EP2447395A3 - Electrode for producing chlorine through electrolysis - Google Patents
Electrode for producing chlorine through electrolysis Download PDFInfo
- Publication number
- EP2447395A3 EP2447395A3 EP11186428A EP11186428A EP2447395A3 EP 2447395 A3 EP2447395 A3 EP 2447395A3 EP 11186428 A EP11186428 A EP 11186428A EP 11186428 A EP11186428 A EP 11186428A EP 2447395 A3 EP2447395 A3 EP 2447395A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- electrode
- ruthenium
- electrolysis
- titanium
- electrically conductive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/26—Chlorine; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
- C25B11/093—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one noble metal or noble metal oxide and at least one non-noble metal oxide
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Catalysts (AREA)
- Chemically Coating (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Es wird eine Elektrode mindestens bestehend aus einem elektrisch leitenden Substrat und einer katalytisch aktiven Beschichtung beschrieben, bei der die katalytische aktive Schicht auf zwei katalytisch aktiven Komponenten basiert, die mindestens Iridium, Ruthenium oder Titan als Metalloxid oder Mischoxid oder Mischungen der genannten Oxide enthält, wobei der Gesamtgehalt an Ruthenium bezogen auf die Summe der Elemente Iridium, Ruthenium und Titan, 10 bis 28 Mol-% beträgt, und dass mindestens eine Basisschicht vorgesehen ist, die auf dem elektrisch leitenden Träger aufgebracht ist und die für wässrige Elektrolyte undurchlässig ist.It describes an electrode at least consisting of an electrically conductive substrate and a catalytically active coating, wherein the catalytic active layer is based on two catalytically active components containing at least iridium, ruthenium or titanium as a metal oxide or mixed oxide or mixtures of said oxides, wherein the total content of ruthenium based on the sum of the elements iridium, ruthenium and titanium is 10 to 28 mol%, and that at least one base layer is provided, which is applied to the electrically conductive support and which is impermeable to aqueous electrolytes.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102010043085A DE102010043085A1 (en) | 2010-10-28 | 2010-10-28 | Electrode for electrolytic chlorine production |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2447395A2 EP2447395A2 (en) | 2012-05-02 |
EP2447395A3 true EP2447395A3 (en) | 2013-01-30 |
Family
ID=45023580
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11186428A Withdrawn EP2447395A3 (en) | 2010-10-28 | 2011-10-25 | Electrode for producing chlorine through electrolysis |
Country Status (5)
Country | Link |
---|---|
US (1) | US20120103828A1 (en) |
EP (1) | EP2447395A3 (en) |
JP (1) | JP2012092449A (en) |
CN (1) | CN102465312A (en) |
DE (1) | DE102010043085A1 (en) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2823079B1 (en) | 2012-02-23 | 2023-02-22 | Treadstone Technologies, Inc. | Corrosion resistant and electrically conductive surface of metal |
RU2507640C1 (en) * | 2012-07-02 | 2014-02-20 | Федеральное государственное бюджетное учреждение науки Институт проблем химической физики РАН (ИПХФ РАН) | Catalytic electrode for alcohol fuel elements |
KR101406721B1 (en) * | 2013-04-03 | 2014-06-16 | 한국에너지기술연구원 | Manufacturing methods of materials powder for performance improved electrode and using the same electrode and its application. |
CN103774177B (en) * | 2014-01-26 | 2015-12-02 | 福州大学 | A kind ofly embed activated coating of ruthenium zirconium tin-oxide and preparation method thereof |
CN103774175B (en) * | 2014-01-26 | 2015-12-02 | 福州大学 | A kind ofly embed activated coating of ruthenium zirconium tin titanium oxide and preparation method thereof |
TWI731845B (en) * | 2014-11-24 | 2021-07-01 | 義商第諾拉工業公司 | Anode for electrolytic evolution of chlorine |
