EP2268843A1 - Coating process, workpiece or tool and its use - Google Patents
Coating process, workpiece or tool and its useInfo
- Publication number
- EP2268843A1 EP2268843A1 EP09731789A EP09731789A EP2268843A1 EP 2268843 A1 EP2268843 A1 EP 2268843A1 EP 09731789 A EP09731789 A EP 09731789A EP 09731789 A EP09731789 A EP 09731789A EP 2268843 A1 EP2268843 A1 EP 2268843A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- workpiece
- layer
- tool
- tii
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 34
- 239000011248 coating agent Substances 0.000 claims abstract description 18
- 238000004544 sputter deposition Methods 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 8
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 4
- 239000000919 ceramic Substances 0.000 claims abstract description 4
- 229910052751 metal Inorganic materials 0.000 claims abstract description 4
- 239000002184 metal Substances 0.000 claims abstract description 4
- 239000010959 steel Substances 0.000 claims abstract description 4
- 239000000758 substrate Substances 0.000 claims abstract description 4
- 239000011195 cermet Substances 0.000 claims abstract description 3
- 238000005520 cutting process Methods 0.000 claims description 13
- 239000007789 gas Substances 0.000 claims description 7
- 230000000694 effects Effects 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229910052684 Cerium Inorganic materials 0.000 claims 1
- 238000002441 X-ray diffraction Methods 0.000 claims 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- 238000003754 machining Methods 0.000 abstract 1
- 238000003801 milling Methods 0.000 description 8
- 239000010410 layer Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 4
- 238000005240 physical vapour deposition Methods 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000000168 high power impulse magnetron sputter deposition Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000000541 cathodic arc deposition Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000005555 metalworking Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000005546 reactive sputtering Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/0021—Reactive sputtering or evaporation
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/54—Controlling or regulating the coating process
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T407/00—Cutters, for shaping
- Y10T407/19—Rotary cutting tool
- Y10T407/1904—Composite body of diverse material
Definitions
- the invention relates to a method for coating a base body made of hard metal, a cermet, steel or ceramic with at least one Tii -X AI X N layer by means of a DC sputtering process. Furthermore, the invention relates to a workpiece or tool and its use, which is coated by the above method.
- carbide / metal cutting inserts currently produced are coated to make the cutting insert harder and / or more wear resistant.
- a coating for example, hard materials from the system Ti- Al-N-C are chosen.
- PVD processes are also used for the coating.
- a special PVD process is the so-called arc evaporation (arc-PVD).
- arc-PVD arc evaporation
- an anode eg chamber wall
- cathode consisting of the (metallic) coating material
- a trigger Trigger
- the temperature at the cathode is so high that the material locally melts and evaporates.
- the arc moves over the cathode.
- the vaporized particles are almost completely ionized.
- TiAIN layers can be produced which have an advantageous (200) texture.
- sputtering cathode sputtering
- HIPIMS high-power pulse magnetron sputtering
- the case supplied power density is so great that the glow discharge occurring already has characteristics of an arc discharge.
- the HIPIMS uses very high voltages. Since the target is used as a cathode, this process is associated with an increased resuttering effect, resulting in a low deposition rate. Along with this, the growth rate is comparatively low.
- a tool with a protective layer system has a MeX coating, where Me comprises titanium and aluminum and X is at least one of nitrogen or carbon.
- the ratio Q1 of the diffraction intensities of the (200) plane to the (111) plane is greater than 1.
- ⁇ within the layer 1 GPa ⁇ ⁇ ⁇ 6 GPa.
- an arc vapor deposition or the vapor deposition by means of reactive sputtering is selected.
- Another object of the present invention is to use tools that are particularly suitable for metalworking.
- An advantageous embodiment of the method according to the invention provides that the plasma density is increased by means of the hollow cathode effect.
- the hollow cathode effect can be observed under certain conditions with a glow discharge. During the glow discharge, zones form on the surface of the cathodes, which is referred to as a cathode drop or smoldering seam. If the adjacent cathode surfaces are brought together so closely that these zones overlap, the quasi-neutrality of the plasma is abolished and strong ionization of the gases flowing past these surfaces occurs. According to a further embodiment of the invention, all the reaction gases are passed through a hollow cathode.
- the hollow cathode discharge is preferably operated permanently in the DC sputtering method according to the invention.
- magnetic fields are used to increase the plasma density, wherein preferably the magnetic field lines are perpendicular to the substrate surface to be coated. Electrically charged particles moving at a velocity v relative to a magnetic field have the Lorentz force perpendicular to the direction of motion. In a homogeneous magnetic field, the particles move on circular paths, which increases the plasma density.
- An advantageous embodiment of the workpiece, which is produced by the method according to claim 1, is that in the Tii -X Al x N layer for x 0.5 ⁇ x ⁇ 0.7 applies.
- a further advantageous embodiment is that the thickness of the Ti 1-X Al x N layer is at most 15 microns, preferably at most 10 microns.
