EP2279237A1 - Aqueous textile treatment means - Google Patents
Aqueous textile treatment meansInfo
- Publication number
- EP2279237A1 EP2279237A1 EP09742122A EP09742122A EP2279237A1 EP 2279237 A1 EP2279237 A1 EP 2279237A1 EP 09742122 A EP09742122 A EP 09742122A EP 09742122 A EP09742122 A EP 09742122A EP 2279237 A1 EP2279237 A1 EP 2279237A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition according
- weight
- textile
- textiles
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004753 textile Substances 0.000 title claims description 25
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 16
- 235000020665 omega-6 fatty acid Nutrition 0.000 claims abstract description 7
- 229940033080 omega-6 fatty acid Drugs 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000008139 complexing agent Substances 0.000 claims description 6
- 239000004615 ingredient Substances 0.000 claims description 5
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 4
- 239000008280 blood Substances 0.000 claims description 4
- 210000004369 blood Anatomy 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000002516 radical scavenger Substances 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 2
- 235000020778 linoleic acid Nutrition 0.000 claims description 2
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 claims description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 claims 1
- 229940095259 butylated hydroxytoluene Drugs 0.000 claims 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims 1
- 239000012530 fluid Substances 0.000 abstract 1
- 239000007844 bleaching agent Substances 0.000 description 6
- 239000007921 spray Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- -1 alkali metal salts Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 2
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- XSXIVVZCUAHUJO-AVQMFFATSA-N (11e,14e)-icosa-11,14-dienoic acid Chemical compound CCCCC\C=C\C\C=C\CCCCCCCCCC(O)=O XSXIVVZCUAHUJO-AVQMFFATSA-N 0.000 description 1
- YUFFSWGQGVEMMI-JLNKQSITSA-N (7Z,10Z,13Z,16Z,19Z)-docosapentaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCCCCC(O)=O YUFFSWGQGVEMMI-JLNKQSITSA-N 0.000 description 1
- DQGMPXYVZZCNDQ-KBPWROHVSA-N (8E,10E,12Z)-octadecatrienoic acid Chemical compound CCCCC\C=C/C=C/C=C/CCCCCCC(O)=O DQGMPXYVZZCNDQ-KBPWROHVSA-N 0.000 description 1
- HOBAELRKJCKHQD-UHFFFAOYSA-N (8Z,11Z,14Z)-8,11,14-eicosatrienoic acid Natural products CCCCCC=CCC=CCC=CCCCCCCC(O)=O HOBAELRKJCKHQD-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- HVGRZDASOHMCSK-UHFFFAOYSA-N (Z,Z)-13,16-docosadienoic acid Natural products CCCCCC=CCC=CCCCCCCCCCCCC(O)=O HVGRZDASOHMCSK-UHFFFAOYSA-N 0.000 description 1
- ASOKPJOREAFHNY-UHFFFAOYSA-N 1-Hydroxybenzotriazole Chemical compound C1=CC=C2N(O)N=NC2=C1 ASOKPJOREAFHNY-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- DJHGAFSJWGLOIV-UHFFFAOYSA-N Arsenic acid Chemical compound O[As](O)(O)=O DJHGAFSJWGLOIV-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 235000021298 Dihomo-γ-linolenic acid Nutrition 0.000 description 1
- 235000021294 Docosapentaenoic acid Nutrition 0.000 description 1
- RPWFJAMTCNSJKK-UHFFFAOYSA-N Dodecyl gallate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC(O)=C(O)C(O)=C1 RPWFJAMTCNSJKK-UHFFFAOYSA-N 0.000 description 1
- 235000021297 Eicosadienoic acid Nutrition 0.000 description 1
- 229940123457 Free radical scavenger Drugs 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229920001448 anionic polyelectrolyte Polymers 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- 235000021342 arachidonic acid Nutrition 0.000 description 1
- 229940114079 arachidonic acid Drugs 0.000 description 1
- 229940000488 arsenic acid Drugs 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- HOBAELRKJCKHQD-QNEBEIHSSA-N dihomo-γ-linolenic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/CCCCCCC(O)=O HOBAELRKJCKHQD-QNEBEIHSSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- CVCXSNONTRFSEH-UHFFFAOYSA-N docosa-2,4-dienoic acid Chemical compound CCCCCCCCCCCCCCCCCC=CC=CC(O)=O CVCXSNONTRFSEH-UHFFFAOYSA-N 0.000 description 1
