EP2334829B1 - Device for smoothing the surface of a sinter mixture - Google Patents
Device for smoothing the surface of a sinter mixture Download PDFInfo
- Publication number
- EP2334829B1 EP2334829B1 EP09736372.5A EP09736372A EP2334829B1 EP 2334829 B1 EP2334829 B1 EP 2334829B1 EP 09736372 A EP09736372 A EP 09736372A EP 2334829 B1 EP2334829 B1 EP 2334829B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- scraper
- scrapers
- grate carriage
- sinter
- grate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
- 239000000203 mixture Substances 0.000 title claims description 21
- 238000009499 grossing Methods 0.000 title claims description 6
- 239000007769 metal material Substances 0.000 claims description 2
- 238000005245 sintering Methods 0.000 description 16
- 239000000463 material Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000005273 aeration Methods 0.000 description 3
- 239000011362 coarse particle Substances 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 238000005056 compaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
- C22B1/20—Sintering; Agglomerating in sintering machines with movable grates
- C22B1/205—Sintering; Agglomerating in sintering machines with movable grates regulation of the sintering process
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B21/00—Open or uncovered sintering apparatus; Other heat-treatment apparatus of like construction
- F27B21/02—Sintering grates or tables
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/0033—Charging; Discharging; Manipulation of charge charging of particulate material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/12—Travelling or movable supports or containers for the charge
- F27D3/123—Furnace cars
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D99/00—Subject matter not provided for in other groups of this subclass
Definitions
- This invention relates to a device for smoothing the surface of a sinter mixture in a grate carriage, before the same enters an ignition furnace, by means of at least one scraper between the charging point of the sinter mixture and the ignition furnace.
- a sinter mixture is produced, which contains iron ores, aggregates and coke as fuel, and via a charging device is charged onto the grate carriages of the sintering machine circulating as an endless belt.
- the coke contained in the sinter mixture is ignited, and an induced-draft fan disposed below the grate carriage belt draws the burning front through the sinter mixture, so that a sinter cake completely burnt through is obtained at the dumping end of the belt. Due to the heat produced in the process, the fine ores will melt at the surface, so that their grains undergo a firm connection.
- the finished sinter is supplied to the blast furnace.
- EP 0 286 381 A2 describes an inclined screen for feeding a raw mix onto a pallet of a sintering apparatus.
- the sintering mix is fed from a drum feeder onto a sloping plate and adjacent bars extending longitudinally of the sloping plate.
- the forward end of the pallet becomes the lower portion and the top end portion of the bars has level differences, so that the gaps between the bars are wider at the top edge side.
- fine particles of the raw mix falling on the bar fall through to the pallet from the basic edge side, and coarse particles of the sintering raw mix fall through to the pallet from the top edge side of the bars.
- a sift feeding to form a lower coarse particle layer and an upper fine particle layer on the pallet is carried out so that a grain size in a height direction of a raw mixed layer can be optionally formed.
- Document JP 2002 121820 discloses a method to stabilize an upper layer part of a sintering bed even when it is exposed to circulating waste gas containing much moisture. For that purpose, the solid fuel blending ratio is increased in the upper layer part of the sintering bed and/or the upper layer part is compacted. Irrespective of the chosen way to adapt the upper layer part, material is fed by a drum feeder and falls to sloping chute from which it slides to the sinter bed.
- Document JP 11 2011355 describes a device to top a groove and to flatten a surface of material prepared for a sintering process.
- This device includes a screw system of material scrapers which are rotated by revolution changer. To scrape up the material toward a groove, spiral veins are attached in opposition.
- US 4,648,900 relates to a method for producing a charge of high permeability and stable structure of a sintering bed. The method comprises the steps of compacting the moist material mixture, forming a coherent cake and breaking the cake into pieces of a size suitable or forming a suction-sinter charge. Therefore, each cake is moved down its respective support plate to a spiked role, which disintegrates the cake into pieces of given size. The pieces then fall onto a grate, forming either of two layers, depending on the position of the plate.
