Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/38—Cationic compounds
  • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
  • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
  • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/02—Inorganic compounds ; Elemental compounds
  • C11D3/04—Water-soluble compounds
  • C11D3/10—Carbonates ; Bicarbonates
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/26—Organic compounds containing nitrogen
  • C11D3/32—Amides; Substituted amides

Definitions

• This invention relates to particulate detergent compositions comprising surfactant and hydroxamate, particularly to compositions comprising carbonate.
• WO2010069957 a clay particulate soil cleaning benefit is disclosed for the use of hydroxamates with specified ratios and types of surfactants.
• the invention may be used in either liquid or solid format cleaning systems.
• the compositions given are designed to be able to remove everyday dirt and stains that are commonly found in a wash load.
• One type of clay that is particularly resistant to removal by surfactants alone is red clay, such as red pottery clay or Red Georgia clay. This is a particulate soil stain.
• PCT/EP2010/055256 and PCT/EP2010/055257 we propose a particulate detergent based on coating an over sized core of sticky surfactant blend with a thick coat of sodium carbonate.
• the core may be formed by extrusion and cutting of a very dry surfactant blend.
• the extrudates are made with an abnormally large diameter in excess of 3 mm (typically about 5 mm) and the thickness of the cut portions is relatively thin, at less than 2 mm, to assist with dissolution of the core.
• the sodium carbonate coating is sprayed on at a level of about 30 wt%. This process arrives at a unique combination of surfactants and sodium carbonate. Hitherto the amount of sodium carbonate has either been much higher than the amount of surfactant or else additional, usually inorganic, builder material such as zeolite or silicate has been included into the composition.
• surfactant blend allows the particles to give good detergency even without any conventional detergent builder, thus eliminating the need for such builders in the core. Additional materials may be added to the core and / or the coating, as convenient for the processing or composition performance.
• a particulate detergent composition comprising at least 70% by number coated (core and shell) detergent particles comprising 40 to 90 wt% surfactant and 20 to 40 wt% sodium carbonate, the ratio of surfactant to sodium carbonate being at least 1.5:1, characterised in that the coated particles further comprise hydroxamate.
• the amount of hydroxamate preferably lies in the range 0.005 to 12 wt% of the particle.
• the particles comprise a core comprising surfactant material and a coating comprising sodium carbonate, most preferably the hydroxamate is located in the core. Having the hydroxamate in the core of the particle improves the appearance of the particle. Furthermore, since the hydroxamate is intended to work with the surfactant blend, as explained in WO2010069957 , it is desirable that it is released to the wash liquor at the same time as the slower dissolving surfactant in the core.
• the particles preferably comprise levels of sodium carbonate that are less than half the total active detergent.
• the majority of the sodium carbonate should be provided by the coating.
• hydroxamate with surfactant and these lower than normal levels of sodium carbonate give a surprising effect on clay soils especially under hard water conditions.
• the move to relatively unbuilt compositions is desirable from an environmental and sustainability viewpoint as it reduces the chemical loading per wash.
• Even the most calcium tolerant surfactant blends tend to suffer reduced wash performance on some stain and soil types when high water hardness levels are encountered. It is undesirable to simply increase the dose of the surfactant to restore the wash performance because this then increases the chemical loading disproportionately to the increased detergency.
• compositions of the invention are concentrated particulate compositions the amount of hydroxamate in the particle is large as a percentage of the composition.
• the core is made by extrusion of a dry surfactant blend.
• dry is meant less than 1 wt% water.
• Preferred cores comprise blends of anionic and nonionic surfactant, the anionic surfactant being present in an excess over the nonionic surfactant.
• Most preferred cores comprise calcium tolerant blends of surfactants as defined hereafter.
• the coated detergent particle has a core to shell ratio of from 3 to 1:1 by weight, preferably 2.5 to 1.5 to 1 and optimally about 2:1 when the shell comprise an inorganic salt (sodium carbonate).
• the preferred ratio of anionic to nonionic surfactant for particulate red clay soil removal is at least 1:1, more preferably at least 3:2. Preferably, it is at most 9:1. A most preferred range is 1:1 to 9:1, or 3:2 to 9:1.
