EP2352413A1 - Method for operating a dishwasher - Google Patents
Method for operating a dishwasherInfo
- Publication number
- EP2352413A1 EP2352413A1 EP09736941A EP09736941A EP2352413A1 EP 2352413 A1 EP2352413 A1 EP 2352413A1 EP 09736941 A EP09736941 A EP 09736941A EP 09736941 A EP09736941 A EP 09736941A EP 2352413 A1 EP2352413 A1 EP 2352413A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- dishwasher
- desorption
- program step
- desorption process
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 40
- 238000001035 drying Methods 0.000 claims abstract description 53
- 238000003795 desorption Methods 0.000 claims abstract description 44
- 239000000463 material Substances 0.000 claims abstract description 25
- 238000001179 sorption measurement Methods 0.000 claims abstract description 19
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 6
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000010457 zeolite Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 61
- 239000007788 liquid Substances 0.000 claims description 45
- 238000004140 cleaning Methods 0.000 claims description 32
- 238000010438 heat treatment Methods 0.000 claims description 31
- 230000000694 effects Effects 0.000 claims description 12
- 239000003599 detergent Substances 0.000 claims description 8
- 238000001514 detection method Methods 0.000 claims description 4
- 238000011156 evaluation Methods 0.000 claims description 4
- 239000013505 freshwater Substances 0.000 claims description 3
- 239000007921 spray Substances 0.000 description 8
- 239000002594 sorbent Substances 0.000 description 7
- 238000001816 cooling Methods 0.000 description 6
- 239000002274 desiccant Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L15/00—Washing or rinsing machines for crockery or tableware
- A47L15/0018—Controlling processes, i.e. processes to control the operation of the machine characterised by the purpose or target of the control
- A47L15/0021—Regulation of operational steps within the washing processes, e.g. optimisation or improvement of operational steps depending from the detergent nature or from the condition of the crockery
- A47L15/0042—Desorption phases of reversibly dehydrogenated drying material, e.g. zeolite in a sorption drying system
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L15/00—Washing or rinsing machines for crockery or tableware
- A47L15/42—Details
- A47L15/48—Drying arrangements
- A47L15/481—Drying arrangements by using water absorbent materials, e.g. Zeolith
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L15/00—Washing or rinsing machines for crockery or tableware
- A47L15/0002—Washing processes, i.e. machine working principles characterised by phases or operational steps
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L2401/00—Automatic detection in controlling methods of washing or rinsing machines for crockery or tableware, e.g. information provided by sensors entered into controlling devices
- A47L2401/12—Water temperature
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L2401/00—Automatic detection in controlling methods of washing or rinsing machines for crockery or tableware, e.g. information provided by sensors entered into controlling devices
- A47L2401/18—Air temperature
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L2501/00—Output in controlling method of washing or rinsing machines for crockery or tableware, i.e. quantities or components controlled, or actions performed by the controlling device executing the controlling method
- A47L2501/11—Air heaters
Definitions
- the invention relates to a method for operating a dishwasher, in particular a domestic dishwasher according to the preamble of patent claim 1.
- the reversibly dehydratable drying material is heated to very high temperatures, whereby water stored in this drying material emerges as hot water vapor and is conducted into the rinsing container by means of an airflow generated by the fan a washware in the rinse tank and the air in the rinse tank are heated,
- a sorption drying system has proven to be energy-saving and quiet drying of the dishes proved to be very beneficial.
- the object of the invention is to achieve a further improved desorption result for the reversibly dehydratable drying material of the sorption drying apparatus.
- the invention is based on a method for operating a dishwasher, in particular a domestic dishwasher, with a sorption drying system in which a desorption process of a reversibly dehydratable dry material, in particular zeolite, is effected at least temporarily.
- parameters influencing the desorption process are evaluated for determining the time for carrying out the desorption.
- the air temperature in the dishwasher and / or the water inlet temperature are detected as parameters.
- the air temperature in the dishwasher depends on room temperature in the vicinity of the dishwasher. However, the air temperature can also deviate greatly from the room temperature, if shortly before a Spülprogrammlauf took place without it could come to a cooling of the dishwasher. If only the air temperature or water inlet temperature is detected, the determination of the time for performing the desorption can be made on the basis of stored values, e.g. in tabular form. In this case, the degree of cooling is determined by the water inlet temperature by refilling with liquid, in particular with water from a home-side supply system.