- Document JP 2003 277841 discloses a method for improving the ventilation at the upper part of a sintering raw material layer. This method is based on a plurality of fine holes having a prescribed cross sectional shape and depth. The holes penetrate the upper surface of the upper layer part of the sintering raw material layer. During sintering, a raw material is formed by dispersing these fine holes. The raw material is fed by a drum feeder and falls to sloping chute and onto the sintering bed.
- this object substantially is solved by a device comprising the features of claim 1.
- the laterally oscillating movement of the scrapers removes the waves (longitudinal waves) extending substantially in longitudinal direction of the sinter bed surface.
- a plurality of, correspondingly narrow, scrapers can be suspended in a row one beside the other above the travelling way of the grate carriage distributed across its width.
- the bearing force of the scrapers substantially is determined by their own weight.
- the lateral oscillating movement of the scrapers can for instance be effected by means of a cam disk, cam shaft or crank drive and/or pneumatically or hydraulically.
- the scrapers can be made of a metallic or non-metallic material and can have different shapes.
- the direction of travel of a grate carriage 1 from a charging point 4 for a sinter mixture to an ignition furnace 2 extends from the left to the right.
- one or more scrapers 3 is/are suspended in a row one beside the other across the width of the grate carriage 1 so as to reciprocate about an axis of rotation D transverse to the direction of travel of the grate carriage 1 such that they drag along the sinter bed surface when the grate carriage 1 moves through below the same, and thus remove any transverse waves present.
- the scrapers 3 can be subjected to a lateral oscillating movement, so as to level out longitudinal waves present in the surface of the sinter bed.
- the laterally oscillating movement of the scrapers 3 can be effected by cam disk, cam shaft or crank drives (not shown in detail) and/or pneumatically or hydraulically.
- the scrapers 3 are slightly angled or bent at their free end 7, which comes to rest on the respective sinter bed surface, so that the reciprocating movement can easily be initiated and maintained when the grate carriage moves through below the same.
- the free ends can for instance also be formed like a rake, in order to increase the smoothing effect and make the same more uniform.
- the scrapers 3 can be mounted at different levels individually or all together and/or be adjusted in their height above the travelling way 5.
- the bearing force of the scrapers 3 substantially is determined by their own weight. It can, however, be changed by additional weights (not shown).
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Manufacturing & Machinery (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Tunnel Furnaces (AREA)
Description
- This invention relates to a device for smoothing the surface of a sinter mixture in a grate carriage, before the same enters an ignition furnace, by means of at least one scraper between the charging point of the sinter mixture and the ignition furnace.
- During sintering in iron metallurgy, fine ores and concentrates not immediately ready for use should be agglomerated, so that they can then be supplied to the blast-furnace process. For sintering purposes, a sinter mixture is produced, which contains iron ores, aggregates and coke as fuel, and via a charging device is charged onto the grate carriages of the sintering machine circulating as an endless belt. The coke contained in the sinter mixture is ignited, and an induced-draft fan disposed below the grate carriage belt draws the burning front through the sinter mixture, so that a sinter cake completely burnt through is obtained at the dumping end of the belt. Due to the heat produced in the process, the fine ores will melt at the surface, so that their grains undergo a firm connection. Upon separation of rust layer and sinter returns, the finished sinter is supplied to the blast furnace.
- When charging the sinter mixture onto the grate carriage, longitudinal and transverse grooves are formed on the surface of the sinter bed. For technical reasons, these grooves are undesirable because of their influence on the ignition behaviour in the ignition furnace and because of their influence on aeration. To remove such surface irregularities, rigidly mounted scrapers have been used so far. The same have the disadvantage that the sinter mixture is dammed up and sheared off when moving through below the same in flow direction. In this way, an undesired compaction of the surface is obtained, which impedes a good aeration.
