibles, such as glasses, metals ...), we compress the garbage or non-inert waste to a final pressure greater than 800 bar (800 10 5 Pa), which allows to separate a wet fraction and a fraction combustible.
• the wet fraction essentially made up of biomass can be treated by known methods, for example by appropriate biological seeding, in order to produce either composts by aerobic fermentation or gases by anaerobic fermentation (anaerobic digestion producing "biogas” ) capable of providing heat energy, the anaerobic digestate of fermentation being itself compostable.
• the solid fuel fraction of low relative humidity can either be directly and immediately incinerated in a furnace, or stored outside, then be reclaimed and incinerated during periods to meet a delayed energy demand.
• this combustible fraction which is still considered as a waste remains subject to waste treatment regulations.
• its incineration involves the use of a regulatory furnace, a flue gas treatment device, and a solution for inerting the purification residues of these fumes. As a result, it involves very expensive investments.
• WO 2007/037768 describes a particularly complex process that is supposed to be able to produce combustible gases from various wastes.
• One of the steps of the process consists of gasification of non-inert solid waste previously dried, crushed and packed into granules.
• This method is not usable in the case of waste containing a significant proportion of biomass, and in any case is extremely complex and non-competitive, the cost of treatment being greater than the gains that can be obtained by the valuation.
• US 2007/0181047 discloses a solid waste treatment method of drying the waste and then gasifying it to produce a combustible gas.
• the process is not applicable to waste containing a high proportion of biomass and is in any case non-competitive account the drying, grinding and filtering steps must be carried out before the gasification.
• the invention aims to provide a method of treating garbage or waste which, on the one hand, applies to all kinds of garbage and waste, including high biomass content, and, d On the other hand, it is possible to produce, under economically competitive conditions on an industrial scale, materials which are no longer waste and a minimum quantity of inert final residues.
• the invention aims to provide such a method that allows to significantly increase the amount of energy that can be recovered per unit mass of garbage or waste.
• the units of gaseous volume (m) are the normalized units, that is to say representing the volume occupied by a gas or gas mixture at a temperature of 0 ° C. and under a pressure of 1 bar ( 10 5 Pa).
• endothermic gasification denotes a chemical reaction, of which at least one of the products is a gas and whose overall energy balance shows an absorption of energy, this energy being in particular provided in the form of heat.
• Exothermic combustion or oxidation means a chemical reaction whose energy balance is positive, the energy produced being dissipated in the form of a heat emission.
• the invention relates to a waste or waste treatment method in which:
• waste or waste is subjected to at least one compression stage under conditions suitable for separating them into a fraction, said putrescible fraction, in the form of a pulp of relative humidity greater than 50%, and in a fraction, referred to as a dry fraction; , relative humidity less than 20%,
• the wet fraction extracted by compression of garbage or waste is made of putrescible materials, original fast-fermenting animal or plant and, on the other hand, that the dry fraction, which is formed of cellulose-based materials (paper, cardboard, ...) and polymeric synthetic materials (possibly including composite materials) , can be subjected to a simple endothermic gasification treatment, of good yield and producing a synthetic gas (essentially a mixture of carbon monoxide, hydrogen, nitrogen and carbon dioxide) which can then be directly valorized by combustion, possibly mixed with natural gas and / or with the biogas resulting from the methanisation of the putrescible fraction.
• a synthetic gas essentially a mixture of carbon monoxide, hydrogen, nitrogen and carbon dioxide
• the inventor has found that the dry fraction, as produced at the outlet of the press in the form of blocks of compact sheets has a density substantially of the order of 0.85 and is nonflammable compact mass.
• said dry fraction is easily breakable, after simple disintegration, dry matter having a pulverulent character, therefore very reactive to combustion and gasification.
• the endothermic gasification of such a pulverulent dry matter avoids the occurrence of preferential passages for the gases in the dry matter and allows a homogeneous treatment of all of said dry matter.
• the dry fraction obtained after preliminary sorting followed by compression typically comprises substantially 93% endothermic pyrolysis gasifiable material, 3% of inert material neither combustible nor gasifiable nor fermentable and only 4% of putrescible organic matter.
• the inventor has found that the simple endothermic gasification treatment of a quantity of dry fraction, obtained by compression of the garbage or waste (after possible extraction of the inert materials), formed of cellulose-based materials and polymeric synthetic materials produces a small amount of ultimate residues that remain waste.