• the preferred coated detergent particle has perpendicular dimensions x, y and z, wherein x is from 1 to 2 mm, y is from 3 to 8 mm, and z is from 3 to 8 mm, wherein the particle comprises:
• the sodium carbonate is present as a coating (shell) and the surfactant is present as a core. More preferably the hydroxamate is present in the core.
• the coating may comprise from 0 to 2 wt% of an organic polymer, more preferably from 0 to 0.4 wt% of the particle.
• Preferred polymers include sodium carboxymethyl cellulose.
• the preferred ratio of hydroxamate to detersive surfactant system (surfactant) for optimum particulate red clay soil removal lies in the range 1:4 to 1: 8000. More preferred is 1:7 to 1:40. An even more preferred range of ratios being 1:10 to 1:25 parts by weight.
• the hydroxamate may be incorporated into the surfactant core at various stages of the manufacturing process and may possibly be incorporated into the coating. Ingredients may alternatively be added as a further coating layer before or after the sodium carbonate coating is applied.
• wt % refer to the total percentage in the particle as dry weights.
• the particles are preferably substantially the same shape and size as one another.
• the variation in x, y or z should each be less than 20, preferably less than 10%.
• the amount of coating on each coated particle is advantageously from 10 to 40, more preferably 18 to 35 % by weight of the particle.
• the number percentage of the packaged composition of particles comprising the core and shell is preferably at least 85%.
• the coated particles preferably comprise from 0.001 to 3 wt % perfume.
• the core of the coated particles preferably comprises less than 5 wt%, even more preferably less than 2.5 wt% inorganic materials.
• the coating is preferably sodium carbonate in admixture with a minor amount of SCMC and further optionally in admixture with one or more of sodium silicate, water soluble fluorescer, water soluble or dispersible shading dye and pigment or coloured dye.
• the coating could alternatively be Burkeite, a double salt of sodium carbonate and sodium sulphate. It could even be citric acid, or even a polymer such as CP5. The important thing is that the amount of sodium carbonate in the wash solution must be less than the amount of the surfactant system.
• the particles are desirably oblate spheroids with diameter of 3 to 6 mm and thickness of 1 to 2 mm.
• the particles may be distributed and used in a package of any of the conventionally employed types.
• the package is preferably resealable.
• the package may be of any convenient size.
• the cores advantageously have a diameter of greater than 2 mm, preferably greater than 3 mm, most preferably greater than 4 mm and preferably have a diameter of less than 7 mm, most preferably less than 5 mm. They advantageously have a maximum thickness of greater than 0.2 mm and less than 3 mm, preferably less than 2 mm, most preferably less than about 1.5 mm and more than about 0.5 mm, even 0.7 mm.
• the preferred core is of circular cross section, they may alternatively have other cross sections such as triangular, rectangular and even complex cross sections, such as one mimicking a flower with rotationally symmetrical "petals". The key being that the average thickness of the core should be kept below the level where dissolution will be slow.
• the LAS containing surfactant blends can be extruded to make solid detergent particles that are hard enough to be used without any need to be structured by inorganic materials or other structurants as commonly found in prior art extruded detergent particles.
• the amount of surfactant in the detergent particle can be much higher and the amount of builder in the detergent particle can be much lower than is conventional.
• the co-surfactant is chosen from the group consisting of: SLES, and nonionic, together with optional soap and mixtures thereof.
• SLES SLES
• nonionic the upper limit for the amount of nonionic surfactant has been found to be 20 wt% of the total surfactant to avoid the dried material being too soft and cohesive to extrude because it has a hardness value less than 0.5 MPa.
• the cores may be coated by transferring them to a fluid bed and spraying onto them up to 40 wt% (based on coated detergent particle) of inorganic material in aqueous solution and drying off the water.
• composition may also comprise, for example, an antifoam granule.
• the coating is coloured. Particles of different colours may be used in admixture.
• the coating quality and appearance is very good due to the excellent surface of the cut extrudates onto which the coating is applied in association with the large particle size and S/V ratios of the preferred particles.
• the detergent particles comprise perfume.
• the perfume may be added into the extruder or premixed with the surfactant blend in the mill, or in a mixer placed after the mill, either as a liquid or as encapsulated perfume particles.
