EP2313080B1 - Re-applicable mascara composition - Google Patents
Re-applicable mascara composition Download PDFInfo
- Publication number
- EP2313080B1 EP2313080B1 EP09774054.2A EP09774054A EP2313080B1 EP 2313080 B1 EP2313080 B1 EP 2313080B1 EP 09774054 A EP09774054 A EP 09774054A EP 2313080 B1 EP2313080 B1 EP 2313080B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- peg
- wax
- mascara
- mascara composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 117
- 239000001993 wax Substances 0.000 claims description 53
- 238000000576 coating method Methods 0.000 claims description 36
- 210000000720 eyelash Anatomy 0.000 claims description 27
- 239000000178 monomer Substances 0.000 claims description 26
- 239000011248 coating agent Substances 0.000 claims description 25
- 229920001577 copolymer Polymers 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 235000013871 bee wax Nutrition 0.000 claims description 18
- 239000012166 beeswax Substances 0.000 claims description 18
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical group C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 16
- 239000000049 pigment Substances 0.000 claims description 15
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- 125000000217 alkyl group Chemical group 0.000 claims description 5
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- 238000000034 method Methods 0.000 claims description 5
- 125000006527 (C1-C5) alkyl group Chemical group 0.000 claims description 4
- FLCAEMBIQVZWIF-UHFFFAOYSA-N 6-(dimethylamino)-2-methylhex-2-enamide Chemical compound CN(C)CCCC=C(C)C(N)=O FLCAEMBIQVZWIF-UHFFFAOYSA-N 0.000 claims description 4
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- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229940073609 bismuth oxychloride Drugs 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229940075510 carbopol 981 Drugs 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 229960002380 dibutyl phthalate Drugs 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000008387 emulsifying waxe Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 230000003779 hair growth Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- HNMCSUXJLGGQFO-UHFFFAOYSA-N hexaaluminum;hexasodium;tetrathietane;hexasilicate Chemical class [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].S1SSS1.S1SSS1.[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] HNMCSUXJLGGQFO-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- ZCTXEAQXZGPWFG-UHFFFAOYSA-N imidurea Chemical compound O=C1NC(=O)N(CO)C1NC(=O)NCNC(=O)NC1C(=O)NC(=O)N1CO ZCTXEAQXZGPWFG-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012184 mineral wax Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000346 nonvolatile oil Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- 229940098695 palmitic acid Drugs 0.000 description 1
- 150000002942 palmitic acid derivatives Chemical class 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentā4āenā2āone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000012169 petroleum derived wax Substances 0.000 description 1
- 235000019381 petroleum wax Nutrition 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- AGMRJQXCAJZJNK-UHFFFAOYSA-M sodium;2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-dodecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOS([O-])(=O)=O AGMRJQXCAJZJNK-UHFFFAOYSA-M 0.000 description 1
- CRPCXAMJWCDHFM-UHFFFAOYSA-M sodium;5-oxopyrrolidine-2-carboxylate Chemical compound [Na+].[O-]C(=O)C1CCC(=O)N1 CRPCXAMJWCDHFM-UHFFFAOYSA-M 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229960004274 stearic acid Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003445 sucroses Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000979 synthetic dye Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 229940057400 trihydroxystearin Drugs 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/925—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/927—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of insects, e.g. shellac
Definitions
- the present invention relates to a cosmetic composition suitable for application to keratinous fibers, more preferably to eyelashes.
- the cosmetic composition of the present invention contains a unique combination of a chemically modified wax and a polymeric film-former, which provides excellent re-wettability and allows re-application of the cosmetic composition to the eyelashes for boosting the lash volume hours after the initial application without having to remove the initial coating from the eyelashes.
- Traditional mascaras are made of various film formers dispersed in one or more solvents. After application, the solvents evaporate and leave a rigid, liquid-impervious coating composed of the film formers on the eyelashes. Such coating is designed to adhere securely to the eyelashes and stays thereon for an extended period of time to achieve the desired long wear effect.
- rigid, liquid-impervious coating once formed, cannot be re-wetted by the mascara composition, which renders it very difficult to apply additional coatings to the eyelashes to freshen up the previously applied mascara or to boost the lash volume.
- US 2008/102051 describes aqueous hair styling compositions comprising polyols such as sorbitol or mannitol, where the polyols provide increase of stiffness in low- to no- volatile organic compounds hair styling products.
- US 2007/212316 relates to a mascara composition containing a latex polymer, a self-emulsifying wax (chemically modified wax containing at least one emulsifier component) and water.
- emulsifier is not added.
- the compositions provide length and volume. In some embodiments, the compositions do not contain added emulsifier. Said compositions provide long wear and curl, together with easy removability with water.
- the chemically modified wax may be chosen from PEG-8 beeswax, PEG-6 beeswax, PEG-12 beeswax, or PEG-12 carnauba wax.
- the latex polymer may be copolymer of (meth)acrylique acid and its esters. The problem is removability with water, There is no suggestion of re-application of the cosmetic composition without having to remove the initial coating.
- US 2005/061349 describes methods for applying mascara compositions to eyelashes, where washable mascara is applied followed by waterproof mascara.
- the washable mascara composition, the waterproof mascara composition, or both contain fibers.
- the composition may comprise a film-forming polymer made of the combination of a first tacky film former soluble or dispersible in water such as among others PVP/DMAPA acrylates copolymers (STYLEZE CC-10), and a second tacky film former soluble in oil.
- PVP/DMAPA acrylates copolymers STYLEZE CC-10
- Acrylates are described among polymers. Nowhere combination of acrylates with chemically modified wax is suggested.
- the present invention relates in general to a mascara composition with sufficient re-wettability suitable for re-application.
- the present invention relates to a mascara composition containing:
- the present invention relates to a method of enhancing the appearance of eyelashes, including applying a first coating of the above-described mascara composition over the eyelashes, and subsequently applying one or more additional coatings of such mascara composition over the eyelashes after the first coating is allowed to dry thereon for a sufficient period of time.
- the present invention employs a unique combination of a chemically modified wax and a particular polymeric film former to form a mascara composition with excellent re-wettability that can be readily re-applied to eyelashes already coated with such mascara.
- the mascara composition of the present invention can be used for freshening up the initial look after an extended period of time, or it can be used to provide as many additional coatings as needed to continuously build up the lash volume so as to achieve a more dramatic effect.
- the mascara composition is an aqueous-based composition.
- aqueous-based as used herein broadly covers any composition containing one or more aqueous phases, including, but not limited to: compositions containing primarily aqueous phase, oil-in-water (O/W), water-in-oil (W/O), oil-in-water-in-oil (O/W/O) or water-in-oil-in-water (W/O/W) emulsions containing both oil and aqueous phases, water-in-silicone or silicone-in-water emulsions, and the like.
- the mascara composition of the present invention is in the form of an oil-in-water emulsion.
- the aqueous phase(s) can be present in the mascara composition of the present invention in a total amount ranging from about 1% to about 90%. More preferably, the aqueous phase(s) is present at a large amount in the mascara composition of the present invention, e.g., more than 20%, and most preferably from about 40% to about 70%, by total weight of the composition.
- the term "chemically modified waxā means a natural or synthetic wax that has been functionalized with hydrophilic functional groups.
- the chemical modified wax of the present invention is formed by reacting a natural or synthetic wax having carboxylic acid groups with a mono-, di-, or polyhydric alcohol or alkoxylated alcohol, a C 2 -C 4 alkylene glycol and the like.
- the chemical modified wax of the present invention is a natural wax having carboxylic acid groups reacted with an ethoxylated alcohol, preferably polyethylene glycol (PEG).
- PEG polyethylene glycol
- Exemplary waxes suitable for use in the present invention include natural or synthetic waxes reacted with polyethylene glycol, where the number of repeating ethylene oxide groups ranges from about 2 to 100.