• the mass proportion of ultimate residues obtained after endothermic gasification of a quantity of dry fraction is less than 20% of the mass of the starting dry fraction, in particular less than 10%, especially substantially close to 5%.
• the process according to the invention makes it possible to transform garbage or waste entirely into gas (which is not waste), compost, and inert material (glasses, metals and other recyclables, final waste in small quantities).
• the non-inert materials are converted into gas, in particular fuel gas, of high energy value with excellent production efficiency and low cost, which makes it possible to achieve an overall recovery rate of the waste. greater than 90%.
• the endothermic gasification treatment is carried out so as to produce a gaseous composition, called synthetic gas, comprising at least one combustible gas, capable of being burned by exothermic oxidation.
• the endothermic gasification process according to the invention allows the production of a quantity of synthesis gas of which at least a proportion is oxidizable and which is capable of supplying energy during their subsequent oxidative combustion.
• the endothermic gasification process of the dry fraction according to the invention is thus different from combustion incineration processes which produce totally oxidized gases, and which are not energetically recoverable.
• the endothermic gasification treatment is carried out in a reactor, called a gasification reactor, so as to produce a synthesis gas comprising at least one fuel gas selected from the group consisting of dihydrogen (H 2 ) and carbon monoxide (CO).
• a gasification reactor so as to produce a synthesis gas comprising at least one fuel gas selected from the group consisting of dihydrogen (H 2 ) and carbon monoxide (CO).
• the endothermic gasification of said dry fraction is carried out and a synthesis gas is produced consisting essentially of dihydrogen (H 2 ) and carbon monoxide (CO), which are oxidizable and recoverable combustible gases and to a lesser extent of the nitrogen (N 2 ) and carbon dioxide (CO 2 ). It is possible that an endothermic gasification treatment produces nitrogen (N 2 ) and carbon dioxide (CO 2 ) but the total proportion of these two gases in the synthesis gas mixture will not exceed a molar proportion 15%, typically of the order of 10%.
• a synthesis gas consisting essentially of dihydrogen (H 2 ) and carbon monoxide (CO), which are oxidizable and recoverable combustible gases and to a lesser extent of the nitrogen (N 2 ) and carbon dioxide (CO 2 ). It is possible that an endothermic gasification treatment produces nitrogen (N 2 ) and carbon dioxide (CO 2 ) but the total proportion of these two gases in the synthesis gas mixture will not exceed a molar proportion 15%
• an endothermic gasification treatment according to the invention for example in a reducing medium, produces a quantity of synthesis gas containing methane (CH 4 ), which is a gas of particular interest because of its number oxidation (-4) weak.
• CH 4 methane
• a quantity of energy for the endothermic gasification treatment is provided in the form of heat energy.
• the inventor has observed that the increase in the temperature of the dry fraction composed of cellulose-based materials and synthetic materials allows the production of synthesis gas, said synthesis gas being devoid of toxic agents contained in the waste or garbage .
• the endothermic gasification treatment is carried out from a plurality of reagents comprising at least said portion of dry fraction and water vapor.
• the dry fraction obtained by compression has a relative humidity of less than 20% at the outlet of the press.
• the relative humidity of the dry fraction can increase and stabilize, for example, at a value between 26% and 28%.
• the endothermic gasification treatment is carried out without adding additional water.
• the amount of water necessary for the optimal completion of the endothermic gasification is adapted by adding an additional quantity of water if necessary according to the particular chemical composition of the dry fraction.
• the quantity of water required for carrying out the endothermic gasification is provided in the form of water vapor, by adding this water vapor in the endothermic gasification reactor during endothermic gasification.
• the endothermic gasification treatment can be carried out in any case known per se.
• the endothermic gasification treatment is carried out at atmospheric pressure by disposing, in a shaft furnace, also called a gasifier, a layer of dry fraction derived from waste through which an oxidizing gas is blown in the presence of a amount of water vapor.
• a shaft furnace also called a gasifier
• the endothermic gasification treatment is carried out at a temperature of between 700 ° C. and 900 ° C.
• the endothermic gasification treatment is carried out at a temperature of between 800 ° C. and 85 ° C.
• this endothermic gasification temperature is sufficient to effect the endothermic gasification of at least a portion of the dry fraction of relative humidity of less than 20%.
• At least a portion of the amount of heat energy for the endothermic gasification treatment is provided by a combustion of at least a portion, said part to be burned, of the dry fraction with a quantity of gas oxidizing oxidant, said combustion being carried out in the gasification reactor.
