EP2229474A1 - Conjugate fiber having low-temperature processability, nonwoven fabric and formed article using the conjugate fiber - Google Patents
Conjugate fiber having low-temperature processability, nonwoven fabric and formed article using the conjugate fiberInfo
- Publication number
- EP2229474A1 EP2229474A1 EP08863375A EP08863375A EP2229474A1 EP 2229474 A1 EP2229474 A1 EP 2229474A1 EP 08863375 A EP08863375 A EP 08863375A EP 08863375 A EP08863375 A EP 08863375A EP 2229474 A1 EP2229474 A1 EP 2229474A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- component
- fiber
- conjugate fiber
- nonwoven fabric
- conjugate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 404
- 239000004745 nonwoven fabric Substances 0.000 title claims abstract description 115
- 238000002844 melting Methods 0.000 claims abstract description 77
- 230000008018 melting Effects 0.000 claims abstract description 74
- -1 polypropylene Polymers 0.000 claims abstract description 46
- 229920001577 copolymer Polymers 0.000 claims abstract description 41
- 238000012545 processing Methods 0.000 claims description 121
- 238000000034 method Methods 0.000 claims description 109
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 62
- 239000005977 Ethylene Substances 0.000 claims description 62
- 239000000155 melt Substances 0.000 claims description 35
- 238000009826 distribution Methods 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 108091023288 HOTAIR Proteins 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 abstract description 29
- 229920001155 polypropylene Polymers 0.000 abstract description 29
- 239000004711 α-olefin Substances 0.000 description 43
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 31
- 229920005989 resin Polymers 0.000 description 24
- 239000011347 resin Substances 0.000 description 24
- 239000003795 chemical substances by application Substances 0.000 description 18
- 238000004519 manufacturing process Methods 0.000 description 16
- 238000010438 heat treatment Methods 0.000 description 15
- 238000001125 extrusion Methods 0.000 description 13
- 239000002216 antistatic agent Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 12
- 239000000194 fatty acid Substances 0.000 description 12
- 229930195729 fatty acid Natural products 0.000 description 12
- 239000000654 additive Substances 0.000 description 10
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 9
- 238000002788 crimping Methods 0.000 description 9
- 238000010586 diagram Methods 0.000 description 9
- 238000002074 melt spinning Methods 0.000 description 9
- 238000005259 measurement Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 7
- GWTCIAGIKURVBJ-UHFFFAOYSA-L dipotassium;dodecyl phosphate Chemical compound [K+].[K+].CCCCCCCCCCCCOP([O-])([O-])=O GWTCIAGIKURVBJ-UHFFFAOYSA-L 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 230000002093 peripheral effect Effects 0.000 description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 229920013716 polyethylene resin Polymers 0.000 description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
- 238000009960 carding Methods 0.000 description 5
- 238000005520 cutting process Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 241001477893 Mimosa strigillosa Species 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- 239000012968 metallocene catalyst Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 230000004520 agglutination Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 3
- 238000003672 processing method Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 235000008694 Humulus lupulus Nutrition 0.000 description 1
- 244000025221 Humulus lupulus Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/02—Heat treatment
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/04—Supporting filaments or the like during their treatment
- D01D10/049—Supporting filaments or the like during their treatment as staple fibres
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/06—Washing or drying
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/32—Side-by-side structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/443—Heat-resistant, fireproof or flame-retardant yarns or threads
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H13/00—Other non-woven fabrics
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/04—Heat-responsive characteristics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
- Y10T428/2931—Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/608—Including strand or fiber material which is of specific structural definition
Definitions
- the present invention relates to a conjugate fiber that demonstrates low-temperature processability during heat processing and excellent heat adhesiveness without shrinking significantly.
- the present invention also relates to a nonwoven fabric and formed article that use the conjugate fiber and have excellent bulkiness and excellent feeling.
- conjugate fibers having low-temperature processability have conventionally been proposed, and ethylene • crolefin copolymer has been used as a component forming these conjugate fibers, for the reason that the melting point of the component can be easily controlled by using it.
- a sheath-core and side-by-side conjugate fiber in which a "mixture" of a polyethylene resin having a low melting point of 90 to 125°C and a polyethylene resin having a high melting point of 120 to 135°C is used as one of conjugate components (see, for example, Patent Literature l).
- the conjugate fiber proposed in Patent Literature 1 does not necessarily have sufficient low temperature processability because the polyethylene resin having a low melting point of 90 to 125°C is used and at the same time the polyethylene resin having a high melting point of 120 to 135°C is "mixed" into the abovementioned low-melting point polyethylene resin in an amount of, substantially, 30 % by weight or more in order to achieve stable productivity, and because the mixture of these polyethylene resins is used as one component of the conjugate fiber.
- Patent Literature 2 which relates to a latently crimpable conjugate fiber that utilizes a characteristic that the conjugate fiber containing an ethylene ⁇ - olefin copolymer as a component shrinks easily during heat processing, such a latently crimpable conjugate fiber is not suitable for obtaining a nonwoven fabric that does not shrink but has excellent uniformity. Moreover, such a latently crimpable conjugate fiber utilizes a difference in shrinkage characteristics between the plurality of constituents, and hence pealing occurs easily in these components after heat processing.
- Patent Literature l International Publication No. 00/36200
- Patent Literature 2 Japanese Patent Application Publication No.
- An object of the present invention is to provide a conjugate fiber, which has low-temperature processability, is prevented from shrinking, has excellent heat adhesiveness and excellent card passability when processing the conjugate fiber into a nonwoven fabric and particularly when performing card processing, and is capable of obtaining a bulky nonwoven fabric with excellent uniformity.
- Another object of the present invention is to provide bulky nonwoven fabric and formed article of them having excellent uniformity and excellent low-temperature processability.
- a conjugate fiber that forms a specific side-by-side cross section that has a first component containing a specific ethylene or olefin copolymer as a component for contributing to low-temperature processability of the conjugate fiber, i.e., a component having a lower melting point and softened and molten when heated, in a specific amount or more, and a second component containing a crystalline polypropylene.
- the present invention is a conjugate fiber in which a first component that contains at least 75 % by weight of an ethylene ⁇ -olefin copolymer having a melting point of 70 to 100 0 C and a second component that contains a crystalline polypropylene form a side-byside cross section, wherein, in a fiber cross section perpendicular to a fiber axis, the first component accounts for 55 to 90% of an outer periphery of the fiber, a borderline between the first component and the second component forms a curve bulging toward the first component, and an area ratio between the first component and the second component (first component/second component) is in a range of 70/30 to 30/70.
- examples of the ethylene orolefin copolymer to be used include an ethylene - ⁇ -olefLn copolymer having a molecular weight distribution (MwMn) of 1.5 to 2.5, a density of 0.87 to 0.91 g/cm 3 , and a melt index (MI) of 10 to 35 g/10 min as measured under conditions with a temperature of 190 0 C and a load of 21.2 N based on ASTM D- 1238.
- MwMn molecular weight distribution
- MI melt index
- the conjugate fiber of the present invention can be processed into a nonwoven fabric to produce a nonwoven fabric, and the conjugate fiber of the present invention can be processed or the nonwoven fabric obtained from the conjugate fiber of the present invention can be processed to obtain a shaped article.
- the present invention is also intended for a nonwoven fabric obtained by processing the conjugate fiber into a nonwoven fabric, a formed article obtained using the conjugate fiber, and a formed article obtained using the nonwoven fabric.
- Examples of the processing into a nonwoven fabric include a hot-air adhesion method and a hot-water adhesion method.
- the conjugate fiber of the present invention has a side-byside cross section in which a first component containing 75 % by weight of an ethylene -crolefin copolymer having a melting point of 70 to 100 0 C accounts for 55 to 90% of an outer periphery of the fiber in a fiber cross section perpendicular to a fiber axis, a borderline between the first component and the second component forms a curve bulging toward the first component, and in which an area ratio between the first component and the second component (first component/second component) is in a range of 70/30 to 30/70.
- the first component containing the ethylene crolefin copolymer covers mainly the surface of the fiber
- the first component shows an excellent heat adhesiveness at a heat processing temperature of 100 0 C or lower. Specifically, excellent low-temperature processability is obtained.
- the second component containing a crystalline polypropylene is exposed to a part of the surface of the fiber, the second component can reduce the intensity of the surface friction particular to the ethylene xx-olefin copolymer, and can also be produced stably in a fiber manufacturing process even without adding lubricant at all or by adding a little lubricant. Particularly when performing card processing, excellent fiber passability can be obtained during the card processing.
- a problem in the cross-sectional shape of a general two-component side-byside conjugate fiber having a combination of half-moon-shaped components is the pealing of the components.
- the side-byside cross section of the conjugate fiber of the present invention is configured such that the first component containing ethylene orolefin copolymer accounts for 55 to 90% of the length of the outer periphery, the borderline between the first component and the second component forms a curve bulging toward the first component, and such that the area ratio between the first component and the second component (first component/second component) is in a range of 70/30 to 30/70.
- the conjugate fiber of the present invention can effectively prevent shrinkage by adopting a specific fiber cross-sectional shape with a specific ethylene ⁇ -olefin copolymer used as the first component.
- the nonwoven fabric obtained using the conjugate fiber of the present invention is bulky and soft, has less width reduction (reduction of the width in relation to a direction of flow of the nonwoven fabric) due to small shrinkage when subjected to heat processing, hence excellent productivity and excellent uniformity can be achieved.
- the conjugate fiber of the present invention has, as an effective component, a component that contains an ethylene crolefin copolymer having a melting point of 70 to 100 0 C, heat processing can be performed thereon at 100 0 C or lower.
- a medium such as steam and hot water also can be used so that appropriate conditions for obtaining a nonwoven fabric or a formed article can be selected from a wide range of choice in accordance with the use application, environment and circumstances.
- FIG. l A schematic diagram showing an example of the side-by-side cross-sectional shape of a conjugate fiber of the present invention. Best Mode for Carrying Out the Invention
- the conjugate fiber of the present invention has a first component containing an ethylene ⁇ olefin copolymer.
- This ethylene ⁇ -olef ⁇ n copolymer comprises ethylene and ⁇ -olefin units.
- the ⁇ -olefin include, specifically, linear ⁇ -olefins such as propylene, butene-1, pentene-1, hexene-1, heptene-1, and octene-1. Butene-1 and octene l are preferred but octene l is more preferred.
- the ⁇ -olefin content of the ethylene ⁇ -olefin copolymer is preferably 30 mol% or less and more preferably 20 mol% or less.
- the ⁇ -olefin content is normally 1 mol% or more.
- the content in this case is expressed in molar ratio percentage (( ⁇ -olefin)/( ⁇ -olefin + ethylene)).
- Excessive ⁇ -olefin content delays solidification during the fiber manufacturing process and causes fusion between fibers and thereby a possible damage the productivity.
- the ⁇ -olefin content is 30 mol% or less, sufficient rigidity of the fiber can be obtained and, particularly when performing card processing, excellent fiber passability can be obtained during the card processing.
- the melting point of the ethylene ⁇ -olefin copolymer to be used is 70 to 100 0 C, and preferably 80 to 100 0 C.
- the melting point of at least 70 0 C can prevent fusion between fibers, and, for example, when drying an antistatic agent or other treatment agent applied to the surface of the fiber during the fiber manufacturing process, fusion between the fibers can be prevented and excellent productivity can be exerted.
- the melting point of 100 0 C or lower not only is it possible to set the temperature for processing the fiber into a nonwoven fabric or a formed article at 100 0 C or lower, but also a medium such as steam and hot water can be used for heat processing, and a processing method in which a comparatively low-temperature medium is used can be selected.
- this 100 0 C or less melting point is preferred as it is not necessary to concern about the influence on other components of the fiber that are essentially not molten.
- the melting point described here is a melting peak temperature that is obtained when the ethylene crolefin copolymer is measured using a differential scanning calorimeter (DSC). When a plurality of melting peaks are confirmed the temperature of the largest melting peak is taken as the melting point, and when a plurality of close melting peaks are confirmed the lower temperature of those is taken as the melting point.
- the molecular weight distribution (Mw/Mn), which is the ratio between the weight- average molecular weight (Mw) of the ethylene ⁇ -olefin copolymer and the number average molecular weight (Mn), is preferably 1.5 to 2.5 and more preferably 1.7 to 2.3.
- Mw/Mn the molecular weight distribution
- Mw/Mn the molecular weight distribution is in a range of 1.5 to 2.5, excellent spinnability is obtained in the fiber manufacturing process, and thus this molecular weight distribution is preferred in terms of the fabric property in order to obtain a strong conjugate fiber.
- the density of the ethylene ⁇ olefin copolymer is preferably 0.87 to 0.91 g/cm 3 and particularly preferably 0.88 to 0.90 g/cm 3 .
- the density of the ethylene ⁇ olefin copolymer is at least 0.87 g/cm 3 , appropriate surface viscosity can be obtained when processing the copolymer into a fiber, and agglutination hardly occurs during fiber manufacture. Therefore, this density is suitable for using the ethylene crolefin copolymer as a main component of the fiber.
- the density is 0.91 g/cm 3 or lower
- the melting point of the ethylene orolefin copolymer is comparatively as low as 100 0 C or lower, and thus this ethylene ⁇ -olefin copolymer is suitable as the ethylene crolefin copolymer to be used in the present invention.
- the melt index (MI) of the ethylene ⁇ -olefin copolymer is preferably 10 to 35 g/10 min and more preferably 15 to 30 g/10 min in consideration of achieving stable production during the fiber manufacturing process.
- the MI described here is a value that is measured under conditions with a temperature of 190 0 C and a load of 21.2 N based on ASTM D- 1238.
- the ethylene xx-olefin copolymer to be used may be a mixture of one kind or two or more types.
- additives can be compounded into the ethylene crolefin copolymer used in the present invention.
- Preferred examples of the additives include lubricant, heat-resistant stabilizer, antioxidant, weatherproof stabilizer, antistatic agent, colorant and the like.
- Preferred used as a lubricant includes fatty acid amides such as oleic amide and erucic acid amide, fatty acid esters such as butyl stearate, polyolefin waxes such as polyethylene wax and polypropylene wax, and metallic soap such as calcium stearate, and the like. More preferred examples include fatty acid amides such as oleic amide, erucic acid amide, stearic acid amide, behen acid amide and the like.
- the first component contained in the conjugate fiber of the present invention needs to include the abovementioned ethylene ⁇ -olefin copolymer in an effective amount so as to be involved in heat adhesion at low temperature and so that steam or hot water can be used as a heat medium particularly when processing the conjugate fiber into a nonwoven fabric or performing the processing of formed article.
- the ethylene - ⁇ rolefin copolymer content is preferably at least 75%, or more preferably at least 85% in relation to the weight of the first component, and particularly preferably 100% as a resin raw material. It is preferred that the ethylene ⁇ -olefin copolymer be at least 75% in the first component so that the performance of the ethylene ⁇ -olefin copolymer can be realized subjectively.
- low-density polyethylene, high-density polyethylene, ethylene vinyl acetate copolymer, propylene copolymer and the like can be the resin raw materials that the first component may contain in addition to the ethylene crolefin copolymer under the condition that at least 75% of the ethylene crolefin copolymer is contained in relation to the weight of the first component.