- Such waxes include, but are not limited to: PEG-esterified beeswax, PEG-esterified candelilla wax, PEG-esterified carnauba wax, PEG-esterified lanolin, PEG-esterified spermaceti wax, PEG-esterified shellac wax, PEG-esterified bayberry wax, and PEG-esterified sugar cane wax, among which PEG-8 beeswax, PEG-6 beeswax, PEG-12 beeswax, PEG-12 carnauba wax, and PEG-sorbitan beeswax are preferred. Most preferred is PEG-8 beeswax, which is commercially available under the trade name "APIFILĀ®" from GattefossĆ© Canada Inc. in Toronto, Canada.
- the chemically modified wax can be pre-formed by first reacting the above-described natural or synthetic wax with the alcohol at an elevated temperature and then mixed with other ingredients to form the compositions of the present invention.
- the chemically modified wax can be formed in situ, e.g., by mixing the above-described natural or synthetic wax and the alcohol with other ingredients of the composition of the present invention and then heating the mixture at an elevated temperature to effectuate in situ reaction between the wax and the alcohol, thereby resulting in a composition with the chemically modified wax formed in situ therein.
- the chemically modified wax is preferably present in an amount ranging from about 0.1 % to about 20% by total weight of the composition. More preferably, the chemically modified wax is present in an amount not more than 15%, e.g., from about 1% to about 10%, and most preferably from about 2% to about 6%, by total weight of the composition.
- Another component of the mascara composition of the present invention is a polymeric film former comprising monomers having the formula and monomers having the formula wherein n is 3 to 6; P is O or NR 3 ; R 1 , R 2 , R 3 , R 4 , and R 5 are independently H or C 1 -C 5 alkyl; R6 is C 2 -C 16 alkyl or alkylene; wt% of X monomers ranges from about 60 to about 99, more preferably from about 70 to about 95, and most preferably from about 80 to about 90; wt% of Y monomers ranges from about 1 to about 40, more preferably from about 5 to about 30, and most preferably from about 10 to about 20.
- n is 3, so that the X monomer is vinylpyrrolidone.
- the Y monomer can be selected from the group consisting of alkylaminoalkyl methacrylamide monomers, alkylaminoalkylene methacrylamide monomers, alkylaminoalkyl methacrylate monomers, alkylaminoalkylene methacrylate monomers, alkylaminoalkyl acrylamide monomers, alkylaminoalkylene acrylamide monomers, alkylaminoalkyl acrylate monomers, and alkylaminoalkylene acrylate monomers.
- the polymeric film former of the present invention can be selected from the group consisting of vinylpyrrolidone/alkylaminoalkyl methacrylamide copolymers, vinylpyrrolidone/alkylaminoalkylene methacrylamide copolymers, vinlypyrrolidone/alkylaminoalkyl methacrylate copolymers, vinlypyrrolidone/alkylaminoalkylene methacrylate copolymers, vinlypyrrolidone/alkylaminoalkyl acrylamide copolymers, vinlypyrrolidone/alkylaminoalkylene acrylamide copolymers, vinlypyrrolidone/alkylaminoalkylene acrylamide copolymers, vinlypyrrolidone/alkylaminoalkyl acrylate copolymers, and vinlypyrrolidone/alkylaminoalkylene acrylate copolymers.
- polymeric film former of the present invention is a vinylpyrrolidone/dimethylaminopropyl methacrylamide (DMAPMA) copolymer, which is commercially available under the trade name "STYLEZEĀ® CC-10" from International Specialty Products (ISP) in Wayne, NJ.
- DMAPMA vinylpyrrolidone/dimethylaminopropyl methacrylamide
- the above-described polymeric film former is preferably present in an amount ranging from about 0.1 % to about 70% by total weight of the composition. More preferably, the polymeric film former is present in an amount ranging from about 1% to about 20%, and most preferably from about 2% to about 10%, by total weight of the composition.
- the chemically modified wax and the specific polymeric film former of the present invention jointly form a soft, flexible mascara coating over the eyelashes that can be readily re-wetted by the aqueous phase(s) contained in a newly applied coating of mascara and thereby allow re-application of such mascara composition to the eyelashes directly over the mascara-coated eyelashes.
- mascara compositions containing the chemically modified wax in combination with several polymeric film formers typically used in conventional mascara compositions do not have the re-wettable characteristic of the mascara compositions of the present invention and cannot be comfortably re-applied to mascara-coated eyelashes. Therefore, selection of the specific polymeric film former and the combined use of such specific film former with the chemically modified wax by the present invention to form a re-applicable mascara composition are both surprising and un-expected over the conventional art.
- the mascara compositions of the present invention typically contain one or more fillers, inorganic or organic pigments, such as iron oxides or D&C or FD&C colorants or lakes thereof. Suggested ranges of such fillers and pigments are from about 0.1 to 80%, preferably from about 0.1 to 50%.
- Specific examples of particulate fillers include talc, mica, magnesium carbonate, calcium carbonate, magnesium silicate, aluminum magnesium silicate, silica, polyethylene powder, methacrylate powder, polystyrene powder, silk powder, crystalline cellulose, starch, titanated mica, bismuth oxychloride, zinc oxide, and the like.
- Pigments include iron oxides such as red, yellow iron, black iron oxides, ultramarines, iron oxide titanated mica, salts or lakes of aluminum, barium or calcium, and the like. Other colors, such as organic or synthetic dyes, can also be included in the cosmetic compositions of the present invention.
- the pigments are hydrophilic, which may include, but are not limited to pigments that are inherently hydrophilic (e.g., metal oxides) due to their polarity, or pigments (e.g., carbon black) that are surface-treated with a material so as to confer hydrophilicity.
- hydrophilic may include, but are not limited to pigments that are inherently hydrophilic (e.g., metal oxides) due to their polarity, or pigments (e.g., carbon black) that are surface-treated with a material so as to confer hydrophilicity.
- silicone surfactants such as oxyalkylenated silicones, PEG-dimethicones, dimethicone copolyol, alkyl-substituted dimethicone copolyols (e.g., cetyl or stearyl dimethicone copolyol); sulfopolyesters, such as those commercially available under the tradenames of Eastman AQ 14000 and Eastman
- iron oxides surface-treated with PEG-9 dimethicone or decyl glucoside can be readily used in the present invention.
- Carbon black surface-treated with Eastman AQ 55 polymer can also be used for the practice of the present invention.
- the hydrophilic pigments may present in the mascara compositions of the present invention at an amount ranging from about 0.1% to about 30%, and preferably from about 0.5% to about 20%, by total weight of the compositions.
- the mascara composition of the present invention is aqueous-based, and it preferably contains from about 5% to about 90%, and most preferably from about 20% to about 70%, of water.
- the aqueous phase may further include a water-miscible solvent (generally having a water-miscibility of greater than 50% by weight at 25Ā°C).
- water-miscible solvents include C 1 -C 5 monoalcohols, such as ethanol or isopropanol, C 2 -C 8 glycols, such as propylene glycol, ethylene glycol, butylene glycol, and dipropylene glycol, C 3 -C 4 ketones and C 2 -C 4 aldehydes.
- Such water-miscible solvent may be presented in an amount ranging from about 0.01 % to about 40%, and more preferably from about 0.5% to about 10%, by total weight of the composition.
- the aqueous mascara composition of the present invention can be in the form of either oil-in-water emulsion or water-in-oil emulsion with one or more lipophilic materials included therein.
- the lipophilic materials can be selected from oils and fats commonly used in the cosmetic products, and if present, such oils and fats are provided in a total amount ranging from about 0.1% to about 40%, more preferably from about 0.5% to about 20%, by total weight of the composition.
- Oils typically used in cosmetic products include polar oils, nonpolar oils, volatile oils, non-volatile oils, and mixtures thereof.