• the perfume may be mixed with a nonionic material and blended. Such a blend may alternatively be applied by coating the extruded particles, for example by spraying it mixed with molten nonionic surfactant.
• Perfume may also be introduced into the composition by means of a separate particles comprising perfume and then the detergent particle does not need to comprise any perfume.
• Surfactant blends that do not require builders to be present for effective detergency in hard water are preferred. Such blends are called calcium tolerant surfactant blends if they pass the test set out hereinafter. Thus, it is advantageous if the extruded core is made using a calcium tolerant surfactant blend according to the test herein described. However, the invention may also be of use for washing with soft water, either naturally occurring or made using a water softener. In this case, calcium tolerance is not so important and surfactant blends other than calcium tolerant ones may be used.
• LAS can be at least partially replaced by MES (methyl ester sulphonate), or, less preferably, partially replaced by up to 20 wt % PAS.
• MES methyl ester sulphonate
• the surfactants are mixed together before being input to the drier. Conventional mixing equipment is used. Hydroxamate is also mixed in at this point to ensure that it is well distributed. The hydroxamate is supplied in soapy form and addition to the core later in the process, for example in the extruder, can lead to poor distribution with lumps of hydroxamate material being embedded into the cores.
• scraped film devices may be used.
• a preferred form of scraped film device is a wiped film evaporator.
• One such suitable wiped film evaporator is the "Dryex system" based on a wiped film evaporator available from Ballestra S.p.A..
• Alternative drying equipment includes tube-type driers, such as a Chemithon Turbo Tube® drier, and soap driers.
• the hot material exiting the scraped film drier is subsequently cooled and broken up into suitable sized pieces to feed to the extruder. Simultaneous cooling and breaking into flakes may conveniently be carried out using a chill roll. If the flakes from the chill roll are not suitable for direct feed to the extruder then they can be milled in a milling apparatus and /or they can be blended with other liquid or solid ingredients in a blending and milling apparatus, such as a ribbon mill. Such milled or blended material is desirably of particle size 1 mm or less for feeding to the extruder.
• Particulate material with a mean particle size of 10 nm to 10 ⁇ m is preferred for use as a milling aid.
• materials there may be mentioned, by way of example: aerosil®, alusil®, and microsil®.
• the extruder provides further opportunities to blend in ingredients other than surfactants, or even to add further surfactants.
• all of the anionic surfactant, or other surfactant supplied in admixture with water; i.e. as paste or as solution, is added into the drier to ensure that the water content can then be reduced and the material fed to and through the extruder is sufficiently dry.
• Additional materials that can be blended into the extruder are thus mainly those that are used at low levels in a detergent composition: such as fluorescer, shading dye, enzymes, perfume, silicone antifoams, polymeric additives and preservatives.
• Solid additives are generally preferred. Liquids, such as perfume may be added at levels up to 2.5 wt%, preferably up to 1.5 wt%. Solid particulate structuring (liquid absorbing) materials or builders, such as zeolite, carbonate, silicate are preferably not added to the blend being extruded. These materials are not needed due to the self structuring properties of the very dry LAS-based feed material. If any is used the total amount should be less than 5 wt%, preferably less than 4 wt%, most preferably less than 3 wt%. At such levels no significant structuring occurs and the inorganic particulate material is added for a different purpose, for instance as a flow aid to improve the feed of particles to the extruder.
• the output from the extruder is shaped by the die plate used.
• the extruded material has a tendency to swell up in the centre relative to the periphery.
• Coating allows the particles to be coloured easily. It also further reduces the stickiness of the hygroscopic surfactant core to a point where the particles are free flowing. Coating makes them more suitable for use in detergent compositions that may be exposed to high humidity for long periods.
• the extruded particles can be considered as oblate spheroids with a major radius "a" and minor radius "b".
• the coating preferably comprises sodium carbonate, possibly in admixture with sodium sulphate, and even sodium chloride or sodium silicate.
• Food dyes, shading dyes, fluorescer and other optical modifiers can be added to the coating by dissolving them in the spray-on solution or dispersion.