- Workpieces according to claim 4, which are produced by the method according to claim 1, are particularly suitable for the production of cutting, forming or stamping tools, preferably of indexable inserts, shank tools, in particular of drills or cutters or wear components.
- Fig. 2 increase the plasma density by additional magnetic fields.
- a cathode drop or a glow seam 2 is formed at the cathode 1. If the cathode 1 is moved toward one another sufficiently far in the direction of the arrow 3, a zone 4 results, in which the glowing edges overlap. In this area the quasi-neutrality of the plasma is abolished. If a neutral gas 5 is passed through the zone 4, the gas stream 7 is ionized and the plasma 6 is formed.
- FIG. 1 Another possibility for increasing the plasma density is shown in FIG.
- the substrate 10 to be coated is penetrated by the perpendicular magnetic field with the magnetic field lines 11. Electrically charged particles 13 are forced due to the effective Lorentz force on circular paths 12, which increases the plasma density.
- An embodiment according to the invention having a texture coefficient Qi 2.5 and a compressive residual stress of -1.6 GPa achieved a tool life of 3600 mm.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physical Vapour Deposition (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Drilling Tools (AREA)
Abstract
The invention relates to a process for coating a substrate composed of cemented hard material, a cermet, steel or ceramic with at least one Ti1‑xAIxN layer by means of a DC sputtering process. The invention further relates to a workpiece or tool which has been coated by the abovementioned process and its use. It is an object of the present invention to provide a process by means of which it is possible to produce coatings which combine the advantages of the sputtering process and the arc process, i.e. make it possible to obtain a coating which has a low roughness and an advantageous (200) texture. A further object of the present invention is to provide a workpiece which has a coating having the properties mentioned. A further object of the present invention is to use tools which are particularly suitable for metal machining. The object achieved by the process is characterized in that ionization aids are used for increasing the plasma densities.
Description
Beschichtunqsverfahren. Werkstück oder Werkzeug und dessen Verwendung Beschichtunqsverfahren. Workpiece or tool and its use
Die Erfindung betrifft ein Verfahren zur Beschichtung eines Grundkörpers aus Hartmetall, einem Cermet, aus Stahl oder aus Keramik mit mindestens einer Tii-XAIXN-Schicht mittels eines DC-Sputterverfahrens. Ferner betrifft die Erfindung ein Werkstück oder Werkzeug und dessen Verwendung, welches nach dem oben genannten Verfahren beschichtet ist.The invention relates to a method for coating a base body made of hard metal, a cermet, steel or ceramic with at least one Tii -X AI X N layer by means of a DC sputtering process. Furthermore, the invention relates to a workpiece or tool and its use, which is coated by the above method.
Die meisten derzeit hergestellten Schneidkörper aus Hartmetall zur/Metallzerspanung werden beschichtet, um den Schneideinsatz härter und/oder verschleißfester zu machen. Als Beschichtung werden beispielsweise Hartstoffe aus dem System Ti- Al-N-C gewählt. Zur Beschichtung werden neben CVD-Verfahren auch PVD-Verfahren eingesetzt.Most carbide / metal cutting inserts currently produced are coated to make the cutting insert harder and / or more wear resistant. As a coating, for example, hard materials from the system Ti- Al-N-C are chosen. In addition to CVD processes, PVD processes are also used for the coating.
Ein besonderes PVD-Verfahren ist das sog. Lichtbogenverdampfen (arc-PVD). Zwischen einer Anode (z. B. Kammerwand) und einer Kathode, die aus dem (metallischen) Beschichtungsmaterial besteht, wird unter Zuhilfenahme einer Zϋndhilfe (Trigger) ein Lichtbogen gezündet. Dabei entsteht an der Kathode eine derart hohe Temperatur, dass das Material lokal aufschmilzt und verdampft. Der Lichtbogen bewegt sich dabei über die Kathode. Im Lichtbogen werden die verdampften Teilchen nahezu vollständig ionisiert. Mittels des arc-PVD-Verfahrens sind beispielsweise TiAIN-Schichten erzeugbar, die eine vorteilhafte (200)-Textur aufweisen.A special PVD process is the so-called arc evaporation (arc-PVD). Between an anode (eg chamber wall) and a cathode consisting of the (metallic) coating material, an arc is ignited with the aid of a trigger (trigger). In the process, the temperature at the cathode is so high that the material locally melts and evaporates. The arc moves over the cathode. In the arc, the vaporized particles are almost completely ionized. By means of the arc PVD process, for example, TiAIN layers can be produced which have an advantageous (200) texture.
Ein anderes PVD-Verfahren zur Verdampfung des Beschichtungsmaterials, wie es beispielsweise in der DE 10 2005 021 927 A1 allgemein beschrieben wird, ist das sog. Sputtern (Kathodenzerstäubung). Dabei wird ein aus dem Beschichtungsmaterial bestehendes Target mit energiereichen Ionen beschossen, so dass Atome aus dem Festkörper herausgelöst werden und in die Gasphase übergehen. Mittels des Sputterns sind hervorragende Oberflächenqualitäten erzeugbar, insbesondere Oberflächen mit einer geringen Rauigkeit.