- the oils can be selected from the group consisting of hydrocarbon-based oils, fluoro and/or silicone oils, oils of mineral, animal, plant, or synthetic origin, provided that that they form a homogeneous and stable mixture along with other ingredients of the mascara composition of the present invention.
- oils for use in the mascara compositions of the present invention include polyisobutene, polybutene, polydecene, or hydrogenated derivatives thereof.
- Fats as employed by the present invention may be selected from the group consisting of vegetable fats, synthetic fats, and mixtures thereof.
- the fats used in the present invention are C 6 -C 30 fatty acids or C 6 -C 30 fatty acid mono- or diesters of glycerin selected from the group consisting of glyceryl stearates, diglyceryl distearate, diglyceryl diisostearate, glyceryl palmitates, palmitates of C 18 -C 36 triglyceride, glyceryl behenates, and mixtures thereof.
- the mascara composition of the present invention may include one or more additional structuring agents including other waxes commonly used in cosmetic products or other ingredients that increase the viscosity or thickness of the composition. If present, the additional structuring agents are preferably provided in a total amount ranging from about 0.1% to about 70%, and more preferably from about 0.5% to about 60%, by total weight of the composition.
- waxes examples include, but are not limited to animal waxes, vegetable waxes, mineral waxes, various fractions of natural waxes, synthetic waxes, petroleum waxes, polyethylene waxes, polypropylene waxes, polyurethane waxes, hydrocarbon-based waxes such as Fischer-Tropsch waxes, silicone waxes, and mixtures thereof.
- Preferred other waxes in practice of the present invention include beeswax, lanolin wax, shellac wax, carnauba wax, candelilla wax, bayberry wax, ozokerite, ceresin, paraffin, microcrystalline waxes, polyethylene waxes, C 24 -C 45 methicones, and the like.
- Other types of structuring agents can also be used for increasing the viscosity or thickness of the mascara compositions of the present invention, such as those having an HLB of from about 1 to about 8 and having a melting point of at least about 45Ā°C.
- Suitable structuring agents may include saturated C 14 to C 30 fatty alcohols, saturated C 16 to C 30 fatty alcohols containing from about 1 to about 5 moles of ethylene oxide, saturated C 16 to C 30 diols, saturated C 16 to C 30 monoglycerol ethers, saturated C 16 to C 30 hydroxy fatty acids, C 14 to C 30 hydroxylated and nonhydroxylated saturated fatty acids, C 14 to C 30 saturated ethoxylated fatty acids, amines and alcohols containing from about 1 to about 5 moles of ethylene oxide diols, C 14 to C 30 saturated glyceryl mono esters with a monoglyceride content of at least 40%, C 14 to C 30 saturated polyglycerol esters having from about 1 to about 3 alkyl group and from about 2 to about 3 saturated glycerol units, C 14 to C 30 glyceryl mono ethers, C 14 to C 30 sorbitan mono/diesters, C 14 to C 30 saturated ethoxylated sorbitan mono
- Preferred other structuring agents for practice of the present invention are selected from stearic acid, palmitic acid, stearyl alcohol, cetyl alcohol, behenyl alcohol, stearic acid, palmitic acid, the polyethylene glycol ether of stearyl alcohol having an average of about 1 to about 5 ethylene oxide units, the polyethylene glycol ether of cetyl alcohol having an average of about 1 to about 5 ethylene oxide units, and mixtures thereof.
- More preferred other structuring agents are selected from stearyl alcohol, cetyl alcohol, behenyl alcohol, the polyethylene glycol ether of stearyl alcohol having an average of about 2 ethylene oxide units (steareth-2), the polyethylene glycol ether of cetyl alcohol having an average of about 2 ethylene oxide units, and mixtures thereof. Even more preferred structuring agents are selected from stearic acid, palmitic acid, stearyl alcohol, cetyl alcohol, behenyl alcohol, steareth-2, and mixtures thereof.
- hydrophilic gelling agents such as the acrylic acid/ethyl acrylate copolymers and the carboxyvinyl polymers sold by the B.F. Goodrich Company under the trademark of CarbopolĀ® resins.
- These resins consist essentially of a colloidally water-soluble polyalkenyl polyether crosslinked polymer of acrylic acid crosslinked with from 0.75% to 2.00% of a crosslinking agent such as polyallyl sucrose or polyallyl pentaerythritol. Examples include Carbopol 934, Carbopol 940, Carbopol 950, Carbopol 980, Carbopol 951 and Carbopol 981.
- Carbopol 934 is a water-soluble polymer of acrylic acid crosslinked with about 1% of a polyallyl ether of sucrose having an average of about 5.8 allyl groups for each sucrose molecule. Also suitable for use herein are carbomers sold under the Trade Name "Carbopol Ultrez 10, Carbopol ETD2020, Carbopol 1382, Carbopol 1342 and Pemulen TR-1 (CTFA Designation: Acrylates/10-30 Alkyl Acrylate Crosspolymer). Combinations of the above polymers are also useful herein.
- Other gelling agents suitable for use herein include oleogels such as trihydroxystearin. Hydrophobically modified celluloses are also suitable for use as structuring agents. If present, the gelling agents are provided in a total amount ranging from about 0.05% to about 20%, and more preferably from about 0.5% to about 10%, by total weight of the composition.
- the mascara composition of the present invention may further include fibers for lash lengthening effects.
- the fibers useful in the present invention can be either natural fibers or synthetic fibers. Natural fibers include, but are not limited to: cotton fibers, silk fibers, wool fibers, and the like. Synthetic fibers include, but are not limited to: polyester fibers, rayon fibers, nylon fibers, and other polyamide fibers. If present, the fibers are preferably provided at an amount ranging from about 0.01% to about 10% by total weight of the composition.
- the mascara composition of the present invention may also contain one or more hair care actives, such as hair straightening agents, hair curling agents, hair conditioning agents, hair growth agents, and the like. If present, such hair care actives may range from about 0.01% to about 50%, preferably from about 0.05% to about 35% by total weight of the composition.
- hair care actives such as hair straightening agents, hair curling agents, hair conditioning agents, hair growth agents, and the like. If present, such hair care actives may range from about 0.01% to about 50%, preferably from about 0.05% to about 35% by total weight of the composition.
- the cosmetic composition of the present invention may further include one or more humectants. If present, they may range from about 0.1 to 20% by weight of the total composition and include polyhydric alcohols including glycerol, C 1-4 alkylene glycols such as butylene, propylene, ethylene glycol, glycerin, and the like, polyalkylene glycols, and alkylene polyols and mixtures thereof, hyaluronic acid, urea, sorbitol, sodium 2-pyrrolidone-5-carboxylate, soluble collagen, dibutylphthalate and gelatin.
- polyhydric alcohols including glycerol, C 1-4 alkylene glycols such as butylene, propylene, ethylene glycol, glycerin, and the like, polyalkylene glycols, and alkylene polyols and mixtures thereof, hyaluronic acid, urea, sorbitol, sodium 2-pyrrolidone-5-carboxylate,
- Suitable preservatives include, but are not limited to: potassium sorbate, imidazolidinyl urea, p-hydroxy benzoate, esters of p-hydroxybenzoic acid, various parabens (as disclosed in the 12 th Edition of CTFA's International Cosmetic Ingredient Dictionary and Handbook), ethylhexylglycerin, caprylyl glycol/phenoxyethanol/hexylene glycol, and the like.
- Other preservatives suitable for use in the cosmetic compositions of the present invention are disclosed in the 12 th Edition of CTFA's International Cosmetic Ingredient Dictionary and Handbook, the entire disclosure of which is herein incorporated by reference for all purposes.
- the cosmetic composition of the present invention may optionally comprise a fragrance in an amount sufficient to make the composition more appealing to the consumer.
- the fragrance is in the amount of from about 0.001% to about 10% by total weight of the composition.