- 235000010386 dodecyl gallate Nutrition 0.000 description 1
- 239000000555 dodecyl gallate Substances 0.000 description 1
- 229940080643 dodecyl gallate Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical group 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- VZCCETWTMQHEPK-UHFFFAOYSA-N gamma-Linolensaeure Natural products CCCCCC=CCC=CCC=CCCCCC(O)=O VZCCETWTMQHEPK-UHFFFAOYSA-N 0.000 description 1
- VZCCETWTMQHEPK-QNEBEIHSSA-N gamma-linolenic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/CCCCC(O)=O VZCCETWTMQHEPK-QNEBEIHSSA-N 0.000 description 1
- 235000020664 gamma-linolenic acid Nutrition 0.000 description 1
- 229960002733 gamolenic acid Drugs 0.000 description 1
- GBHRVZIGDIUCJB-UHFFFAOYSA-N hydrogenphosphite Chemical class OP([O-])[O-] GBHRVZIGDIUCJB-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 239000000473 propyl gallate Substances 0.000 description 1
- 229940075579 propyl gallate Drugs 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/42—Per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Definitions
- Aqueous textile treatment agent Aqueous textile treatment agent
- the present invention relates to an aqueous bleaching agent based on hydrogen peroxide, which is particularly suitable for direct use as a laundry treatment agent, but also as an additive in conventional washing processes.
- stains In order to remove stubborn stains, so-called stains, from textiles, they are often treated with special pre-treatment agents before the actual washing process.
- peroxide-containing pretreatment agents are generally used. Because of the ease of use conditions then such pretreatment agents are usually liquid and are poured directly or optionally after dilution with water on the stain or applied with the aid of a cloth or sponge on the stain.
- an improved removal of the bleachable stains from the textile is achieved only by intensive and longer exposure time of the peroxide-containing agent, then subjecting the textile then a household washing process, which can be used in addition to mechanical washing process, the so-called hand wash.
- liquid and aqueous bleaching agents are observed after storage of the funds usually a more or less pronounced decrease in their bleaching performance.
- This decrease in power can be attributed to the reduction in the amount of bleach-active agent.
- aqueous hydrogen peroxide formulations decompose by the presence of heavy metal ions, such as iron, copper, nickel, cobalt or manganese ions.
- heavy metal ions such as iron, copper, nickel, cobalt or manganese ions.
- European Patent Application EP 0 913 462 discloses that 1-hydroxybenzotriazole and a multiplicity of its substituted derivatives can increase the storage stability of peroxygen compounds in aqueous formulations.
- the present invention which aims to contribute to this, is a liquid water-containing bleach or laundry treatment agent containing hydrogen peroxide and omega-6 fatty acid and optionally further compatible with these components ingredients.
- the agent preferably contains 0.1 wt .-% to 5 wt .-%, in particular 0.5 wt .-% to 4 wt .-% and particularly preferably 0.9 wt .-% to 2 wt .-% hydrogen peroxide.
- 0.1 wt .-% to 5 wt .-% in particular 0.5 wt .-% to 4 wt .-% and particularly preferably 0.9 wt .-% to 2 wt .-% hydrogen peroxide.
- Omega-6 fatty acids are unsaturated fatty acids that have a carbon-carbon double bond in omega-6 position, that is, at the sixth bond from the end of the fatty acid chain.
- Suitable omega-6 fatty acids include, for example, linoleic acid, gamma-linolenic acid, eicosadienoic acid, dihomo-gamma-linolenic acid, arachidonic acid, docosadienoic acid, arsenic acid, docosapentaenoic acid, calendulic acid, and mixtures thereof.
- the compositions according to the invention preferably contain from 0.1% by weight to 10% by weight, in particular from 0.5% by weight to 6% by weight, of omega-6 fatty acid. Preference is given to agents which contain linoleic acid.
