EP2454356A1 - Agent liquide détergent ou de nettoyage renfermant un polymère pour l'inhibition des gris - Google Patents

Agent liquide détergent ou de nettoyage renfermant un polymère pour l'inhibition des gris

Info

Publication number
EP2454356A1
EP2454356A1 EP10728245A EP10728245A EP2454356A1 EP 2454356 A1 EP2454356 A1 EP 2454356A1 EP 10728245 A EP10728245 A EP 10728245A EP 10728245 A EP10728245 A EP 10728245A EP 2454356 A1 EP2454356 A1 EP 2454356A1
Authority
EP
European Patent Office
Prior art keywords
acid
weight
washing
cleaning agent
graying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP10728245A
Other languages
German (de)
English (en)
Other versions
EP2454356B1 (fr
Inventor
Marc-Steffen Schiedel
Ulrich Pegelow
Peter Schmiedel
Evelyn Langen
Sabine SCHÜMANN
Martina Hutmacher
Heinz-Jürgen VÖLKEL
Matthias Sunder
Birgit GLÜSEN
Cornelius Bessler
Timothy O'connell
Stephan Gomolka
Eva-Maria Wikker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
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Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to PL10728245T priority Critical patent/PL2454356T3/pl
Publication of EP2454356A1 publication Critical patent/EP2454356A1/fr
Application granted granted Critical
Publication of EP2454356B1 publication Critical patent/EP2454356B1/fr
Revoked legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3719—Polyamides or polyimides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/378—(Co)polymerised monomers containing sulfur, e.g. sulfonate

