EP2242827B1 - Fabric softening laundry detergent - Google Patents
Fabric softening laundry detergent Download PDFInfo
- Publication number
- EP2242827B1 EP2242827B1 EP09706862.1A EP09706862A EP2242827B1 EP 2242827 B1 EP2242827 B1 EP 2242827B1 EP 09706862 A EP09706862 A EP 09706862A EP 2242827 B1 EP2242827 B1 EP 2242827B1
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- EP
- European Patent Office
- Prior art keywords
- mole
- weight
- composition
- mixtures
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004744 fabric Substances 0.000 title claims description 90
- 239000003599 detergent Substances 0.000 title claims description 57
- 239000000203 mixture Substances 0.000 claims description 172
- 229920000642 polymer Polymers 0.000 claims description 54
- 239000000178 monomer Substances 0.000 claims description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 239000003795 chemical substances by application Substances 0.000 claims description 33
- 230000008901 benefit Effects 0.000 claims description 31
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 31
- 239000000194 fatty acid Substances 0.000 claims description 31
- 229930195729 fatty acid Natural products 0.000 claims description 31
- 150000004665 fatty acids Chemical class 0.000 claims description 31
- -1 hydroxyalkyl acrylate Chemical compound 0.000 claims description 28
- 239000002304 perfume Substances 0.000 claims description 28
- 229920001296 polysiloxane Polymers 0.000 claims description 28
- 125000002091 cationic group Chemical group 0.000 claims description 26
- 125000000129 anionic group Chemical group 0.000 claims description 22
- 125000000217 alkyl group Chemical group 0.000 claims description 20
- 239000004094 surface-active agent Substances 0.000 claims description 20
- 229920000098 polyolefin Polymers 0.000 claims description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 14
- 239000003094 microcapsule Substances 0.000 claims description 14
- 239000010445 mica Substances 0.000 claims description 12
- 229910052618 mica group Inorganic materials 0.000 claims description 12
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 11
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 10
- 239000013078 crystal Substances 0.000 claims description 10
- 239000003607 modifier Substances 0.000 claims description 10
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 9
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- GSPKZYJPUDYKPI-UHFFFAOYSA-N diethoxy sulfate Chemical compound CCOOS(=O)(=O)OOCC GSPKZYJPUDYKPI-UHFFFAOYSA-N 0.000 claims description 7
- 239000003792 electrolyte Substances 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical group [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002738 chelating agent Substances 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 5
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 5
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 4
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 4
- 150000001450 anions Chemical group 0.000 claims description 4
- 229940073609 bismuth oxychloride Drugs 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 4
- 125000005208 trialkylammonium group Chemical group 0.000 claims description 4
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 3
- 229920002873 Polyethylenimine Polymers 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims description 2
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 claims description 2
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 claims description 2
- ZPYXSMUBNKNPSF-UHFFFAOYSA-N 4-(prop-2-enoylamino)butane-1-sulfonic acid Chemical compound OS(=O)(=O)CCCCNC(=O)C=C ZPYXSMUBNKNPSF-UHFFFAOYSA-N 0.000 claims description 2
- 241000251468 Actinopterygii Species 0.000 claims description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 2
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 229920013822 aminosilicone Polymers 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 claims description 2
- 238000007046 ethoxylation reaction Methods 0.000 claims description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims description 2
- VHSPRUFVQLFKKA-UHFFFAOYSA-N [Cl-].CC=CC(=O)NCCC[N+](C)(C)C Chemical compound [Cl-].CC=CC(=O)NCCC[N+](C)(C)C VHSPRUFVQLFKKA-UHFFFAOYSA-N 0.000 claims 1
- 238000012360 testing method Methods 0.000 description 32
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 27
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 26
- 238000005406 washing Methods 0.000 description 21
- 238000000151 deposition Methods 0.000 description 19
- 230000008021 deposition Effects 0.000 description 18
- 238000004140 cleaning Methods 0.000 description 16
- 239000003995 emulsifying agent Substances 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 14
- 238000009472 formulation Methods 0.000 description 14
- 239000004615 ingredient Substances 0.000 description 14
- 239000004530 micro-emulsion Substances 0.000 description 14
- 229920001577 copolymer Polymers 0.000 description 13
- 239000000975 dye Substances 0.000 description 13
- 239000002245 particle Substances 0.000 description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 12
- 102000004190 Enzymes Human genes 0.000 description 11
- 108090000790 Enzymes Proteins 0.000 description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 11
- 229940088598 enzyme Drugs 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 239000003945 anionic surfactant Substances 0.000 description 10
- 239000000839 emulsion Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 229920000742 Cotton Polymers 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 239000004359 castor oil Substances 0.000 description 9
- 235000019438 castor oil Nutrition 0.000 description 9
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 9
- 235000011121 sodium hydroxide Nutrition 0.000 description 9
- 239000002689 soil Substances 0.000 description 9
- 239000011149 active material Substances 0.000 description 8
- 235000010338 boric acid Nutrition 0.000 description 8
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 7
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 7
- 239000004327 boric acid Substances 0.000 description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000002736 nonionic surfactant Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 150000004996 alkyl benzenes Chemical class 0.000 description 6
- 229960004063 propylene glycol Drugs 0.000 description 6
- 235000013772 propylene glycol Nutrition 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 150000008051 alkyl sulfates Chemical class 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical class NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 5
- 238000004900 laundering Methods 0.000 description 5
- 239000002609 medium Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 5
- 239000001993 wax Substances 0.000 description 5
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- QPCDCPDFJACHGM-UHFFFAOYSA-K pentetate(3-) Chemical compound OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O QPCDCPDFJACHGM-UHFFFAOYSA-K 0.000 description 4
- 239000000375 suspending agent Substances 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 229920006029 tetra-polymer Polymers 0.000 description 4
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 108091005804 Peptidases Proteins 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004365 Protease Substances 0.000 description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 3
- 229920006317 cationic polymer Polymers 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 3
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- SECPZKHBENQXJG-FPLPWBNLSA-N (Z)-Palmitoleic acid Natural products CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 2
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Chemical group 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 229920004482 WACKER® Polymers 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 230000001153 anti-wrinkle effect Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001720 carbohydrates Chemical group 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 description 2
- PMPJQLCPEQFEJW-HPKCLRQXSA-L disodium;2-[(e)-2-[4-[4-[(e)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C\C1=CC=C(C=2C=CC(\C=C\C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-HPKCLRQXSA-L 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 2
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- 230000001804 emulsifying effect Effects 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N ethyl stearic acid Natural products CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
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- AOHAPDDBNAPPIN-UHFFFAOYSA-N myristicinic acid Natural products COC1=CC(C(O)=O)=CC2=C1OCO2 AOHAPDDBNAPPIN-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N n-hexadecanoic acid Natural products CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
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- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
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- 238000003856 thermoforming Methods 0.000 description 2
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- 125000006686 (C1-C24) alkyl group Chemical group 0.000 description 1
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
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- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- YJHSJERLYWNLQL-UHFFFAOYSA-N 2-hydroxyethyl(dimethyl)azanium;chloride Chemical compound Cl.CN(C)CCO YJHSJERLYWNLQL-UHFFFAOYSA-N 0.000 description 1
- FPIAKQHHSBQHDE-UHFFFAOYSA-N 2-methylprop-2-enoic acid;prop-2-enamide;prop-2-enoic acid Chemical compound NC(=O)C=C.OC(=O)C=C.CC(=C)C(O)=O FPIAKQHHSBQHDE-UHFFFAOYSA-N 0.000 description 1
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- CVLHGLWXLDOELD-UHFFFAOYSA-N 4-(Propan-2-yl)benzenesulfonic acid Chemical compound CC(C)C1=CC=C(S(O)(=O)=O)C=C1 CVLHGLWXLDOELD-UHFFFAOYSA-N 0.000 description 1
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- 150000002009 diols Chemical class 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
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- 239000003063 flame retardant Substances 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
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- 239000004519 grease Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
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- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
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- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
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- 150000003009 phosphonic acids Chemical class 0.000 description 1
- YXJYBPXSEKMEEJ-UHFFFAOYSA-N phosphoric acid;sulfuric acid Chemical compound OP(O)(O)=O.OS(O)(=O)=O YXJYBPXSEKMEEJ-UHFFFAOYSA-N 0.000 description 1
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- 239000004014 plasticizer Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
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- 229910052700 potassium Inorganic materials 0.000 description 1
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- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
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- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
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- 239000000429 sodium aluminium silicate Substances 0.000 description 1
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- GIPRGFRQMWSHAK-UHFFFAOYSA-M sodium;2-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=CC=C1S([O-])(=O)=O GIPRGFRQMWSHAK-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
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- 125000000547 substituted alkyl group Chemical group 0.000 description 1
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- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
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- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
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- DTOSIQBPPRVQHS-UHFFFAOYSA-N α-Linolenic acid Chemical compound CCC=CCC=CCC=CCCCCCCCC(O)=O DTOSIQBPPRVQHS-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3796—Amphoteric polymers or zwitterionic polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
- The present invention relates to the field of domestic fabric laundering compositions that provide softness to fabrics through the wash and contain polymers.
- Numerous consumer products are available for the laundering of household/domestic fabrics. Similarly, many products exist that may be added during the rinse cycle of standard washing machine cycles or in domestic dryers that will deposit softening and/or other care actives onto the fabrics. This type of two or three step process has become very common for those consumers looking for both excellent cleaning and fabric softening. However, this two or three step process is more time-consuming and costly than a single wash-added product. More recently, due to consumer demands, manufacturers of laundry detergent products have sought to provide one product that provides both cleaning and fabric care benefits such as softness, through the wash.
