EP2302018A1 - Procédé de transport continu à sec d'un matériau devant être oxydé partiellement pour le revêtement d'un réacteur mis sous pression - Google Patents
Procédé de transport continu à sec d'un matériau devant être oxydé partiellement pour le revêtement d'un réacteur mis sous pression Download PDFInfo
- Publication number
- EP2302018A1 EP2302018A1 EP20090012157 EP09012157A EP2302018A1 EP 2302018 A1 EP2302018 A1 EP 2302018A1 EP 20090012157 EP20090012157 EP 20090012157 EP 09012157 A EP09012157 A EP 09012157A EP 2302018 A1 EP2302018 A1 EP 2302018A1
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- EP
- European Patent Office
- Prior art keywords
- reactor
- extruder
- gas
- pressure
- conveyed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
- C10J3/30—Fuel charging devices
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
- C10J2200/158—Screws
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0903—Feed preparation
Definitions
- the present invention relates to a method for conveying a partially oxidized material for charging a printed reactor, in particular a gasification reactor.
- From the gasifier reactor can be generated by the partial oxidation process gas subsequently, which then either used to synthesis gas for valuable chemicals or use a gas turbine under far more environmentally friendly alternative method, the starting materials mentioned under CO2 sequestration for energy production.
- the starting materials In order to feed the starting materials into the reactor, the starting materials must experience an increase in pressure. As a rule, the starting materials are 2 to 5 bar brought over the reactor operating pressure before being transferred to the reactor.
- the one common method is to first prepare a suspension of carbon powder and other partially oxidizable materials with a liquid such as oil or just water, which is then pressurized to higher pressure by a pump and then sprayed into the reactor.
- the water Since a lot of coal is to be used as starting material for the gasification reactors, the water is usually used as an accompanying agent in these processes.
- the feeding of water substantially reduces the reactor power since the water to be used reduces the required high reaction temperature due to the evaporation. This can only be compensated by combustion reaction of the coal to unwanted CO2, which reduces the reactor yield with respect to carbon used to form the desired main products CO and H2.
- the coal dust or other feed material in different particle sizes and shapes in batch cycles from a non-pressurized main silo batchwise and periodically first transferred to an intermediate silo, which depending on the cycle with feed material filled, then time-printed with a carrier gas. Thereafter, the feed material is emptied into a pressure silo (called "Pressurized Surge Hopper") and then the intermediate silo is time-relaxed again before the next filling process is initiated.
- a series of intermittently operating intermediate silos is necessary.
- the intermediate silos must be designed on the one hand for receiving large quantities and on the other hand for pressure cycling. These factors require a high investment.
- discontinuous process management requires a variety of valves and pipes with large diameters, which must be designed for a pressure cycling.
- the circumstance is additionally increased by the fact that one must always receive the conveyed material with a carrier gas in the fluidized bed for handling large quantities of goods in large silos.
- a large amount of inert gas is also necessary, as well as for the discontinuous pressure increase in the intermediate silos and the pressure silo.
- inert gas compressor can easily be used without redundancy for cost and maintenance reasons, a complete shutdown of the system takes place as soon as the compressor fails. In the event of such a failure, comprehensive steps to re-start the entire system are indispensable.
- the object of the present invention is to provide an improved process for the promotion of a partially oxidized material for charging a printed reactor.
- the invention shows a process for the continuous dry promotion of a partially oxidized material for charging a printed reactor, in particular a gasification reactor available, wherein the material from a non-pressurized silo is fed to at least one extruder, whereby the material in the compression zone of the extruder Compression up to above the current operating pressure of the reactor learns.
- As a partially oxidized material may be coal dust or carbon powder, granules, pellets of various starting materials or a mixture of different types of coal, refinery waste such as tar residues, pet coke, organic waste from chemical plants, dried powdered biomass, wood waste of various kinds, dried powdered black liquor Paper and pulp industry and other sustainable materials.
- An extruder is a conveying device which picks up material according to the functional principle of a screw conveyor and presses it out of an outlet opening under pressure increase.
- An extruder in this case has a worm shaft or worm, which is arranged rotatably in a worm cylinder.
- the nominal diameter of the worm cylinder corresponds essentially to the outer diameter of the worm.
- At one end of the screw is a drive, in most cases an electric motor with gear unit (extruder gear), which ensures the rotation of the screw.
- Materials to be processed are usually fed to the screw on this side via a funnel from above.
- At the other end of the worm cylinder is the outlet opening.
