EP2373767A1 - A method for the production of pellets or briquettes - Google Patents
A method for the production of pellets or briquettesInfo
- Publication number
- EP2373767A1 EP2373767A1 EP09744786A EP09744786A EP2373767A1 EP 2373767 A1 EP2373767 A1 EP 2373767A1 EP 09744786 A EP09744786 A EP 09744786A EP 09744786 A EP09744786 A EP 09744786A EP 2373767 A1 EP2373767 A1 EP 2373767A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- reactor
- steam
- pellets
- briquettes
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/442—Wood or forestry waste
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B11/00—Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
- C10L5/34—Other details of the shaped fuels, e.g. briquettes
- C10L5/36—Shape
- C10L5/361—Briquettes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
- C10L5/34—Other details of the shaped fuels, e.g. briquettes
- C10L5/36—Shape
- C10L5/363—Pellets or granulates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/445—Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/08—Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Definitions
- the present invention relates to a method for the production of pellets and briquettes, from lignin containing material, such as from raw materials of wood, bamboo, bagasse, straw, or grass.
- Fuel pellets of wood are one of the fastest growing forms of bioenergy. Wood pellets and briquettes have also several other applications, but the most common field of use is as fuel pellets. Today, wood pellets are produced in substantial volumes at a large number of plants, especially in Europe and North America.
- the raw materials are primarily sawdust, with a typical particle size of less than 3 mm and a typical relative moisture content of about 50-55% by weight, and raw materials which are residual products from planing mills, furniture factories etc, with a typical relative moisture content in the range of about 10-18% by weight.
- Raw materials with a relative moisture content of more than about 18-20% by weight are dried prior to pelletization. These materials constitute the major portion of the raw materials, which today are mostly sawdust.
- the drying is usually carried out in drum dryers into which the raw materials are introduced and into which there are injected flue gases from a combustion plant fuelled by chips/bark or the like, direct drying taking place on the basis of flue gases.
- flue gases from a combustion plant fuelled by chips/bark or the like
- several types of dryers are in use, including low temperature dryers. Grinding
- the next step is mechanical fine grinding of the raw materials, down to a typical particle size of less than about 2 mm. This is usually done in an impact mill (hammer mill).
- the material is then passed to pellet presses, where pelletization typically is carried out in that the material is pressed through cylindrical holes in a ring die, and the compressed material that comes out is cut into pellets.
- the newly produced pellets which have a high temperature and a soft consistency, are then passed to a cooler, which is a vessel through which air is passed, so that a controlled cooling of the pellets is obtained, and at the same time the volume of fines is reduced. Finished pellets then exit the cooler.
- Briquettes are produced from the same raw materials as pellets. While pellets have a typical diameter of about 6.8 or 12 mm and a length of about 10-20 mm, briquettes are larger, with a typical diameter of about 50 mm, and a length from about 20 mm and upwards to about 300 mm. Briquettes are not produces in ring dies, but in separate briquette presses where the raw material is compressed. The briquettes typically have a lower volumetric weight than pellets.
- lignin containing material should be understood as any material containing lignin which may be used in the invention, such as lignocellulosic materials, wood comprising materials, for example wood, bamboo, bagasse, straw, or grass.
- the lignin containing material may be in any suitable and processable form, such as in the form of powder, dust, sawdust, chips, splinters, chippings, shavings, cuttings or similar particles.
- a method for the production of pellets or briquettes from lignin containing material characterized by comprising the steps of: (a) passing the material, if it has a relative moisture content of more than about 30%, alternatively more than about 20% by weight, to a drying step and drying it " to a relative moisture content of about 0-30%, alternatively about 0-20% by weight; (b) passing the material, optionally via an intermediate storage step, to a heat treatment step and heating the material to about 180-235 0 C by injecting steam into a reactor; (c) maintaining the material in the reactor at the temperature reached for a sufficient time to soften the material and release lignin; (d) reducing the pressure in the reactor in at least one step; and
- the material is chosen from the group comprising: lignocellulosic material, wood comprising material, wood, bamboo, bagasse, straw, or grass.
- the material may also be chosen from group comprising: dust, saw dust, chips, splinters, coarse particles, chippings, shavings or cuttings.
- the invention concerns a method the steam injected into the reactor is superheated unsaturated steam, which further reduces the moisture of the material during the heat treatment, such as in the range of about 1-5 percent units, about 4-5 percent units and alternatively about 5 percent units of relative moisture of the material.
- the super heated unsaturated steam is for example injected to the reactor at about 350 0 C and about 20 bars.
- the treated material may in a step (d2) also be emptied between the steps (d) and (e), from the reactor and received in a receiving tank or cyclone where the steam is separated from the material, so that as little condensate from the steam as possible is brought along as moisture further in the process or product.
- the treated material may be mixed with additional treated or non-treated lignin containing material, in a step (d3) between step (d) and (e), preferably after the step (d2).
- the material may in one embodiment be dried to a relative moisture content of about 5- 15 % by weight, alternatively about 2-12% by weight before it passes to the reactor step (b).
- the retention time in the reactor may be within the range of about 10 seconds to 2 hour, about 30 seconds to 60 minutes, about 1-30 minutes, about 1-20 minutes, about 1- 15minutes and alternatively about 1-12 minutes.
- the last pressure reduction of the reactor takes place suddenly by steam explosion so that the material is defibrated, while in another embodiment the depressurization of the reactor takes place slowly without steam explosion.
- the material may be coarse particles, such as cellulose chips, such as with a length of about 25 mm.
- the material may also be finely divided before the reactor step, such as in the form of dust or sawdust or more finely divided material, such as with a length of less than about 3 mm.
- the admixed lignin containing material has a moisture content of less than about 18% by weight and/or a typical particle size of less than about 2 mm.
