EP2340318A1 - Copper-tin alloy, composite material and use thereof - Google Patents
Copper-tin alloy, composite material and use thereofInfo
- Publication number
- EP2340318A1 EP2340318A1 EP09744964A EP09744964A EP2340318A1 EP 2340318 A1 EP2340318 A1 EP 2340318A1 EP 09744964 A EP09744964 A EP 09744964A EP 09744964 A EP09744964 A EP 09744964A EP 2340318 A1 EP2340318 A1 EP 2340318A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- copper
- alloy
- tin
- weight
- tin alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical class [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 239000002131 composite material Substances 0.000 title claims abstract description 23
- 229910052718 tin Inorganic materials 0.000 claims abstract description 36
- 239000000463 material Substances 0.000 claims abstract description 21
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 18
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 11
- 229910052742 iron Inorganic materials 0.000 claims abstract description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 31
- 230000007704 transition Effects 0.000 claims description 9
- 229910052802 copper Inorganic materials 0.000 claims description 8
- 239000011888 foil Substances 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 abstract description 55
- 239000000956 alloy Substances 0.000 abstract description 55
- 229910052725 zinc Inorganic materials 0.000 abstract description 10
- 230000000704 physical effect Effects 0.000 abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 18
- 229910017755 Cu-Sn Inorganic materials 0.000 description 12
- 229910017927 Cu—Sn Inorganic materials 0.000 description 12
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 12
- 239000010949 copper Substances 0.000 description 11
- 239000011574 phosphorus Substances 0.000 description 11
- 239000011701 zinc Substances 0.000 description 9
- 238000005260 corrosion Methods 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 6
- 229910017518 Cu Zn Inorganic materials 0.000 description 5
- 229910017752 Cu-Zn Inorganic materials 0.000 description 5
- 229910017943 Cu—Zn Inorganic materials 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 5
- 239000010941 cobalt Substances 0.000 description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 5
- 238000005275 alloying Methods 0.000 description 4
- 229910001369 Brass Inorganic materials 0.000 description 3
- 229910000881 Cu alloy Inorganic materials 0.000 description 3
- 238000003723 Smelting Methods 0.000 description 3
- 239000010951 brass Substances 0.000 description 3
- 238000004870 electrical engineering Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- 229910002535 CuZn Inorganic materials 0.000 description 2
- 229910017827 Cu—Fe Inorganic materials 0.000 description 2
- 229910000640 Fe alloy Inorganic materials 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- IYRDVAUFQZOLSB-UHFFFAOYSA-N copper iron Chemical compound [Fe].[Cu] IYRDVAUFQZOLSB-UHFFFAOYSA-N 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910001096 P alloy Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- -1 nickel and chromium Chemical compound 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/02—Alloys based on copper with tin as the next major constituent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12389—All metal or with adjacent metals having variation in thickness
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12708—Sn-base component
- Y10T428/12715—Next to Group IB metal-base component
Definitions
- the invention relates to a copper-tin alloy, a composite material with such a copper-tin alloy and a use of the copper-tin alloy and the composite material.
- the copper-tin alloy and the composite material comprising it are particularly suitable for connection elements in electrical engineering and in electronics.
- the invention is particularly concerned with the problem of recyclability.
- copper alloys based on Cu-Zn, Cu-Sn and Cu-Fe are widely used today for connecting elements in electrical engineering and in electronics.
- copper alloys are used for lead frames and connectors.
- Important criteria for the selection of materials are modulus of elasticity, yield strength, relaxation behavior and bendability.
- the electrical conductivity and the corrosion resistance are important criteria for the reliable function of the components over the lifetime of the overall system. Often there is an overlap of property requirements, which in principle preclude each other, such as the combination a good conductivity with high corrosion resistance.
- alloying elements in copper, such as nickel and chromium on the one hand improve the corrosion resistance, on the other hand they considerably reduce the conductivity.
- Cu-Zn or brass alloys are solid solution hardening materials. They are binary alloys, which usually contain between 5 and 40 wt .-% of zinc. With increasing zinc content, tensile strength and hardness increase. The elongation reaches a maximum at 30% by weight of zinc. Higher strength and hardness values can only be achieved by cold forming.