Definitions

  • the invention relates to a liquid washing or cleaning agent containing surfactant (s), water and a graying-inhibiting polymer.
  • detergents or cleaners To increase the washing or cleaning performance of detergents or cleaners they often contain one or more additives.
  • detergents in order to prevent re-release of previously released soil in finer distribution (redeposition), detergents contain so-called graying inhibitors, such as carboxymethylcellulose.
  • EP 054325 A1 describes a detergent with carboxymethyl cellulose as a graying inhibitor.
  • Carboxymethylcellulose can be incorporated easily, a much lower
  • This object is achieved by using an anionic polymer in a liquid washing or cleaning agent, comprising water and surfactant, for graying inhibition in the washing and / or cleaning of textile fabrics.
  • anionic polymers have a graying-inhibiting effect in liquid, aqueous detergents or cleaners. Furthermore, it has been found that the use of an anionic polymer in a liquid washing or cleaning composition comprising water, surfactant and a graying-inhibiting polysaccharide leads to an increase in the graying-inhibiting effect of the washing or cleaning agent in the washing and / or cleaning of fabrics.
  • anionic polymer is selected from the group comprising acrylic polymers, polyamino acids, polyuronic acids, polyvinylsulfonic acids,
  • Polyalkendicarboxylic acids and mixtures thereof include acrylic acid homopolymers, acrylic acid copolymers, methacrylic acid homopolymers,
  • Methacrylic acid copolymers polyaspartic acids, poly-D-galacturonic acid, poly-D-glucuronic acid, poly-L-iduronic acid, alginic acid, hyaluronic acid, vinylsulfonic acid homopolymers, vinylsulfonic acid copolymers, maleic acid homopolymers, maleic acid copolymers,
  • Fumaric acid homopolymers are either very readily soluble in water or can be stably dispersed in the matrix of an aqueous liquid washing or liquid cleaning agent without precipitations, phase separations and / or high viscosity increases.
  • the anionic polymer is used to increase the graying-inhibiting effect of a detergency-cleaning agent containing a graying-inhibiting polysaccharide
  • the graying-inhibiting polysaccharide is selected from the group consisting of
  • Carboxymethyl cellulose (CMC), ethersulfonic acid salts of starch, ether sulfonic acid salts of cellulose, acid sulfuric ester salts of cellulose, acid sulfuric acid ester salts of starch, methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose
  • Methylhydroxyethylcellulose methylcarboxymethylcellulose, ethylhydroxyethylcellulose and mixtures thereof.
  • the graying-inhibiting polysaccharide is carboxymethylcellulose, especially sodium carboxymethylcellulose.
  • graying-inhibiting polysaccharides in combination with the anionic polymer, lead to detergents or cleaners having a particularly good anti-gray effect.
  • the invention relates to the use of an anionic polymer in a liquid washing or cleaning agent comprising water and surfactant for graying inhibition in the washing and / or cleaning of fabrics at 10 to 30 0 C.
  • the invention relates to the use of an anionic polymer in a liquid washing or cleaning agent comprising water, surfactant and a graying-inhibiting polysaccharide, for increasing the graying-inhibiting effect of the washing or cleaning
  • the invention relates to a liquid washing or cleaning agent containing
  • liquid washing or cleaning agents are obtained when using acrylic acid homopolymers having an average molecular weight Mw of 1,200 or 4,500.
  • the invention relates to a liquid detergent or cleaner containing
  • acrylic acid homopolymers having an average molecular weight Mw of 1,200 or 4,500 gives liquid washing or cleaning agents which have an extremely high grayness inhibition.
  • This special structure makes it possible to disperse graying-inhibiting polysaccharides, in particular sodium carboxymethylcellulose, in a storage-stable manner.
  • the graying-inhibiting effect of the polysaccharides is further enhanced synergistically by the presence of an acrylic acid homopolymer having an average molecular weight of 1,200 or 4,500.
  • an anionic polymer for graying inhibition is used in a liquid washing or cleaning agent.
  • the anionic polymer preferably comprises acrylic polymers, polyamino acids, polyuronic acids, polyvinylsulfonic acids, polyalkendicarboxylic acids and mixtures thereof.
  • acrylic polymer is understood as meaning homopolymers or copolymers which contain at least acrylic acid or methacrylic acid as a monomer
  • polyamino acids in the context of this invention does not include the natural homopolymers or copolymers of this class of polymers (for example proteins). but the synthetic polycondensation products of predominantly ⁇ -amino acids.
  • Polyuronic acids include homopolymers or copolymers of these sugar acids.
  • polyvinylsulfonic acids includes homopolymers or copolymers containing vinylsulfonic acid as a monomer.
  • polyalkendicarboxylic acids includes, for example, homopolymers or copolymers with maleic acid or
  • Fumaric acid as a monomer.
