EP2334171A2 - Insecticidal gassing agent containing active ingredient in the form of a granulate - Google Patents
Insecticidal gassing agent containing active ingredient in the form of a granulateInfo
- Publication number
- EP2334171A2 EP2334171A2 EP09778392A EP09778392A EP2334171A2 EP 2334171 A2 EP2334171 A2 EP 2334171A2 EP 09778392 A EP09778392 A EP 09778392A EP 09778392 A EP09778392 A EP 09778392A EP 2334171 A2 EP2334171 A2 EP 2334171A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- granules
- insecticidal
- active ingredient
- combustible
- fumigant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
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- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 description 1
- INISTDXBRIBGOC-CGAIIQECSA-N [cyano-(3-phenoxyphenyl)methyl] (2s)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoate Chemical compound N([C@@H](C(C)C)C(=O)OC(C#N)C=1C=C(OC=2C=CC=CC=2)C=CC=1)C1=CC=C(C(F)(F)F)C=C1Cl INISTDXBRIBGOC-CGAIIQECSA-N 0.000 description 1
- YXWCBRDRVXHABN-JCMHNJIXSA-N [cyano-(4-fluoro-3-phenoxyphenyl)methyl] 3-[(z)-2-chloro-2-(4-chlorophenyl)ethenyl]-2,2-dimethylcyclopropane-1-carboxylate Chemical compound C=1C=C(F)C(OC=2C=CC=CC=2)=CC=1C(C#N)OC(=O)C1C(C)(C)C1\C=C(/Cl)C1=CC=C(Cl)C=C1 YXWCBRDRVXHABN-JCMHNJIXSA-N 0.000 description 1
- IHVPAVRHNZFQKC-UHFFFAOYSA-N [cyano-(6-phenoxypyridin-2-yl)methyl] 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=N1 IHVPAVRHNZFQKC-UHFFFAOYSA-N 0.000 description 1
- YLFSVIMMRPNPFK-WEQBUNFVSA-N acrinathrin Chemical compound CC1(C)[C@@H](\C=C/C(=O)OC(C(F)(F)F)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YLFSVIMMRPNPFK-WEQBUNFVSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 description 1
- 229950002373 bioresmethrin Drugs 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 125000006226 butoxyethyl group Chemical group 0.000 description 1
- 150000001715 carbamic acids Chemical class 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- LSFUGNKKPMBOMG-UHFFFAOYSA-N cycloprothrin Chemical compound ClC1(Cl)CC1(C=1C=CC=CC=1)C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 LSFUGNKKPMBOMG-UHFFFAOYSA-N 0.000 description 1
- 229960001591 cyfluthrin Drugs 0.000 description 1
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 description 1
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- HCQHIEGYGGJLJU-UHFFFAOYSA-N didecyl hexanedioate Chemical compound CCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCC HCQHIEGYGGJLJU-UHFFFAOYSA-N 0.000 description 1
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 description 1
- CNHQWLUGXFIDAT-UHFFFAOYSA-N dioctyl 2-hydroxybutanedioate Chemical compound CCCCCCCCOC(=O)CC(O)C(=O)OCCCCCCCC CNHQWLUGXFIDAT-UHFFFAOYSA-N 0.000 description 1
- VJHINFRRDQUWOJ-UHFFFAOYSA-N dioctyl sebacate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCC(=O)OCC(CC)CCCC VJHINFRRDQUWOJ-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000009513 drug distribution Methods 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- NYPJDWWKZLNGGM-RPWUZVMVSA-N esfenvalerate Chemical compound C=1C([C@@H](C#N)OC(=O)[C@@H](C(C)C)C=2C=CC(Cl)=CC=2)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-RPWUZVMVSA-N 0.000 description 1
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 1
- 229950005085 etofenprox Drugs 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229950006668 fenfluthrin Drugs 0.000 description 1
- XQUXKZZNEFRCAW-UHFFFAOYSA-N fenpropathrin Chemical compound CC1(C)C(C)(C)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 XQUXKZZNEFRCAW-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- ZXQYGBMAQZUVMI-GCMPRSNUSA-N gamma-cyhalothrin Chemical compound CC1(C)[C@@H](\C=C(/Cl)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-GCMPRSNUSA-N 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000001046 green dye Substances 0.000 description 1
- WIFXJBMOTMKRMM-UHFFFAOYSA-N halfenprox Chemical compound C=1C=C(OC(F)(F)Br)C=CC=1C(C)(C)COCC(C=1)=CC=CC=1OC1=CC=CC=C1 WIFXJBMOTMKRMM-UHFFFAOYSA-N 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- VPRAQYXPZIFIOH-UHFFFAOYSA-N imiprothrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)N(CC#C)CC1=O VPRAQYXPZIFIOH-UHFFFAOYSA-N 0.000 description 1
- 239000005910 lambda-Cyhalothrin Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- HNXNKTMIVROLTK-UHFFFAOYSA-N n,n-dimethyldecanamide Chemical class CCCCCCCCCC(=O)N(C)C HNXNKTMIVROLTK-UHFFFAOYSA-N 0.000 description 1
- VHRUBWHAOUIMDW-UHFFFAOYSA-N n,n-dimethyloctanamide Chemical compound CCCCCCCC(=O)N(C)C VHRUBWHAOUIMDW-UHFFFAOYSA-N 0.000 description 1
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 1
- 238000010943 off-gassing Methods 0.000 description 1
- 229930184652 p-Terphenyl Natural products 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 229960003536 phenothrin Drugs 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- 229920001223 polyethylene glycol Chemical class 0.000 description 1
- SMKRKQBMYOFFMU-UHFFFAOYSA-N prallethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OC1C(C)=C(CC#C)C(=O)C1 SMKRKQBMYOFFMU-UHFFFAOYSA-N 0.000 description 1
- BPJZKLBPJBMLQG-KWRJMZDGSA-N propanoyl (z,12r)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(=O)OC(=O)CC BPJZKLBPJBMLQG-KWRJMZDGSA-N 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 229940015367 pyrethrum Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000001044 red dye Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- HPYNBECUCCGGPA-UHFFFAOYSA-N silafluofen Chemical compound C1=CC(OCC)=CC=C1[Si](C)(C)CCCC1=CC=C(F)C(OC=2C=CC=CC=2)=C1 HPYNBECUCCGGPA-UHFFFAOYSA-N 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005936 tau-Fluvalinate Substances 0.000 description 1
- INISTDXBRIBGOC-XMMISQBUSA-N tau-fluvalinate Chemical compound N([C@H](C(C)C)C(=O)OC(C#N)C=1C=C(OC=2C=CC=CC=2)C=CC=1)C1=CC=C(C(F)(F)F)C=C1Cl INISTDXBRIBGOC-XMMISQBUSA-N 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 1
- HDYJUDNYXOWDOP-UHFFFAOYSA-N tris(2-ethylhexyl) benzene-1,3,5-tricarboxylate Chemical compound CCCCC(CC)COC(=O)C1=CC(C(=O)OCC(CC)CCCC)=CC(C(=O)OCC(CC)CCCC)=C1 HDYJUDNYXOWDOP-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/20—Combustible or heat-generating compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Definitions
- the present invention relates to novel insecticidal fumigants prepared using active ingredient granules, to the methods of making such fumigants, and to their use for controlling harmful and / or troublesome insects.
- Flammable insecticidal fumigants have long been known and commercially available. They are e.g. manufactured and distributed as "Mosquito Coil” (or simply “coils”). In these coils, various insecticides can be used, e.g. from the class of pyrethroids. However, some active ingredients used in conventional coils, however, have the disadvantage that they due Chem.-physic. Parameters tend to escape relatively quickly, so their durability is limited. The volatility of some pyrethroid is attempted by the addition of evaporation inhibitors, e.g. Adipates or sebacates (e.g., EP 0 693 254), but with limited success. Furthermore, these coils are dried at lower temperatures to minimize such losses of active ingredient in the preparation
- the technical problem underlying the present invention is to provide long-lasting combustible insecticidal fumigants and to provide processes for their preparation.