- It is important to realize, however, that these two goals (cleaning and softness) are traditionally diametrically opposed. Cleaning of fabrics typically results in the removal of dirt, allergens, stains, and other deposited materials. In contrast, providing a care benefit (such as a soft fabric feel) typically results from the deposition of beneficial care actives onto the fabrics. It is therefore difficult to simultaneously clean (remove) and soften (deposit) fabrics through the wash. In the past, it has been recognized in through the wash cleaning and care products that deposited care actives may entrap dirt or other materials onto the fabrics, resulting in a dingy appearance that is obviously undesirable to consumers. The deposited care actives may also themselves leave visible residue if they do not deposited evenly over the fabric surface. Similarly, it has been seen that the care actives are not deposited at all or are removed by the cleaning ingredients.
- More recently, it has been recognized that low levels of cationic polymers, termed "cationic deposition aids" are capable of improving deposition onto fabrics of a range of desirable benefit agents, for fabric softening, perfumes, anti-wrinkle agents, hueing dyes, and the like. Such cationic deposition aids are described the art and fall generally into two classes: (1) "natural" types comprising a carbohydrate moiety, such as cationic hydroxyethylcellulose or cationic guar gum; and (2) "synthetic types" comprising cationic moieties but no carbohydrate. These "synthetic types" are exemplified by copolymers of polyacrylanide (PAM) and methacrylamidopropyltrimethylammonium chloride (MAPTAC). One difficulty with the "natural" types is their incompatibility with laundry detergent enzymes, especially enzymes having some degree of cellulase activity.
- Furthermore, it has now been discovered that synthetic cationic deposition aids comprising cationic and uncharged (nonionic) monomers in the absence of anionic monomers at the pH of laundry washing tend to leave unsightly residues on laundered fabrics. These residues are easily visualized by the human eye when the laundered fabrics have a dark color. However, these findings are surprising in that prior disclosures of similar materials, such as
U.S. Patent 6,949,498 , provide only indiscriminate lists of cationic polymers in liquid laundry detergents. Such disclosures only provide a measure of fabric softness benefits associated with the cationic polymers without any suggestion of visible residues, much less any disclosures of how to remedy such problems. - Accordingly, it would be highly desirable to identify improved laundry detergents comprising selected polymers capable of providing care benefits through the wash to fabrics while maintaining good cleaning and avoiding unsightly residues.
-
US 6,949,498 relates to laundry cleansing and cleaning compositions comprising a mix of catuonic polymer and anionic surfactant. - It has now been surprisingly and unexpectedly discovered that a select group of polymers, containing monomeric units derived from a combination of cationic monomers, nonionic monomers, and anionic monomers in a particular ratio, when incorporated into laundry detergent products, are capable of providing care benefits through the wash to fabrics while maintaining good cleaning and avoiding unsightly residues. Without intending to be limited by theory, it is believed that at a laundry wash pH, such as from 6 to 11, the present polymers are capable of depositing on fabrics in the laundering operation, but do so without leaving visible residue on laundry fabrics.
- All measurements referenced herein are at room temperature ( 21.1°C) and at atmospheric pressure, unless otherwise indicated.
- "Ampholytic" and "amphoteric" may be used interchangeably, and describe a polymer that comprises anionic monomeric units and cationic monomeric units. An ampholytic polymer may be: anionic at a pH that is higher than its isoelectric point; and cationic at a pH that is lower than its isoelectric point; wherein the isoelectric point is the pH at which the net charge on a polymer is zero.
- "Net charge" as used herein refers to the sum of the electric charges of the monomeric units comprising a polymer. The net charge of ampholytic and other ionic polymers may be dependant upon conditions including, but not limited to the pH, temperature and soluble salt concentration of the carrier containing the polymers, such as the continuous phase of an aqueous dispersion.
- "Monomer" as used herein refers to a molecule that may be capable of reacting to form polymers by chemical union with monomers such as itself, or other monomers or monomeric units. "Monomeric unit" as used herein refers to a chemically bound unit in a polymer that is derived from a monomer.
- "Composition" as used herein may encompass the terms: dispersion, solution, melt (such as of a pure liquid substance), or fluid. "Dispersion" as used herein refers to a system of particles that may be evenly distributed in a medium, which is in turn referred to herein as the "continuous phase". The term "aqueous dispersion" as used herein may comprise a dispersion of particles (which may comprise the present polymers) distributed in a continuous phase comprising water.
- "Viscosity" as used herein refers to the resistance of a fluid to flow due to a shearing force. The viscosity of a fluid may be dependent upon the conditions under which it is measured, such as fluid temperature.
- "Comprising" as used herein means that various components, ingredients or steps can be conjointly employed in practicing the present invention. Accordingly, the term "comprising" encompasses the more restrictive terms "consisting essentially of" and "consisting of". The present compositions can comprise, consist essentially of, or consist of any of the required and optional elements disclosed herein.
- Markush language as used herein encompasses combinations of the individual Markush group members, unless otherwise indicated.
- All percentages, ratios and proportions used herein are by weight percent of the composition, unless otherwise specified. All average values are calculated "by weight" of the composition or components thereof, unless otherwise expressly indicated.
- Mole percent (mol %) as used herein may mean either the percent of a monomeric unit in relation to all monomeric units of the polymer; or the mole fraction of reagents or reactants based upon other reagents or reactants.
- All numerical ranges disclosed herein, are meant to encompass each individual number within the range and to encompass any combination of the disclosed upper and lower limits of the ranges.
- The laundry detergent compositions according to the present invention contain water, a deposition polymer, fatty acid, and electrolyte and have a pH of from about 6 to about 11. Each of these components as well as optional ingredients for such compositions and methods of using such compositions are described in detail as follows.
- The laundry detergent compositions of the present invention contain from about 5% to about 95%, alternatively from about 10% to about 95%, by weight of the composition, of water. In one embodiment, they may contain from about 40% to about 90%, by weight of the composition, of water, alternatively from about 50% to about 90%. The compositions have a pH of from about 6 to about 11, alternatively from about 7 to about 9.
- Other types of water-miscible liquids, such alkanols, diols, other polyols, ethers, amines, and the like, may also be added to the detergent compositions of the present invention as cosolvents or stabilizers. However, these should generally be minimized for cost purposes.
- The detergent compositions of the present invention may be in any convenient form. In one embodiment, the compositions are in the form of a liquid, a gel, a unit dose (pouched) product, or are part of a laundry kit.
- The laundry compositions of the present invention from 0.02% to 2%, by weight of the composition, of a deposition polymer having a number average molecular weight of from 700,000 to 4,000,000. In one embodiment, the molecular weight is from about 800,000 to about 3,000,000, alternatively from about 1,000,000 to about 2,500,000. In one embodiment, the laundry compositions of the present invention contain from about 0.05% to about 1%, by weight of the composition, of the deposition polymer, alternatively from about 0.1% to about 0.5%. In one embodiment, the deposition polymer has a charge density of less than 1 meq/gram.
- The deposition polymer includes monomeric units, wherein the monomeric units are derived from monomers. The monomers include nonionic monomers, cationic monomers and anionic monomers wherein the overall mole ratio of the monomers, according to the following equation,
is from 0.25 to 0.8. In one embodiment, the overall mole ratio is from about 0.28 to 0.8, alternatively is from about 0.3 to about 0.8, alternatively is from about 0.35 to about 0.7, alternatively is from 0.35 to 0.6. - The deposition polymer according to the present invention includes at least 50%, by mole, of monomeric units derived from nonionic monomers selected from acrylamide, N,N-dialkyl acrylamide, methacrylamide, N,N-dialkylmethacrylamide, hydroxyalkyl acrylate and vinyl pyrrolidone, vinyl acetate, vinyl alcohol, and mixtures thereof.
- In one embodiment, the deposition polymer contains at least 70% of monomeric units derived from nonionic monomers. In one embodiment, the nonionic monomer is selected from acrylamide, vinyl pyrrolidone, and mixtures thereof, alternatively is acrylamide.
- The deposition polymer according to the present invention includes from 3% to 30%, by mole, of monomeric units derived from cationic monomers selected from N,N-dialkylaminoalkyl methacrylate, N,N-dialkylaminoalkyl acrylate, N,N-dialkylaminoalkyl acrylamide, N,N-dialkylaminoalkylmethacrylamide, methacylamidoalkyl trialkylammonium chloride, acrylamidoalkylltrialkylammonium chloride, vinylamine, quaternized vinyl imidazole and diallyl dialkyl ammonium chloride, and mixtures thereof.
- In one embodiment, the deposition polymer contains from about 3% to about 10%, by mole, of monomeric units derived from cationic monomers. In one embodiment, the cationic monomers are selected from [(3-methylacrylamido) alkyl] trialkylammonium chloride, diallyldimethylammonium chloride, and mixtures thereof, alternatively is 3-methacrylamidopropyltrimethyl ammonium chloride.
- The deposition polymer according to the present invention includes from 1% to 20%, by mole, of monomeric units derived from anionic monomers selected from acrylic acid, acrylic acid, methacrylic acid, maleic acid, vinyl sulfonic acid, styrene sulfonic acid, acrylamidopropylmethane sulfonic acid (AMPS), salts thereof, and mixtures thereof.
- In one embodiment, the deposition polymer includes from about 2.5% to about 6%, by mole, of monomeric units derived from anionic monomers. In one embodiment, the anionic monomer is selected from acrylic acid, methacrylic acid, and mixtures thereof, alternatively is acrylic acid.
- In one embodiment, the polymer is formed from monomeric units derived from (on a mole basis) 90% acrylamide, 5% MAPTAC and 5% acrylic acid. In another embodiment, the polymer is formed from monomeric units derived from (on a mole basis) 92% acrylamide, 1.6% acrylic acid, 1.4% methacrylic acid, and 5% MAPTAC.