CN112575282B (en) | 2015-04-15 | 2023-12-19 | 踏石科技有限公司 | Method for treating metal component surface to achieve lower contact resistance |
JP2016204732A (en) * | 2015-04-28 | 2016-12-08 | 旭化成株式会社 | Electrode for electrolysis |
JP6775300B2 (en) * | 2016-02-10 | 2020-10-28 | 住友電気工業株式会社 | Electrodes for redox flow batteries and redox flow batteries |
KR102272749B1 (en) * | 2016-11-22 | 2021-07-06 | 아사히 가세이 가부시키가이샤 | Electrode for electrolysis |
CN107142491A (en) * | 2017-04-10 | 2017-09-08 | 广东卓信环境科技股份有限公司 | A kind of gas permeable electrode and preparation method thereof |
DE102017214810A1 (en) | 2017-08-24 | 2019-02-28 | Gabriele Keddo | Device and method for water disinfection and preparation of a disinfectant |
KR102393900B1 (en) * | 2017-09-29 | 2022-05-03 | 주식회사 엘지화학 | Coating composition for electrolysis cathode |
IT201800003533A1 (en) * | 2018-03-14 | 2019-09-14 | Industrie De Nora Spa | ELECTRODE FOR ELECTROCHLORATION PROCESSES |
IT201800006544A1 (en) * | 2018-06-21 | 2019-12-21 | ANODE FOR ELECTROLYTIC EVOLUTION OF CHLORINE | |
CN109518168B (en) * | 2018-12-14 | 2020-11-03 | 广西大学 | Preparation method of active titanium-based electrode plate with high-stability coating |
CN111517419A (en) * | 2020-03-20 | 2020-08-11 | 昆明学院 | Catalytic electrode with phosphorus selectivity and preparation method thereof |
CN111704211A (en) * | 2020-06-26 | 2020-09-25 | 陕西科技大学 | Preparation method of platinum ruthenium titanium yttrium DSA electrode |
CN111994967A (en) * | 2020-08-26 | 2020-11-27 | 海南尚合超电新能源科技有限公司 | Preparation method of titanium-doped high-nickel ternary lithium ion positive electrode material |
CN114472121B (en) * | 2021-12-21 | 2023-03-24 | 西安泰金新能科技股份有限公司 | Preparation method of high-activity coating titanium anode |
CN114457368B (en) * | 2022-03-08 | 2023-11-21 | 昆明冶金研究院有限公司 | Coated titanium anode for zinc electrodeposition and preparation method thereof |
CN114560536B (en) * | 2022-03-09 | 2023-07-28 | 四川塔菲尔环境科技有限公司 | Terbium-rhenium modified Ti/RuO 2 Dimensionally stable anode, preparation method and application |
CN118291953A (en) * | 2024-04-02 | 2024-07-05 | 绵阳宏博环保有限公司 | Vanadium and ruthenium modified titanium dioxide electrode and preparation and application methods thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2084189A (en) * | 1980-08-18 | 1982-04-07 | Diamond Shamrock Corp | Coated catalytic electrode for electrochemical processes |
US4331528A (en) * | 1980-10-06 | 1982-05-25 | Diamond Shamrock Corporation | Coated metal electrode with improved barrier layer |
CA1190184A (en) * | 1980-10-07 | 1985-07-09 | Henri B. Beer | Coated film-forming metal electrode with surface oxide barrier layer incorporating rhodium and/or iridium |
US6019878A (en) * | 1997-04-17 | 2000-02-01 | De Nora S.P.A. | Anode for oxygen evolution in electrolytes containing fluorides or fluoride-complex anions |
WO2010055065A1 (en) * | 2008-11-12 | 2010-05-20 | Industrie De Nora S.P.A. | Electrode for electrolysis cell |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1195871A (en) | 1967-02-10 | 1970-06-24 | Chemnor Ag | Improvements in or relating to the Manufacture of Electrodes. |
US3616445A (en) | 1967-12-14 | 1971-10-26 | Electronor Corp | Titanium or tantalum base electrodes with applied titanium or tantalum oxide face activated with noble metals or noble metal oxides |
US3562008A (en) | 1968-10-14 | 1971-02-09 | Ppg Industries Inc | Method for producing a ruthenium coated titanium electrode |
US3776834A (en) | 1972-05-30 | 1973-12-04 | Leary K O | Partial replacement of ruthenium with tin in electrode coatings |
US3882002A (en) | 1974-08-02 | 1975-05-06 | Hooker Chemicals Plastics Corp | Anode for electrolytic processes |
US3950240A (en) | 1975-05-05 | 1976-04-13 | Hooker Chemicals & Plastics Corporation | Anode for electrolytic processes |