• Use of a builder salt such as sodium carbonate is particularly advantageous because it allows the detergent particle to have an even better performance by buffering the system in use at an ideal pH for maximum detergency of the anionic surfactant system. It also increases ionic strength, which improves cleaning in hard water, and it is compatible with other detergent ingredients that may be admixed with the coated extruded detergent particles.
• the amount of coating should lie in the range 3 to 50 wt% of the particle, preferably 20 to 40 wt% for the best results in terms of anti-caking properties of the detergent particles.
• the particulate detergent composition is a mixture of:
• the coated particles dissolve easily in water and leave very low or no residues on dissolution, due to the absence of insoluble structurant materials such as zeolite.
• the hydroxamate does not generate any residues.
• the coated particles have an exceptional visual appearance, due to the smoothness of the coating coupled with the smoothness of the underlying cores, which is also believed to be a result of the lack of particulate structuring material in the extruded core particles.
• the coated detergent particle is preferably curved.
• the size is such that y and z are at least 3 mm, preferably 4 mm, most preferably 5 mm and x lies in the range 1 to 2 mm.
• the coated laundry detergent particle may be shaped as a disc.
• the core is primarily surfactant. It may also include detergency additives, such as perfume, shading dye, enzymes, cleaning polymers and soil release polymers.
• the coated laundry detergent particle comprises between 40 to 90 wt% of a surfactant, most preferably 55 to 75 wt %.
• a surfactant most preferably 55 to 75 wt %.
• the nonionic and anionic surfactants of the surfactant system may be chosen from the surfactants described " Surface Active Agents" Vol. 1, by Schwartz & Perry, Interscience 1949 , Vol. 2 by Schwartz, Perry & Berch, Interscience 1958 , in the current edition of " McCutcheon's Emulsifiers and Detergents” published by Manufacturing Confectioners Company or in " Tenside Taschenbuch", H. Stache, 2nd Edn., Carl Hauser Verlag, 1981 .
• the surfactants used are saturated.
• Suitable anionic detergent compounds that may be used are usually water-soluble alkali metal salts of organic sulphates and sulphonates having alkyl radicals containing from about 8 to about 22 carbon atoms, the term alkyl being used to include the alkyl portion of higher acyl radicals.
• suitable synthetic anionic detergent compounds are sodium and potassium alkyl sulphates, especially those obtained by sulphating higher C8 to C18 alcohols, produced for example from tallow or coconut oil, sodium and potassium alkyl C9 to C20 benzene sulphonates, particularly sodium linear secondary alkyl C10 to C15 benzene sulphonates; and sodium alkyl glyceryl ether sulphates, especially those ethers of the higher alcohols derived from tallow or coconut oil and synthetic alcohols derived from petroleum.
• anionic surfactants are sodium lauryl ether sulphate (SLES), particularly preferred with 1 to 3 ethoxy groups, sodium C10 to C15 alkyl benzene sulphonates and sodium C12 to C18 alkyl sulphates. Also applicable are surfactants such as those described in EP-A-328 177 (Unilever), which show resistance to salting out, the alkyl polyglycoside surfactants described in EP-A-070 074, and alkyl monoglycosides. The chains of the surfactants may be branched or linear.
• the fatty acid soap used preferably contains from about 16 to about 22 carbon atoms, preferably in a straight chain configuration.
• the anionic contribution from soap may be from 0 to 30 wt% of the total anionic. Use of more than 10 wt% soap is not preferred.
• At least 50 wt % of the anionic surfactant is selected from: sodium C11 to C15 alkyl benzene sulphonates; and, sodium C12 to C18 alkyl sulphates.
• Ethoxylated alkyl sulphates (SLES) may also be used as may methyl ester sulphonates (MES). All of these secondary surfactants should be used in minor amounts compared to LAS.
• the anionic surfactant is present in the coated laundry detergent particle at levels between 25 to 85 wt%, more preferably 40 to 70wt%.
• Suitable non-ionic detergent compounds which may be used include, in particular, the reaction products of compounds having a hydrophobic group and a reactive hydrogen atom, for example, aliphatic alcohols, acids, amides or alkyl phenols with alkylene oxides, especially ethylene oxide either alone or with propylene oxide.