- the disadvantage of the Cu-Zn alloys lies in the relatively poor weldability, because the alloying element zinc has a relatively high vapor pressure. Pure zinc boiling at 1, 013 bar already at 907 0 C.
- Cu-Zn alloys have a low elastic modulus of about 110 KN / mm 2 (Sl unit: GPa) on.
- tinned brass bands can not be recycled well due to the tin included for corrosion protection reasons.
- the relaxation behavior of Cu-Zn alloys is also pronounced, limiting the operating temperature.
- Cu-Sn alloys ie tin bronzes
- the Cu-Sn alloys are usually added some phosphorus, which is why these alloys are also referred to as phosphorus bronzes.
- the properties of these alloys are determined primarily by the tin content, which is usually between 4 and 8 wt .-%.
- the modulus of elasticity of phosphorus bronzes is between 115 and 120 kN / mm 2 (SI unit: GPa).
- the bendability of tin bronzes is excellent. Rising Sn levels improve the flexibility for a given temper.
- Cu-Sn alloys are used in the form of bands for stamped parts and connectors, if a good to very good spring characteristic, a good electrical cal and thermal resistance, low stress relaxation, good flexibility, good weldability and solderability are required. Even in tinned form, phosphorus bronzes are easy to recycle. Tin is already included in the alloy as such.
- the low-alloyed copper materials include the Cu-Fe alloys.
- the material property of pure copper e.g. the strength, the softening or relaxation behavior can be improved.
- a CuFe2P alloy in the tempering stage FH is widely used for stamped grids in automotive engineering.
- the sharp-edged bendability is still present.
- the modulus of elasticity is about 125 KN / mm 2 (GPa) and thus the material has good spring properties.
- the electrical conductivity is between 60% and 70% IACS (International Annealed Copper Standard: 100% IACS equals about 58 MS / m). A tinning of the material for corrosion protection reasons is well possible.
- the electrical conductivity of a CuFe2P alloy is reduced by 25% upon reflow by a dissolving tin of about 1% by weight.
- the tinned punching scrap which usually make up 50% to 70% of the material used in the manufacture of stamped laths, can not be returned directly to the melting process, but rather must be smelted and electrochemically separated. The return to the material cycle is therefore as a cathode. This process is very energy intensive and thus very expensive compared to the direct melting of the scraps.
- the object of the invention is to specify an alloy and a composite material whose physical and technological properties are as close as possible to that of a CuFe2P alloy, which are laser-weldable as well as possible and can be readily recycled. Another task is a
- the above object is achieved by a copper-tin alloy having the composition according to claim 1.
- the copper-tin alloy comprises 0.2 to 0.8% by weight of tin (Sn), 0.1 to 0.6% by weight of nickel (Ni) and / or cobalt (Co), 0 to 0.05% by weight of zinc (Zn), 0 to 0.02% by weight of iron (Fe), 0.008 to 0.05% by weight of phosphorus (P) and the remainder copper (Cu).
- the invention is based on the idea of specifying an alternative to the CuFe2P alloy, new alloy, which has comparable properties, but can be easily recycled even in tinned state. Pure Cu-Sn alloys, such as a CuSnO, 15 alloy, undoubtedly have the potential to be used as such an alternative.
- the scrap of such an alloy can be fed directly to the recycling cycle.
- the mechanical and technological properties correspond to those of a CuFe2P alloy relatively well. Significant weaknesses occur, however, in the softening behavior and the oxidation resistance.
- a copper-tin alloy with a specific tuning of the alloying elements tin, nickel and / or cobalt and phosphorus has comparable mechanical and technological properties to a CuFe2P alloy as well as for the respective further processing and end use required property profile in the area of the softening behavior and the relaxation, ie the creep of the component under tension at elevated temperature achieved.
- It is either Nickel or cobalt with the specified content. In this case, part of the nickel is preferably replaced by cobalt, in which case the sum of the two alloying elements together gives the stated proportion.
- an alloy layer forms between the base material and the tin pad.
- the aforementioned Cu-Sn alloy exhibits a property profile comparable to the CuFe 2 P alloy in the area of the softening behavior and the relaxation. This will be apparent from FIG. There, the relaxation is plotted in percent over the temperature in 0 C. The dashed line shows the course of the CuFe2P alloy and the solid line the course of the aforementioned new Cu-Sn alloy.