- The polymers of the present invention may also contain counterions. "Counterions", as used herein refers to any innocuous ions which do not adversely affect the functioning of the invention and serve only to balance the charge of otherwise non-neutral monomers or other actives. When not otherwise specified, and a monomer or other active material of the present compositions is anionic, suitable counterions include sodium, potassium, alkanolammonium and mixtures thereof. When not otherwise specified and a monomer or other active material of the present compositions is cationic, suitable counter-ions include nitrate, sulphate, chloride, carbonate, bicarbonate and mixtures thereof.
- The detergent compositions herein include from 5% to 60%, alternatively from about 5% to 40%, by weight of the composition, of a surfactant system containing from about 1% to about 25%, by weight of the surfactant system, of fatty acid, alternatively from about 3% to about 15%, alternatively from about 3% to about 10%. The laundry detergent compositions of the present invention may contain from about 75% to about 99%, by weight of the surfactant system, of a detersive surfactant.
- Detersive surfactants utilized can be of the anionic, nonionic, zwitterionic, ampholytic or cationic type or can comprise compatible mixtures of these types. Detergent surfactants useful herein are described in
U.S. Patent 3,664,961, Norris, issued May 23, 1972 ;U.S. Patent 3,919,678, Laughlin et al., issued December 30, 1975 ;U.S. Patent 4,222,905, Cockrell, issued September 16, 1980 ;U.S. Patent No. 4,285,841, Barrat et al., issued August 25, 1981 ;U.S. Pat. No. 4,285,841, Barrat et al, issued Aug. 25, 1981 ;U.S. Pat. No. 4,284,532, Leikhim et al, issued Aug. 18, 19811 ; and inU.S. Patent 4,239,659, Murphy, issued December 16, 1980 . Anionic and nonionic surfactants are preferred - Fatty acids useful herein include those commonly commercially available. Such fatty acids may contain from about 8 to about 20 carbon atoms and can also contain from about 1 to about 10 ethylene oxide units in the hydrocarbon chain.
- Suitable fatty acids are saturated and/or unsaturated and can be obtained from natural sources such a plant or animal esters (e.g., palm kernel oil, palm oil, coconut oil, babassu oil, safflower oil, tall oil, castor oil, tallow and fish oils, grease, and mixtures thereof), or synthetically prepared (e.g., via the oxidation of petroleum or by hydrogenation of carbon monoxide via the Fisher Tropsch process). Examples of suitable saturated fatty acids for use in the compositions of this invention include captic, lauric, myristic, palmitic, stearic, arachidic and behenic acid. Suitable unsaturated fatty acid species include: palmitoleic, oleic, linoleic, linolenic and ricinoleic acid. Examples of preferred fatty acids are saturated C12 fatty acid, saturated C12-C14 fatty acids, and saturated or unsaturated C12 to C18 fatty acids, and mixtures thereof.
- The laundry detergent compositions of the present invention may contain at least 0.1 %, by weight of the compositions, of an electrolyte.
- Electrolytes useful herein include non-surface active electrolytes (as opposed to surfactants separately described herein). Examples of electrolytes useful herein include (i) polycarboxylic acid salts such as salts of citric acid, succinic acid, tartaric acids; salts of phosphonic acids or aminocarboxylic acids (which could also be chelating agents); (iii) salts of boric acids, and (iv) mixtures thereof.
- The laundry detergent compositions of the present invention may contain a fatty acid crystal modifier.
- The fatty acid crystal modifier is selected from sodium alkyl ethoxysulfate; quaternary ammonium surfactant; polyethyleneimine having a molecular weight of from about 300 to about 6000 and an average alkoxylation of from about 3 to about 30 moles of alkylene oxide per nitrogen; ethoxylated tetraethylene-pentaimines having an average ethoxylation of from 15 to 18; zwitterionic surfactants (such as alkyldimethylamine N-oxides, including dodecyldimethylamine N-oxide); chelating agents; zwitterionic amine-based soil release polymers; nonionic alkylpolyethoxylate; and mixtures thereof.
- The fatty acid crystal modifier may be selected from at least 5%, by weight of the composition, of sodium alkyl ethoxysulfate. In one embodiment, the composition contains from about 5% to about 25%, by weight of the composition, of sodium alkyl ethoxysulfate. Sodium alkyl ethoxysulfate is commonly used as a surfactant in laundry detergent compositions.
- The fatty acid crystal modifier may be selected from about 0.1% to about 10%, by weight of the composition of a quaternary ammonium surfactant having the formula
- The fatty acid crystal modifier may be selected from about 0.1% to about 10%, by weight of the composition, of a zwitterionic surfactant. Zwitterionic surfactants useful herein include those commonly known in the art such as alkyl amine oxides.
- The fatty acid crystal modifier may be selected from about 0.05% to about 3%, by weight of the composition, alternatively from about 0.1 % to about 1% of a chelating agent. Chelating agents useful herein include diethylene triamine penta acetate (DTPA).
- The fatty acid crystal modifier may be selected from about 0.1 % or more, by weight of the composition, of a zwitterionic amine-based soil-release polymer.
- The laundry detergent compositions useful herein may include a fabric care benefit agent. As used herein, "fabric care benefit agents" refers to detergent ingredients which are water dispersible or water insoluble and can provide fabric care benefits such as fabric softening, color protection, pill/fuzz reduction, anti-abrasion, anti-wrinkle, perfume longevity and the like, to garments and fabrics, particularly on cotton garments and fabrics.
- These fabric care benefit agents typically have the solubility in distilled water of less than 100g/L, preferably less than 10g/L at 25°C. It is believed that if the solubility of the fabric care benefit agent is more than 10g/L, it will remain soluble in the wash liquor and consequently will not deposit onto the fabrics.
- Examples of water insoluble fabric care benefit agents useful herein include dispersible polyolefins, polymer latexes, organosilicones, perfume or other active microcapsules, and mixtures thereof. The fabric care benefit agents can be in the form of emulsions, latexes, dispersions, suspensions, micelles and the like, and preferably in the form of microemulsions, swollen micelles or latexes. As such, they can have a wide range of particle sizes from about 1 nm to 100 um and preferably from about 5 nm to 10 um. The particle size of the microemulsions can be determined by conventional methods, such as using a Leeds & Northrup Microtrac UPA particle sizer.
- Emulsifiers, dispersing agents and suspension agents may be used. The weight ratio of emulsifiers, dispersing agents or suspension agents to the fabric care benefit agents is about 1:100 to about 1:2. Preferably, the weight ratio ranges from about 1:50 to 1:5. Any surfactants suitable for making polymer emulsions or emulsion polymerizations of polymer latexes can be used to make the water insoluble fabric care benefit agents of the present invention. Suitable surfactants include anionic, cationic, and nonionic surfactants or mixtures thereof. Nonionic and anionic surfactants are preferred.
Typically, the emulsification of the care agent is achieved in situ in the liquid detergent. In such case, the benefit agent is slowly added to the liquid detergent with vigorous mixing. - Suitable organosilicones, include, but not limited to (a) non-functionalized silicones such as polydimethylsiloxane (PDMS); and (b) functionalized silicones such as silicones with one or more functional groups selected from the group consisting of amino, amido, alkoxy, alkyl, phenyl, polyether, acrylate, siliconehydride, mercaptoproyl, carboxylate, sulfate phosphate, quaternized nitrogen, and combinations thereof.
- In typical embodiments, the organosilicones suitable for use herein have a viscosity ranging from about 10 to about 700,000 CSt (centistokes) at 20°C. In other embodiments, the suitable organosilicones have a viscosity from about 10 to about 100,000 CSt.
- (a) Polydimethylsiloxanes (PDMS) have been described in Cosmetics and Toiletries. They can be linear, branched, cyclic, grafted or cross-linked or cyclic structures. In some embodiments, the detergent compositions comprise PDMS having a viscosity of from about 100 to about 700,000 CSt at 20 °C.
- (b) Exemplary functionalized silicones include but are not limited to aminosilicones, amidosilicones, silicone polyethers, alkylsilicones, phenyl silicones and quaternary silicones.
-
- m is from 4 to 50,000, preferably from 10 to 20,000;
- k is from 1 to 25,000, preferably from 3 to 12,000;
- each R is H or C1-C8 alkyl or aryl group, preferably C1-C4 alkyl, and more preferably a methyl group;
- X is a linking group having the formula:
- i) -(CH2)p- wherein p is from 2 to 6, preferably 2 to 3;
- ii)
- iii)
- Q has the formula:
- i) -NH2, - NH - (CH2)r - NH2, wherein r is from 1 to 4, preferably 2 to 3; or
- ii) - (O - CHR2 - CH2)s - Z, wherein s is from 1 to 100, preferably 3 to 30;
wherein R2 is H or C1-C3 alkyl, preferably H or CH3; and Z is selected from the group consisting of - OR3, - OC(O)R3, - CO- R4 - COOH, -SO3, - PO(OH)2, and mixtures thereof; further wherein R3 is H, C1-C26 alkyl or substituted alkyl, C6-C26 aryl or substituted aryl, C7-C26 alkylaryl or substituted alkylaryl groups, preferably R3 is H, methyl, ethyl propyl or benzyl groups; R4 is -CH2- or -CH2CH2- groups; and - iii)
- iv)
- Another class of organosilicone useful herein is modified polyalkylene oxide polysiloxanes of the general formula:
wherein Q is NH2 or -NHCH2CH2NH2; R is H or C1-C6 alkyl; r is from 0 to 1000; m is from 4 to 40,000; n is from 3 to 35,000; and p and q are integers independently selected from 2 to 30. - When r =0, nonlimiting examples of such polysiloxanes with polyalkylene oxide are Silwet® L-7622, Silwet® L-7602, Silwet® L-7604, Silwet® L-7500, Magnasoft® TLC, available from GE Silicones of Wilton, CT; Ultrasil® SW-12 and Ultrasil® DW-18 silicones, available from Noveon Inc., of Cleveland OH; and DC-5097, FF-400® available from Dow Corning® of Midland, MI. Additional examples are KF-352®, KF-6015®, and KF-945®, all available from Shin Etsu Silicones of Tokyo, Japan.
