Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L19/00—Compositions of rubbers not provided for in groups C08L7/00 - C08L17/00
  • C08L19/003—Precrosslinked rubber; Scrap rubber; Used vulcanised rubber
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
  • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
  • C08L23/04—Homopolymers or copolymers of ethene
  • C08L23/08—Copolymers of ethene
  • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
  • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
  • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
  • C08L23/10—Homopolymers or copolymers of propene
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
  • C08K3/013—Fillers, pigments or reinforcing additives
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
  • C08K5/005—Stabilisers against oxidation, heat, light, ozone
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
  • C08K5/0066—Flame-proofing or flame-retarding additives
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
  • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
  • C08L23/04—Homopolymers or copolymers of ethene
  • C08L23/06—Polyethene
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
  • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
  • C08L23/04—Homopolymers or copolymers of ethene
  • C08L23/08—Copolymers of ethene
  • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
  • C08L23/0853—Ethene vinyl acetate copolymers
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
  • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
  • C08L23/16—Ethene-propene or ethene-propene-diene copolymers

Definitions

• the present invention relates to building components, such as roofing elements, and more particularly to building components that are formed of specified combinations of synthetic materials to simulate building components formed from natural materials and to enhance the desirable properties of the building components.
• Synthetic products have been developed which simulate natural-appearing building components for use in decks, roofs, such as slate roofs, and other building structures.
• these synthetic building components are either very heavy, or if weight is a consideration, rather thin, when constructed thinner than natural slate or other natural roofing tiles, in order to reduce the weight required.
• the properties of certain materials used to form these materials necessitate that the processing of the material be carefully controlled in order to form useful products.
• the molding process must be closely controlled to prevent the item molded from the polypropylene from having undesirable properties, such as limited impact resistance, such as in compression molding processes.
• the building component composition should allow for increased ease of manufacture such that the building component can be formed with the desired appearance in any suitable molding process. Further, when the building components are to be removed and replaced, it would be desirable to be able to recycle the building components to form additional building components, as opposed to simply disposing of them.
• a one-piece building component such as a roofing element
• a building component composition including various materials selected to provide various benefits to the building component.
• the composition for the building component is formed of a polymeric resin combined with a binder.
• the presence of the binder allows for the manipulation of the properties of the polymeric resin, especially in the case of recycled polymeric resins, and the resulting building component, in manner that improves the ability to process the resin to form a building component using various molding techniques.
• These property benefits include increased mold resistance, fire retardency, increased wind resistance, increased impact resistance, and appearance.
• the binder utilized in the composition of the roofing element enables the composition for the building component to be formed with synthetic components that can be obtained from scrap or other recycled materials. Also, the use of these materials and the binder renders the roofing component itself entirely recyclable for forming additional building components
• the primary materials used in forming the roofing tiles include polymeric resins or plastics of various types, such as polypropylene, giving the composition a large amount of flexibility when processing the composition into the desired roofing element. The additional components of the composition are then added to this initial starting material and subsequently formed into the building component with the desired shape, color and size.
• the synthetic roofing element comprises a body composed of a material which is molded so as to very closely resemble the appearance of natural building materials, such as slate, ceramic, wood, and stone, among others.
• the synthetic building component of the present invention may be manufactured, such as in any suitable molding, extrusion or similar process for composite plastic materials, to realistically resemble other natural materials for use in building structure applications and for use, generally, in other cladding capacities not limited to roofing applications, including but not limited to siding, foundation, decking and decorative trim applications, among others.
• such natural materials to be emulated according to the present invention may include stone, clay, cedar and other finishes intended to emulate the look and texture of stone and wood materials.
• the synthetic building component of the invention when emulating a stone or ceramic finish may be formed to replicate the shape, size, structure and texture of clay, terra cotta, Spanish/mission tile, barrel tile and ceramic tile.
• the synthetic building component when emulating a wood finish, may be formed to replicate the shape, size, structure, texture and grain of any of a variety of hardwoods and soft woods, such as cedar, oak, mahogany, and the like.
• the building component of the present invention is formed of a composition including as a primary component or ingredient a plastic or polymeric resin material that comprises one or more plastics selected from polyesters, polyolefms, polyethylenes, including high-, medium- and low-density polyethylene, polystyrenes, polyamides, polypropylenes, and equivalents and combinations thereof.
• the plastic or resin component of the composition of the roofing element is present within a range of about 10% to 90% by weight of the composition for the roofing element.
• the plastic ingredient of the building component of the present invention gives the building component the mechanical properties of hardness, rigidness, being infusible and insoluble (i.e., waterproof), and, optionally has extensive cross-linking.
