EP2320163A2 - Heat pump system - Google Patents
Heat pump system Download PDFInfo
- Publication number
- EP2320163A2 EP2320163A2 EP09810158A EP09810158A EP2320163A2 EP 2320163 A2 EP2320163 A2 EP 2320163A2 EP 09810158 A EP09810158 A EP 09810158A EP 09810158 A EP09810158 A EP 09810158A EP 2320163 A2 EP2320163 A2 EP 2320163A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat
- heat exchanger
- conduit
- refrigerant
- accumulator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B30/00—Heat pumps
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B13/00—Compression machines, plants or systems, with reversible cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2313/00—Compression machines, plants or systems with reversible cycle not otherwise provided for
- F25B2313/021—Indoor unit or outdoor unit with auxiliary heat exchanger not forming part of the indoor or outdoor unit
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2313/00—Compression machines, plants or systems with reversible cycle not otherwise provided for
- F25B2313/027—Compression machines, plants or systems with reversible cycle not otherwise provided for characterised by the reversing means
- F25B2313/02741—Compression machines, plants or systems with reversible cycle not otherwise provided for characterised by the reversing means using one four-way valve
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2400/00—General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
- F25B2400/24—Storage receiver heat
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B30/00—Heat pumps
- F25B30/06—Heat pumps characterised by the source of low potential heat
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D21/00—Defrosting; Preventing frosting; Removing condensed or defrost water
- F25D21/06—Removing frost
- F25D21/12—Removing frost by hot-fluid circulating system separate from the refrigerant system
Definitions
- the present invention relates generally to heat pump systems and, more particularly, to a defrosting and cooling promotion structure of an outdoor heat exchanger of a heat pump system.
- a heat pump operates a vapor-compression refrigeration cycle in the reverse manner to that of cooling operation, that is, when a heating operation is carried out, an indoor heat exchanger is used as a condenser, and an outdoor heat exchanger is used as an evaporator, whereas when a cooling operation is carried out, the outdoor heat exchanger is used as the condenser, and the indoor heat exchanger is used as the evaporator. Therefore, the evaporation or condensation of refrigerant in an outdoor heat exchanger must be satisfactory in order for the coefficient of performance to be enhanced.
- the inventor and applicant of the present invention developed a heat pump system which can solve the above-mentioned most important factor of the heat pump, and this heat pump system was disclosed in Patent document 1.
- the heat pump system includes a base refrigeration circuit, a heat accumulator, a heating heat exchanger, a heat exchanger and first and second 2 endothermic heat exchangers.
- a compressor, a four-way valve, an indoor heat exchanger, a cooling expansion valve, a heating expansion valve, an outdoor heat exchanger and the four-way valve are connected in sequence by a conduit.
- the four-way valve is connected to the compressor by a suction conduit.
- the heat accumulator is provided on the conduit between the cooling expansion valve and the heating expansion valve.
- the heat accumulator is charged with a heat medium and contains a latent heat storage material.
- the heating heat exchanger is provided on the portion of the conduit that passes through the heat accumulator.
- the heat exchanger is connected to the heat accumulator by a return conduit to which a supply conduit and a circulation pump are coupled.
- the heat exchanger is located adjacent to an inlet side of the outdoor heat exchanger.
- the first and second endothermic heat xchangers are provided in parallel on the suction conduit and are installed in the heat accumulator so that they are selectively operated depending on the temperature of refrigerant vapor sucked into the compressor.
- the heating heat exchanger functions as a supercooling condenser so that the heat of condensation is stored in the heat medium contained in the heat accumulator that is maintained at a predetermined temperature, and when the temperature of the atmosphere decreases to at or below the dew point or increases to a preset temperature or more, the heat medium circulates through the outdoor heat exchanger to heat or cool the outside air sucked into the outdoor heat exchanger.
- the outdoor heat exchanger can be defrosted or prevented from having frost form on it.
- the condensation of refrigerant vapor becomes satisfactory. Therefore, even when the temperature of the atmosphere is comparatively low or high, the coefficient of performance can be enhanced. Furthermore, because dry-saturated or superheated vapor is sucked into the compressor, the coefficient of performance can be further enhanced.