- the conjugate fiber of the present invention contains a crystalline polypropylene as the second component.
- This crystalline polypropylene is a propylene homopolymer or a copolymer of propylene and a small amount of ⁇ -olefin (normally 2 % by weight or less), and examples of such a crystalline polypropylene include a general-purpose polypropylene that is obtained by using a Ziegler-Natta catalyst or a metallocene catalyst.
- MFR melt mass flow rate
- the second component forming the conjugate fiber of the present invention which contains the crystalline polypropylene, a mixture of the crystalline polypropylene and propylene ⁇ olefin copolymer, or a mixture of crystalline polypropylenes having different properties such as the melt mass flow rate (MFR) and molecular weight distribution (Mw/Mn) can be used suitably as long as the effect of the conjugate fiber is not damaged significantly.
- MFR melt mass flow rate
- Mw/Mn molecular weight distribution
- the first component containing the ethylene crolefin copolymer and the second component containing the crystalline polypropylene form a side-by-side cross section having a specific structure.
- the first component containing the ethylene • ⁇ -olefin copolymer accounts for 55 to 90% of an outer periphery of the fiber
- the second component containing the crystalline polypropylene accounts for 45 to 10% of the same. Because the first component containing a specific ethylene ⁇ -olefin copolymer accounts for 55% or more of the outer periphery of the fiber, heat processing can be performed at 100 0 C or lower.
- the second component containing the crystalline polypropylene accounts for 10% or more of the outer periphery of the fiber, the crystalline polypropylene continuously appear on the fiber, not only is it possible to reduce the friction between fibers or friction to a metal but also viscosity that occurs when the ethylene ⁇ olefin copolymer is used on the surface of the fiber, and excellent spinnability and card processability can be obtained when performing the card processing. It is particularly preferred that the first component containing the ethylene crolefin copolymer account for 60 to 80% of the outer periphery of the fiber and that the second component containing the crystalline polypropylene account for 40 to 20% of the same.
- the borderline between the first component and the second component forms a curve bulging toward the first component.
- the borderline between the first component and the second component becomes longer compared to the conjugate fiber having a general side-by-side cross-sectional structure where half-moon-shaped components are joined together. Specifically, the joint area between the both components is increased and, by providing the conjugate fiber of the present invention with a structure where the first component wraps the second component, the second component can be prevented from being released from this conjugate fiber.
- the fiber cross section perpendicular to the fiber axis has a structure where the borderline forms a curve bulging toward the first component such that the relationship between the length of a segment cd and a segment ce satisfy a relationship of cd ⁇ 0.8 ce.
- cd ⁇ ce more preferably cd ⁇ 1.5 ce, or particularly preferably cd ⁇ 2ce, excellent un-releasability between the conjugate components and heat shrinkability are obtained when performing heat processing and forming processing.
- the borderline between the first component and the second component that forms a curve bulging toward the first component is considered to take up a part of the outer periphery of a circle or an ellipse formed by an outer periphery of the second component, it is preferred that the length (g) of the borderline exceed 50% or more preferably at least 60% of the entire outer peripheral length (h) of the circle or ellipse formed by the second component.
- the conjugate fiber of the present invention can be manufactured using a conventionally known side-by-side conjugate spinneret.
- the conjugate fiber of the present invention can be manufactured using a side-byside conjugate spinneret, for example, Japanese Patent Application Publication S48- 11417 or Japanese Patent Application Publication S52-74011.
- the flowability (viscosity) thereof that is measured when melting it at some temperature selected in the range about 190 0 C, and a temperature range in which the flowability (viscosity) enabling the fiber to be manufactured is selected based on fluctuation of melt flowability (melt viscosity) to obtain an extrusion temperature as the fiber manufacturing condition.
- the second component containing the crystalline polypropylene when the flowability (viscosity) thereof is measured by melting the second component at about 230 0 C, to select an extrusion temperature.
- the cross -sectional configuration of the conjugate fiber of the present invention can be formed easily when the ratio of the melt index (MI) of the first component to the melt mass flow rate (MFR) of the second component is 1.5 to 3 times, although it is not possible to say definitely because temperature dependence of the flowability (uptrend of viscosity) varies depending on the resins used. More preferably, this ratio is in a range of 1.8 to 2.5.
- the proportion of the first component and the second component on the fiber cross section in relation to the outer periphery of the fiber can be increased or decreased even if the extrusion temperature and the melt viscosity are not changed.
- a treatment agent may be applied to a surface of the conjugate fiber of the present invention in order to improve processing stability when manufacturing the fiber.
- the treatment agent is mainly an antistatic agent, but is also a hydrophilic agent capable of improving wettability of the surface of the fiber.
- examples of the components of these antistatic agent and hydrophilic agent include alkyl phosphate, ethylene oxide adduct thereof, sorbitan fatty acid ester ethylene oxide adduct, polyglycerol fatty acid ester, polyoxy ethylene modified silicone and the like.
- a single component selected from these components or a mixture of any of the components is used as the treatment agent.
- the heat shrinkage percentage of the conjugate fiber of the present invention that is obtained when heat-processing the conjugate fiber at 100 0 C for five minutes is 50% or lower, preferably 30% or lower, and more preferably 20% or lower.
- the heat shrinkage percentage described here which is expressed in percentage (%), is a difference in size (reduced amount) between the conjugate fibers that are and are not subjected to heat processing, the conjugate fibers being obtained by inserting the conjugate fiber of the present invention, staple fiber, into a card machine, cutting the fibrous web that is thus extracted from a card outlet (the web is in the form of a sheet with entangled fibers) into a certain shape, and then performing the heat processing thereon at 100 0 C for five minutes.
- the heat shrinkage percentage of the present invention is obtained by cutting the conjugate fiber of the present invention into any length such as 30 to 65 mm to obtain a staple fiber, and inserting this staple fiber into a miniature card machine to create a fibrous web having a mass per unit area of 200 g/m 2 .
- This fibrous web is cut along a pattern of 250 mm x 250 mm in a flow direction (MD) of the fiber and a direction perpendicular to this flow direction (CD).
- MD flow direction
- CD direction perpendicular to this flow direction
- This fibrous web is left stand for ten minutes, thereafter the length of the MD of this cut fibrous web is measured immediately before performing the heat processing, and then the fibrous web is subjected to the heat processing in a circulating hot air oven at 100 0 C for five minutes.
- the length of MD is measured again, and the value of the heat shrinkage percentage is obtained by the following equation.
- Heat Shrinkage Percentage (%) ⁇ (Lo - OfL 0 ) x 100 Lo : The length of MD before the heat processing L- The length of MD after the heat processing
- the lower this value the smaller the shrinkage of the fibrous web when processing the conjugate fiber into a nonwoven fabric, hence stable processing can be performed and a nonwoven fabric with excellent uniformity can be obtained.
- conditions for measuring the heat shrinkage described here are not specified/limited to the conditions for processing the conjugate fiber of the present invention, the heat processing conditions, the conditions for processing the conjugate fiber into a nonwoven fabric, and usage of the conjugate fiber.
- crimps are generated easily during the heat processing for manufacturing the fiber, due to the cross-sectional structure of the conjugate fiber and the resin configuration thereof, hence, as a result, the effect of improving bulkiness of the fiber can be exerted.
- the fibrous web for use in processing the conjugate fiber into a nonwoven fabric the fibrous web being an assembly of fibers that are cut into a predetermined length to process the conjugate fiber into a nonwoven fabric, when performing the heat processing, the fiber itself shrinks easily, because of existing freely each other in the web.
- the part that shrinks easily pulls and gathers the fibers existing in the surroundings to form a clump, and the part that has lost fibers due to this gathering is reduced in mass per unit area, whereby weight unevenness becomes extremely noticeable in the entire nonwoven fabric, making it difficult to obtain a nonwoven fabric having excellent uniformity.
- the conjugate fiber of the present invention has the side-by-side cross-sectional structure composed of two components, but has a cross-sectional shape in which the first component containing the ethylene ⁇ -olefin copolymer accounts for 55 to 90% of the outer periphery of the fiber and wraps the second component containing the crystalline polypropylene.
- an ethylene orolefin copolymer having a melting point of 70 to 100 0 C, or preferably an ethylene • crolefin copolymer having a molecular weight distribution (Mw/Mn) of 1.5 to 2.5, a density of 0.87 to 0.91 g/cm 3 , and a melt index (MI) of 10 to 35 g/10 min shrinkage properties obtained during the heat processing can be retained at 50% or lower where the processing into a nonwoven fabric and the processing into a formed article can be stably performed, while taking the advantage of the bulk improving effect obtained from latent crimps by adopting the side-by-side cross-sectional structure.
- the conjugate fiber of the present invention that has a combination of a specific resin structure and a specific conjugate structure. It is unexpected that, while surprisingly preventing shrinkage by using the specific ethylene crolefin copolymer and combining it with the crystalline polypropylene to obtain a fiber that further has a specific fiber cross-sectional configuration, it is possible to obtain a nonwoven fabric that has excellent bulkiness, which is generally considered to be a conflicting performance, excellent feeling, and excellent heat processing properties at a low temperature of 100 0 C.
- the fineness of the conjugate fiber of the present invention is not particularly limited.
- a conjugate fiber that is suitably processed into a nonwoven fabric or formed article may be selected in consideration of the properties of the components forming the conjugate fiber and of processing stability when manufacturing the fiber.
- a fiber having a fineness of 1 to 5 dtex is preferably selected when using the conjugate fiber in a powder puff or a medicine sheet that comes into direct contact with a human skin.
- a fiber having a fineness of 1 to 10 dtex is suitable for use in a liquid retaining material such as an ink cartridge of a printer.
- a fiber having a fineness of 1 to 20 dtex is suitable for use in a liquid volatizing material such as an aromatic substance core of home fragrance.
- the length of the conjugate fiber of the present invention is not particularly limited, and hence may be long or short.
- the cut length can be appropriately selected in accordance with the fineness of the conjugate fiber, the method of processing the conjugate fiber, and the use application of the conjugate fiber.
- the staple fiber When the staple fiber is subjected to the card processing, it is preferred that the staple fiber be cut into 20 to 125 mm. In order to obtain excellent card passability and uniformity of the fibrous web, it is preferred that the staple fiber be cut into 25 to 75 mm.
- the conjugate fiber be chopped into 3 to 25 mm with the air-laid method.
- the conjugate fiber of the present invention preferably has crimps in order to spread the fiber bundle and obtain a bulky fibrous web and nonwoven fabric.
- the number of crimps to be obtained or the type of crimps can be selected appropriately in accordance with the fineness and cut length of the conjugate fiber, the method for processing the conjugate fiber, and the use application of the conjugate fiber. For example, when a conjugate fiber (staple fiber) having a fineness of 3.3 to 6.6 dtex and a cut length of 38 to 45 mm is processed into a fibrous web by a carding method, it is preferred that the number of crimps be 10 to 25 peaks/25 mm.
- the number of crimps be 5 to 15 peaks/25 mm.
- the crimps can be, for example, in a zigzag shape or a spiral structure.
- the fibrous web is formed first, the heat processing is performed thereon, and then the method for processing into a nonwoven fabric is used.
- a fibrous web formation method include a carding method for passing a card machine and an air-laid method for inserting fibers into a cylindrical drum provided with a slit and accumulating the fibers on a belt conveyor by rotating the drum, but the fibrous web formation method is not limited to these methods.
- other fibers can be blended as long as the effects of the present invention are not impaired significantly.
- the fibers that can be blended include rayon and cotton for improving the water retention ability, polyethylene terephthalate for making an obtained nonwoven fabric bulkier, and other hollow fibers.
- a span lace method or a needle punching method for etangling the fibers within the fibrous web by means of a water stream, compressed air, a needle or the like can be used before performing the heat processing, to improve the strength of the fibrous web and change the feeling.
- the heat processing method include a hot-air adhesion method, a hot-water adhesion method, hot-roll adhesion method and the like.
- the hot-air adhesion method or the hot- water adhesion method is preferred as the heat processing method to be performed after forming the conjugate fiber of the present invention into the fibrous web.
- the hot-air adhesion method is a method for softening and melting a low-melting point component of the conjugate fiber by passing heated air through the fibrous web and adhering the fibers at their contact point. Because this adhesion method does not impair the bulkiness by compressing a certain area unlike the hot-roll adhesion method, this adhesion method is suitable for providing a bulky nonwoven fabric having excellent uniformity and excellent feeling, which is the object of the present invention.
- This hot- air adhesion method is suitable for obtaining a bulky nonwoven fabric having excellent feeling. Therefore, particularly when the hot-air adhesion method is used to heat-process a conjugate fibrous web that has short fibers each having a general side-by-side cross section with two half-moon-shaped components, large shrinkage occur easily compared to when other adhesion methods are used, due to high freedom of the fibrous web on the conveyor, and thus a nonwoven fabric with excellent uniformity and excellent feeling cannot be obtained easily.
- the conjugate fiber of the present invention is designed to effectively prevent shrinkage caused by heat-processing the conjugate fiber into a nonwoven fabric, and thus can be used suitably in this hot-air adhesion method in particular. Therefore, the conjugate fiber of the present invention can provide a nonwoven fabric having an excellent feeling, while keeping the advantage of bulkiness that is essentially provided by the hot- air adhesion method.
- the hot-water adhesion method is a method for softening and melting a low-melting point component of the conjugate fiber by passing heated water or steam through the fibrous web and adhering the fibers at their contact point.
- the first component containing the ethylene ⁇ -olefin copolymer having a melting point of 70 to 100 0 C accounts for the majority of the peripheral surface of the fiber, a hot-water adhesion method that performs the heat processing at 100 0 C or lower can be essentially applied. Hot water, steam or other comparatively inexpensive medium that does not require any special equipment is used in this adhesion method.
- the treatment agent applied onto the surface of the conjugate fiber of the present invention can be washed away while processing the conjugate fiber into a nonwoven fabric.
- the treatment agent applied onto the surface of the fiber is essential in the conjugate fiber (staple fiber, chop for air-laid method and the like) manufacturing process, but is not necessary or is rather an obstruction after processing the fiber into a nonwoven fabric or formed article, depending on the use application.
- Examples of said use application include a food protection sheet such as a packing material and a plastic tray that come into direct contact with food, a powder puff impregnated in a cosmetic item, and a stick for applying a medical agent to an affected part of the body.
- a method for configuring the treatment agent of the fiber surface by selecting a safe element such as a food additive or a corresponding component, or a method for performing cleansing to wash away the treatment agent after forming the fiber into a nonwoven fabric or formed article.
- configuring the treatment agent using a human-friendly component does not eliminate the effect of the treatment agent on the cosmetic item or medical agent, and thus it is desired that the treatment agent does not remain on the nonwoven fabric or formed article in order to keep the stable performance.
- performing the cleansing after processing the fiber into a nonwoven fabric or formed article requires equipment and time and thus is disadvantageous in terms of cost.
- the conjugate fiber of the present invention in which the hot-water adhesion method can be adopted is industrially very significant because the present invention can efficiently provide, for the abovementioned use application and at low cost, a bulky nonwoven fabric or formed article that has almost no treatment agent thereon or on which the amount of the treatment agent attached to the fiber is so small that it does not cause the above problems. It is most preferred that the conjugate fiber of the present invention be processed into a nonwoven fabric or formed article by means of the hot-water adhesion method, or that a heat-processed nonwoven fabric obtained by the hot-air adhesion method be processed into a formed article by means of the hot- water adhesion method.