- the mascara compositions of the present application can be first applied to the eyelashes to form an initial coating thereover, and it can be readily re-applied to mascara-coated eyelashes to form one or more additional coatings over the eyelashes after the initial coating is allowed to dry for a sufficient period of time. Such sufficient period of time can range from about 10 seconds to about 2 minutes. Further, the mascara compositions of the present application can be re-applied to mascara-coated eyelashes after an extended period of time, e.g., more than 10 minutes or more preferably, more than 1 hour after application of the initial coating.
- the mascara compositions of the present application can be re-applied as many times as desired to form multiple additional coatings, each of which is allowed to dry for a sufficient period of time and each is directly applied over the previous coating, so as to continuously build up the lash volume for a desired dramatic effect.
- Formula 1 Components Wt % Deionized Water 56.39 Hydroxyethylcellulose 0.50 Aminomethyl propanediol 1.58 Butylene glycol 1.00 Disodium EDTA 0.10 Iron oxide/PEG-9 dimethicone 2.50 Water/D&C Black #2 Dye/Acacia Senegal gum/decyl glucoside 5.00 Simethicone 0.08 Mica 4.00 Vinylpyrrolidone/DMAPMA copolymer 5.00 Stearic acid 6.10 Paraffin wax 3.20 PEG-8 beeswax 4.00 Camauba wax 1.60 Glyceryl stearate 5.00 Polyisobutene 1.60 Phenoxyethanol/caprylyl glycol/potassium sorbate/water/hexylene glycol 0.70 Ethylhexylglycerin 0.60 Green tea extract 1.00 Water/polyaminopropyl biguanide 0.05
- Comparative Formulas 2-5 which contained all the ingredients of Formula 1 except that the VP/DMAPMA copolymer therein was replaced with other polymers, were formed, as follows: Comparative Formulas 2-5 Components Wt % Formula 2 Formula 3 Formula 4 Formula 5 Deionized Water 56.39 56.39 56.39 Hydroxyethylcellulose 0.50 0.50 0.50 0.50 Aminomethyl propanediol 1.58 1.58 1.58 Butylene glycol 1.00 1.00 1.00 1.00 Disodium EDTA 0.10 0.10 0.10 0.10 0.10 0.10 0.10 Iron oxide/PEG-9 dimethicone 2.50 2.50 2.50 2.50 2.50 2.50 Water/D&C Black #2 Dye/Acacia Senegal gum/decyl glucoside 5.00 5.00 5.00 Sime
- Formula 1 When applied to eyelashes, Formula 1 formed a flexible coating that could be easily re-wetted and re-applied after 3 hours of the initial application, with minimum difficulty of application and little clumping.
- all of the Comparative Formulas 2-5 formed rigid coatings that could not be re-wetted by the respective comparative mascara formula, and re-application of the comparative mascara composition over already-coated lashes was difficult. Therefore, it was demonstrated that selection of the specific polymeric film former and the combined use of such specific film former with the chemically modified wax by the present invention to form a re-applicable mascara composition are both surprising and unexpected over the conventional art.
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Description
- The present invention relates to a cosmetic composition suitable for application to keratinous fibers, more preferably to eyelashes. The cosmetic composition of the present invention contains a unique combination of a chemically modified wax and a polymeric film-former, which provides excellent re-wettability and allows re-application of the cosmetic composition to the eyelashes for boosting the lash volume hours after the initial application without having to remove the initial coating from the eyelashes.
- Traditional mascaras are made of various film formers dispersed in one or more solvents. After application, the solvents evaporate and leave a rigid, liquid-impervious coating composed of the film formers on the eyelashes. Such coating is designed to adhere securely to the eyelashes and stays thereon for an extended period of time to achieve the desired long wear effect. However, such rigid, liquid-impervious coating, once formed, cannot be re-wetted by the mascara composition, which renders it very difficult to apply additional coatings to the eyelashes to freshen up the previously applied mascara or to boost the lash volume.
- There is notable discomfort when a user tries to brush through mascara-covered eyelashes. Separation of eyelashes becomes extremely difficult, with significant clumping as well as potential flaking of the initial coating. Currently there is no commercially available mascara composition that allows comfortable re-application of the mascara over a previously applied, already-dried mascara coating for achieving a more dramatic effect. Therefore, in order to boost the lash volume and achieve the desired dramatic effect, the user typically has to completely remove the previously applied mascara coating and all other eye makeup before reapplying a more volumizing mascara product.
- There is therefore a need for a new mascara composition that allows comfortable re-application over mascara-coated eyelashes. It will be especially advantageous to provide a mascara composition that enables the user to achieve a modest daytime look with just one initial coating of mascara, and then re-apply as many additional coatings as needed to continuously build up the lash volume to achieve a more dramatic evening look, without having to remove the initial coating of mascara and with minimum discomfort and clumping. It is also desired to provide a low smudge or zero smudge mascara composition that does not interact with the sebum of the skin and can therefore be worn by the user with comfort comparable to that of the conventional mascara products.
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US 2008/102051 describes aqueous hair styling compositions comprising polyols such as sorbitol or mannitol, where the polyols provide increase of stiffness in low- to no- volatile organic compounds hair styling products. -
US 2007/212316 relates to a mascara composition containing a latex polymer, a self-emulsifying wax (chemically modified wax containing at least one emulsifier component) and water. In some compositions emulsifier is not added. The compositions provide length and volume. In some embodiments, the compositions do not contain added emulsifier. Said compositions provide long wear and curl, together with easy removability with water. The chemically modified wax may be chosen from PEG-8 beeswax, PEG-6 beeswax, PEG-12 beeswax, or PEG-12 carnauba wax. The latex polymer may be copolymer of (meth)acrylique acid and its esters. The problem is removability with water, There is no suggestion of re-application of the cosmetic composition without having to remove the initial coating. -
US 2005/061349 describes methods for applying mascara compositions to eyelashes, where washable mascara is applied followed by waterproof mascara. The washable mascara composition, the waterproof mascara composition, or both contain fibers. The composition may comprise a film-forming polymer made of the combination of a first tacky film former soluble or dispersible in water such as among others PVP/DMAPA acrylates copolymers (STYLEZE CC-10), and a second tacky film former soluble in oil. Acrylates are described among polymers. Nowhere combination of acrylates with chemically modified wax is suggested. - The present invention relates in general to a mascara composition with sufficient re-wettability suitable for re-application.
- In one aspect, the present invention relates to a mascara composition containing:
- (a) a chemically modified wax with one or more hydrophilic functional groups;
- (b) a polymeric film former comprising monomers having the formula
- (c) pigments; and
- (d) water.
- In another aspect, the present invention relates to a method of enhancing the appearance of eyelashes, including applying a first coating of the above-described mascara composition over the eyelashes, and subsequently applying one or more additional coatings of such mascara composition over the eyelashes after the first coating is allowed to dry thereon for a sufficient period of time.
- Other aspects and objectives of the present invention will become more apparent from the ensuing description, examples, and claims.
- Except in operating and comparative examples, or where otherwise explicitly indicated, all numbers in this description indicating amounts or ratios of material or conditions of reaction, physical properties of materials and/or use are to be understood as modified by the word "about." All percentages are presented as percentages by weight of the final composition, unless otherwise specified.
- The present invention employs a unique combination of a chemically modified wax and a particular polymeric film former to form a mascara composition with excellent re-wettability that can be readily re-applied to eyelashes already coated with such mascara. The mascara composition of the present invention can be used for freshening up the initial look after an extended period of time, or it can be used to provide as many additional coatings as needed to continuously build up the lash volume so as to achieve a more dramatic effect.