- refrigerant liquid is supercooled, and the outside air sucked into the outdoor heat exchanger is heated or cooled, so that even when the temperature of the atmosphere is comparatively high or low, the coefficient of performance can be enhanced without interrupting the operation of the system.
- the refrigerant liquid may be excessively supercooled.
- the supercooled state of the refrigerant liquid exceeds the optimum level, although the coefficient of performance is increased, the specific volume of the refrigerant liquid is reduced.
- evaporation of refrigerant supplied into the outdoor heat exchanger further deteriorates, resulting in suction of wet-saturated vapor into the compressor.
- an object of the present invention is to provide a heat pump system which heats or cools the outdoor heat exchanger by using a costless heat source and the supercooled condensation heat of refrigerant liquid to maintain the refrigerant liquid at an appropriate degree of supercooling, and increase the coefficient of performance without using a fee-charging heat source.
- the present invention provides a heat pump system, including: a base refrigeration circuit in which a compressor, a four-way valve, an indoor heat exchanger, a cooling expansion valve, a heating expansion valve, an outdoor heat exchanger and the four-way valve are connected in a sequence by a refrigerant conduit, and the four-way valve and the compressor are connected to each other by a refrigerant suction conduit; a heat accumulator comprising a bypass refrigerant conduit having both ends connected to the refrigerant conduit between the cooling expansion valve and the heating expansion valve, the heat accumulator having therein a heating heat exchanger provided on the bypass refrigerant conduit, with a heat medium injected into the heat accumulator; an auxiliary heat exchanger connected to the heat accumulator by a heat medium supply conduit provided with a heat medium circulation pump and by a heat medium return conduit, the auxiliary heat exchanger being installed in the outdoor heat exchanger; and an outdoor heat exchanger defrosting and cooling means having a heat exchanger connected to
- the heat exchanger when the temperature of the atmosphere is at or below a predetermined temperature (for example, 5°C) or is at or above a predetermined temperature (for example, 30°C), the heat exchanger is maintained at a predetermined temperature by a costless heat source flowing through a heat accumulator, and brine which is maintained at a predetermined temperature circulates through a heat exchanger installed in the outdoor heat exchanger.
- a predetermined temperature for example, 5°C
- a predetermined temperature for example, 30°C
- the heat medium that has been heated and stored in the heat accumulator circulates through the auxiliary heat exchanger installed in the outdoor heat exchanger, so that the coefficient of performance can still be satisfactory.
- Fig. 1 is a diagram showing the construction of an embodiment of the present invention.
- Fig. 1 is a diagram showing the construction of an embodiment of the present invention.
- Reference numeral 10 denotes a base refrigeration circuit.
- a compressor 11 a compressor 11, a four-way valve 12, an indoor heat exchanger 13, a cooling expansion valve 14, a heating expansion valve 15, an outdoor heat exchanger 16 and the four-way valve 12 are connected in a sequence by a refrigerant conduit 17.
- the four-way valve 12 is connected to the compressor 11 by a refrigerant suction conduit 18.
- Reference numeral 20 denotes a heat accumulator.
- the heat accumulator 20 includes a bypass refrigerant conduit 21, both ends of which are connected to the refrigerant conduit 17 at positions spaced apart from each other by a predetermined distance between the cooling expansion valve 14 and the heating expansion valve 15.
- the heat accumulator 20 contains therein a heating heat exchanger 22 which is provided on the bypass refrigerant conduit 21.
- the heat accumulator 20 is injected with a heat medium 23.
- Reference numeral 30 denotes an auxiliary heat exchanger.
- the auxiliary heat exchanger 30 is connected to the heat accumulator 20 by a heat medium supply conduit 31 provided with a heat medium circulation pump 32 and by a heat medium return conduit 33 in such a way that heat pipes of the auxiliary heat exchanger 30 are located between the heat pipes of the outdoor heat exchanger 16 at positions spaced apart from each other at regular intervals or are integrally or separately installed on a side surface of the outdoor heat exchanger 16. It is desirable that the heat pipes of the auxiliary heat exchanger 30 be located between the heat pipes of the outdoor heat exchanger 16 at regular intervals, because heat transfer efficiency can be more enhanced.
- Reference numeral 40 denotes an outdoor heat exchanger defrosting and cooling means.