• Oxidative combustion of a portion of the dry fraction is carried out with a quantity of oxidizing oxidizing gas so as to produce the energy necessary to increase and maintain the temperature allowing the endothermic gasification reaction to occur.
• the endothermic gasification treatment and the combustion of said part to be burned are carried out simultaneously in a single gasification reactor.
• the energy produced by combustion of said portion to be burned allows the rise of the temperature of the dry fraction which decomposes, in the presence of water vapor, into synthesis gas.
• the inventor has found that the combustion of said part to be burned leads to the production of non-combustible gases, in particular carbon dioxide, but also advantageously makes it possible to reach the endothermic gasification temperature which produces valuable combustible gases.
• the oxidizing gas is a gaseous composition comprising molecular oxygen.
• the oxidizing gas is in particular chosen from the group consisting of atmospheric air and pure molecular oxygen.
• the oxidizing gas is brought into contact with said part to be burned by means of devices known per se, making it possible to introduce an oxidizing gas composition into a combustion chamber, and also to control the quantity and the rate of delivery of the quantity of oxidizing gas. in contact with said part to be burned in order to maintain the optimal temperature of endothermic gasification and to optimize the production of synthetic gas that can be recovered and is liable to be burned by exothermic oxidation.
• the endothermic gasification treatment is carried out with a mass proportion of said part to be burned between 5% and 25%, in particular of the order of 10%, of the dry fraction.
• the inventor has observed that the combustion in air of a small part, in particular a mass proportion of the order of 10%, of the dry fraction advantageously makes it possible to gasify the complementary fraction of 90% of said dry fraction, producing a quantity of synthetic gases that can be recovered and liable to be burned by exothermic oxidation, as well as a small quantity of ash and inert residues.
• the endothermic gasification treatment is carried out with a quantity of oxidizing oxidizing gas of the order of 6000 m per ton of said part to be burned.
• the inventor has also determined that the amount of oxidizing oxidizing gas necessary for the oxidative combustion of one ton of dry fraction resulting from the compression of refuse or waste according to the invention is 6000 m 3 , this volume of oxidizing gas permitting to gasify about 9 tons of dry fraction resulting from the compression of garbage or waste.
• the endothermic gasification treatment is carried out from a quantity of oxidant gas previously heated and then introduced into the gasification reactor by increasing the production efficiency of synthesis gas.
• said amount of oxidizing gas is heated by heat exchange between at least a portion of the synthesis gas produced by the endothermic gasification treatment and said amount of oxidizing gas.
• a heat exchange is carried out between a quantity of a hot synthesis gas produced by the endothermic gasification treatment and said amount of oxidizing gas prior to its introduction into the gasification reactor. This results in a heating of the amount of oxidant gas but also, advantageously, a cooling of the synthesis gas produced.
• a portion of the amount of heat energy required for the endothermic gasification treatment is produced outside the gasification reactor, said gasification reactor then being able to be hermetically closed, especially with respect to atmospheric gases.
• the endothermic gasification treatment is carried out in a closed gasification reactor whose endothermic gasification furnace is heated to a temperature of between 700 ° C. and 900 ° C. with heating means. outside the reactor gasification.
• External heating means of the reactor known per se are used, making it possible to avoid producing, in the hearth of the endothermic gasification reactor, a quantity of non-combustible gas, in particular a molar proportion of non-combustible gas greater than 10%.
• the endothermic gasification treatment is carried out in a gas-tight endothermic gasification plant, maintained under a pressure greater than atmospheric pressure, or on the contrary in an installation maintained in a vacuum in such a way the synthesis gas produced by endothermic gasification does not escape from the gasification plant and the atmospheric gases do not penetrate inside the gasification plant.
• the endothermic gasification treatment can also advantageously be carried out in so-called rotating grid installations, in which the ashes and inert gasification residues are evacuated automatically.
• the endothermic gasification treatment is carried out in a closed gasification reactor whose endothermic gasification furnace is heated to a temperature of between 1200 ° C. and 1300 ° C. 0 C with external heating means to the gasification reactor to produce biofuels.
• At least a part of the amount of heat energy for the endothermic gasification treatment is produced by a combustion, outside the gasification reactor, of at least a part, said part to be burned, of the dry fraction with a quantity of oxidizing oxidizing gas.