-
EP 0 286 381 A2 describes an inclined screen for feeding a raw mix onto a pallet of a sintering apparatus. The sintering mix is fed from a drum feeder onto a sloping plate and adjacent bars extending longitudinally of the sloping plate. As the bars are sloped, the forward end of the pallet becomes the lower portion and the top end portion of the bars has level differences, so that the gaps between the bars are wider at the top edge side. Thus, fine particles of the raw mix falling on the bar fall through to the pallet from the basic edge side, and coarse particles of the sintering raw mix fall through to the pallet from the top edge side of the bars. Thereby, a sift feeding to form a lower coarse particle layer and an upper fine particle layer on the pallet is carried out so that a grain size in a height direction of a raw mixed layer can be optionally formed. There is no scraping effect by the bars onto the sintering mix fed to the pallet since the sintering mix layer is formed on the pallet only after the pallet has passed the tip of the bars. - Document
JP 2002 121820 - Document
JP 11 2011355 US 4,648,900 relates to a method for producing a charge of high permeability and stable structure of a sintering bed. The method comprises the steps of compacting the moist material mixture, forming a coherent cake and breaking the cake into pieces of a size suitable or forming a suction-sinter charge. Therefore, each cake is moved down its respective support plate to a spiked role, which disintegrates the cake into pieces of given size. The pieces then fall onto a grate, forming either of two layers, depending on the position of the plate. - Document
JP 2003 277841 - It is the object of the present invention to remove the undesired irregularities on the surface of the sinter mixture without the disadvantages stated for the prior art and thereby increase the product quality of the sintered material.
- In accordance with the invention, this object substantially is solved by a device comprising the features of claim 1.
- In this way, it is achieved that irregularities of the sinter bed surface are levelled out before entry of the grate carriage into the ignition furnace without damming up the material and without undesired compaction, so that a uniform ignition behaviour in the ignition furnace and the desired aeration are ensured. Due to the particular type of reciprocating scrapers, the overflow of material on the side walls of the grate carriage, which also occurs in the prior art, is avoided. Preferred embodiments of the invention are evident form the dependent claims. Advantageously, the scrapers can be subjected to a lateral oscillating movement in addition to the reciprocating movement. While the mere reciprocating movement provides for levelling out the waves (transverse waves) extending substantially transverse to the direction of travel of the grate carriage, the laterally oscillating movement of the scrapers removes the waves (longitudinal waves) extending substantially in longitudinal direction of the sinter bed surface.
- Advantageously, a plurality of, correspondingly narrow, scrapers can be suspended in a row one beside the other above the travelling way of the grate carriage distributed across its width.
- With regard to different sinter bed heights in the grate carriage, it furthermore is advantageous when the height of the scrapers above the travelling way is adjustable.
- The bearing force of the scrapers substantially is determined by their own weight.
- It is, however, also possible that one or more additional weights are mounted on the scrapers, in order to produce or adjust the desired bearing force.
- In a particular aspect of the invention, the lateral oscillating movement of the scrapers can for instance be effected by means of a cam disk, cam shaft or crank drive and/or pneumatically or hydraulically.
- The scrapers can be made of a metallic or non-metallic material and can have different shapes.
- To initiate and maintain the reciprocating movement of the scrapers when the grate carriage with the sinter mixture accommodated therein moves through below the same, it is particularly advantageous when the scrapers are angled or bent at their free ends in direction of travel of the grate carriage.
- Further objects, features, advantages and possible applications of the invention can be taken from the following description of embodiments and the drawing. All features described and/or illustrated per se or in any combination form the subject-matter of the invention, also independent of their inclusion in individual claims and/or their back-reference.
- In the drawing:
- Fig. 1
- shows a schematic side view of a device of the invention for smoothing the surface of a sinter mixture in a grate carriage before the same enters an ignition furnace, and
- Fig. 2
- schematically shows an oblique view of such smoothing device with a grate carriage disposed below the same.
- As shown in
Fig. 1 , the direction of travel of a grate carriage 1 from acharging point 4 for a sinter mixture to anignition furnace 2 extends from the left to the right. Above thetravelling way 5 for the grate carriage 1 one or more scrapers 3 is/are suspended in a row one beside the other across the width of the grate carriage 1 so as to reciprocate about an axis of rotation D transverse to the direction of travel of the grate carriage 1 such that they drag along the sinter bed surface when the grate carriage 1 moves through below the same, and thus remove any transverse waves present. - By means of an oscillation drive 6 indicated in
Figure 2 , the scrapers 3 can be subjected to a lateral oscillating movement, so as to level out longitudinal waves present in the surface of the sinter bed. The laterally oscillating movement of the scrapers 3 can be effected by cam disk, cam shaft or crank drives (not shown in detail) and/or pneumatically or hydraulically. - As can be taken from
Figure 1 , the scrapers 3 are slightly angled or bent at theirfree end 7, which comes to rest on the respective sinter bed surface, so that the reciprocating movement can easily be initiated and maintained when the grate carriage moves through below the same. The free ends can for instance also be formed like a rake, in order to increase the smoothing effect and make the same more uniform. - In adaptation to different bed heights, the scrapers 3 can be mounted at different levels individually or all together and/or be adjusted in their height above the
travelling way 5. - The bearing force of the scrapers 3 substantially is determined by their own weight. It can, however, be changed by additional weights (not shown).