- the outdoor heat exchanger defrosting and cooling means 40 includes a heat exchanger 41 which is connected to the heat medium supply conduit 31 and the heat medium return conduit 33 by a brine supply conduit 42 provided with a brine circulation pump 43 and by a brine return conduit 44. Furthermore, a costless heat reservoir 45 is located around the heat exchanger 41. A costless heat source circulates through the costless heat reservoir 45 so that there is continuous heat exchange between the costless heat source and the heat exchanger 41 in order to maintain brine circulating through the auxiliary heat exchanger 30 at an appropriate temperature (for example, about 20°C).
- Regenerative energy such as river water, seawater, collected underground water, fluid (e.g., air or hot water) heated by a solar collector, rainwater, waste water, etc.
- fluid e.g., air or hot water
- a solar collector e.g., water
- rainwater e.g., waste water
- regenerative energy can be easily obtained from around a place where the present invention is installed.
- the temperature of the costless heat source be as high as possible, in particular, in the cold season.
- the temperature of the costless heat source not be over 25°C.
- a refrigerant suction bypass conduit 50 passes through the heat accumulator 20 and is connected to the refrigerant suction conduit 18.
- An endothermic heat exchanger 51 is provided on the portion of the refrigerant suction bypass conduit 50 that passes through the heat accumulator 20. The endothermic heat exchanger 51 heats refrigerant gas to be sucked into the compressor 11 so that the refrigerant gas is dry-saturated and superheated to prevent liquid back phenomenon and liquid hammer phenomenon of the compressor 11.
- a solenoid valve S1 is provided on the refrigerant conduit 17 at a predetermined position between both ends of the bypass refrigerant conduit 21, and a solenoid valve S2 is provided on the bypass refrigerant conduit 21 in proximity to the junction between the bypass refrigerant conduit 21 and the refrigerant conduit 17.
- a detecting signal generated from a temperature sensor 60 which is provided on the refrigerant conduit 17 between the indoor heat exchanger 13 and the outdoor heat exchanger 16 registers a predetermined temperature range (for example, when it is 35°C or more)
- the solenoid valve S1 closes and the solenoid valve S2 opens to supercool the refrigerant liquid.
- a solenoid valve S3 and a solenoid valve S4 are respectively provided on the heat medium supply conduit 31 and the brine supply conduit 42 at positions adjacent to outlet ports of the circulation pumps 32 and 43.
- a detecting signal generated from a temperature sensor 61 provided on the outdoor heat exchanger 16 is within a predetermined temperature range (for example, during the heating operation, it is 10°C or less, and during the cooling operation, it is 30°C or more)
- the solenoid valve S3 is closed and the solenoid valve S4 is open so that the brine that was heated in the heat exchanger 41 by the costless heat source circulates through the auxiliary heat exchanger 30.
- a temperature sensor 63 is provided on the costless heat reservoir 45 so that when the temperature of the costless heat source decreases to a predetermined temperature, the solenoid valve S3 is open and the solenoid valve S4 is closed in the reverse manner to the above so as to circulate the heat medium, heated and stored in the heat accumulator 20, through the auxiliary heat exchanger 30, thus defrosting the outdoor heat exchanger 16.
- solenoid valves S5 and S6 are respectively provided on the refrigerant suction conduit 18 at a position adjacent to a connection inlet of the refrigerant suction bypass conduit 50 and at the connection inlet of the refrigerant suction bypass conduit 50.
- a detecting signal generated from a temperature sensor 64 provided on the refrigerant suction conduit 18 indicates a preset temperature range (for example, 5°C or less)
- the solenoid valve S5 is closed and the solenoid valve S6 is open so that the refrigerant gas to be sucked into the compressor 11 is superheated by heating it in the heat accumulator 20.
- reference numerals 66 and 67 denote check valves.
- the four-way valve 12 is controlled such that when the heating operation is carried out, the refrigerant flows in the direction of the solid arrow, and when the cooling operation is carried out, the refrigerant flows in the direction of the dotted arrow. Then, when the heating operation is carried out, the indoor heat exchanger 13 functions as a condenser, and when the cooling operation is carried out, the indoor heat exchanger 13 functions as an evaporator.