• the plastic or polymeric resin material may be obtained as virgin thermoplastic polymer materials, or can be obtained from recycled material streams formed essentially of the above polymers.
• the plastic ingredient is formed from at least partially from polypropylene materials.
• Polypropylene has previously been used for constructing building components, but has been limited in its use to only virgin polypropylene.
• the use of exclusively virgin polypropylene has resulted in building components having limited desirable qualities, such as fire and impact resistance, due to the issues with processing the virgin polypropylene in an injection molding process.
• the other essential component of the building component composition is one or more binders that are present preferably in an amount of up to about 90% by weight of the overall composition, and more preferably between about 1% and about 75% by weight.
• the binder effectively alters the properties of the polymeric resin used to form the building component to provide a building component having the desired fire, impact and wear resistance, while also allowing the building component to be formed utilizing multiple molding processes.
• the presence of the binder alters the melt index of the polymeric resin thereby allowing the resin and binder to be used in different molding processes to form the building component, such as injection molding, compression molding, and extrusion, among others.
• the binder changes the physical properties of the resulting building component, including the impact resistance without degrading the natural properties of the primary ingredient, such as it fire resistance.
• the binder itself takes the form of another polymeric resin distinct from that used as the primary ingredient of the building component, but can be similar to those resins used as the primary ingredient.
• the polyethylene resins discussed previously can also be utilized, or function in the composition as the binder for the other resins present in the composition, hi addition to polyethylene, other suitable plastics or polymeric resins that can be used as the binder include ethylene/vinyl acetate polymers, which can be used alone or in combination with an ultra low density polyethylene to form the binder, such as EVAC- Ethylene- Vinyl Acetate Copolymer, as well as LLDPE- Linear Low Density Polyethylene, LDPE- Low Density Polyethylene, Metalocine , EAA-Ethylene/ Acrylic Acid Copolymer, ultra low density polypropylene, EEA Poly(Ethylene-Ethyl Acrylate) , EAA-Ethylene/ Acrylic Acid Copolymer, PVB- Poly(Vinyl Butyral), EMAC-
• Polyolefin (often applied to elastomers), TPU- Thermoplastic Polyurethene (often applied to elastomers), or materials of comparable physical properties.
• the binder in combination with the different polymeric resins as the primary ingredient essentially allows the composition to be modified as necessary to provide a building component with the desired properties based on the type and amount of the binder that is used.
• the binder is selected based on its properties to create a composition that can be formed into the desired building component using the specified process, and that has the desired impact, wear and heat or fire resistance properties. Therefore, in the case of use of a recycled polymeric resin material as the primary component which may not have the desired initial characteristics, a binder can be selected and added to the recycled resin to provide a composition that has the desired properties and can effectively be used to form a building component. Further, because each of the resin components used in the composition can come from recycled materials, the entire building component formed from the composition can itself be fully recycled.
• the building components of the present invention may preferably include other ingredients in the composition.
• One of these ingredients is a filler compound.
• the compounds that can be utilized as the filler for the building component composition of the present invention include chemical constituents that are inactive chemical compounds which act as reinforcing agents that impart to a composition matrix considerable stiffness and rigidity, as compared with those of a pure thermoplastic or polymeric resin component.
• the filler compounds for the composition of the building component of the present invention are used to increase the modulus of elasticity and strength of the composition forming the building component.
• thermoplastic or polymeric resin component with the filler compound is used to produce a composite building component that is less brittle and more resistant to impact stresses, and at the same time maintaining adequate compressive, tensile, flexural and shear strengths, respectively, to the formed building component.
• the filler compounds that can be used in the composition for the roofing elements include filler compounds selected from the group consisting of calcium oxide; calcium carbonate; cement; fly ash; fiberglass fibers; metal shavings; metal oxides, such as zinc oxide; polyester fibers; aluminum oxides; mica; perlite; zeolites; vermiculite; silica; silicates; quartz sands, #12 sand; #30 sand, #60 sand; aggregate particles/granules of stone, rock, marble, gravel, glass, clay and talc and equivalents and combinations thereof.
• One additional filler compound that is most preferably utilized in the composition for the building component of the present invention is composed of polymeric compounds and recycled tire bits.
• Both ethylene propylene-diamine monomer copolymers and styrene butadiene rubber, which is obtained from shredded vehicle tires, are excellent filler materials in the molded products of the invention, and are typically obtained by recycling waste materials which would otherwise go to already full land fills.