• the quantity of heat required for the endothermic gasification treatment is produced by means of the combustion of a portion of the dry fraction, with a relative humidity of less than 20%, which is consequently combustible, outside the reactor of gasification, and said amount of heat is transmitted to said endothermic gasification reactor.
• the gasification reactor is separated from the furnace in which the combustion of said combustion portion occurs, and can not contain non-combustible gas from the combustion of said burning portion of the combustible dry fraction.
• the gasification reactor is heated by separate combustion of a small portion of the dry fraction.
• At least a portion of the amount of heat energy for the endothermic gasification treatment is produced by combustion of a portion of the syngas produced by endothermic gasification.
• a quantity of synthesis gas produced by an endothermic gasification treatment is advantageously used as a fuel, possibly after storage, as a heat energy source for a subsequent endothermic gasification treatment.
• At least a portion of the amount of heat energy required for the endothermic gasification treatment is produced by combustion, inside and / or outside the endothermic gasification reactor, part of the biogas produced by anaerobic fermentation of the putrescible fraction.
• at least a portion of the amount of thermal energy required for the endothermic gasification treatment is produced by a combustion of a gaseous composition comprising a quantity of biogas produced by anaerobic fermentation of the putrescible fraction and a quantity of synthesis gas. produced by endothermic gasification of a portion of dry fraction.
• the endothermic gasification reactor is, furthermore, adapted to allow the collection of the synthesis gases produced during the endothermic gasification treatment of the dry fraction resulting from the compression separation.
• the endothermic gasification reactor is equipped with devices known per se and making it possible to introduce the dry fraction into the reactor of endothermic gasification, and known devices for extracting ashes and inert gasification residues.
• the daily endothermic gasification capacity of the hearth of an endothermic gasification reactor may vary according to the amounts of dry fraction to be gasified, with a capacity typically comprised between one hundred kilograms and ten hundred kilograms of dry fraction for applications in the field. scale, with a capacity of several hundred tonnes of dry fraction for industrial applications.
• a step is taken to extract inert materials neither putrescible nor combustible, so that the garbage or waste resulting from this separation are essentially formed of non-inert materials.
• the putrescible fraction subjected to methanation and the dry fraction subjected to endothermic gasification are substantially free of inert materials neither putrescible nor gasifiable.
• said garbage or waste is compressed to a pressure greater than 700 bar (700 10 5 Pa), in particular between 720 bar (720 10 5 Pa) and 750 bars (750 10 5 Pa), in at least one compression chamber with extrusion orifices through which the putrescible fraction flows.
• the inventor has also observed an acceleration of the anaerobic fermentation rate, leading to a considerable reduction in the time required for this fermentation, because of the penetration of the agents of the fermentation, facilitated by the destructuring of the animal and / or plant tissues. under the combined effect of high pressure applied to garbage or waste during compression and pressure variation during extrusion.
• the separation treatment is carried out at a site, called a separation site, distinct from a site, called a gasification site, on which the endothermic gasification treatment is carried out.
• a site of separation of waste by compression is chosen so as to minimize the distance separating it from the garbage production areas.
• an endothermic gasification site of the dry fraction is chosen so as to minimize the distance between the gas production sites (by endothermic gasification) and the energy conversion site of the gas produced by endothermic gasification.
• an anaerobic fermentation site of the putrescible fraction which is close to the site of separation of the waste by compression is chosen so as to reduce the time between the steps of production and controlled methanization of the putrescible fraction and avoiding the production of uncontrolled gas, outside a biogas enclosure.
• the bringing together of the production sites of the putrescible fraction and methanization of said putrescible fraction makes it possible in particular to avoid the transport, particularly by road, of this putrescible fraction, with rapid fermentation, and liable to generate nuisances for the environment during transport.
• the treatment is carried out by endothermic gasification of the dry fraction after a storage time.
• the dry fraction having a low content of putrescible material and a relative humidity of less than 20%, is particularly suitable for being transported and stored without nuisance.
• the stability of said dry fraction thus makes it possible to delay the production of gas over time.
• the postponement of the endothermic gasification treatment by means of the temporary storage of the dry fraction makes it possible to adapt the production of synthesis gas in order to meet energy needs, and in particular for synthesis gas.
• a gas composition comprising a quantity of synthesis gas and an amount of at least one gas selected from the group consisting of said biogas and natural gas.