- the present invention can carry out the heating function or the cooling function in the same manner as that of the conventional technique.
- the brine which is kept at a constant temperature by the costless heat source, circulates through the auxiliary heat exchanger 30 provided on the outdoor heat exchanger 16.
- the outdoor heat exchanger 16 can be defrosted.
- the outdoor heat exchanger 16 is cooled to promote evaporation of the refrigerant gas. Thereby, the coefficient of performance of the heat pump system can remain satisfactory.
- the solenoid valve S2 is open by a detecting signal of the temperature sensor 60 so that the refrigerant liquid is supercooled in the heat accumulator 20, thus enhancing the coefficient of performance.
- the heat medium is heated by the heat of condensation and then stored in the heat accumulator 20.
- the heat medium that has been heated and stored is circulated through the auxiliary heat exchanger 30 so that the coefficient of performance can be maintained satisfactory during the heating operation.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Compression-Type Refrigeration Machines With Reversible Cycles (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020080083160A KR100970870B1 (ko) | 2008-08-26 | 2008-08-26 | 히트 펌프 시스템 |
PCT/KR2009/004625 WO2010024553A2 (ko) | 2008-08-26 | 2009-08-20 | 히트 펌프 시스템 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2320163A2 true EP2320163A2 (en) | 2011-05-11 |
Family
ID=41722080
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09810158A Withdrawn EP2320163A2 (en) | 2008-08-26 | 2009-08-20 | Heat pump system |
Country Status (6)
Country | Link |
---|---|
US (1) | US20110146321A1 (zh) |
EP (1) | EP2320163A2 (zh) |
JP (1) | JP2012500379A (zh) |
KR (1) | KR100970870B1 (zh) |
CN (1) | CN102132110A (zh) |
WO (1) | WO2010024553A2 (zh) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2960629B1 (fr) * | 2010-05-31 | 2014-09-12 | Valeo Systemes Thermiques | Procede de controle d'un dispositif de stockage dans un circuit de refrigerant |
JP5693932B2 (ja) * | 2010-11-29 | 2015-04-01 | 高砂熱学工業株式会社 | 冷却システム、及び冷却方法 |
KR200465485Y1 (ko) * | 2010-12-31 | 2013-02-28 | (주)세종엠엔이 | 하이브리드 히트펌프 시스템 |
US8701432B1 (en) | 2011-03-21 | 2014-04-22 | Gaylord Olson | System and method of operation and control for a multi-source heat pump |
KR101218546B1 (ko) * | 2011-05-23 | 2013-01-09 | 진주환 | 히트 펌프 시스템 |
KR101258181B1 (ko) * | 2011-05-23 | 2013-04-25 | 진주환 | 히트 펌프 시스템 |
CN103115456B (zh) * | 2011-11-16 | 2015-03-25 | 山东天宝空气能热泵技术有限公司 | 复合冷暖系统 |
US9534818B2 (en) | 2012-01-17 | 2017-01-03 | Si2 Industries, Llc | Heat pump system with auxiliary heat exchanger |
KR101351826B1 (ko) | 2012-03-28 | 2014-01-15 | 주식회사 신진에너텍 | 지하수를 이용한 온실용 히트펌프 냉난방 장치 |
KR101258182B1 (ko) * | 2012-05-07 | 2013-04-30 | 진주환 | 히트 펌프 시스템 |
KR101218548B1 (ko) | 2012-05-07 | 2013-01-09 | 진주환 | 히트 펌프 시스템 |
CN102692097A (zh) * | 2012-06-11 | 2012-09-26 | 江苏望远节能科技开发有限公司 | 一种地下含水构造层蓄能循环系统 |
CN102767921B (zh) * | 2012-08-02 | 2014-11-05 | 广东工业大学 | 一种双路预冷的高效热泵装置及其控制方法 |
CN104704300B (zh) * | 2012-10-10 | 2016-10-05 | 三菱电机株式会社 | 空调装置 |