- the mass per unit area of the nonwoven fabric that is obtained when processing the conjugate fiber of the present invention into a nonwoven fabric can be appropriately selected based on the purpose of use.
- the mass per unit area is preferably in a range of 20 to 5Q ⁇ g/m 2 for a food packing material, 30 to 150 g/m 2 for a powder puff or a medicine sheet, and 50 to 250 g/m 2 for a stick for applying a medical agent.
- the bulkiness of the nonwoven fabric that is obtained when processing the conjugate fiber of the present invention into a nonwoven fabric can be calculated based on a specific volume and can be easily at least 20 cm 3 /g, or preferably at least 30 cm 3 /g.
- conjugate fiber of the present invention is processed into a nonwoven fabric
- another nonwoven fabric a fibrous web, thermoplastic film, sheet or the like may be stacked on this nonwoven fabric, depending on the purpose.
- a breathable film, a porous film, a porous nonwoven fabric may be laminated to the nonwoven fabric
- an elastic nonwoven fabric composed of elastomer or other ethylene -crolefin copolymer may be stacked on the nonwoven fabric.
- formed article means a finished product that is obtained using the conjugate fiber of the present invention without processing the conjugate fiber into a nonwoven fabric, and a finished product that is obtained by processing the conjugate fiber into a nonwoven fabric.
- a fibrous web of a desired mass per unit area that is obtained by the carding method or the like can be formed into a sliver, which is then placed in a specific mold and subjected to heat processing, whereby the "formed article" can be obtained.
- the conjugate fiber of the present invention is formed into fibrous webs of a desired mass per unit area by means of the carding method or air-laid method or the like, which are then processed into a nonwoven fabric by means of the hot-air adhesion method or the like.
- nonwoven fabrics are stacked, cut or combined to have a desired mass per unit area and thickness, and the resulting fabric can be integrated into the "formed article" by means of the hot-air adhesion method or hot- water adhesion method.
- the obtained nonwoven fabric can be stacked, cut or combined to have a desired mass per unit area and thickness, which is then placed in a specific mold and subjected to heat processing, whereby the "formed article" can be obtained. Additional processing can be easily performed on the "formed article” obtained using the conjugate fiber of the present invention, for example, by cutting a part of the formed article or heat -processing the formed article.
- the conjugate fiber of the present invention can be suitably used for use applications as a powder puff, medicine sheet, a sheet for cooling fever, a food plastic tray, a cushion material, a buffer material, an aromatic substance core of home fragrance, a liquid retaining material such as a humidifier, a nursery sheet, a wiper, and the like.
- MI Measurement was performed under conditions with a temperature of 190 0 C and a load of 21.2 N based on ASTM D- 1238.
- the resin was cut to have a weight of 4.20 to 4.80 mg, which is then put into a sample pan and a cover is placed thereon. Measurement was performed thereon at a rate of temperature increase 10 °C/min in an N2 purge between 30°C to 200 0 C, to obtain a melt chart. The chart was analyzed to obtain a melting peak temperature.
- Measurement was performed under conditions with a temperature of 230 0 C and a load of 21.2 N based on JIS K7210.
- the thickness of a fiber calculated from the weight per length. (Unit: dtex)
- Results obtained were: the proportion (%) of the first component to the length of the outer periphery of the fiber in the fiber cross section perpendicular to the fiber axis, " the ratio of the length of a fiber cd to the length of a fiber ce (cd/ce) when supposing that two intersections of the outer periphery of the fiber and the borderline between the first component and the second component are taken as point a and point b, the borderline forming a curve bulging toward the first component, and that a point where the segment ab is halved is taken as point c, and a point where the borderline between the first component and the second component intersects with a straight line that extends in a direction perpendicular to a line ab through point c is taken as point d, and a point where said straight bine that extends in a direction perpendicular to a line ab through point c intersects with the outer periphery of the fiber on the second component side as point e; the ratio of the length g
- the first component of the second component can be distinguished in the fiber cross section by heat processing the fiber after cutting it so as to be perpendicular to the length direction. For example, the cut fiber is left stand in an oven dryer heated at 100 0 C, and the first component is then softened, molten, and observed through the optical microscope or scanning electron microscope to check which part of the fiber cross section corresponds to the first component.
- Length of peripheral surface of first component (%) OU/L) x 100 L 1 : Length of peripheral surface of first component h' Entire length of peripheral surface of fiber cross section (8) Heat shrinkage percentage
- the fibrous web of 200 g/m 2 that was inserted into a miniature card machine was cut along a pattern of 250 mm x 250 mm in a flow direction
- the obtained fiber was left stand for ten minutes, and then the cut fibrous webs were placed on a piece of craft paper (350 mm x 700 mm) to measure the length thereof in MD. Subsequently, the craft paper was folded into two to slightly cover the top of the fibrous webs, which is then put into a
- the processed product was taken out from the dryer and cooled at room temperature for five minutes, and the length thereof in MD was measured.
- the heat shrinkage percentage was calculated based on the following equation.
- Heat shrinkage percentage (%) ⁇ (Lo - L)/Lo ⁇ x 100 Lo : Length of MD before heat processing L- Length of MD after heat processing
- the weight per unit area of the nonwoven fabric and fibrous web calculated from the weight of the nonwoven fabric or fibrous web cut into a certain area. (Unit: g/m 2 )
- the weight of the nonwoven fabric that was cut into 250 mm x 250 mm was measured by ⁇ F-200," an electronic scale balance produced by A&D Company. The obtained numeric value was multiplied by 16 to calculate the mass per unit area.
- the weight per unit volume of the nonwoven fabric calculated according to mass per unit area measurement and thickness measurement. (Unit: cm 3 /g)
- the thickness of the nonwoven fabric was measured using
- the uniformity of the appearance, softness by hand touch, stiffness, bulging and the like of the nonwoven fabric were determined comprehensively.
- the first component was an ethylene - ⁇ -olefin copolymer polymerized using a metallocene catalyst, wherein ⁇ -olefin was octene- 1 and contained in the copolymer in an amount of 10 mol%.
- the density was 0.880, the melting point 72°C, the melt index (MI) 18 g/10 min, and the molecular weight distribution (MwMn) 1.9.
- the second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 8 g/10 min and a melting point of 160 0 C.
- the density, melting point, melt index (MI), and molecular weight distribution (MwMn) of the first component were measured using the measuring methods of (l) to (4) described above.
- the melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above.
- the results are shown in the section corresponding to components on Table 1.
- the obtained conjugate fiber (staple fiber) was measured using the measuring methods of (6) and (7) described above.
- the results are shown in the section corresponding to yarn quality on Table 1 along with schematic diagrams. Peeling of the components was not observed in the fiber cross section in the direction perpendicular to the fiber axis.
- the first component was an ethylene ⁇ olefin copolymer polymerized using a metallocene catalyst, wherein crolefin was octene- 1 and contained in the copolymer in an amount of 9 mol%.
- the density was 0.885, the melting point 78°C, the melt index (MI) 30 g/10 min, and the molecular weight distribution (Mw/Mn) 2.0.
- the second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 16 g/10 min and a melting point of 160 0 C.
- the density, melting point, melt index (MI), and molecular weight distribution (Mw/Mn) of the first component were measured using the measuring methods of (l) to (4) described above.
- the melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above.
- the results are shown in the section corresponding to components on Table 1.
- the obtained conjugate fiber (staple fiber) was measured using the measuring methods of (6) and (7) described above.
- the results are shown in the section corresponding to yarn quality on Table 1 along with schematic diagrams. Peeling of the components was not observed in the fiber cross section in the direction perpendicular to the fiber axis.
- the first component was an ethylene ⁇ -olefin copolymer polymerized using a metallocene catalyst, wherein ⁇ -olefin was octene-1 and contained in the copolymer in an amount of 5 mol%.
- the density was 0.902, the melting point 98°C, the melt index (MI) 30 g/10 min, and the molecular weight distribution (Mw/Mn) 2.1.
- the second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 16 g/10 min and a melting point of 160 0 C.
- the density, melting point, melt index (MI), and molecular weight distribution (Mw/Mn) of the first component were measured using the measuring methods of (l) to (4) described above.
- the melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above.
- the results are shown in the section corresponding to components on Table 1.
- the obtained conjugate fiber (staple fiber) was measured using the measuring methods of (6) and (7) described above.
- the results are shown in the section corresponding to yarn quality on Table 1 along with schematic diagrams. Peeling of the components was not observed in the fiber cross section in the direction perpendicular to the fiber axis.
- This fibrous web was subjected to hot-air adhesion processing by using a through-air processing device of hot-air circulation type under conditions with a preset temperature of 98°C, a hot air velocity of 0.38 m/sec, and a processing time of 14 seconds.
- the property of thus obtained through-air nonwoven fabric was measured and evaluated using the measuring methods of (9) to (ll) described above. The results are shown in the section corresponding to nonwoven fabric property on Table 1.
- the first component was an ethylene crolefin copolymer, wherein ⁇ -olefin was octene-1 and contained in the copolymer in an amount of 2 mol%.
- the density was 0.913, the melting point 107 0 C, the melt index (MI) 30 g/10 min, and the molecular weight distribution (MwMn) 3.0.
- the second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 16 g/10 min and a melting point of 160 0 C.
- an antistatic agent that has ethylene oxide additives of sorbitan fatty acid ester and lauryl phosphate potassium salt as the main components is attached to these components. Good spinnability was obtained.
- spun conjugate filament having a fineness of 11.5 dtex was drawn 3.3 times by using a 70 0 C heating device provided with a heating roll, and crimped by means of a crimping device. Thereafter, the filament was cut into 38 mm to obtain a conjugate fiber (staple fiber) having a fineness of 3.8 dtex (fiber diameter of 23.2 ⁇ m).
- the density, melting point, melt index (MI), and molecular weight distribution (MwMn) of the first component were measured using the measuring methods of (l) to (4) described above.
- the melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above.
- the results are shown in the section corresponding to components on Table 2.
- the obtained conjugate fiber (staple fiber) was measured using the measuring methods of (6) and (7) described above.
- Comparative Example 1 is significantly different from Example 3 in that the melting point is 107 0 C in this example, but the same method as that of Example 3 was used to produce a nonwoven fabric.
- the processing temperature enable to be adopted for the obtained conjugate fiber was not low enough to adopt the hot-water adhesion method, and thus the conjugate fiber could not be processed into a nonwoven fabric or a formed article. Therefore, evaluation of the shrinkage percentage of the fibrous webs at 100 0 C according to the low-temperature processing ended up meaningless.
- the first component was an ethylene crolefin copolymer, wherein ⁇ olefin was propylene and butene that are contained in the copolymer in an amount of 3 mol% and 3 mol%.
- the density was 0.897, the melting point 81°C, the melt index (MI) 4 g/10 min, and the molecular weight distribution (MwMn) 2.0.
- the second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 8 g/10 min and a melting point of 160 0 C.
- an antistatic agent that has ethylene oxide additives of sorbitan fatty acid ester and lauryl phosphate potassium salt as the main components is attached to these components.
- agglutination was observed.
- spun conjugate filament having a fineness of 9.8 dtex was drawn 1.7 times by using a 60 0 C heating device provided with a heating roll to provide the filament with crimps by means of a crimping device. Thereafter, the filament was cut into 38 mm to obtain a conjugate fiber (staple fiber) having a fineness of 6.8 dtex (fiber diameter of 31.1 ⁇ m).
- the density, melting point, melt index (MI), and molecular weight distribution (MwMn) of the first component were measured using the measuring methods of (l) to (4) described above.
- the melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above.
- the results are shown in the section corresponding to components on Table 2.
- the obtained conjugate fiber (staple fiber) was measured using the measuring methods of (6) and (7) described above.
- the results are shown in the section corresponding to yarn quality on Table 2 along with schematic diagrams. Because the melt index (MI) of the first component is low, the borderline between the first component and the second component in the fiber cross section in the direction perpendicular to the fiber axis formed a curve bulging toward the second component.
- the first component was an ethylene crolefin copolymer, wherein ⁇ -olefin was propylene that is contained in the copolymer in an amount of 15 mol%.
- the density was 0.863, the melting point 50 0 C, the melt index (MI) 21 g/10 min, and the molecular weight distribution (MwMn) 2.0.
- the second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 16 g/10 min and a melting point of 16O 0 C.
- the melt index (MI) of the first component is significantly low in relation to the melt mass flow rate (MFR) of the second component
- MFR melt mass flow rate
- the density, melting point, melt index (MI), and molecular weight distribution (Mw/Mn) of the first component were measured using the measuring methods of (l) to (4) described above.
- the melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above. The results are shown in the section corresponding to components on Table 2.
- MFR melt mass flow rate
- a mixture of two resins was used as the first component.
- One of the resins was an ethylene ⁇ -olefin copolymer, wherein ⁇ -olefin was propylene that is contained in the copolymer in an amount of 12 mol%.
- the density was 0.870, the melting point 75°C, the melt index (MI) 1 g/10 min, and the molecular weight distribution (Mw/Mn) 1.9.
- the other resin was a propylene ⁇ -olefin copolymer, wherein crolefin was ethylene and butene-1 that are contained in the copolymer in an amount of 1 mol% each.
- the melting point was 128°C and the melt mass flow rate (MFR) was 16 g/10 min.
- MFR melt mass flow rate
- Table 2 shows the property of an ethylene propene copolymer, which is a resin having a lower melting point.
- the second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 8 g/10 min and a melting point of 160 0 C.
- an antistatic agent that has ethylene oxide additives of sorbitan fatty acid ester and lauryl phosphate potassium salt as the main components is attached to these components. Good spinnability was obtained.
- spun conjugate filament having a fineness of 9.7 dtex was drawn 2.6 times by using a 60 0 C heating device provided with a heating roll to provide the filament with crimps by means of a crimping device. Thereafter, the filament was cut into 38 mm to obtain a conjugate fiber (staple fiber) having a fineness of 4.4 dtex (fiber diameter of 25.1 ⁇ m).
- the density, melting point, melt index (MI), and molecular weight distribution (Mw/Mn) of the first component were measured using the measuring methods of (l) to (4) described above.
- the melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above.
- the results are shown in the section corresponding to components on Table 2.
- the property of the obtained conjugate fiber (staple fiber) was measured using the measuring methods of (6) and (7) described above.
- the results are shown in the section corresponding to yarn quality on Table 2 along with schematic diagrams.
- cd/ce 0.2 and g/h ⁇ 0.5.
- lOOg of the obtained conjugate fiber (staple fiber) was inserted into a
- a mixture of two resins was used as the first component.
- One of the resins was a low-density polyethylene. The density thereof was 0.918, the melting point 105 0 C, the melt index (MI) 24 g/10 min, and the molecular weight distribution 7.0.
- the other resin was an ethylene-vinyl acetate copolymer. The density thereof was 0.939, the melting point 92°C, the melt index (Ml) 20 g/10 min, and the molecular weight distribution (MwMn) 5.0. These two resins were mixed at a weight ratio of 75/25. Note that Table 3 shows the property of the ethylene-vinyl acetate copolymer, which is a resin having a lower melting point.