- the invention concerns a method as above, wherein the method comprises an additional step of:
- the invention concerns pellets or briquettes which are produced as described over.
- the pellets or briquettes may contain a relative moisture content of about 5% by weight or less, or about 2% by weight or less and possibly have an energy content of about 5.0 MWh/tonne or more, or about 5.2 MWh/tonne or more.
- the material that is to be used may be pre-dried, or have a relative moisture content of less than 30%, or less than 20% by weight, and thus not require drying. If the moisture is above 30%, or above 20% the material is dried as a step in the process itself.
- the material that is fed into the reactor thus has a substantially lower moisture content than has previously been used in the prior art.
- the present invention discloses a moisture content after drying of about 0- 30%, alternatively about 0-20%, as against 30-45% in the prior art, thereby overcoming some major objections still in existence in the art as explained introductory.
- the reduced moisture in the material results in lower steam consumption in the reactor, which gives lower production costs.
- the relative moisture content of the material entering the reactor is preferably in the range of about 5-15 % by weight, or about 2-12% by weight.
- drying can be carried out in one step (only prior to steam explosion) instead of in two steps as in the prior art (which comprises drying prior to steam explosion and drying before the material passes into the pellet press), which gives substantially lower investment costs than if two drying steps are used as earlier.
- Some drying may occur by injecting superheated (unsaturated) steam into the reactor, instead of dry saturated steam, such as for example after step (d) of the method above. This will result in dry material evaporating until the steam has been saturated, and that the moisture in the material after processing in the reactor is lower than if only saturated steam had been injected.
- the retention time in the reactor is advantageously about 1-12 minutes.
- the reduction of pressure in the reactor takes place either: (1) in that the last pressure reduction takes place suddenly, thereby obtaining a steam explosion in which the material is defibrated and lignin is released; or
- Method (2) is most appropriate when the material is relatively finely divided prior to treatment in the reactor (as e.g., sawdust with a typical length of less than 3 mm, or even more finely divided material), whereas method (1) is preferable when there are coarser particles (as e.g., cellulose chips, with a typical length of about 25 mm). This is due to the fact that with method (1), there is no need for mechanical fine grinding after the treatment in a reactor even though the raw materials are of the size of cellulose chips. However, if method (2) is used, the raw materials should be more finely divided than cellulose chips if the material is to be able to pass directly to pelletization without any further mechanical grinding.
- Defibration by steam explosion is just one of the parameters that are of primary importance in rendering the material suitable for pelletization.
- Tests show that an increase in temperature and in particular in retention time not only makes it easier to defibrate material by steam explosion, but also makes the material softer and gives more released lignin even without steam explosion, which thus renders the material more suitable for pelletization.
- the design of the reactor and equipment associated therewith permits discharge when the material has low moisture content. It is quite possible to equip the reactor so that it can be emptied even without a sudden reduction in pressure (steam explosion) in the last step.
- the treated material is pelletized, optionally after it has been mixed with other lignin containing material, for example, non-steam exploded lignin containing material.
- the admixed lignin containing material advantageously has a moisture content no higher than 18% by weight and a typical particle size no greater than 2 mm.
- the treated material may be briquetted instead of pelletized in a briquette press.
- the present invention By using the present invention, the early and major reduction in moisture results in the heat-induced hydrolysis of the organic material starting later and being weaker than in the known methods. Thus, the present invention reduces the loss of dry matter that is a problem in the prior art.
- pellets or briquettes can be obtained with a moisture content of 2% and lower which have the same good binding properties as other known pellets prepared from steam-exploded wood.
- the invention also results in a number of advantages compared with mechanical production of wood pellets and briquettes.
- the advantages over the mechanical process for the production of pellets reside in higher quality and higher capacity.
- Higher quality consists in the treated pulp having binding properties which far exceed the previously obtained pulps and the improved binding properties of the pellets lead to a lower volume of fines (dust), and a better cohesion.
- Higher capacity of the pellet presses or briquette press, with the same electricity consumption, is obtained because the pulp in the present invention has a softer consistency and is easier to pelletize than mechanically finely ground wood, and the bulk weight of the pellets or briquettes can 5 also be increased without increasing the consumption of electricity.
- pellets prepared according to the invention are virtually non-hygroscopic. Mechanically produced pellets and briquettes absorb moisture soo easily that they must be stored and handled in dry conditions. If they come into contact with water, they will lose their form and revert to a form of wood powder or sawdust.
- the pellets and briquettes according to the invention can be handled and stored without contact with water or moisture being a problem; they retain their shape and only absorb water to a slight degree, and only after a long time.
- pellets and briquettes of the present invention it is possible to use the same storage and transport facilities those already present for coal.
- mechanically produced pellets on the other hand, separate facilities must be provided to ensure dry handling during storage and transport.
- the present invention also means that the storage facilities can be made far more cheaply than today.
- the present invention thus provides an improved method that obtains an improved product as disclosed above.
- the method provided according to the invention can be5 accommodated to existing pellet or briquette plants which today use neither steam explosion nor elevated temperature treatment with steam for pelletization.
- FIG. 1 shows a graph where temperature is plotted against time for two separate processing courses. Examples of embodiments
- the raw materials may be any kind of lignin containing material.
- Raw materials with a relative moisture content of more than about 30%, alternatively more than about 20% by weight are dried to a relative moisture content of about 0-30%, alternatively about 0-20% by weight. This is done typically as direct drying in a drum dryer into which flue gases are injected, but other drying methods may also be used.
- the raw materials are then passed from the drying step directly, or optionally after intermediate storage, to a reactor in which the raw materials are heat- treated, optionally steam-exploded. This takes place in that after the raw materials have been introduced into the reactor, the filling valve for chips is closed, and steam is injected into the reactor until the temperature has reached about 180-235°C, and at a pressure of for example about 20 bar.