- both the air and the water inlet temperature are detected, a comparison with stored values can also be made and / or the difference of the two temperatures is evaluated and the time of desorption is determined. The difference between these two temperature values is therefore a measure for determining how strong the temperature in the interior of the dishwasher will fall below the starting temperature.
- the detection of the room temperature can also be provided alone or together with the water inlet temperature at the installation site of the dishwasher.
- a desorption process is carried out at least partially during a first program step during which the heating means of the dishwasher are operated when the air temperature is higher than the water inlet temperature by a predetermined temperature value at the most.
- the heating means may be an air heater, can be erwakbar with the air, which is driven by the drying material.
- no excessive cooling is to be expected by refilling with liquid, so that a Desortionsvorgang is performed in the first program step in which a heating of liquid takes place, such as the program step cleaning or the program step pre-wash, if a particularly intensive cleaning is desired.
- a desorption process is carried out at least partially during a program step in which heating means are operated after an at least partial liquid change when the air temperature is higher than the water inlet temperature by at least a predetermined temperature value.
- heating means are operated after an at least partial liquid change when the air temperature is higher than the water inlet temperature by at least a predetermined temperature value.
- the predetermined temperature value is selected substantially between 3 to 30 0 C, in particular between 5 and 15 ° C. This ensures that only in the case of large temperature differences does the time of the desorption process be postponed, in which due to the high starting temperature no complete and efficient desorption is to be expected.
- the desorption process is carried out at least partially during a program step cleaning with detergent addition and cleaning action. This allows a particularly energy-efficient cleaning of items to be washed.
- the desorption process is carried out at least partially during a pre-rinse program step without cleaning agent addition.
- the cleaning effect during the program step of pre-rinsing and thus of the rinsing program can be increased.
- the desorption process is carried out at least partially during a program rinse with rinse aid addition.
- the drying effect during the subsequent program step drying can be increased or the duration of the program step drying can be reduced.
- a quantity of liquid, in particular a quantity of fresh water from a home-side water supply system is cached.
- the water tank is at the end of a Rinsing program run filled, so that in the meantime, until the next start of a Spellerprogramm takeanks cached in the water tank amount of water from the inlet water temperature of eg 15 ° C can warm to room temperature.
- This liquid heated to room temperature is used in a rinse cycle to perform the rinse program step of pre-rinse.
- a renewed filling with water from the water supply system causes a corresponding cooling below the room temperature.
- a dishwasher in particular a domestic dishwasher, which is formed at least partially in at least one program step of a plurality of program steps
- detection means for detecting environmental parameters at the site of the dishwasher and evaluation means for determining the time for
- FIG. 1 is a schematic representation of an embodiment of a dishwasher according to the invention with a sorption drying system
- FIG. 2 shows a schematic representation of the temperature profile during a first embodiment of a rinsing program run according to the invention
- FIG. 3 shows a schematic representation of the temperature profile of a further, second exemplary embodiment of a rinsing program run according to the invention.
- FIG. 4 is a schematic representation of the temperature profile of a further, third exemplary embodiment of a rinsing program run according to the invention. Reference is first made to FIG.
- a dishwasher GS designed in the present exemplary embodiment as a domestic dishwasher has an interior space IR serving as a washing container, which can be opened or closed for loading and unloading by means of a door (not shown) pivotably hinged to the dishwasher GS.
- Interior IR of the dishwasher GS dish baskets GK are provided for receiving items to be cleaned, which can be pulled out of the interior IR of the dishwasher GS to facilitate loading and unloading.
- means for supplying items to be washed with liquid are provided in the interior IR of the dishwasher GS as spraying arms SA, wherein the liquid may, for example, be filled with water. can act with detergents or with rinse aid added water, so as to effect a cleaning effect or streak-free drying.
- the liquid flowing down from the items to be washed collects in a pump sump PS, which is arranged in the bottom area of the interior IR of the dishwasher GS.
