EP2409849A1 - Combinaison d'une substance luminescente et d'un hologramme - Google Patents
Combinaison d'une substance luminescente et d'un hologramme Download PDFInfo
- Publication number
- EP2409849A1 EP2409849A1 EP10170447A EP10170447A EP2409849A1 EP 2409849 A1 EP2409849 A1 EP 2409849A1 EP 10170447 A EP10170447 A EP 10170447A EP 10170447 A EP10170447 A EP 10170447A EP 2409849 A1 EP2409849 A1 EP 2409849A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- luminescent substance
- radiation
- volume hologram
- oxide
- radiation source
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000463 material Substances 0.000 title description 6
- 239000000126 substance Substances 0.000 claims abstract description 86
- 230000005855 radiation Effects 0.000 claims abstract description 53
- 239000000203 mixture Substances 0.000 claims abstract description 39
- 238000001514 detection method Methods 0.000 claims abstract description 17
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims abstract description 12
- 238000004020 luminiscence type Methods 0.000 claims abstract description 12
- 230000003287 optical effect Effects 0.000 claims abstract description 12
- 229910021644 lanthanide ion Inorganic materials 0.000 claims abstract description 11
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 6
- 230000001678 irradiating effect Effects 0.000 claims abstract description 4
- 230000003213 activating effect Effects 0.000 claims abstract description 3
- 239000003550 marker Substances 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims description 14
- 150000002222 fluorine compounds Chemical class 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 12
- 239000002019 doping agent Substances 0.000 claims description 11
- 150000004645 aluminates Chemical class 0.000 claims description 7
- 229910001428 transition metal ion Inorganic materials 0.000 claims description 5
- 229910052727 yttrium Inorganic materials 0.000 claims description 5
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 5
- 229910052691 Erbium Inorganic materials 0.000 claims description 4
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 4
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 4
- 239000003999 initiator Substances 0.000 claims description 4
- 238000005259 measurement Methods 0.000 claims description 4
- 150000003624 transition metals Chemical class 0.000 claims description 4
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 3
- 229910052693 Europium Inorganic materials 0.000 claims description 3
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 3
- 229910052689 Holmium Inorganic materials 0.000 claims description 3
- 229910052765 Lutetium Inorganic materials 0.000 claims description 3
- 229910052775 Thulium Inorganic materials 0.000 claims description 3
- 238000010538 cationic polymerization reaction Methods 0.000 claims description 3
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims description 3
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 3
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims description 3
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims description 3
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims description 3
- 238000012795 verification Methods 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- 229910052779 Neodymium Inorganic materials 0.000 claims description 2
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 2
- 229910052772 Samarium Inorganic materials 0.000 claims description 2
- 229910052771 Terbium Inorganic materials 0.000 claims description 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 2
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 2
- 239000007870 radical polymerization initiator Substances 0.000 claims description 2
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims description 2
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims description 2
- -1 dibromodecylthio Chemical group 0.000 description 19
- 150000003568 thioethers Chemical class 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 6
- 239000000178 monomer Substances 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 230000005284 excitation Effects 0.000 description 4
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 4
- 229960003237 betaine Drugs 0.000 description 3
- 238000000295 emission spectrum Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 210000001124 body fluid Anatomy 0.000 description 2
- 239000010839 body fluid Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000001427 coherent effect Effects 0.000 description 2
- 125000005520 diaryliodonium group Chemical class 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- OZLBDYMWFAHSOQ-UHFFFAOYSA-N diphenyliodanium Chemical class C=1C=CC=CC=1[I+]C1=CC=CC=C1 OZLBDYMWFAHSOQ-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000013307 optical fiber Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- GIGGEWZKBRIZLD-UHFFFAOYSA-N (1,3-dibromo-2,2-dimethyl-3-prop-2-enoyloxypropyl) prop-2-enoate Chemical compound C(C=C)(=O)OC(C(C)(C(OC(C=C)=O)Br)C)Br GIGGEWZKBRIZLD-UHFFFAOYSA-N 0.000 description 1
- HYQXPEYCYNAMNO-UHFFFAOYSA-N (2,3-dibromophenyl) prop-2-enoate Chemical compound BrC1=CC=CC(OC(=O)C=C)=C1Br HYQXPEYCYNAMNO-UHFFFAOYSA-N 0.000 description 1
- CNLVUQQHXLTOTC-UHFFFAOYSA-N (2,4,6-tribromophenyl) prop-2-enoate Chemical compound BrC1=CC(Br)=C(OC(=O)C=C)C(Br)=C1 CNLVUQQHXLTOTC-UHFFFAOYSA-N 0.000 description 1
- HHQAGBQXOWLTLL-UHFFFAOYSA-N (2-hydroxy-3-phenoxypropyl) prop-2-enoate Chemical compound C=CC(=O)OCC(O)COC1=CC=CC=C1 HHQAGBQXOWLTLL-UHFFFAOYSA-N 0.000 description 1