Ein besonderes Sputter-Verfahren ist das High-Power-Impuls-Magnetron-Sputtering (HIPIMS), welches sich durch eine impulsförmige Zufuhr der elektrischen Leistung auf das als Kathode wirkende Target auszeichnet (vgl. dazu DE 10 2006 017 382 A1 , US 6,296,742). Die dabei zugeführte Leistungsdichte ist so groß, dass die auftretende Glimmentladung bereits Charakteristika einer Bogenentladung aufweist. Beim HIPIMS werden sehr hohe Spannungen verwendet. Da das Target als Kathode verwendet wird, ist dieses Verfahren mit einem erhöhten Resputtering-Effekt verbunden, was zu einer geringen Abscheidungsrate führt. Damit einhergehend ist die Wachstumsgeschwindigkeit vergleichsweise niedrig.Another PVD method for evaporating the coating material, as generally described, for example, in DE 10 2005 021 927 A1, is the so-called sputtering (cathode sputtering). In this case, an existing from the coating material target is bombarded with high-energy ions, so that atoms are dissolved out of the solid and go into the gas phase. By means of sputtering, excellent surface qualities can be produced, in particular surfaces with a low roughness. A special sputtering method is the high-power pulse magnetron sputtering (HIPIMS), which is characterized by a pulse-shaped supply of electrical power to the target acting as a cathode (see DE 10 2006 017 382 A1, US 6,296,742). , The case supplied power density is so great that the glow discharge occurring already has characteristics of an arc discharge. The HIPIMS uses very high voltages. Since the target is used as a cathode, this process is associated with an increased resuttering effect, resulting in a low deposition rate. Along with this, the growth rate is comparatively low.
In der EP 10 178870 B1 wird ein Werkzeug mit einem schützenden Schichtsystem offenbart. Das Werkzeug weist ein MeX Beschichtung auf, wobei Me Titan und Aluminium umfasst und X mindestens eines von Stickstoff oder Kohlenstoff ist. Das Verhältnis Q1 der Beugungsintensitäten der (200)-Ebene zur (111 )-Ebene ist größer als 1. Für die Druckspannung σ innerhalb der Schicht gilt 1 GPa ≤ σ ≤ 6 GPa. Als Beschichtungsverfahren wird eine Lichtbogenbedampfung oder die Bedampfung mittels reaktiven Sputterns gewählt.In EP 10 178870 B1 a tool with a protective layer system is disclosed. The tool has a MeX coating, where Me comprises titanium and aluminum and X is at least one of nitrogen or carbon. The ratio Q1 of the diffraction intensities of the (200) plane to the (111) plane is greater than 1. For the compressive stress σ within the layer, 1 GPa ≦ σ ≦ 6 GPa. As a coating method, an arc vapor deposition or the vapor deposition by means of reactive sputtering is selected.
Es ist Aufgabe der vorliegenden Erfindung ein Verfahren anzugeben, mit dem Beschichtungen erzeugbar sind, die die Vorteile des Sputterverfahrens und des arc- Verfahrens gleichsam verbinden, also eine Beschichtung zu ermöglichen, die eine geringe Rauhigkeit und eine vorteilhafte (200)-Textur aufweist.It is an object of the present invention to provide a method by means of which coatings can be produced which as it were combine the advantages of the sputtering method and the arc method, ie to enable a coating which has a low roughness and an advantageous (200) texture.
Es ist ferner Aufgabe der vorliegenden Erfindung ein Werkstück zu schaffen, welches eine Beschichtung mit den genannten Eigenschaften aufweist.It is a further object of the present invention to provide a workpiece which has a coating with the properties mentioned.
Eine weitere Aufgabe der vorliegenden Erfindung besteht darin, zur Metallbearbeitung besonders geeignete Werkzeuge zu verwenden.Another object of the present invention is to use tools that are particularly suitable for metalworking.
Diese Aufgaben werden durch das Verfahren nach Anspruch 1 , durch das hartstoff- beschichtete Werkstück nach Anspruch 6 und durch dessen Verwendung nach Anspruch 9 gelöst.
Bei dem Verfahren nach Anspruch 1 werden zur Erhöhung der Plasmadichten loni- sationshilfen verwendet.These objects are achieved by the method according to claim 1, by the hard-material-coated workpiece according to claim 6 and by its use according to claim 9. In the method according to claim 1, ionization aids are used to increase the plasma densities.