- the experiments were for one Load time of 5,000 hours and an initial voltage of 65% Rp 0.2 performed.
- the new Cu-Sn alloy is further distinguished by the direct traceability of tin-coated scrap from the individual stages of the value-added chain.
- the tin-coated scrap can be returned directly to the smelting process, so that the recycling costs are significantly lower than smelting.
- the smelting costs for example, can quickly reach the level of manufacturing costs with a scrap content of 70% and put into question the economic efficiency. For this reason, consideration of the metal values between a copper-iron alloy such as the CuFe2P alloy and the Cu-Sn alloy given here does not alter the fact that the alloy given is economically and ecologically (the additional use of electricity and acid for the electrolytic treatment of the scrap can be omitted) represents a useful alternative to tinned copper-iron alloys.
- the stated copper-tin alloy contains a proportion of Sn between 0.3 and 0.7% by weight, in particular between 0.4 and 0.6% by weight
- a further advantageous adaptation of the properties can be made if the proportion of Ni and / or Co in the copper-tin alloy between 0.2 and 0.55 wt .-%, in particular between 0.3 and 0.5 wt. -% lies.
- the copper-tin alloy has 0.3 to 0.7 wt% Sn, 0.2 to 0.55 wt% Ni and / or Co, 0 to
- the copper-tin alloy is further improved when it contains 0.4 to 0.6% by weight Sn, 0.3 to 0.5% by weight Ni and / or Co, 0 to 0.03% by weight. % Zn, 0 to 0.01% by weight
- a further advantageous precise adjustment of the properties of the copper-tin alloy can be carried out if there is a total of impurities and other admixtures of at most 0.3% by weight.
- a copper-tin alloy containing 0.38 wt% Sn, 0.30 wt% Ni and / or Co, 0.003 wt% Zn 1 0.008 wt%. % Fe, 0.014 wt .-% P, and the remainder comprises Cu.
- the new copper-tin alloy is very good laser weldable, since no volatile elements are included and the alloy is free of a second phase. In particular, the alloy does not exhibit NiP precipitates.
- the alloy is ideally suited for a good laser-weldable composite material, which can be used in particular for stamped grid.
- a base material of the aforementioned copper-tin alloy is provided with a tin layer or covered, which can be made in particular by the method of hot tinning.
- a layer of pure or free tin on the base material of the specified copper-tin alloy.
- the composite is characterized by a high relaxation resistance up to temperatures of 100 0 C. It has inside the core as the specified copper-tin alloy with a composition in accordance with the then-directed claims on.
- the outer coating or tin cover ensures high corrosion resistance.
- the thickness of the tin layer is preferably between 1 and 3 ⁇ m.
- a transition layer between the base material and the tin layer is formed.
- the tin layer is preferably applied in such a way that the transition layer comprises an intermetallic phase of Cu, Ni and / or Co and Sn.
- the formation of the transition layer is in particular designed such that it has a thickness between 0.1 and 1 micron.
- the alloy of the core transitions through the transition layer into a layer of pure tin. Via the formed transition or alloy layer, a good connection of the tin layer is achieved.
- the overall result is a five-layer structure.
- On one core of the specified copper-tin alloy as a base material sits on both sides of a layer of an intermetallic phase, consisting of CuNiCoSn with a thickness between 0.1 and 1, 0 microns.
- the composite material is finally covered for corrosion protection reasons with a layer of free or pure tin, which has a thickness of 1, 0 to 3.0 microns.
- the layer composite material has a total thickness of 0.2 to 1 mm, preferably up to 2 mm, particularly preferably up to 3 mm.
- the electrical conductivity of the specified composite material corresponds to that of the previously used comparison material CuFe2P. Thermal conductivity and other technological values of the composite are also fully comparable.