CN104515318B (zh) * | 2013-09-30 | 2016-08-31 | 珠海格力电器股份有限公司 | 空调系统 |
KR101356276B1 (ko) | 2013-11-14 | 2014-01-29 | 이정석 | 공기열 히트펌프의 빙축 및 냉난방 시스템 |
US20150267946A1 (en) * | 2014-03-18 | 2015-09-24 | Suntrac Solar Manufacturing, Llc | Solar panel interface with air conditioning and/or heat pump unit system |
US9976785B2 (en) * | 2014-05-15 | 2018-05-22 | Lennox Industries Inc. | Liquid line charge compensator |
US10330358B2 (en) | 2014-05-15 | 2019-06-25 | Lennox Industries Inc. | System for refrigerant pressure relief in HVAC systems |
CN105276874A (zh) * | 2014-07-10 | 2016-01-27 | 南京理工大学 | 一种利用储存液体过冷热除霜的热泵空调机组 |
CN104807258B (zh) * | 2015-05-25 | 2017-05-03 | 合肥美的暖通设备有限公司 | 空调系统及其的蓄热除霜装置、方法 |
ITUB20153364A1 (it) * | 2015-09-03 | 2017-03-03 | Begafrost S R L | Sistema per lo sbrinamento dell?evaporatore esterno in un impianto a pompa di calore. |
CN106642791A (zh) * | 2016-12-28 | 2017-05-10 | 翁立波 | 一种容积式双工况多功能水风冷机组 |
CN106767079B (zh) * | 2017-01-10 | 2019-01-22 | 美的集团武汉制冷设备有限公司 | 蓄热组件和空调器 |
US10663199B2 (en) | 2018-04-19 | 2020-05-26 | Lennox Industries Inc. | Method and apparatus for common manifold charge compensator |
US10830514B2 (en) | 2018-06-21 | 2020-11-10 | Lennox Industries Inc. | Method and apparatus for charge compensator reheat valve |
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US4569207A (en) * | 1977-04-21 | 1986-02-11 | James Larry S | Heat pump heating and cooling system |
JPS5686463U (zh) * | 1979-12-08 | 1981-07-11 | ||
JPS63161365A (ja) * | 1986-12-24 | 1988-07-05 | 松下電器産業株式会社 | ヒ−トポンプ式空気調和機 |
US4796437A (en) | 1987-10-23 | 1989-01-10 | James Larry S | Multifluid heat pump system |
KR100357988B1 (ko) * | 2000-05-08 | 2002-10-25 | 진금수 | 히트 펌프식 냉·난방장치 |
KR100402366B1 (ko) | 2001-08-31 | 2003-10-17 | 진금수 | 히트 펌프 시스템 |
KR100493493B1 (ko) | 2003-05-31 | 2005-06-02 | 진금수 | 냉동 사이클 |
KR20050119548A (ko) * | 2004-06-16 | 2005-12-21 | 윤명혁 | 온수공급용 히트펌프 시스템 |
CN1804516A (zh) * | 2005-01-10 | 2006-07-19 | 颜世峰 | 空气能热泵加热循环系统 |
CN100458313C (zh) * | 2006-05-26 | 2009-02-04 | 陈则韶 | 有水内循环换热回路的热泵热水机组 |
JP4856489B2 (ja) * | 2006-07-31 | 2012-01-18 | サンデン株式会社 | 給湯装置 |
-
2008
- 2008-08-26 KR KR1020080083160A patent/KR100970870B1/ko not_active IP Right Cessation
-
2009
- 2009-08-20 WO PCT/KR2009/004625 patent/WO2010024553A2/ko active Application Filing
- 2009-08-20 CN CN2009801328557A patent/CN102132110A/zh active Pending
- 2009-08-20 EP EP09810158A patent/EP2320163A2/en not_active Withdrawn
- 2009-08-20 US US13/060,594 patent/US20110146321A1/en not_active Abandoned
- 2009-08-20 JP JP2011523741A patent/JP2012500379A/ja not_active Ceased
Non-Patent Citations (1)
Title |
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See references of WO2010024553A2 * |
Also Published As
Publication number | Publication date |
---|---|
WO2010024553A3 (ko) | 2010-06-17 |
US20110146321A1 (en) | 2011-06-23 |
WO2010024553A2 (ko) | 2010-03-04 |
KR100970870B1 (ko) | 2010-07-16 |
CN102132110A (zh) | 2011-07-20 |
JP2012500379A (ja) | 2012-01-05 |
KR20100024551A (ko) | 2010-03-08 |
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