- JZDQKBZKFIWSNW-UHFFFAOYSA-N (4-methoxyphenyl)-phenyliodanium Chemical compound C1=CC(OC)=CC=C1[I+]C1=CC=CC=C1 JZDQKBZKFIWSNW-UHFFFAOYSA-N 0.000 description 1
- VQVGJEIVVJBMCV-UHFFFAOYSA-N (4-octoxyphenyl)-phenyliodanium Chemical compound C1=CC(OCCCCCCCC)=CC=C1[I+]C1=CC=CC=C1 VQVGJEIVVJBMCV-UHFFFAOYSA-N 0.000 description 1
- CYIGRWUIQAVBFG-UHFFFAOYSA-N 1,2-bis(2-ethenoxyethoxy)ethane Chemical compound C=COCCOCCOCCOC=C CYIGRWUIQAVBFG-UHFFFAOYSA-N 0.000 description 1
- LFKLPJRVSHJZPL-UHFFFAOYSA-N 1,2:7,8-diepoxyoctane Chemical compound C1OC1CCCCC1CO1 LFKLPJRVSHJZPL-UHFFFAOYSA-N 0.000 description 1
- SSZOCHFYWWVSAI-UHFFFAOYSA-N 1-bromo-2-ethenylbenzene Chemical compound BrC1=CC=CC=C1C=C SSZOCHFYWWVSAI-UHFFFAOYSA-N 0.000 description 1
- DNJRKFKAFWSXSE-UHFFFAOYSA-N 1-chloro-2-ethenoxyethane Chemical compound ClCCOC=C DNJRKFKAFWSXSE-UHFFFAOYSA-N 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- XZJPYETUABEQFI-UHFFFAOYSA-N 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluorooctane-1,8-diol Chemical compound OCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CO XZJPYETUABEQFI-UHFFFAOYSA-N 0.000 description 1
- OYKPJMYWPYIXGG-UHFFFAOYSA-N 2,2-dimethylbutane;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(C)(C)C OYKPJMYWPYIXGG-UHFFFAOYSA-N 0.000 description 1
- WVXLLHWEQSZBLW-UHFFFAOYSA-N 2-(4-acetyl-2-methoxyphenoxy)acetic acid Chemical compound COC1=CC(C(C)=O)=CC=C1OCC(O)=O WVXLLHWEQSZBLW-UHFFFAOYSA-N 0.000 description 1
- GHTVHGGJFHMYBA-UHFFFAOYSA-N 2-(7-oxabicyclo[4.1.0]heptane-4-carbonyloxy)ethyl 7-oxabicyclo[4.1.0]heptane-4-carboxylate Chemical compound C1CC2OC2CC1C(=O)OCCOC(=O)C1CC2OC2CC1 GHTVHGGJFHMYBA-UHFFFAOYSA-N 0.000 description 1
- JJRUAPNVLBABCN-UHFFFAOYSA-N 2-(ethenoxymethyl)oxirane Chemical compound C=COCC1CO1 JJRUAPNVLBABCN-UHFFFAOYSA-N 0.000 description 1
- OOGPFCFGQOSOOZ-UHFFFAOYSA-N 2-[2,6-dibromo-4-[2-[3,5-dibromo-4-(2-prop-2-enoyloxyethoxy)phenyl]propan-2-yl]phenoxy]ethyl prop-2-enoate Chemical compound C=1C(Br)=C(OCCOC(=O)C=C)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(OCCOC(=O)C=C)C(Br)=C1 OOGPFCFGQOSOOZ-UHFFFAOYSA-N 0.000 description 1
- ZTUUJKGWAPOKIV-UHFFFAOYSA-N 2-[2,6-dibromo-4-[3,5-dibromo-4-(2-prop-2-enoyloxyethoxy)phenyl]sulfonylphenoxy]ethyl prop-2-enoate Chemical compound BrC1=C(OCCOC(=O)C=C)C(Br)=CC(S(=O)(=O)C=2C=C(Br)C(OCCOC(=O)C=C)=C(Br)C=2)=C1 ZTUUJKGWAPOKIV-UHFFFAOYSA-N 0.000 description 1
- UXPIIFXGFYDVSZ-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxycarbonyl]phenyl]benzoic acid Chemical compound CC(=C)C(=O)OCCOC(=O)C1=CC=CC=C1C1=CC=CC=C1C(O)=O UXPIIFXGFYDVSZ-UHFFFAOYSA-N 0.000 description 1
- AFIDVFAKOZHKML-UHFFFAOYSA-N 2-[4-[4-(2-prop-2-enoyloxyethoxy)phenyl]sulfonylphenoxy]ethyl prop-2-enoate Chemical compound C1=CC(OCCOC(=O)C=C)=CC=C1S(=O)(=O)C1=CC=C(OCCOC(=O)C=C)C=C1 AFIDVFAKOZHKML-UHFFFAOYSA-N 0.000 description 1
- WTYYGFLRBWMFRY-UHFFFAOYSA-N 2-[6-(oxiran-2-ylmethoxy)hexoxymethyl]oxirane Chemical compound C1OC1COCCCCCCOCC1CO1 WTYYGFLRBWMFRY-UHFFFAOYSA-N 0.000 description 1
- UUODQIKUTGWMPT-UHFFFAOYSA-N 2-fluoro-5-(trifluoromethyl)pyridine Chemical compound FC1=CC=C(C(F)(F)F)C=N1 UUODQIKUTGWMPT-UHFFFAOYSA-N 0.000 description 1
- RZVINYQDSSQUKO-UHFFFAOYSA-N 2-phenoxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC1=CC=CC=C1 RZVINYQDSSQUKO-UHFFFAOYSA-N 0.000 description 1
- KVPYIEPKUGXISR-UHFFFAOYSA-N 2-phenoxypropyl prop-2-enoate Chemical compound C=CC(=O)OCC(C)OC1=CC=CC=C1 KVPYIEPKUGXISR-UHFFFAOYSA-N 0.000 description 1
- ROPDSOYFYJCSTC-UHFFFAOYSA-N 2-phenoxyundecyl prop-2-enoate Chemical compound CCCCCCCCCC(COC(=O)C=C)OC1=CC=CC=C1 ROPDSOYFYJCSTC-UHFFFAOYSA-N 0.000 description 1
- NGIFKNRDRATMHS-UHFFFAOYSA-N 3-[4-[4-(3-prop-2-enoyloxypropoxy)phenyl]sulfonylphenoxy]propyl prop-2-enoate Chemical compound C1=CC(OCCCOC(=O)C=C)=CC=C1S(=O)(=O)C1=CC=C(OCCCOC(=O)C=C)C=C1 NGIFKNRDRATMHS-UHFFFAOYSA-N 0.000 description 1
- NGPVHDLDDPEXPJ-UHFFFAOYSA-M 3-ethyl-4,5-diphenyl-4,5-dihydro-1,3-thiazol-3-ium;iodide Chemical compound [I-].CC[N+]1=CSC(C=2C=CC=CC=2)C1C1=CC=CC=C1 NGPVHDLDDPEXPJ-UHFFFAOYSA-M 0.000 description 1
- YFLRTUOBKDGQDO-UHFFFAOYSA-N 4-[2-(7-oxabicyclo[4.1.0]heptan-4-ylmethoxy)ethoxymethyl]-7-oxabicyclo[4.1.0]heptane Chemical compound C1CC2OC2CC1COCCOCC1CC2OC2CC1 YFLRTUOBKDGQDO-UHFFFAOYSA-N 0.000 description 1
- OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 description 1
- YXALYBMHAYZKAP-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-ylmethyl 7-oxabicyclo[4.1.0]heptane-4-carboxylate Chemical compound C1CC2OC2CC1C(=O)OCC1CC2OC2CC1 YXALYBMHAYZKAP-UHFFFAOYSA-N 0.000 description 1
- GBJVVSCPOBPEIT-UHFFFAOYSA-N AZT-1152 Chemical compound N=1C=NC2=CC(OCCCN(CC)CCOP(O)(O)=O)=CC=C2C=1NC(=NN1)C=C1CC(=O)NC1=CC=CC(F)=C1 GBJVVSCPOBPEIT-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- XWUNIDGEMNBBAQ-UHFFFAOYSA-N Bisphenol A ethoxylate diacrylate Chemical compound C=1C=C(OCCOC(=O)C=C)C=CC=1C(C)(C)C1=CC=C(OCCOC(=O)C=C)C=C1 XWUNIDGEMNBBAQ-UHFFFAOYSA-N 0.000 description 1
- TZPDKWYWKMUKFZ-UHFFFAOYSA-N C1=CC=CC2=C(C(=O)OCCOC(=O)C=C)C(C(=O)O)=CC=C21 Chemical compound C1=CC=CC2=C(C(=O)OCCOC(=O)C=C)C(C(=O)O)=CC=C21 TZPDKWYWKMUKFZ-UHFFFAOYSA-N 0.000 description 1
- VZBILKJHDPEENF-UHFFFAOYSA-M C3-thiacarbocyanine Chemical compound [I-].S1C2=CC=CC=C2[N+](CC)=C1C=CC=C1N(CC)C2=CC=CC=C2S1 VZBILKJHDPEENF-UHFFFAOYSA-M 0.000 description 1