- the auger itself is generally divided into three zones that perform different tasks.
- the feed zone In the rear area of the worm cylinder is the so-called feed zone.
- the material to be extruded is e.g. fed through a funnel and compacted.
- the compression zone In which the material is further compressed by the reduced flight depth of the screw and thus the pressure necessary for the discharge is built up.
- the discharge zone ensures a homogeneous material flow.
- the extruder can be, for example, a single-screw extruder, twin-screw extruder (homokinous or countercurrent), multi-screw extruder, coked extruder or planetary extruder.
- the promotion and the pressure build-up are caused by the friction of the mass rotating with the screw on the stationary housing wall (cylinder) in the single-screw and co-rotating twin-screw extruder - in this context one speaks of friction promotion.
- the mass thus left in the rotation is pushed by the helical flights to the outlet opening.
- twin-screw extruder the principle of forced extraction predominates.
- the invention thus provides a continuous high-pressure delivery of dry material, in particular pulverized coal, for the partial oxidation in a coal gasification reactor for the production of the process gas. It is a continuous process for the dry production of coal dust and / or a mixture of partially oxidized materials, in which the conveyed from a non-pressurized silo by means of a suitable conveying member via one or more extruder feed tank one or more extruder (s) is supplied whereby the pulverized feed undergoes compression in the compression zone of the extruder and is subsequently fed to a first overpressure container.
- the material can be transferred from the first overpressure container with one and / or more series-connected overpressure tube chain conveyor (s) in a second high-pressure vessel, from where the material by one or several feed-feed unit (s) - each comprising a rotary valve, a reactor feed line and a Eindüseön for the pneumatic conveyance by means of a conveying gas (saturated steam, superheated steam, inert gas, carbon dioxide, natural gas or a mixture of these gases in any volume ratio) in the Gasification reactor is injected, where the material is reacted at high temperatures and high pressure to process gas, ash and slag.
- a conveying gas saturated steam, superheated steam, inert gas, carbon dioxide, natural gas or a mixture of these gases in any volume ratio
- the material for the partial oxidation consists mainly of coal dust of any type and particle size distribution with a residual moisture content of 0.1 to 10% by weight.
- the material from a silo after grinding by a screw conveyor, belt conveyor or a tube chain conveyor to one or more extruder storage tank (s) is supplied.
- the extruder and other suitable materials such as petroleum coke, coal or hydrocarbon granules in any ratio is supplied so that the conveyed in a temperature range of 5 ° C to 100 ° C under N 2, CO2 or other Inertgaspolster for the partial oxidation can be mixed in a gasification reactor.
- the conveyed in a single-stage and multi-stage extrusion process with the use of one or more serially connected extruder (s) of appropriate design and / or intermediate cooling of the conveyed material is compressed to an overpressure between 0.1 to 100 barü and the extruder discharge pressure as the prevailing operating pressure in the subsequent containers and tube chain conveyor (s) is brought between 0.1 to 20 bar above the pressure of the gasification reactor,
- the compression and frictional heat of the extrusion process continuously from the conveyed material with a coolant such as water, cooling brine, refrigerant indirectly over the lateral surface of the extruder and / or via the shaft (s) of the extruder is discharged in such a manner, wherein the conveyed material is held in a temperature range between 20 ° C and at most 100 ° C such that will not take place there to evaporate the residual moisture.
- the extruder consists essentially only of a compression zone and a downstream integrated coarse and fine crushing zone with sieve insert (Nibbler zone), wherein the compressed coal pieces are rubbed again to coal dust and transferred to a first pressure vessel.
- the present invention further comprises a method for conveying a partially oxidized material for charging a printed reactor, in particular a gasification reactor, wherein the material from an overpressure container via at least one feed unit, which a rotary feeder, a Eindüs ein for the pneumatic winningguttransport and a Reakor feed line comprises, is transported pneumatically to the reactor, wherein advantageously in the rotary valve in the position to be discharged, a conveying gas is injected, whereby the material with the conveying gas in the reactor feed line forms a pneumatic operating condition and is thus guided to the combustion chamber of the reactor.
- Such a method can be used independently of the use of an extruder and is independently subject of the present invention.
- this process can also be used in combination with an extruder.
- the conveyed from a first pressure vessel via Rohrweiche- and quick-closing fittings by means of one and / or more connected in series positive pressure tube chain conveyor (s) to a second pressure vessel is transported, wherein the second pressure vessel is indirectly mounted as the reactor feed tank in the vicinity of the reactor and in the lower part with one or more feed-feed unit (s) consisting of a rotary valve, a conveying gas-Eindüsetechnisch and a reactor -Feed admir that conveys conveyed pneumatically to the associated reactor.