• Preferred nonionic detergent compounds are C6 to C22 alkyl phenol-ethylene oxide condensates, generally 5 to 25 EO, i.e. 5 to 25 units of ethylene oxide per molecule, and the condensation products of aliphatic C8 to C18 primary or secondary linear or branched alcohols with ethylene oxide, generally 5 to 50 EO.
• the non-ionic is 10 to 50 EO, more preferably 20 to 35 EO. Alkyl ethoxylates are particularly preferred.
• the non-ionic surfactant is present in the coated laundry detergent particle at levels between 5 to 25 wt%, more preferably 7 to 19 wt%.
• Cationic surfactant may be present as minor ingredients at levels preferably between 0 to 5 wt%.
• surfactants are mixed together before being dried. Conventional mixing equipment may be used.
• the surfactant core of the laundry detergent particle may be formed by roller compaction and subsequently coated e.g. with an inorganic salt.
• the core is calcium tolerant and this is a preferred aspect because this reduces the need for a builder.
• Surfactant blends that do not require builders to be present for effective detergency in hard water are preferred. Such blends are called calcium tolerant surfactant blends if they pass the test set out hereinafter. However, the invention may also be of use for washing with soft water, either naturally occurring or made using a water softener. In this case, calcium tolerance is no longer important and blends other than calcium tolerant ones may be used.
• Suitable calcium tolerant co-surfactants include SLES 1-7EO, and alkyl ethoxylate non-ionic surfactants, particularly those with melting points less than 40°C.
• a LAS/SLES surfactant blend has a superior foam profile to a LAS Nonionic surfactant blend and is therefore preferred for hand washing formulations requiring high levels of foam. SLES may be used at levels of up to 30%.
• a LAS/NI surfactant blend provides a harder particle and its lower foam profile makes it more suited for automatic washing machine use.
• the main component of the coating is preferably a sodium carbonate salt.
• Other water compatible ingredients may be included in the coating. For example fluorescer, SCMC, shading dye, silicate, pigments and dyes.
• the coating is preferably 40 to 100 wt % sodium carbonate. So, for example if it is 90% Burkeite then that is considered for the purposes of this patent application to be 45% sodium carbonate.
• the coating is preferably present at a level that reduces the stickiness of the detergent particle to a point where the particles are free flowing.
• the amount of coating should lay in the range 5 to 40 wt % of the particle, preferably 20 to 40 wt %, even more preferably 25 to 35 wt % for the best results in terms of anti-caking properties of the detergent particles.
• the coating is applied to the surface of the surfactant core, by crystallisation from an aqueous solution or slurry e.g. of sodium carbonate.
• the spray preferably contains greater than 50g/L, more preferably 200 g/L of the salt.
• An aqueous spray-on of the coating solution in a fluidised bed has been found to give good results and may also generate a slight rounding of the detergent particles during the fluidisation process. Drying and/or cooling may be needed to finish the process.
• the thickness of coating obtainable by use of a given coating level is much greater than would be achieved on typically sized detergent granules (0.5 to 2 mm diameter spheres).
• this surface area to volume ratio must be greater than 3 mm -1 .
• the coating thickness is inversely proportional to this coefficient and hence for the coating the ratio "Surface area of coated particle" divided by "Volume of coated particle” should be less than 15 mm -1 .
• a preferred calcium tolerant coated laundry detergent particle has a surfactant system which comprises 50 to 95 wt% anionic surfactant, preferably sodium linear alkylbenzene sulphonate.
• Dye may advantageously be added to the coating, it may also be added to the surfactant mix in the core. In that case preferably the dye is dissolved in the surfactant before the core is formed.
• the dye is added to the coating slurry and agitated before applying to the core of the particle.
• Application may be by any suitable method, preferably spraying on to the core particle as detailed above.
• the dye may be any colour, preferable the dye is blue, violet, green or red. Most preferably the dye is blue or violet.
• the dye is preferably a shading dye for imparting a perception of whiteness to a laundry textile.
• the dye may be covalently bound to polymeric species.
• a combination of dyes may be used.
• the coated detergent particle is the coated detergent particle
• the coated detergent particle comprises from 70 to 100 wt %, preferably 85 to 90 wt %, of a detergent composition.