- The mascara composition is an aqueous-based composition. The term "aqueous-based" as used herein broadly covers any composition containing one or more aqueous phases, including, but not limited to: compositions containing primarily aqueous phase, oil-in-water (O/W), water-in-oil (W/O), oil-in-water-in-oil (O/W/O) or water-in-oil-in-water (W/O/W) emulsions containing both oil and aqueous phases, water-in-silicone or silicone-in-water emulsions, and the like. Preferably, the mascara composition of the present invention is in the form of an oil-in-water emulsion. The aqueous phase(s) can be present in the mascara composition of the present invention in a total amount ranging from about 1% to about 90%. More preferably, the aqueous phase(s) is present at a large amount in the mascara composition of the present invention, e.g., more than 20%, and most preferably from about 40% to about 70%, by total weight of the composition.
- The term "chemically modified wax" means a natural or synthetic wax that has been functionalized with hydrophilic functional groups. Preferably, but not necessarily, the chemical modified wax of the present invention is formed by reacting a natural or synthetic wax having carboxylic acid groups with a mono-, di-, or polyhydric alcohol or alkoxylated alcohol, a C2-C4 alkylene glycol and the like. More preferably, the chemical modified wax of the present invention is a natural wax having carboxylic acid groups reacted with an ethoxylated alcohol, preferably polyethylene glycol (PEG). Exemplary waxes suitable for use in the present invention include natural or synthetic waxes reacted with polyethylene glycol, where the number of repeating ethylene oxide groups ranges from about 2 to 100. Such waxes include, but are not limited to: PEG-esterified beeswax, PEG-esterified candelilla wax, PEG-esterified carnauba wax, PEG-esterified lanolin, PEG-esterified spermaceti wax, PEG-esterified shellac wax, PEG-esterified bayberry wax, and PEG-esterified sugar cane wax, among which PEG-8 beeswax, PEG-6 beeswax, PEG-12 beeswax, PEG-12 carnauba wax, and PEG-sorbitan beeswax are preferred. Most preferred is PEG-8 beeswax, which is commercially available under the trade name "APIFILĀ®" from GattefossĆ© Canada Inc. in Toronto, Canada.
- The chemically modified wax can be pre-formed by first reacting the above-described natural or synthetic wax with the alcohol at an elevated temperature and then mixed with other ingredients to form the compositions of the present invention. Alternatively, the chemically modified wax can be formed in situ, e.g., by mixing the above-described natural or synthetic wax and the alcohol with other ingredients of the composition of the present invention and then heating the mixture at an elevated temperature to effectuate in situ reaction between the wax and the alcohol, thereby resulting in a composition with the chemically modified wax formed in situ therein.
- The chemically modified wax is preferably present in an amount ranging from about 0.1 % to about 20% by total weight of the composition. More preferably, the chemically modified wax is present in an amount not more than 15%, e.g., from about 1% to about 10%, and most preferably from about 2% to about 6%, by total weight of the composition.
- Another component of the mascara composition of the present invention is a polymeric film former comprising monomers having the formula
- Preferably, n is 3, so that the X monomer is vinylpyrrolidone. The Y monomer can be selected from the group consisting of alkylaminoalkyl methacrylamide monomers, alkylaminoalkylene methacrylamide monomers, alkylaminoalkyl methacrylate monomers, alkylaminoalkylene methacrylate monomers, alkylaminoalkyl acrylamide monomers, alkylaminoalkylene acrylamide monomers, alkylaminoalkyl acrylate monomers, and alkylaminoalkylene acrylate monomers. Correspondingly, the polymeric film former of the present invention can be selected from the group consisting of
vinylpyrrolidone/alkylaminoalkyl methacrylamide copolymers,
vinylpyrrolidone/alkylaminoalkylene methacrylamide copolymers,
vinlypyrrolidone/alkylaminoalkyl methacrylate copolymers,
vinlypyrrolidone/alkylaminoalkylene methacrylate copolymers,
vinlypyrrolidone/alkylaminoalkyl acrylamide copolymers,
vinlypyrrolidone/alkylaminoalkylene acrylamide copolymers,
vinlypyrrolidone/alkylaminoalkyl acrylate copolymers, and vinlypyrrolidone/alkylaminoalkylene acrylate copolymers. Most preferred as the polymeric film former of the present invention is a vinylpyrrolidone/dimethylaminopropyl methacrylamide (DMAPMA) copolymer, which is commercially available under the trade name "STYLEZEĀ® CC-10" from International Specialty Products (ISP) in Wayne, NJ. - The above-described polymeric film former is preferably present in an amount ranging from about 0.1 % to about 70% by total weight of the composition. More preferably, the polymeric film former is present in an amount ranging from about 1% to about 20%, and most preferably from about 2% to about 10%, by total weight of the composition.
- Although not wishing to be bound by any particular theory, it is believed by the inventors that the chemically modified wax and the specific polymeric film former of the present invention jointly form a soft, flexible mascara coating over the eyelashes that can be readily re-wetted by the aqueous phase(s) contained in a newly applied coating of mascara and thereby allow re-application of such mascara composition to the eyelashes directly over the mascara-coated eyelashes. As shown in the comparative examples hereinafter, mascara compositions containing the chemically modified wax in combination with several polymeric film formers typically used in conventional mascara compositions do not have the re-wettable characteristic of the mascara compositions of the present invention and cannot be comfortably re-applied to mascara-coated eyelashes. Therefore, selection of the specific polymeric film former and the combined use of such specific film former with the chemically modified wax by the present invention to form a re-applicable mascara composition are both surprising and un-expected over the conventional art.
- The mascara compositions of the present invention typically contain one or more fillers, inorganic or organic pigments, such as iron oxides or D&C or FD&C colorants or lakes thereof. Suggested ranges of such fillers and pigments are from about 0.1 to 80%, preferably from about 0.1 to 50%. Specific examples of particulate fillers include talc, mica, magnesium carbonate, calcium carbonate, magnesium silicate, aluminum magnesium silicate, silica, polyethylene powder, methacrylate powder, polystyrene powder, silk powder, crystalline cellulose, starch, titanated mica, bismuth oxychloride, zinc oxide, and the like. Pigments include iron oxides such as red, yellow iron, black iron oxides, ultramarines, iron oxide titanated mica, salts or lakes of aluminum, barium or calcium, and the like. Other colors, such as organic or synthetic dyes, can also be included in the cosmetic compositions of the present invention.
- In a preferred, but not necessary, embodiment of the present invention, the pigments are hydrophilic, which may include, but are not limited to pigments that are inherently hydrophilic (e.g., metal oxides) due to their polarity, or pigments (e.g., carbon black) that are surface-treated with a material so as to confer hydrophilicity. Pigment treatment materials that may confer hydrophilicity include silicone surfactants, such as oxyalkylenated silicones, PEG-dimethicones, dimethicone copolyol, alkyl-substituted dimethicone copolyols (e.g., cetyl or stearyl dimethicone copolyol); sulfopolyesters, such as those commercially available under the tradenames of Eastman AQ 14000 and Eastman AQ 55 from Eastman Chemical Company (Kingsport, TN). The use of hydrophilic pigments functions to further improve the re-wettability of the mascara compositions of the present invention. For example, iron oxides surface-treated with PEG-9 dimethicone or decyl glucoside can be readily used in the present invention. Carbon black surface-treated with Eastman AQ 55 polymer can also be used for the practice of the present invention. The hydrophilic pigments may present in the mascara compositions of the present invention at an amount ranging from about 0.1% to about 30%, and preferably from about 0.5% to about 20%, by total weight of the compositions.
- As mentioned hereinabove, the mascara composition of the present invention is aqueous-based, and it preferably contains from about 5% to about 90%, and most preferably from about 20% to about 70%, of water. In addition to water, the aqueous phase may further include a water-miscible solvent (generally having a water-miscibility of greater than 50% by weight at 25Ā°C). Examples of such water-miscible solvents include C1-C5 monoalcohols, such as ethanol or isopropanol, C2-C8 glycols, such as propylene glycol, ethylene glycol, butylene glycol, and dipropylene glycol, C3-C4 ketones and C2-C4 aldehydes. Such water-miscible solvent may be presented in an amount ranging from about 0.01 % to about 40%, and more preferably from about 0.5% to about 10%, by total weight of the composition.