- This object is achieved by the inventive fumigants, which are characterized in that the insecticidal active ingredient is incorporated into the compositions in the form of granules.
- the present invention therefore relates to novel combustible insecticidal fumigants prepared using active ingredient-containing granules, the processes for producing such fumigants and their use for controlling harmful and / or troublesome insects. Moreover, the invention relates to the use of granules for the production of combustible insecticidal fumigants.
- the combustible insecticidal fumigants according to the invention are significantly less prone to loss of active ingredient through outgassing than the predecessors described in the prior art. As a result, a longer shelf life or a reduced use of active ingredient can be realized.
- the subject of the present invention is therefore a combustible insecticidal fumigant, characterized in that it comprises an insecticide, a granulate as carrier material and an evaporation inhibitor.
- the insecticide and the evaporation inhibitor are contained in the granules.
- agents according to the invention are sometimes referred to below as “coils”, it goes without saying that the agents in no way have to be sipral-shaped, but can be produced in any desired forms and have the properties essential to the invention.
- insecticides can be used in the erf ⁇ ndungswashen funds all insecticides, which are used in coils already described. Preference is given to using pyrethroids, for
- Bioallethrin S-cyclopentyl isomer bioethanomethrin, biopermethrin, bioresmethrin,
- Chlovaporthrin cis-cypermethrin, cis-resmethrin, cis-permethrin, clocythrin, cycloprothrin,
- Fenvalerate Flubrocythrinates, Flucythrinates, Flufenprox, Flumethrin, Fluvalinate, Fubfenprox,
- Deltamethrin, beta-cyfluthrin, transfluthrin, resmethrin and metofluthrin Particularly preferred are transfluthrin and metofluthrin. Very particularly preferred is transfluthrin.
- Active ingredient-containing granules are known from the prior art and can be prepared by the methods described therein. Examples include extrusion of granules and the coating of support materials by spraying or mixing with a solution containing active ingredient.
- granules are particles which have an average particle size of 50 to 800 ⁇ m, preferably 100 to 500 ⁇ m, particularly preferably 125 to 400 ⁇ m.
- porous carrier suitable, for example based on cellulose (Biodac 20/50 ®, Fa. Kadant Inc.), meerschaum (sepiolite ® 30/60) or pumice (porous volcanic rock).
- the content of insecticide based on the granules contained in the erf ⁇ ndungswashen means, can be varied within a wide range. Typically it is 0.1 to 20 Wt .-%, preferably at 0.5 to 10 wt .-%, particularly preferably from 1 to 10 wt .-% and most preferably at 2 to 5 wt .-%.
- compositions according to the invention additionally contain an evaporation inhibitor.
- an evaporation inhibitor Suitable are all evaporation inhibitors described as such in the prior art, for example (poly) -aromatic, as well as acyclic hydrocarbons present in pure form, as well as in mixtures.
- diphenyl, diphenyl ether, o-, m-, p-terphenyl, mixtures of hydrogenated hydrocarbons for example in their commercially available forms, Diphyl THT ®, ® Santotherm, Therm S 900 ®, butyl stearate, butyl oleate, methyl acetylricinoleate, Diethylglycoldistearat; Isopar ® V, D Exsol ® 140 (Exxon), butoxyethyl, tetrahydrofurfuryl, Epoxymethylstearat, Epoxybutyloleat etc .; dibasic aliphatic acid esters, for example, didecyl adipate, di-2-ethylene adipate, dimethoxyethyl adipate, di-2-ethylene azelate, diisodecyl acetate, di-2-ethylhexyl sebacate, dibutyl se
- Particularly preferred substances from the class of adipates for example, under the names Adimoll ® (Fa. Lanxess AG), Plastomoll ® (Messrs. BASF AG), from the class of Polyadipates, eg under the name Ultramoll ® (Fa. Lanxess AG), and from the class of sebacates, for example, under the designation Synative ® (Fa. Cognis GmbH) are commercially available.
- liquid evaporation inhibitor it can be used for dissolving or suspending the insecticide and then sprayed on the carrier.
- the insecticide-containing granules are preferably prepared by dissolving the insecticide in the corresponding, preferably liquid, evaporation inhibitor and then applying it to the carrier material.
- the application is preferably carried out by spray application.
- the content of evaporation inhibitor can be varied within a wide range.
- the upper limit is the content in that the flowability of the granules should be maintained. Typically lies it is from 0.5 to 50% by weight, preferably from 1 to 30% by weight, more preferably from 2 to 25% by weight and most preferably from 5 to 20% by weight.
- granules containing carrier material, insecticide and evaporation inhibitor the granules having particle sizes of 50 ⁇ m to 800 ⁇ m.
- the preparation of the fumigant according to the invention is carried out by known methods, which are exemplified below. In principle, any known production method is easily changeable so that means according to the invention can be produced.
- starch or starch-like products of different origin are used and cooked in hot water or steam. This creates a sticky and just still flowable dough. Also, the use of industrially produced, pre-swollen starch in powdered form is possible to simplify the process. However, because of the higher cost, such products are rarely used. In higher mechanized
- this process step is carried out in special kneaders.
- the basic raw material of the fumigants are wood flours of different provenance according to local availability. Flours of tropical hardwoods and coconut shells in various proportions give advantages both in production and in product quality.
- the wood flour can also be replaced by ground charcoal. This results in black products that do not require another dye.
- large belt or paddle mixers are used.
- the wood meals are also the active ingredient-containing granules, which are the peculiarity of the fumigant invention, added in the desired amount.
- coils that are usually brown are colored by the addition of dye.
- dye In addition to green dye also occasionally red dye is used.
- the wood flour mixture, adhesive and optionally color are finally combined in a roller mixer and kneaded until mixed to the required homogeneity and consistency, mixed and rolled.
- the finished mass is then emptied into a reservoir from which the following continuously operating belt extruder is fed.
- the coil mass is extruded at a higher temperature to form a strip which is approximately 5 mm thick and up to 20 cm wide and smooth. This volume will be about 1.20 m long Cut pieces that are fed to a punching machine. Punching in different degrees of mechanization are in use.
- the drying of the products takes place, for example, in such a way that the punched products are placed by hand on wire mesh or perforated metal trays and these are stacked on trolleys. To dry the products, these trolleys are moved into drying rooms and dried for 6 - 8 hours at 60 ° - 70 0 C.
- the drying of the coils is finished when the moisture content is 6 - 8%.
- the present invention is a process for producing the inventive fumigant, characterized in that first wood meal is mixed with the insecticide-containing granules and then adhesive in the form of starch or starch-like products and optionally color is added and kneaded, mixed and rolled and the resulting mass is extruded and dried.
- the fumigants according to the invention can be used against different insects. This can e.g. be:
- Acarina e.g. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.
- Opiliones e.g. Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
- Zygentoma e.g. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
- Diptera e.g. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys Calcitrans, Tipula paludosa.
- Lepidoptera e.g. Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
- Ctenocephalides canis Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.
- Hymenoptera for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetra ⁇ ⁇ norium caespitum.
- Anoplura eg Pediculus humanus capitis, Pediculus humanus corporis, Pemphigus spp., Phylloera vastatrix, Phthirus pubis.
- Heteroptera eg Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.
- insects from the class of Diptera e.g. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys Calcitrans, Tipula paludosa.
- Aedes aegypti Aedes albopictus
- Aedes taeniorhynchus Aopheles spp.
- Calliphora erythrocephala Chrysozona pluvialis
- the application of the fumigant according to the invention is carried out in a known manner by ignition.
- Tranfluthrin was adipate (DOA Plastomoll ®) in a concentration of 20 wt .-% dissolved.
- DOA Plastomoll ® adipate
- the resulting solution was coated on a granulate (sepiolite ® 30/60) was applied by spraying in an amount of 15 wt .-%.