- saturated aqueous steam is used in the drying step at a temperature in the range given above.
- the steam supplied to the reactor is superheated (unsaturated) steam, the moisture of the material may be further reduced during the heat treatment itself.
- a pressure reduction is then carried out in one or more steps. In the last pressure reduction, the pressure is reduced to atmospheric pressure, and the treated material is discharged from the reactor.
- the material has then been transformed into a pulp, in the case of wood as raw materials into a brown-coloured "wood pulp", with a substantially softer consistency than the ingoing raw material. If the last pressure reduction takes place as a sudden drop in pressure, this is a steam explosion in the traditional sense. If the last pressure reduction takes place gradually and cautiously, there is no steam explosion that defibrates the material, but the material is nevertheless given a softer consistency and a characteristic brown colour.
- the brown colour is due to the fact that the lignin has been softened and partly released through retention in the temperature range mentioned above.
- the pulp that is discharged from the reactor may be received in a receiving tank or cyclone where the steam is separated from the pulp, so that minimum condensate from the steam remains as moisture further in the process or product.
- the material is then optionally mixed with dried raw materials that have been ground down in an impact mill to a particle size suitable for pelletization.
- the optionally admixed lignin containing material advantageously has a moisture content that is no higher than 18% by weight and a typical particle size no larger than 2 mm. This mixed pulp or optionally unmixed material is then passed to pelletization or briquetting.
- the material (the mixed mass or possibly the unmixed material) is subsequently passed to pellet and/or briquetting presses, where the pelletization typically takes place in that the material is pressed through cylindrical holes in a ring die and the compressed material that comes out is cut into pellets, or the material is alternatively pressed into briquettes in a briquetting press.
- the newly produced pellets or briquettes which have a high temperature and a soft consistency, are then preferably passed to a cooler, which is a vessel through which air is passed, so that a controlled cooling of the pellets is obtained, and at the same time the volume of the fines is reduced. Finished pellets /briquettes then exit the cooler.
- the process in the reactor can be optimized in a number of ways.
- the basic relations are that: - If the temperature of the reactor is increased, the retention time can be reduced; if the temperature is lowered, the retention time must be increased. By increasing the temperature, capacity can be increased through a shorter retention time.
- the optimum treatment conditions are different for different types of lignin containing material, even for different types of wood. There are also local variations (inter alia, on the basis of growth conditions) within the individual material types, which means that the optimization of the process conditions give best results when done for the individual plant.
- Fig. 1 the principles of the relation or dependency between processing parameters are illustrated for two different ways of processing a certain material, in this case temperature and retention time at a certain pressure.
- Curve A Light processing
- Curve B “Intense processing” represents parameters that provide a more vigorous treatment which for a given retention time always is treated at a higher temperature compared to a "mild processing”, and which may be optimal for other markets, such as bulk supplies which involves more severe handling.
- Pellets/briquettes treated in a "severe processing” have a higher bulk weight than pellets/briquettes treated by a "light processing".
- the curves will move outward in the diagram, i.e. away from origo, in order to provide the same degree of processing.
- the change in retention time and temperature will generally follow the same type of shape or course of the curves.
- the displacement will be different for each type of material, and sub type of material, such as for different types of wood.
- the curve will have the same structure, but a different position and somewhat different course in the diagram. For example, there are important differences in the curves for soft and hard wood, and even a certain difference between spruce/fir and pine.
- the curve for pine will for example be further away from origo than the curve for spruce/fir for the same degree of processing.
- the processing parameter of a retention time of about 1-12 minutes is only a preferred interval, based on desired processing time in a plant and the degree of processing, in relation to a practical temperature and pressure ranges, hi most cases, it will be preferable to remain within these ranges, but in some cases other conditions outside of these ranges may be preferable.
- Such ranges may for example be within about 10 seconds to 2 hour, or about 30 seconds to 60 minutes, about 1-30 minutes, about 1-20 minutes or about 1-15 minutes and any ranges in between.
- a small producer may prefer to work at the lowest possible pressure and temperature ranges for steam, so that less costly steam equipment may be used, and security and competence for operators are less strict, although for most producers, higher temperatures would be more profitable.
- longer retention time needed for working at low temperature/pressure reduces the production capacity. Still, this may be preferable for example if supply of steam is limited. Also, longer retention time at low temperatures, such as at about 180°C may also be used for a certain time only, such as during start-up or ending of the process run, as processing starts at about 180 0 C and continues as long as the temperature is kept above 180 0 C.
- the optimal mixture ratio of steam-exploded/heat treated pulp to other lignin containing materials, such as wood, in pellets/briquettes depends upon a number of factors, which are often different for each individual plant.
- the type of lignin containing material, such as wood, used is a major factor, as is the availability of raw materials at the plant in general.
- the relation between electricity costs and the thermal energy used in the reactor process is also important because the portion that is mixed with the steam-exploded pulp is finely ground in an impact mill in advance, which requires electrical energy. It is also of major importance which market the products, pellets or briquettes are destined for, as the relative importance of the increase in quality may be different.
- the consistency of the steam-exploded /heat-treated pulp also has an effect on the quality of the pellets/briquettes, and thus on what mixture ratios are optimal.
- the particle size for the raw materials/the material upon entering the reactor is decisive for whether the pulp becomes a brown powder, as when ingoing raw material is sawdust, or whether the pulp has a consistency more like dry shredded peat, with longer fibre bundles that are soft.
- Pellets/briquettes from the last type of pulp provide even better properties as regards a smaller quantity of fines than steam-exploded pulp from sawdust.
- the ingoing raw material in the reactor must be far larger than the typical particle size for sawdust, and some types of lignin containing materials are better suited than others for producing such pulp.