- Both the specified copper-tin alloy and the tinned composite material is excellent for tapes, foils, profiled strips, stampings or
- Connector in particular for applications in electrical engineering or electronics suitable.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Conductive Materials (AREA)
- Electroplating Methods And Accessories (AREA)
- Non-Insulated Conductors (AREA)
- Contacts (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008054183 | 2008-10-31 | ||
PCT/EP2009/007669 WO2010049118A1 (en) | 2008-10-31 | 2009-10-27 | Copper-tin alloy, composite material and use thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2340318A1 true EP2340318A1 (en) | 2011-07-06 |
EP2340318B1 EP2340318B1 (en) | 2017-02-15 |
Family
ID=41508956
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09744964.9A Active EP2340318B1 (en) | 2008-10-31 | 2009-10-27 | Copper-tin alloy, composite material and use thereof |
Country Status (9)
Country | Link |
---|---|
US (1) | US20110206941A1 (en) |
EP (1) | EP2340318B1 (en) |
JP (1) | JP2012506952A (en) |
KR (1) | KR20110079638A (en) |
CN (1) | CN102177265B (en) |
BR (1) | BRPI0921441A2 (en) |
ES (1) | ES2623604T3 (en) |
RU (1) | RU2482204C2 (en) |
WO (1) | WO2010049118A1 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2738900T3 (en) | 2010-11-17 | 2020-01-27 | Luvata Appleton Llc | Alkaline collector anode |
CN102176809A (en) * | 2011-01-14 | 2011-09-07 | 中国科学院上海技术物理研究所 | Debugger for SMD (Surface Mounted Device) resistor and capacitor on PCB (printed-circuit board) |
CN102703748B (en) * | 2012-07-06 | 2013-10-16 | 山东大学 | Preparation method of nanometer porous copper tin alloy |
RU2502817C1 (en) * | 2012-12-18 | 2013-12-27 | Юлия Алексеевна Щепочкина | Copper-base alloy |
JP5773015B2 (en) | 2013-05-24 | 2015-09-02 | 三菱マテリアル株式会社 | Copper alloy wire |
JP6113674B2 (en) | 2014-02-13 | 2017-04-12 | 株式会社神戸製鋼所 | Copper alloy strip with surface coating layer with excellent heat resistance |
RU2587110C9 (en) * | 2014-09-22 | 2016-08-10 | Дмитрий Андреевич Михайлов | COPPER ALLOY, TelO DOPED WITH TELLURIUM, FOR COLLECTORS OF ELECTRIC MACHINES |
CN107034381B (en) * | 2017-04-26 | 2019-03-19 | 江西理工大学 | A kind of Cu-Ni-Co-Sn-P copper alloy and preparation method thereof |
RU2709909C1 (en) * | 2018-11-26 | 2019-12-23 | Федеральное государственное автономное образовательное учреждение высшего образования "Белгородский государственный национальный исследовательский университет" (НИУ "БелГУ") | Low-alloyed copper alloy |
CN116411202A (en) * | 2021-12-29 | 2023-07-11 | 无锡市蓝格林金属材料科技有限公司 | Copper-tin alloy wire and preparation method thereof |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5727051A (en) * | 1980-07-25 | 1982-02-13 | Nippon Telegr & Teleph Corp <Ntt> | Copper nickel tin alloy for integrated circuit conductor and its manufacture |
JPH0612796B2 (en) * | 1984-06-04 | 1994-02-16 | 株式会社日立製作所 | Semiconductor device |
JPS6379929A (en) * | 1987-08-26 | 1988-04-09 | Nippon Telegr & Teleph Corp <Ntt> | Copper-nickel-tin alloy for integrated circuit conductor and its production |
US5322575A (en) * | 1991-01-17 | 1994-06-21 | Dowa Mining Co., Ltd. | Process for production of copper base alloys and terminals using the same |
JP3550233B2 (en) * | 1995-10-09 | 2004-08-04 | 同和鉱業株式会社 | Manufacturing method of high strength and high conductivity copper base alloy |
JP3408929B2 (en) * | 1996-07-11 | 2003-05-19 | 同和鉱業株式会社 | Copper-based alloy and method for producing the same |
US6254702B1 (en) * | 1997-02-18 | 2001-07-03 | Dowa Mining Co., Ltd. | Copper base alloys and terminals using the same |
US6679956B2 (en) * | 1997-09-16 | 2004-01-20 | Waterbury Rolling Mills, Inc. | Process for making copper-tin-zinc alloys |
JP4308931B2 (en) * | 1997-11-04 | 2009-08-05 | 三菱伸銅株式会社 | Sn or Sn alloy-plated copper alloy thin plate and connector manufactured with the thin plate |
US6136104A (en) * | 1998-07-08 | 2000-10-24 | Kobe Steel, Ltd. | Copper alloy for terminals and connectors and method for making same |
RU2138573C1 (en) * | 1998-12-24 | 1999-09-27 | Мочалов Николай Алексеевич | Copper-based alloy |