- The aqueous mascara composition of the present invention can be in the form of either oil-in-water emulsion or water-in-oil emulsion with one or more lipophilic materials included therein. The lipophilic materials can be selected from oils and fats commonly used in the cosmetic products, and if present, such oils and fats are provided in a total amount ranging from about 0.1% to about 40%, more preferably from about 0.5% to about 20%, by total weight of the composition. Oils typically used in cosmetic products include polar oils, nonpolar oils, volatile oils, non-volatile oils, and mixtures thereof. More specifically, the oils can be selected from the group consisting of hydrocarbon-based oils, fluoro and/or silicone oils, oils of mineral, animal, plant, or synthetic origin, provided that that they form a homogeneous and stable mixture along with other ingredients of the mascara composition of the present invention. Exemplary oils for use in the mascara compositions of the present invention include polyisobutene, polybutene, polydecene, or hydrogenated derivatives thereof. Fats as employed by the present invention may be selected from the group consisting of vegetable fats, synthetic fats, and mixtures thereof. Preferably the fats used in the present invention are C6-C30 fatty acids or C6-C30 fatty acid mono- or diesters of glycerin selected from the group consisting of glyceryl stearates, diglyceryl distearate, diglyceryl diisostearate, glyceryl palmitates, palmitates of C18-C36 triglyceride, glyceryl behenates, and mixtures thereof.
- In addition to the chemically modified wax as described herein, the mascara composition of the present invention may include one or more additional structuring agents including other waxes commonly used in cosmetic products or other ingredients that increase the viscosity or thickness of the composition. If present, the additional structuring agents are preferably provided in a total amount ranging from about 0.1% to about 70%, and more preferably from about 0.5% to about 60%, by total weight of the composition. Examples of other waxes include, but are not limited to animal waxes, vegetable waxes, mineral waxes, various fractions of natural waxes, synthetic waxes, petroleum waxes, polyethylene waxes, polypropylene waxes, polyurethane waxes, hydrocarbon-based waxes such as Fischer-Tropsch waxes, silicone waxes, and mixtures thereof. Preferred other waxes in practice of the present invention include beeswax, lanolin wax, shellac wax, carnauba wax, candelilla wax, bayberry wax, ozokerite, ceresin, paraffin, microcrystalline waxes, polyethylene waxes, C24-C45 methicones, and the like. Other types of structuring agents can also be used for increasing the viscosity or thickness of the mascara compositions of the present invention, such as those having an HLB of from about 1 to about 8 and having a melting point of at least about 45Ā°C.
- Other suitable structuring agents may include saturated C14 to C30 fatty alcohols, saturated C16 to C30 fatty alcohols containing from about 1 to about 5 moles of ethylene oxide, saturated C16 to C30 diols, saturated C16 to C30 monoglycerol ethers, saturated C16 to C30 hydroxy fatty acids, C14 to C30 hydroxylated and nonhydroxylated saturated fatty acids, C14 to C30 saturated ethoxylated fatty acids, amines and alcohols containing from about 1 to about 5 moles of ethylene oxide diols, C14 to C30 saturated glyceryl mono esters with a monoglyceride content of at least 40%, C14 to C30 saturated polyglycerol esters having from about 1 to about 3 alkyl group and from about 2 to about 3 saturated glycerol units, C14 to C30 glyceryl mono ethers, C14 to C30 sorbitan mono/diesters, C14 to C30 saturated ethoxylated sorbitan mono/diesters with about 1 to about 5 moles of ethylene oxide, C14 to C30 saturated methyl glucoside esters, C14 to C30 saturated sucrose mono/diesters, C14 to C30 saturated ethoxylated methyl glucoside esters with about 1 to about 5 moles of ethylene oxide, C14 to C30 saturated polyglucosides having an average of between 1 to 2 glucose units and mixtures thereof, having a melting point of at least about 45Ā°C. Preferred other structuring agents for practice of the present invention are selected from stearic acid, palmitic acid, stearyl alcohol, cetyl alcohol, behenyl alcohol, stearic acid, palmitic acid, the polyethylene glycol ether of stearyl alcohol having an average of about 1 to about 5 ethylene oxide units, the polyethylene glycol ether of cetyl alcohol having an average of about 1 to about 5 ethylene oxide units, and mixtures thereof. More preferred other structuring agents are selected from stearyl alcohol, cetyl alcohol, behenyl alcohol, the polyethylene glycol ether of stearyl alcohol having an average of about 2 ethylene oxide units (steareth-2), the polyethylene glycol ether of cetyl alcohol having an average of about 2 ethylene oxide units, and mixtures thereof. Even more preferred structuring agents are selected from stearic acid, palmitic acid, stearyl alcohol, cetyl alcohol, behenyl alcohol, steareth-2, and mixtures thereof.
- Also useful as structuring agents, particularly in the aqueous phase of the compositions of the present invention, are hydrophilic gelling agents such as the acrylic acid/ethyl acrylate copolymers and the carboxyvinyl polymers sold by the B.F. Goodrich Company under the trademark of CarbopolĀ® resins. These resins consist essentially of a colloidally water-soluble polyalkenyl polyether crosslinked polymer of acrylic acid crosslinked with from 0.75% to 2.00% of a crosslinking agent such as polyallyl sucrose or polyallyl pentaerythritol. Examples include Carbopol 934, Carbopol 940, Carbopol 950, Carbopol 980, Carbopol 951 and Carbopol 981. Carbopol 934 is a water-soluble polymer of acrylic acid crosslinked with about 1% of a polyallyl ether of sucrose having an average of about 5.8 allyl groups for each sucrose molecule. Also suitable for use herein are carbomers sold under the Trade Name "Carbopol Ultrez 10, Carbopol ETD2020, Carbopol 1382, Carbopol 1342 and Pemulen TR-1 (CTFA Designation: Acrylates/10-30 Alkyl Acrylate Crosspolymer). Combinations of the above polymers are also useful herein. Other gelling agents suitable for use herein include oleogels such as trihydroxystearin. Hydrophobically modified celluloses are also suitable for use as structuring agents. If present, the gelling agents are provided in a total amount ranging from about 0.05% to about 20%, and more preferably from about 0.5% to about 10%, by total weight of the composition.
- In some embodiments, the mascara composition of the present invention may further include fibers for lash lengthening effects. The fibers useful in the present invention can be either natural fibers or synthetic fibers. Natural fibers include, but are not limited to: cotton fibers, silk fibers, wool fibers, and the like. Synthetic fibers include, but are not limited to: polyester fibers, rayon fibers, nylon fibers, and other polyamide fibers. If present, the fibers are preferably provided at an amount ranging from about 0.01% to about 10% by total weight of the composition.
- The mascara composition of the present invention may also contain one or more hair care actives, such as hair straightening agents, hair curling agents, hair conditioning agents, hair growth agents, and the like. If present, such hair care actives may range from about 0.01% to about 50%, preferably from about 0.05% to about 35% by total weight of the composition.
- The cosmetic composition of the present invention may further include one or more humectants. If present, they may range from about 0.1 to 20% by weight of the total composition and include polyhydric alcohols including glycerol, C1-4 alkylene glycols such as butylene, propylene, ethylene glycol, glycerin, and the like, polyalkylene glycols, and alkylene polyols and mixtures thereof, hyaluronic acid, urea, sorbitol, sodium 2-pyrrolidone-5-carboxylate, soluble collagen, dibutylphthalate and gelatin.