- the rotary valve (s) are provided with a speed-controlled drive, depending on the load case of the reactor conveyed in accordance with the supplied amount of feed from the main silo and extruder delivery (s) from the second pressure vessel and in the lower position the rotary valve (blowing shoe) a pneumatic gas flow consisting of saturated steam, superheated steam, natural gas, an inert gas such as N2 or CO2 or a mixture of said carrier gases arbitrary ratio suspend, whereby the conveyed is introduced into the combustion chamber of the associated reactor.
- the conveyed material guide is controlled by means of a gravimetric and / or solids volume measurement by the speed control of the first conveying member (eg screw conveyor, belt conveyor or tube chain conveyor) and tuning control of the following conveyors such that it is in the extruder head tank, in the first and second pressurized containers can always form a minimum minimum level at which reactor load cases of 5% to 100% normal load case can be set variably.
- the first conveying member eg screw conveyor, belt conveyor or tube chain conveyor
- the conveyed is continuously transferred from the first pressure vessel through one and / or more in series installed tube chain conveyor in a reactor assigned second pressure vessel from which the conveyed via one and / or more feed-feed unit (s), the in each case together with a rotary valve, a Eindüsetechnisch for pneumatic conveying and a reactor feed line together, depending on the needs and system state, the feed-feed units be put into operation, while the conveyed in the reactor feed line various arbitrary Transportzusatand (eg Dense Flow Phase) can form before the conveyed mouths in the combustion chamber of the reactor.
- a Transportzusatand eg Dense Flow Phase
- the shaft feedthrough in all rotating components are additionally equipped with Lauter protection and sealing gas and Staubausschleusung.
- the present invention further comprises a method of conveying a partially oxidized material to charge a printed reactor, in particular a gasification reactor, the material being treated with a carrier gas, e.g. Saturated steam, inert gas, natural gas, hydrocarbons, CO2, in particular with superheated steam is injected into the reactor, wherein the carrier gas itself serves as a reactant for the partial oxidation of the material.
- a carrier gas e.g. Saturated steam, inert gas, natural gas, hydrocarbons, CO2
- Such a method is independent of the other promotion of the material of advantage and independent subject of the present invention.
- the method is advantageously used in combination with an extruder and / or a feed unit as described above.
- the conveyed with an overpressure of 0.1 barü to 100 barü and a differential pressure to the operating pressure of the gasification between 0.1 to 20 bar and a load index of 0.1 to 50 kg of coal dust per kg of carrier gas at temperatures between 20 ° C to 100 ° C in the reactor with a carrier gas (saturated steam, inert gas, natural gas, hydrocarbons, CO2), in particular with superheated steam, which itself serves as a reactant for the partial oxidation of coal.
- a carrier gas saturated steam, inert gas, natural gas, hydrocarbons, CO2
- a discharge eg Oszillomaten
- Oszillomaten e.g Oszillomaten
- a particularly advantageous embodiment according to the invention is a continuous process for the dry extraction of coal dust and / or a mixture of partially oxidized materials (mixture of the material to be conveyed consisting of different types of coal, petroleum coke, recirculating ash and chemical additives as "co-feed "in any mixing ratio) without the use of fluidized bed or fluidized bed gas in silos, in which the conveyed from a non-pressurized silo, which serves for the intermediate storage of coal dust under an inert atmosphere and is characterized by a built-discharge (eg, oscilloscites), the Conveyed material by means of a suitable conveying device (eg screw conveyor, belt conveyor or tube chain conveyor process-controlled with gravimetric or solid particle measurement) and via one or more extruder feed first to one or more extruder (s) - possibly with intermediate cooling of securitiesg utes- is fed, whereby the pulverized feed in the compression zone of the extruder undergoes high pressure compression to above the current operating pressure of the gasification
- the second pressure vessel is the coal gasification reactor indirectly allocated and by one or more feed unit (s) - consisting of each a rotary valve, a Eindüse réelle for pneumatic conveyance and a reactor feed line - which are installed in the lower part of the container, characterized in that in each of the rotary valves in the discharged Position a delivery gas (saturated steam, superheated steam, inert gas, carbon dioxide, natural gas or a mixture of these gases in any volume ratio) is injected, whereby the conveyed with the injection gas in the reactor feed line any pneumatic operating condition (eg Dense flow phase ) and thus leads to the combustion chamber of the reactor, where the conveyed with air, pure oxygen, natural gas or other hydrocarbon compounds and / or liquid fuel materials (naphtha, oil, light and medium fractions, etc.), each by their own separate lines
- a delivery gas saturated steam, superheated steam, inert gas, carbon dioxide, natural gas or a mixture of these gases in any volume ratio
- the extruder used is characterized by two features, namely that on the one hand, the heat resulting from the compression and friction is discharged from the conveyed indirectly with a coolant through the jacket cooling of the extruder and / or through the shaft of the extruder, so that the Residual moisture in the feed during the compression does not begin to evaporate and is retained in the absorbed or in the liquid state and on the other by the feature that the extruder for breaking the possibly used agglomerated materials in a second extrusion zone with an integrated coarse and fine crusher Sieve insert (Nibbler) is equipped.