DE10025106A1 (en) * | 2000-05-20 | 2001-11-22 | Stolberger Metallwerke Gmbh | Electrically conductive metal tape and connectors from it |
ATE414182T1 (en) * | 2003-03-03 | 2008-11-15 | Mitsubishi Shindo Kk | HEAT RESISTANT COPPER ALLOY MATERIALS |
EP1716732A2 (en) * | 2004-01-21 | 2006-11-02 | Enthone, Incorporated | Tin-based coating of electronic component |
JP4660735B2 (en) * | 2004-07-01 | 2011-03-30 | Dowaメタルテック株式会社 | Method for producing copper-based alloy sheet |
JP4461269B2 (en) * | 2004-09-15 | 2010-05-12 | Dowaメタルテック株式会社 | Copper alloy with improved conductivity and method for producing the same |
JP4350049B2 (en) * | 2005-02-07 | 2009-10-21 | 株式会社神戸製鋼所 | Method for producing copper alloy sheet with excellent stress relaxation resistance |
JP4959141B2 (en) * | 2005-02-28 | 2012-06-20 | Dowaホールディングス株式会社 | High strength copper alloy |
JP4887851B2 (en) * | 2005-03-17 | 2012-02-29 | Dowaメタルテック株式会社 | Ni-Sn-P copper alloy |
JP3871064B2 (en) * | 2005-06-08 | 2007-01-24 | 株式会社神戸製鋼所 | Copper alloy plate for electrical connection parts |
JP4756195B2 (en) * | 2005-07-28 | 2011-08-24 | Dowaメタルテック株式会社 | Cu-Ni-Sn-P copper alloy |
JP4439447B2 (en) * | 2005-08-03 | 2010-03-24 | 株式会社神戸製鋼所 | Manufacturing method of irregular cross-section copper alloy sheet |
JP4984108B2 (en) * | 2005-09-30 | 2012-07-25 | Dowaメタルテック株式会社 | Cu-Ni-Sn-P based copper alloy with good press punchability and method for producing the same |
JP4680765B2 (en) * | 2005-12-22 | 2011-05-11 | 株式会社神戸製鋼所 | Copper alloy with excellent stress relaxation resistance |
RU2315124C2 (en) * | 2006-01-10 | 2008-01-20 | ОАО "Каменск-Уральский завод по обработке цветных металлов" | Tin-and-zinc bronze for manufacture of wire |
JP4845747B2 (en) * | 2007-01-12 | 2011-12-28 | 株式会社神戸製鋼所 | Copper alloy material with plating for fuse and manufacturing method thereof |
KR101138569B1 (en) * | 2007-12-21 | 2012-05-10 | 미쓰비시 신도 가부시키가이샤 | High Strength and High Thermal Conductivity Copper Alloy Tube and Method for Producing The Same |
-
2009
- 2009-10-27 WO PCT/EP2009/007669 patent/WO2010049118A1/en active Application Filing
- 2009-10-27 RU RU2011121810/02A patent/RU2482204C2/en not_active IP Right Cessation
- 2009-10-27 BR BRPI0921441A patent/BRPI0921441A2/en not_active Application Discontinuation
- 2009-10-27 JP JP2011533596A patent/JP2012506952A/en active Pending
- 2009-10-27 CN CN200980139788.1A patent/CN102177265B/en not_active Expired - Fee Related
- 2009-10-27 ES ES09744964.9T patent/ES2623604T3/en active Active
- 2009-10-27 US US13/126,219 patent/US20110206941A1/en not_active Abandoned
- 2009-10-27 EP EP09744964.9A patent/EP2340318B1/en active Active
- 2009-10-27 KR KR1020117007862A patent/KR20110079638A/en not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO2010049118A1 * |
Also Published As
Publication number | Publication date |
---|---|
KR20110079638A (en) | 2011-07-07 |
CN102177265A (en) | 2011-09-07 |
WO2010049118A1 (en) | 2010-05-06 |
BRPI0921441A2 (en) | 2016-01-05 |
CN102177265B (en) | 2014-07-09 |
US20110206941A1 (en) | 2011-08-25 |
JP2012506952A (en) | 2012-03-22 |
ES2623604T3 (en) | 2017-07-11 |
RU2482204C2 (en) | 2013-05-20 |
RU2011121810A (en) | 2012-12-10 |
EP2340318B1 (en) | 2017-02-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2340318B1 (en) | Copper-tin alloy, composite material and use thereof | |
DE60101026T2 (en) | Copper alloy containing silver | |
DE3429393C2 (en) | ||
DE10065735B4 (en) | A method of making a copper alloy for a connector and copper alloy obtainable by the method | |
WO2016023790A2 (en) | Composite material for a sliding bearing | |
EP1157820B1 (en) | Metal strip with high electric conductibility and connector made from it | |
WO2013023717A2 (en) | Copper alloy | |
EP1158618B1 (en) | Metal strip with high electric conductibility and connector made from it | |
DE10138204B4 (en) | Electric contact | |
DE3527341C1 (en) | Copper-chromium-titanium-silicon alloy and use thereof | |
DE102014014239A1 (en) | Electrical connection element | |
EP1698707B1 (en) | Sliding bearing with a lead free copper based bearing metal layer containing tin and zinc | |
CH669211A5 (en) | COPPER-CHROME-TITANIUM-SILICONE ALLOY AND THEIR USE. | |
DE3530736C2 (en) | ||