- HACYVFGBGPWCTG-UHFFFAOYSA-N CCCN1C=[S+]C2=C1[CH-]C(=C([CH-]2)C)C Chemical compound CCCN1C=[S+]C2=C1[CH-]C(=C([CH-]2)C)C HACYVFGBGPWCTG-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- DAEAVXOREOXTJD-UHFFFAOYSA-N [1-[3-[2-prop-2-enoyloxy-3-(2,4,6-tribromophenoxy)propoxy]phenoxy]-3-(2,4,6-tribromophenoxy)propan-2-yl] prop-2-enoate Chemical compound BrC1=CC(Br)=CC(Br)=C1OCC(OC(=O)C=C)COC1=CC=CC(OCC(COC=2C(=CC(Br)=CC=2Br)Br)OC(=O)C=C)=C1 DAEAVXOREOXTJD-UHFFFAOYSA-N 0.000 description 1
- YJAHPBBPYFDPLT-UHFFFAOYSA-N [3-ethoxy-4-[2-(2-ethoxy-4-prop-2-enoyloxyphenyl)propan-2-yl]phenyl] prop-2-enoate Chemical compound CCOC1=CC(OC(=O)C=C)=CC=C1C(C)(C)C1=CC=C(OC(=O)C=C)C=C1OCC YJAHPBBPYFDPLT-UHFFFAOYSA-N 0.000 description 1
- ZCZFEIZSYJAXKS-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] prop-2-enoate Chemical compound OCC(CO)(CO)COC(=O)C=C ZCZFEIZSYJAXKS-UHFFFAOYSA-N 0.000 description 1
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 1
- MXHLJMGGWQSJGS-UHFFFAOYSA-N [4-(2,3-diethoxy-4-prop-2-enoyloxyphenyl)sulfonyl-2,3-diethoxyphenyl] prop-2-enoate Chemical compound CCOC1=C(OC(=O)C=C)C=CC(S(=O)(=O)C=2C(=C(OCC)C(OC(=O)C=C)=CC=2)OCC)=C1OCC MXHLJMGGWQSJGS-UHFFFAOYSA-N 0.000 description 1
- YOAHNDFMRWNINV-UHFFFAOYSA-N [4-[(2,3-diethoxy-4-prop-2-enoyloxyphenyl)methyl]-2,3-diethoxyphenyl] prop-2-enoate Chemical compound C1=CC(OC(=O)C=C)=C(OCC)C(OCC)=C1CC1=CC=C(OC(=O)C=C)C(OCC)=C1OCC YOAHNDFMRWNINV-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001515 alkali metal fluoride Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910001618 alkaline earth metal fluoride Inorganic materials 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- DJUWPHRCMMMSCV-UHFFFAOYSA-N bis(7-oxabicyclo[4.1.0]heptan-4-ylmethyl) hexanedioate Chemical compound C1CC2OC2CC1COC(=O)CCCCC(=O)OCC1CC2OC2CC1 DJUWPHRCMMMSCV-UHFFFAOYSA-N 0.000 description 1
- KBWLNCUTNDKMPN-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) hexanedioate Chemical compound C1OC1COC(=O)CCCCC(=O)OCC1CO1 KBWLNCUTNDKMPN-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000000298 carbocyanine Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000004113 cell culture Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000002872 contrast media Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- BOTLEXFFFSMRLQ-UHFFFAOYSA-N cyclopentyloxycyclopentane Chemical compound C1CCCC1OC1CCCC1 BOTLEXFFFSMRLQ-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- 239000012955 diaryliodonium Chemical class 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 150000002012 dioxanes Chemical class 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- ZINJLDJMHCUBIP-UHFFFAOYSA-N ethametsulfuron-methyl Chemical compound CCOC1=NC(NC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(=O)OC)=N1 ZINJLDJMHCUBIP-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229940052303 ethers for general anesthesia Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- BNRNAKTVFSZAFA-UHFFFAOYSA-N hydrindane Chemical compound C1CCCC2CCCC21 BNRNAKTVFSZAFA-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002601 lanthanoid compounds Chemical class 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- KHARCSTZAGNHOT-UHFFFAOYSA-L naphthalene-2,3-dicarboxylate Chemical compound C1=CC=C2C=C(C([O-])=O)C(C(=O)[O-])=CC2=C1 KHARCSTZAGNHOT-UHFFFAOYSA-L 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 229940127557 pharmaceutical product Drugs 0.000 description 1
- WRAQQYDMVSCOTE-UHFFFAOYSA-N phenyl prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1 WRAQQYDMVSCOTE-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-M phthalate(1-) Chemical compound OC(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-M 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- GEKRJZFHLJNDQM-UHFFFAOYSA-N s-(naphthalen-1-ylmethyl) prop-2-enethioate Chemical compound C1=CC=C2C(CSC(=O)C=C)=CC=CC2=C1 GEKRJZFHLJNDQM-UHFFFAOYSA-N 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- WLOQLWBIJZDHET-UHFFFAOYSA-N triphenylsulfonium Chemical class C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 WLOQLWBIJZDHET-UHFFFAOYSA-N 0.000 description 1
- WUKMCKCDYKBLBG-UHFFFAOYSA-N tris(4-methoxyphenyl)sulfanium Chemical compound C1=CC(OC)=CC=C1[S+](C=1C=CC(OC)=CC=1)C1=CC=C(OC)C=C1 WUKMCKCDYKBLBG-UHFFFAOYSA-N 0.000 description 1
- QKFJVDSYTSWPII-UHFFFAOYSA-N tris(4-methylphenyl)sulfanium Chemical compound C1=CC(C)=CC=C1[S+](C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 QKFJVDSYTSWPII-UHFFFAOYSA-N 0.000 description 1
- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
- B41M3/144—Security printing using fluorescent, luminescent or iridescent effects
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/44—Latent security elements, i.e. detectable or becoming apparent only by use of special verification or tampering devices or methods
- D21H21/48—Elements suited for physical verification, e.g. by irradiation
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
- G07D7/003—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using security elements
- G07D7/0032—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using security elements using holograms
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
- G07D7/06—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using wave or particle radiation
- G07D7/12—Visible light, infrared or ultraviolet radiation
- G07D7/1205—Testing spectral properties
Definitions
- the invention relates to a composition for marking articles comprising a luminescent substance based on oxides, oxide sulfides and / or oxide fluorides of lanthanide ions and a holographic support for recording or reconstruction of a volume hologram.