- MFR melt mass flow rate
- an antistatic agent that has ethylene oxide additives of sorbitan fatty acid ester and lauryl phosphate potassium salt as the main components is attached to these components.
- a number of broken yarns were observed during spinning.
- spun conjugate filament having a fineness of 9.7 dtex was drawn 2.6 times by using a 60 0 C heating device provided with a heating roll to provide the filament with crimps by means of a crimping device. Thereafter, the filament was cut into 38 mm to obtain a conjugate fiber (staple fiber) having a fineness of 3.3 dtex (fiber diameter of 21.5 ⁇ m).
- the density, melting point, melt index (MI), and molecular weight distribution (MwMn) of the first component were measured using the measuring methods of (l) to (4) described above.
- the melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above.
- the results are shown in the section corresponding to components on Table 3.
- the property of the obtained conjugate fiber (staple fiber) was measured using the measuring methods of (6) and (7) described above.
- the results are shown in the section corresponding to yarn quality on Table 3 along with schematic diagrams.
- Example 5 and crimps are provided on the filament using the crimping device.
- the filament is then cut into 5 mm to obtain a conjugate fiber (chop for air-laid) having a fineness of 3.3 dtex (fiber diameter of 21.5 ⁇ m).
- the conjugate fiber (staple fiber) obtained in Example 3 was processed into a fibrous web by means of the carding method, and this fibrous web was formed into a rod-like sliver.
- the fibrous web formed into a sliver was placed into a cylindrical mold (10 mm x 10 mm x 60 mm) made from a 20-mesh metallic wire having a wire diameter of 0.29 mm, which is then subjected to hot-air adhesion processing by means of a through-air processing device of hot-air circulation type under conditions with a preset temperature of 98°C, hot air velocity of 1.2 m/sec, and a processing time of 12 seconds, to obtain a cubical fiber formed article.
- the obtained fiber formed article has excellent cushioning characteristics.
- the conjugate fiber (chop for air-laid) obtained in Example 4 was processed into a fibrous web having a mass per unit area of 50 g/m 2 by means of the air-laid method, and this fibrous web was subjected to hot-air adhesion processing by using a through-air processing device of hot-air circulation type under conditions with a preset temperature of 98°C, a hot air velocity of 0.38 m/sec, and a processing time of 14 seconds.
- the obtained through-air nonwoven fabric was placed into a glass tube having an inner diameter of 8 mm, which is then immersed into boiled water and boiled for two minutes.
- the through-air nonwoven fabric was then cooled after the boiling, to obtain a cylindrical fiber formed article.
- the obtained fiber formed article is moderately soft and has less fluctuation in fiber density. Therefore, this fiber formed article is suitable for retaining fluid and the like.
- the conjugate fiber of the present invention in which the first component containing an ethylene ⁇ -olefin copolymer of a specific property and the second component containing a crystalline polypropylene form the side-by-side cross section, has low-temperature processability and low heat shrinkage percentage. Therefore, this conjugate fiber is useful in producing bulky nonwoven fabric and formed articles having excellent uniformity and excellent feeling at a heat processing temperature of 100 0 C or lower.
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Abstract
A conjugate fiber is provided, in which a first component that contains at least 75% by weight of an ethylene-α-olef in copolymer having a melting point of 70 to 1000C and a second component that contains a crystalline polypropylene forma side-by-side cross section, wherein, in a fiber cross section perpendicular to a fiber axis, the first component accounts for 55 to 90% of an outer periphery of the fiber, a borderline between the first component and the second component forms a curve bulging toward the first component, and an area ratio between the first component and the second component (first component/second component) is in a range of 70/30 to 30/70. The conjugate fiber demonstrates low-temperature processability and excellent card passability when processed into a nonwoven fabric, and can produce a bulky nonwoven fabric having excellent uniformity.
Description
DESCRIPTION
Conjugate Fiber Having Low-Temperature Processability, Nonwoven Fabric and Formed Article Using The Conjugate Fiber
Technical Field
The present invention relates to a conjugate fiber that demonstrates low-temperature processability during heat processing and excellent heat adhesiveness without shrinking significantly. The present invention also relates to a nonwoven fabric and formed article that use the conjugate fiber and have excellent bulkiness and excellent feeling. Background Art
Various conjugate fibers having low-temperature processability have conventionally been proposed, and ethylene •crolefin copolymer has been used as a component forming these conjugate fibers, for the reason that the melting point of the component can be easily controlled by using it. For example, there is proposed a sheath-core and side-by-side conjugate fiber in which a "mixture" of a polyethylene resin having a low melting point of 90 to 125°C and a polyethylene resin having a high melting point of 120 to 135°C is used as one of conjugate components (see, for example, Patent Literature l). There is also proposed a latently crimpable conjugate fiber in which a component containing an ethylene α-olefin copolymer and a component containing a polyester resin are "each" used as one of conjugate components (see, for example, Patent Literature 2). However, the conventional conjugate fibers having low-temperature processability practically have a lot of room yet to improve. The conjugate
fiber proposed in Patent Literature 1, for example, does not necessarily have sufficient low temperature processability because the polyethylene resin having a low melting point of 90 to 125°C is used and at the same time the polyethylene resin having a high melting point of 120 to 135°C is "mixed" into the abovementioned low-melting point polyethylene resin in an amount of, substantially, 30 % by weight or more in order to achieve stable productivity, and because the mixture of these polyethylene resins is used as one component of the conjugate fiber. Moreover, as described in Patent Literature 2 which relates to a latently crimpable conjugate fiber that utilizes a characteristic that the conjugate fiber containing an ethylene α- olefin copolymer as a component shrinks easily during heat processing, such a latently crimpable conjugate fiber is not suitable for obtaining a nonwoven fabric that does not shrink but has excellent uniformity. Moreover, such a latently crimpable conjugate fiber utilizes a difference in shrinkage characteristics between the plurality of constituents, and hence pealing occurs easily in these components after heat processing. When the melting adhesive component and the other non-melting component are pealed when processing the latently crimpable conjugate fiber into a nonwoven fabric, the fiber composed of the adhesive component and the fiber composed of the other non-melting component are almost mixed within the nonwoven fabric. As a result that a number of such fibers composed of the non-melting component which cannot contribute toward enhancing the nonwoven fabric generate, the strength of the nonwoven fabric cannot be exhibited.
As described above, those fibers with low-temperature processability
that hitherto have been proposed need to be improved in the low-temperature processability thereof and uniformity and strength of the obtained nonwoven fabrics.
[Patent Literature l] International Publication No. 00/36200 [Patent Literature 2] Japanese Patent Application Publication No.
2006-233381
Disclosure of the Invention
An object of the present invention is to provide a conjugate fiber, which has low-temperature processability, is prevented from shrinking, has excellent heat adhesiveness and excellent card passability when processing the conjugate fiber into a nonwoven fabric and particularly when performing card processing, and is capable of obtaining a bulky nonwoven fabric with excellent uniformity. Another object of the present invention is to provide bulky nonwoven fabric and formed article of them having excellent uniformity and excellent low-temperature processability.
As a result of keen study, the inventors have found that the above objects can be achieved by a conjugate fiber that forms a specific side-by-side cross section that has a first component containing a specific ethylene or olefin copolymer as a component for contributing to low-temperature processability of the conjugate fiber, i.e., a component having a lower melting point and softened and molten when heated, in a specific amount or more, and a second component containing a crystalline polypropylene. Therefore, the present invention is a conjugate fiber in which a first component that contains at least 75 % by weight of an ethylene α-olefin
copolymer having a melting point of 70 to 1000C and a second component that contains a crystalline polypropylene form a side-byside cross section, wherein, in a fiber cross section perpendicular to a fiber axis, the first component accounts for 55 to 90% of an outer periphery of the fiber, a borderline between the first component and the second component forms a curve bulging toward the first component, and an area ratio between the first component and the second component (first component/second component) is in a range of 70/30 to 30/70.
In an embodiment of the present invention, examples of the ethylene orolefin copolymer to be used include an ethylene -α-olefLn copolymer having a molecular weight distribution (MwMn) of 1.5 to 2.5, a density of 0.87 to 0.91 g/cm3, and a melt index (MI) of 10 to 35 g/10 min as measured under conditions with a temperature of 1900C and a load of 21.2 N based on ASTM D- 1238. The above conjugate fiber can show a heat shrinkage percentage of
50% or lower when subjected to heat processing at 1000C for five minutes.
The conjugate fiber of the present invention can be processed into a nonwoven fabric to produce a nonwoven fabric, and the conjugate fiber of the present invention can be processed or the nonwoven fabric obtained from the conjugate fiber of the present invention can be processed to obtain a shaped article.
Therefore, the present invention is also intended for a nonwoven fabric obtained by processing the conjugate fiber into a nonwoven fabric, a formed article obtained using the conjugate fiber, and a formed article obtained using the nonwoven fabric.
Examples of the processing into a nonwoven fabric include a hot-air
adhesion method and a hot-water adhesion method.
The conjugate fiber of the present invention has a side-byside cross section in which a first component containing 75 % by weight of an ethylene -crolefin copolymer having a melting point of 70 to 1000C accounts for 55 to 90% of an outer periphery of the fiber in a fiber cross section perpendicular to a fiber axis, a borderline between the first component and the second component forms a curve bulging toward the first component, and in which an area ratio between the first component and the second component (first component/second component) is in a range of 70/30 to 30/70. Because the first component containing the ethylene crolefin copolymer covers mainly the surface of the fiber, the first component shows an excellent heat adhesiveness at a heat processing temperature of 1000C or lower. Specifically, excellent low-temperature processability is obtained. Furthermore, because the second component containing a crystalline polypropylene is exposed to a part of the surface of the fiber, the second component can reduce the intensity of the surface friction particular to the ethylene xx-olefin copolymer, and can also be produced stably in a fiber manufacturing process even without adding lubricant at all or by adding a little lubricant. Particularly when performing card processing, excellent fiber passability can be obtained during the card processing.
A problem in the cross-sectional shape of a general two-component side-byside conjugate fiber having a combination of half-moon-shaped components is the pealing of the components. The side-byside cross section of the conjugate fiber of the present invention is configured such that the first component containing ethylene orolefin copolymer accounts for 55 to 90% of the length of the outer periphery, the borderline between the first
component and the second component forms a curve bulging toward the first component, and such that the area ratio between the first component and the second component (first component/second component) is in a range of 70/30 to 30/70. For this reason, pealing hardly occurs between the components, and preferable workability can be exerted in, particularly, the card processing, without impairing the fiber passability obtained during the card processing and the intensity of the nonwoven fabric obtained after processing the conjugate fiber into a nonwoven fabric. Moreover, although the cross-sectional shape of the general two-component side-by-side conjugate fiber having a combination of half-moon-shaped components shrinks easily when subjected to heat processing, it is considered that the conjugate fiber of the present invention can effectively prevent shrinkage by adopting a specific fiber cross-sectional shape with a specific ethylene α-olefin copolymer used as the first component. The nonwoven fabric obtained using the conjugate fiber of the present invention is bulky and soft, has less width reduction (reduction of the width in relation to a direction of flow of the nonwoven fabric) due to small shrinkage when subjected to heat processing, hence excellent productivity and excellent uniformity can be achieved. Moreover, because the conjugate fiber of the present invention has, as an effective component, a component that contains an ethylene crolefin copolymer having a melting point of 70 to 1000C, heat processing can be performed thereon at 1000C or lower. Therefore, when processing the conjugate fiber of the present invention into a nonwoven fabric or a formed article, a medium such as steam and hot water also can be used so that appropriate conditions for obtaining a nonwoven fabric or a formed article can be selected from a wide
range of choice in accordance with the use application, environment and circumstances.
Brief Description of Drawings
[Fig. l] A schematic diagram showing an example of the side-by-side cross-sectional shape of a conjugate fiber of the present invention. Best Mode for Carrying Out the Invention
The conjugate fiber of the present invention has a first component containing an ethylene α olefin copolymer. This ethylene α-olefϊn copolymer comprises ethylene and α-olefin units. Examples of the α-olefin include, specifically, linear α-olefins such as propylene, butene-1, pentene-1, hexene-1, heptene-1, and octene-1. Butene-1 and octene l are preferred but octene l is more preferred. The α-olefin content of the ethylene α-olefin copolymer is preferably 30 mol% or less and more preferably 20 mol% or less. The α-olefin content is normally 1 mol% or more. The content in this case is expressed in molar ratio percentage ((α-olefin)/(α-olefin + ethylene)). Excessive α-olefin content delays solidification during the fiber manufacturing process and causes fusion between fibers and thereby a possible damage the productivity. When the α-olefin content is 30 mol% or less, sufficient rigidity of the fiber can be obtained and, particularly when performing card processing, excellent fiber passability can be obtained during the card processing.
The melting point of the ethylene α-olefin copolymer to be used is 70 to 1000C, and preferably 80 to 1000C. The melting point of at least 70 0C can prevent fusion between fibers, and, for example, when drying an antistatic agent or other treatment agent applied to the surface of the fiber during the fiber manufacturing process, fusion between the fibers can be
prevented and excellent productivity can be exerted. Furthermore, when the melting point of 1000C or lower, not only is it possible to set the temperature for processing the fiber into a nonwoven fabric or a formed article at 1000C or lower, but also a medium such as steam and hot water can be used for heat processing, and a processing method in which a comparatively low-temperature medium is used can be selected. In addition, this 1000C or less melting point is preferred as it is not necessary to concern about the influence on other components of the fiber that are essentially not molten. The melting point described here is a melting peak temperature that is obtained when the ethylene crolefin copolymer is measured using a differential scanning calorimeter (DSC). When a plurality of melting peaks are confirmed the temperature of the largest melting peak is taken as the melting point, and when a plurality of close melting peaks are confirmed the lower temperature of those is taken as the melting point.
The molecular weight distribution (Mw/Mn), which is the ratio between the weight- average molecular weight (Mw) of the ethylene α-olefin copolymer and the number average molecular weight (Mn), is preferably 1.5 to 2.5 and more preferably 1.7 to 2.3. When the molecular weight distribution (Mw/Mn) is in a range of 1.5 to 2.5, excellent spinnability is obtained in the fiber manufacturing process, and thus this molecular weight distribution is preferred in terms of the fabric property in order to obtain a strong conjugate fiber.
The density of the ethylene α olefin copolymer is preferably 0.87 to 0.91 g/cm3 and particularly preferably 0.88 to 0.90 g/cm3. When the density of the ethylene α olefin copolymer is at least 0.87 g/cm3, appropriate surface
viscosity can be obtained when processing the copolymer into a fiber, and agglutination hardly occurs during fiber manufacture. Therefore, this density is suitable for using the ethylene crolefin copolymer as a main component of the fiber. When, on the other hand, the density is 0.91 g/cm3 or lower, the melting point of the ethylene orolefin copolymer is comparatively as low as 1000C or lower, and thus this ethylene α-olefin copolymer is suitable as the ethylene crolefin copolymer to be used in the present invention.