• Such filler materials have already been “vulcanized”, so they are fire retardant as well, which provides additional benefit to he roofing elements of the present invention. They are relatively inexpensive, water repellant and high temperature resistant, so they are especially suitable for use in building components such as roofing materials (shingles), floor coverings (tiles and sheet material), and other construction materials among other items.
• Other filler compounds, such as those described previously, could also be used to replace all or a part of the preferred copolymer and rubber materials, so long as the replacement filler compounds have the needed properties to the building component, especially water and heat resistance.
• the composition used to form the building component of the present invention also preferably contains various additional additives.
• the additives can include compounds such as thermal stabilizers, ultraviolet (UV) light stabilizers, pigments or colorants, compatibilizers, processing aids, flame retardant additives, and other functional chemicals capable of improving processing of the materials and performance of the building components formed from the composition.
• the colorants are preferably present in an amount of up to 15% by weight of the overall composition, and more preferably up to about 10% by weight between preferred coloring in the formulation is natural iron oxide.
• preferred coloring in the formulation is natural iron oxide.
• any other suitable natural or synthetic coloring materials may also be used to provide the building components with the desired appearance.
• the components are preferably present in an amount of up to 60% by weight of the overall composition, and more preferably between about 1% and about 50% by weight, with a couple of preferred components are aluminum trihydrate and magnesium hydroxide.
• Other fire retardants may be used instead of either the aluminum trihydrate or the magnesium hydroxide.
• Plastisan B made by 3 V Corp., Georgetown, S. C, Phos-check, available from Solutia Corp., St, Louis, Mo.
• Dover- phos-9228 made by Dover Chemical, Dover, Ohio.
• composition for the roofing elements can contribute to the fire retardency of the building components other than the actual fire retardant, such as the preferred filler material including the recycled tire rubber which as a result of being vulcanized, already has a fire retardant aspect to it.
• the UV components can be present in the composition in an amount of up to about 20% by weight of the overall composition, and more preferably from between about 0.1% to about 16% by weight, and can include UV inhibitors and UV stabilizers.
• the UV stabilizers can include Tinuvin®783 FDL or Univol 5050H, from Ciba® of Basel, Switzerland, which each show significant contribution to long-term thermal stability for the composite material element, and helps to keep the material from chalking on the surface over time.
• the UV inhibitors may include Chimassorb® 81 or Univol 3008, from Ciba® of Basel, Switzerland, which are each a solid-form UV absorber of the 2-hydroxy-benzophenone class.
• the absorbance spectrum (in the UVB range only) for the inhibitor and relatively low photo-permanence makes it useful in this application, as it helps to absorb the UV rays that could otherwise cause premature degradation of the material performance for the composition forming the building components.
• the composition can also include antioxidants as an ingredient preferably present in an amount of up to 10% by weight of the overall composition, and more preferably between about 1% and about 8% by weight, such as Irganox ® B225 or Annox B8011, from Ciba® of Basel, Switzerland, which are phenolic based anti-oxidants that hinder thermally induced oxidation of polymers in high temperature applications.
• the antioxidants function to stabilize the color and appearance of the surface of the composite material used to form the building components.
• the stabilization function of the antioxidants effectively controls the look of the building components throughout the varying temperatures of the processing of the material, instead of allowing the high processing temperatures to negatively affect the look of the color and surface of the building components.
• ethylene vinyl acetate and ultra low density polyethylene as a binder in an amount of between about 10-40% by weight, and more preferably about 15% by weight;
• a fire retardant i.e., aluminum tri-hydrate or magnesium hydroxide in an amount of 10-35% by weight
• iron oxide in an amount of between about 1-10% by weight
• high density polyethylene as a primary resin ingredient in an amount of between about 5-50% by weight
• U. V. stabilizer in an amount of between about 1-8% by weight; 7.
• U.V. inhibitor in an amount of between about 1-8% by weight; 8. antioxidant in an amount of between about 1-8% by weight.
• the above materials are added together in the form of dry powders into a suitable mixing apparatus and agitated therein for a sufficient time period to achieve a uniform and homogeneous building component composition.
• the desired coloring for the particular building component desired is added to the composition in the mixing apparatus during the agitation of the composition within the apparatus to achieve a uniform and homogeneous distribution of the coloring throughout the composition.
• This uniformly mixed composition can then be utilized in various forms to form the desired roofing element by introducing the composition into a suitably-shaped mold to form the building component therein under sufficient temperature and pressure.
• certain methods that can be utilized to process the composition into the building element having the desired shape include extrusion, compression molding, injection molding, and thermoforming.
• the uniform composition can be further processed, such as to enable the composition to be stored for later use, or to place the composition in a form, e.g., forming the composition into multiple pellets, to increase the ease of use of the composition in other processes to form building components, to maximize quality of the composition and the roofing elements formed therefrom, and to aid in creating a less hazardous production environment by reducing the dust generated from the use of the composition.