-
- 1
- grate carriage
- 2
- ignition furnace
- 3
- scraper
- 4
- charging point
- 5
- travelling way
- 6
- oscillation drive
- 7
- angled or bent end
- D
- axis of rotation
Claims (9)
- A device for smoothing the surface of a sinter mixture in a grate carriage (1), before the same enters an ignition furnace (2), by means of at least one scraper (3) between the charging point (4) of the sinter bed mixture and the ignition furnace (2), the at least one scraper (3) is suspended above the travelling way (5) of the grate carriage (1) so as to reciprocate in and against its direction of travel such that the scraper (3) drags along the sinter bed surface when the grate carriage (1) moves through below the same,
characterized in that the at least one scraper (3) can be subjected to a lateral oscillating movement. - The device according to claim 1 , characterized in that a plurality of scrapers (3) are arranged in a row one beside the other above the travelling way (5) of the grate carriage (1) distributed across its width.
- The device according to any of the preceding claims, characterized In that the height of the scrapers (3) above the travelling way (5) is adjustable.
- The device according to any of the preceding claims, characterized in that the bearing force of the scrapers (3) is determined by their own weight.
- The device according to any of the preceding claims, characterized in that on the at least one scraper (3) one or more additional weights can be mounted.
- The device according to any of the preceding claims, characterized in that the lateral oscillating movement of the at least one scraper (3) is effected by means of a cam disk, cam shaft or crank drive and/or pneumatically or hydraulically.
- The device according to any of the preceding claims, characterized in that the at least one scraper (3) is made of a metallic or non-metallic material.
- The device according to any of the preceding claims, characterized in that the scrapers (3) have different shapes.
- The device according to any of the preceding claims, characterized in that the at least one scraper (3) is angled or bent (7) at its free end in direction of travel of the grate carriage (1).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL09736372T PL2334829T3 (en) | 2008-10-09 | 2009-09-15 | Device for smoothing the surface of a sinter mixture |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008051063.7A DE102008051063B4 (en) | 2008-10-09 | 2008-10-09 | Device for smoothing the surface of a sintered mixture |
PCT/EP2009/006662 WO2010040442A1 (en) | 2008-10-09 | 2009-09-15 | Device for smoothing the surface of a sinter mixture |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2334829A1 EP2334829A1 (en) | 2011-06-22 |
EP2334829B1 true EP2334829B1 (en) | 2013-11-06 |
Family
ID=41402311
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09736372.5A Not-in-force EP2334829B1 (en) | 2008-10-09 | 2009-09-15 | Device for smoothing the surface of a sinter mixture |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP2334829B1 (en) |
CN (1) | CN102177261B (en) |
AR (1) | AR073734A1 (en) |
BR (1) | BRPI0920427B1 (en) |
DE (1) | DE102008051063B4 (en) |
EA (1) | EA018399B1 (en) |
ES (1) | ES2442022T3 (en) |
PL (1) | PL2334829T3 (en) |
UA (1) | UA104727C2 (en) |
WO (1) | WO2010040442A1 (en) |
ZA (1) | ZA201101554B (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103421948A (en) * | 2012-05-24 | 2013-12-04 | 山东省冶金设计院股份有限公司 | Method for changing state of upper part of mixed materials on trolley and method for realizing above method |