• the coated detergent particles are substantially the same shape and size by this is meant that at least 90 to 100 % of the coated laundry detergent particles in the in the x, y and z dimensions are within a 20 %, preferably 10%, variable from the largest to the smallest coated laundry detergent particle in the corresponding dimension.
• the particle preferably comprises from 0 to 15 wt % water, more preferably 0 to 10 wt %, most preferably from 1 to 5 wt % water, at 293K and 50% relative humidity. This facilitates the storage stability of the particle and its mechanical properties.
• ingredients described below may be present in the coating or the core.
• the coated laundry detergent particle preferably comprises a fluorescent agent (optical brightener).
• fluorescent agents are well known and many such fluorescent agents are available commercially. Usually, these fluorescent agents are supplied and used in the form of their alkali metal salts, for example, the sodium salts.
• the total amount of the fluorescent agent or agents used in the composition is generally from 0.005 to 2 wt %, more preferably 0.01 to 1.0 wt %.
• Preferred fluorescers are selected from the classes distyrylbiphenyls, triazinylaminostilbenes, bis(1,2,3-triazol-2-yl)stilbenes, bis(benzo[b]furan-2-yl)biphenyls, 1,3-diphenyl-2-pyrazolines and courmarins.
• the fluorescer is preferably sulphonated.
• Preferred classes of fluorescer are: Di-styryl biphenyl compounds, e.g. Tinopal (Trade Mark) CBS-X, Di-amine stilbene di-sulphonic acid compounds, e.g. Tinopal DMS pure Xtra and Blankophor (Trade Mark) HRH, and Pyrazoline compounds, e.g. Blankophor SN.
• Di-styryl biphenyl compounds e.g. Tinopal (Trade Mark) CBS-X
• Di-amine stilbene di-sulphonic acid compounds e.g. Tinopal DMS pure Xtra and Blankophor (Trade Mark) HRH
• Pyrazoline compounds e.g. Blankophor SN.
• Preferred fluorescers are: sodium 2 (4-styryl-3-sulfophenyl)-2H-napthol[1,2-d]triazole, disodium 4,4'-bis ⁇ [(4-anilino-6-(N methyl-N-2 hydroxyethyl) amino 1,3,5-triazin-2-yl)]amino ⁇ stilbene-2-2' disulfonate, disodium 4,4'-bis ⁇ [(4-anilino-6-morpholino-1,3,5-triazin-2-yl)]aminol stilbene-2-2' disulfonate, and disodium 4,4'-bis(2-sulfostyryl)biphenyl.
• Tinopal® DMS is the disodium salt of disodium 4,4'-bis ⁇ [(4-anilino-6-morpholino-1,3,5-triazin-2-yl)]amino) stilbene-2-2' disulfonate.
• Tinopal® CBS is the disodium salt of disodium 4,4'-bis(2-sulfostyryl)biphenyl.
• the composition comprises a perfume.
• the perfume is preferably in the range from 0.001 to 3 wt %, most preferably 0.1 to 1 wt %.
• CTFA Cosmetic, Toiletry and Fragrance Association
• OPD Chemicals Buyers Directory 80th Annual Edition, published by Schnell Publishing Co.
• compositions of the present invention it is envisaged that there will be four or more, preferably five or more, more preferably six or more or even seven or more different perfume components.
• top notes are defined by Poucher (Journal of the Society of Cosmetic Chemists 6(2):80 [1955 ]).
• Preferred top-notes are selected from citrus oils, linalool, linalyl acetate, lavender, dihydromyrcenol, rose oxide and cis-3-hexanol.
• the coated laundry detergent particles do not contain a peroxygen bleach, e.g., sodium percarbonate, sodium perborate, and peracid.
• a peroxygen bleach e.g., sodium percarbonate, sodium perborate, and peracid.
• the composition may comprise one or more polymers.
• polymers are carboxymethylcellulose, poly (ethylene glycol), poly(vinyl alcohol), polyethylene imines, ethoxylated polyethylene imines, water soluble polyester polymers polycarboxylates such as polyacrylates, maleic/acrylic acid copolymers and lauryl methacrylate/acrylic acid copolymers.