- the moisture in the raw materials when they enter the reactor to be steam-exploded/heat-treated is considerably lower (about 0-30%, alternatively about 0-20% by weight) than in the prior art method (30 - 45% by weight).
- Lower steam requirements also give a shorter filling time and pressure reduction time for steam, which in turn gives a greater number of portions or batches per time unit. This means higher production capacity in a reactor of a given size.
- the mass may possibly be dried according to the present invention by using superheated (unsaturated) steam in the reactor during the heat treatment, instead of saturated steam which is common for such heat treatment.
- superheated steam may be supplied at conditions and amounts that result in the same temperature range (about 180-235 0 C) in the reactor for the heat treatment that is necessary for the processing ass described earlier.
- Such conditions may for example be unsaturated aqueous steam of about 350 °C, at about 20 bars.
- a reduction in moisture in the raw material is in this way obtained of typically up to 5 percent units. That is to say that material loaded into the reactor with relative moisture of about 20% might be reduced to about 15%, and likewise that if material with relative moisture of about 12% is fed to the reactor theo moisture of this material might be reduced down to about 7%, by injecting superheated steam into the reactor.
- the present invention makes it possible to obtain extremely dry material for pelleting or briquetting, and thereby extremely dry pellets or briquettes.
- the technique of superheated steam for reduction of water of the material in the reactor is used to reduce the temperature or the time of the drying step before the heat treatment in order to obtain the same product with the same properties as described earlier.
- different results and products maybe obtained.
- the pressure reduction may alternatively be carried out so that a steam explosion is obtained, or the pressure reduction can be carried out so gradually that there is no steam explosion.
- the choice between these methods is made on the basis of whether the material is so finely divided beforehand that it is not necessary to defibrate it by steam explosion.
- the method that is provided according to the present invention can be accommodated to existing pellet/briquette plants that are based on mechanical fine grinding and pelletization or briquetting without other investments than in reactor(s), steam production, receiving the pulp and handling the steam that is separated from the pulp, and optional mixing with mechanically finely ground lignin containing material, for example wood.
- a reactor can be put in the production line instead of fine grinding (typically with an impact mill).
- some of the raw materials may optionally be moved after the dryer to a reactor and some to mechanical fine grinding, - typically in that larger particles are taken to the reactor.
- the two-step drying method from the prior art is to be accommodated to existing plants, an additional dryer must be invested in for drying of the pulp after steam explosion, i.e., before the pulp is pelletized or briquetted.
- the same dryer could not be used for raw materials that are to be steam-exploded and the portion of the raw materials that is optionally to be finely ground mechanically, since the requirement of relative moisture content after the drying is very different in the two cases.
- the method according to the invention is preferable to implement practically, logistically and economically in existing plants.
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL09744786T PL2373767T3 (en) | 2008-12-15 | 2009-10-05 | A method for the production of pellets or briquettes |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NO20085249A NO327839B3 (en) | 2008-12-15 | 2008-12-15 | Process for producing wood pellets and pellets thereof |
NO20092136A NO335883B1 (en) | 2009-06-02 | 2009-06-02 | Process for making wood pellets and briquettes |
PCT/NO2009/000346 WO2010071440A1 (en) | 2008-12-15 | 2009-10-05 | A method for the production of pellets or briquettes |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2373767A1 true EP2373767A1 (en) | 2011-10-12 |
EP2373767B1 EP2373767B1 (en) | 2018-07-25 |
Family
ID=41467157
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09744786.6A Active EP2373767B1 (en) | 2008-12-15 | 2009-10-05 | A method for the production of pellets or briquettes |
Country Status (17)
Country | Link |
---|---|
US (2) | US10570349B2 (en) |
EP (1) | EP2373767B1 (en) |
JP (4) | JP2012512270A (en) |
KR (2) | KR101526840B1 (en) |
CN (2) | CN102245748A (en) |
AU (1) | AU2009327630C1 (en) |
BR (1) | BRPI0923508A8 (en) |
CA (1) | CA2746998C (en) |
ES (1) | ES2693144T3 (en) |
LT (1) | LT2373767T (en) |
NZ (1) | NZ593489A (en) |
PL (1) | PL2373767T3 (en) |
PT (1) | PT2373767T (en) |
RU (1) | RU2518068C2 (en) |
TR (1) | TR201815603T4 (en) |
WO (1) | WO2010071440A1 (en) |
ZA (1) | ZA201104425B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3095654A1 (en) | 2019-05-03 | 2020-11-06 | Europeenne De Biomasse | Steam cracking control to improve the PCI of black granules |
FR3095655A1 (en) | 2019-05-03 | 2020-11-06 | Europeenne De Biomasse | Mixture of steam cracked biomass and lignin for pellet production |
Families Citing this family (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102009040172A1 (en) * | 2009-09-04 | 2011-03-10 | Dieffenbacher Gmbh + Co. Kg | Method and plant for producing pellets from biomass in a pelleting press for use as fuel in fireplaces |
CN101993752B (en) * | 2010-11-25 | 2013-09-18 | 东南大学 | Method and device for preparing fuel by utilizing sludge and straw |