- When r = 1 to 1000, nonlimiting examples of this class of organosilicones are Ultrasil® A21 and Ultrasil® A-23, both available from Noveon, Inc. of Cleveland, OH; BY16-876® from Dow Coming Toray Ltd., Japan; and X22-3939A® from Shin Etsu Corporation, Tokyo Japan.
-
- i.
- ii.
- iii. -SO3
- iv.
- v.
- vi.
- Another class of silicones is cationic silicones. These are typically produced by reacting a diamine with an epoxide. They are described in
WO 02/18528 WO 04/041983 WO 04/056908 US 5,981,681 andUS 5,807,956 (assigned to OSi Specialties). These are commercially available under the trade names Magnasoft® Prime, Magnasoft® HSSD, Silsoft® A-858 (all from GE Silicones) and Wacker SLM21200®. - One embodiment of the composition of the present invention contains organosilicone emulsions, which comprise organosilicones dispersed in a suitable carrier (typically water) in the presence of an emulsifier (typically an anionic surfactant).
- In another embodiment, the organosilicones are in the form of microemulsions. The organosilicone microemulsions may have an average particle size in the range from about 1 nm to about 150 nm, or from about 10 nm to about 100 nm, or from about 20 nm to about 50 nm. Microemulsions are more stable than conventional macroemulsions (average particle size about 1-20 microns) and when incorporated into a product, the resulting product has a preferred clear appearance. More importantly, when the composition is used in a typical aqueous wash environment, the emulsifiers in the composition become diluted such that the microemulsions can no longer be maintained and the organosilicones coalesce to form significantly larger droplets which have an average particle size of greater than about 1 micron. Since the selected organosilicones are water insoluble or have limited solubility in water, they will crash out of the wash liquor, resulting in more efficient deposition onto the fabrics and enhanced fabric care benefits. In a typical immersive wash environment, the composition is mixed with an excess of water to form a wash liquor, which typically has a weight ratio of water : composition ranging from 10:1 to 400:1.
- A typical embodiment of the composition comprising from about 0.01% to about 10%, by weight of composition of the organosilicones and an effective amount of an emulsifier in a carrier. The "effective amount" of emulsifier is the amount sufficient to produce an organosilicone microemulsion in the carrier, preferably water. In some embodiments, the amount of emulsifiers ranges from about 5 to about 75 parts, or from about 25 to about 60 parts per 100 weight parts organosilicone.
- The microemulsion typically comprises from about 10 to about 70%, or from about 25 to about 60%, by weight of the microemulsion of the dispersed organosilicones; from about 0.1 to about 30%, or from about 1 to about 20%, by weight of the microemulsion of anionic surfactant; optionally, from about 0 to about 3 %, or from about 0.1 to about 20%, by weight of the microemulsion of nonionic surfactant; and the balance being water, and optionally other carriers. Selected organosilicone polymers (all those disclosed herein above, excluding PDMS and cationic silicones) are suitable for forming microemulsions; these organosilicones are sometimes referred to as the "self emulsifying silicones". Emulsifiers, particularly anionic surfactants, may be added to aid the formation of organosilicone microemulsions in the composition. Optionally, nonionic surfactants useful as laundry adjuncts to provide detersive benefits can also aid the formation and stability of the microemulsions. In a typical embodiment, the amount of emulsifiers is from about 0.05% to about 15% by weight of the composition.
- Nonlimiting examples of anionic surfactants include the following: alkyl sulfonates, such as C11-C18 alkyl benzene sulfonates (LAS) or C10-C20 branched-chain and random alkyl sulfates (AS); C10-C18 alkyl ethoxy sulfates (AExS) wherein x is from 1-30; mid-chain branched alkyl sulfates (
US 6,020,303 andUS 6,060,443 ) or mid-chain branched alkyl alkoxy sulfates (US 6,008,181 andUS 6,020,303 ); C10-C18 alkyl alkoxy carboxylates comprising 1-5 ethoxy units; modified alkylbenzene sulfonate (MLAS) as discussed inWO 99/05243 WO 99/05242 WO 99/05244 WO 99/05082 WO 99/05084 WO 99/05241 WO 99/07656 WO 00/23549 WO 00/23548 - All dispersible polyolefins that provide fabric care benefits can be used as a fabric care benefit agents in the compositions of the present invention. The polyolefins can be in the form of waxes, emulsions, dispersions or suspensions. Examples of polyolefins useful herein are discussed below.
- The polyolefin may be a polyethylene, polypropylene, or a mixture thereof. The polyolefin may be at least partially modified to contain various functional groups, such as carboxyl, alkylamide, sulfonic acid or amide groups. In one embodiment, the polyolefin is at least partially carboxyl modified or, in other words, oxidized.
- For ease of formulation, the dispersible polyolefin may be introduced as a suspension or an emulsion of polyolefin dispersed in an aqueous medium by use of an emulsifying agent. When an emulsion is employed, the emulsifier may be any suitable emulsification agent including anionic, cationic, or nonionic surfactants, or mixtures thereof. Almost any suitable surfactant may be employed as the emulsifier of the present invention. The dispersible polyolefin is dispersed by use of an emulsifier or suspending agent in a ratio 1:100 to about 1:2. Preferably, the ratio ranges from about 1:50 to 1:5.
- The polyolefin suspension or emulsion may comprise from about 1% to about 60%, alternatively from about 10% to about 55%, and still alternatively from about 20 to about 50% by weight of polyolefin.
- The polyolefin may have a wax dropping point (see ASTM D3954-94, volume 15.04 "Standard Test Method for Dropping Point of Waxes", the method incorporated herein by reference) from about 20 to 170°C and more preferably from about 50 to 140°C. Suitable polyethylene waxes are available commercially from suppliers including but not limited to Honeywell (A-C polyethylene), Clariant (Velustrol emulsion), and BASF (LUWAX).
- Polymer latex is typically made by an emulsion polymerization process which includes one or more monomers, one or more emulsifiers, an initiator, and other components familiar to those of ordinary skill in the art. All polymer latexes that provide fabric care benefits can be used as water insoluble fabric care benefit agents of the present invention. Non-limiting examples of suitable polymer latexes include those disclosed in
WO 02/018451 - Polymer latexes suitable for use herein as fabric care benefit agents include those having a glass transition temperature of from about -120°C to about 120°C and preferably from about - 80°C to about 60°C. Suitable emulsifiers include anionic, cationic, nonionic and amphoteric surfactants. Suitable initiators include all initiators that are suitable for emulsion polymerization of polymer latexes. The particle size of the polymer latexes can be from about 1 nm to about 10 µm and is preferably from about 10 nm to about 1 µm.
- The laundry compositions herein may contain microcapsules or microencapsulates containing one or more fabric care active materials. The terms "microcapsules" and "microencapsulates" are used interchangeably herein.
- Microcapsules useful herein include urea/formaldehyde microcapsules, melamine/formaldehyde microcapsules, more generally aminoplast or polyamide microcapsules, and other types of core-shell microcapsules or microencapsulates having median particle sizes ranging from below 1 micron to 100 micron or higher can be used in the present compositions, suitably at levels of from 0.01% to 5% of the composition by weight. Smaller particle sizes, e.g., 10 microns or below (median) are preferred for incorporation into nonviscous liquid formulations, whereas in more viscous or thickened formulations, larger particle sizes can be employed and may offer desirable visual attributes. Such microcapsules can be colored or uncolored, e.g., by use of dyes and/or pigments, and further, can contain any useful compatible detergent adjunct including perfumes, anti-fungals, odor control agents, antistatic agents, fluorescent whitening agents, antimicrobial actives, emollients, UV protection agents, flame retardants, brighteners, enzymes and the like, enclosed in the core of the microencapsulate. Such materials are most commonly derived from technology and processes long ago established for making carbonless copy paper, and are available from a range of commercial suppliers such as Ciba, Givaudan/Quest BASF, IFF, Cognis, Appleton Papers, Chemitech and others. See for example
WO-200274430 A1 US-20070202063 A1 (Appleton Papers);DE--10000223 A1 (BASF);WO2003002699 A1 (Colgate);WO03054125 US-2004138093 A1 orUS--2004142828 A1 orEP-----1533415 A1 orUS20060287205 A1 orUS20070004610 A1 (IFF);EP-----1640063 A1 (Cognis);WO--2006056357 A1 (Innovacel);WO--2007063001 A1 (Ciba). - A perfume microcapsule contains an encapsulated perfume composition to provide a latent source of perfume. The perfume composition that is encapsulated may be comprised of 100% perfume, which encompasses individual perfume ingredients or perfume accords; optionally, the perfume composition may include non-volatile materials such as diluents. The diluent may be present from 0% to 50% of the perfume formulation. Exemplary diluents include isopropyl myristate, polyethylene glycol, propanediol, and combinations thereof.