The melt index (MI) of the ethylene α-olefin copolymer is preferably 10 to 35 g/10 min and more preferably 15 to 30 g/10 min in consideration of achieving stable production during the fiber manufacturing process. The MI described here is a value that is measured under conditions with a temperature of 1900C and a load of 21.2 N based on ASTM D- 1238.
The ethylene xx-olefin copolymer to be used may be a mixture of one kind or two or more types.
Variety of additives can be compounded into the ethylene crolefin copolymer used in the present invention. Preferred examples of the additives include lubricant, heat-resistant stabilizer, antioxidant, weatherproof stabilizer, antistatic agent, colorant and the like. Preferred used as a lubricant includes fatty acid amides such as oleic amide and erucic acid amide, fatty acid esters such as butyl stearate, polyolefin waxes such as polyethylene wax and polypropylene wax, and metallic soap such as calcium stearate, and the like. More preferred examples include fatty acid amides such as oleic amide, erucic acid amide, stearic acid amide, behen acid amide and the like.
The first component contained in the conjugate fiber of the present
invention needs to include the abovementioned ethylene α-olefin copolymer in an effective amount so as to be involved in heat adhesion at low temperature and so that steam or hot water can be used as a heat medium particularly when processing the conjugate fiber into a nonwoven fabric or performing the processing of formed article. The ethylene -αrolefin copolymer content is preferably at least 75%, or more preferably at least 85% in relation to the weight of the first component, and particularly preferably 100% as a resin raw material. It is preferred that the ethylene α-olefin copolymer be at least 75% in the first component so that the performance of the ethylene α-olefin copolymer can be realized subjectively.
For example, low-density polyethylene, high-density polyethylene, ethylene vinyl acetate copolymer, propylene copolymer and the like can be the resin raw materials that the first component may contain in addition to the ethylene crolefin copolymer under the condition that at least 75% of the ethylene crolefin copolymer is contained in relation to the weight of the first component. A method for uniformly mixing the resins and using them or a method for inserting the other resin from a feed port provided on the way of kneading process where the ethylene -cr olefin copolymer has been kneaded and already is in molten state.
The conjugate fiber of the present invention contains a crystalline polypropylene as the second component. This crystalline polypropylene is a propylene homopolymer or a copolymer of propylene and a small amount of α-olefin (normally 2 % by weight or less), and examples of such a crystalline polypropylene include a general-purpose polypropylene that is obtained by using a Ziegler-Natta catalyst or a metallocene catalyst.
The crystalline polypropylene of the present invention preferably has a melting point of 150 to 165°C and more preferably 155 to 165°C, and preferably has a melt mass flow rate (MFR = 2300C, 21.2N) in a range of 0.1 to 80 g/10 min and more preferably 3 to 40 g/10 min. As the second component forming the conjugate fiber of the present invention, which contains the crystalline polypropylene, a mixture of the crystalline polypropylene and propylene α olefin copolymer, or a mixture of crystalline polypropylenes having different properties such as the melt mass flow rate (MFR) and molecular weight distribution (Mw/Mn) can be used suitably as long as the effect of the conjugate fiber is not damaged significantly. Moreover, it is not a problem to compound other thermoplastic resin, inorganic substances such as titanium dioxide, calcium carbonate and magnesium hydroxide, or various additives (fire-retardant, heat-resistant stabilizer, antioxidant, weatherproof stabilizer, antistatic agent, colorant and the like). It is appropriate that at least 75 % by weight of the crystalline polypropylene is generally contained in the second component forming the conjugate fiber of the present invention.
In the conjugate fiber of the present invention, the first component containing the ethylene crolefin copolymer and the second component containing the crystalline polypropylene form a side-by-side cross section having a specific structure.
In the fiber cross section perpendicular to a fiber axis, the first component containing the ethylene •α-olefin copolymer accounts for 55 to 90% of an outer periphery of the fiber, and the second component containing the crystalline polypropylene accounts for 45 to 10% of the same. Because the first component containing a specific ethylene α-olefin copolymer
accounts for 55% or more of the outer periphery of the fiber, heat processing can be performed at 1000C or lower. Also, because the second component containing the crystalline polypropylene accounts for 10% or more of the outer periphery of the fiber, the crystalline polypropylene continuously appear on the fiber, not only is it possible to reduce the friction between fibers or friction to a metal but also viscosity that occurs when the ethylene α olefin copolymer is used on the surface of the fiber, and excellent spinnability and card processability can be obtained when performing the card processing. It is particularly preferred that the first component containing the ethylene crolefin copolymer account for 60 to 80% of the outer periphery of the fiber and that the second component containing the crystalline polypropylene account for 40 to 20% of the same.
In the fiber cross section perpendicular to the fiber axis in the conjugate fiber of the present invention, the borderline between the first component and the second component forms a curve bulging toward the first component. By providing the conjugate fiber with this structure, the borderline between the first component and the second component becomes longer compared to the conjugate fiber having a general side-by-side cross-sectional structure where half-moon-shaped components are joined together. Specifically, the joint area between the both components is increased and, by providing the conjugate fiber of the present invention with a structure where the first component wraps the second component, the second component can be prevented from being released from this conjugate fiber. Suppose that two intersections of the outer periphery of the fiber and the borderline between the first component and the second component
are taken as point a and point b, the borderline forming a curve bulging toward the first component, and that a point where the segment ab is halved is taken as point c, and a point where the borderline between the first component and the second component intersects with a straight line that extends in a direction perpendicular to a line ab through point c is taken as point d, and a point where said straight line that extends in a direction perpendicular to a line ab through point c intersects with the outer periphery of the fiber on the second component side as point e. It is particularly preferred that the fiber cross section perpendicular to the fiber axis has a structure where the borderline forms a curve bulging toward the first component such that the relationship between the length of a segment cd and a segment ce satisfy a relationship of cd ≥ 0.8 ce. When satisfying the relationship of cd ≥ ce, more preferably cd ≥ 1.5 ce, or particularly preferably cd ≥ 2ce, excellent un-releasability between the conjugate components and heat shrinkability are obtained when performing heat processing and forming processing.
Furthermore, when the borderline between the first component and the second component that forms a curve bulging toward the first component is considered to take up a part of the outer periphery of a circle or an ellipse formed by an outer periphery of the second component, it is preferred that the length (g) of the borderline exceed 50% or more preferably at least 60% of the entire outer peripheral length (h) of the circle or ellipse formed by the second component. Especially when both ends of the diameter or long axis of the circle or ellipse formed by the second component exists within the fiber cross section perpendicular to the fiber axis of the conjugate fiber, and when the length of the diameter or long axis is f, a
conjugate structure where the second component produces an anchoring function against the first component can be formed in the case where the relationship between the f and the length of the segment ab satisfies f > ab, the segment ab obtained by the two intersections point a and point b where the borderline between the first component and the second component intersect with the outer periphery of the fiber. Therefore, the effect of preventing the second component from being released can be enhanced extremely effectively.
It is preferred that the ratio between the two components that form the conjugate fiber of the present invention be, in the fiber cross section perpendicular to the fiber axis, first component/second component = 70/30 to 30/70, in order to maintain the configuration of the cross section to obtain stability during fiber manufacture and a balance between the strength and degree of elongation that is obtained when processing the conjugate fiber into a nonwoven fabric. More preferably, the ratio is 60/40 to 40/60.
The conjugate fiber of the present invention can be manufactured using a conventionally known side-by-side conjugate spinneret. The conjugate fiber of the present invention can be manufactured using a side-byside conjugate spinneret, for example, Japanese Patent Application Publication S48- 11417 or Japanese Patent Application Publication S52-74011.
In order to form the cross-sectional shape of the conjugate fiber of the present invention by using the side-byside spinneret, it is necessary to obtain a balance in the flowability (viscosity or the like) of the molten first component containing the ethylene crolefin copolymer and the molten second component containing the crystalline polypropylene, and the
flowability is adjusted under a fiber manufacturing condition in consideration of the melt index (MI) and melt mass flow rate (MFR) of these two components. For example, for the first component containing the ethylene crolefin copolymer, the flowability (viscosity) thereof that is measured when melting it at some temperature selected in the range about 1900C, and a temperature range in which the flowability (viscosity) enabling the fiber to be manufactured is selected based on fluctuation of melt flowability (melt viscosity) to obtain an extrusion temperature as the fiber manufacturing condition. Similarly, for the second component containing the crystalline polypropylene, when the flowability (viscosity) thereof is measured by melting the second component at about 2300C, to select an extrusion temperature. When selecting an extrusion temperature such that the melt flowability (melt viscosity) of the first component is relatively greater than the melt flowability (melt viscosity) of the second component, and when extruding both components with the pressure, the proportion of the first component covering the peripheral surface of the fiber relatively increases. For example, the cross -sectional configuration of the conjugate fiber of the present invention can be formed easily when the ratio of the melt index (MI) of the first component to the melt mass flow rate (MFR) of the second component is 1.5 to 3 times, although it is not possible to say definitely because temperature dependence of the flowability (uptrend of viscosity) varies depending on the resins used. More preferably, this ratio is in a range of 1.8 to 2.5. The larger this ratio, the easier to obtain the configuration where the first component wraps the second component, thus the proportion of the second component taking up the outer periphery of the fiber is reduced. Also, by changing the ratio of discharging amount of both
components, the proportions of the first component and the second component on the fiber cross section in relation to the outer periphery of the fiber can be increased or decreased even if the extrusion temperature and the melt viscosity are not changed. This means that the area ratio between the components on the fiber cross section perpendicular to the fiber axis is changed, and thus, for example, when the area ratio of the second component taking up the cross section perpendicular to the fiber axis is relatively high, the proportion of the second component in relation to the outer periphery of the fiber increases easily under the same manufacturing condition.
When manufacturing the conjugate fiber of the present invention, it is possible to adopt a normal melt spinning method with selection of such the extrusion temperature or resin discharge amount as the above.
A treatment agent may be applied to a surface of the conjugate fiber of the present invention in order to improve processing stability when manufacturing the fiber. The treatment agent is mainly an antistatic agent, but is also a hydrophilic agent capable of improving wettability of the surface of the fiber. Examples of the components of these antistatic agent and hydrophilic agent include alkyl phosphate, ethylene oxide adduct thereof, sorbitan fatty acid ester ethylene oxide adduct, polyglycerol fatty acid ester, polyoxy ethylene modified silicone and the like. A single component selected from these components or a mixture of any of the components is used as the treatment agent.
The heat shrinkage percentage of the conjugate fiber of the present invention that is obtained when heat-processing the conjugate fiber at 1000C for five minutes is 50% or lower, preferably 30% or lower, and more
preferably 20% or lower.
The heat shrinkage percentage described here, which is expressed in percentage (%), is a difference in size (reduced amount) between the conjugate fibers that are and are not subjected to heat processing, the conjugate fibers being obtained by inserting the conjugate fiber of the present invention, staple fiber, into a card machine, cutting the fibrous web that is thus extracted from a card outlet (the web is in the form of a sheet with entangled fibers) into a certain shape, and then performing the heat processing thereon at 1000C for five minutes. Specifically, the heat shrinkage percentage of the present invention is obtained by cutting the conjugate fiber of the present invention into any length such as 30 to 65 mm to obtain a staple fiber, and inserting this staple fiber into a miniature card machine to create a fibrous web having a mass per unit area of 200 g/m2. This fibrous web is cut along a pattern of 250 mm x 250 mm in a flow direction (MD) of the fiber and a direction perpendicular to this flow direction (CD). This fibrous web is left stand for ten minutes, thereafter the length of the MD of this cut fibrous web is measured immediately before performing the heat processing, and then the fibrous web is subjected to the heat processing in a circulating hot air oven at 1000C for five minutes. After the heat processing, the length of MD is measured again, and the value of the heat shrinkage percentage is obtained by the following equation.
Heat Shrinkage Percentage (%) = {(Lo - OfL0) x 100 Lo: The length of MD before the heat processing L- The length of MD after the heat processing
Here, the lower this value, the smaller the shrinkage of the fibrous
web when processing the conjugate fiber into a nonwoven fabric, hence stable processing can be performed and a nonwoven fabric with excellent uniformity can be obtained.
Note that conditions for measuring the heat shrinkage described here are not specified/limited to the conditions for processing the conjugate fiber of the present invention, the heat processing conditions, the conditions for processing the conjugate fiber into a nonwoven fabric, and usage of the conjugate fiber.
In a conjugate fiber that has a conventionally known side-by-side cross -sectional structure, crimps are generated easily during the heat processing for manufacturing the fiber, due to the cross-sectional structure of the conjugate fiber and the resin configuration thereof, hence, as a result, the effect of improving bulkiness of the fiber can be exerted. Particularly, as in the fibrous web for use in processing the conjugate fiber into a nonwoven fabric, the fibrous web being an assembly of fibers that are cut into a predetermined length to process the conjugate fiber into a nonwoven fabric, when performing the heat processing, the fiber itself shrinks easily, because of existing freely each other in the web. Therefore, although bulkiness was realized when the fibrous web was obtained, the fiber would shrink significantly after processing the fiber into a nonwoven fabric, and consequently the realized bulkiness could not be maintained. Moreover, although various things were tried in order to obtain uniform mass per unit area of the fibrous web, weight unevenness cannot be eliminated completely and the freedom of the fiber within the fibrous web ranges slightly variously. Therefore, the part having higher freedom tends to shrink easily when performing the heat processing to process the conjugate fiber into a
non woven fabric. For this reason, the part that shrinks easily pulls and gathers the fibers existing in the surroundings to form a clump, and the part that has lost fibers due to this gathering is reduced in mass per unit area, whereby weight unevenness becomes extremely noticeable in the entire nonwoven fabric, making it difficult to obtain a nonwoven fabric having excellent uniformity.
On the other hand, the conjugate fiber of the present invention has the side-by-side cross-sectional structure composed of two components, but has a cross-sectional shape in which the first component containing the ethylene α-olefin copolymer accounts for 55 to 90% of the outer periphery of the fiber and wraps the second component containing the crystalline polypropylene. Moreover, by using an ethylene orolefin copolymer having a melting point of 70 to 1000C, or preferably an ethylene •crolefin copolymer having a molecular weight distribution (Mw/Mn) of 1.5 to 2.5, a density of 0.87 to 0.91 g/cm3, and a melt index (MI) of 10 to 35 g/10 min, shrinkage properties obtained during the heat processing can be retained at 50% or lower where the processing into a nonwoven fabric and the processing into a formed article can be stably performed, while taking the advantage of the bulk improving effect obtained from latent crimps by adopting the side-by-side cross-sectional structure.
It is unknown as to why such an excellent shrinkage retaining mechanism can be realized by the conjugate fiber of the present invention that has a combination of a specific resin structure and a specific conjugate structure. It is unexpected that, while surprisingly preventing shrinkage by using the specific ethylene crolefin copolymer and combining it with the crystalline polypropylene to obtain a fiber that further has a specific fiber
cross-sectional configuration, it is possible to obtain a nonwoven fabric that has excellent bulkiness, which is generally considered to be a conflicting performance, excellent feeling, and excellent heat processing properties at a low temperature of 1000C. The fineness of the conjugate fiber of the present invention is not particularly limited. A conjugate fiber that is suitably processed into a nonwoven fabric or formed article may be selected in consideration of the properties of the components forming the conjugate fiber and of processing stability when manufacturing the fiber. For example, a fiber having a fineness of 1 to 5 dtex is preferably selected when using the conjugate fiber in a powder puff or a medicine sheet that comes into direct contact with a human skin. A fiber having a fineness of 1 to 10 dtex is suitable for use in a liquid retaining material such as an ink cartridge of a printer. In addition, a fiber having a fineness of 1 to 20 dtex is suitable for use in a liquid volatizing material such as an aromatic substance core of home fragrance.