CN102535216B (en) * | 2011-12-27 | 2015-08-12 | 北京晨峰投资控股有限公司 | A kind ofly compress wood chip, production method that bamboo chip becomes block |
PL229082B1 (en) | 2012-03-06 | 2018-06-29 | Ecofuel Spolka Z Ograniczona Odpowiedzialnoscia | Pressure-molded agglomerated solid fuel, a method for producing a molded agglomerated solid fuel and the use thereof |
FI20125362L (en) * | 2012-03-29 | 2013-09-30 | Upm Kymmene Corp | Alignment and procedure and system for processing alignment |
WO2013191897A1 (en) * | 2012-06-22 | 2013-12-27 | Sundrop Fuels, Inc. | Pretreating biomass using steam explosion before gasification |
EP2765178A1 (en) | 2013-02-07 | 2014-08-13 | Arbaflame Technology AS | Method of producing carbon-enriched biomass material |
WO2014124399A1 (en) * | 2013-02-08 | 2014-08-14 | Zilkha Biomass Fuels Ill C | Method for producing fuel pellets and other lignocellulosic products with reduced hemicellulose, alkali metal and chlorine contents |
NO342736B1 (en) * | 2013-02-20 | 2018-08-06 | Arbaflame Tech As | Process and apparatus for producing biomass fuel |
US9255187B2 (en) * | 2013-03-15 | 2016-02-09 | Synergy Horizon Limited | Method for production of dry hydrolytic lignin |
CN103555387B (en) * | 2013-11-07 | 2015-02-11 | 济南开发区星火科学技术研究院 | Preparation method of bio-fuel |
EP2873715A1 (en) | 2013-11-17 | 2015-05-20 | "Latvian State Institute of Wood Chemistry" Derived public person | Method for production of fuel pellets |
US9296122B2 (en) * | 2013-12-16 | 2016-03-29 | Jeff F. Gustafson | Compressed smoking chip disc and process for making the same |
GB2528832A (en) | 2014-06-06 | 2016-02-10 | Glommen Skog Sa | Method |
CN104212531A (en) * | 2014-09-25 | 2014-12-17 | 江南大学 | Method for preparing solid fuel by exploding biomass waste through external gas assisted by steam |
WO2017025511A1 (en) * | 2015-08-10 | 2017-02-16 | Biogasol Aps | Mixed composition biomass pellets |
FI126555B (en) * | 2015-11-26 | 2017-02-15 | Valmet Technologies Oy | Biomass-based fuel arranged to reduce the chemical and / or mechanical influence of the flue gas on heat transfer surfaces and the method for its production |
ITUB20159375A1 (en) * | 2015-12-15 | 2017-06-15 | Familia S R L | FUEL DEVICE AND METHOD FOR MANUFACTURING THE DEVICE |
US20200131318A1 (en) | 2016-08-23 | 2020-04-30 | National Research Council Of Canada | Lignin pellets and process for producing same |
NO345925B1 (en) * | 2017-08-16 | 2021-10-25 | Arbaflame Tech As | Method and apparatus for production of cellulose based fuel pellets. |
JP6986739B2 (en) * | 2017-09-06 | 2021-12-22 | 株式会社エム・アイ・エス | Bamboo biomass fuel manufacturing method |
US11939549B2 (en) | 2017-10-04 | 2024-03-26 | Mitsubishi Ube Cement Corporation | Biomass solid fuel |
US11174443B2 (en) * | 2017-12-12 | 2021-11-16 | University Of Louisville Research Foundation, Inc. | Torrefied biomass briquettes and related methods |
JP6381836B1 (en) * | 2018-01-15 | 2018-08-29 | 太平洋セメント株式会社 | Pellet biomass fuel storage method, pellet biomass fuel storage |
US11091715B2 (en) | 2018-04-11 | 2021-08-17 | Regents Of The University Of Minnesota | Fuel compositions based on binders from birch bark |
US11085003B2 (en) | 2018-04-11 | 2021-08-10 | Regents Of The University Of Minnesota | Fuel compositions based on binders from cutin-containing materials |
CN110776969A (en) * | 2018-07-31 | 2020-02-11 | 龙门县景龙生物能源有限公司 | High-calorific-value biomass granular fuel and preparation method thereof |
FR3087790B1 (en) * | 2018-10-29 | 2021-06-25 | Europeenne De Biomasse | CONTINUOUS MANUFACTURING PROCESS OF A COMBUSTIBLE MATERIAL FOR AN INDUSTRIAL BOILER, MATERIAL AND CORRESPONDING INSTALLATION |
SE543284C2 (en) * | 2019-03-14 | 2020-11-17 | Stora Enso Oyj | Process for producing agglomerated lignin |
FR3097554B1 (en) | 2019-06-24 | 2021-11-26 | Europeenne De Biomasse | Process for the production of a biofuel by steam cracking |
FR3097555B1 (en) | 2019-06-24 | 2021-11-26 | Europeenne De Biomasse | Process for the production of a biofuel by steam cracking |
RU2721560C1 (en) * | 2019-11-20 | 2020-05-20 | Федеральное государственное бюджетное учреждение науки Научно-исследовательский геотехнологический центр Дальневосточного отделения Российской академии наук | Production method of fuel granules from frozen peat |
KR102354445B1 (en) | 2020-10-14 | 2022-01-25 | (주)진에너텍 | Sludge coal production device using waste mushroom medium and bagasse |
KR102365646B1 (en) | 2020-10-14 | 2022-02-23 | (주)진에너텍 | Manufacturing method of sludge fuel coal using waste mushroom medium and bagasse |
JPWO2022153830A1 (en) * | 2021-01-12 | 2022-07-21 | ||
JP7388669B2 (en) | 2021-07-02 | 2023-11-29 | 株式会社Ihi | Solid fuel production system and solid fuel production method |
JP2023095161A (en) * | 2021-12-24 | 2023-07-06 | 出光興産株式会社 | Method for producing solid biomass fuel |
Family Cites Families (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US351067A (en) | 1886-10-19 | Machine for the manufacture of wood pulp | ||
US1578609A (en) | 1924-09-24 | 1926-03-30 | William H Mason | Process and apparatus for disintegration of wood and the like |
US1586159A (en) | 1924-09-24 | 1926-05-25 | William H Mason | Low-temperature explosion process of disintegrating wood and the like |
US1824221A (en) | 1928-10-24 | 1931-09-22 | Masonite Corp | Process and apparatus for disintegration of fibrous material |
US1922313A (en) | 1931-06-27 | 1933-08-15 | Masonite Corp | Process and apparatus for disintegration of material |
US3533906A (en) | 1967-10-11 | 1970-10-13 | Haigh M Reiniger | Permanently reacted lignocellulose products and process for making the same |
CA960203A (en) | 1970-05-19 | 1974-12-31 | Werner Wenzel | Method of and apparatus for producing adsorbent materials, particularly cokes |