- the luminescent substance has a characteristic emission spectrum and can be used in combination with the volume hologram for authentication and / or identification of products such as substances or mixtures of substances.
- a subject of the invention is a composition for marking articles, comprising (i) a luminescent substance comprising (a) an IR-stimulable component comprising at least one oxide, oxide sulfide or oxide fluoride of lanthanide ions, and (b) optionally one by UV Radiation excitable component and (ii) a holographic support for recording or reconstruction of a volume hologram.
- a luminescent substance comprising (a) an IR-stimulable component comprising at least one oxide, oxide sulfide or oxide fluoride of lanthanide ions, and (b) optionally one by UV Radiation excitable component and (ii) a holographic support for recording or reconstruction of a volume hologram.
- the possibilities for marking objects e.g. Construction or spare parts of electronic equipment, machinery, vehicles, aircraft, etc., packaging or containers, e.g. of pharmaceutical products, fashion items, documents, banknotes, etc. significantly improved.
- the possibility of information storage is also significantly increased.
- the composition according to the invention can be used to label Products in different ways.
- the luminescent substance can be introduced into the holographic carrier, it being possible for particles of the luminescent substance to be dispersed in the entire region of the carrier, in a part thereof or in individual layers thereof.
- the luminescent substance can also be arranged as a layer on one or both surfaces of the carrier.
- the luminescent substance is present separately from the carrier, so that luminescent substance and holographic carrier can be present in or on different regions of the product to be marked, wherein these two regions can be adjacent or separate from one another.
- Component (i) of the composition is a luminescent substance comprising (a) an IR-stimulable component comprising at least one oxide, oxide sulfide or oxide fluoride of lanthanide ions, and (b) optionally a UV-excitable component.
- Lanthanoid compounds for use as anti-Stokes luminescent substances are, for example, in WO 00/60527 .
- WO 2008/000461 as well as in the U.S. Patents 6,802,992 and 6 686 074 described, the contents of which are hereby incorporated by reference.
- These lanthanoid oxide sulfides can be used to label substances or mixtures of substances.
- Component (i) is an IR-radiation excitable component comprising an oxide, oxide sulfide or oxide fluoride of lanthanide ions.
- Component (b) is a UV-activatable component, which is conveniently an inorganic compound inert under ambient conditions, for example an optionally doped aluminate, which absorbs in the UV wavelength range and is characteristic of the compound Luminescence radiation, eg fluorescence radiation, emitted.
- Such compositions are the subject of the German patent application DE 10 2010 028 818.7 , the contents of which are expressly referred to.
- Component (a) is preferably a luminescent substance with "upconverter” and / or “anti-Stokes” properties.
- component (a) comprises an oxide, oxide or oxyfluoride of yttrium and an oxide, oxide or oxide fluoride of at least one, at least two or at least three further elements selected from lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, terbium , Dysprosium, holmium, erbium, thulium, ytterbium and lutetium, and optionally at least one dopant selected from oxides and / or fluorides of main or subgroup elements.
- component (a) is a luminescent substance as in WO 2008/000461 described.
- the oxide, oxide sulfide or oxide fluoride of yttrium is preferably present in a proportion of ⁇ 85 mol% ⁇ 90 mol%, ⁇ 92 mol%, ⁇ 94 mol% or ⁇ 96 mol% , Further oxides, oxide sulfides or oxide fluorides are preferably present in a proportion of in each case up to 5 mol%, up to 3.5 mol% or up to 2 mol% based on the entire component (a).
- the further oxides, oxide sulfides or oxide fluorides are preferably selected from the oxides, oxide sulfides or oxide fluorides of erbium, ytterbium and of at least one further element, in particular of lutetium, gadolinium, holmium, thulium, dysprosium and / or europium.
- the oxides, oxide sulfides or oxide fluorides of erbium and ytterbium are preferably present in a proportion of 0.5-2 mol%, particularly preferably 1-2 mol% based on the total component (a).
- the further oxides, oxide sulfides or oxide fluorides are preferably used in minor proportions of, for example, 0.1-1 mol%, particularly preferably 0.1-0.5 mol%, based on the total component (a).
- component (a) of the luminescent substance besides the oxide, oxide sulfide or oxide fluoride of yttrium may contain oxides, oxide sulfides or oxide fluorides of 1, 2, 3, 4, 5, 6, 7 or even more other elements.
- Component (a) of the luminescent substance additionally additionally contains at least one dopant selected from oxides and / or fluorides of main or subgroup elements.
- the dopants are preferably present in a proportion of up to 5 mol%, more preferably of up to 2 mol%, even more preferably of up to 1 mol%, even more preferably of 0.05-1 mol% and most preferably from 0.1 to 0.2 mol% based on the entire component (a).