  • Particularly preferred polymers include acrylic acid homopolymers, acrylic acid copolymers, methacrylic acid homopolymers, methacrylic acid copolymers, polyaspartic acids, poly-D-galacturonic acid, poly-D-glucuronic acid, poly-L-iduronic acid, alginic acid, hyaluronic acid, vinylsulfonic acid copolymers, vinylsulfonic acid copolymers, maleic acid homopolymers,
  • the alkali metal salts of the homopolymers of acrylic acid or of methacrylic acid are particularly preferably used. These may have an average molecular weight Mw of 600 to 750,000. However, because of their superior solubility, short-chain homopolymers of the two monomers having an average molecular weight Mw of from 1,000 to 15,000, and more preferably from 1,000 to 8,000, are particularly advantageous.
  • copolymeric polycarboxylates in particular those of acrylic acid with methacrylic acid and of acrylic acid or methacrylic acid with maleic acid.
  • the polymers may also contain allylsulfonic acids, such as allyloxybenzenesulfonic acid and methallylsulfonic acid, as a monomer.
  • Suitable acrylic and methacrylic acid (co) polymers include, for example, the
  • acrylic acid copolymers are furthermore suitable, for example: (i) copolymers of acrylic acid and / or methacrylic acid (INCI acrylates copolymer), which are obtainable, for example, under the trade names Aculyn®, Acusol® or Tego® Polymer; (ii) crosslinked
  • acrylic acid copolymers which include about the crosslinked with an allyl ether of sucrose or pentaerythritol copolymers of C 10 - 30 -alkyl acrylates with acrylic acid and / or methacrylic acid (INCI acrylates / C 1O - 3 o alkyl acrylate crosspolymer) and include, for example available under the trade name Carbopol®.
  • Other suitable polymers are
  • anionic polymers include copolymers of acrylic acid, ethyl acrylate and the sodium salt of 2-methyl-2 - [(1-oxo-2-propen-1-yl) amino] -1-propanesulfonate, copolymers of 4-styrenesulfonic acid and maleic acid, poly 2-acrylamido-2-methyl-1-propanesulfonic acid or copolymers of acrylic acid and acrylamide.
  • said (co) polymers are used in at least partially neutralized form, specifically in the form of their alkali metal salts, preferably sodium salts.
  • the anionic polymer is used in an amount of 0.15 to 20 wt .-%, based on the total washing or cleaning agent. Particularly preferably, the amount of anionic polymer is 0.5 to 6 wt .-%, based on the total washing or cleaning agent.
  • the washing or cleaning agent contains surfactant (s) in addition to the anionic polymer, wherein anionic, nonionic, zwitterionic and / or amphoteric surfactants can be used. From an application point of view, preference is given to mixtures of anionic and nonionic surfactants.
  • the total surfactant content of the liquid washing or cleaning agent is preferably below 60% by weight and more preferably below 45% by weight, based on the total liquid washing or cleaning agent.
  • Suitable nonionic surfactants include alkoxylated fatty alcohols, alkoxylated
  • Fatty acid alkyl esters Fatty acid alkyl esters, fatty acid amides, alkoxylated fatty acid amides, polyhydroxy fatty acid amides, alkylphenol polyglycol ethers, amine oxides, alkyl polyglucosides and mixtures thereof.
  • the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture may contain, as they are usually present in Oxoalkoholresten.
  • alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for example of coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred.
  • Preferred ethoxylated alcohols include, for example, C12 - 14 - alcohols containing 3 EO, 4 EO or 7 EO, C 9 n-alcohol with 7 EO, C-ms alcohols containing 3 EO, 5 EO, 7 EO or 8 EO , C 12 -i 8 -alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as
  • Levels of ethoxylation represent statistical averages, which may be an integer or a fractional number for a particular product.
  • Preferred alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
  • NRE narrow rank ethoxylates
  • fatty alcohols with more than 12 EO can also be used. Examples of these are tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
  • Nonionic surfactants containing EO and PO groups together in the molecule can also be used according to the invention.
  • the washing, cleaning, aftertreatment or washing aid contains a C 12 -i 8 -fatty alcohol with 7 EO or a Ci 3 -i 5 -oxo-alcohol with 7 EO as nonionic surfactant.
  • the content of nonionic surfactants in the washing or cleaning agent is preferably 3 to 40 wt .-%, preferably 5 to 30 wt .-% and in particular 7 to 20 wt .-%, each based on the total detergent or cleaning agent.
  • the washing or cleaning agent may also contain anionic surfactants.
  • the anionic surfactant used is preferably sulfonates, sulfates, soaps, alkyl phosphates, anionic silicone surfactants and mixtures thereof.
  • surfactants of the sulfonate type preferably come C 9 .i 3 -Alkylbenzolsulfonate,
  • Olefinsulfonate ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as obtained for example from Ci 2 _i 8 monoolefins with terminal or internal double bond by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation, into consideration.
  • Alk (en) ylsulfates are the alkali metal and in particular the sodium salts of