• compositions comprise at least 0.5 wt% of soil release polymer. This improves the multiwash performance of the detergent system for the removal of the clay. Inclusion of at least 0.5 wt% anti redeposition polymer is also beneficial due to the very high efficiency of primary detergency soil removal meaning that there is an increased level of soil in the wash liquor, which must then be prevented from redeposition onto the same or a different piece of fabric.
• One or more enzymes are preferably present in the composition.
• the level of each enzyme is from 0.0001 wt% to 0.5 wt% protein.
• enzymes include proteases, alpha-amylases, cellulases, lipases, peroxidases/oxidases, pectate lyases, and mannanases, or mixtures thereof.
• Any enzyme present in the composition may be stabilized using conventional stabilizing agents, e.g., a polyol such as propylene glycol or glycerol, a sugar or sugar alcohol, lactic acid, boric acid, or a boric acid derivative, e.g., an aromatic borate ester, or a phenyl boronic acid derivative such as 4-formylphenyl boronic acid, and the composition may be formulated as described in e.g. WO 92/19709 and WO 92/19708 .
• a polyol such as propylene glycol or glycerol
• a sugar or sugar alcohol lactic acid, boric acid, or a boric acid derivative, e.g., an aromatic borate ester, or a phenyl boronic acid derivative such as 4-formylphenyl boronic acid
• Sequestrants may be present in the detergent particles. However, because the hydroxamate technology is affected by competing sequestrants, for maximum performance of the hydroxamate any phosphonate or similar sequestrants that may complex with iron are preferably absent or used at a low level of up to 1 wt%, preferably less that 0.5 wt%.
• Hydroxamic acids are a class of chemical compounds in which a hydroxylamine is inserted into a carboxylic acid.
• the general structure of a hydroxamic acid is the following: in which R1 is an organic residue, for example alkyl or alkylene groups.
• the hydroxamic acid may be present as its corresponding alkali metal salt, or hydroxamate.
• the hydroxamates may conveniently be formed from the corresponding hydroxamic acid by substitution of the acid hydrogen atom by a cation:
• L+ is a monovalent cation such as for example the alkali metals (e.g. potassium, sodium), or ammonium or a substituted ammonium.
• the hydroxamic acid or its corresponding hydroxamate has the structure: wherein R1 is a straight or branched C4-C20 alkyl, or a straight or branched substituted C4-C20 alkyl, or a straight or branched C4-C20 alkenyl, or a straight or branched substituted C4-C20 alkenyl, or an alkyl ether group CH3 (CH2)n (EO)m wherein n is from 2 to 20 and m is from 1 to 12, or a substituted alkyl ether group CH3 (CH2)n (EO)m wherein n is from 2 to 20 and m is from 1 to 12, and the types of substitution include one or more of -NH2, -OH, -S-, -O-, -COOH, and and R2 is selected from hydrogen and a moiety that forms part of a cyclic structure with a branched R1 group
• references to a number of carbon atoms include mixed chain length materials provided that some of the hydroxamate material falls within the ranges specified and the ratios and amounts are determined by excluding any material falling outside of the specified range.
• the preferred hydroxamates are those where R2 is Hydrogen and R1 is C8 to C18 alkyl, preferably normal alkyl, preferably >80% saturated, more preferably > 90% saturated.
• hydroxamate containing particulate compositions according to the invention are particularly suitable for use on particulate stains such as soils and clays, especially red clay, and also surprisingly grass.
• R1 is an alkyl ether group CH3 (CH2)n (EO)m wherein n is from 2 to 20 and m is from 1 to 12 then the alkyl moiety terminates this side group.
• R1 is chosen from the group consisting of C4, C5, C6, C7, C8, C9, C10, C11, or C12 or C14 normal alkyl group, most preferably R1 is at least a C8-14 normal alkyl group. When the C8 material is used this is called octyl hydroxamic acid.
• the potassium salt is particularly useful.
• hydroxamic acids whilst less preferred, are suitable for use in the present invention.
• suitable compounds include, but are not limited to, the following compounds:
• Such hydroxamic acids are commercially available.