US3961913A (en) | 1974-03-29 | 1976-06-08 | Combustion Equipment Associates, Inc. | Process for treating organic wastes and product thereof |
JPS5331642B2 (en) | 1975-02-10 | 1978-09-04 | ||
US4324561A (en) * | 1975-06-26 | 1982-04-13 | Nipac, Ltd. | Combustible fuel pellets formed from botanical material |
CA1267407B (en) | 1981-11-12 | 1990-04-03 | Edward A. Delong | Method of rendering lignin separable from cellulose and hemicellulose and the product so produced |
CA1141376A (en) * | 1981-11-12 | 1983-02-15 | Edward A. De Long | Method of rendering lignin separable from cellulose and hemicellulose and the product so produced |
AT374491B (en) * | 1982-01-20 | 1984-04-25 | Voest Alpine Ag | METHOD FOR CONTINUOUS DRYING AND FINISHING OF ORGANIC SOLIDS, E.g. BROWN COALS |
JPS59102989A (en) * | 1982-12-03 | 1984-06-14 | Japan Steel Works Ltd:The | Manufacture of fuel pellet |
US5017319A (en) | 1984-03-30 | 1991-05-21 | Shen Kuo C | Method of making composite products from lignocellulosic materials |
US4601113A (en) | 1985-04-26 | 1986-07-22 | Westinghouse Electric Corp. | Method and apparatus for fluidized steam drying of low-rank coals |
US4751034A (en) * | 1986-03-14 | 1988-06-14 | Delong Edward A | Method of molding using dissociated lignocellulosic material and the product so produced |
US4828573A (en) * | 1987-04-13 | 1989-05-09 | Technology Research & Development, Inc. | Method of manufacturing a pelletized fuel |
NZ229080A (en) * | 1989-05-11 | 1991-10-25 | Convertech Group Ltd | Two stage process and equipment for the steam hydrolysis of woody material |
US5071447A (en) | 1989-10-31 | 1991-12-10 | K-Fuel Partnership | Apparatus and process for steam treating carbonaceous material |
RU2046821C1 (en) * | 1992-08-12 | 1995-10-27 | Научно-технический и производственно-внедренческий центр "ТОКЕМА" | Method of making fuel briquet from wood waste |
CN1078607C (en) | 1995-08-09 | 2002-01-30 | Kfx公司 | Method and apparatus for reducing by-products content in carbonaceous materials |
US6387221B1 (en) | 1998-06-25 | 2002-05-14 | James D. Schoenhard | Processing method and system to convert garbage to oil |
US6273923B1 (en) | 1999-01-25 | 2001-08-14 | Kenaf Biocatalytic Services, Llc | Catalytic vacuum distillation process |
RU2191799C2 (en) * | 2000-08-14 | 2002-10-27 | Открытое акционерное общество Алтайский научно-исследовательский институт технологии машиностроения | Method of briquetting ligno-containing materials and complex of means for method embodiment |
AU9348601A (en) | 2000-09-26 | 2002-04-08 | Tech Resources Pty Ltd | Upgrading solid material |
NZ515288A (en) | 2001-11-06 | 2003-07-25 | Lignotech Developments Ltd | Processing of ligno-cellulose materials with steam in a pressure vessel |
US6818027B2 (en) * | 2003-02-06 | 2004-11-16 | Ecoem, L.L.C. | Organically clean biomass fuel |
DE10322228A1 (en) * | 2003-05-18 | 2004-12-09 | Dieffenbacher Gmbh + Co. Kg | Process for the production of compacts |
NZ529640A (en) | 2003-11-19 | 2006-09-29 | Mattersmiths Holdings Ltd | Method of removing moisture from a lignocellulosic substrate such as wood |
US7198655B2 (en) | 2004-05-03 | 2007-04-03 | Evergreen Energy Inc. | Method and apparatus for thermally upgrading carbonaceous materials |
NO320971L (en) * | 2004-07-08 | 2006-02-20 | Norsk Pellets Vestmarka As | Process for preparing fuel pellets |
JP4468123B2 (en) * | 2004-09-22 | 2010-05-26 | 栗田工業株式会社 | Method and apparatus for treating organic waste |
US7198925B2 (en) * | 2004-09-30 | 2007-04-03 | Iogen Energy Corporation | Pre-treatment of bales of feedstock |
WO2006077652A1 (en) * | 2005-01-24 | 2006-07-27 | Osaka Industrial Promotion Organization | Woody biomas solid fuel and method for production thereof |
EP2573154B1 (en) | 2005-04-29 | 2019-07-24 | Altaca Insaat ve Dis Ticaret A.S. | Apparatus for converting organic material |
CN101218329B (en) * | 2005-05-16 | 2012-10-03 | 常绿生物燃料公司 | Agricultural fibre fuel pellets |
US7824523B2 (en) | 2005-05-17 | 2010-11-02 | Earthfirst Technologies, Inc. | Catalytically activated vacuum distillation system |
JP2007153684A (en) * | 2005-12-06 | 2007-06-21 | Met:Kk | Activated carbon and method for manufacturing pellet |
EP2032675B1 (en) | 2006-05-05 | 2018-02-28 | Inaeris Technologies, LLC | Improved process for converting carbon-based energy carrier material |
US20080277082A1 (en) | 2007-05-07 | 2008-11-13 | Andritz Inc. | High pressure compressor and steam explosion pulping method |
WO2009018469A1 (en) | 2007-07-31 | 2009-02-05 | Hoffman Richard B | System and method of preparing pre-treated biorefinery feedstock from raw and recycled waste cellulosic biomass |
US20090041639A1 (en) | 2007-08-10 | 2009-02-12 | Warren Vanderpool | Waste processing system |
US20090056208A1 (en) * | 2007-08-28 | 2009-03-05 | Stephane Gauthier | Cubing machine for manufacture of plant biomass solid fuel |
CA2701949A1 (en) | 2007-10-09 | 2009-04-16 | Sunopta Bioprocess Inc. | Two-stage enzymatic hydrolysis process for treating lignocellulosic materials |
US8057639B2 (en) | 2008-02-28 | 2011-11-15 | Andritz Inc. | System and method for preextraction of hemicellulose through using a continuous prehydrolysis and steam explosion pretreatment process |
US7931784B2 (en) | 2008-04-30 | 2011-04-26 | Xyleco, Inc. | Processing biomass and petroleum containing materials |
US8021445B2 (en) | 2008-07-09 | 2011-09-20 | Skye Energy Holdings, Inc. | Upgrading carbonaceous materials |
AT507261B1 (en) * | 2008-09-11 | 2010-09-15 | Siemens Vai Metals Tech Gmbh | PROCESS FOR THE PREPARATION OF AGGLOMERATES |
CN101824347A (en) * | 2009-03-06 | 2010-09-08 | 北京泛欧瑞德科技有限公司 | Biomass composite granular fuel, and manufacturing method and device thereof |
-
2009
- 2009-10-05 BR BRPI0923508A patent/BRPI0923508A8/en not_active Application Discontinuation