- Example A Analogously to Example A, a granulate with 3 wt .-% transfluthrin, 12 wt .-% Isopar ® M and 85 wt .-% Biodac ® 20/50 was prepared.
- Example A Analogously to Example A a granulate with 3 wt .-% transfluthrin, 12 wt .-% Synative ® ES DEHS and 85 wt .-% Biodac 20/50 ® was prepared.
- Example A Analogous to Example A, a granulate with 3 wt .-% transfluthrin, 12 wt .-% Plastomoll ® DOA and 85 wt .-% Sepiolith ® 30/60 was prepared.
- Example A Analogously to Example A was a pellet with 5 wt .-% transfluthrin, 10 wt .-% produced Plastomoll ® DOA and 85 wt .-% Biodac 20/50 ®.
- Example A Analogous to Example A, a granulate with 3 wt .-% transfluthrin, 10 wt .-% Plastomoll ® DOA and 85 wt .-% pumice (grain size 0.3 to 1 mm) was prepared.
- Example 1 Analogous to Example A, a granulate with 5 wt .-% transfluthrin, 10 wt .-% Plastomoll ® DOA and 85 wt .-% pumice (grain size 90 to 600 microns) was prepared.
- example 1 Analogous to Example A, a granulate with 5 wt .-% transfluthrin, 10 wt .-% Plastomoll ® DOA and 85 wt .-% pumice (grain size 90 to 600 microns) was prepared. example 1
- Wood and coconut flours Particle size: 80 mesh (0.180 mm), tolerance: +/- 10%, maximum water content 13%
- the active ingredient content of the coils was both directly after preparation, and after open storage in a climatic chamber at 25 m 3 40 0 C. The results are shown in Table 4 below.
Abstract
The invention relates to novel insecticidal gassing agents, produced using active ingredient granulate, the method for production of such gassing agents and use thereof for preventing harmful and/or troublesome insects.
Description
Insektizide Begasungsmittel enthaltend Wirkstoff in Form eines Granulats Insecticidal fumigant containing active ingredient in the form of granules
Die vorliegende Erfindung betrifft neuartige insektizide Begasungsmittel, die unter Benutzung von Wirkstoffgranulaten hergestellt werden, die Verfahren zur Herstellung solcher Begasungsmittel sowie deren Verwendung zur Bekämpfung schädlicher und/oder lästiger Insekten.The present invention relates to novel insecticidal fumigants prepared using active ingredient granules, to the methods of making such fumigants, and to their use for controlling harmful and / or troublesome insects.
Brennbare insektizide Begasungsmittel sind seit langem bekannt und kommerziell erhältlich. Sie werden z.B. als „Mosquito Coil" (oder einfach „Coils") hergestellt und vertrieben. In diesen Coils können verschiedene Insektizide eingesetzt werden, z.B. aus der Klasse der Pyrethroide. Manche eingesetzte Wirkstoffe weisen bei üblichen Coils allerdings den Nachteil auf, dass sie aufgrund chem.-physik. Parameter die Tendenz haben, relativ schnell entweichen, so dass ihre Haltbarkeit begrenzt ist. Der Flüchtigkeit mancher Pyrethroid versucht man durch die Zugabe von Verdampfungshemmern, z.B. Adipaten oder Sebazaten, entgegenzuwirken (z.B. EP 0 693 254), allerdings nur mit begrenztem Erfolg. Des Weiteren trocknet man diese Coils bei niedrigeren Temperaturen, um solche Wirkstoffverluste bei der Herstellung zu minimierenFlammable insecticidal fumigants have long been known and commercially available. They are e.g. manufactured and distributed as "Mosquito Coil" (or simply "coils"). In these coils, various insecticides can be used, e.g. from the class of pyrethroids. However, some active ingredients used in conventional coils, however, have the disadvantage that they due Chem.-physic. Parameters tend to escape relatively quickly, so their durability is limited. The volatility of some pyrethroid is attempted by the addition of evaporation inhibitors, e.g. Adipates or sebacates (e.g., EP 0 693 254), but with limited success. Furthermore, these coils are dried at lower temperatures to minimize such losses of active ingredient in the preparation
Es besteht demnach Bedarf für verbesserte brennbare insektizide Begasungsmittel, die eine längere Lagerstabilität aufweisen. Dementsprechend ist die der vorliegenden Erfindung zugrunde liegende technische Aufgabe die Bereitstellung lang haltbarer brennbarer insektizider Begasungsmittel sowie die Bereitstellung von Verfahren zu ihrer Herstellung. Diese Aufgabe wird durch die erfindungsgemäßen Begasungsmittel gelöst, die sich dadurch auszeichnen, dass der insektizide Wirkstoff in die Mittel in Form eines Granulats eingearbeitet wird.There is therefore a need for improved combustible insecticidal fumigants which have a longer shelf life. Accordingly, the technical problem underlying the present invention is to provide long-lasting combustible insecticidal fumigants and to provide processes for their preparation. This object is achieved by the inventive fumigants, which are characterized in that the insecticidal active ingredient is incorporated into the compositions in the form of granules.
Die vorliegende Erfindung betrifft daher neuartige brennbare insektizide Begasungsmittel, die unter Benutzung eines wirkstoffhaltigen Granulats hergestellt werden, die Verfahren zur Herstellung solcher Begasungsmittel sowie deren Verwendung zur Bekämpfung schädlicher und/oder lästiger Insekten. Außerdem betrifft die Erfindung die Verwendung von Granulaten zur Herstellung von brennbaren insektiziden Begasungsmitteln.The present invention therefore relates to novel combustible insecticidal fumigants prepared using active ingredient-containing granules, the processes for producing such fumigants and their use for controlling harmful and / or troublesome insects. Moreover, the invention relates to the use of granules for the production of combustible insecticidal fumigants.
Überraschenderweise wurde gefunden, dass die erfindungsgemäßen brennbaren insektiziden Begasungsmittel deutlich weniger zum Verlust von Wirkstoff durch Ausgasung neigen als die im Stand der Technik beschriebenen Vorgänger. Dadurch lässt sich eine längere Haltbarkeit oder ein reduzierter Wirkstoffeinsatz verwirklichen.Surprisingly, it has been found that the combustible insecticidal fumigants according to the invention are significantly less prone to loss of active ingredient through outgassing than the predecessors described in the prior art. As a result, a longer shelf life or a reduced use of active ingredient can be realized.
Gegenstand der vorliegenden Erfindung ist daher ein brennbares insektizides Begasungsmittel, dadurch gekennzeichnet, dass dieses ein Insektizid, ein Granulat als Trägermaterial sowie einen Verdampfungshemmer umfasst. Dabei sind das Insektizid und der Verdampfungshemmer im Granulat enthalten.
Für die Herstellung der erfindungsgemäßen Mittel ist kein besonderer technischer Aufwand zu treiben. Vielmehr können vorhandene Apparaturen weiterhin benutzt werden. So ist auch der eigentlich Herstellungsprozess der brennbaren insektiziden Begasungsmittel in keiner Weise verschieden von dem bisher verwendeten und dem Fachmann bekannten Verfahren. Es unterscheidet sich lediglich in der Art eingesetzten Formulierung vom Stand der Technik.The subject of the present invention is therefore a combustible insecticidal fumigant, characterized in that it comprises an insecticide, a granulate as carrier material and an evaporation inhibitor. The insecticide and the evaporation inhibitor are contained in the granules. For the preparation of the compositions according to the invention no special technical effort is required. Rather, existing equipment can continue to be used. Thus, the actual production process of the combustible insecticidal fumigant is in no way different from the previously used and known in the art methods. It differs only in the type used formulation of the prior art.
Obwohl die erfindungsgemäßen Mittel nachfolgend teils als „Coil" bezeichnet werden, ist es selbstverständlich, dass die Mittel keineswegs sipralförmig sein müssen, sondern in beliebigen Ausprägungen hergestellt und die erfϊndungswesentlichen Eigenschaften haben können.Although the agents according to the invention are sometimes referred to below as "coils", it goes without saying that the agents in no way have to be sipral-shaped, but can be produced in any desired forms and have the properties essential to the invention.