DE102013007274A1 (en) | Copper casting alloy for asynchronous machines | |
EP2906733B1 (en) | Material for electric contact components | |
DE69814657T2 (en) | COPPER BASED ALLOY, CHARACTERIZED BY DECAY CURING AND CURING IN SOLID CONDITION | |
EP1749897B1 (en) | Process including annealing for producing water-bearing copper cast parts with lowered tendency of migration | |
DE102018208116A1 (en) | Copper tape for making electrical contacts and method of making a copper tape and connectors | |
EP1288321B1 (en) | Material for a metal strip | |
EP1292422A1 (en) | Method for connecting shape-memory material and steel or copper material | |
EP2290114A1 (en) | Water-guiding component | |
DE1483176A1 (en) | Copper-zinc alloy | |
DE2333820C3 (en) | Use of a copper-zinc-iron-cobalt alloy | |
DE1483176C (en) | Copper zinc alloy |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20110304 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: AL BA RS |
|
DAX | Request for extension of the european patent (deleted) | ||
17Q | First examination report despatched |
Effective date: 20160104 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
INTG | Intention to grant announced |
Effective date: 20161027 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 867934 Country of ref document: AT Kind code of ref document: T Effective date: 20170315 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 502009013650 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: FP |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2623604 Country of ref document: ES Kind code of ref document: T3 Effective date: 20170711 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170515 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170516 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170615 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170515 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 9 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 502009013650 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20171116 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20171027 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 10 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20171027 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 867934 Country of ref document: AT Kind code of ref document: T Effective date: 20171027 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20171027 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20091027 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170215 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170215 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170615 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: TR Payment date: 20201023 Year of fee payment: 12 Ref country code: NL Payment date: 20201028 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20201022 Year of fee payment: 12 Ref country code: ES Payment date: 20201228 Year of fee payment: 12 Ref country code: FR Payment date: 20201022 Year of fee payment: 12 Ref country code: IT Payment date: 20201026 Year of fee payment: 12 Ref country code: CH Payment date: 20201021 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20201028 Year of fee payment: 12 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MM Effective date: 20211101 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20211031 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20211027 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211101 Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211027 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211031 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211027 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20230220 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211028 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R081 Ref document number: 502009013650 Country of ref document: DE Owner name: SUNDWIGER MESSINGWERK GMBH, DE Free format text: FORMER OWNER: SUNDWIGER MESSINGWERK GMBH & CO. KG, 58675 HEMER, DE |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20240321 Year of fee payment: 15 |