• the inventor further observed that the gases constituting the synthesis gas produced by endothermic gasification of the dry fraction and the biogas produced by anaerobic fermentation of the putrescible fraction, obtained according to the invention from the waste or garbage, are no longer legally considered as waste and may be used as raw material fuel for the production of energy.
• the recycle gas is stored prior to combustion.
• the storage of the recycling gas obtained by a process according to the invention said recycling gas being composed for part of biogas obtained by anaerobic fermentation (delayed or instantaneous) of the putrescible fraction resulting from the compression of the waste or garbage and for a other part of synthesis gas obtained by endothermic gasification treatment (delayed or instantaneous) of the dry fraction resulting from the compression of the waste or garbage, allows the use, itself instantaneous or deferred, of the recycling gas for energy needs in industrial sectors, in communities, for the production of electricity.
• the recycling gas prior to its combustion, the recycling gas is stored and if necessary, it is transported in containers or through a network of pipes.
• the biogas and the synthesis gas are separately stored.
• at least one step of purification of biogas and synthesis gas is carried out.
• At least 90% is converted, typically
• garbage or waste in at least a fraction of combustible gas that can be burned by exothermic oxidation, to a residual compost of anaerobic digestion comprising from 40% to 50% of organic matter, and in at least a fraction of inert materials neither putrescible nor combustible, but mostly recyclable (glasses, metals, etc .).
• the invention also relates to a process characterized in combination by all or some of the characteristics mentioned above or below.
• the treatment method according to the invention is applied to a starting composition 10 which consists of household waste or waste.
• the starting composition 10 can be formed of any composition of raw waste containing both putrescible materials (biomass) and non-putrescible materials (including cellulose-based materials: paper, cardboard, ... and polymeric synthetic materials : thermoplastics, thermosets, resins, textiles ).
• the average composition resulting from an urban collection is typically the following (by weight):
• a first step 11 the inert materials are extracted (that is to say the materials neither putrescible nor combustible nor gasifiable such as metals, glasses ).
• This extraction is carried out conventionally by mechanical sorting, automatic or manual and / or by magnetic sorting.
• This extraction step 11 produces on the one hand inert materials 12, and a composition 13 of garbage or waste resulting from this extraction, formed almost entirely of degradable (non-inert) materials, that is to say scalable.
• the inert materials 12 extracted by mechanical and / or magnetic sorting represent of the order of 20% to 25% of the starting composition 10.
• composition 13 of garbage or wastes obtained after extraction of the inert materials is subjected to a high pressure compression separation treatment 14 in a press, until it undergoes a final pressure greater than 700 bar (700 ⁇ 10 5 Pa), typically of the order of 720 bar (720 10 5 Pa) to 750 bar (750 10 5 Pa), having the effect of separating:
• This separation step 14 may be performed in a manner well known in itself, for example as described by EP 0563173, or EP 1173325, or FR 2577167, or the like.
• the wet pulp 15 is the fraction of the composition 13 of garbage or waste likely to flow through the extrusion orifices under the effect of the pressure applied to this composition 13.
• the moist pulp 15 of uniform brown color present in a more or less pasty state has in any case a high relative humidity, typically between 50% and 60%, and is a putrescible fraction that can be immediately shipped for a future treatment delocalized or treated on site within the required time to take advantage of its relatively pure biomass quality; it is subjected to a biological treatment 17 of anaerobic fermentation producing a biogas 18 comprising methane (typically of the order of 60%), carbon dioxide, carbon monoxide and various other gases in lesser amounts.
• the wet pulp 15 generated at the end of the separation step 14 has a very fast fermentation capacity because of the burst, subsequent to the extrusion, of the cells constituting the putrescible organic matter (of animal or vegetable origin). ). It also has a water retention capacity of the order of 2.5 times its mass of dry matter. As a result, the wet pulp 15 does not leak liquid.
• the biological treatment 17 of anaerobic fermentation of the wet pulp 15 further generates a residual compost of anaerobic digestion, comprising from 40% to 50% of organic material, substantially free of inert or plastic undesirable, particularly suitable for use as agricultural fertilizer.
• the agricultural fertilizer complies with the French NF U44-051 standard, fixing at 30% the minimum proportion of organic matter used in composts.
• the residual compost of anaerobic digestion is further enriched in mineral fertilizing materials which are not modified during the methanisation.
• the putrescible fraction is subjected, immediately after the compression separation treatment, to an anaerobic fermentation treatment in a bioreactor as marketed by the company LINDE (Switzerland).