- a preferred dopant is a fluoride which may be exemplified by an alkaline earth metal fluoride or alkali metal fluoride, e.g. as potassium fluoride, can be used.
- the fluoride is preferably present in a proportion of 0.1-0.2 mol% based on the entire component (a).
- dopants are alkaline earth metals and / or subgroup elements which are in the form of cations which are twice or more positively charged, preferably in the form of oxides and / or fluorides.
- Particularly preferred dopants are calcium, zinc and / or titanium, for example in the form of the oxides calcium oxide, zinc oxide or titanium dioxide.
- the cationic dopants are preferably present in a proportion of 0.1-0.2 mol%, based on the total component (a).
- the IR-excitable component (a) of the luminescent substance (i) is characterized on the one hand by a high luminescence intensity and on the other hand by emission lines or peaks which are characteristic of the presence and the proportions of the individual fractions.
- Component (a) of the luminescent substance (i) can, as in WO 2008/000461 described produced.
- dopants for example of polyvalent cations and / or fluoride, causes drastic changes in the position and / or intensity of individual emission wavelengths. Furthermore, a strong increase in the total luminescence intensity is also found. It is believed that in addition to the two-photon absorption known in anti-Stokes materials, three-photon absorption also takes place.
- Component (b) of the luminescent substance (i) is a component which can be excited by UV radiation and emits a characteristic luminescence radiation after excitation. It is preferably an aluminate which is optionally doped with transition metal and / or lanthanide ions.
- Component (b) preferably contains an aluminate of alkaline earth metal ions, transition metal ions and / or lanthanide ions, preferably an aluminate of barium or magnesium or an aluminate of yttrium, optionally doped with Eu, Mn, Th and / or Cr ions.
- the location and / or intensity of the emission wavelengths can be varied.
- the UV sensitivity is increased.
- the dopant of component (b) is favorably present in a proportion of up to 10 mol%, up to 5 mol% or up to 1 mol% based on the entire component (b).
- the component (b) is favorably present in a total proportion of 1-30%, 5-20% or 8-12% based on the total weight of the components (a) and (b).
- the components (a) and / or (b) are present in the luminescent substance (i), preferably in crystalline form. Furthermore, it is preferred that the individual components consist of a single phase, for example a crystalline phase, which can be determined by X-ray diffractometric methods.
- the component (a) is particularly preferably in hexagonal crystalline form. If appropriate, the individual components (a) and / or (b) may also each consist of a mixture of a plurality of luminescent substances.
- the luminescent substance is usually present in the form of particles, the mean particle size being ⁇ 5 nm, in particular ⁇ 1 nm.
- the particle size is preferably in the range of 10 nm-100 ⁇ m, preferably 50 nm-50 ⁇ m, and particularly preferably about 100 nm-10 ⁇ m.
- the components (a) and (b) are preferably present in the luminescent substance (i) in a substantially homogeneous distribution, e.g. as a homogeneous distribution of particles, in particular of crystalline particles as described above before.
- This homogeneous distribution can be achieved by co-grinding the components in conventional milling equipment, e.g. Ball mills, can be achieved.
- Component (ii) of the agent according to the invention is a carrier for receiving or reconstructing a volume hologram.
- the carrier is a common carrier for volume holograms, eg a holographic film.
- the carrier may be a transparent or opaque carrier.
- the support may be of any size, eg from 1 mm 2 to 10 cm 2 . A usual size is about 15 x 20 mm.
- the shape of the carrier can be arbitrary, for example, round, rectangular, oval or irregular.
- the hologram may be a transmission or reflection (transmitted light) hologram. Specific types of holograms are Denisjuk holograms, RGB holograms, rainbow holograms, and computer-generated or digital holograms.
- the hologram contains stored data, information or interference patterns, for example in the form of one-dimensional or multidimensional barcodes, images, alphanumeric Characters, digital data bits or combinations thereof. The data may be stored in visible or invisible form.
- volume holograms The recording of volume holograms is performed by irradiating a photosensitive composition with coherent light at a reference wavelength or a reference wavelength combination.
- the reference wavelength is, for example, in the range of 100-1000 nm.
- Preferred materials for generating volume holograms are photosensitive compositions comprising polymerizable materials.
- the hologram can be recorded by an individualized irradiation, so that each individual hologram contains individual information.
- Preferred photosensitive compositions are in US 5,453,340 described, the disclosure of which is incorporated herein by reference.
- the photosensitive composition comprises (ii): (a) one or more radical polymerizable compounds, (b) one or more radical polymerization initiators, (c) one or more cationically polymerizable compounds other than (a), (d) one or several initiators for a cationic polymerization and (e) optionally further components.
- Suitable radically polymerizable compounds (a) are acrylic-based monomers, styrene-based monomers and / or vinyl-based monomers. Specific monomers are acrylamide, methacrylamide, phenyl acrylate, 2-phenoxyethyl acrylate, (acryloxyethyl) naphthalenedicarboxylate monoester, methylphenoxyethyl acrylate, nonylphenoxyethyl acrylate, ⁇ -acryloxyetyl hydrogenphthalate, phenoxypolyethylene glycol acrylate, 2,4,6-tribromophenyl acrylate, (2-methacryloxyethyl) diphenate monoester, benzyl acrylate, 2 , 3-Dibromophenyl acrylate, 2-hydroxy-3-phenoxypropyl acrylate, 2-naphthyl acrylate, N-vinylcarbazole, 2- (9-carbazole) ethyl acrylate, triphen
- any radical-generating substances such as organic dyes with polymer salts, eg, cyanines or salts of diphenyliodonium and diaryliodonium, can be used.
- organic dyes with polymer salts eg, cyanines or salts of diphenyliodonium and diaryliodonium
- cyanines or salts of diphenyliodonium and diaryliodonium can be used.
- Specific examples are anhydro-3,3'-dicarboxymethyl-9-ethyl-2,2'-thiacarbocyanine betaine, anhydro-3-carboxymethyl-3 ', 9-diethyl-2,2'-thiacarbocyanine betaine, 3,3', 9- Triethyl 2,2'-thiacarbocyanine iodide, 3,9-diethyl-3'-carboxymethyl-2,2'-thiacarbocyanine iodide and 3,3 ', 9-trieth
- Component (c) of the photosensitive composition (ii) is one or more cationically polymerizable compounds.