  • Sulfuric acid semi-esters of Ci 2 -C 8 fatty alcohols for example from coconut fatty alcohol,
  • Ci 2 -Ci 6 alkyl sulfates and Ci 2 -Ci 5 alkyl sulfates and Ci 4 -Ci 5 alkyl sulfates are preferred.
  • 2,3-alkyl sulfates are also suitable anionic surfactants.
  • sulfuric acid monoesters of straight-chain or branched C 7 ethoxylated with 1 to 6 moles of ethylene oxide are suitable.
  • 2 i-alcohols such as 2-methyl-branched Cg-n-alcohols having on average 3.5 mol of ethylene oxide (EO) or C 12 -i 8 -fatty alcohols having 1 to 4 EO, are suitable.
  • anionic surfactants are soaps.
  • Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and, in particular, soap mixtures derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids.
  • the anionic surfactants including the soaps may be in the form of their sodium, potassium or magnesium or ammonium salts.
  • the anionic surfactants are in the form of their sodium salts.
  • Further preferred counterions for the anionic surfactants are also the protonated forms of choline, triethylamine or methylethylamine.
  • the content of anionic surfactants in a washing or cleaning agent may be from 1 to 40% by weight, preferably from 5 to 30% by weight and most preferably from 10 to 25% by weight, based in each case on the total washing or cleaning agent ,
  • the anionic polymer is used in a liquid detergent or cleaning composition which contains a stably dispersed, graying-inhibiting polysaccharide to increase the graying-inhibiting effect of the detergent or cleaning agent.
  • the liquid washing or cleaning agent preferably contains carboxymethyl cellulose (CMC), an ether sulfonic acid salt of starch
  • Cellulose ether sulfonic acid salt cellulose acid acid sulfuric acid ester salt, starch, methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose methyl hydroxyethyl cellulose, methyl carboxymethyl cellulose,
  • very particularly preferred is the graying-inhibiting polysaccharide
  • Carboxymethylcellulose especially sodium carboxymethylcellulose.
  • the amount of graying-inhibiting polysaccharide is 0.1 to 5 wt .-%, based on the total amount of the detergent or cleaning agent.
  • the amount of is preferably
  • Graying-inhibiting polysaccharide between 0.2 and 4 wt .-% and very particularly preferably between 0.5 and 3 wt .-%, each based on the total amount of the detergent or cleaning agent.
  • the anionic polymers are used in liquid detergents or cleaners containing water as the main solvent. In addition, the washing or
  • Non-aqueous solvents include mono- or polyhydric alcohols, alkanolamines or glycol ethers, provided that they are miscible with water in the specified concentration range.
  • the solvents are selected from ethanol, n-propanol, i-propanol, butanols, glycol, propanediol, butanediol, glycerol, diglycol, propyldiglycol, butyldiglycol, hexylene glycol,
  • Non-aqueous solvents may be used in the washing or cleaning agent in amounts between 0.5 and 15 wt .-%, but preferably below 12 wt .-% and.
  • the washing or cleaning agent may contain other ingredients that further improve the performance and / or aesthetic properties of the detergent or cleaning agent.
  • the washing or cleaning agent preferably additionally contains one or more substances from the group of builders, bleaching agents, bleach catalysts, bleach activators, enzymes, electrolyte, nonaqueous solvents, pH adjusters, perfumes, perfume carriers, fluorescers,
  • Grayness inhibitors anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, preservatives,
  • Corrosion inhibitors antistatic agents, bittering agents, ironing aids, repellents and impregnating agents, swelling and anti-slip agents, plasticizing components and UV absorbers.
  • Table 1 below shows the compositions of two detergents E1 and E2 and of a comparative formulation V1 (all amounts are given in% by weight of active compound based on the composition).
  • Table 1 Compositions of washing or cleaning agents E1, E2 and V1
  • the two detergents E1 and E2 were stable for several weeks.
  • Total surfactant content ⁇ 33% by weight
  • another commercial liquid detergent V4 total surfactant content: ⁇ 15% by weight
  • the two liquid detergents V3 and V4 contained no graying-inhibiting polysaccharide and the sodium salt of
  • Citric acid as builder Citric acid as builder.
  • Test fabrics WFK 10 A or WFK 20 A
  • 4 SBL 2004 wipes each with standardizes
  • Has grayness inhibition such as a powder detergent.
  • washing or cleaning agent E1 even has a significantly stronger, graying-inhibiting effect than the powder detergent V2.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne l'utilisation d'un polymère anionique dans un agent liquide détergent ou de nettoyage, pour l'inhibition des gris par lavage et/ou nettoyage de surfaces textiles. L'invention concerne en outre un agent liquide détergent et de nettoyage renfermant un homopolymère d'acide acrylique.
EP10728245.1A 2009-07-17 2010-07-05 Composition détergente liquide comprenant un polymère pour l'inhibition des gris Revoked EP2454356B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL10728245T PL2454356T3 (pl) 2009-07-17 2010-07-05 Ciekły środek piorący lub czyszczący z polimerem inhibitującym szarzenie