- 2009-10-05 KR KR1020157002909A patent/KR101526840B1/en active IP Right Grant
- 2009-10-05 CN CN2009801506183A patent/CN102245748A/en active Pending
- 2009-10-05 WO PCT/NO2009/000346 patent/WO2010071440A1/en active Application Filing
- 2009-10-05 EP EP09744786.6A patent/EP2373767B1/en active Active
- 2009-10-05 AU AU2009327630A patent/AU2009327630C1/en not_active Ceased
- 2009-10-05 ES ES09744786.6T patent/ES2693144T3/en active Active
- 2009-10-05 LT LTEP09744786.6T patent/LT2373767T/en unknown
- 2009-10-05 TR TR2018/15603T patent/TR201815603T4/en unknown
- 2009-10-05 KR KR1020117016388A patent/KR101525648B1/en active IP Right Grant
- 2009-10-05 PT PT09744786T patent/PT2373767T/en unknown
- 2009-10-05 CA CA2746998A patent/CA2746998C/en not_active Expired - Fee Related
- 2009-10-05 RU RU2011129312/04A patent/RU2518068C2/en active
- 2009-10-05 CN CN201611224622.8A patent/CN106929117A/en active Pending
- 2009-10-05 JP JP2011540623A patent/JP2012512270A/en active Pending
- 2009-10-05 PL PL09744786T patent/PL2373767T3/en unknown
- 2009-10-05 NZ NZ593489A patent/NZ593489A/en not_active IP Right Cessation
-
2011
- 2011-06-13 US US13/159,233 patent/US10570349B2/en active Active
- 2011-06-14 ZA ZA2011/04425A patent/ZA201104425B/en unknown
-
2014
- 2014-09-26 JP JP2014196287A patent/JP6255325B2/en not_active Expired - Fee Related
-
2016
- 2016-10-28 JP JP2016212221A patent/JP2017075318A/en active Pending
-
2017
- 2017-08-10 JP JP2017155758A patent/JP2018059051A/en active Pending
-
2020
- 2020-01-23 US US16/751,044 patent/US20200157448A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
---|
See references of WO2010071440A1 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3095654A1 (en) | 2019-05-03 | 2020-11-06 | Europeenne De Biomasse | Steam cracking control to improve the PCI of black granules |
FR3095655A1 (en) | 2019-05-03 | 2020-11-06 | Europeenne De Biomasse | Mixture of steam cracked biomass and lignin for pellet production |
WO2020225506A1 (en) * | 2019-05-03 | 2020-11-12 | Europeenne De Biomasse | Mixture of steam-cracked biomass and lignin for granule production |
WO2020225505A1 (en) * | 2019-05-03 | 2020-11-12 | Europeenne De Biomasse | Steam cracking control for improving the pci of black granules |
Also Published As
Publication number | Publication date |
---|---|
KR101526840B1 (en) | 2015-06-05 |
ZA201104425B (en) | 2012-03-28 |
EP2373767B1 (en) | 2018-07-25 |
WO2010071440A1 (en) | 2010-06-24 |
LT2373767T (en) | 2018-12-10 |
JP2014237859A (en) | 2014-12-18 |
PT2373767T (en) | 2018-11-09 |
CN102245748A (en) | 2011-11-16 |
ES2693144T3 (en) | 2018-12-07 |
KR20150023934A (en) | 2015-03-05 |
AU2009327630B2 (en) | 2014-06-26 |
CA2746998C (en) | 2016-01-19 |
PL2373767T3 (en) | 2019-03-29 |
US10570349B2 (en) | 2020-02-25 |
JP6255325B2 (en) | 2017-12-27 |
AU2009327630C1 (en) | 2015-04-16 |
JP2017075318A (en) | 2017-04-20 |
RU2011129312A (en) | 2013-01-20 |
KR101525648B1 (en) | 2015-06-03 |
TR201815603T4 (en) | 2018-11-21 |
JP2018059051A (en) | 2018-04-12 |
RU2518068C2 (en) | 2014-06-10 |
BRPI0923508A8 (en) | 2017-07-11 |
JP2012512270A (en) | 2012-05-31 |
BRPI0923508A2 (en) | 2016-01-26 |
AU2009327630A1 (en) | 2011-07-07 |
NZ593489A (en) | 2013-09-27 |
KR20110094347A (en) | 2011-08-23 |
CA2746998A1 (en) | 2010-06-24 |
US20200157448A1 (en) | 2020-05-21 |
CN106929117A (en) | 2017-07-07 |
US20110302832A1 (en) | 2011-12-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20200157448A1 (en) | Method for the production of pellets or briquettes | |
EP2580307B1 (en) | Methods for the manufacture of fuel pellets and other products from lignocellulosic biomass | |
Samson et al. | Assessment of pelletized biofuels | |
Ibitoye et al. | Densification of agro-residues for sustainable energy generation: an overview | |
JP2019502013A (en) | Biofuel | |
US20160002554A1 (en) | Systems and methods of forming densified biomass | |
Varnero et al. | Power form agripellets | |
Talero et al. | Use of Colombian oil palm wastes for pellets production: reduction of the process energy consumption by modifying moisture content | |
Lestander | Pellet and briquette production | |
Sokhansanj et al. | Steam Treatment of Cellulosic Biomass for Pelletization | |
WO2019220808A1 (en) | Method for producing brown coal-containing coke | |
NO20141130L (en) | Process of producing pellets and briquettes | |
NO335883B1 (en) | Process for making wood pellets and briquettes | |
NO327839B1 (en) | Method of producing wood pellets and pellets thereof | |
CZ30771U1 (en) | A shaped fuel based on a mixture of biomass and coal dust | |
Warajanont et al. | Biomass Pellet |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20110708 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR |
|
DAX | Request for extension of the european patent (deleted) | ||
17Q | First examination report despatched |
Effective date: 20120417 |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: ZILKHA BIOMASS FUELS I LLC |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: ZILKHA BIOMASS TECHNOLOGIES LLC |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: C10L 5/36 20060101ALI20171208BHEP Ipc: C10L 9/08 20060101ALI20171208BHEP Ipc: C10L 5/44 20060101AFI20171208BHEP |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20180206 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1021773 Country of ref document: AT Kind code of ref document: T Effective date: 20180815 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602009053442 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: RO Ref legal event code: EPE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: FP |
|
REG | Reference to a national code |