- the spray arms SA are fluidly connected via a supply line ZL with a circulation pump UP, which is arranged in a floor assembly BO below the interior IR of the dishwasher GS, among other components components of the dishwasher.
- a circulation pump UP In operation, i. when the circulation pump UP is running, the circulation pump UP sucks the liquid accumulated in the pump sump PS and delivers it through the supply line ZL to the spray arms SA.
- the circulating pump In order to heat the liquid circulated by the operation of the circulating pump UP, the circulating pump has an integrated water heater WZ for heating the liquid.
- a separate instantaneous water heater or another water heater may be provided for emptying the interior IR of the dishwasher GS.
- a drain pump LP For emptying the interior IR of the dishwasher GS, a drain pump LP is provided, which is also in fluid-conducting connection with the pump sump PS and can be connected to a disposal line EL to a house-side sewage disposal network.
- the dishwasher GS has a Sorptionstrockungssystem, with the arranged in the baskets GR and cleaned items at the end of a Rinse program run can be dried.
- a sorption SB is provided in the bottom assembly BO, which is air-conductively connected via an air duct LK with an inlet El, wherein for generating a forced flow, a fan LT is provided.
- an outlet opening AU is provided in the bottom area of the interior IR dishwasher GS.
- Dishwasher GS passed. In order to dry the circulating air is in the
- Sorption SB a drying agent for performing an exothermic drying provided. It is a reversibly dehydratable drying material, e.g. Zeolite, which absorbs water due to its hydroscopic property, at the same time heat energy is released. This released heat energy becomes a
- Drying process is an amount of liquid stored in the drying material ZEO.
- an air heater HZ is provided, which is arranged in the present embodiment in the sorption SB.
- an air heater outside the sorbent tank SB e.g. in the air passage LK to cause heating of the conveyed into the sorbent SB air.
- an air flow generated by the fan LT is heated, so that the drying material ZEO can be heated to temperatures at which the amount of water stored in the drying material ZEO can be released again.
- Dishwashers GS continuous for cleaning and drying of items to be cleaned, wash programs, which consist of a plurality of program steps, which are passed through successively.
- a program can from the Program steps pre-rinse V, cleaning R, intermediate rinsing Z, rinsing K and drying T exist, with individual program steps, such.
- the pre-rinsing V or intermediate rinsing Z can also be hidden, while it is also conceivable to pass through individual program steps repeatedly, such as the intermediate rinsing Z.
- Wash ware is charged with water without the addition of detergents, this either with unheated water or with heated water by means of a heater.
- water can be used that has been stored in a water tank (not shown).
- a water tank can be in heat-conducting connection with the environment of the dishwasher, so that liquid stored in the water tank, such as water from a home-side supply system, can warm up to room temperature.
- cleaning step R cleaning of items to be washed takes place by application of detergent-added water, ie during the cleaning stage, a detergent is added. Furthermore, a heating of the liquid, so as to increase the cleaning effect of the cleaning agent.
- the cleaning step R is composed of a heating phase P1, P2, in which the liquid is heated in the dishwasher GS by means of heating until a predetermined maximum temperature is reached and a subsequent Nachwaschphase together, while the heater is turned off, the slowly cooling liquid by the circulating pump UP is circulated.
- the intermediate rinse Z program step liquid is applied to the items to be washed in order to convey dirt residues from the dishwasher GS.
- the next step in the program is rinsing K in preparation for the program step drying T, in which water mixed with rinse aid is circulated by means of the circulation pump and applied to the now cleaned items via the spray arms SA.
- the program step drying T in which the ware is no longer charged with liquid, but by operation of the fan LT through the interior IR of the dishwasher GS and the sorbent SB circulating air flow is generated.
- a complete or at least partial fluid change can be carried out between the individual program steps, ie the dishwasher GS is emptied by means of the drain pump LP and the disposal line EL and refilled again by a supply line (not shown) making a connection to a house-side supply system.
- heating of liquid takes place only in the program step cleaning R.
- the liquid circulated by the circulation pump UP is transmitted through heated air heater HZ in the sorption SB to a maximum temperature T1, wherein at the same time the fan LT generates a circulating through the interior IR of the dishwasher GS air flow.