Eine vorteilhafte Ausführungsform des erfindungsgemäßen Verfahrens sieht vor, dass die Plasmadichte mittels des Hohlkathodeneffektes erhöht wird. Der Hohlkatho- deneffekt ist unter bestimmten Voraussetzungen bei einer Glimmentladung zu beobachten. Bei der Glimmentladung bilden sich an der Oberfläche der Kathoden Zonen aus, die als Kathodenfall oder Glimmsaum bezeichnet wird. Werden die benachbarten Kathodenoberflächen so nahe zusammengeführt, dass sich diese Zonen überlappen, so wird die Quasineutralität des Plasmas aufgehoben und es entsteht eine starke Ionisierung der an diesen Flächen vorbeiströmenden Gasen. Nach einer weiteren Ausgestaltung der Erfindung werden alle Reaktionsgase durch eine Hohlkathode geführt. Vorzugsweise wird bei dem erfindungsgemäßen DC-Sputterverfahren die Hohlkathodenentladung permanent betrieben.An advantageous embodiment of the method according to the invention provides that the plasma density is increased by means of the hollow cathode effect. The hollow cathode effect can be observed under certain conditions with a glow discharge. During the glow discharge, zones form on the surface of the cathodes, which is referred to as a cathode drop or smoldering seam. If the adjacent cathode surfaces are brought together so closely that these zones overlap, the quasi-neutrality of the plasma is abolished and strong ionization of the gases flowing past these surfaces occurs. According to a further embodiment of the invention, all the reaction gases are passed through a hollow cathode. The hollow cathode discharge is preferably operated permanently in the DC sputtering method according to the invention.
Eine andere vorteilhafte Ausgestaltung des Verfahrens besteht darin, dass zur Erhöhung der Plasmadichte Magnetfelder verwendet werden, wobei vorzugsweise die Magnetfeldlinien senkrecht auf der zu beschichtenden Substratoberfläche stehen. Auf elektrisch geladene Teilchen, die sich mit einer Geschwindigkeit v relativ zu einem Magnetfeld bewegen, wirkt senkrecht zur Bewegungsrichtung die Lorentzkraft. Bei einem homogenen Magnetfeld bewegen sich die Teilchen auf Kreisbahnen, wodurch sich die Plasmadichte erhöht.Another advantageous embodiment of the method is that magnetic fields are used to increase the plasma density, wherein preferably the magnetic field lines are perpendicular to the substrate surface to be coated. Electrically charged particles moving at a velocity v relative to a magnetic field have the Lorentz force perpendicular to the direction of motion. In a homogeneous magnetic field, the particles move on circular paths, which increases the plasma density.
Eine vorteilhafte Ausgestaltung des Werkstückes, welches nach dem Verfahren nach Anspruch 1 hergestellt ist, besteht darin, dass in der Tii-XAIXN-Schicht für x 0,5 < x < 0,7 gilt.An advantageous embodiment of the workpiece, which is produced by the method according to claim 1, is that in the Tii -X Al x N layer for x 0.5 <x <0.7 applies.
Eine weitere vorteilhafte Ausgestaltung besteht darin, dass die Dicke der Ti1-XAIXN- Schicht maximal 15 μm, vorzugsweise maximal 10 μm beträgt.
Werkstücke nach Anspruch 4, die nach dem Verfahren nach Anspruch 1 hergestellt sind, eignen sich besonders gut für die Herstellung von Zerspanungs-, Umform- oder Stanzwerkzeugen, vorzugsweise von Wendeschneidplatten, Schaftwerkzeugen, insbesondere von Bohrern oder Fräsern oder von Verschleißbauteilen.A further advantageous embodiment is that the thickness of the Ti 1-X Al x N layer is at most 15 microns, preferably at most 10 microns. Workpieces according to claim 4, which are produced by the method according to claim 1, are particularly suitable for the production of cutting, forming or stamping tools, preferably of indexable inserts, shank tools, in particular of drills or cutters or wear components.
Vorteilhafte Ausgestaltungen des erfindungsgemäßen Verfahrens werden im Folgenden anhand der Figuren erläutert. Es zeigen:Advantageous embodiments of the method according to the invention are explained below with reference to the figures. Show it:
Fig. 1a, b Entstehung des Hohlkathodeneffektes,1a, b formation of the hollow cathode effect,
Fig. 1c Gasstrom durch Hohlkathode,1c gas flow through hollow cathode,
Fig. 2 Erhöhung der Plasmadichte durch zusätzliche Magnetfelder.Fig. 2 increase the plasma density by additional magnetic fields.
Bei einer Glimmentladung entsteht an der Kathode 1 ein Kathodenfall bzw. ein Glimmsaum 2. Werden den Kathoden 1 genügend weit in Pfeilrichtung 3 aufeinander zu bewegt, entsteht eine Zone 4, in der sich die Glimmsäume überlappen. In diesem Bereich wird die Quasineutralität des Plasmas aufgehoben. Wird ein Neutralgas 5 durch die Zone 4 geleitet, wird der Gasstrom 7 ionisiert und es entsteht das Plasma 6.In the case of a glow discharge, a cathode drop or a glow seam 2 is formed at the cathode 1. If the cathode 1 is moved toward one another sufficiently far in the direction of the arrow 3, a zone 4 results, in which the glowing edges overlap. In this area the quasi-neutrality of the plasma is abolished. If a neutral gas 5 is passed through the zone 4, the gas stream 7 is ionized and the plasma 6 is formed.