Als Insektizide lassen sich in den erfϊndungsgemäßen Mitteln alle Insektizide einsetzen, die in bereits beschriebenen Coils eingesetzt werden. Bevorzugt einsetzbar sind Pyrethroide, zumAs insecticides can be used in the erfϊndungsgemäßen funds all insecticides, which are used in coils already described. Preference is given to using pyrethroids, for
Beispiel Acrinathrin, Allethrin (d-cis-trans, d-trans), Beta-Cyfluthrin, Bifenthrin, Bioallethrin,Example acrinathrin, allethrin (d-cis-trans, d-trans), beta-cyfluthrin, bifenthrin, bioallethrin,
Bioallethrin-S-cyclopentyl-isomer, Bioethanomethrin, Biopermethrin, Bioresmethrin,Bioallethrin S-cyclopentyl isomer, bioethanomethrin, biopermethrin, bioresmethrin,
Chlovaporthrin, Cis-Cypermethrin, Cis-Resmethrin, Cis-Permethrin, Clocythrin, Cycloprothrin,Chlovaporthrin, cis-cypermethrin, cis-resmethrin, cis-permethrin, clocythrin, cycloprothrin,
Cyfluthrin, Cyhalothrin, Cypermethrin (alpha-, beta-, theta-, zeta-), Cyphenothrin, Deltamethrin, Empenthrin (lR-isomer), Esfenvalerate, Etofenprox, Fenfluthrin, Fenpropathrin, Fenpyrithrin,Cyfluthrin, cyhalothrin, cypermethrin (alpha, beta, theta, zeta), cyphenothrin, deltamethrin, empenthrin (IR isomer), esfenvalerate, etofenprox, fenfluthrin, fenpropathrin, fenpyrithrin,
Fenvalerate, Flubrocythrinate, Flucythrinate, Flufenprox, Flumethrin, Fluvalinate, Fubfenprox,Fenvalerate, Flubrocythrinates, Flucythrinates, Flufenprox, Flumethrin, Fluvalinate, Fubfenprox,
Gamma-Cyhalothrin, Imiprothrin, Kadethrin, Lambda-Cyhalothrin, Metofluthrin, Permethrin (eis-, trans-), Phenothrin (lR-trans isomer), Prallethrin, Profluthrin, Protrifenbute, Pyresmethrin,Gamma-cyhalothrin, imiprothrin, kadethrin, lambda-cyhalothrin, metofluthrin, permethrin (cis, trans), phenothrin (lR-trans isomer), prallethrin, profuthrin, protrifenbute, pyresmethrin,
Resmethrin, RU 15525, Silafluofen, Tau-Fluvalinate, Tefluthrin, Terallethrin, Tetramethrin (-1R- isomer), Tralomethrin, Transfluthrin, ZXI 8901, Pyrethrin (pyrethrum), Eflusilana. Bevorzugt sindResmethrin, RU 15525, silafluofen, tau-fluvalinate, tefluthrin, terallethrin, tetramethrin (-1R-isomer), tralomethrin, transfluthrin, ZXI 8901, pyrethrin (pyrethrum), eflusilana. Preferred are
Deltamethrin, Beta-Cyfluthrin, Transfluthrin, Resmethrin und Metofluthrin. Besonders bevorzugt sind Transfluthrin und Metofluthrin. Ganz besonders bevorzugt ist Transfluthrin.Deltamethrin, beta-cyfluthrin, transfluthrin, resmethrin and metofluthrin. Particularly preferred are transfluthrin and metofluthrin. Very particularly preferred is transfluthrin.
Wirkstoffhaltige Granulate sind aus dem Stand der Technik bekannt und lassen sich nach den dort beschriebenen Methoden herstellen. Beispielhaft genannt seien Extrusion von Granulaten und die Beschichtung von Trägermaterialien durch Besprühen oder Vermischen mit einer wirkstoffhaltigen Lösung. Als Granulat im Sinne dieser Erfindung sind Partikel anzusehen, die eine mittlere Teilchengröße von 50 bis 800 μm aufweisen, bevorzugt 100 bis 500 μm, besonders bevorzugt 125 bis 400 μm.Active ingredient-containing granules are known from the prior art and can be prepared by the methods described therein. Examples include extrusion of granules and the coating of support materials by spraying or mixing with a solution containing active ingredient. For the purposes of this invention, granules are particles which have an average particle size of 50 to 800 μm, preferably 100 to 500 μm, particularly preferably 125 to 400 μm.
Als Trägermaterial (z.B. zur Sprühbeschichtung) eignen sich alle handelsüblichen zu diesem Zweck vorgesehenen, porösen Träger, z.B. auf Basis von Zellulose (Biodac® 20/50, Fa. Kadant Inc.), Meerschaum (Sepiolith® 30/60) oder Bims (poröses Vulkangestein).As a carrier material (for example, for spray coating) are all commercial provided for this purpose, porous carrier, suitable, for example based on cellulose (Biodac 20/50 ®, Fa. Kadant Inc.), meerschaum (sepiolite ® 30/60) or pumice (porous volcanic rock).
Der Gehalt an Insektizid, bezogen auf die in den erfϊndungsgemäßen Mitteln enthaltenen Granulate, kann in einem weiten Bereich variiert werden. Typischerweise liegt er bei 0,1 bis 20
Gew.-%, bevorzugt bei 0,5 bis 10 Gew.-%, besonders bevorzugt bei 1 bis 10 Gew.-% und ganz besonders bevorzugt bei 2 bis 5 Gew.-%.The content of insecticide, based on the granules contained in the erfϊndungsgemäßen means, can be varied within a wide range. Typically it is 0.1 to 20 Wt .-%, preferably at 0.5 to 10 wt .-%, particularly preferably from 1 to 10 wt .-% and most preferably at 2 to 5 wt .-%.