- the air heater HZ heats the drying material ZEO into the sorption container SB to temperatures at which the amount of water stored in the drying material ZEO is expelled from the drying material ZEO and conveyed through the outlet opening AU into the interior IR dishwasher GS.
- the blow-out opening AU is cooled in the interior IR dishwasher GS, so as to ensure that due to the heating power of the air heater HZ no excessive heating of the blow-out opening HZ with overheating damage occurs.
- the circulation pump UP is operated so that liquid is conveyed by the circulation pump from the pump sump PS through the supply line to the spray arm SA.
- the spray arms SA are set in rotation and cause by spraying the exhaust opening AU, in particular a cap covering the discharge opening AU with liquid, a cooling thereof.
- the amount of liquid is heated from the first temperature T1 to the second temperature T2 by means of the water heater WZ.
- the rotational speed of the circulation pump UP to increase the spray pressure of the water jets emerging from the spray arm SA.
- the amount of liquid circulated by the circulation pump UP increased by a refilling step, for example, at time t1 (see Figure 2) and then increases the speed of the circulation pump UP, e.g. continuously until the recirculation pump runs under run-flat condition, i.e., does not draw in air bubbles during operation, which reduces the delivery rate of the recirculation pump UP and results in undesirable noise.
- This makes it possible to take into account the amount of liquid released during the desorbing, which was stored in the drying material ZEO, in the dimensioning of the amount of liquid to be replenished and thus to reduce the total water requirement with improved cleaning performance.
- Liquid i. with rinse aid added water, can drain from the dishes due to gravity and in the pump sump PS of the interior of the IR
- Dishwasher GS can collect. As a result, the of the
- Sorption drying system reduces the amount of liquid to be absorbed and thus the duration of the program step drying T.
- liquid is heated in the first of the program steps, the pre-rinsing program step V.
- liquid is heated from a starting temperature TO during a phase PV to a temperature TV by means of the air heating HZ, as described above by means of the fan LT a circulating through the interior IR of the dishwasher GS and the sorbent SB air flow is generated.
- the air heater HZ is deactivated.
- the drying material ZEO is not yet completely desorbed, i. in the drying material ZEO a residual amount of water is stored.
- the liquid is heated by the air heater HZ to a temperature T1 in the subsequent program step cleaning R and then by operating the Water heating to the temperature T2 heated.
- the desorption phase of the drying agent ZEO in the sorption container SB is divided into two in this exemplary embodiment and is distributed over two program steps, namely the preprocessing program step V and the program step cleaning R.
- a further phase P3 (see FIG. 3) can be provided, while the water heater WZ is used to further heat the liquid to a temperature T3.
- the liquid is heated during the rinsing step K.
- the water heater WZ liquid which is water or water mixed with rinse aid
- T4 is heated to a temperature T4.
- the water heating and the air heater HZ be used to complete, for example, a previously not complete in the course of the program desorption.
- another phase P5 further heating of the liquid to a Temperature T5 done to improve drying with the sorption drying system.