US4039409A (en) | 1975-12-04 | 1977-08-02 | General Electric Company | Method for gas generation utilizing platinum metal electrocatalyst containing 5 to 60% ruthenium |
BR8006373A (en) * | 1979-10-08 | 1981-04-14 | Diamond Shamrock Corp | ELECTRODE FOR USE IN ELECTRIC PROCESSES, PROCESS FOR ITS MANUFACTURING, AND USE OF THE ELECTRODE |
CA1190186A (en) | 1980-08-18 | 1985-07-09 | Henri B. Beer | Electrode with mixed oxide interface on valve metal base and stable outer coating |
CA1190185A (en) * | 1980-08-18 | 1985-07-09 | Michael Katz | Electrode with outer coating and protective intermediate conductive polymer coating on a conductive base |
EP0097154A1 (en) | 1981-12-28 | 1984-01-04 | Diamond Shamrock Corporation | Electrocatalytic electrode |
JPS60159185A (en) | 1984-01-31 | 1985-08-20 | Permelec Electrode Ltd | Manufacture of electrode |
DE4032417A1 (en) | 1990-10-12 | 1992-04-16 | Univ Halle Wittenberg | Dimensionally stable anode esp. for chlor-alkali electrolysis - has ruthenium-titanium mixed oxide multilayer with concn. gradient |
JP3319887B2 (en) * | 1994-10-05 | 2002-09-03 | クロリンエンジニアズ株式会社 | Method for producing hypochlorite |
EP0867527B1 (en) | 1997-02-27 | 2001-03-21 | Aragonesas Industrias Y Energia, S.A. | Electrode with catalytic coating for electrochemical processes and manufacture thereof |
DE10200072A1 (en) | 2002-01-03 | 2003-07-31 | Bayer Ag | Electrodes for electrolysis in acid media |
DE10347703A1 (en) * | 2003-10-14 | 2005-05-12 | Bayer Materialscience Ag | Construction unit for bipolar electrolyzers |
MX2007002355A (en) | 2004-09-01 | 2007-05-11 | Eltech Systems Corp | Pd-containing coating for low chlorine overvoltage. |
CN1900368B (en) | 2006-06-30 | 2010-05-12 | 福州大学 | Titanium anode containing ruthenium coating of high cerium content and its preparing method |
ITMI20061974A1 (en) | 2006-10-16 | 2008-04-17 | Industrie De Nora Spa | ANODE FOR ELECTROLYSIS |
-
2010
- 2010-10-28 DE DE102010043085A patent/DE102010043085A1/en not_active Withdrawn
-
2011
- 2011-10-25 US US13/280,564 patent/US20120103828A1/en not_active Abandoned
- 2011-10-25 EP EP11186428A patent/EP2447395A3/en not_active Withdrawn
- 2011-10-27 JP JP2011235871A patent/JP2012092449A/en active Pending
- 2011-10-28 CN CN2011103337009A patent/CN102465312A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2084189A (en) * | 1980-08-18 | 1982-04-07 | Diamond Shamrock Corp | Coated catalytic electrode for electrochemical processes |
US4331528A (en) * | 1980-10-06 | 1982-05-25 | Diamond Shamrock Corporation | Coated metal electrode with improved barrier layer |
CA1190184A (en) * | 1980-10-07 | 1985-07-09 | Henri B. Beer | Coated film-forming metal electrode with surface oxide barrier layer incorporating rhodium and/or iridium |
US6019878A (en) * | 1997-04-17 | 2000-02-01 | De Nora S.P.A. | Anode for oxygen evolution in electrolytes containing fluorides or fluoride-complex anions |
WO2010055065A1 (en) * | 2008-11-12 | 2010-05-20 | Industrie De Nora S.P.A. | Electrode for electrolysis cell |
Also Published As
Publication number | Publication date |
---|---|
JP2012092449A (en) | 2012-05-17 |
US20120103828A1 (en) | 2012-05-03 |
CN102465312A (en) | 2012-05-23 |
DE102010043085A1 (en) | 2012-05-03 |
EP2447395A2 (en) | 2012-05-02 |
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RIC1 | Information provided on ipc code assigned before grant |
Ipc: C25B 1/26 20060101AFI20121221BHEP Ipc: C25B 11/04 20060101ALI20121221BHEP |
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RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: BAYER INTELLECTUAL PROPERTY GMBH |
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RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
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Effective date: 20130815 |