Eine andere Möglichkeit zur Erhöhung der Plasmadichte ist in Fig. 2 dargestellt. Das zu beschichtende Substrat 10 wird durch das senkrecht angeordnete Magnetfeld mit den Magnetfeldlinien 11 durchdrungen. Elektrisch geladene Teilchen 13 werden aufgrund der wirkenden Lorentzkraft auf Kreisbahnen 12 gezwungen, wodurch sich die Plasmadichte erhöht.Another possibility for increasing the plasma density is shown in FIG. The substrate 10 to be coated is penetrated by the perpendicular magnetic field with the magnetic field lines 11. Electrically charged particles 13 are forced due to the effective Lorentz force on circular paths 12, which increases the plasma density.
Mit dem erfindungsgemäßen Verfahren bzw. mit Schneideinsätzen, die nach dem erfindungsgemäßen Verfahren beschichtet wurden, konnten bei Vergleichsversuchen folgende Vorteile festgestellt werden.
Beispiel 1With the method according to the invention or with cutting inserts which were coated by the method according to the invention, the following advantages could be determined in comparative experiments. example 1
Eckfräsen (Einzahntest) von 42Cr Mo 4V Fräswerkzeugtyp: M680 D63 Z1 Wendeschneidplattenform: XPHT160412 Schnittgeschwindigkeit Vc = 220 m/min Vorschub pro Zahn fz = 0,25 mm Schnitttiefe ap = 2,5 mm Eingriffsbreite ae = 38 mmShoulder milling (single tooth test) of 42Cr Mo 4V Milling tool type: M680 D63 Z1 Insert type: XPHT160412 Cutting speed Vc = 220 m / min Feed per tooth fz = 0.25 mm Cutting depth ap = 2.5 mm Engagement width ae = 38 mm
Die Standardbeschichtung mit einem Texturkoeffizienten von Qi = 0,4 erreichte einen Standweg von 4000 mm. Demgegenüber erreichte eine erfindungsgemäße Ausführungsform mit einem Texturkoeffizienten Qi = 1 ,8 und einer Druckeigenspannungen von -1 ,6 GPa einen Standweg von 7000 mm.The standard coating with a texture coefficient of Qi = 0.4 achieved a tool life of 4000 mm. In contrast, an embodiment according to the invention having a texture coefficient Qi = 1.8 and a compressive residual stress of -1.6 GPa achieved a tool life of 7000 mm.
Beispiel 2Example 2
Eckfräsen(Einzahntest) von X 5CrNi 18-10 Fräswerkzeugtyp: M680 D63 Z1 Wendeschneidplattenform: XPHT160412 Anstellwinkel : 90°Shoulder milling (single tooth test) of X 5CrNi 18-10 Milling tool type: M680 D63 Z1 Insert shape: XPHT160412 Angle of attack: 90 °
Schnittgeschwindigkeit Vc = 100 m/min Vorschub pro Zahn fz = 0,11 mm Schnitttiefe ap = 2,5 mm Eingriffsbreite ae = 35 mmCutting speed Vc = 100 m / min feed per tooth fz = 0.11 mm cutting depth ap = 2.5 mm engaging width ae = 35 mm
Die Standardbeschichtung mit einem Texturkoeffizienten von Qi = 0,8 erreichte einen Standweg von 1700 mm. Mit einer erfindungsgemäßen Beschichtung, die einen Texturkoeffizienten Qi = 2,67 sowie eine Druckeigenspannungen von -1 ,8 GPa aufweist, wurde ein Standweg von 2800 mm erreicht.
Beispiel 3The standard coating with a texture coefficient of Qi = 0.8 achieved a tool life of 1700 mm. With a coating according to the invention which has a texture coefficient Qi = 2.67 and a compressive residual stress of -1.8 GPa, a tool life of 2800 mm was achieved. Example 3
Eckfräsen(Einzahntest) von X 5CrNi 18-10 Fräswerkzeugtyp: M680 D80 Z1 Wendeschneidplattenform: XPHT160412 Anstellwinkel : 90°Shoulder milling (single tooth test) of X 5CrNi 18-10 Milling tool type: M680 D80 Z1 Insert shape: XPHT160412 Angle of attack: 90 °
Schnittgeschwindigkeit Vc = 250 m/min Vorschub pro Zahn fz = 0,15 mm Schnitttiefe ap = 2,5 mm Eingriffsbreite ae = 24 mmCutting speed Vc = 250 m / min feed per tooth fz = 0.15 mm cutting depth ap = 2.5 mm engaging width ae = 24 mm
Die Standardbeschichtung mit einem Texturkoeffizienten von Qi = 0,6 erreichte einen Standweg von 2400 mm. Eine erfindungsgemäße Ausführungsform mit einem Texturkoeffizienten Qi = 2,5 und einer Druckeigenspannungen von -1 ,6 GPa erreichte einen Standweg von 3600 mm.The standard coating with a texture coefficient of Qi = 0.6 achieved a tool life of 2400 mm. An embodiment according to the invention having a texture coefficient Qi = 2.5 and a compressive residual stress of -1.6 GPa achieved a tool life of 3600 mm.