Die erfindungsgemäßen Mittel enthalten zusätzlich einen Verdampfungshemmer. Geeignet sind alle im Stand der Technik als solche beschriebenen Verdampfungshemmer, z.B. (poly)- aromatische, als auch acyclische Kohlenwasserstoffe in reiner Form, als auch in Gemischen vorliegend. Bevorzugt werden Diphenyl, Diphenyl-ether, o-, m-, p-Terphenyl, Mischungen hydrierter Kohlenwasserstoffe, z.B. in ihren handelsüblichen Formen, Diphyl THT®, Santotherm®, Therm S 900®, Butylstearat, Butyloleat, Methylacetylricinoleat, Diethylglycoldistearat; Isopar V®, Exsol D 140® (Exxon), Butoxyethylstearat, Tetrahydrofurfuryloleat, Epoxymethylstearat, Epoxybutyloleat usw.; zweibasische aliphatische Säureester, beispielsweise Didecyladipat, Di-2- ethylenadipat, Dimethoxyethyladipat, Di-2-ethylenazelat, Diisodecylazetat, Di-2- ethylhexylsebazat, Dibutylsebazat, Dioctylmalat, Dioctylfumarat usw.; aromatische Carbonsäureester, beispielsweise Diethylglycolbenzoat, Trioctyltrimellitat, Tri(2-ethylhexyl)- trimesat usw.; Carbonsäurederivate wie z.B. Harnstoffe, Carbamidsäuren, Carbamidsäurester und Carbonsäureamide wie z.B N,N-Dimethyloctanamide und N,N-Dimethyldecanamide und deren Mischungen,, Propylenglykolester und Glycerinester wie z.B. Rizinussäureester, Polyethylenglykolderivate wie z.B. Diethyleneglykoldibutylether, Alkylsulfonsäureester des Phenols, anorganische Säureester, beispielsweise Trikresylphosphat, Tri-2-ethylhexylphosphat, Tributylphosphat u.s.w; Phthalsäureester, beispielsweise Di-2-ethylhexylphthalat, Dibutylphthalat, Diisobutylphthalat, Dicyclohexylphthalat u.s.w; Citronensäureester, beispielsweise Triethylcitrat, Tributylcitrat, Tributylacetylcitrat u.s.w.. Besonders bevorzugt werden Substanzen aus der Klasse der Adipate, die z.B. unter den Bezeichungen Adimoll® (Fa. Lanxess AG), Plastomoll® (Fa. BASF AG), aus der Klasse der Polyadipate, z.B. under der Bezeichnung Ultramoll® (Fa. Lanxess AG), und aus der Klasse der Sebacate, die z.B. unter den Bezeichung Synative® (Fa. Cognis GmbH) kommerziell erhältlich sind.The compositions according to the invention additionally contain an evaporation inhibitor. Suitable are all evaporation inhibitors described as such in the prior art, for example (poly) -aromatic, as well as acyclic hydrocarbons present in pure form, as well as in mixtures. Preferred are diphenyl, diphenyl ether, o-, m-, p-terphenyl, mixtures of hydrogenated hydrocarbons, for example in their commercially available forms, Diphyl THT ®, ® Santotherm, Therm S 900 ®, butyl stearate, butyl oleate, methyl acetylricinoleate, Diethylglycoldistearat; Isopar ® V, D Exsol ® 140 (Exxon), butoxyethyl, tetrahydrofurfuryl, Epoxymethylstearat, Epoxybutyloleat etc .; dibasic aliphatic acid esters, for example, didecyl adipate, di-2-ethylene adipate, dimethoxyethyl adipate, di-2-ethylene azelate, diisodecyl acetate, di-2-ethylhexyl sebacate, dibutyl sebacate, dioctyl malate, dioctyl fumarate, etc .; aromatic carboxylic esters, for example, diethyl glycol benzoate, trioctyl trimellitate, tri (2-ethylhexyl) trimesate, etc .; Carboxylic acid derivatives such as ureas, carbamic acids, Carbamidsäurester and carboxylic acid amides such as N, N-Dimethyloctanamide and N, N-dimethyldecanamides and mixtures thereof, propylene glycol esters and glycerol esters such as castor acid ester, polyethylene glycol derivatives such as Diethyleneglykoldibutylether, alkyl sulfonic acid esters of phenol, inorganic acid esters, such as tricresyl phosphate, Tri-2-ethylhexyl phosphate, tributyl phosphate, etc .; Phthalic acid esters, for example, di-2-ethylhexyl phthalate, dibutyl phthalate, diisobutyl phthalate, dicyclohexyl phthalate, etc .; Citric acid esters such as triethyl citrate, tributyl citrate, tributyl, etc. Particularly preferred substances from the class of adipates, for example, under the names Adimoll ® (Fa. Lanxess AG), Plastomoll ® (Messrs. BASF AG), from the class of Polyadipates, eg under the name Ultramoll ® (Fa. Lanxess AG), and from the class of sebacates, for example, under the designation Synative ® (Fa. Cognis GmbH) are commercially available.
Im Fall eines flüssigen Verdampfungshemmers kann dieser zum Lösen bzw. zum -Suspendieren des Insektizids benutzt werden und dann auf den Träger gesprüht werden.In the case of a liquid evaporation inhibitor, it can be used for dissolving or suspending the insecticide and then sprayed on the carrier.
Bevorzugt werden die insektizidhaltigen Granulate hergestellt, indem das Insektizid in dem entsprechenden, bevorzugt flüssigen, Verdampfungshemmer gelöst und anschließend auf das Trägermaterial appliziert wird. Die Applikation erfolgt bevorzugt durch Sprühapplikation.The insecticide-containing granules are preferably prepared by dissolving the insecticide in the corresponding, preferably liquid, evaporation inhibitor and then applying it to the carrier material. The application is preferably carried out by spray application.
Der Gehalt an Verdampfungshemmer, bezogen auf die in den erfindungsgemäßen Mitteln enthaltenen Granulate, kann in einem weiten Bereich variiert werden. Nach oben begrenzt wird der Gehalt dadurch, dass die Fließfähigkeit des Granulats erhalten bleiben sollte. Typischerweise liegt
er bei 0,5 bis 50 Gew.-%, bevorzugt bei 1 bis 30 Gew.-%, besonders bevorzugt bei 2 bis 25 Gew.- % und ganz besonders bevorzugt bei 5 bis 20 Gew.-%.The content of evaporation inhibitor, based on the granules contained in the agents according to the invention, can be varied within a wide range. The upper limit is the content in that the flowability of the granules should be maintained. Typically lies it is from 0.5 to 50% by weight, preferably from 1 to 30% by weight, more preferably from 2 to 25% by weight and most preferably from 5 to 20% by weight.
Ebenfalls Gegenstand der vorliegenden Erfindung sind Granulate, enthaltend Trägermaterial, Insektizid und Verdampfungshemmer, wobei die Granulate Teilchengrößen von 50 μm bis 800 μm aufweisen.Likewise provided by the present invention are granules containing carrier material, insecticide and evaporation inhibitor, the granules having particle sizes of 50 μm to 800 μm.
Die Herstellung der erfindungsgemäßen Begasungsmittel erfolgt nach bekannten Methoden, die im Folgenden beispielhaft erläutert werden. Prinzipiell ist jedes bekannte Herstellungsverfahren leicht so veränderbar, dass damit erfindungsgemäße Mittel hergestellt werden können.The preparation of the fumigant according to the invention is carried out by known methods, which are exemplified below. In principle, any known production method is easily changeable so that means according to the invention can be produced.
Zur Erzeugung einer Klebewirkung werden Stärke oder stärkeähnliche Produkte unterschiedlicher Herkunft eingesetzt und in heißem Wasser oder durch Wasserdampf gekocht. Dabei entsteht ein klebriger und gerade noch fließfähiger Teig. Auch der Einsatz von industriell erzeugter, vorgequollener Stärke in pulverisierter Form ist zur Vereinfachung des Prozesses möglich. Wegen der höheren Kosten werden solche Produkte jedoch selten eingesetzt. In höher mechanisiertenTo produce an adhesive effect starch or starch-like products of different origin are used and cooked in hot water or steam. This creates a sticky and just still flowable dough. Also, the use of industrially produced, pre-swollen starch in powdered form is possible to simplify the process. However, because of the higher cost, such products are rarely used. In higher mechanized
Betrieben und größeren Produktionschargen wird dieser Prozessschritt in speziellen Knetern durchgeführt.On farms and larger production batches, this process step is carried out in special kneaders.
Der Basisrohstoff der Begasungsmittel sind Holzmehle unterschiedlicher Provenienz entsprechend der lokalen Verfügbarkeit. Mehle von tropischen Harthölzern und Kokosschalen in verschiedenen Mischungsverhältnissen ergeben Vorteile sowohl in der Herstellung als auch in der Produktqualität. Das Holzmehl kann auch durch gemahlene Holzkohle ersetzt werden. Dies ergibt schwarze Produkte, die keinen weiteren Farbstoff benötigen. Für die Herstellung der Mischung kommen große Band- oder Schaufelmischer zum Einsatz. Zu den Holzmehlen werden auch die wirkstoffhaltigen Granulate, die die Besonderheit der erfindungsgemäßen Begasungsmittel sind, in der gewünschten Menge hinzugefügt.The basic raw material of the fumigants are wood flours of different provenance according to local availability. Flours of tropical hardwoods and coconut shells in various proportions give advantages both in production and in product quality. The wood flour can also be replaced by ground charcoal. This results in black products that do not require another dye. For the preparation of the mixture large belt or paddle mixers are used. The wood meals are also the active ingredient-containing granules, which are the peculiarity of the fumigant invention, added in the desired amount.
Häufig werden Coils, die normalerweise braun sind, durch Zugabe von Farbstoff gefärbt. Neben grünem Farbstoff wird auch vereinzelt roter Farbstoff verwendet.Frequently, coils that are usually brown are colored by the addition of dye. In addition to green dye also occasionally red dye is used.