• anaerobic fermentation treatment of the putrescible fraction resulted in the average production of 149 m 3 of biogas per ton of treated wet pulp.
• the gas produced by the anaerobic fermentation treatment of the putrescible fraction is predominantly (60%) methane.
• the dry fraction 16 is subjected to an endothermic gasification treatment 19 at a temperature of between 700 ° C. and 900 ° C., making it possible to produce a synthetic gas comprising carbon monoxide (typically of the order of 45%), dihydrogen (Typically of the order of 50%) and in smaller proportions of nitrogen gas (N 2 ) and carbon dioxide.
• the calorific value of the synthetic gas thus produced is between 12500 kJ / m 3 and 19000 kJ / m 3 .
• the dry fraction 16 contains both mainly cellulosic materials (paper, cardboard, sanitary textiles, etc.) and polymeric synthetic materials (including composite materials).
• This dry fraction can be subjected to an endothermic gasification treatment, with good yields and good conditions, especially given its low humidity, lack of biomass and its loose particle form. At the end of this endothermic gasification treatment, in addition to the synthesis gas 20, it recovers a low proportion of inert ash.
• the biogas 18 can be burned 21 and the synthetic gas can be burned 22, these combustions can be carried out in appropriate facilities to use these gases 18, 20 as fuels for example in boilers for heating or hot water production, steam or electricity production or other.
• the biogas 18 and the synthetic gas 20 can be mixed in whole or in part with each other (mixing step 23) and / or with natural gas (mixing step 24) before being used as fuels in a combustion step 21 and / or 22.
• dry fraction retained inside the enclosure of the press and containing proportions by mass of 93% of pyrogasifiable materials (of which 68% of cellulosic materials, in particular papers, cardboard, sanitary textiles, and 25% of plastics ), 3% incombustible inert substances (glasses, metals, miscellaneous minerals and others that escaped initial sorting) and 4% putrescible organic matter.
• the dry fraction is in the form of blocks of compact sheets, easily manipulated, and whose density is substantially close to 0.85 at the press outlet. It is observed that these blocks constituting the dry fraction, stored in the open air, are only superficially penetrated by rainwater and that these blocks of dry fraction emit, consequently, no water of percolation. We observe In addition to these blocks constituting the dry fraction, despite the presence of a reduced proportion of putrescible material (3%), no significant sign of fermentation. These blocks of combustible material are inert and present no risk of autoignition. They do not give off any odor.
• the relative humidity rate of the dry fraction varies from 20% at the immediate exit of the press and stabilizes at a value of between 26 and 28% after storage, by natural rehumidification by the humidity of the air.
• the elemental composition of the dry gasifiable fraction is as follows, as a percentage by mass of dry matter: carbon 53.5%, dihydrogen 7.7%, sulfur 0.5%, dioxygen 37.0%, dinitrogen 0.7% and chlorine 0.6%.
• a pilot endothermic gasification experiment is carried out on these dry materials resulting from the compression of household waste freed from inert materials.
• About 150 to 200 kg of dry matter obtained by compression separation are placed in a closed gasification reactor.
• the endothermic gasification temperature is maintained at a value of between 800 ° C. and 85 ° C.
• the relative share of the reactor charge devoted to creating the conditions for the endothermic gasification is of the order of 10% of the dry matter at treat.
• the air consumption is of the order of 0.6 m per kilogram of dry matter.
• the air used for the combustion of a portion of the dry fraction is heated prior to its introduction into the reactor by recovering the heat released by the gas produced by gasification.
• a quantity of gas of 0.83 kg is obtained from 1 kg of dry fraction, composed of gaseous dihydrogen (H 2 , 50%), carbon monoxide (45%), and to a lesser extent, of N 2 dinitrogen. and carbon dioxide.
• the gas product has a heating value substantially close to 15000 kJ / m 3 .
• the invention can be the subject of numerous alternative embodiments, in particular as regards the processes and installations used to carry out the separation processes by compression 14, anaerobic fermentation 17, or endothermic gasification 19. These treatments are well known in themselves and can be chosen and optimized according to the compositions to be treated.

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• 2009
  • 2009-07-20 US US13/386,123 patent/US20120122194A1/en not_active Abandoned
  • 2009-07-20 CA CA2768526A patent/CA2768526A1/fr not_active Abandoned
  • 2009-07-20 WO PCT/FR2009/051441 patent/WO2011010002A1/fr active Application Filing
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