- examples are glycidyl-based compounds, epoxides or vinyl-based compounds.
- Specific monomers are Diglycerolpolyglycidylether, pentaerythritol polyglycidyl ether, 1,4-bis (2,3-epoxypropoxyperfluorisopropyl) cyclohexane, sorbitol polyglycidyl ether, trimethylolpropane polyglycidyl ether, resorcinol diglycidyl ether, 1,6-hexanediol diglycidyl ether, polyethylene glycol diglycidyl ether, phenyl glycidyl ether, pt-Butylphenyldiglycidylether, diglycidyl adipate, diglycidyl o-phthalate, dibromophenyl
- Component (d) of the photosensitive composition (ii) is an initiator of cationic polymerization.
- compounds which produce Br Zernstedt or Lewis acids after decomposition for example Diaryliodoniumsalze, Triarylsulfonsalze, Eisenallensalze and the like.
- diaryliodonium salts are tetrafluoroborates, hexafluorophosphates, Hexafluoroarsenates and hexafluoroantimonates of iodonium compounds.
- triarylsulfone salts are tetrafluoroborates, hexafluorophosphates, hexafluoroarsenates and hexafluoroantimonates of sulfonium or triphenylsulfonium compounds such as 4-tert-butyltriphenylsulfonium, tris (4-methylphenyl) sulfonium, tris (4-methoxyphenyl) sulfonium, 4-thiophenyltriphenylsulfonium. Combinations of several of the compounds mentioned are suitable.
- the photosensitive composition may optionally contain organic solvents, e.g. Ketones, esters, ethers, dioxanes, hydrocarbons such as cyclohexane, halogenated hydrocarbons, aromatics, alcohols or mixtures of one or more such solvents.
- organic solvents e.g. Ketones, esters, ethers, dioxanes, hydrocarbons such as cyclohexane, halogenated hydrocarbons, aromatics, alcohols or mixtures of one or more such solvents.
- Solventless photopolymer compositions can also be used.
- Further possible additives are binders, thermopolymerization inhibitors, silane coupling agents, plasticizers, dyes and / or copolymers.
- the recording and reconstruction of a volume hologram from a photosensitive composition can be carried out by known methods using coherent light radiation, eg laser light, such as in US 5,453,340 described, done. Other methods for producing holograms are in US 2009/286165 A described. The disclosure of this document is expressly incorporated by reference.
- the combination of luminescent substance and holographic support can be used for authentication or identification, for example as security marking of objects, eg substances or mixtures of substances. In this way, the authenticity of products or documents can be determined.
- the holographic support is usually mounted on a surface of the object to be marked. This can be done, for example, by using adhesive material. Alternatively, however, the holographic support can also be incorporated into the surface of the article to be coated.
- the Luminescent substance can be introduced into the carrier and / or be present as a layer on the upper and / or lower surface of the carrier, for example in an adhesive material used for binding the carrier to the article.
- the luminescent substance can also be applied separately from the carrier in or on the object. In this case, the luminescent substance and the carrier may be present side by side, for example in adjoining relation, or on different, spatially separated regions of the article.
- the data or information present in the luminescent substance and in the hologram can be correlated with one another.
- the data may also be associated with an external data carrier, e.g. an optical disc, a FLASH memory or an RFID.
- the luminescent substance can be introduced into or applied to any solid and / or liquid substances or substance mixtures.
- the luminescent substance can be applied to carrier substances, such as paints, toners, inks, paints, etc., or into products, such as plastics, metals, glass, silicones, paper, rubber, medicaments, etc.
- carriers substances such as paints, toners, inks, paints, etc.
- products such as plastics, metals, glass, silicones, paper, rubber, medicaments, etc.
- objects can be provided with a coating of the luminescent substance on its surface or parts thereof which have a layer thickness of, for example, 1-10 ⁇ m, preferably 1-5 ⁇ m.
- the luminescent substance is added to the product or a portion of the product in an amount of 20-2000 ppm, preferably 50-200 ppm.
- the luminescent substance according to the invention is suitable for use in biological systems, eg cell cultures, samples from body fluids or tissue sections or as a contrast agent.
- the luminescent substance can be coupled in nano- or microparticulate form to biological detection reagents.
- the surfaces of particles of the luminescent substance may be modified with deodetomines or other adhesive substances to provide the suspending properties, for example, in organic liquids such as oils, gasolines, liquefied gases etc., in aqueous fluids such as body fluids, in aqueous-organic fluid systems and flowable powders such as toners.
- the smaller the particles the lower their tendency to sedimentation.
- intensive grinding for example, the particle size can be reduced so far, for example to ⁇ 100 nm, that a stable suspension of the particles in liquids is achieved even without the addition of adhesive substances.
- An anti-counterfeiting of the marking is given by the fact that the emission lines characteristic of the respective luminescent substance represent a cryptographic key which can be compared to a detector adapted to the respective substance, i. the castle can be detected.
- the combination of the holographic support with the luminescent substance represents a further significant improvement in the anti-counterfeiting security of the marking.
- the luminescent substance preferably contains two components which can be excited to luminescence by radiation in different wavelength ranges.
- component (a) can be excited to luminescence with IR radiation in the range of 850-1500 nm, in particular of 920-1000 nm, and / or component (b) with UV radiation in the range of 350-420 nm, especially from 380-410 nm, are excited to luminescence.
- the presence of the luminescent substance in an article is detected by irradiation with two wavelengths.
- a first wavelength in the infrared range in particular with IR monochromatic laser light or with an IR light emitting diode with wavelengths between about 850 nm and 1500 nm, preferably between about 920 nm and 1000 nm, more preferably between about 950 nm and 1000 nm, most preferably between 920 nm and 985 nm, wherein component (a) is excited and the resulting emission radiation approximately in the range between 300 nm and 1700 nm, in particular between 350 nm and 1000 nm is detected.
- the irradiation of component (a) is preferably carried out with a power of 1-200 mW, in particular 10-80 mW.
- a second wavelength in the UV range in particular with UV monochromatic laser light or with a UV light emitting diode with wavelengths between about 350 nm and 450 nm, preferably between about 380 nm and 400 nm is used, wherein the Component (b) excited and the emission radiation by eg Fluorescence is detected in the range between 300 nm and 1700 nm, in particular between 350 nm and 1000 nm.