• One additional advantage of the building component compositions of the present inventions is the lack of the need for any pre-heating step in the processing of the composition. In some other similar processes using similar materials it is necessary to preheat or to chemically cure the virgin polymer composition while processing the composition prior to forming the building component. Unfortunately, this required step has the drawback of degrading the properties of the virgin material being processed, which results in a building component with degraded properties. In the process for forming the roofing component of the composition of the present invention, there is no preheat or chemical curing step.
• the materials or ingredients for the composition are simply mixed together in dry powdered form and then either immediately heated for molding the building components, or cooled and pelletized, such that the pellets can be stored or transported for later use when they can be heated and molded into the finished product. This reduces the energy consumption and stress on the material by reducing the number of heat cycles. And also saves on the amount of fossil fuel used in the processing of the building components as no additional heat needs to be applied to the composition.
• a roof sheathing material is manufactured with a formulation similar to that employed in Example 1, but without styrene butadiene rubber and a mineral filler.
• TPO Thermoplastic Polyolefin as a binder up to about 50% by weight (of the overall composition);
• ethylene vinyl acetate and ultra low density polyethylene as a binder in an amount of between about 10-40% by weight, and more preferably about 15% by weight;
• a fire retardant i.e., aluminum tri-hydrate or magnesium hydroxide in an amount of 10-35% by weight
• polypropylene as a primary ingredient in an amount of between about 5-50% by weight
• the polypropylene is used to make the product slightly flexible but is still rigid enough to be used as the desired component, such as for decking, due to the presence of the binder which alters the natural properties of the polypropylene, even when in recycled form, to achieve these properties. Additionally, since this component is designed for use under other building materials, no colorants are added to the composition.
• the material composition provides a strong non-rotting material that tightly seals and/or engages with fasteners to prevent water intrusion.
• the product formed from this composition is impact- resistant, and is has a much greater useful life than the natural product it replaces, such that this particular application of the building component composition can eliminate the need for underlayments that degrade over time.
• the sheathing can also be made in a standard size without any loss of the composition in the manufacturing process. This material composition is also fully recyclable.
• a fire retardant in an amount of 45% by weight (of the overall composition);
• ultra low density polyethylene and/or ethylene vinyl acetate as a binder in an amount of 25% by weight;
• high density polyethylene as a portion of the primary ingredient in an amount of about 20% by weight
• low density polyethylene as a portion of the primary ingredient in an amount of about 10% by weight
• EXAMPLE 4 A Spanish replica tile that is very lightweight and which is class A fire and Class
• Example 4 hail rated can be molded from the following composition of the present invention formed in a manner similar to Example 1 :
• polypropylene a primary ingredient in an amount of up to about 75% by weight (of the overall composition); 2. calcium carbonate in an amount of between about 10-50% by weight, and more preferably about 35% by weight;
• Linear Low Density Polyethylene as a binder system present in an amount of between about 1-20% by weight; 5. a U. V. stabilizer present in an amount of between about 0.1- 8% by weight; and
• a U.V. inhibitor present in an amount of between about 0.1- 8% by weight.
• a shake or cedar replica shingle can be formed with the following components in another preferred embodiment of the composition of the present invention: 1. polypropylene a primary ingredient present in an amount of up to about 75% by weight of the overall composition;
• calcium carbonate present in an amount of between about 10-50% by weight, and more preferably present in an amount of about 35% by weight;
• a fire retardant present in an amount of between about 20-50% by weight;
• ultra low density polypropylene as a binder system present in an amount of between about 1-20% by weight;
• a U.V. stabilizer present in an amount of between about 0.1%- 8% by weight; and 6. a U.V. inhibitor present in an amount of between about 0.1%- 8% by weight.

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• Chemical & Material Sciences (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Organic Chemistry (AREA)
• Compositions Of Macromolecular Compounds (AREA)
• Roof Covering Using Slabs Or Stiff Sheets (AREA)

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• 2008
  • 2008-06-11 US US12/137,078 patent/US20090308009A1/en not_active Abandoned
• 2009
  • 2009-06-10 WO PCT/US2009/046853 patent/WO2009152213A1/en not_active Ceased
  • 2009-06-10 JP JP2011513653A patent/JP2011524441A/ja active Pending
  • 2009-06-10 KR KR1020107028691A patent/KR20110017391A/ko not_active Withdrawn
  • 2009-06-10 EP EP09763503A patent/EP2291442A1/en not_active Withdrawn

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