Ref country code: PT Ref legal event code: SC4A Ref document number: 2373767 Country of ref document: PT Date of ref document: 20181109 Kind code of ref document: T Free format text: AVAILABILITY OF NATIONAL TRANSLATION Effective date: 20181022 |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2693144 Country of ref document: ES Kind code of ref document: T3 Effective date: 20181207 |
|
REG | Reference to a national code |
Ref country code: NO Ref legal event code: T2 Effective date: 20180725 |
|
REG | Reference to a national code |
Ref country code: EE Ref legal event code: FG4A Ref document number: E016293 Country of ref document: EE Effective date: 20181023 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181125 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181025 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181026 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180725 |
|
REG | Reference to a national code |
Ref country code: SK Ref legal event code: T3 Ref document number: E 28879 Country of ref document: SK |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602009053442 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180725 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180725 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181005 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180725 |
|
26N | No opposition filed |
Effective date: 20190426 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180725 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181031 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181005 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20091005 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180725 Ref country code: MK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180725 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: UEP Ref document number: 1021773 Country of ref document: AT Kind code of ref document: T Effective date: 20180725 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: TR Payment date: 20201005 Year of fee payment: 12 Ref country code: NL Payment date: 20201021 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: LT Payment date: 20201001 Year of fee payment: 12 Ref country code: PT Payment date: 20201005 Year of fee payment: 12 Ref country code: GB Payment date: 20201008 Year of fee payment: 12 Ref country code: ES Payment date: 20201116 Year of fee payment: 12 Ref country code: FI Payment date: 20201001 Year of fee payment: 12 Ref country code: EE Payment date: 20201001 Year of fee payment: 12 Ref country code: AT Payment date: 20201021 Year of fee payment: 12 Ref country code: FR Payment date: 20201020 Year of fee payment: 12 Ref country code: CZ Payment date: 20201005 Year of fee payment: 12 Ref country code: NO Payment date: 20201005 Year of fee payment: 12 Ref country code: DE Payment date: 20201026 Year of fee payment: 12 Ref country code: IE Payment date: 20201008 Year of fee payment: 12 Ref country code: SE Payment date: 20201030 Year of fee payment: 12 Ref country code: RO Payment date: 20201002 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SK Payment date: 20201001 Year of fee payment: 12 Ref country code: PL Payment date: 20201002 Year of fee payment: 12 Ref country code: BE Payment date: 20201028 Year of fee payment: 12 Ref country code: LV Payment date: 20201001 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20201021 Year of fee payment: 12 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MM4D Effective date: 20211005 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 602009053442 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: EE Ref legal event code: MM4A Ref document number: E016293 Country of ref document: EE Effective date: 20211031 |
|
REG | Reference to a national code |
Ref country code: NO Ref legal event code: MMEP |
|
REG | Reference to a national code |
Ref country code: FI Ref legal event code: MAE |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: EUG |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CZ Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211005 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MM Effective date: 20211101 |
|
REG | Reference to a national code |
Ref country code: SK Ref legal event code: MM4A Ref document number: E 28879 Country of ref document: SK Effective date: 20211005 Ref country code: AT Ref legal event code: MM01 Ref document number: 1021773 Country of ref document: AT Kind code of ref document: T Effective date: 20211005 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20211031 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20211005 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211005 Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211006 Ref country code: RO Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211005 Ref country code: PT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20220405 Ref country code: NO Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211031 Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211101 Ref country code: LT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211005 Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211005 Ref country code: EE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211031 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20220503 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211005 Ref country code: FI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211005 Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211005 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211005 Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211005 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20230214 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211006 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211005 |