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL09736941T PL2352413T3 (en) | 2008-11-07 | 2009-10-16 | Method for operating a dishwasher |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008043576A DE102008043576A1 (en) | 2008-11-07 | 2008-11-07 | Method for operating a dishwasher |
PCT/EP2009/063601 WO2010052116A1 (en) | 2008-11-07 | 2009-10-16 | Method for operating a dishwasher |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2352413A1 true EP2352413A1 (en) | 2011-08-10 |
EP2352413B1 EP2352413B1 (en) | 2012-09-05 |
Family
ID=41343319
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09736941A Active EP2352413B1 (en) | 2008-11-07 | 2009-10-16 | Method for operating a dishwasher |
Country Status (8)
Country | Link |
---|---|
US (1) | US9955845B2 (en) |
EP (1) | EP2352413B1 (en) |
CN (1) | CN102209484B (en) |
DE (1) | DE102008043576A1 (en) |
ES (1) | ES2391249T3 (en) |
PL (1) | PL2352413T3 (en) |
RU (1) | RU2505263C2 (en) |
WO (1) | WO2010052116A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5445566B2 (en) * | 2011-11-29 | 2014-03-19 | パナソニック株式会社 | dishwasher |
DE102012013322A1 (en) | 2012-07-06 | 2014-01-09 | Eichenauer Heizelemente Gmbh & Co. Kg | dishwasher |
DE102013101673A1 (en) | 2013-02-20 | 2014-08-21 | Miele & Cie. Kg | Dishwasher and method for operating a dishwasher |
IT201700078567A1 (en) * | 2017-07-13 | 2019-01-13 | Candy Spa | Method for automatically evaluating the movement of an object within a washing area of a dishwasher machine. |
DE102021207644A1 (en) * | 2021-07-19 | 2023-01-19 | BSH Hausgeräte GmbH | Household dishwashing machine with a sorption drying system and associated method for carrying out an energy-saving dishwashing program |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1144692A (en) * | 1965-03-12 | 1969-03-05 | Pall Corp | Gas drier with automatic cycle control and process |
US8293024B2 (en) * | 2003-07-30 | 2012-10-23 | Bsh Bosch Und Siemens Hausgeraete Gmbh | Dishwasher |
DE10353774A1 (en) * | 2003-07-30 | 2005-02-24 | BSH Bosch und Siemens Hausgeräte GmbH | Drying items in domestic dish washing machines has a reversible hydroscopic material filled column through which recirculated air is driven by a fan |
DE10353775A1 (en) | 2003-07-30 | 2005-02-24 | BSH Bosch und Siemens Hausgeräte GmbH | Drying items in domestic process machines has reversible hydroscopic material filled column through which recirculated air is driven by fan |
DE10356787A1 (en) | 2003-12-04 | 2005-07-07 | BSH Bosch und Siemens Hausgeräte GmbH | dishwasher |
JP2006020753A (en) * | 2004-07-07 | 2006-01-26 | Matsushita Electric Ind Co Ltd | Dishwasher |
DE102004057019A1 (en) * | 2004-11-25 | 2006-06-01 | BSH Bosch und Siemens Hausgeräte GmbH | Water-bearing household appliance with a storage container |
CN200951070Y (en) * | 2004-12-09 | 2007-09-26 | Bsh博施及西门子家用器具有限公司 | Dish-washing machine |
DE102005004097A1 (en) * | 2004-12-09 | 2006-06-14 | BSH Bosch und Siemens Hausgeräte GmbH | Dishwasher and method of operating the same |
DE102005004096A1 (en) | 2004-12-09 | 2006-06-14 | BSH Bosch und Siemens Hausgeräte GmbH | Dishwasher with a Sorptionstrockenvorrichtung |
DE102007017284B3 (en) * | 2007-04-12 | 2008-11-13 | BSH Bosch und Siemens Hausgeräte GmbH | Temperature detection with zeolite drying |
-
2008
- 2008-11-07 DE DE102008043576A patent/DE102008043576A1/en not_active Withdrawn
-
2009
- 2009-10-16 WO PCT/EP2009/063601 patent/WO2010052116A1/en active Application Filing
- 2009-10-16 ES ES09736941T patent/ES2391249T3/en active Active
- 2009-10-16 EP EP09736941A patent/EP2352413B1/en active Active
- 2009-10-16 RU RU2011119250/12A patent/RU2505263C2/en active
- 2009-10-16 US US13/126,481 patent/US9955845B2/en active Active
- 2009-10-16 PL PL09736941T patent/PL2352413T3/en unknown
- 2009-10-16 CN CN200980144506.7A patent/CN102209484B/en active Active
Non-Patent Citations (1)
Title |
---|
See references of WO2010052116A1 * |
Also Published As
Publication number | Publication date |
---|---|
EP2352413B1 (en) | 2012-09-05 |
US9955845B2 (en) | 2018-05-01 |
US20110203614A1 (en) | 2011-08-25 |
PL2352413T3 (en) | 2013-02-28 |
RU2505263C2 (en) | 2014-01-27 |
ES2391249T3 (en) | 2012-11-22 |
WO2010052116A1 (en) | 2010-05-14 |
CN102209484B (en) | 2014-11-12 |
DE102008043576A1 (en) | 2010-05-12 |
CN102209484A (en) | 2011-10-05 |
RU2011119250A (en) | 2012-12-20 |
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