- the agents preferably contain from 80% to 94% by weight of water.
- You can also water-miscible solvent, in particular alcohols having 1 to 4 carbon atoms, in particular methanol, ethanol, isopropanol and tert-butanol, diols having 2 to 4 carbon atoms, in particular ethylene glycol and propylene glycol, and mixtures thereof and those from the above Classes of derivable ether.
- Such water-miscible solvents are preferably present in the compositions according to the invention in amounts of not more than 5% by weight, in particular from 0.1% by weight to 2% by weight.
- Preferred agents contain alcohols having 1 to 4 carbon atoms, in particular ethanol.
- Compositions according to the invention may additionally contain complexing agents for metal ions.
- Suitable complexing agents are, for example, the alkali metal salts of ethylenediaminetetraacetic acid (EDTA) or nitrilotriacetic acid (NTA) and alkali metal salts of anionic polyelectrolytes such as poly maleates and polysulfonates.
- a preferred class of complexing agents are the phosphonates. These preferred compounds include, in particular, organophosphonates, for example 1-hydroxyethane-1, 1- diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriamine penta (methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane-1,2,4-tricarboxylic acid (PBS-AM), which are also available in the form of their Ammonium or alkali metal salts are used.
- organophosphonates for example 1-hydroxyethane-1, 1- diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriamine penta (methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane-1,2,4-tricarboxylic acid (PBS-AM), which are also available in the form of their Ammonium or alkali metal salts are used.
- Such complexing agents are preferably present in the compositions according to the
- compositions according to the invention may additionally contain radical scavengers, for example phenols which are substituted by sterically hindered groups, bisphenols and thiobisphenols, butylhydroxytoluene (BHT), butylhydroxyanisole (BHA), t-butylhydroquinone (TBHQ), tocopherol, propyl gallate and the long-chain (C 8 -C 22 ) esters of gallic acid, such as dodecyl gallate.
- radical scavengers for example phenols which are substituted by sterically hindered groups, bisphenols and thiobisphenols, butylhydroxytoluene (BHT), butylhydroxyanisole (BHA), t-butylhydroquinone (TBHQ), tocopherol, propyl gallate and the long-chain (C 8 -C 22 ) esters of gallic acid, such as dodecyl gallate.
- agents according to the invention contain up to 1%
- the agents according to the invention are preferably weakly alkaline and in particular have a pH in the range from 8 to 10, particularly preferably 8 to 9.
- the agents according to the invention may contain system-compatible acids or bases, in particular ammonium or alkali hydroxides.
- compositions according to the invention may contain further ingredients customary in textile pretreatment agents, as long as they do not interact in an unreasonable manner with the previously mentioned active ingredients.
- fragrances may be mentioned here.
- the agents can be prepared in a less complicated way by simply mixing their ingredients. They are homogeneous systems with a high storage stability and good stain removal performance with low textile damage potential and high skin friendliness. Preferably, they are used for stain-removing treatment of locally-soiled textiles, with a particularly preferred field of application being the removal of blood-stained soils from textiles.
- the Removing stain applies, it preferably acts on the desired if the human body textile located only so long that it does not dry, and it, preferably with the help of a textile cloth, a sponge or a paper towel removed. If necessary, you can repeat this procedure.
- the agent can also be applied in the form of a foam to the part of the textile to be cleaned.
- a manually activated spray dispenser in particular, is suitable. selects from the group comprising aerosol spray dispensers, even pressure building spray dispensers, pump spray dispensers and trigger spray dispensers. It is also possible to add the composition of the invention in the form of an additive to a detergent in the particular machine laundry of textiles.