- A variety of water soluble preservatives can be added to the cosmetic compositions of the present invention to provide a prolonged shelf life. Suitable preservatives include, but are not limited to: potassium sorbate, imidazolidinyl urea, p-hydroxy benzoate, esters of p-hydroxybenzoic acid, various parabens (as disclosed in the 12th Edition of CTFA's International Cosmetic Ingredient Dictionary and Handbook), ethylhexylglycerin, caprylyl glycol/phenoxyethanol/hexylene glycol, and the like. Other preservatives suitable for use in the cosmetic compositions of the present invention are disclosed in the 12th Edition of CTFA's International Cosmetic Ingredient Dictionary and Handbook, the entire disclosure of which is herein incorporated by reference for all purposes.
- The cosmetic composition of the present invention may optionally comprise a fragrance in an amount sufficient to make the composition more appealing to the consumer. Preferably, the fragrance is in the amount of from about 0.001% to about 10% by total weight of the composition.
- The mascara compositions of the present application can be first applied to the eyelashes to form an initial coating thereover, and it can be readily re-applied to mascara-coated eyelashes to form one or more additional coatings over the eyelashes after the initial coating is allowed to dry for a sufficient period of time. Such sufficient period of time can range from about 10 seconds to about 2 minutes. Further, the mascara compositions of the present application can be re-applied to mascara-coated eyelashes after an extended period of time, e.g., more than 10 minutes or more preferably, more than 1 hour after application of the initial coating. Most advantageously, the mascara compositions of the present application can be re-applied as many times as desired to form multiple additional coatings, each of which is allowed to dry for a sufficient period of time and each is directly applied over the previous coating, so as to continuously build up the lash volume for a desired dramatic effect.
- The following examples further illustrate various specific embodiments of the present invention, without limiting the broad scope thereof.
-
Formula 1 Components Wt % Deionized Water 56.39 Hydroxyethylcellulose 0.50 Aminomethyl propanediol 1.58 Butylene glycol 1.00 Disodium EDTA 0.10 Iron oxide/PEG-9 dimethicone 2.50 Water/D&C Black #2 Dye/Acacia Senegal gum/decyl glucoside 5.00 Simethicone 0.08 Mica 4.00 Vinylpyrrolidone/DMAPMA copolymer 5.00 Stearic acid 6.10 Paraffin wax 3.20 PEG-8 beeswax 4.00 Camauba wax 1.60 Glyceryl stearate 5.00 Polyisobutene 1.60 Phenoxyethanol/caprylyl glycol/potassium sorbate/water/hexylene glycol 0.70 Ethylhexylglycerin 0.60 Green tea extract 1.00 Water/polyaminopropyl biguanide 0.05 - A comparative study was carried out in order to evaluate the compatibility of polymeric film formers other than the VP/DMAPMA copolymer with the PEG-8 beeswax in forming re-applicable mascara compositions. Specifically, Comparative Formulas 2-5, which contained all the ingredients of Formula 1 except that the VP/DMAPMA copolymer therein was replaced with other polymers, were formed, as follows:
Comparative Formulas 2-5 Components Wt % Formula 2 Formula 3 Formula 4 Formula 5 Deionized Water 56.39 56.39 56.39 56.39 Hydroxyethylcellulose 0.50 0.50 0.50 0.50 Aminomethyl propanediol 1.58 1.58 1.58 1.58 Butylene glycol 1.00 1.00 1.00 1.00 Disodium EDTA 0.10 0.10 0.10 0.10 Iron oxide/PEG-9 dimethicone 2.50 2.50 2.50 2.50 Water/D&C Black #2 Dye/Acacia Senegal gum/decyl glucoside 5.00 5.00 5.00 5.00 Simethicone 0.08 0.08 0.08 0.08 Mica 4.00 4.00 4.00 4.00 Vinylpyrrolidone/DMAPMA copolymer -- -- -- -- DAITOSOL 5000J (water/acrylates/octyl acrylate copolymer) 5.00 -- -- -- SYNTRAN EX35-1 (ammonium acrylates copolymer/butylene glycol/sodium laureth-12 sulfate) -- 5.00 -- -- COVACRYL P12 (water/acrylate copolymer) -- -- 5.00 -- THORCO FLEX IV C (water/polyvinyl acetate/acrylates/hydroxyesters acrylates copolymer/butylene glycol) -- -- -- 5.00 Stearic acid 6.10 6.10 6.10 6.10 Paraffin wax 3.20 3.20 3.20 3.20 PEG-8 beeswax 4.00 4.00 4.00 4.00 Carnauba wax 1.60 1.60 1.60 1.60 Glyceryl stearate 5.00 5.00 5.00 5.00 Polyisobutene 1.60 1.60 1.60 1.60 Phenoxyethanol/caprylyl glycol/potassium sorbate/water/hexylene glycol 0.70 0.70 0.70 0.70 Ethylhexylglycerin 0.60 0.60 0.60 0.60 Green tea extract 1.00 1.00 1.00 1.00 Water/polyaminopropyl biguanide 0.05 0.05 0.05 0.05 - When applied to eyelashes, Formula 1 formed a flexible coating that could be easily re-wetted and re-applied after 3 hours of the initial application, with minimum difficulty of application and little clumping. In contrast, all of the Comparative Formulas 2-5 formed rigid coatings that could not be re-wetted by the respective comparative mascara formula, and re-application of the comparative mascara composition over already-coated lashes was difficult. Therefore, it was demonstrated that selection of the specific polymeric film former and the combined use of such specific film former with the chemically modified wax by the present invention to form a re-applicable mascara composition are both surprising and unexpected over the conventional art.
- Although the invention has been variously disclosed herein with reference to illustrative embodiments and features, it will be appreciated that the embodiments and features described hereinabove are not intended to limit the scope of the invention, and that other variations, modifications and other embodiments will suggest themselves to those of ordinary skill in the art. The invention therefore is to be broadly construed, consistent with the claims hereafter set forth.
Claims (15)
- A mascara composition comprising:(a) a chemically modified wax with one or more hydrophilic functional groups;(b)a polymeric film former comprising monomers having the formula
(c) pigments; and(d) water. - The mascara composition of claim 1, wherein the chemically modified wax is formed by reacting a synthetic or natural wax with a mono-, di-, or polyhydric or alkoxylated alcohol.
- The mascara composition of claim 1, wherein chemically modified wax is formed by reacting a natural wax with polyethylene glycol (PEG).
- The mascara composition of claim 3, wherein the chemically modified wax is selected from the group consisting of PEG-esterified beeswax, PEG-esterified candelilla wax, PEG- esterified carnauba wax, PEG-esterified lanolin, PEG-esterified spermaceti wax, PEG- esterified shellac wax, PEG-esterified bayberry wax, and PEG-esterified sugar cane wax.
- The mascara composition of claim 1, wherein the chemically modified wax is selected from the group consisting of PEG-8 beeswax, PEG-6 beeswax, PEG- 12 beeswax,
PEG- 12 carnauba wax, and PEG-sorbitan beeswax. - The mascara composition of claim 1, wherein the chemically modified wax is present in an amount ranging from about 0.1% to about 20% by total weight of the composition, preferably in an amount ranging from about 1% to about 10% by total weight of the composition.
- The mascara composition of claim 1, wherein the polymeric film former is selected from the group consisting of vinylpyrrolidone/alkylaminoalkyl methacrylamide copolymers, vinylpyrrolidone/alkylaminoalkylene methacrylamide copolymers,
vinylpyrrolidone/alkylaminoalkyl methacrylate copolymers,
vinylpyrrolidone/alkylaminoalkylene methacrylate copolymers,
vinylpyrrolidone/alkylaminoalkyl acrylamide copolymers,
vinylpyrrolidone/alkylaminoalkylene acrylamide copolymers,
vinylpyrrolidone/alkylaminoalkyl acrylate copolymers, and
vinylpyrrolidone/alkylaminoalkylene acrylate copolymers. - The mascara composition of claim 1, wherein the polymeric film former is a vinylpyrrolidone/dimethylaminopropyl methacrylamide (DMAPMA) copolymer.