- the present invention further comprises a system for the continuous dry delivery of a partially oxidized material for feeding a printed reactor, comprising at least one non-pressurized silo, an extruder and a first pressure vessel, wherein the material from the non-pressurized silo is fed to the extruder, whereby the material in the compression zone of the extruder can be compressed above the current operating pressure of the reactor and transported in the first pressure vessel.
- the present invention further includes systems for performing any of the methods set forth above.
- FIG. 1 it is here according to FIG. 1 to processes for a continuous process for the dry extraction of coal dust 1 and / or a mixture of partially oxidized materials (mixture of the conveyed consisting of different types of coal, petroleum coke, recirculating ash and chemical additives, called co-feed 2 in any mixing ratio) without Use of fluidized bed or fluidized bed gas in silos, in which the conveyed from a non-pressurized silo 3, which serves for the intermediate storage of coal dust under an inert atmosphere and is characterized by a built-in discharge element 3a (eg., Osszilomaten), the conveyed by means of a suitable authoritiesorgans 4 (eg screw conveyor, belt conveyor or tube chain conveyor process controlled under gravimetric or solid particle measurement) and one or more extruder feed 5 first to one and / or more extruder (s) 6 - and / or supplied with intermediate cooling of the conveyed material, wherein the pulveris Feed in the compression zone of the extruder undergoe
- the material to be conveyed is transferred under pressure by means of an overpressure conveying element 10 (eg overpressure tube chain conveyor and / or several series-connected overpressure tube chain conveyors) into a second high pressure container 11 under inert gas pressure cushion, the second pressure container 11 being the coal gasification reactor 17 is indirectly allocated and by one or several rotary valve (s) 12 combined with reactor feed line (s) 14 in the lower part of the container in such a way that in each of the rotary valves 12 in the position to be discharged a conveying gas 13 (saturated steam, superheated steam, inert gas, carbon dioxide, Natural gas or a mixture of these gases in any volume ratio) is injected, whereby the conveyed with the injection gas 13 in the reactor feed line 14 forms an arbitrary pneumatic operating state (eg Dense flow phase) and is thus guided to the combustion chamber of the reactor 17 ,
- an overpressure conveying element 10 eg overpressure tube chain conveyor and / or several series-connected overpressure tube chain conveyors
- the extruder 6 used has a cooling system, so that the resulting from the compression and friction heat from the conveyed material is discharged indirectly with a coolant through the jacket cooling of the extruder and / or in addition by the waves of the extruder 6a such that the residual moisture in the Feed does not begin to evaporate during compression and is retained in the absorbed or in the liquid state of aggregation. Furthermore, the extruder is equipped to break the agglomerated carbon powder used in a second extrusion zone with an integrated coarse and fine crusher with sieve insert (Nibbler) before the conveyed material is discharged into the first overpressure template 7.
- the pulverized coal pressure increasing device consisting of extruder feed 5 and extruder 6 (possibly with first pressure vessel 7 with diverter 8 and quick-closing 9) should be redundant with one facility (called "skid") functioning as the operating ski and the other as stand-by.
- skid one facility
- a relaxation of the pressure vessel over a separate gas line as well as coal emptying on drain valve 18 may be required.
- the present inventive method uses a number of drives, the shaft is in contact with the conveyed under pressure. Therefore, it is appropriate to apply a suitable shaft seal such as labyrinth seal with impinged inert barrier gas or particularly suitable sliding seals with inert lubricant gas as a sealing member.
- a suitable shaft seal such as labyrinth seal with impinged inert barrier gas or particularly suitable sliding seals with inert lubricant gas as a sealing member.