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009027812A DE102009027812A1 (de) 2009-07-17 2009-07-17 Flüssiges Wasch- oder Reinigungsmittel mit vergrauungsinhibierendem Polymer
PCT/EP2010/059585 WO2011006792A1 (fr) 2009-07-17 2010-07-05 Agent liquide détergent ou de nettoyage renfermant un polymère pour l'inhibition des gris

Publications (2)

Publication Number Publication Date
EP2454356A1 true EP2454356A1 (fr) 2012-05-23
EP2454356B1 EP2454356B1 (fr) 2017-03-01

Family

ID=42668594

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10728245.1A Revoked EP2454356B1 (fr) 2009-07-17 2010-07-05 Composition détergente liquide comprenant un polymère pour l'inhibition des gris

Country Status (10)

Country Link
US (1) US8486883B2 (fr)
EP (1) EP2454356B1 (fr)
JP (1) JP2012533638A (fr)
KR (1) KR101777882B1 (fr)
DE (1) DE102009027812A1 (fr)
ES (1) ES2623155T3 (fr)
HU (1) HUE032295T2 (fr)
MX (1) MX2012000783A (fr)
PL (1) PL2454356T3 (fr)
WO (1) WO2011006792A1 (fr)

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DE102009027811A1 (de) * 2009-07-17 2011-01-20 Henkel Ag & Co. Kgaa Flüssiges Wasch-oder Reinigungsmittel mit vergrauungsinhibierendem Polysaccarid
BR112013029567B1 (pt) * 2011-05-20 2021-03-30 Dow Global Technologies Llc Mistura para promover desprendimento de sujeira de pano, método para promover desprendimento de sujeira de pano sujo e formulação de detergente para lavagem de roupa
DE102012202178A1 (de) * 2012-02-14 2013-08-14 Henkel Ag & Co. Kgaa Enzymhaltiges Reinigungsmittel mit mehrwertigen Alkoholen
DE102012213949A1 (de) * 2012-08-07 2014-02-13 Henkel Ag & Co. Kgaa Maschinelles Geschirrspülmittel enthaltend hydrophob modifizierte Polysaccharide
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EP3101107B1 (fr) * 2015-06-05 2019-04-24 The Procter and Gamble Company Composition de detergent liquide compacte pour blanchisserie
EP3101102B2 (fr) * 2015-06-05 2023-12-13 The Procter & Gamble Company Composition de detergent liquide compacte pour blanchisserie
DE102019007303A1 (de) * 2019-10-21 2021-04-22 Henkel Ag & Co. Kgaa Vergrauungsinhilbierende Waschmittel
DE102019007302A1 (de) * 2019-10-21 2021-04-22 Henkel Ag & Co. Kgaa Vergrauungsinhibierende Waschmittel

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Also Published As

Publication number Publication date
EP2454356B1 (fr) 2017-03-01
ES2623155T3 (es) 2017-07-10
JP2012533638A (ja) 2012-12-27
DE102009027812A1 (de) 2011-01-20
KR20120050430A (ko) 2012-05-18
WO2011006792A1 (fr) 2011-01-20
KR101777882B1 (ko) 2017-09-12
US20120151683A1 (en) 2012-06-21
PL2454356T3 (pl) 2017-08-31
HUE032295T2 (hu) 2017-09-28
MX2012000783A (es) 2012-02-28
US8486883B2 (en) 2013-07-16

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