EP2253741A3 - Process for the demulsifying cleaning of metallic surfaces - Google Patents

Process for the demulsifying cleaning of metallic surfaces Download PDF

Info

Publication number
EP2253741A3
EP2253741A3 EP10173888.8A EP10173888A EP2253741A3 EP 2253741 A3 EP2253741 A3 EP 2253741A3 EP 10173888 A EP10173888 A EP 10173888A EP 2253741 A3 EP2253741 A3 EP 2253741A3
Authority
EP
European Patent Office
Prior art keywords
bath
organic compound
demulsifying
metallic surfaces
anionic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP10173888.8A
Other languages
German (de)
French (fr)
Other versions
EP2253741B1 (en
EP2253741A2 (en
Inventor
Stella Bauerochse
Carola Komp
Ralph Van Den Berg
Peter Claude
Franz Dressler
Joachim Geldner
Zafer YÜKSEL
Eckart SCHÖNFELDER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chemetall GmbH
Original Assignee
Chemetall GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=38266742&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP2253741(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Chemetall GmbH filed Critical Chemetall GmbH
Publication of EP2253741A2 publication Critical patent/EP2253741A2/en
Publication of EP2253741A3 publication Critical patent/EP2253741A3/en
Application granted granted Critical
Publication of EP2253741B1 publication Critical patent/EP2253741B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/08Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/835Mixtures of non-ionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/78Pretreatment of the material to be coated
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
    • C23G1/16Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions using inhibitors
    • C23G1/18Organic inhibitors
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
    • C23G1/19Iron or steel
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • C23G5/06Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using emulsions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/16Metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Cosmetics (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

Die Erfindung betrifft ein Verfahren zur demulgierenden Reinigung von metallischen Oberflächen, die gegebenenfalls mit Öl(en), mit mindestens einer weiteren unpolaren organischen Verbindung, mit Fett(en), mit Seife(n), mit Partikelschmutz oder/und mit mindestens einer anionischen organischen Verbindung verschmutzt sind, mit einer wässerigen, alkalischen, Tensidhaltigen Badlösung, wobei das Bad beim Reinigen der metallischen Oberflächen mit Öl(en), mit mindestens einer weiteren unpolaren organischen Verbindung, mit Fett(en), mit Seife(n), mit Partikelschmutz oder/und mit mindestens einer anionischen organischen Verbindung verschmutzt wird, das dadurch gekennzeichnet ist, dass das Bad mindestens ein demulgierendes Tensid enthält oder/und dieses dem Bad zugesetzt wird, dass das Bad außerdem mindestens eine kationische organische Verbindung enthält oder/und diese dem Bad zugesetzt wird und dass das Bad auch bei zunehmender Verschmutzung insbesondere mit mindestens einer anionischen organischen Verbindung in einem demulgierenden Zustand gehalten wird.The invention relates to a process for the demulsifying purification of metallic surfaces, optionally with oil (s), with at least one other nonpolar organic compound, with fat (s), with soap (s), with particle dirt or / and with at least one anionic organic The bath when cleaning the metallic surfaces with oil (s), with at least one other non-polar organic compound, with grease (s), with soap (s), with particle dirt or / and contaminated with at least one anionic organic compound, characterized in that the bath contains at least one demulsifying surfactant and / or that is added to the bath, that the bath also contains at least one cationic organic compound and / or added to the bath and that the bath even with increasing pollution in particular with at least one anionic n organic compound is maintained in a demulsifying state.

EP10173888.8A 2006-04-18 2007-03-26 Process for the demulsifying cleaning of metallic surfaces Active EP2253741B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006018216A DE102006018216B4 (en) 2006-04-18 2006-04-18 Process for the demulsifying cleaning of metallic surfaces
EP07727340.7A EP2010696B1 (en) 2006-04-18 2007-03-26 Process for the demulsifying cleaning of metallic surfaces

Related Parent Applications (3)

Application Number Title Priority Date Filing Date
EP07727340.7A Division-Into EP2010696B1 (en) 2006-04-18 2007-03-26 Process for the demulsifying cleaning of metallic surfaces
EP07727340.7A Division EP2010696B1 (en) 2006-04-18 2007-03-26 Process for the demulsifying cleaning of metallic surfaces
EP07727340.7 Division 2007-03-26

Publications (3)

Publication Number Publication Date
EP2253741A2 EP2253741A2 (en) 2010-11-24
EP2253741A3 true EP2253741A3 (en) 2014-01-08
EP2253741B1 EP2253741B1 (en) 2018-05-16

Family

ID=38266742

Family Applications (2)

Application Number Title Priority Date Filing Date
EP07727340.7A Active EP2010696B1 (en) 2006-04-18 2007-03-26 Process for the demulsifying cleaning of metallic surfaces
EP10173888.8A Active EP2253741B1 (en) 2006-04-18 2007-03-26 Process for the demulsifying cleaning of metallic surfaces

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP07727340.7A Active EP2010696B1 (en) 2006-04-18 2007-03-26 Process for the demulsifying cleaning of metallic surfaces

Country Status (10)