- The detergent compositions of the present invention can also include any number of additional optional ingredients. These include conventional laundry detergent composition components such as detersive builders, enzymes, enzyme stabilizers (such as propylene glycol, boric acid and/or borax), suds suppressors, soil suspending agents, soil release agents, other fabric care benefit agents, pH adjusting agents, smectite clays, solvents, hydrotropes and phase stabilizers, structuring agents, dye transfer inhibiting agents, optical brighteners, perfumes and coloring agents. The various optional detergent composition ingredients, if present in the compositions herein, should be utilized at concentrations conventionally employed to bring about their desired contribution to the composition or the laundering operation. Frequently, the total amount of such optional detergent composition ingredients can range from about 5% to about 50%, alternatively from about 30% to about 40%, by weight of the composition. A few of the optional ingredients which can be used are described in greater detail as follows:
- The laundry detergent compositions of the present invention may comprise from about 0.02% to about 0.5%, by weight of the composition, of a pearlescent agent. Examples of pearlescent agents useful herein include mica, metal oxide coated mica, bismuth oxy chloride coated mica, bismuth oxychloride, glass, metal oxide coated glass, ethylene glycol distearate, fish scales, and mixtures thereof. In one embodiment, the pearlescent agent has an average particle size of from 0.1 to 50 microns and has a platelet or spherical geometry.
- The compositions herein are contemplated for using in traditional machine-washing or hand-washing methods. The compositions may also be used on a commercial scale for laundering commercial quantities of fabrics or textiles. Use of the laundry compositions herein to launder or pre-treat fabrics is contemplated herein. Such use to impart an improved fabric feel and/or cleaning benefit to fabrics is further contemplated herein.
- The compositions of the present invention may be encapsulated within a water soluble film. The water-soluble film may be made from polyvinyl alcohol or other suitable variations, carboxy methyl cellulose, cellulose derivatives, starch, modified starch, sugars, PEG, waxes, or combinations thereof.
- In another embodiment the water-soluble may include other adjuncts such as co-polymer of vinyl alcohol and a carboxylic acid.
US patent 7,022,656 B2 (Monosol) describes such film compositions and their advantages. One benefit of these copolymers is the improvement of the shelf-life of the pouched detergents thanks to the better compatibility with the detergents. Another advantage of such films is their better cold water (less than 10°C) solubility. Where present the level of the co-polymer in the film material, is at least 60% by weight of the film. The polymer can have any weight average molecular weight, preferably from 1000 daltons to 1,000,000 daltons, more preferably from 10,000 daltons to 300,000 daltons, even more preferably from 15,000 daltons to 200,000 daltons, most preferably from 20,000 daltons to 150,000 daltons. Preferably, the co-polymer present in the film is from 60% to 98% hydrolysed, more preferably 80% to 95% hydrolysed, to improve the dissolution of the material. In a highly preferred execution, the co-polymer comprises from 0.1 mol% to 30 mol%, preferably from 1 mol% to 6 mol%, of said carboxylic acid. - The water-soluble film of the present invention may further comprise additional co-monomers. Suitable additional co-monomers include sulphonates and ethoxylates. An example of preferred sulphonic acid is 2-acrylamido-2-methyl-1-propane sulphonic acid (AMPS). A suitable water-soluble film for use in the context of the present invention is commercially available under tradename M8630™ from Mono-Sol of Indiana, US. The water-soluble film herein may also comprise ingredients other than the polymer or polymer material. For example, it may be beneficial to add plasticisers, for example glycerol, ethylene glycol, diethyleneglycol, propanediol, 2-methyl-1,3-propane diol, sorbitol and mixtures thereof, additional water, disintegrating aids, fillers, anti-foaming agents, emulsifying/dispersing agents, and/or antiblocking agents. It may be useful that the pouch or water-soluble film itself comprises a detergent additive to be delivered to the wash water, for example organic polymeric soil release agents, dispersants, dye transfer inhibitors. Optionally the surface of the film of the pouch may be dusted with fine powder to reduce the coefficient of friction. Sodium aluminosilicate, silica, talc and amylose are examples of suitable fine powders.
- The encapsulated pouches of the present invention can be made using any conventionally known techniques. In one embodiment, the pouches are made using horizontal form filling thermoforming techniques.
- The presence of residues is assessed in a full scale washing machine test using Miele Novotronic W527.
-
- 1. The fabric used to assess residues on fabrics is a black velvet (Material source: Denholme Velvets, Halifax Road, Denholme, Bradford, West Yorkshire, England BD13 4EZ - tel. (01274) 832 646, with the specifications 150 cm C.R. Cotton Pile Velvet, quality 8897, black, 72% Cotton, 28% Modal).
- 2. A pouch is made by sewing a rectangle of black velvet (dimensions 23.5 cm x 47 cm that is folded to make a square with the velvet on the inside) using an overlock stitch, sewing along two sides leaving one open edge. The pouch is turned inside out so that the velvet is on the outside.
- 3. A dosing ball is filled using the recommended dosage for each product according to packaging instructions for normal/median soil and normal/median water hardness (125g). For every experiment, a new and unused dosing ball is filled. The dosing ball is placed inside the black velvet pouch.
- 4. The pouch is then closed by making a 2 cm wide fold across the open side and is secured with 3 plastic stitches.
- 5. For the wash test, the black pouch is placed in the back of the washing machine (Miele Novotronic W527) with the opening of the dosing ball up, without any further ballast load. The washing machine is switched on using the wool wash program at 40°C, using city water (2.5mmol/L). At end of the wash cycle, the pouches are immediately removed from the washing machine. The pouches are opened along the three sides (all stitched and sewed sides), except the folded side. For every test product, a run with a reference product is performed at the same time (for comparison). Every experiment is repeated 2 times to have 3 replicates per test product.
- 6. The pouches are graded after drying over night (horizontally on a flat surface), by 2 qualified graders, using the following grading instructions and scale (relative scale to reference product results):
- To indicate less residues (instead of more residues), the signs of the scale above are inverted to positive numbers.
- Each item is assessed by the two graders, and the grades are averaged; if the grades given by the two judges differ by more than 1 PSU (except -1 and +1), the grading is repeated. Three replicates are assessed and their results averaged to obtain the final grade.
- The residues test described above was carried out using the standard composition described below in Table 2 as a reference composition against the same composition containing one of the different copolymers listed in Table 3.
Table 2 - Standard Composition Ingredients (% by weight) Copolymer (see Table 3) 0.19 Alkylbenzene sulfonic acid 1.2 C14-15 alcohol 8-ethoxylate 4.0 C12-14 alcohol 3-ethoxylate sulphate, Na salt 6.8 Citric acid 2.4 C12-18 fatty acid 4.5 Detergent enzymes 0.2 Trans-sulphated ethoxylated hexamethylene diamine quat 0.7 Pentamethylene triamine pentaphosphonic acid 0.1 Hydrogenated castor oil 0.3 Ethanol 1.0 Boric acid 1.2 Sodium hydroxide 3.0 Perfume 0.6 Water 72 Dyes, miscellaneous minors balance Table 3 - Copolymers and Test Results Material Mole % Overall Mole Ratio Residue Results Acr. Amide Acr. Acid MetAcr. Acid Maptac An /(An+Cat) PSU R Table 2 formulation None None None None NA 0.0 1 PamMAPTAC 88 0 0 12 0.00 -4.0 2 Merquat 5300 90 5 0 5 0.50 0.0 3 45D (77/3/20) 88.7 3.4 0 7.9 0.30 -1.3 4 45C (79/1/20) 91 1.1 0 7.5 0.13 -2.3 5 50D (35/60/5) 36 62 0 1.7 0.97 0.5 6 Tetrapolymer 1 93.5 1.5 0 5 0.23 -2.1 7 Tetrapolymer 2 92 1.6 1.4 5 0.38 0.0 - Based on consumer input, a residue grade difference of 2 PSU from the reference composition (i.e., a PSU of -2 or less) in this test will deliver consumer noticeable, unsatisfactory, residues levels. Therefore, the polymers which provide acceptable residues levels when included in the standard composition are the Table 2 polymers 2, 3, 5, and 7.
- The relative softness of fabrics washed in laundry products containing polymers is assessed in a full scale washing machine test using Miele Novotronic W527.
- Fabric softness is a relative characteristic that in this protocol is evaluated by trained human softness graders that tactically examine a range of white fabric swatches washed in commercially available washing machines with standard dosages of laundry detergent. Identical sets of fabric swatches are separately washed in a reference detergent product and in a test product. The softness results are a comparison of the resulting fabric swatches from each test product wash with the fabrics from the reference detergent product wash using the PSU score described below. All data are generated by usingcommercially available washing machines manufactured by Miele and sold as the Novatronic W527 model and commercially available laundry dryers manufactured by Miele and sold as the Novotronic T490 model.
- Multiple types of fabrics cut into swatches and used to assess the softness. The fabrics used are:
- 1) White terries with a swatch size of 30cm x 30cm and a weight of 450g/m2, supplied by Maes Textiles - Brabantstraat117, 8790 Waregem, Belgium
- 2) White knitted 100% cotton with a swatch size of 50cm x 40cm and a weight of 165-175g/m2, having a rib of 1/1, supplied by Abanderado Industriepark West 61, 9100 Sint Niklaas, Belgium ,and
- 3) White polycotton (50% polyester blended with 50% cotton) with a swatch size of 100cm x 120cm and a weight of 130g/m2, supplied by Dewerchin Vruchtendreef 19, 8520 Kuurne), Belgium
- All fabric swatches used in the testing protocol, including reference fabric swatches are washed (before beginning testing) three times each with commercially available Ariel Liquid (at the recommended dosage for medium soil, medium water hardness of 75ml, dosed via a dosing ball) at 60°C using the short ("wit/bont") standard program with city water (2.5mmol/l) in order to remove any sizing applied by the manufacturers.