- the irradiation of component (b) is preferably carried out with a power of 2-50 mW, in particular 5-30 mW.
- the components (a) and (b) of the luminescent substance are separately excited to luminescence by irradiation with a wavelength in the IR range and by irradiation with a wavelength in the UV range, and the emission radiation of components (a) and ( b) is detected separately.
- the excitation of component (a) and component (b) may be sequential, i. take place at different times, preferably first the component (a) and then the component (b) is excited.
- the reconstruction of the image produced by the holographic support may be carried out in a conventional manner by irradiation e.g. with a wavelength identical to the reference wave used to record the hologram.
- This wavelength can be in the range between 100-1000 nm and especially between 220-600 nm, e.g. at 266 nm, 405 nm or 530 nm.
- the wavelength may be identical to or different from a wavelength used to excite the luminescent substance.
- the Emission radiation of the luminescent substance are detected digitally together with the signal derived from the holographic carrier.
- digitized signals of the components (a) and (b) of the luminescent substance and of the hologram originating signals or parts of these signals (eg signals of individual peaks) can be converted by cryptographic measures using appropriate algorithms into a new signal.
- the data density can be increased by a factor of up to about 10 6 or more.
- the radiation sources are preferably each laser.
- the readout system preferably further contains a contact sensor, for example an optical contact sensor, which controls the radiation sources, so that activation of the radiation source takes place only when the readout system contacts a sample to be determined.
- a contact sensor for example an optical contact sensor, which controls the radiation sources, so that activation of the radiation source takes place only when the readout system contacts a sample to be determined.
- the irradiation of the product containing the luminescent substance by the readout system can be carried out directly with an optical waveguide or another optically relevant transfer medium, eg a solid optical body, a fluid, gas, etc.
- the detection can be done visually or by means of detectors.
- optical waveguides whose heads are ground as a converging lens, so that incident light (IR or UV light) and light emitted by the luminescent substance (specific emission spectrum) form a unit and can be focused at the same point.
- incident light IR or UV light
- light emitted by the luminescent substance specifically emission spectrum
- An advantage of this is that no mechanical misalignment between receiver and transmitter can take place.
- the attenuation factor of the optical fiber e.g. made of glass or plastic, may vary, the transition from the optical components (radiation source or detection element) to the optical waveguide being mounted with little covision.
- the length of the optical fiber may vary and is typically between 1 cm and 50 cm.
- the readout system further includes one or more optical detection elements which are used for the selective detection of the authenticity of the luminescent substance, e.g. in terms of wavelength and / or intensity, and the hologram are provided.
- the detection elements may be, for example, diodes, photoelements or electronic detectors.
- detector matrices are used with a plurality of detectors preferably set differently, e.g. Diodes, photoelements or CCD matrices.
- the detectors of the detector array may be equipped with a spectrometer and / or optical filters, e.g. Bandpass filters, combined.
- the readout system may also include a programmable electronic unit that enables digital evaluation and conditioning of the measurement signal.
- the readout system of the present invention is desirably used in conjunction with a combination of luminescent composition and volume hologram as previously described.
- step (b) first the irradiation in the IR range and then the irradiation in the UV range.
- step (d) comprises digital processing of the measurement signal or parts thereof.
Landscapes
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Computer Security & Cryptography (AREA)
- Holo Graphy (AREA)
- Credit Cards Or The Like (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10170447A EP2409849A1 (fr) | 2010-07-22 | 2010-07-22 | Combinaison d'une substance luminescente et d'un hologramme |
PCT/EP2011/062552 WO2012010665A2 (fr) | 2010-07-22 | 2011-07-21 | Combinaison d'une matière luminescente et d'un hologramme |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10170447A EP2409849A1 (fr) | 2010-07-22 | 2010-07-22 | Combinaison d'une substance luminescente et d'un hologramme |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2409849A1 true EP2409849A1 (fr) | 2012-01-25 |
Family
ID=42598759
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10170447A Withdrawn EP2409849A1 (fr) | 2010-07-22 | 2010-07-22 | Combinaison d'une substance luminescente et d'un hologramme |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP2409849A1 (fr) |
WO (1) | WO2012010665A2 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105667111A (zh) * | 2016-01-21 | 2016-06-15 | 张利平 | 一种可变化图案与文字的包装盒应用方法 |
DE102017103780A1 (de) | 2017-02-23 | 2018-08-23 | Tailorlux Gmbh | Verfahren zur Identifizierung eines Materials bzw. Materialgemisches |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5453340A (en) | 1991-04-17 | 1995-09-26 | Nippon Paint Company, Ltd. | Photosensitive composition for volume hologram recording |
WO1999046133A1 (fr) * | 1998-03-10 | 1999-09-16 | De La Rue International Limited | Procede de fabrication d'un article de securite |
WO2000060527A1 (fr) | 1999-04-07 | 2000-10-12 | Sicpa Holding S.A. | Procede et dispositif d'excitation d'un materiau luminescent |
US6686074B2 (en) | 2001-03-16 | 2004-02-03 | Bundesdruckerei Gmbh | Secured documents identified with anti-stokes fluorescent compositions |
US20040099740A1 (en) * | 2002-11-25 | 2004-05-27 | Chresand Thomas J. | Merchandising components for authenticating products, and combinations and methods utilizing the same |
US6802992B1 (en) | 1997-03-05 | 2004-10-12 | Wieczoreck Juergen | Non-green anti-stokes luminescent substance |