Beispiel 4Example 4
Eckfräsen(Einzahntest) von CK 45 Fräswerkzeugtyp: M680 D80 Z1 Wendeschneidplattenform: XPHT160412 Anstellwinkel : 90°Shoulder milling (single tooth test) by CK 45 Milling tool type: M680 D80 Z1 Insert shape: XPHT160412 Angle of attack: 90 °
Schnittgeschwindigkeit Vc = 280 m/min Vorschub pro Zahn fz = 0,25 mm Schnitttiefe ap = 2,5 mm Eingriffsbreite ae = 44 mmCutting speed Vc = 280 m / min feed per tooth fz = 0.25 mm cutting depth ap = 2.5 mm engaging width ae = 44 mm
Die Standardbeschichtung mit einem Texturkoeffizienten von Qi = 0,6 erreichte einenThe standard coating with a texture coefficient of Qi = 0.6 reached one
Standweg von 5400 mm. Eine erfindungsgemäße Ausfϋhrungsform mit einem Texturkoeffizienten Qi = 2,5 und einer Druckeigenspannungen von -1 ,5 GPa erreichte einen Standweg von 7400 mm.
Standstill of 5400 mm. An embodiment according to the invention with a texture coefficient Qi = 2.5 and a compressive residual stress of -1.5 GPa achieved a tool life of 7400 mm.
Claims
1. Verfahren zur Beschichtung eines Grundkörpers aus Hartmetall, einem Cer- met, aus Stahl oder aus Keramik mit mindestens einer Tii-XAIXN-Schicht mittels eines DC-Sputterverfahrens, dadu rch geken nzeich net, dass zur Erhöhung der Plasmadichten lonisationshilfen verwendet werden.1. A method for coating a base body made of cemented carbide, a cerium, steel or ceramic with at least one Tii -X AI X N layer by means of a DC sputtering, dadu rch geken net nets that used to increase the plasma densities lonisationshilfen become.
2. Verfahren nach Anspruch 1 , dadurch gekennzeichnet, dass die Plasmadichte mittels des Hohlkathodeneffektes erhöht wird.2. The method according to claim 1, characterized in that the plasma density is increased by means of the hollow cathode effect.
3. Verfahren nach Anspruch 2, dadurch gekennzeichnet, dass alle Reaktionsgase durch eine Hohlkathode geführt werden.3. The method according to claim 2, characterized in that all the reaction gases are passed through a hollow cathode.
4. Verfahren nach Anspruch 2 oder 3, gekennzeichnet durch ein DC- Sputterverfahren, bei dem die Hohlkathodenentladung permanent betrieben wird.4. The method according to claim 2 or 3, characterized by a DC sputtering method in which the hollow cathode discharge is permanently operated.
5. Verfahren nach Anspruch 1 , dadurch gekennzeichnet, dass zur Erhöhung der Plasmadichte Magnetfelder verwendet werden, wobei vorzugsweise die Magnetfeldlinien senkrecht auf der zu beschichtenden Substratoberfläche stehen.5. The method according to claim 1, characterized in that magnetic fields are used to increase the plasma density, wherein preferably the magnetic field lines are perpendicular to the substrate surface to be coated.
6. Hartstoffbeschichtetes Werkstück oder Werkzeug mit einem Grundkörper aus einem Hartmetall, einem Cermet, aus Stahl oder aus Keramik und mindestens einer Tii-XAIXN-Schicht, die einen QrQuotient > 1 aufweist, wobei Qi das Verhältnis der Beugungsintensitäten von I (200) zu 1(111 ) definiert, welche den (200)-Gitterebenen bzw. den (111 )-Gitterebenen bei der Röntgenbeugung des Materials unter Benutzung der δ-2θ-Methode zuzuordnen sind, dadu rch geken nze ich net, dass diese durch DC-Sputtern hergestellte Schicht eine Druckeigenspannung von -1 GPa bis -2 GPa besitzt. 6. A hard-coated workpiece or tool having a base made of a hard metal, a cermet, steel or ceramic and at least one Tii -X Al x N layer having a Qr quotient> 1, wherein Qi is the ratio of the diffraction intensities of I (200 ) to 1 (111), which are attributable to the (200) lattice planes and the (111) lattice planes, respectively, in the X-ray diffraction of the material using the δ-2θ method, thus indicating that these are represented by DC Sputtered layer has a compressive residual stress of -1 GPa to -2 GPa.
7. Werkstück oder Werkzeug nach Anspruch 6, dadurch gekennzeichnet, dass in der Tii-xAlχN-Schicht 0,5 < x < 0,7 beträgt.7. workpiece or tool according to claim 6, characterized in that in the Tii -x AlχN layer 0.5 <x <0.7.