- In addition to the fabric swatches, in each washing cycle an extra ballast load is added to get to a total weight of approximately 3kg of fabrics in the washing cycle (see Table 4, below). The ballast load consists of two large terry towels (80cm x 50cm, supplied by Maes Textiles) and six pieces of knitted cotton (50cm x 50cm, supplied by Abanderado). After completion of the three washing cycles, all fabrics are then tumble dried in a commercially available dryer. Upon drying, the fabrics are then ready to use in softness testing.
- For the reference product and for each of the test compositions, a test load of fabrics as shown in Table 4 is utilized.
Table 4 - Test Load Fabric type Number of swatches used per load Total weight of swatches/ballast Drying process used Swatches: Terry swatches 16 Approx. 660g 8 line dry 8 tumble dry Knitted cotton 8 Approx. 280g 8 line dry Polycotton 8 Approx. 1260g 8 tumble dry Ballast load (not examined): Terry towels 2 Approx. 340g irrelevant Knitted cotton 6 Approx. 450g irrelevant Total load weight: Approx. 3 kg - A test load of fabrics is then washed three times each in succession (cycles 1, 2, and 3) with 75ml (recommended dosage for medium water hardness, medium soil) of the laundry product to be analyzed, dispensing with a dosing ball. Reference laundry product is washed under the same conditions as test products.
- The washing machines are fed with city water (2.5mmol/L) at 40°C and are set to the short ("widbont") standard program with spinning at 1200rpm. The washing machines are not rotated to avoid contamination between the products. All three cycles for each laundry product test load must be completed on the same day with tumble drying of all fabrics in between cycles 1 and 2, and in between cycles 2 and 3, using the setting "Kastdroog" on the dryer.
- After cycle 3, the fabrics that need to be line dried (as shown in Table 4) are taken out and line dried overnight in a controlled temperature and humidity room set at 21°C, 50% relative humidity. The other fabrics are dried in a tumble dryer, using the "Extra dry" setting.
- The day after drying, the fabric swatches are graded for softness by two different trained softness graders, utilizing a PSU scale. The PSU scale as referenced herein is a paired comparison between a fabric swatch treated with test product and the same type of fabric swatch treated with the reference product, using a grading scale going from -4 to 4. This paired comparison PSU grading scale is shown below in Table 5.
Table 5 - PSU Grading Scale SCORE MEANING 0 There is no difference 1 I think this one is softer (unsure) 2 I know this one is softer (sure) 3 This one is a lot more softer 4 This one is a whole lot softer - A positive grading scale number indicates that the fabric swatch treated with the test product is softer than the one of the reference product, a negative grading scale number indicates that the reference swatch is softer. If for a particular set of swatches, the grades given by the two softness graders differ by more than 1 PSU (except -1 and +1), regrading occurs.
- For each test product, each of the swatches from the load (except the ballast load) is compared with one swatch of the same fabric type washed with the reference product. As such, 32 PSU gradings are completed per grader for each test product (8 gradings for terry swatches line dry, 8 gradings for terry swatches tumble dry, 8 gradings for knitted cotton line dry and 8 numbers for polycotton tumble dry).
- At the end, an average softness score is calculated by averaging all 32 gradings from both graders.
- The softness test described above was carried out using a standard commercially available fabric softening laundry detergent composition shown in Table 6 as a reference product, and comparing it to test compositions according to the formulation set forth in Table 2 containing in turn one of each of the different copolymers listed in Table 3.
Table 6 - Reference Formulation for Softness Data Active Material Weight % Composition pH : 7.5 - 8.5 C12 - C14 alkyl polyethoxylate (7) 1.2 Alkylbenzene sulfonic acid 9.0 Citric Acid 1.5 C12-18 fatty acid 4.38 Rapeseed fatty acid 2.46 Enzymes 0.4 Boric Acid 0.79 Diethylene triamine penta methylene phosphonic acid 0.4 Brightener 0.09 Hydrogenated Castor Oil structurant 0.2 Ethanol 2.38 1, 2 propanediol 3.68 Sodium hydroxide 3.34 Sodium cumene sulphonate 0.8 Polyethyleneimine 0.06 Silicone suds suppressor 0.15 Dye 0.003 Perfume 0.62 Bentonite softnening clay 3.36 Water Up to 100 - The copolymers used in the test composition and the softness results obtained are summarized in Table 7.
Table 7 Material Mole % Relative Softness Overall Mole Ratio Acrylamide Acrylic Acid Methacrylic Acid Maptac PSU Table 1 R formulation None None None None 0 NA 1 PamMAPTAC 88 0 0 12 + 1.0 0.00 2 Merquat 5300 90 5 0 5 + 0.5 0.50 3 45D (77/3/20) 8.7 3.4 0 7.9 + 1.2 0.30 4 45C (79/1/20) 91 1.1 0 7.5 + 0.9 0.13 5 50D (35/60/5) 36 62 0 1.7 - 1.5 0.97 6 Tetrapolymer 1 93.5 1.5 0 5 0.8 0.23 7 Tetrapolymer 2 92 1.6 1.4 5 0.9 0.38 - As may be seen by comparing the data outlined in Tables 3 and 7, incorporation of polymers 2, 3 or 7 into the test composition of Table 2 provides both good softness benefits and an acceptable amount of residues on fabrics. The other polymers, when incorporated into the test composition of Table 2 are included as comparative examples.
- Additional detergent composition examples according to the present invention are shown as compositions 3A and 3B, below. It is predicted that these formulations will provide good cleaning, softness and acceptably low visible residues on fabrics when used in traditional consumer washing machines.
Ingredients (% by weight) 3A 3B Alkylbenzene sulfonic acid - 3.0 C14-15 alcohol 8-ethoxylate - 2.5 C12-14 alcohol 3-ethoxylate sulphate, Na salt 22 12 N-C10-12 alkyl, N-2-hydroxyethyl, N,N-dimethyl ammonium chloride 3.0 1.5 Citric acid 3.5 1.0 C12-18 fatty acid 2.0 7.0 Copolymers 2, 3 and/or 7 from Table 7 above 0.25 0.28 Silicone polyether 2.0 2.0 Detergent enzymes 0.4 1.1 Ethoxylated polyimine 1.3 2.0 Pentamethylene triamine pentaphosphonic acid - 0.3 Hydrogenated castor oil - 0.2 1,2 propandiol 5.5 0.2 Cumene sulfonic acid, Na salt 1.5 - Ethanol 3.0 2.2 Monoethanolamine (MEA) 2.7 10 Boric acid 0.9 1.5 Sodium hydroxide 3.0 3.0 Perfume 0.6 0.7 Water 47 59 Dyes, miscellaneous minors balance balance - Additional laundry detergent composition examples according to the present invention are shown as compositions 4A to 4E, below. It is predicted that these formulations will provide good cleaning, softness and acceptably low visible residues on fabrics when used in traditional consumer washing machines.
Active Material in weight % 4A 4B 4C 4D 4E Composition pH : 7.5 - 8.5 C14 - C15 alkyl poly ethoxylate (8) 4.4 6.25 4.0 4.0 6.25 C12 - C14 alkyl poly ethoxylate (3) sulfate Na salt 7.46 10.6 6.78 6.78 10.6 Alkylbenzene sulfonic acid 1.19 0.79 1.19 1.19 0.79 Citric Acid 2.64 3.75 2.4 2.4 3.75 C12-18 fatty acid 4.93 7.02 4.48 4.48 7.02 Enzymes 0.2 0.32 0.4 0.4 0.61 Boric Acid 1.35 1.93 1.23 1.23 1.93 Trans-sulphated ethoxylated hexamethylene diamine quat 0.78 1.11 0.71 0.71 1.11 Diethylene triamine penta methylene phosphonic acid 0.12 0.17 0.11 0.11 0.17 N-C10 alkyl, N-2-hydroxyethyl,N,N-dimethyl ammonium chloride - - 1.0 - - Hydrogenated Castor Oil structurant 0.300 0.2 0.3 0.3 0.2 Ethanol 1.55 2.2 1.41 1.41 2.2 1, 2 propanediol 0.07 0.16 0.15 0.15 0.16 Sodium hydroxide 3.41 4.8 3.1 3.1 4.8 Silicone PDMS emulsion 0.0030 0.003 0.003 0.003 0.003 Dye 0.00084 0.00084 0.00084 0.00084 0.00084 Mica/TiO2 (ex BASF) 0.05 - 0.05 - Perfume 0.65 0.65 0.65 0.65 1.0 Merquat 5300* 0.19 0.3 0.19 0.19 0.3 Perfume microcapsules** - - 0.325 0.325 0.52 Water Up to 100 Up to 100 Up to 100 Up to 100 Up to 100 ** Level expressed as perfume oil delivered via capsules
* Merquat 5300 is terpolymer with mole ratio : 90% PAM/5% AA/5%MAPTAC produced by Nalco. - Additional laundry detergent composition examples according to the present invention are shown as compositions 5A to 5E, below. It is predicted that these formulations will provide good cleaning, softness and acceptably low visible residues on fabrics when used in traditional consumer washing machines.