- The mascara composition of claim 1, wherein the polymeric film former is present in an amount ranging from about 0.1% to about 20% by total weight of the composition, preferably in an amount ranging from about 1% to about 10% by total weight of the composition.
- The mascara composition of claim 1, wherein the pigments are hydrophilic pigments which comprises pigments surface-treated with a hydrophilic material.
- The mascara composition of claim 1, wherein the pigments are present in a total amount ranging from about 1% to about 30% by total weight of the composition and wherein water is present in an amount ranging from about 20% to about 90% by total weight of the composition, preferably in an amount ranging from about 40% to about 70% by total weight of the composition.
- The mascara composition of claim 1, wherein said composition is in the form of an oil-in-water emulsion.
- A method of enhancing the appearance of eyelashes comprising applying a first coating of a mascara composition over the eyelashes, and subsequently applying one or more additional coatings of said mascara composition over the eyelashes after the first coating is allowed to dry thereon for a sufficient period of time, wherein said mascara composition comprises:(a) a chemically modified wax with one or more hydrophilic functional groups;(b) a polymeric film former comprising monomers having the formula
(c) pigments; and(d) water. - The method of claim 13, wherein the first coating is allowed to dry for at least 10 minutes before application of the additional coatings.
- The method of claim 13, wherein two or more additional coatings are subsequently applied to the eyelashes, wherein each additional coating is allowed to dry for a sufficient period of time before application of the next coating and wherein the subsequent application of additional coatings is carried out more than 1 hour after application of the first coating.
Applications Claiming Priority (2)
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|---|---|---|---|
| US7682508P | 2008-06-30 | 2008-06-30 | |
| PCT/US2009/047796 WO2010002602A2 (en) | 2008-06-30 | 2009-06-18 | Re-applicable mascara composition |
Publications (3)
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|---|---|
| EP2313080A2 EP2313080A2 (en) | 2011-04-27 |
| EP2313080A4 EP2313080A4 (en) | 2014-06-25 |
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| FR2993453B1 (en) * | 2012-07-20 | 2016-05-13 | Oreal | COSMETIC COMPOSITION FOR COATING KERATINIC FIBERS |
| FR2993454B1 (en) * | 2012-07-20 | 2016-08-26 | Oreal | COSMETIC COMPOSITION FOR COATING KERATINIC FIBERS |
| KR102022455B1 (en) * | 2012-10-18 | 2019-09-18 | (ģ£¼)ģėŖØė ķ¼ģķ½ | Cosmetic composition for eyebrow or eyelash |
| US9238774B2 (en) | 2012-11-02 | 2016-01-19 | Empire Technology Development Llc | Soil fixation, dust suppression and water retention |
| US9174871B2 (en) | 2012-11-02 | 2015-11-03 | Empire Technology Development Llc | Cement slurries having pyranose polymers |
| US9212245B2 (en) | 2012-12-04 | 2015-12-15 | Empire Technology Development Llc | High performance acrylamide adhesives |
| FR3009194B1 (en) * | 2013-07-30 | 2016-11-04 | Oreal | COSMETIC COMPOSITION FOR COATING KERATINIC FIBERS |
| CN103494717B (en) * | 2013-08-16 | 2015-03-25 | å¹æå·ēÆäŗåå¦åē§ęęéå ¬åø | Non-irritant mascara cream and preparation method thereof |
| KR20160085444A (en) | 2015-01-08 | 2016-07-18 | ģ¤ģ£¼ģ° | Jeju Myth Papertoy book |
| EP3228304A1 (en) * | 2016-04-04 | 2017-10-11 | Mascara Plus S.r.l. | Cosmetic composition |
| KR102598347B1 (en) * | 2016-09-30 | 2023-11-06 | (ģ£¼)ģėŖØė ķ¼ģķ½ | Oil in water type makeup cosmetic composition |
| AU2019227891A1 (en) * | 2018-03-01 | 2020-10-01 | Gojo Industries, Inc. | Alcohol-based hand conditioners for repeated use |
| EP3574888A1 (en) * | 2018-05-30 | 2019-12-04 | The Boots Company PLC | Cosmetic preservative system |
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| US4980155A (en) * | 1989-09-11 | 1990-12-25 | Revlon, Inc. | Two phase cosmetic composition |
| US5356627A (en) * | 1993-02-01 | 1994-10-18 | Estee Lauder, Inc. | Waterproof cosmetic compositions |
| US5750121A (en) | 1996-03-15 | 1998-05-12 | Elizabeth Arden, A Division Of Conopco, Inc. | Color cosmetic composition containing alcohol modified wax |
| US5684105A (en) | 1996-07-23 | 1997-11-04 | Isp Investments Inc. | Process for providing homogeneous copolymers of vinylpyrrolidone and 3-dimethylaminopropyl methacrylamide (DMAPMA) which form clear aqueous solutions having high cloud points |
| JPH10287820A (en) * | 1997-04-10 | 1998-10-27 | Kao Corp | Fine particle pigment |
| FR2783707B1 (en) | 1998-09-25 | 2000-11-03 | Oreal | MAKEUP COMPOSITION COMPRISING POLY-ALPHA-OLEFIN |
| US6207778B1 (en) | 1999-05-07 | 2001-03-27 | Isp Investments Inc. | Conditioning/styling terpolymers |
| US6503521B1 (en) * | 2000-11-22 | 2003-01-07 | L'ORĆ©AL S.A. | Fiber-containing base composition for use with mascara |
| US6726917B2 (en) | 2000-12-18 | 2004-04-27 | L'oreal Sa | Fiber-containing cosmetic composition |
| US20030026815A1 (en) | 2001-06-05 | 2003-02-06 | Scott Alic Anthony | Film forming cosmetic compositions |
| DE10245586A1 (en) | 2002-09-27 | 2004-04-08 | Basf Ag | Use of polymers based on N-vinylcaprolactam |
| JP2004269396A (en) * | 2003-03-07 | 2004-09-30 | Kanebo Ltd | Oily makeup cosmetic |
| US20050025736A1 (en) | 2003-07-30 | 2005-02-03 | Janusz Jachowicz | Hair and skin altering and protecting compositions |
| US20050061349A1 (en) * | 2003-09-19 | 2005-03-24 | L'oreal S.A. | Two-step mascara |
| JP2006306849A (en) * | 2005-03-29 | 2006-11-09 | Kose Corp | Oil-in-water eye makeup cosmetic emulsion |
| FR2887886B1 (en) * | 2005-07-01 | 2010-01-08 | Oreal | NEUTRALIZED CATIONIC POLYMER, COMPOSITION COMPRISING THE SAME AND COSMETIC TREATMENT METHOD |
| JP2009503153A (en) * | 2005-07-22 | 2009-01-29 | ććć¦ć§ć«ć»ć¤ć³ćæć¼ćć·ć§ćć«ć»ć¤ć³ć³ć¼ćć¬ć¼ććć | Cleaning composition, its product and method of use |
| JP2007169419A (en) * | 2005-12-21 | 2007-07-05 | Kao Corp | Polymer emulsion for cosmetic for eyelash |
| US20070212316A1 (en) * | 2006-03-10 | 2007-09-13 | L'oreal | Mascara composition with self-emulsifying waxes and latex polymers |
| FR2900036B1 (en) * | 2006-04-21 | 2008-07-18 | Oreal | KIT FOR MAKE-UP AND / OR CARE |
| US20080102051A1 (en) * | 2006-10-31 | 2008-05-01 | Henkel Kgaa | Use of polyols to increase stiffness in low voc hair styling products |
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| KR20130067318A (en) | 2013-06-21 |
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