- the shaft seal can be trimmed with an additional lantern through which the penetrating coal dust can be discharged with an inert purge gas from the lantern space.
- the tube chain conveyor (or the set of pressurized tube chain conveyors connected in series) could possibly be installed in duplicate, although this device is considered to be low maintenance and repair. All other components can be easily installed thanks to their excellent granted function.
- the invention offers in continuous operation, in the extruder head tank 5 and in the first and second pressure vessels 7 and 11 to ensure a minimum level of conveyed so that the inert cushion gas does not unnecessarily via rotary valve enters the reactor and thus has a high consumption.
- the first conveyor member 4 are equipped with a frequency-controlled speed control, which can be controlled via a suitable baingutmengentician (level control, gravimetric or solid volume measurement desgl.).
- a suitable baingutmengentician level control, gravimetric or solid volume measurement desgl.
- the components rotary valve, injection line 13 and reactor feed line 14 together form a respective feed-feeding unit.
- the second pressure vessel 11 may be provided with one or more feed-feeding unit (s).
- a number of feed feed units allow the gasification reactor to accept variable load cases of the system.
- Such operating conditions are such. B. at low load, starting or Abfahrlast easily adjustable.
- the conveyed different grade or a mixture of different starting materials which have passed the apparatuses 3 to 10, fed through one or more feed-feed unit (s) in the reactor.
- the conveyed material is placed in a pneumatic transport state immediately before the reactor inlet in the reactor feed line.
- various pneumatic operating conditions such as dilute phase conveying, dense phase convection with bypass, dense phase pressure conveying can form here, the latter conveying mechanism having a loading index of 0.1 up to 50 kg of coal dust per kg conveying gas and a pressure gradient between the second pressure vessel and the reactor operating pressure of 0.1 to 20 bar are particularly suitable for gasification reactors.
- any pneumatic operating state can be set in any load state of the system, without the interte carrier gas, the progress of the desired chemical reactions disadvantageous affected.
- the pneumatic transport state can be adjusted in a simple manner by means of gravimetric solids feed and quantity measurement in the carrier gas stream 13 by means of a control valve (or for each carrier gas component such as inert gas, natural gas, etc.).
- One of the essential features of the method according to the invention is that the solids are conveyed in the dry state.
- the usual process control by a coal slurry (slurry feed) with a carrier liquid - usually water - is no longer necessary.
- the disadvantageous for the reaction and reactor load water is eliminated.
- the superheated steam 13 to be injected is partly converted chemically into process gas in the reactor, secondly the chemically unreacted steam can easily be condensed out in the following quenchers and condensers.
- the followers are not unnecessarily burdened by inert gases.
- the latter feature helps to reduce the size of the downstream equipment (especially for gas purification and possibly CO2 separation) and reduces the investment.
- the process gas is further processed into chemical products, the latter feature is of particular interest.
- Present processes do not unnecessarily reduce the partial pressures of the reactive components (CO and H2) for CO conversion. This has a positive effect on the design of the catalytic secondary reactors, if z. B. the process gas for ammonia synthesis, methanol, SNG or Fischer-Tropsch synthesis is to be used. This results, for example, in existing ammonia synthesis, as well as in methanol synthesis plants, now higher reactor capacities are possible.
- the amount of purge gas from the synthesis loop can be reduced, if the process gas from the outset with less Inert gas component is loaded.
- the process gas produced is to be used according to the present invention for a gas turbine with particularly suitable overpressure CO2 separation, so the process leads to enormous relief when the process gas is no longer by the carbon supply with inert carrier gas such. B. N2 is additionally charged. In this case, the size and extent of the CO2 separation will be smaller.
- this method requires much lower investment volume, maintenance costs, etc., which have a positive effect on the profitability of the entire system.