The length of the conjugate fiber of the present invention is not particularly limited, and hence may be long or short. When cutting into a short fiber, the cut length can be appropriately selected in accordance with the fineness of the conjugate fiber, the method of processing the conjugate fiber, and the use application of the conjugate fiber. When the staple fiber is subjected to the card processing, it is preferred that the staple fiber be cut into 20 to 125 mm. In order to obtain excellent card passability and uniformity of the fibrous web, it is preferred that the staple fiber be cut into 25 to 75 mm. Moreover, when processing the conjugate fiber of the present invention into nonwoven fabric by using an air-laid method, it is preferred
that the conjugate fiber be chopped into 3 to 25 mm with the air-laid method.
The conjugate fiber of the present invention preferably has crimps in order to spread the fiber bundle and obtain a bulky fibrous web and nonwoven fabric. The number of crimps to be obtained or the type of crimps can be selected appropriately in accordance with the fineness and cut length of the conjugate fiber, the method for processing the conjugate fiber, and the use application of the conjugate fiber. For example, when a conjugate fiber (staple fiber) having a fineness of 3.3 to 6.6 dtex and a cut length of 38 to 45 mm is processed into a fibrous web by a carding method, it is preferred that the number of crimps be 10 to 25 peaks/25 mm. When a conjugate fiber (chop for air-laid method) having a fineness of 3.3 to 6.6 dtex and a cut length of 3 to 6 mm is processed into a fibrous web by the air-laid method, it is preferred that the number of crimps be 5 to 15 peaks/25 mm. The crimps can be, for example, in a zigzag shape or a spiral structure.
In order to process the conjugate fiber of the present invention into a nonwoven fabric, preferably the fibrous web is formed first, the heat processing is performed thereon, and then the method for processing into a nonwoven fabric is used. Examples of a fibrous web formation method include a carding method for passing a card machine and an air-laid method for inserting fibers into a cylindrical drum provided with a slit and accumulating the fibers on a belt conveyor by rotating the drum, but the fibrous web formation method is not limited to these methods. When using these formation methods, other fibers can be blended as long as the effects of the present invention are not impaired significantly. Examples of the fibers that can be blended include rayon and cotton for improving the water
retention ability, polyethylene terephthalate for making an obtained nonwoven fabric bulkier, and other hollow fibers.
In order to heat-process a fibrous web into a nonwoven fabric after forming this fibrous web having a desired mass per unit area by means of these fibrous web formation method, a span lace method or a needle punching method for etangling the fibers within the fibrous web by means of a water stream, compressed air, a needle or the like can be used before performing the heat processing, to improve the strength of the fibrous web and change the feeling. Examples of the heat processing method include a hot-air adhesion method, a hot-water adhesion method, hot-roll adhesion method and the like. Above all, the hot-air adhesion method or the hot- water adhesion method is preferred as the heat processing method to be performed after forming the conjugate fiber of the present invention into the fibrous web. The hot-air adhesion method is a method for softening and melting a low-melting point component of the conjugate fiber by passing heated air through the fibrous web and adhering the fibers at their contact point. Because this adhesion method does not impair the bulkiness by compressing a certain area unlike the hot-roll adhesion method, this adhesion method is suitable for providing a bulky nonwoven fabric having excellent uniformity and excellent feeling, which is the object of the present invention.
This hot- air adhesion method is suitable for obtaining a bulky nonwoven fabric having excellent feeling. Therefore, particularly when the hot-air adhesion method is used to heat-process a conjugate fibrous web that has short fibers each having a general side-by-side cross section with two half-moon-shaped components, large shrinkage occur easily compared to
when other adhesion methods are used, due to high freedom of the fibrous web on the conveyor, and thus a nonwoven fabric with excellent uniformity and excellent feeling cannot be obtained easily. The conjugate fiber of the present invention, on the other hand, is designed to effectively prevent shrinkage caused by heat-processing the conjugate fiber into a nonwoven fabric, and thus can be used suitably in this hot-air adhesion method in particular. Therefore, the conjugate fiber of the present invention can provide a nonwoven fabric having an excellent feeling, while keeping the advantage of bulkiness that is essentially provided by the hot- air adhesion method.
The hot-water adhesion method is a method for softening and melting a low-melting point component of the conjugate fiber by passing heated water or steam through the fibrous web and adhering the fibers at their contact point. In the conjugate fiber of the present invention, because the first component containing the ethylene α-olefin copolymer having a melting point of 70 to 1000C accounts for the majority of the peripheral surface of the fiber, a hot-water adhesion method that performs the heat processing at 1000C or lower can be essentially applied. Hot water, steam or other comparatively inexpensive medium that does not require any special equipment is used in this adhesion method. By performing the processing with such a medium, most treatment agent applied onto the surface of the conjugate fiber of the present invention can be washed away while processing the conjugate fiber into a nonwoven fabric. The treatment agent applied onto the surface of the fiber is essential in the conjugate fiber (staple fiber, chop for air-laid method and the like) manufacturing process, but is not necessary or is rather an obstruction after processing the fiber
into a nonwoven fabric or formed article, depending on the use application. Examples of said use application include a food protection sheet such as a packing material and a plastic tray that come into direct contact with food, a powder puff impregnated in a cosmetic item, and a stick for applying a medical agent to an affected part of the body. There is also a method for configuring the treatment agent of the fiber surface by selecting a safe element such as a food additive or a corresponding component, or a method for performing cleansing to wash away the treatment agent after forming the fiber into a nonwoven fabric or formed article. However, configuring the treatment agent using a human-friendly component does not eliminate the effect of the treatment agent on the cosmetic item or medical agent, and thus it is desired that the treatment agent does not remain on the nonwoven fabric or formed article in order to keep the stable performance. Furthermore, performing the cleansing after processing the fiber into a nonwoven fabric or formed article requires equipment and time and thus is disadvantageous in terms of cost.
Therefore, the conjugate fiber of the present invention in which the hot-water adhesion method can be adopted is industrially very significant because the present invention can efficiently provide, for the abovementioned use application and at low cost, a bulky nonwoven fabric or formed article that has almost no treatment agent thereon or on which the amount of the treatment agent attached to the fiber is so small that it does not cause the above problems. It is most preferred that the conjugate fiber of the present invention be processed into a nonwoven fabric or formed article by means of the hot-water adhesion method, or that a heat-processed nonwoven fabric obtained by the hot-air adhesion method be processed into
a formed article by means of the hot- water adhesion method.
The mass per unit area of the nonwoven fabric that is obtained when processing the conjugate fiber of the present invention into a nonwoven fabric can be appropriately selected based on the purpose of use. For example, the mass per unit area is preferably in a range of 20 to 5Q^g/m2 for a food packing material, 30 to 150 g/m2 for a powder puff or a medicine sheet, and 50 to 250 g/m2 for a stick for applying a medical agent.
Moreover, the bulkiness of the nonwoven fabric that is obtained when processing the conjugate fiber of the present invention into a nonwoven fabric can be calculated based on a specific volume and can be easily at least 20 cm3/g, or preferably at least 30 cm3/g.
When the conjugate fiber of the present invention is processed into a nonwoven fabric, another nonwoven fabric, a fibrous web, thermoplastic film, sheet or the like may be stacked on this nonwoven fabric, depending on the purpose. For example, a breathable film, a porous film, a porous nonwoven fabric may be laminated to the nonwoven fabric, an elastic nonwoven fabric composed of elastomer or other ethylene -crolefin copolymer may be stacked on the nonwoven fabric.
In the present invention, "formed article" means a finished product that is obtained using the conjugate fiber of the present invention without processing the conjugate fiber into a nonwoven fabric, and a finished product that is obtained by processing the conjugate fiber into a nonwoven fabric. When obtaining the formed article without processing the conjugate fiber into a nonwoven fabric, a fibrous web of a desired mass per unit area that is obtained by the carding method or the like can be formed into a sliver, which is then placed in a specific mold and subjected to heat processing,
whereby the "formed article" can be obtained. When obtaining the formed article by processing the conjugate fiber into a nonwoven fabric, the conjugate fiber of the present invention is formed into fibrous webs of a desired mass per unit area by means of the carding method or air-laid method or the like, which are then processed into a nonwoven fabric by means of the hot-air adhesion method or the like. Thus obtained nonwoven fabrics are stacked, cut or combined to have a desired mass per unit area and thickness, and the resulting fabric can be integrated into the "formed article" by means of the hot-air adhesion method or hot- water adhesion method. In addition, after the conjugate fiber of the present invention is processed into a nonwoven fabric, the obtained nonwoven fabric can be stacked, cut or combined to have a desired mass per unit area and thickness, which is then placed in a specific mold and subjected to heat processing, whereby the "formed article" can be obtained. Additional processing can be easily performed on the "formed article" obtained using the conjugate fiber of the present invention, for example, by cutting a part of the formed article or heat -processing the formed article.
The conjugate fiber of the present invention can be suitably used for use applications as a powder puff, medicine sheet, a sheet for cooling fever, a food plastic tray, a cushion material, a buffer material, an aromatic substance core of home fragrance, a liquid retaining material such as a humidifier, a nursery sheet, a wiper, and the like. [Examples]
Next, the present invention is described specifically by using examples and comparative examples, but the present invention is not limited to the following examples. Note that the terms and measuring
methods used in the present specification, particularly the examples and comparative examples, and the following tables 1 to 3 are defined as follows.
(1) Melt Index
MI: Measurement was performed under conditions with a temperature of 1900C and a load of 21.2 N based on ASTM D- 1238.
Note that the numeric values shown in the tables are the results of measuring a resin. (Unit: g/min)
(2) Density
Measurement was performed based on JIS K7112. Note that the numeric values shown in the tables are the results of measuring the resin. (Unit: g/cm3)
(3) Molecular Weight Distribution (MwMn)
The ratio between weight- average molecular weight and number average molecular weight, which is obtained by means of a gel permeation chromatography. Measurement was performed using "GPC- 150C" produced by Waters. (Column: One TSKgel GMHβ-HT produced by Tosoh
Corporation, 7.5 cm LD. x 60 cm)
Note that the numeric values shown in the tables are the results of measuring a raw material resin. (4) Melting Point
The temperature at which the resin melts, measured by means of a differential scanning calorimeter (DSC). (Unit: 0C)
Measurement was performed using DSC "Q- 10" produced by TA
Instruments. The resin was cut to have a weight of 4.20 to 4.80 mg, which is then put into a sample pan and a cover is placed thereon. Measurement was performed thereon at a rate of temperature increase 10 °C/min in an N2
purge between 30°C to 2000C, to obtain a melt chart. The chart was analyzed to obtain a melting peak temperature.
(5) Melt Mass Flow Rate (MFR)
Measurement was performed under conditions with a temperature of 2300C and a load of 21.2 N based on JIS K7210.
Note that the numeric values shown in the tables are the results of measuring the raw material resin. (Unit: g/min)
(6) Fineness, Fiber Diameter
The thickness of a fiber, calculated from the weight per length. (Unit: dtex)
When each fiber is longer than 60 mm, a bundle of fibers is cut into 60 mm, and the weight of 150 cut fibers was measured using "AEL-40SM," an electronic balance produced by Shimadzu Corporation. The obtained numeric value was multiplied by 1111 to obtain fineness of the resulting fibers. When the length of the fibers was not sufficient, the fibers were observed through a scanning electron microscope. One hundred fibers were selected from the obtained image, and the diameter of each fiber was measured. The fineness was calculated from the average value of the diameters and the specific gravity of the fibers. (7) Proportion of the first component to the length of the outer periphery of the fiber cross section, observation of cross-sectional shape
Results obtained were: the proportion (%) of the first component to the length of the outer periphery of the fiber in the fiber cross section perpendicular to the fiber axis," the ratio of the length of a fiber cd to the length of a fiber ce (cd/ce) when supposing that two intersections of the outer periphery of the fiber and the borderline between the first component
and the second component are taken as point a and point b, the borderline forming a curve bulging toward the first component, and that a point where the segment ab is halved is taken as point c, and a point where the borderline between the first component and the second component intersects with a straight line that extends in a direction perpendicular to a line ab through point c is taken as point d, and a point where said straight bine that extends in a direction perpendicular to a line ab through point c intersects with the outer periphery of the fiber on the second component side as point e; the ratio of the length g of the borderline to the entire outer peripheral length h (g/h) of a circle or an ellipse formed by the second component, when the borderline between the first component and the second component that forms a curve bulging toward the first component is considered to take up a part of the outer periphery of the circle or ellipse formed by the outer periphery of the second component; and a relationship between the length f of the diameter or long axis of the circle or ellipse and the length of the segment ab when both ends of the diameter or long axis of the circle or ellipse formed by the second component exists within the fiber cross section perpendicular to the fiber axis of the conjugate fiber. The conjugate fiber was cut so as to be perpendicular to the length direction, and thus obtained fibers were observed through an optical microscope or a scanning electron microscope, whereby the above results were obtained.
Observation was performed using an optical microscope produced by NIKON Corporation or a scanning electron microscope, "JSM-T220," produced by Jeol Datum. The length of each part where each component is exposed to the fiber surface was measured from the obtained image and calculated from the following equation. Note that the first component of
the second component can be distinguished in the fiber cross section by heat processing the fiber after cutting it so as to be perpendicular to the length direction. For example, the cut fiber is left stand in an oven dryer heated at 100 0C, and the first component is then softened, molten, and observed through the optical microscope or scanning electron microscope to check which part of the fiber cross section corresponds to the first component. Length of peripheral surface of first component (%) = OU/L) x 100 L1: Length of peripheral surface of first component h' Entire length of peripheral surface of fiber cross section (8) Heat shrinkage percentage
A change (reduction rate) in length per unit of the fibrous web obtained after performing the heat treatment, calculated from the ratio between change amount and unit length. (Unit: %)
The fibrous web of 200 g/m2 that was inserted into a miniature card machine was cut along a pattern of 250 mm x 250 mm in a flow direction
(MD) of the fiber and a direction perpendicular to this flow direction (CD).
The obtained fiber was left stand for ten minutes, and then the cut fibrous webs were placed on a piece of craft paper (350 mm x 700 mm) to measure the length thereof in MD. Subsequently, the craft paper was folded into two to slightly cover the top of the fibrous webs, which is then put into a
100-degree convection oven (circulating hot air oven) produced by SANYO
Electric Co., Ltd., to heat process it for five minutes. The processed product was taken out from the dryer and cooled at room temperature for five minutes, and the length thereof in MD was measured. The heat shrinkage percentage was calculated based on the following equation.