RU2614475C2 (en) * | 2015-09-03 | 2017-03-28 | Открытое акционерное общество "Научно-исследовательский институт металлургической теплотехники" (ОАО "ВНИИМТ") | Charge igniting method and furnace for its implementation |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB918850A (en) * | 1958-06-18 | 1963-02-20 | Yawata Iron & Steel Co | An automatic control for a granular bulk material conveyor |
US3262770A (en) * | 1962-05-11 | 1966-07-26 | Yawata Iron & Steel Co | Method of controlling the thickness of a charged raw material layer in dwight-lloyd sintering machine |
FR1443771A (en) * | 1965-08-13 | 1966-06-24 | Cerro Corp | Method and apparatus for feeding sinter machines |
AT376245B (en) * | 1979-11-06 | 1984-10-25 | Voest Alpine Ag | METHOD FOR SINTERING FINE-GRAINED IRON ORES |
SE434958B (en) * | 1980-12-08 | 1984-08-27 | Bostroem Olle | PROCEDURE AND DEVICE FOR INSTALLING A CHARGING SUGMENT OR IN A STATIONER OR HUGE SUGGESTING PAN ASTADKOMMA A CHARGE WITH HIGH PERMEABILITY AND STABLE STRUCTURE |
AU603879B2 (en) * | 1987-04-06 | 1990-11-29 | Nippon Steel Corporation | Apparatus and method for feeding sintering raw mix |
CN1009757B (en) * | 1987-04-06 | 1990-09-26 | 新日本制铁株式会社 | Apparatus and method for feeding sintering raw mix |
JP3889142B2 (en) * | 1998-01-20 | 2007-03-07 | Jfeスチール株式会社 | Raw material breathability homogenizer in the width direction of a sintering machine and method for producing a sintered ore |
JP3721068B2 (en) * | 2000-10-16 | 2005-11-30 | 株式会社神戸製鋼所 | Exhaust gas circulation method sintering operation method |
JP2003277841A (en) * | 2002-03-22 | 2003-10-02 | Jfe Steel Kk | Method for producing sintered ore |
CN2935056Y (en) * | 2006-08-11 | 2007-08-15 | 昆明钢铁股份有限公司 | Feeder of sintering machine |
CN101187529A (en) * | 2007-12-12 | 2008-05-28 | 王梓骥 | Sintering machine oscillating sieve material distribution method and device |
-
2008
- 2008-10-09 DE DE102008051063.7A patent/DE102008051063B4/en not_active Expired - Fee Related
-
2009
- 2009-09-15 PL PL09736372T patent/PL2334829T3/en unknown
- 2009-09-15 CN CN200980139809.XA patent/CN102177261B/en not_active Expired - Fee Related
- 2009-09-15 ES ES09736372.5T patent/ES2442022T3/en active Active
- 2009-09-15 UA UAA201102384A patent/UA104727C2/en unknown
- 2009-09-15 BR BRPI0920427-0A patent/BRPI0920427B1/en not_active IP Right Cessation
- 2009-09-15 EP EP09736372.5A patent/EP2334829B1/en not_active Not-in-force
- 2009-09-15 EA EA201100341A patent/EA018399B1/en not_active IP Right Cessation
- 2009-09-15 WO PCT/EP2009/006662 patent/WO2010040442A1/en active Application Filing
- 2009-10-08 AR ARP090103880A patent/AR073734A1/en unknown
-
2011
- 2011-02-28 ZA ZA2011/01554A patent/ZA201101554B/en unknown
Also Published As
Publication number | Publication date |
---|---|
CN102177261B (en) | 2014-01-01 |
CN102177261A (en) | 2011-09-07 |
EA018399B1 (en) | 2013-07-30 |
EP2334829A1 (en) | 2011-06-22 |
PL2334829T3 (en) | 2014-04-30 |
BRPI0920427A2 (en) | 2015-12-22 |
AR073734A1 (en) | 2010-11-24 |
WO2010040442A1 (en) | 2010-04-15 |
ES2442022T3 (en) | 2014-02-07 |
DE102008051063A1 (en) | 2010-04-22 |
EA201100341A1 (en) | 2011-10-31 |
BRPI0920427B1 (en) | 2018-01-23 |
ZA201101554B (en) | 2012-05-30 |
DE102008051063B4 (en) | 2014-08-21 |
UA104727C2 (en) | 2014-03-11 |
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