Active Material in weight % 5A 5B 5C 5D 5E Composition pH : 7.5 - 8.5 C14 - C15 alkyl poly ethoxylate (8) - 15.57 - 15.57 15.57 C12 - C14 alkyl poly ethoxylate (7) 15.57 - 15.57 - - Alkylbenzene sulfonic acid 19.43 19.43 19.43 19.43 19.43 Citric Acid 0.5 0.5 0.5 0.5 0.5 C12-18 fatty acid 15.54 15.54 15.54 15.54 15.54 Enzymes 2.1 2.1 2.1 2.1 2.1 Boric Acid - 1.0 1.0 1.0 1.0 Trans-sulphated ethoxylated hexamethylene diamine quat 2.75 2.75 2.75 2.75 2.75 PEI 600 EO20 1.0 1.0 1.0 1.0 1.0 HEDP 1.0 1.0 1.0 1.0 1.0 FWA - Brightener 0.28 - - - - Hydrogenated Castor Oil Structurant 0.2 0.2 0.2 0.2 0.2 Glycerol - - - - 8 1, 2 propanediol 8.0 8.0 8.0 8.0 9.0 Sodium hydroxide 0.1 0.1 0.1 0.1 0.1 Silicone PDMS emulsion - - - 0.003 0.003 Mono Ethanol Amine (MEA) 8.84 8.84 8.84 8.84 8.84 Mica/TiO2 pearl (ex BASF) - 0.1 0.05 - - Perfume 1.40 1.40 1.40 1.40 1.40 Merquat 5300 0.60 0.5 0.35 0.80 0.80 Perfume micro capsules - - 0.86 0.86 0.86 Water (with dyes and other minors) Up to 100 Up to 100 Up to 100 Up to 100 Up to 100 - Additional laundry detergent composition examples according to the present invention are shown as compositions 6A to 6D, below. It is predicted that these formulations will provide good cleaning, softness and acceptably low visible residues on fabrics when used in traditional consumer washing machines.
Active Material Weight % 6A 6B 6C 6D C14 - C 15 alkyl poly ethoxylate (8) 3.7 3.7 3.7 3.7 C12 - C14 alkyl poly ethoxylate (3) sulfate Na salt 15.0 15.0 15.0 15.0 Alkylbenzene sulfonic acid 16.3 16.3 16.3 16.3 Citric Acid 4.1 4.1 4.1 4.1 C12-18 fatty acid 7.2 7.2 7.2 7.2 Enzymes as raw material solution 2.4 2.4 2.4 2.4 Boric Acid 0.5 0.5 0.5 0.5 PEI 600 EO20 3 3 3 3 HEDP 1.6 1.6 1.6 1.6 FWA - Brightener 0.28 - - - CaCl2 0.03 0.03 0.03 0.03 1,2 propanediol 4.0 4.0 4.0 4.0 Sodium hydroxide to pH 8.0 to pH 8.0 to pH 8.0 to pH 8.0 Mono Ethanol Amine (MEA) 10.31 10.31 10.31 10.31 Dye 0.001 0.001 0.001 0.001 Mica/TiO2 pearl (ex BASF) - 0.05 - 0.05 Perfume 1.5 1.5 1.5 1.5 Merquat 5300 0.6 0.5 0.35 0.8 Perfume microcapsules - - 0.86 0.86 Water Up to 100 Up to 100 Up to 100 Up to 100 - Additional laundry detergent composition examples according to the present invention are shown as compositions 7A to 7F, below. It is predicted that these formulations will provide good cleaning, softness and acceptably low visible residues on fabrics when used in traditional consumer washing machines.
7A 7B I 7C I 7D 7E 7F Ingredient (assuming 100% activity) Weight % AExS 21.0 12.6 21.0 12.6 21.0 5.7 LAS -- 1.7 -- 1.7 -- 4.8 Branched Alkyl sulfate -- 4.1 -- 4.1 -- 1.3 NI 23-9 0.4 0.5 0.4 0.5 0.4 0.2 C12 trimethylammonium chloride 3.0 -- 3.0 -- 3.0 -- Citric Acid 2.5 2.4 2.5 2.4 2.5 -- C12-18 Fatty Acids 3.4 1.3 3.4 1.3 3.4 0.3 Protease B 0.4 0.4 0.4 0.4 0.4 0.1 Carezyme 0.1 0.1 0.1 0.1 0.1 -- Tinopal AMS-X 0.1 0.1 0.1 -- 0.1 0.3 TinopalCBS-X -- -- -- 0.1 -- ethoxylated (EO15) tetraethylene pentaimine 0.3 0.4 0.3 0.4 0.3 0.4 PEI 600 EO20 0.6 0.8 0.6 0.8 0.6 0.3 Zwitterionic ethoxylated quaternized sulfated hexamethylene diamine 0.8 -- 0.8 -- 0.8 -- PP-54951 3.4 3.0 3.4 3.0 3.4 2.7 KF-8892 -- -- -- -- 3.4 -- Merquat 5300 0.2 0.2 0.2 0.2 -- 0.3 Diethylene triamine penta acetate, MW = 393 0.2 0.3 0.2 0.2 0.2 -- Mica/TiO2 pearl (ex BASF) 0.2 0.1 -- -- -- 0.1 Ethyleneglycol distearate (EGDS) pearl -- -- 1.0 1.0 -- Hydrogenated castor oil 0.1 0.1 - - - 0.1 Sodium hydroxide To pH 8.0 To pH 8.0 To pH 8.0 To pH 8.0 To pH 8.0 To pH 8.0 water, perfumes, dyes, and other optional agents/components to 100% balance to 100% balance to 100% balance To 100% balance to 100% balance to 100% balance 1: supplied by Dow Coming Corporation, Midland, MI
2 : supplied by Shin-Etsu Silicones, Akron, OH - Additional laundry detergent composition examples according to the present invention are shown as compositions 8A to 8C, below. It is predicted that these formulations will provide good cleaning, softness and acceptably low visible residues on fabrics when used in traditional consumer washing machines.
8A 8B 8C Ingredient (assuming 100% activity) weight % weight % weight % AExS 21.0 12.6 21.0 LAS -- 1.7 -- Branched Alkyl sulfate -- 4.1 -- NI 23-9 0.4 0.5 0.4 C12 trimethylammonium chloride 3.0 -- 3.0 Citric Acid 2.5 2.4 2.5 C12-18 Fatty Acids 3.4 1.3 3.4 Protease B 0.4 0.4 0.4 Carezyme 0.1 0.1 0.1 Tinopal AMS-X 0.1 0.1 0.1 TinopalCBS-X -- -- -- ethoxylated (EO15) tetraethylene pentaimine 0.3 0.4 0.3 PEI 600 EO20 0.6 0.8 0.6 Zwitterionic ethoxylated quaternized sulfated hexamethylene diamine 0.8 -- 0.8 PP-54951 3.4 3.0 3.4 Merquat 5300 0.2 0.2 0.2 Diethylene triamine penta acetate, MW = 393 0.2 0.3 0.2 Mica/TiO2 pearl (ex BASF) 0.2 -- 0.1 Ethyleneglycol distearate (EGDS pearl) 1.0 -- Hydrogenated castor oil 0.1 -- 0.1 Sodium Hydroxide To pH 8.0 To pH 8.0 To pH 8.0 water, perfumes, dyes, and other optional agents/components to 100% balance to 100% balance to 100% balance 1: supplied by Dow Coming Corporation, Midland, MI - An example of a laundry detergent composition useful for inclusion in a water soluble (unit dose) detergent package is found below. To form the water soluble package, approximately 45ml of the composition is enclosed within a Monosol M8630 soluble film by a traditional thermoforming process.
Active Material Weight % Glycerol 7.00 Propylene glycol 13.30 Monoethanolamine 6.90 Caustic soda 1.00 Potassium sulfite 0.18 C24EO7 alcohol ethoxylate 16.90 Optical brightener FWA36 0.28 Alkylbenzenesulfonic acid 22.30 C 12-18 fatty acid 18.20 Protease 1.10 Perfume 1.50 Dyes ppm Minors <0.1% TiO2 coated mica 0.10 Silicone softener 2.00 Hydrogenated castor oil 0.20 Merquat 5300 0.2 Water 8.83 Total 100 - The citation of any document is not to be construed as an admission that it is prior art with respect to the present invention. To the extent that any meaning or definition of a term in this written document conflicts with any meaning or definition of the term in a document incorporated by reference, the meaning or definition assigned to the term in this written document shall govern.
- While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
SCORE (PSU) | MEANING |
0 | There is no difference |
-1 | I think this one has more residues (unsure) |
-2 | This one has somewhat more residues (sure) |
-3 | This one has a lot more residues |
-4 | This one has hugely more residues (a "day and night" difference) |
Claims (11)
- A laundry detergent composition comprising from 5% to 90% , by weight of the composition, of water and having a pH of from 6 to 11, wherein the composition further comprises:a) from 0.02% to 2%, by weight of the composition, of a polymer having a number average molecular weight of from 700,000 to 4,000,000 and comprising monomeric units, wherein the monomeric units are derived from monomers, said monomers comprising:i) at least 50%, by mole, of nonionic monomers selected from acrylamide, N,N-dialkyl acrylamide, methacrylamide, N,N-dialkylmethacrylamide, hydroxyalkyl acrylate and vinyl pyrrolidone, vinyl acetate, vinyl alcohol, and mixtures thereof; preferably selected from acrylamide, vinyl pyrrolidone, and mixtures thereof;ii) from 3% to 30%, by mole, of cationic monomers selected from N,N-dialkylaminoalkyl methacrylate, N,N-dialkylaminoalkyl acrylate, N,N-dialkylaminoalkyl acrylamide, N,N-dialkylaminoalkylmethacrylamide, methacrylamidoalkyl trialkylammonium chloride, acrylamidoalkylltrialkylammonium chloride, vinylamine, quaternized vinyl imidazole and diallyl dialkyl ammonium chloride, and mixtures thereof; preferably from [(3-methylacrylamido) alkyl] trialkylammonium chloride, diallyldimethylammonium chloride, and mixtures thereof; more preferably is 3-methacrylamidopropyltrimethyl ammonium chloride;iii. from 1% to 20%, by mole, of anionic monomers selected from acrylic acid, methacrylic acid, maleic acid, vinyl sulfonic acid, styrene sulfonic acid, acrylamidopropylmethane sulfonic acid (AMPS), salts thereof, and mixtures thereof; preferably from acrylic acid, methacrylic acid, and mixtures thereof; more preferably acrylic acid;
wherein the overall mole ratio of the monomers, according to the following equation,
is from 0.25 to 0.8, preferably from 0.35 to 0.6; andb) from 5% to 60%, by weight of the composition, of a surfactant system comprising from 1 % to 25%, by weight of the surfactant system, of fatty acid. - A laundry detergent composition according to Claim 1 wherein the monomeric units are derived from at least 70%, by mole, of acrylamide.