Die Holzmehlmischung, Klebstoff und gegebenenfalls Farbe werden schließlich in einem Walzenmischer vereinigt und bis zur Erreichung der erforderlichen Homogenität und Konsistenz geknetet, gemischt und gewalzt. Die fertige Masse wird danach in einen Vorratsbehälter entleert, aus dem der folgende kontinuierlich arbeitende Band - Extruder gespeist wird.The wood flour mixture, adhesive and optionally color are finally combined in a roller mixer and kneaded until mixed to the required homogeneity and consistency, mixed and rolled. The finished mass is then emptied into a reservoir from which the following continuously operating belt extruder is fed.
Mittels Doppelwellen -Extrudern wird die Coilmasse bei höherer Temperatur zu einem ca. 5 mm dickem und bis zu 20 cm breiten und glatten Band extrudiert. Dieses Band wird in ca. 1,20 m lange
Stücke geschnitten, die einer Stanzmaschine zugeführt werden. Stanzen in unterschiedlichen Mechanisierungsgraden sind im Einsatz.By means of double-shaft extruders, the coil mass is extruded at a higher temperature to form a strip which is approximately 5 mm thick and up to 20 cm wide and smooth. This volume will be about 1.20 m long Cut pieces that are fed to a punching machine. Punching in different degrees of mechanization are in use.
Die Trocknung der Produkte erfolgt beispielweise in der Weise, dass die ausgestanzten Produkte per Hand auf Drahtnetz - oder Lochblechhorden gelegt und diese auf Hordenwagen gestapelt werden. Zur Trocknung der Produkte werden diese Hordenwagen in Trockenräume gefahren und während 6 - 8 Stunden bei 60° - 700C getrocknet.The drying of the products takes place, for example, in such a way that the punched products are placed by hand on wire mesh or perforated metal trays and these are stacked on trolleys. To dry the products, these trolleys are moved into drying rooms and dried for 6 - 8 hours at 60 ° - 70 0 C.
Hochmechanisierte Betriebe betreiben kontinuierliche Trockner, die sich unmittelbar an die Stanzmaschinen anschließen und automatisch beschickt werden. Die Produkte liegen in kleineren Horden, die ihrerseits in 2 Endlosketten hängen und über mehrere Etagen durch den Ofen geführt werden. Die Öfen können bis zu 60 m lang und 8 m hoch und mit Endlosketten bis zu 600 m Länge bestückt sein. Die Trockentemperatur beträgt ebenfalls 60° - 700C und die Verweilzeit der Coils 3 - 4- Stunden.Highly mechanized companies operate continuous dryers, which connect directly to the punching machines and are fed automatically. The products are in smaller hordes, which in turn hang in 2 endless chains and are passed over several floors through the oven. The ovens can be up to 60 m long and 8 m high and equipped with endless chains up to 600 m in length. The drying temperature is also 60 ° - 70 0 C and the residence time of the coils 3 - 4 hours.
Die Trocknung der Coils ist beendet, wenn der Feuchtigkeitsgehalt 6 - 8 % beträgt.The drying of the coils is finished when the moisture content is 6 - 8%.
Gegenstand der vorliegenden Erfindung ist ein Verfahren zur Herstellung der erfϊndungsgemäßen Begasungsmittel, dadurch gekennzeichnet, dass zunächst Holzmehl mit dem insektizidhaltigen Granulat gemischt wird und anschließend Klebstoff in Form von Stärke oder stärkeähnlichen Produkten sowie gegebenenfalls Farbe zugegeben und geknetet, gemischt und gewalzt werden und die resultierende Masse extrudiert und getrocknet wird.The present invention is a process for producing the inventive fumigant, characterized in that first wood meal is mixed with the insecticide-containing granules and then adhesive in the form of starch or starch-like products and optionally color is added and kneaded, mixed and rolled and the resulting mass is extruded and dried.
Je nach verwendetem Wirkstoff lassen sich die erfϊndungsgemäßen Begasungsmittel gegen unterschiedliche Insekten verwenden. Dies können z.B. sein:Depending on the active ingredient used, the fumigants according to the invention can be used against different insects. This can e.g. be:
Aus der Ordnung der Scorpionidea z.B. Buthus occitanus.From the order of Scorpionidea e.g. Buthus occitanus.
Aus der Ordnung der Acarina z.B. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.From the order of Acarina e.g. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.
Aus der Ordnung der Araneae z.B. Aviculariidae, Araneidae.From the order of the Araneae e.g. Aviculariidae, Araneidae.
Aus der Ordnung der Opiliones z.B. Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.From the order of Opiliones e.g. Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
Aus der Ordnung der Isopoda z.B. Oniscus asellus, Porcellio scaber.
Aus der Ordnung der Diplopoda z.B. Blaniulus guttulatus, Polydesmus spp..From the order of the Isopoda eg Oniscus asellus, Porcellio scaber. From the order of the Diplopoda eg Blaniulus guttulatus, Polydesmus spp ..
Aus der Ordnung der Chilopoda z.B. Geophilus spp..From the order of Chilopoda e.g. Geophilus spp ..
Aus der Ordnung der Zygentoma z.B. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.From the order of Zygentoma e.g. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
Aus der Ordnung der Blattaria z.B. Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa.From the order of the Blattaria e.g. Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa.
Aus der Ordnung der Saltatoria z.B. Acheta domesticus.From the order of Saltatoria e.g. Acheta domesticus.
Aus der Ordnung der Dermaptera z.B. Forficula auricularia.From the order of the Dermaptera e.g. Forficula auricularia.
Aus der Ordnung der Isoptera z.B. Kalotermes spp., Reticulitermes spp.From the order of Isoptera e.g. Kalotermes spp., Reticulitermes spp.
Aus der Ordnung der Psocoptera z.B. Lepinatus spp., Liposcelis spp.From the order of Psocoptera e.g. Lepinatus spp., Liposcelis spp.
Aus der Ordnung der Coleoptera z.B. Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum.From the order of Coleoptera e.g. Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum.
Aus der Ordnung der Diptera z.B. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys calcitrans, Tipula paludosa.From the order of Diptera e.g. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys Calcitrans, Tipula paludosa.
Aus der Ordnung der Lepidoptera z.B. Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.From the order of Lepidoptera e.g. Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
Aus der Ordnung der Siphonaptera z.B. Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.From the order of siphonaptera e.g. Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.
Aus der Ordnung der Hymenoptera z.B. Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetra~τnorium caespitum.From the order of Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetra ~ τnorium caespitum.
Aus der Ordnung der Anoplura z.B. Pediculus humanus capitis, Pediculus humanus corporis, Pemphigus spp., Phylloera vastatrix, Phthirus pubis.
Aus der Ordnung der Heteroptera z.B. Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.From the order of Anoplura eg Pediculus humanus capitis, Pediculus humanus corporis, Pemphigus spp., Phylloera vastatrix, Phthirus pubis. From the order of Heteroptera eg Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.
Bevorzugt ist die Verwendung zur Bekämpfung von Insekten aus der Klasse der Diptera, z.B. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys calcitrans, Tipula paludosa.Preferably, the use for controlling insects from the class of Diptera, e.g. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys Calcitrans, Tipula paludosa.
Die Anwendung der erfϊndungsgemäßen Begasungsmittel erfolgt in bekannter Weise durch Entzünden.
The application of the fumigant according to the invention is carried out in a known manner by ignition.
HerstellungsbeispielePreparation Examples
Beispiel AExample A
Tranfluthrin wurde in Adipat (Plastomoll® DOA) in einer Konzentration von 20 Gew.-% gelöst. Die resultierende Lösung wurde auf ein Granulat (Sepiolith® 30/60) durch Sprühen in einer Menge von 15 Gew.-% aufgebracht.Tranfluthrin was adipate (DOA Plastomoll ®) in a concentration of 20 wt .-% dissolved. The resulting solution was coated on a granulate (sepiolite ® 30/60) was applied by spraying in an amount of 15 wt .-%.