- the present method can there z. B. by a discharge (similar to that described above, screw conveyor and an additional gas return line back to the pressure silo 3) are equipped, the discharge is performed in the first pressure vessel. From there, the new process can be integrated, whereby a number of advantages mentioned above (such as reactor discharge by eliminating the inert transport gases for the coal supply, etc.) can be used according to the invention.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Filling Or Emptying Of Bunkers, Hoppers, And Tanks (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Air Transport Of Granular Materials (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP20090012157 EP2302018A1 (fr) | 2009-09-24 | 2009-09-24 | Procédé de transport continu à sec d'un matériau devant être oxydé partiellement pour le revêtement d'un réacteur mis sous pression |
US13/261,207 US20120182827A1 (en) | 2009-09-24 | 2010-09-09 | Process for continuous dry conveying of carbonaceous materials subject to partial oxidization to a pressurized gasification reactor |
PCT/US2010/002482 WO2011037606A2 (fr) | 2009-09-24 | 2010-09-09 | Procédé pour transporter à sec et en continu des matières carbonées soumises à une oxydation partielle vers un réacteur de gazéification sous pression |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP20090012157 EP2302018A1 (fr) | 2009-09-24 | 2009-09-24 | Procédé de transport continu à sec d'un matériau devant être oxydé partiellement pour le revêtement d'un réacteur mis sous pression |
Publications (1)
Publication Number | Publication Date |
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EP2302018A1 true EP2302018A1 (fr) | 2011-03-30 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP20090012157 Withdrawn EP2302018A1 (fr) | 2009-09-24 | 2009-09-24 | Procédé de transport continu à sec d'un matériau devant être oxydé partiellement pour le revêtement d'un réacteur mis sous pression |
Country Status (3)
Country | Link |
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US (1) | US20120182827A1 (fr) |
EP (1) | EP2302018A1 (fr) |
WO (1) | WO2011037606A2 (fr) |
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WO2011037606A3 (fr) * | 2009-09-24 | 2013-08-01 | Faramarz Bairamijamal | Procédé pour transporter à sec et en continu des matières carbonées soumises à une oxydation partielle vers un réacteur de gazéification sous pression |
CN107597449A (zh) * | 2017-10-19 | 2018-01-19 | 中冶北方(大连)工程技术有限公司 | 一种袋装粉状药剂的自动上料系统 |
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US8667706B2 (en) * | 2008-08-25 | 2014-03-11 | David N. Smith | Rotary biomass dryer |
AU2012284946A1 (en) * | 2011-07-19 | 2014-02-27 | Mitsubishi Hitachi Power Systems, Ltd. | Drying conveyer, and thermal electric power generation system provided with same |
US10190065B2 (en) * | 2013-03-15 | 2019-01-29 | Mark E. Koenig | Feed delivery system and method for gasifier |
WO2014143170A1 (fr) | 2013-03-15 | 2014-09-18 | Koenig Mark E | Vanne d'isolement |
ITMO20150099A1 (it) * | 2015-05-05 | 2016-11-05 | Syn Gas Gruppo S R L | Impianto di gassificazione |
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- 2010-09-09 US US13/261,207 patent/US20120182827A1/en not_active Abandoned
- 2010-09-09 WO PCT/US2010/002482 patent/WO2011037606A2/fr active Application Filing
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US4466809A (en) * | 1981-05-08 | 1984-08-21 | Creusot-Loire | Fuel supply method for a gasification chamber |
US20050006813A1 (en) * | 2003-07-11 | 2005-01-13 | Kabushiki Kaisha Kobe Seiko Sho | Metering feeder, and system and method for kneading and extruding material |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2011037606A3 (fr) * | 2009-09-24 | 2013-08-01 | Faramarz Bairamijamal | Procédé pour transporter à sec et en continu des matières carbonées soumises à une oxydation partielle vers un réacteur de gazéification sous pression |
CN107597449A (zh) * | 2017-10-19 | 2018-01-19 | 中冶北方(大连)工程技术有限公司 | 一种袋装粉状药剂的自动上料系统 |
CN112691593A (zh) * | 2020-12-18 | 2021-04-23 | 酒泉职业技术学院(甘肃广播电视大学酒泉市分校) | 生物质固体燃料生产用添加粉剂设备 |
CN112691593B (zh) * | 2020-12-18 | 2022-07-29 | 酒泉职业技术学院(甘肃广播电视大学酒泉市分校) | 生物质固体燃料生产用添加粉剂设备 |
CN114686272A (zh) * | 2020-12-27 | 2022-07-01 | 新疆宜化化工有限公司 | 一种提高气化过程中煤灰熔点的复配剂及混合工艺 |
CN112915953A (zh) * | 2021-02-10 | 2021-06-08 | 中国天辰工程有限公司 | 一种气液固三相搅拌釜式反应器 |
CN112915953B (zh) * | 2021-02-10 | 2023-05-30 | 中国天辰工程有限公司 | 一种气液固三相搅拌釜式反应器 |
Also Published As
Publication number | Publication date |
---|---|
US20120182827A1 (en) | 2012-07-19 |
WO2011037606A3 (fr) | 2013-08-01 |
WO2011037606A2 (fr) | 2011-03-31 |
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