Heat shrinkage percentage (%) = {(Lo - L)/Lo} x 100
Lo: Length of MD before heat processing L- Length of MD after heat processing
(9) Mass per unit area
The weight per unit area of the nonwoven fabric and fibrous web, calculated from the weight of the nonwoven fabric or fibrous web cut into a certain area. (Unit: g/m2)
The weight of the nonwoven fabric that was cut into 250 mm x 250 mm was measured by ΗF-200," an electronic scale balance produced by A&D Company. The obtained numeric value was multiplied by 16 to calculate the mass per unit area.
(10) Bulkiness (specific volume)
The weight per unit volume of the nonwoven fabric, calculated according to mass per unit area measurement and thickness measurement. (Unit: cm3/g) The thickness of the nonwoven fabric was measured using
"Digi Thickness Tester" produced by Toyo Seiki Seisaku-Sho, Ltd., under conditions with an anvil load of 2g/cm2 and a speed of 2 mm/sec, and calculated from the obtained numeric value (mm) and mass per unit area (g/m2). (11) Feeling
The uniformity of the appearance, softness by hand touch, stiffness, bulging and the like of the nonwoven fabric were determined comprehensively.
These were determined based on a sensory evaluation performed by trialists on a scale of "good," "fair," and "bad."
Hereinafter, Examples 1 to 6 and Comparative Examples 1 to 6 are
described and the results thereof are shown in Tables 1 to 3. [Example l]
The first component was an ethylene -α-olefin copolymer polymerized using a metallocene catalyst, wherein α-olefin was octene- 1 and contained in the copolymer in an amount of 10 mol%. The density was 0.880, the melting point 72°C, the melt index (MI) 18 g/10 min, and the molecular weight distribution (MwMn) 1.9. The second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 8 g/10 min and a melting point of 1600C. Melt spinning was performed on these two components by means of a side-by-side conjugate spinneret at a volume ratio of first component/second component = 50/50 under conditions with an extrusion temperature (preset temperature) on the first component of 2000C and 2600C on the second component side. At the time of pulling up, an antistatic agent that has ethylene oxide additives of sorbitan fatty acid ester and lauryl phosphate potassium salt as the main components is attached to these components. Good spinnability was obtained. Thus obtained spun conjugate filament having a fineness of 6.5 dtex was drawn 1.7 times by using a 55°C heating device provided with a heating roll, and crimped by means of a crimping device. Thereafter, the filament was cut into 38 mm to obtain a conjugate fiber (staple fiber) having a fineness of 4.4 dtex (fiber diameter of 25.2 μm).
The density, melting point, melt index (MI), and molecular weight distribution (MwMn) of the first component were measured using the measuring methods of (l) to (4) described above. The melting point and melt mass flow rate (MFR) of the second component were measured using
the measuring methods of (4) and (5) described above. The results are shown in the section corresponding to components on Table 1. The obtained conjugate fiber (staple fiber) was measured using the measuring methods of (6) and (7) described above. The results are shown in the section corresponding to yarn quality on Table 1 along with schematic diagrams. Peeling of the components was not observed in the fiber cross section in the direction perpendicular to the fiber axis. Moreover, cd/ce = 7.5, f > ab, and g/h = 0.80. lOOg of the obtained conjugate fiber (staple fiber) was inserted into a 500mm-wide miniature card machine to form a fibrous web. The fiber passability was good during the card processing. The heat shrinkage percentage of this fibrous web was measured using the measuring method of (8) described above. The results are shown in the section corresponding to yarn quality on Table 1. 5Og of the obtained conjugate fiber (staple fiber) were inserted into a 500mm wide miniature card machine to form a fibrous web. This fibrous web was processed using a through-air processing device of hot-air circulation type under conditions with a preset temperature of 98°C, a hot air velocity of 0.8 m/sec, and a processing time of 12 seconds. The property of thus obtained through-air nonwoven fabric was measured and evaluated using the measuring methods of (9) to (ll) described above. The results are shown in the section corresponding to nonwoven fabric property on Table 1.
Because the heat shrinkage percentage of the fibrous web in which the obtained conjugate fiber (staple fiber) is used was as low as 15%, a bulky nonwoven fabric with excellent uniformity and excellent feeling was obtained even when the hot-air adhesion method was used.
[Example 2]
The first component was an ethylene α olefin copolymer polymerized using a metallocene catalyst, wherein crolefin was octene- 1 and contained in the copolymer in an amount of 9 mol%. The density was 0.885, the melting point 78°C, the melt index (MI) 30 g/10 min, and the molecular weight distribution (Mw/Mn) 2.0. The second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 16 g/10 min and a melting point of 1600C.
Melt spinning was performed on these two components by means of a side-by-side conjugate spinneret at a volume ratio of first component/second component = 50/50 under conditions with an extrusion temperature (preset temperature) on the first component of 2000C and 2600C on the second component side. At the time of reeling, an antistatic agent that has ethylene oxide additives of sorbitan fatty acid ester and lauryl phosphate potassium salt as the main components is attached to these components. Good spinnability was obtained. Thus obtained spun conjugate filament having a fineness of 10.2 dtex was stretched 1.7 times by using a 600C heating device provided with a heating roll, and crimped by means of a crimping device. Thereafter, the filament was cut into 38 mm to obtain a conjugate fiber (staple fiber) having a fineness of 7.0 dtex (fiber diameter of 31.7 μm).
The density, melting point, melt index (MI), and molecular weight distribution (Mw/Mn) of the first component were measured using the measuring methods of (l) to (4) described above. The melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above. The results are
shown in the section corresponding to components on Table 1. The obtained conjugate fiber (staple fiber) was measured using the measuring methods of (6) and (7) described above. The results are shown in the section corresponding to yarn quality on Table 1 along with schematic diagrams. Peeling of the components was not observed in the fiber cross section in the direction perpendicular to the fiber axis. Moreover, cd/ce = 6.0, f > ab, and g/h = 0.75. lOOg of the obtained conjugate fiber (staple fiber) was inserted into a 500mm- wide miniature card machine to form a fibrous web. The fiber passability was good during the card processing. The heat shrinkage percentage of this fibrous web was measured using the measuring method of (8) described above. The results are shown in the section corresponding to yarn quality on Table 1. 5Og of the obtained conjugate fiber (staple fiber) were inserted into a 500mm-wide miniature card machine to form a fibrous web. This fibrous web was processed using a through-air processing device of hot-air circulation type under conditions with a preset temperature of 98°C, a hot air velocity of 0.8 m/sec, and a processing time of 12 seconds. The property of thus obtained through-air nonwoven fabric was measured and evaluated using the measuring methods of (9) to (ll) described above. The results are shown in the section corresponding to nonwoven fabric property on Table 1.
Because the heat shrinkage percentage of the fibrous web in which the obtained conjugate fiber (staple fiber) is used was as low as 17%, a bulky nonwoven fabric with excellent uniformity and excellent feeling was obtained even when the hot- air adhesion method was used. [Example 3]
The first component was an ethylene α-olefin copolymer polymerized using a metallocene catalyst, wherein α-olefin was octene-1 and contained in the copolymer in an amount of 5 mol%. The density was 0.902, the melting point 98°C, the melt index (MI) 30 g/10 min, and the molecular weight distribution (Mw/Mn) 2.1. The second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 16 g/10 min and a melting point of 1600C.
Melt spinning was performed on these two components by means of a side-by-side conjugate spinneret at a volume ratio of first component/second component = 45/55 under conditions with an extrusion temperature (preset temperature) on the first component of 2000C and 2600C on the second component side. At the time of pulling up, an antistatic agent that has ethylene oxide additives of sorbitan fatty acid ester and lauryl phosphate potassium salt as the main components is attached to these components. Good spinnability was obtained. Thus obtained spun conjugate filament having a fineness of 10.0 dtex was drawn 2.6 times by using a 700C heating device provided with a heating roll, and crimped by means of a crimping device. Thereafter, the filament was cut into 38 mm to obtain a conjugate fiber (staple fiber) having a fineness of 4.4 dtex (fiber diameter of 25.0 μm).
The density, melting point, melt index (MI), and molecular weight distribution (Mw/Mn) of the first component were measured using the measuring methods of (l) to (4) described above. The melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above. The results are shown in the section corresponding to components on Table 1. The
obtained conjugate fiber (staple fiber) was measured using the measuring methods of (6) and (7) described above. The results are shown in the section corresponding to yarn quality on Table 1 along with schematic diagrams. Peeling of the components was not observed in the fiber cross section in the direction perpendicular to the fiber axis. Moreover, cd/ce = 3.0, f > ab, and g/h = 0.70. lOOg of the obtained conjugate fiber (staple fiber) was inserted into a 500mm wide miniature card machine to collect a fibrous web. The fiber passability was good during the card processing. The heat shrinkage percentage of this fibrous web was measured using the measuring method of (8) described above. The results are shown in the section corresponding to yarn quality on Table 1. 5Og of the obtained conjugate fiber (staple fiber) were inserted into a 500mm-wide miniature card machine to form a fibrous web. This fibrous web was processed using a through-air processing device of hot-air circulation type under conditions with a preset temperature of 98°C, a hot air velocity of 0.8 m/sec, and a processing time of 12 seconds. The property of thus obtained through-air nonwoven fabric was measured and evaluated using the measuring methods of (9) to (ll) described above. The results are shown in the section corresponding to nonwoven fabric property on Table 1.
Because the heat shrinkage percentage of the fibrous web in which the obtained conjugate fiber (staple fiber) is used was as low as 28%, a bulky nonwoven fabric with excellent uniformity and excellent feeling was obtained even when the hot-air adhesion method was used. [Example 4]
Spinning and stretching were performed on the filament under the
same conditions and using the same components as with Example 3, and crimps are provided on the filament using the crimping device. The filament is then cut into 5 mm to obtain a conjugate fiber (chop for air-laid) having a fineness of 4.4 dtex (fiber diameter of 25.0 μm). 20Og of the obtained conjugate fiber (chop for air-laid.) was inserted into an air-laid machine having a pair of forming heads, and consequently a fibrous web was obtained by an air-laid method. Good fiber dischargeablity was obtained from the air-laid machine. This fibrous web was subjected to hot-air adhesion processing by using a through-air processing device of hot-air circulation type under conditions with a preset temperature of 98°C, a hot air velocity of 0.38 m/sec, and a processing time of 14 seconds. The property of thus obtained through-air nonwoven fabric was measured and evaluated using the measuring methods of (9) to (ll) described above. The results are shown in the section corresponding to nonwoven fabric property on Table 1.
As a result of processing the obtained conjugate fiber into the fibrous web using the air-laid method and then subjecting it to the hot- air adhesion method, a bulky nonwoven fabric that hardly shrinks and has excellent uniformity and excellent feeling was obtained. [Comparative Example l]
The first component was an ethylene crolefin copolymer, wherein α-olefin was octene-1 and contained in the copolymer in an amount of 2 mol%. The density was 0.913, the melting point 1070C, the melt index (MI) 30 g/10 min, and the molecular weight distribution (MwMn) 3.0. The second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 16 g/10 min and a melting point of 1600C.
Melt spinning was performed on these two components by means of a side-by-side conjugate spinneret at a volume ratio of first component/second component = 50/50 under conditions with an extrusion temperature (preset temperature) on the first component of 2000C and 2600C on the second component side, thereby producing a conjugate fiber that has a fiber cross -sectional structure in which the borderline between the first component and the second component forms a curve bulging toward the first component. At the time of pulling up, an antistatic agent that has ethylene oxide additives of sorbitan fatty acid ester and lauryl phosphate potassium salt as the main components is attached to these components. Good spinnability was obtained. Thus obtained spun conjugate filament having a fineness of 11.5 dtex was drawn 3.3 times by using a 700C heating device provided with a heating roll, and crimped by means of a crimping device. Thereafter, the filament was cut into 38 mm to obtain a conjugate fiber (staple fiber) having a fineness of 3.8 dtex (fiber diameter of 23.2 μm).
The density, melting point, melt index (MI), and molecular weight distribution (MwMn) of the first component were measured using the measuring methods of (l) to (4) described above. The melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above. The results are shown in the section corresponding to components on Table 2. The obtained conjugate fiber (staple fiber) was measured using the measuring methods of (6) and (7) described above. The results are shown in the section corresponding to yarn quality on Table 2 along with schematic diagrams. In the direction perpendicular to the fiber axis, cd/ce = 3.5, f > ab, and g/h = 0.55.
lOOg of the obtained conjugate fiber (staple fiber) was inserted into a 500mm-wide miniature card machine to form fibrous webs. The fiber passability was good during the card processing. The heat shrinkage percentage of these fibrous webs was measured using the measuring method of (8) described above. The results are shown in the section corresponding to yarn quality on Table 2. 5Og of the obtained conjugate fiber (staple fiber) were inserted into a 500mm-wide miniature card machine to form a fibrous web. These fibrous webs were processed using a through-air processing device of hot-air circulation type under conditions with a preset temperature of 98°C, a hot air velocity of 0.8 m/sec, and a processing time of 12 seconds. However, due to the high melting point of the ethylene octene-1 which is the first component, the fiber entangled point is not melted at the processing temperature of 98°C, hence the conjugate fiber was not processed into a non woven fabric. Although Comparative Example 1 is significantly different from Example 3 in that the melting point is 1070C in this example, but the same method as that of Example 3 was used to produce a nonwoven fabric. However, the processing temperature enable to be adopted for the obtained conjugate fiber was not low enough to adopt the hot-water adhesion method, and thus the conjugate fiber could not be processed into a nonwoven fabric or a formed article. Therefore, evaluation of the shrinkage percentage of the fibrous webs at 1000C according to the low-temperature processing ended up meaningless. [Comparative Example 2]
The first component was an ethylene crolefin copolymer, wherein α olefin was propylene and butene that are contained in the copolymer in an amount of 3 mol% and 3 mol%. The density was 0.897, the melting point
81°C, the melt index (MI) 4 g/10 min, and the molecular weight distribution (MwMn) 2.0. The second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 8 g/10 min and a melting point of 1600C.
Melt spinning was performed on these two components by means of a side-byside conjugate spinneret at a volume ratio of first component/second component = 50/50 under conditions with an extrusion temperature (preset temperature) on the first component of 2200C and 2600C on the second component side. At the time of pulling up, an antistatic agent that has ethylene oxide additives of sorbitan fatty acid ester and lauryl phosphate potassium salt as the main components is attached to these components. However, when the pulled-up spun conjugate filament was checked, agglutination was observed. Thus obtained spun conjugate filament having a fineness of 9.8 dtex was drawn 1.7 times by using a 600C heating device provided with a heating roll to provide the filament with crimps by means of a crimping device. Thereafter, the filament was cut into 38 mm to obtain a conjugate fiber (staple fiber) having a fineness of 6.8 dtex (fiber diameter of 31.1 μm).