8. Werkstück oder Werkzeug nach Anspruch 6 oder 7, dadurch gekennzeichnet, dass die Dicke der Tii-XAIXN-Schicht maximal 15 μm, vorzugsweise maximal8. workpiece or tool according to claim 6 or 7, characterized in that the thickness of the Tii -X AI X N layer is at most 15 microns, preferably a maximum
10 μm beträgt.10 microns.
9. Verwendung des Werkstückes oder Werkzeuges nach einem der Ansprüche 6 bis 8 für die Herstellung von Zerspanungs-, Umform- oder Stanzwerkzeugen, vorzugsweise von Wendeschneidplatten, Schaftwerkzeugen, dabei insbesondere von Bohrern oder Fräsern oder von Verschleißbauteilen. 9. Use of the workpiece or tool according to one of claims 6 to 8 for the production of cutting, forming or stamping tools, preferably of indexable inserts, shank tools, in particular of drills or cutters or wear components.
Applications Claiming Priority (2)
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DE102008019202A DE102008019202A1 (en) | 2008-04-17 | 2008-04-17 | Coating method, workpiece or tool and its use |
PCT/EP2009/002537 WO2009127344A1 (en) | 2008-04-17 | 2009-04-07 | Coating process, workpiece or tool and its use |
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EP2268843A1 true EP2268843A1 (en) | 2011-01-05 |
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EP09731789A Withdrawn EP2268843A1 (en) | 2008-04-17 | 2009-04-07 | Coating process, workpiece or tool and its use |
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US (1) | US8702912B2 (en) |
EP (1) | EP2268843A1 (en) |
JP (1) | JP2011517733A (en) |
KR (1) | KR20100135806A (en) |
CN (1) | CN101981222A (en) |
BR (1) | BRPI0910657A2 (en) |
CA (1) | CA2716619A1 (en) |
DE (1) | DE102008019202A1 (en) |
MX (1) | MX2010011294A (en) |
RU (1) | RU2010146622A (en) |
WO (1) | WO2009127344A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN117548703A (en) * | 2024-01-12 | 2024-02-13 | 山东建筑大学 | Micro-texture cutter with bionic round scale structure and processing method |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011122553A1 (en) * | 2010-03-29 | 2011-10-06 | 京セラ株式会社 | Cutting tool |
US8409702B2 (en) | 2011-02-07 | 2013-04-02 | Kennametal Inc. | Cubic aluminum titanium nitride coating and method of making same |
US9399814B2 (en) * | 2011-09-19 | 2016-07-26 | Lamina Technologies S.A. | Coated cutting tool |
JP6093363B2 (en) * | 2011-09-30 | 2017-03-08 | セメコン アーゲー | Coating of substrates using HIPIMS |
DE102012107163A1 (en) * | 2012-08-03 | 2014-05-15 | INI Coatings Ltd. | Coating a substrate using high energy pulse magnetron sputtering, comprises applying bipolar pulses on at least one aluminum containing magnetron target for producing an aluminum oxide coating, and coating without external heat supply |
US9103036B2 (en) | 2013-03-15 | 2015-08-11 | Kennametal Inc. | Hard coatings comprising cubic phase forming compositions |
DE102013104254A1 (en) | 2013-04-26 | 2014-10-30 | Walter Ag | Tool with CVD coating |
DE102013210155A1 (en) | 2013-05-31 | 2014-12-04 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Method for depositing a transparent, electrically conductive metal oxide layer |
US9896767B2 (en) | 2013-08-16 | 2018-02-20 | Kennametal Inc | Low stress hard coatings and applications thereof |
US9168664B2 (en) | 2013-08-16 | 2015-10-27 | Kennametal Inc. | Low stress hard coatings and applications thereof |
DE102014103220A1 (en) | 2014-03-11 | 2015-09-17 | Walter Ag | TiAIN layers with lamellar structure |
DE102014207454B4 (en) | 2014-04-17 | 2018-07-26 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Apparatus for forming a coating on a substrate surface |
US9994958B2 (en) * | 2016-01-20 | 2018-06-12 | Sumitomo Electric Hardmetal Corp. | Coating, cutting tool, and method of manufacturing coating |
KR102064172B1 (en) * | 2017-09-01 | 2020-01-09 | 한국야금 주식회사 | Hard film having excellent wear resistance and toughness |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE65265T1 (en) * | 1987-08-26 | 1991-08-15 | Balzers Hochvakuum | PROCESS FOR DEPOSITIONING COATINGS ON SUBSTRATES AND VACUUM COATING EQUIPMENT FOR CARRYING OUT THE PROCESS. |
DE4007523A1 (en) * | 1990-03-09 | 1991-09-12 | Karl Marx Stadt Tech Hochschul | Hard layer deposition - uses vacuum chamber with independent arc discharge and electron beam vaporisers with plasma support |