• the hydroxamate is thought to act by binding to metal ions that are present in the soil on the fabric. This binding action, which is, in effect, the known sequestrant property of the hydroxamate is not, in itself, of any use to remove the soil from the fabric.
• the key is the "tail" of the hydroxamate i.e. the group R1 minus any branching that folds back onto the amate Nitrogen via group R2. The tail is selected to have an affinity for the surfactant system.
• the soil removal ability of an already optimised surfactant system is further enhanced by the use of the hydroxamate as it, in effect, labels the difficult to remove particulate material (clay) as "soil” for removal by the surfactant system acting on the hydroxamate molecules now fixed to the particulates via their binding to the metal ions embedded in the clay type particulates.
• the detersive surfactants will adhere to the hydroxamate, leading overall to more surfactants interacting with the fabric, leading to better soil release.
• the hydroxamic acids act as a linker molecule facilitating the removal and suspension of the particulate soil from the fabric into a wash liquor and thus boosting the primary detergency.
• the hydroxamates have a higher affinity for transition metals, like iron, than for alkaline earth metals like calcium and magnesium, therefore the hydroxamic acid primarily acts to improve the removal of soil on fabric, especially particulate soils, and not additionally as a builder for calcium and magnesium.
• a preferred hydroxamate is the coco hydroxamic acid available under the trade name RK853 from Axis House.
• Another preferred material is RK842 (an Alkyl hydroxamic acid made from Palm Kernel Oil) from Axis House.
• coated large detergent particles are manufactured, following the process in PCT/EP2010/055256 .
• the dried blends dropped onto a chill roll, where they were cooled to less than 30°C.
• the cooled dried blend particles were milled using a hammer mill, 2% Alusil® was also added to the hammer mill as a mill aid.
• the resulting milled materials are hygroscopic and were stored in sealed containers.
• the average particle diameter and thickness of samples of the extruded core particles were found to be 4.46 mm and 1.13 mm respectively.
• the standard deviation was acceptably low (less than 10%).
• Coated particles compositions are given in Table 4.
• Table 4 Example 1
• Comparative example B is made up of 92.9 wt% of particles of Comparative Example A and 7.1 wt% of antifoam.
• Table 5 - Composition B -Comparative (dry weights) % in Primary lenticular particle % in Composition LAS Core 59.02 54.83
• Nonionic Core 10.41 9.68 SCMC Core 0.95 0.88 Perfume oil Core 0.76 0.71 Alusil® (flow aid) Core - - Sodium carbonate Coating 28.53 26.5 Fluorescer Coating 0.29 0.27 Dye Coating 0.04 100 92.90 Antifoam secondary particle 7.1 100
• Example 2 is made up of 93.17 wt % of particles of Example 1 and 6.13 wt% antifoam.
• SRI is a measure of how much of a stain on textile is removed during a washing process.
• a SRI aw of 100 means complete removal of a stain.
• ⁇ E* aw is the difference in L a b colour space between the clean (unwashed) fabric and the stain after wash. So a ⁇ E* aw of zero means a stain that is completely removed. Therefore, a SRI aw of 100 is a completely removed stain.
• the clean (or virgin) fabric is an "absolute standard" which is not washed. For each experiment, it refers to an identical piece of fabric to that which the stain is applied. Therefore, its point in L a b colour space stays constant.
• Table 7 Example SRI aw Indian Red Mud from Knitted Polyester SRI aw Indian Red Mud from Knitted Cotton B (comparative) 77.9 59.1 2 (with coco hydroxamic acid) 81.8 60.1
• Comparative compositions C and D were used in the following cleaning experiment. Tergo Wash study at 26°FH Comparative compositions B and C dosed at 1.5g/L Run time 12 mins @ 100rpm Table 9 Composition SRI aw Indian Red Mud from Knitted Polyester C (comparative) 76.6 D (comparative with octyl hydroxamate) 71.7
• Example 1 On the other hand from Example 1, it can be seen that by moving to the higher ratios of active detergent to carbonate the hydroxamate has a significant effect, even if the surfactant level is reduced by the inclusion of the hydroxamate.

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• 2010
  • 2010-10-14 EP EP10187505A patent/EP2441823A1/de not_active Withdrawn

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