- liquid bleach-containing laundry treatment agents B1 to B4 were prepared.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008023014A DE102008023014A1 (en) | 2008-05-09 | 2008-05-09 | Aqueous textile treatment agent |
PCT/EP2009/055547 WO2009135904A1 (en) | 2008-05-09 | 2009-05-07 | Aqueous textile treatment means |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2279237A1 true EP2279237A1 (en) | 2011-02-02 |
EP2279237B1 EP2279237B1 (en) | 2014-10-15 |
Family
ID=40848778
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09742122.6A Not-in-force EP2279237B1 (en) | 2008-05-09 | 2009-05-07 | Aqueous textile treatment means |
Country Status (6)
Country | Link |
---|---|
US (1) | US8821590B2 (en) |
EP (1) | EP2279237B1 (en) |
KR (1) | KR20110015540A (en) |
DE (1) | DE102008023014A1 (en) |
ES (1) | ES2528047T3 (en) |
WO (1) | WO2009135904A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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DE102009002016A1 (en) * | 2009-03-31 | 2010-10-07 | Henkel Ag & Co. Kgaa | Fragrance delivery system for use in a dryer |
SG10201707532WA (en) | 2013-03-14 | 2017-10-30 | 3 In 1 Dental Pllc | Compositions For Treatment Of Xerostomia And For Tooth Treatment |
US20170369819A1 (en) * | 2016-06-27 | 2017-12-28 | The Procter & Gamble Company | Removal of hydrophilic body soils |
US10611891B2 (en) | 2018-02-01 | 2020-04-07 | The Hong Kong Research Institute Of Textiles And Apparel Limited | Textile waste processing |
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JPS49111905A (en) * | 1973-02-27 | 1974-10-24 | ||
US5691295A (en) * | 1995-01-17 | 1997-11-25 | Cognis Gesellschaft Fuer Biotechnologie Mbh | Detergent compositions |
BR9607400A (en) | 1995-02-28 | 1998-06-30 | Procter & Gamble | Pre-treatment of laundry with peroxide bleaches that contain chelators for iron copper or manganese for reduced damage to cloths |
DE69732773T2 (en) * | 1997-10-08 | 2006-04-06 | The Procter & Gamble Co., Cincinnati | Multi-purpose liquid cleaning compositions with effective foam control |
EP0913462A1 (en) | 1997-10-31 | 1999-05-06 | The Procter & Gamble Company | Liquid aqueous bleaching compositions packaged in a UV-resistant container |
US6106854A (en) * | 1998-03-25 | 2000-08-22 | Belfer; William A. | Disinfectant composition for infectious water and surface contaminations |
EP0962520A1 (en) * | 1998-05-29 | 1999-12-08 | The Procter & Gamble Company | Liquid bleaching compositions |
US6225271B1 (en) * | 1998-10-06 | 2001-05-01 | Hoffman & Wright Llc | Black powder gun barrel bore, cartridge, and parts cleaning solution |
DE19948989A1 (en) | 1999-10-12 | 2001-05-23 | Bayer Ag | Storage-stable formulations containing mediators, peroxide compounds and pH stabilizers and their use in enzymatic bleaching systems and enzymatic 2-component bleaching systems and their use |
US6776056B2 (en) * | 2001-08-06 | 2004-08-17 | Cts Corporation | Seat belt tension sensor |
JP4417168B2 (en) * | 2004-04-30 | 2010-02-17 | 花王株式会社 | Bleach cleaning composition |
-
2008
- 2008-05-09 DE DE102008023014A patent/DE102008023014A1/en not_active Withdrawn
-
2009
- 2009-05-07 KR KR1020107025069A patent/KR20110015540A/en not_active Application Discontinuation
- 2009-05-07 ES ES09742122.6T patent/ES2528047T3/en active Active
- 2009-05-07 EP EP09742122.6A patent/EP2279237B1/en not_active Not-in-force
- 2009-05-07 WO PCT/EP2009/055547 patent/WO2009135904A1/en active Application Filing
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2010
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Non-Patent Citations (1)
Title |
---|
See references of WO2009135904A1 * |
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WO2009135904A1 (en) | 2009-11-12 |
DE102008023014A1 (en) | 2009-11-12 |
ES2528047T3 (en) | 2015-02-03 |
US20110041257A1 (en) | 2011-02-24 |
KR20110015540A (en) | 2011-02-16 |
EP2279237B1 (en) | 2014-10-15 |
US8821590B2 (en) | 2014-09-02 |
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