WO2004102490A1 (fr) * | 2003-05-19 | 2004-11-25 | Bundesdruckerei Gmbh | Detecteur servant a reconnaitre l'authenticite d'un element de securite luminescent d'un document de valeur, document de valeur et procede pour la production de ce dernier |
EP1854642A2 (fr) * | 2006-05-12 | 2007-11-14 | JDS Uniphase Corporation | Dispositif de sécurité formé par un hologramme et une encre de distorsion des couleurs |
WO2008000461A2 (fr) | 2006-06-27 | 2008-01-03 | Swiss Authentication Gmbh | Composition d'une substance luminescente |
DE102007058888A1 (de) * | 2007-12-05 | 2009-06-10 | Informium Ag | Fälschungsschutz für Einweggebinde |
US20090286165A1 (en) | 2008-05-16 | 2009-11-19 | Sony Corporation | Hologram laminate, hologram copy method, and hologram producing method |
WO2010046708A1 (fr) * | 2008-10-22 | 2010-04-29 | Kenneth John Drinkwater | Dispositif et procédé de sécurité |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5920058A (en) * | 1996-10-23 | 1999-07-06 | Weber; David C. | Holographic labeling and reading machine for authentication and security applications |
DE102010028818A1 (de) | 2010-05-10 | 2011-11-10 | Swiss Authentication Research And Development Ag | Kombination von Lumineszenzstoffen |
-
2010
- 2010-07-22 EP EP10170447A patent/EP2409849A1/fr not_active Withdrawn
-
2011
- 2011-07-21 WO PCT/EP2011/062552 patent/WO2012010665A2/fr active Application Filing
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5453340A (en) | 1991-04-17 | 1995-09-26 | Nippon Paint Company, Ltd. | Photosensitive composition for volume hologram recording |
US6802992B1 (en) | 1997-03-05 | 2004-10-12 | Wieczoreck Juergen | Non-green anti-stokes luminescent substance |
WO1999046133A1 (fr) * | 1998-03-10 | 1999-09-16 | De La Rue International Limited | Procede de fabrication d'un article de securite |
WO2000060527A1 (fr) | 1999-04-07 | 2000-10-12 | Sicpa Holding S.A. | Procede et dispositif d'excitation d'un materiau luminescent |
US6686074B2 (en) | 2001-03-16 | 2004-02-03 | Bundesdruckerei Gmbh | Secured documents identified with anti-stokes fluorescent compositions |
US20040099740A1 (en) * | 2002-11-25 | 2004-05-27 | Chresand Thomas J. | Merchandising components for authenticating products, and combinations and methods utilizing the same |
WO2004102490A1 (fr) * | 2003-05-19 | 2004-11-25 | Bundesdruckerei Gmbh | Detecteur servant a reconnaitre l'authenticite d'un element de securite luminescent d'un document de valeur, document de valeur et procede pour la production de ce dernier |
EP1854642A2 (fr) * | 2006-05-12 | 2007-11-14 | JDS Uniphase Corporation | Dispositif de sécurité formé par un hologramme et une encre de distorsion des couleurs |
WO2008000461A2 (fr) | 2006-06-27 | 2008-01-03 | Swiss Authentication Gmbh | Composition d'une substance luminescente |
DE102007058888A1 (de) * | 2007-12-05 | 2009-06-10 | Informium Ag | Fälschungsschutz für Einweggebinde |
US20090286165A1 (en) | 2008-05-16 | 2009-11-19 | Sony Corporation | Hologram laminate, hologram copy method, and hologram producing method |
WO2010046708A1 (fr) * | 2008-10-22 | 2010-04-29 | Kenneth John Drinkwater | Dispositif et procédé de sécurité |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105667111A (zh) * | 2016-01-21 | 2016-06-15 | 张利平 | 一种可变化图案与文字的包装盒应用方法 |
DE102017103780A1 (de) | 2017-02-23 | 2018-08-23 | Tailorlux Gmbh | Verfahren zur Identifizierung eines Materials bzw. Materialgemisches |
Also Published As
Publication number | Publication date |
---|---|
WO2012010665A2 (fr) | 2012-01-26 |
WO2012010665A3 (fr) | 2012-06-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
RU2621657C2 (ru) | Способы печати осязаемых элементов защиты | |
US9243169B2 (en) | Security laminate | |
EP2296911B1 (fr) | Procédé de fabrication d'un produit de sécurité et/ou de valeur présentant un motif aléatoire et une chaîne de caractères d'identification corrélée | |
CN106660385B (zh) | 光变磁性安全线和条 | |
EP3220171B1 (fr) | Élément optique anti-contrefaçon | |
EP2569393B1 (fr) | Combinaison d'agents luminescents | |
EP2698404A1 (fr) | Microparticules, ensembles de particules, encre anti-contrefaçon, toner anti-contrefaçon, feuille anti-contrefaçon et support anti-contrefaçon | |
EP2296912B1 (fr) | Procédé de fabrication d'un produit de sécurité et/ou de valeur comprenant des régions présentant une émission de luminescence différente | |
EP1343639A1 (fr) | Film decor | |
EP2155963B8 (fr) | Élément de sécurité transparent | |
CN104144795B (zh) | 被防护清漆覆盖并包含一个或多个无清漆区域的安全文件和该安全文件的永久染色 | |
EP2996880B1 (fr) | Stratifié de sécurité | |
KR20140141678A (ko) | 코딩 레벨이 높은 다층 플레이크 | |
AT515845B1 (de) | Sicherheitselement und Verfahren zur Herstellung eines Sicherheitselements mit lichtstreuenden Strukturen | |
RU2770525C2 (ru) | Сборки и способы получения слоев с оптическим эффектом, содержащих ориентированные несферические сплюснутые магнитные или намагничиваемые частицы пигмента | |
DE102007052952A1 (de) | Verfahren und Vorrichtung zur Herstellung von Hologrammen mit wasserzeichenartiger Struktur | |
DE102012211077A1 (de) | Sicherheitselement mit Beugungsstrukturen aufweisenden Mikrostrukturen sowie Verfahren zur Herstellung und Verifikation | |
WO2012077490A1 (fr) | Particules, encre anti-falsification, toner anti-falsification, feuille anti-falsification, support anti-falsification et procédé de fabrication de particules | |
KR20150096750A (ko) | 무작위 분포된 크레이터를 안에 포함하는 키랄 액정 중합체 층 또는 패턴 | |
SA521430912B1 (ar) | سمات أمنية قابلة للقراءة آلياً وأحبار أمنية | |
EP2409849A1 (fr) | Combinaison d'une substance luminescente et d'un hologramme | |
DE102010015258A1 (de) | Sicherheitselement mit einer lokal hinsichtlich ihrer Lichtausbreitungseigenschaften modifizierten lichtleitenden Struktur und Verfahren zur Herstellung eines solchen Sicherheitselements | |
DE102006032538A1 (de) | Speichermedium mit einem Sicherheitsmerkmal sowie Verfahren zur Herstellung eines Speichermediums mit einem Sicherheitsmerkmal | |
EP3039491B1 (fr) | Procédé de marquage décentralisé d'un document de sécurité | |
EP2214914B1 (fr) | Procédé de production d'un element de sécurité pour un document et document correspondant |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME RS |
|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 20120726 |