- A laundry detergent composition according to any one of the preceding claims wherein the surfactant system comprises from 3% to 15% fatty acid.
- A laundry detergent composition according to any one of the preceding claims wherein the composition further comprises from 5% to 25% sodium alkyl ethoxysulfate.
- A laundry detergent composition according to any one of the preceding claims wherein the detergent composition further comprises a fatty acid crystal modifier; preferably wherein the fatty acid crystal modifier is selected from:a) at least 5%, by weight of the composition of sodium alkyl ethoxysulfate;b) from 0.1% to 10% of a quaternary ammonium surfactant having the formulac) from 0.1% to 5%, by weight of the composition, of alkoxylated polyethyleneimines having a molecular weight of from 300 to 6000 and an average alkoxylation of from 3 to 30 moles of alkylene oxide per nitrogen;d) from 0.1 % to 5%, by weight of the composition, of ethoxylated tetraethylene-pentaimine having an average ethoxylation of from 15 to 18;e) from 1% to 10% of zwitterionic surfactant;f) from 0.05% to 2% of a chelating agent;g) from 0.1% to 5% of a zwitterionic amine-based polymer;h) from 1% to 10% of a nonionic alkylpolyethoxylate; andi) mixtures thereof.
- A laundry detergent composition according to any one of the preceding claims wherein the composition further comprises a water insoluble fabric care benefit agent selected from dispersible polyolefins, polymer latexes, organosilicones, perfume or other active microcapsules, and mixtures thereof.
- A laundry detergent composition according to Claim 6 wherein the organosilicones are selected from polydimethylsiloxanes, aminosilicones, amidosilicones, silicone polyethers, alkylsilicones, phenyl silicones, quaternary silicones and mixtures thereof.
- A laundry detergent composition according to any one of the preceding claims wherein the composition further comprises from 0.02% to 0.5%, by weight of the composition, of a pearlescent agent; preferably wherein the pearlescent agent is selected from the group consisting of mica, metal oxide coated mica, bismuth oxy chloride coated mica, bismuth oxychloride, glass, metal oxide coated glass, ethylene glycol distearate, fish scales, and mixtures thereof.
- A laundry detergent composition according to claim 1, comprising from 10% to 90% water , wherein the composition comprises:b) from 0.05% to 2%, by weight of the composition, of the polymer
, said monomers comprising:i) at least 70%, by mole, of acrylamide;ii) from 3% to 30%, by mole, of [(3-methylacrylamido) propyl] trimethylammonium chloride;b) the surfactant system comprising
from 3% to 15% fatty acid;
andc) at least 0.1%, by weight of the composition, of an electrolyte. - Use of a laundry composition according to Claim 1 to launder or pre-treat fabrics.
- Use of a laundry composition according to Claim 1 to provide softness to fabrics through the wash.
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US2546908P | 2008-02-01 | 2008-02-01 | |
PCT/IB2009/050251 WO2009095823A1 (en) | 2008-02-01 | 2009-01-22 | Fabric softening laundry detergent |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2295531B1 (en) * | 2009-09-14 | 2017-02-22 | The Procter & Gamble Company | A fluid laundry detergent composition |
EP2336285B1 (en) * | 2009-12-18 | 2013-09-04 | The Procter & Gamble Company | Composition comprising microcapsules |
JP5650314B2 (en) * | 2010-04-01 | 2015-01-07 | ザ プロクター アンド ギャンブルカンパニー | Fabric care composition comprising a copolymer |
US9186642B2 (en) | 2010-04-28 | 2015-11-17 | The Procter & Gamble Company | Delivery particle |
US20110268778A1 (en) * | 2010-04-28 | 2011-11-03 | Jiten Odhavji Dihora | Delivery particles |
RU2578597C2 (en) * | 2011-09-01 | 2016-03-27 | Дзе Проктер Энд Гэмбл Компани | Cleaning compositions and pollutant-binding agent for cleaning objects |
EP2802643B1 (en) * | 2012-01-11 | 2015-12-02 | Henkel AG & Co. KGaA | Fragrant, water-soluble packaging |
EP2875110B1 (en) * | 2012-07-19 | 2016-08-17 | The Procter & Gamble Company | Cleaning compositions |
EP2875055B1 (en) * | 2012-07-19 | 2016-03-23 | Basf Se | Hydrophobically modified cationic polymer |
CN105431515A (en) * | 2013-05-24 | 2016-03-23 | 宝洁公司 | Low ph detergent composition |
GB201319923D0 (en) * | 2013-11-12 | 2013-12-25 | Cambridge Entpr Ltd | Novel composition |
US9862912B2 (en) * | 2014-03-26 | 2018-01-09 | The Procter & Gamble Company | Cleaning compositions containing cationic polymers, and methods of making and using same |
WO2015143644A1 (en) * | 2014-03-26 | 2015-10-01 | The Procter & Gamble Company | Cleaning compositions containing cationic polymers, and methods of making and using same |
JP6238450B2 (en) * | 2014-04-03 | 2017-11-29 | ライオン株式会社 | Liquid detergent for textile products |
CN104060472A (en) * | 2014-06-24 | 2014-09-24 | 江苏万淇生物科技有限公司 | Synthetic method of softener capable of improving fabric detergency performance |
EP3186345A1 (en) | 2014-08-27 | 2017-07-05 | The Procter and Gamble Company | Detergent composition comprising a cationic polymer |
WO2016032996A1 (en) | 2014-08-27 | 2016-03-03 | The Procter & Gamble Company | Method of preparing a detergent composition |
CA2956081C (en) * | 2014-08-27 | 2021-03-16 | The Procter & Gamble Company | Detergent composition comprising a cationic polymer |
US9809782B2 (en) | 2014-08-27 | 2017-11-07 | The Procter & Gamble Company | Detergent composition comprising a cationic polymer and anionic/nonionic surfactant mixture |
JP6695855B2 (en) | 2014-08-27 | 2020-05-20 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | Detergent composition containing cationic polymer |
JP6400837B2 (en) * | 2014-08-27 | 2018-10-03 | ザ プロクター アンド ギャンブル カンパニー | How to treat fabric |
JP6430632B2 (en) | 2014-09-25 | 2018-11-28 | ザ プロクター アンド ギャンブル カンパニー | Fabric care composition containing polyetheramine |
CN104651078B (en) * | 2014-10-10 | 2017-10-17 | 浙江艾莱依羽绒制品有限公司 | A kind of shield suede liquid detergent that efficiently deoils of coating fabric or high-density fabric down products |
US9840682B2 (en) | 2014-11-11 | 2017-12-12 | The Procter & Gamble Company | Cleaning compositions with improved sudsing profile comprising a cationic polymer and silicone mixture |
JP6257700B2 (en) | 2016-05-30 | 2018-01-10 | ハリマ化成株式会社 | Pitch control agent and pitch control method |
MX2022005531A (en) * | 2019-12-20 | 2022-06-08 | Procter & Gamble | Particulate fabric care composition. |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NZ243311A (en) * | 1991-06-28 | 1995-02-24 | Calgon Corp | Composition for treatment of skin and nails which comprises an ampholyte terpolymer comprising non-ionic, cationic and anionic monomers |
US20040152616A1 (en) * | 2003-02-03 | 2004-08-05 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Laundry cleansing and conditioning compositions |
KR20070106504A (en) * | 2005-02-07 | 2007-11-01 | 가부시키가이샤 시세이도 | Skin cleanser composition |
US7807766B2 (en) * | 2005-09-21 | 2010-10-05 | Cognis Ip Management Gmbh | Polymers for use in cleaning compositions |
-
2009
- 2009-01-22 BR BRPI0907455-4A patent/BRPI0907455A2/en not_active IP Right Cessation
- 2009-01-22 RU RU2010132282/04A patent/RU2010132282A/en not_active Application Discontinuation
- 2009-01-22 JP JP2010544823A patent/JP2011511124A/en not_active Withdrawn
- 2009-01-22 CA CA2713528A patent/CA2713528A1/en not_active Abandoned
- 2009-01-22 MX MX2010008465A patent/MX2010008465A/en active IP Right Grant
- 2009-01-22 CN CN200980103283XA patent/CN101925670A/en active Pending
- 2009-01-22 WO PCT/IB2009/050251 patent/WO2009095823A1/en active Application Filing
- 2009-01-22 EP EP09706862.1A patent/EP2242827B1/en active Active
- 2009-02-02 AR ARP090100323 patent/AR070401A1/en not_active Application Discontinuation
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CN101925670A (en) | 2010-12-22 |
JP2011511124A (en) | 2011-04-07 |
AR070401A1 (en) | 2010-04-07 |
RU2010132282A (en) | 2012-03-10 |
BRPI0907455A2 (en) | 2015-07-14 |
WO2009095823A1 (en) | 2009-08-06 |
EP2242827A1 (en) | 2010-10-27 |
CA2713528A1 (en) | 2009-08-06 |
MX2010008465A (en) | 2010-08-23 |
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