Beispiel BExample B
Analog zu Beispiel A wurde ein Granulat mit 3 Gew.-% Transfluthrin, 12 Gew.-% Isopar® M und 85 Gew.-% Biodac® 20/50 hergestellt.Analogously to Example A, a granulate with 3 wt .-% transfluthrin, 12 wt .-% Isopar ® M and 85 wt .-% Biodac ® 20/50 was prepared.
Beispiel CExample C
Analog zu Beispiel A wurde ein Granulat mit 3 Gew.-% Transfluthrin, 12 Gew.-% Synative® ES DEHS und 85 Gew.-% Biodac® 20/50 hergestellt.Analogously to Example A a granulate with 3 wt .-% transfluthrin, 12 wt .-% Synative ® ES DEHS and 85 wt .-% Biodac 20/50 ® was prepared.
Beispiel DExample D
Analog zu Beispiel A wurde ein Granulat mit 3 Gew.-% Transfluthrin, 12 Gew.-% Plastomoll® DOA und 85 Gew.-% Sepiolith® 30/60 hergestellt.Analogous to Example A, a granulate with 3 wt .-% transfluthrin, 12 wt .-% Plastomoll ® DOA and 85 wt .-% Sepiolith ® 30/60 was prepared.
Beispiel EExample E
Analog zu Beispiel A wurde ein Granulat mit 5 Gew.-% Transfluthrin, 10 Gew.-% Plastomoll® DOA und 85 Gew.-% Biodac ® 20/50 hergestellt.Analogously to Example A was a pellet with 5 wt .-% transfluthrin, 10 wt .-% produced Plastomoll ® DOA and 85 wt .-% Biodac 20/50 ®.
Beispiel FExample F
Analog zu Beispiel A wurde ein Granulat mit 3 Gew.-% Transfluthrin, 10 Gew.-% Plastomoll® DOA und 85 Gew.-% Bims (Körnung 0,3 bis 1 mm) hergestellt.Analogous to Example A, a granulate with 3 wt .-% transfluthrin, 10 wt .-% Plastomoll ® DOA and 85 wt .-% pumice (grain size 0.3 to 1 mm) was prepared.
Beispiel GExample G
Analog zu Beispiel A wurde ein Granulat mit 5 Gew.-% Transfluthrin, 10 Gew.-% Plastomoll® DOA und 85 Gew.-% Bims (Körnung 90 bis 600 μm) hergestellt.
Beispiel 1Analogous to Example A, a granulate with 5 wt .-% transfluthrin, 10 wt .-% Plastomoll ® DOA and 85 wt .-% pumice (grain size 90 to 600 microns) was prepared. example 1
Zur Herstellung von wirkstoffhaltigen Granulaten wurden Vorlösungen von Transfluthrin in verschiedenen Lösemitteln auf das absortive Trägermaterial Sepiolith 30/60 in einem rotierenden Dragierkessel bei Raumtemperatur aufgetragen. Es wurden fließfähige Granulate mit homogener WirkstoffVerteilung erhalten, deren Zusammensetzung in Tabelle 1 dargestellt ist.To prepare active ingredient-containing granules, preliminary solutions of transfluthrin in various solvents were applied to the absortive carrier material sepiolite 30/60 in a rotating coating pan at room temperature. There were obtained flowable granules with homogeneous drug distribution, whose composition is shown in Table 1.
Tabelle 1: Zusammensetzung der Transfluthrin-GranulateTable 1: Composition of transfluthrin granules
Zur Herstellung von wirkstoffhaltigen Coils bei 70° in einem Mischkneter (Becolabmini, Becomix) wurden 92 g eines Stärkepulvers und 270 g eines Kokospulver zusammen mit 3,9 g einer der obengenannten Wirkstoffgranulate 10 min bei 70° gemischt. Anschließend werden 599 g heißes Wasser (90-1000C) mit 0,3 g Natriumbenzoat zugegeben und weitere 20 min bis zu einem homogenen Teig geknetet. Dieser Teig wurde mit einem handgetriebenen Tischdruckfüller (Dick) zu coils mit einem Durchmesser von 6 mm extrudiert, welche 7h bei 600C getrocknet wurden.For the production of active substance-containing coils at 70 ° in a mixing kneader (Becolabmini, Becomix), 92 g of a starch powder and 270 g of a coconut powder were mixed with 3.9 g of one of the above-mentioned active ingredient granules for 10 min at 70 °. Subsequently, 599 g of hot water (90-100 0 C) are added with 0.3 g of sodium benzoate and kneaded for a further 20 min to a homogeneous dough. This dough was extruded with a hand-driven tabletop pressure filler (Dick) into coils with a diameter of 6 mm, which were dried at 60 0 C for 7 h.
Der Wirkstoffgehalt dieser fertigen Coils wurde sowohl direkt nach Herstellung, als auch nach offener Lagerung in einem 25 m3 Klimakammer bei 400C. Die Ergebnisse sind in Tabelle 2 dargestellt.
Tabelle 2: Experimenteller Wirkstoffgehalt der Transfluthrin-haltigen Coils (in Gew%), hergestellt mit den Granulaten GR1-GR3.The active ingredient content of these finished coils was both directly after preparation, as well as after open storage in a 25 m 3 climate chamber at 40 0 C. The results are shown in Table 2. Table 2: Experimental content of the transfluthrin-containing coils (in% by weight), prepared with the granules GR1-GR3.
Erst nach 72 h offene Lagerung bei 400C wurde einen geringen Verlust von 3-6 % Wirkstoff beobachtet.Only after 72 h open storage at 40 0 C was a slight loss of 3-6% drug observed.
Holz- und Kokosmehle: Partikelgröße: 80 mesh (0.180 mm), Toleranz: +/- 10 %, Wassergehalt maximal 13 %Wood and coconut flours: Particle size: 80 mesh (0.180 mm), tolerance: +/- 10%, maximum water content 13%
Schüttdichte: Holzmehl 0,23 +/- 2 g/ccm, Kokosmehl 0,48 g/ccmBulk density: wood flour 0,23 +/- 2 g / ccm, coconut flour 0,48 g / ccm
Stärke: Viskosität min 60.000 cps (Brookfield HBT 230 V Spindel 2 0.3 rpm, 45 g in 450 ml Wasser, 95°C)Starch: viscosity min 60,000 cps (Brookfield HBT 230 V spindle 2 0.3 rpm, 45 g in 450 ml water, 95 ° C)
Gum Powder (Holz-Klebepulver): Viskosität min 3.500 cps (Brookfield HBT 230 V SpindelGum Powder (wood adhesive powder): viscosity min 3.500 cps (Brookfield HBT 230 V spindle
3; 0.3 rpm, 15 g in 400 ml Wasser)3; 0.3 rpm, 15 g in 400 ml of water)
VergleichsbeispielComparative example
Zur Herstellung von einem wirkstoffhaltigen Granulat wurde analog Beispiel 1 vorgegangen, jedoch als Wirkstoffquelle wurde statt 3,9 g Granulate (3%ig) 0,59 g ein emulgierbares Konzentrat (Transfluthrin EC 20, entspricht „Stand der Technik") eingesetzt. Die Zusammensetzung dieses Konzentrats ist in Tabelle 3 dargestellt.
Tabelle 3: Zusammensetzung von Transfluthrin EC 20The preparation of active ingredient-containing granules was carried out analogously to Example 1, but instead of 3.9 g of granules (3% strength), 0.59 g of an emulsifiable concentrate (transfluthrin EC 20, equivalent to "prior art") were used as the active ingredient this concentrate is shown in Table 3. Table 3: Composition of transfluthrin EC 20
Der Wirkstoffgehalt des coils wurde sowohl direkt nach Herstellung, als auch nach offener Lagerung in einem 25m3 Klimakammer bei 400C. Die Ergebnisse sind in Tabelle 4 dargestellt.The active ingredient content of the coils was both directly after preparation, and after open storage in a climatic chamber at 25 m 3 40 0 C. The results are shown in Table 4 below.