Country Link
US (4) US20100068392A1 (en)
EP (2) EP2010696B1 (en)
CN (2) CN102787320B (en)
BR (1) BRPI0711624B1 (en)
CA (1) CA2650947C (en)
DE (1) DE102006018216B4 (en)
ES (2) ES2586573T3 (en)
MX (1) MX318016B (en)
WO (1) WO2007122056A1 (en)
ZA (1) ZA200809775B (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8557343B2 (en) 2004-03-19 2013-10-15 The Boeing Company Activation method
CN101103085B (en) 2005-01-21 2012-12-26 联邦科学和工业研究组织 Activation method using modifying agent
DE102006018216B4 (en) 2006-04-18 2008-09-25 Chemetall Gmbh Process for the demulsifying cleaning of metallic surfaces
DE102007000501A1 (en) 2007-10-15 2009-04-16 Chemetall Gmbh Cleaning composition for metallic surfaces
WO2011084661A2 (en) 2009-12-17 2011-07-14 3M Innovative Properties Company Sulfonate-functional coatings and methods
BR102012010852A2 (en) * 2012-05-08 2015-04-14 Oxiprana Ind Quimica Ltda LEAD-FREE GALVANIZATION PROCESS FOR METAL MATERIALS
CN103602995B (en) * 2013-10-25 2016-04-06 青岛华仁技术孵化器有限公司 Environmental protection type metal detergency agent
DE102015206812A1 (en) 2015-04-15 2016-10-20 Henkel Ag & Co. Kgaa Polymer-containing pre-rinse before a conversion treatment
ES2763038T3 (en) 2015-04-15 2020-05-26 Henkel Ag & Co Kgaa Thin corrosion protection coatings incorporating polyamidoamine polymers
DE102015209910A1 (en) * 2015-05-29 2016-12-01 Henkel Ag & Co. Kgaa Pre-rinse containing a quaternary amine for conditioning prior to a conversion treatment
DE102015209909A1 (en) * 2015-05-29 2016-12-01 Henkel Ag & Co. Kgaa Conditioning before a conversion treatment of metal surfaces
CN111020604A (en) * 2019-12-30 2020-04-17 奎克化学(中国)有限公司 Water-based cleaning agent for ultrahigh-pressure spraying and preparation method and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0054895A1 (en) * 1980-12-23 1982-06-30 Hoechst Aktiengesellschaft Mixture of surfactants for the cleaning of hard surfaces
DE3247431A1 (en) * 1982-12-22 1984-06-28 Henkel KGaA, 4000 Düsseldorf METHOD FOR REGENERATION OR FOR RECYCLING AQUEOUS DEGREASING AND CLEANING SOLUTIONS
EP0249164A1 (en) * 1986-06-13 1987-12-16 Henkel Kommanditgesellschaft auf Aktien Cationic surfactants based on quaternary ammonium compounds and their use in detergents
DE4014859A1 (en) * 1990-05-09 1991-11-14 Henkel Kgaa USE OF A COMBINATION OF IONIC AND NON-IONIC SURFACES
DE19948413A1 (en) * 1999-10-07 2001-04-12 Unruh Stephan Cleaning solution of pH 8-12 for degreasing work pieces comprises low concentration of anionic, cationic or nonionic surfactant and water

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DE2556527A1 (en) 1975-12-16 1977-06-30 Hoechst Ag Detergent for cleaning metal - contains alkali-stable, low-foam nonionic polyglycol tert.-butyl ether
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DE102006018216B4 (en) 2006-04-18 2008-09-25 Chemetall Gmbh Process for the demulsifying cleaning of metallic surfaces

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0054895A1 (en) * 1980-12-23 1982-06-30 Hoechst Aktiengesellschaft Mixture of surfactants for the cleaning of hard surfaces
DE3247431A1 (en) * 1982-12-22 1984-06-28 Henkel KGaA, 4000 Düsseldorf METHOD FOR REGENERATION OR FOR RECYCLING AQUEOUS DEGREASING AND CLEANING SOLUTIONS
EP0249164A1 (en) * 1986-06-13 1987-12-16 Henkel Kommanditgesellschaft auf Aktien Cationic surfactants based on quaternary ammonium compounds and their use in detergents
DE4014859A1 (en) * 1990-05-09 1991-11-14 Henkel Kgaa USE OF A COMBINATION OF IONIC AND NON-IONIC SURFACES
DE19948413A1 (en) * 1999-10-07 2001-04-12 Unruh Stephan Cleaning solution of pH 8-12 for degreasing work pieces comprises low concentration of anionic, cationic or nonionic surfactant and water

Also Published As

Publication number Publication date
EP2010696B1 (en) 2016-05-11
CN102787320A (en) 2012-11-21
ES2684116T3 (en) 2018-10-01
CA2650947C (en) 2016-05-24
MX318016B (en) 2014-02-12
DE102006018216B4 (en) 2008-09-25
BRPI0711624A2 (en) 2011-12-06
ZA200809775B (en) 2010-02-24
US9731331B2 (en) 2017-08-15
MX2008013310A (en) 2009-01-09
DE102006018216A1 (en) 2007-10-31
US20120273013A1 (en) 2012-11-01
BRPI0711624B1 (en) 2018-04-03
CN101473068B (en) 2012-07-04
EP2010696A1 (en) 2009-01-07
CA2650947A1 (en) 2007-11-01
EP2253741B1 (en) 2018-05-16
WO2007122056A1 (en) 2007-11-01
US20100068392A1 (en) 2010-03-18
EP2253741A2 (en) 2010-11-24
US20140041693A1 (en) 2014-02-13
US20140311533A1 (en) 2014-10-23
CN102787320B (en) 2014-10-29
ES2586573T3 (en) 2016-10-17
CN101473068A (en) 2009-07-01
US8609195B2 (en) 2013-12-17

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