US5346600A (en) * | 1992-08-14 | 1994-09-13 | Hughes Aircraft Company | Plasma-enhanced magnetron-sputtered deposition of materials |
DE4228499C1 (en) * | 1992-09-01 | 1993-10-07 | Dresden Vakuumtech Gmbh | Plasma-aided coating of substrates - with a low-voltage arc discharge between a cathode and an anodic electrode |
JP3016703B2 (en) | 1995-01-31 | 2000-03-06 | 日立ツール株式会社 | Coated hard member |
JP3229947B2 (en) * | 1996-04-26 | 2001-11-19 | 日立ツール株式会社 | Surface-coated indexable inserts |
JP3382781B2 (en) * | 1996-06-05 | 2003-03-04 | 日立ツール株式会社 | Multi-layer coated hard tool |
SE9704607D0 (en) | 1997-12-09 | 1997-12-09 | Chemfilt R & D Ab | A method and apparatus for magnetically enhanced sputtering |
WO1999014392A1 (en) | 1997-09-12 | 1999-03-25 | Balzers Aktiengesellschaft | Tool having a protective layer system |
CZ301516B6 (en) * | 1997-09-12 | 2010-03-31 | Oerlikon Trading Ag, Truebbach | Tool with protective layer system and process for producing thereof |
ATE255173T1 (en) * | 1997-09-12 | 2003-12-15 | Unaxis Balzers Ag | TOOL WITH A PROTECTIVE LAYER SYSTEM |
JPH11131215A (en) * | 1997-10-29 | 1999-05-18 | Hitachi Tool Eng Ltd | Coated hard tool |
JP3476749B2 (en) * | 2000-06-14 | 2003-12-10 | 東芝タンガロイ株式会社 | Ultra-high pressure and high pressure sintered body |
KR100667639B1 (en) * | 2003-06-27 | 2007-01-12 | 스미토모 덴키 고교 가부시키가이샤 | Surface-coated high hardness material for tool |
JP4468302B2 (en) | 2003-09-12 | 2010-05-26 | 日鉱金属株式会社 | Sputtering target and surface finishing method of the target |
DE102004015230B4 (en) * | 2004-03-29 | 2007-07-05 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Method and apparatus for intensifying a pulsed magnetron discharge |
CN100482854C (en) | 2005-01-27 | 2009-04-29 | 中华映管股份有限公司 | Magnetically controlled sputtering process |
DE102005021927A1 (en) | 2005-05-12 | 2006-11-16 | Fette Gmbh | Alloy body as a target for the PVD process, process for producing the alloyed body and PVD process with the alloyed body |
DE102006017382A1 (en) | 2005-11-14 | 2007-05-16 | Itg Induktionsanlagen Gmbh | Method and device for coating and / or treating surfaces |
DE102006019000A1 (en) * | 2006-04-25 | 2007-12-13 | Vtd Vakuumtechnik Dresden Gmbh | Device and method for plasma-assisted deposition of hard material layers |
US8277958B2 (en) * | 2009-10-02 | 2012-10-02 | Kennametal Inc. | Aluminum titanium nitride coating and method of making same |
-
2008
- 2008-04-17 DE DE102008019202A patent/DE102008019202A1/en not_active Withdrawn
-
2009
- 2009-04-07 WO PCT/EP2009/002537 patent/WO2009127344A1/en active Application Filing
- 2009-04-07 EP EP09731789A patent/EP2268843A1/en not_active Withdrawn
- 2009-04-07 MX MX2010011294A patent/MX2010011294A/en unknown
- 2009-04-07 CA CA2716619A patent/CA2716619A1/en not_active Abandoned
- 2009-04-07 JP JP2011504350A patent/JP2011517733A/en active Pending
- 2009-04-07 BR BRPI0910657A patent/BRPI0910657A2/en not_active IP Right Cessation
- 2009-04-07 RU RU2010146622/02A patent/RU2010146622A/en not_active Application Discontinuation
- 2009-04-07 US US12/866,276 patent/US8702912B2/en not_active Expired - Fee Related
- 2009-04-07 CN CN2009801113875A patent/CN101981222A/en active Pending
- 2009-04-07 KR KR1020107022904A patent/KR20100135806A/en not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO2009127344A1 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN117548703A (en) * | 2024-01-12 | 2024-02-13 | 山东建筑大学 | Micro-texture cutter with bionic round scale structure and processing method |
CN117548703B (en) * | 2024-01-12 | 2024-03-12 | 山东建筑大学 | Micro-texture cutter with bionic round scale structure and processing method |
Also Published As
Publication number | Publication date |
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RU2010146622A (en) | 2012-05-27 |
DE102008019202A1 (en) | 2009-10-22 |
JP2011517733A (en) | 2011-06-16 |
BRPI0910657A2 (en) | 2015-09-22 |
CA2716619A1 (en) | 2009-10-22 |
MX2010011294A (en) | 2010-11-09 |
KR20100135806A (en) | 2010-12-27 |
US20110020079A1 (en) | 2011-01-27 |
CN101981222A (en) | 2011-02-23 |
US8702912B2 (en) | 2014-04-22 |
WO2009127344A1 (en) | 2009-10-22 |
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