Tabelle 4: Experimenteller Wirkstoffgehalt des transfluthrin-haltigen coils (in %), hergestellt mit dem Transfluthrin EC 20.Table 4: Experimental content of the transfluthrin-containing coil (in%), produced with the transfluthrin EC 20.
Im Gegensatz zu den Coils in Beispiel 1 wurde einen signifϊcanten Wirkstoffverlust während der Lagerung wurde beobachtet (8% nach 24h und 11% nach 72h).
In contrast to the coils in Example 1, a significant loss of active ingredient during storage was observed (8% after 24h and 11% after 72h).
Claims
1. Brennbares insektizides Begasungsmittel, dadurch gekennzeichnet, dass dieses ein Insektizid, ein Granulat als Trägermaterial sowie einen Verdampfungshemmer umfasst.1. A combustible insecticidal fumigant, characterized in that it comprises an insecticide, a granule as a carrier material and an evaporation inhibitor.
2. Brennbares insektizides Begasungsmittel gemäß Anspruch 1, dadurch gekennzeichnet, dass das Granulat Partikel sind, die eine mittlere Teilchengröße von wenigstens 50 μm aufweisen.2. Combustible insecticidal fumigant according to claim 1, characterized in that the granules are particles having an average particle size of at least 50 microns.
3. Brennbares insektizides Begasungsmittel gemäß Anspruch 1, dadurch gekennzeichnet, dass als Trägermaterial poröse Träger auf Basis von Cellulose, Meerschaum oder Bims geeignet sind.3. Combustible insecticidal fumigant according to claim 1, characterized in that are suitable as support material porous support based on cellulose, meerschaum or pumice.
4. Brennbares insektizides Begasungsmittel gemäß Anspruch 1, dadurch gekennzeichnet, dass als Verdampfungshemmer Adipate, Polyadipate oder Sebacate eingesetzt werden.4. Combustible insecticidal fumigant according to claim 1, characterized in that are used as evaporation inhibitors adipates, polyadipates or sebacates.
5. Verfahren zur Herstellung der brennbaren insektiziden Begasungsmittel gemäß Anspruch 1, dadurch gekennzeichnet, dass zunächst Holzmehl mit dem insektizidhaltigen Granulat gemischt wird und anschließend Klebstoff in Form von Stärke oder stärkeähnlichen Produkten sowie gegebenenfalls Farbe zugegeben und geknetet, gemischt und gewalzt werden und die resultierende Masse extrudiert und getrocknet wird.5. A process for the preparation of the combustible insecticidal fumigant according to claim 1, characterized in that first wood meal is mixed with the insecticide-containing granules and then adhesive in the form of starch or starch-like products and optionally color is added and kneaded, mixed and rolled and the resulting mass is extruded and dried.
6. Granulate, enthaltend Trägermaterial, Insektizid und Verdampfungshemmer, wobei die Granulate Teilchengrößen von 50 μm bis 800 μm aufweisen.6. granules containing carrier material, insecticide and evaporation inhibitor, wherein the granules have particle sizes of 50 microns to 800 microns.
7. Verwendung der Granulate gemäß Anspruch 6 zur Herstellung eines brennbaren insektiziden Begasungsmittels.7. Use of the granules according to claim 6 for the preparation of a combustible insecticidal fumigant.
8. Brennbares insektizides Begasungsmittel, dadurch gekennzeichnet, dass das Insektizid in Form eines Granulats enthalten ist.8. Flammable insecticidal fumigant, characterized in that the insecticide is contained in the form of granules.
9. Brennbares insektizides Begasungsmittel, erhältlich durch Verwendung eines wirkstoffhaltigen Granulats während der Herstellung.9. Combustible insecticidal fumigant, obtainable by using an active ingredient-containing granules during production.
10. Verwendung eines insektiziden Granulats zur Herstellung eines brennbaren insektiziden Begasungsmittels.10. Use of an insecticidal granulate for the production of a combustible insecticidal fumigant.
11. Verfahren zur Herstellung eines brennbaren insektiziden Begasungsmittels, dadurch gekennzeichnet, dass der insektizide Wirkstoff in Form eines Granulats zugegeben wird. 11. A process for the preparation of a combustible insecticidal fumigant, characterized in that the insecticidal active ingredient is added in the form of a granulate.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09778392A EP2334171A2 (en) | 2008-09-16 | 2009-09-08 | Insecticidal gassing agent containing active ingredient in the form of a granulate |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08164383 | 2008-09-16 | ||
EP09778392A EP2334171A2 (en) | 2008-09-16 | 2009-09-08 | Insecticidal gassing agent containing active ingredient in the form of a granulate |
PCT/EP2009/006503 WO2010031507A2 (en) | 2008-09-16 | 2009-09-08 | Insecticidal gassing agent containing active ingredient in the form of a granulate |
Publications (1)
Publication Number | Publication Date |
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EP2334171A2 true EP2334171A2 (en) | 2011-06-22 |
Family
ID=40343647
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP09778392A Withdrawn EP2334171A2 (en) | 2008-09-16 | 2009-09-08 | Insecticidal gassing agent containing active ingredient in the form of a granulate |
Country Status (8)
Country | Link |
---|---|
US (1) | US20110262367A1 (en) |
EP (1) | EP2334171A2 (en) |
JP (1) | JP2012502886A (en) |
CN (1) | CN102149279A (en) |
BR (1) | BRPI0918624A2 (en) |
MX (1) | MX2011002743A (en) |
RU (1) | RU2011114820A (en) |
WO (1) | WO2010031507A2 (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0693254A1 (en) * | 1994-07-14 | 1996-01-24 | Bayer Ag | Gel formulations containing insecticides for vaporizer systems |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2590529A (en) * | 1948-03-03 | 1952-03-25 | Ici Ltd | Fumigating compositions |
JPH0454102A (en) * | 1990-06-22 | 1992-02-21 | Namikata Jiyochiyuufun Seizosho:Kk | Combustible composition suitable for smoking perspiration of pest eliminator |
KR960011194B1 (en) * | 1993-07-29 | 1996-08-21 | 재단법인 한국화학연구소 | Smoke generator carrying agricultural chemicals and process for preparation thereof |
JP3227506B2 (en) * | 1993-08-20 | 2001-11-12 | 株式会社南方除虫粉製造所 | Smoking agent |
US6451332B1 (en) * | 1997-12-16 | 2002-09-17 | Sumitomo Chemical Company, Limited | Pesticidal composition having high pesticidal ingredient vaporization rate method for controlling pests, and method for producing a pesticidal composition |
-
2009
- 2009-09-08 JP JP2011526403A patent/JP2012502886A/en not_active Withdrawn
- 2009-09-08 US US13/063,327 patent/US20110262367A1/en not_active Abandoned
- 2009-09-08 WO PCT/EP2009/006503 patent/WO2010031507A2/en active Application Filing
- 2009-09-08 RU RU2011114820/13A patent/RU2011114820A/en not_active Application Discontinuation
- 2009-09-08 MX MX2011002743A patent/MX2011002743A/en unknown
- 2009-09-08 EP EP09778392A patent/EP2334171A2/en not_active Withdrawn
- 2009-09-08 BR BRPI0918624A patent/BRPI0918624A2/en not_active IP Right Cessation
- 2009-09-08 CN CN200980136011XA patent/CN102149279A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0693254A1 (en) * | 1994-07-14 | 1996-01-24 | Bayer Ag | Gel formulations containing insecticides for vaporizer systems |
Also Published As
Publication number | Publication date |
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US20110262367A1 (en) | 2011-10-27 |
CN102149279A (en) | 2011-08-10 |
WO2010031507A3 (en) | 2010-07-29 |
MX2011002743A (en) | 2011-04-07 |
RU2011114820A (en) | 2012-10-27 |
WO2010031507A2 (en) | 2010-03-25 |
BRPI0918624A2 (en) | 2015-09-22 |
JP2012502886A (en) | 2012-02-02 |
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