The density, melting point, melt index (MI), and molecular weight distribution (MwMn) of the first component were measured using the measuring methods of (l) to (4) described above. The melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above. The results are shown in the section corresponding to components on Table 2. The obtained conjugate fiber (staple fiber) was measured using the measuring methods of (6) and (7) described above. The results are shown in the section corresponding to yarn quality on Table 2 along with schematic
diagrams. Because the melt index (MI) of the first component is low, the borderline between the first component and the second component in the fiber cross section in the direction perpendicular to the fiber axis formed a curve bulging toward the second component. Therefore, cd/ce, f, and g/h could not be measured. Also, peeling was observed between the components. lOOg of the obtained conjugate fiber (staple fiber) was inserted into a 500mm wide miniature card machine to form a fibrous web. The fiber passability was not good during the card processing because unevenness occurred in the fiber dischargeablity. The heat shrinkage percentage of this fibrous web was measured using the measuring method of (8) described above. The results are shown in the section corresponding to yarn quality on Table 2. 5Og of the obtained conjugate fiber (staple fiber) were inserted into a 500mm-wide miniature card machine to form fibrous webs. These fibrous webs were processed using a through-air processing device of hot-air circulation type under conditions with a preset temperature of 98°C, a hot air velocity of 0.8 m/sec, and a processing time of 12 seconds. However, large shrinkage was observed and the strength of the nonwoven fabric was low, and thus a nonwoven fabric with excellent uniformity and excellent feeling was not obtained. The heat shrinkage percentage of each fibrous web in which the obtained conjugate fiber was used was as high as 55%. [Comparative Example 3]
The first component was an ethylene crolefin copolymer, wherein α-olefin was propylene that is contained in the copolymer in an amount of 15 mol%. The density was 0.863, the melting point 500C, the melt index (MI) 21 g/10 min, and the molecular weight distribution (MwMn) 2.0. The
second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 16 g/10 min and a melting point of 16O0C.
Melt spinning was performed on these two components by means of a side-by-side conjugate spinneret at a volume ratio of first component/second component = 50/50 under conditions with an extrusion temperature (preset temperature) on the first component of 2200C and 2600C on the second component side. However, at the time of reeling, agglutination has occurred on the spin conjugate filament, thus it was impossible to stretch it. Regarding this comparative example, the schematic diagrams of the fiber cross section shown in Table 2 were obtained from the agglutinated conjugate spun filament by collecting and observing the fibrous webs somehow. Because the melt index (MI) of the first component is significantly low in relation to the melt mass flow rate (MFR) of the second component, the borderline between the first component and the second component in the fiber cross section perpendicular to the fiber axis formed a straight line. That is, the both conjugate components formed half-moon-shaped conjugate cross sections. In the fiber cross section perpendicular to the fiber axis, cd/ce = 0, and peeling was not observed between the conjugate fibers. The density, melting point, melt index (MI), and molecular weight distribution (Mw/Mn) of the first component were measured using the measuring methods of (l) to (4) described above. The melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above. The results are shown in the section corresponding to components on Table 2. [Comparative Example 4]
A mixture of two resins was used as the first component. One of the resins was an ethylene α-olefin copolymer, wherein α-olefin was propylene that is contained in the copolymer in an amount of 12 mol%. The density was 0.870, the melting point 75°C, the melt index (MI) 1 g/10 min, and the molecular weight distribution (Mw/Mn) 1.9. The other resin was a propylene α-olefin copolymer, wherein crolefin was ethylene and butene-1 that are contained in the copolymer in an amount of 1 mol% each. The melting point was 128°C and the melt mass flow rate (MFR) was 16 g/10 min. These two resins were mixed at a weight ratio of 20/80. Note that Table 2 shows the property of an ethylene propene copolymer, which is a resin having a lower melting point. The second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 8 g/10 min and a melting point of 1600C.
Melt spinning was performed on these two components by means of a side-by-side conjugate spinneret at a volume ratio of first component/second component = 50/50 under conditions with an extrusion temperature (preset temperature) on the first component of 2000C and 2600C on the second component side, to produce a conjugate fiber that has the fiber cross-sectional structure in which the borderline between the first component and the second component forms a curve bulging toward the first component. At the time of pulling up, an antistatic agent that has ethylene oxide additives of sorbitan fatty acid ester and lauryl phosphate potassium salt as the main components is attached to these components. Good spinnability was obtained. Thus obtained spun conjugate filament having a fineness of 9.7 dtex was drawn 2.6 times by using a 600C heating device provided with a heating roll to provide the filament with crimps by means of
a crimping device. Thereafter, the filament was cut into 38 mm to obtain a conjugate fiber (staple fiber) having a fineness of 4.4 dtex (fiber diameter of 25.1 μm).
The density, melting point, melt index (MI), and molecular weight distribution (Mw/Mn) of the first component were measured using the measuring methods of (l) to (4) described above. The melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above. The results are shown in the section corresponding to components on Table 2. The property of the obtained conjugate fiber (staple fiber) was measured using the measuring methods of (6) and (7) described above. The results are shown in the section corresponding to yarn quality on Table 2 along with schematic diagrams. Moreover, in the fiber cross section in the direction perpendicular to the fiber axis, cd/ce = 0.2 and g/h < 0.5. lOOg of the obtained conjugate fiber (staple fiber) was inserted into a
500mm-wide miniature card machine to form a fibrous web. The fiber passability was good during the card processing. The heat shrinkage percentage of this fibrous web was measured using the measuring method of (8) described above. The results are shown in the section corresponding to yarn quality on Table 2. 5Og of the obtained conjugate fiber (staple fiber) were inserted into a 500mm-wide miniature card machine to form a fibrous web. This fibrous web was processed using a through- air processing device of hot-air circulation type under conditions with a preset temperature of 98°C, a hot air velocity of 0.8 m/sec, and a processing time of 12 seconds. However, large shrinkage was observed, and thus a nonwoven fabric with excellent uniformity and excellent feeling could not be obtained. The heat
shrinkage percentage of the fibrous web in which the obtained conjugate fiber is used was as high as 65%. [Comparative Example 5]
A mixture of two resins was used as the first component. One of the resins was a low-density polyethylene. The density thereof was 0.918, the melting point 1050C, the melt index (MI) 24 g/10 min, and the molecular weight distribution 7.0. The other resin was an ethylene-vinyl acetate copolymer. The density thereof was 0.939, the melting point 92°C, the melt index (Ml) 20 g/10 min, and the molecular weight distribution (MwMn) 5.0. These two resins were mixed at a weight ratio of 75/25. Note that Table 3 shows the property of the ethylene-vinyl acetate copolymer, which is a resin having a lower melting point. The second component is a crystalline polypropylene having a melt mass flow rate (MFR) of 8 g/10 min and a melting point of 1600C. Melt spinning was performed on these two components by means of a side-by-side conjugate spinneret at a volume ratio of first component/second component = 50/50 under conditions with an extrusion temperature (preset temperature) on the first component of 2000C and 2600C on the second component side, to produce a conjugate fiber that has the fiber cross -sectional structure in which the borderline between the first component and the second component forms a curve bulging toward the first component. At the time of pulling up, an antistatic agent that has ethylene oxide additives of sorbitan fatty acid ester and lauryl phosphate potassium salt as the main components is attached to these components. A number of broken yarns were observed during spinning. Thus obtained spun conjugate filament having a fineness of 9.7 dtex was drawn 2.6 times by
using a 600C heating device provided with a heating roll to provide the filament with crimps by means of a crimping device. Thereafter, the filament was cut into 38 mm to obtain a conjugate fiber (staple fiber) having a fineness of 3.3 dtex (fiber diameter of 21.5 μm). The density, melting point, melt index (MI), and molecular weight distribution (MwMn) of the first component were measured using the measuring methods of (l) to (4) described above. The melting point and melt mass flow rate (MFR) of the second component were measured using the measuring methods of (4) and (5) described above. The results are shown in the section corresponding to components on Table 3. The property of the obtained conjugate fiber (staple fiber) was measured using the measuring methods of (6) and (7) described above. The results are shown in the section corresponding to yarn quality on Table 3 along with schematic diagrams. Moreover, in the fiber cross section in the direction perpendicular to the fiber axis, cd/ce = 9.5, f > ab, and g/h = 0.86. lOOg of the obtained conjugate fiber (staple fiber) was inserted into a 500mm wide miniature card machine to form a fibrous web. The fiber passability was not good during the card processing because unevenness occurred when discharging the fiber. The heat shrinkage percentage of this fibrous web was measured using the measuring method of (8) described above. The results are shown in the section corresponding to yarn quality on Table 3. 5Og of the obtained conjugate fiber (staple fiber) were inserted into a 500mm wide miniature card machine to form fibrous webs. These fibrous webs were processed using a through-air processing device of hot-air circulation type under conditions with a preset temperature of 98°C, a hot air velocity of 0.8 m/sec, and a processing time of 12 seconds. However,
large shrinkage was observed and the strength of the nonwoven fabric was low, and thus a nonwoven fabric with excellent uniformity and excellent feeling was not obtained.
The heat shrinkage percentage of each fibrous web in which the obtained conjugate fiber was used was as high as 60%. [Comparative Example 6]
Spinning and drawing were performed on the filament under the same conditions and using the same components as with Comparative
Example 5, and crimps are provided on the filament using the crimping device. The filament is then cut into 5 mm to obtain a conjugate fiber (chop for air-laid) having a fineness of 3.3 dtex (fiber diameter of 21.5 μm).
20Og of the obtained conjugate fiber (chop for air-laid) was inserted into an air-laid machine having a pair of forming heads, and consequently a fibrous web was obtained by an air-laid method. Poor fiber dischargeablity was obtained from the air-laid machine. This fibrous web was subjected to hot-air adhesion processing by using a through-air processing device of hot-air circulation type under conditions with a preset temperature of 98°C, a hot air velocity of 0.38 m/sec, and a processing time of 14 seconds. However, although hot-air adhesion was possible at 98°C, shrinkage has occurred, and thus a nonwoven fabric with excellent uniformity and excellent feeling could not be obtained. The results are shown in Table 3. [Example 5]
The conjugate fiber (staple fiber) obtained in Example 3 was processed into a fibrous web by means of the carding method, and this fibrous web was formed into a rod-like sliver. The fibrous web formed into a sliver was placed into a cylindrical mold (10 mm x 10 mm x 60 mm) made
from a 20-mesh metallic wire having a wire diameter of 0.29 mm, which is then subjected to hot-air adhesion processing by means of a through-air processing device of hot-air circulation type under conditions with a preset temperature of 98°C, hot air velocity of 1.2 m/sec, and a processing time of 12 seconds, to obtain a cubical fiber formed article. The obtained fiber formed article has excellent cushioning characteristics. [Example 6]
The conjugate fiber (chop for air-laid) obtained in Example 4 was processed into a fibrous web having a mass per unit area of 50 g/m2 by means of the air-laid method, and this fibrous web was subjected to hot-air adhesion processing by using a through-air processing device of hot-air circulation type under conditions with a preset temperature of 98°C, a hot air velocity of 0.38 m/sec, and a processing time of 14 seconds. The obtained through-air nonwoven fabric was placed into a glass tube having an inner diameter of 8 mm, which is then immersed into boiled water and boiled for two minutes. The through-air nonwoven fabric was then cooled after the boiling, to obtain a cylindrical fiber formed article. The obtained fiber formed article is moderately soft and has less fluctuation in fiber density. Therefore, this fiber formed article is suitable for retaining fluid and the like.
[Table 2]
[Table 3]
Industrial Applicability
The conjugate fiber of the present invention, in which the first component containing an ethylene α-olefin copolymer of a specific property and the second component containing a crystalline polypropylene form the side-by-side cross section, has low-temperature processability and low heat shrinkage percentage. Therefore, this conjugate fiber is useful in producing bulky nonwoven fabric and formed articles having excellent uniformity and excellent feeling at a heat processing temperature of 1000C or lower.
Claims
1. A conjugate fiber in which a first component that contains at least 75 % by weight of an ethylene orolefin copolymer having a melting point of 70 to 1000C and a second component that contains a crystalline polypropylene form a side-byside cross section, wherein, in a fiber cross section perpendicular to a fiber axis, the first component accounts for 55 to 90% of an outer periphery of the fiber, a borderline between the first component and the second component forms a curve bulging toward the first component, and an area ratio between the first component and the second component (first component/second component) is in a range of 70/30 to 30/70.
2. The conjugate fiber according to claim 1, wherein the ethylene -crolefin copolymer has a molecular weight distribution (MwMn) of 1.5 to 2.5, a density of 0.87 to 0.91 g/cm3, and a melt index (MI) of 10 to 35 g/10 min as measured under conditions with a temperature of 1900C and a load of 21.2 N based on ASTM D- 1238.
3. The conjugate fiber according to claim 1 or 2, wherein a heat shrinkage percentage thereof that is obtained when subjected to heat processing at 1000C for five minutes is 50% or lower.
4. A nonwoven fabric, which is obtained by processing the conjugate fiber described in any one of claims 1 to 3 into a nonwoven fabric.
5. The nonwoven fabric according to claim 4, wherein the conjugate fiber is processed into a nonwoven fabric by a hot- air adhesion method or a hot-water adhesion method.
6. A formed article, which is obtained by using the conjugate fiber described in any one of claims 1 to 3.
7. A formed article, which is obtained by using the nonwoven fabric described in claim 4 or 5.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007323616 | 2007-12-14 | ||
| PCT/JP2008/073148 WO2009078479A1 (en) | 2007-12-14 | 2008-12-15 | Conjugate fiber having low-temperature processability, nonwoven fabric and formed article using the conjugate fiber |
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| Publication Number | Publication Date |
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| EP2229474A1 true EP2229474A1 (en) | 2010-09-22 |
| EP2229474A4 EP2229474A4 (en) | 2011-03-02 |
| EP2229474B1 EP2229474B1 (en) | 2017-06-07 |
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| EP08863375.5A Active EP2229474B1 (en) | 2007-12-14 | 2008-12-15 | Conjugate fiber having low-temperature processability, nonwoven fabric and formed article using the conjugate fiber |
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|---|---|
| US (1) | US20100261399A1 (en) |
| EP (1) | EP2229474B1 (en) |
| JP (1) | JP5535911B2 (en) |
| KR (1) | KR101259968B1 (en) |
| CN (1) | CN101939470B (en) |
| BR (1) | BRPI0819934B1 (en) |
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| JP5842353B2 (en) * | 2010-04-13 | 2016-01-13 | Jnc株式会社 | Bulky nonwoven fabric |
| JP6083239B2 (en) * | 2012-05-23 | 2017-02-22 | 東レ株式会社 | Fiber-reinforced plastic and method for producing the same |
| CN102978724B (en) * | 2012-12-21 | 2015-05-13 | 东华大学 | Dual-component parallel composite fiber and preparation method thereof |
| JP6222997B2 (en) * | 2013-05-31 | 2017-11-01 | Ｅｓファイバービジョンズ株式会社 | Thermal adhesive composite fiber with excellent flexibility and non-woven fabric using the same |
| TWI550147B (en) * | 2013-11-20 | 2016-09-21 | Fabrication method and finished product of juxtaposed polypropylene crimp telescopic fiber | |
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| CN107106355B (en) | 2014-11-06 | 2020-11-03 | 宝洁公司 | Crimped fiber spunbond nonwoven web/laminate |
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| EP4335420A3 (en) | 2017-02-16 | 2024-05-29 | The Procter & Gamble Company | Absorbent articles with substrates having repeating patterns of apertures comprising a plurality of repeat units |
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| KR102152393B1 (en) * | 2019-07-11 | 2020-09-04 | 도레이첨단소재 주식회사 | Non-woven fabric of crimped composite fiber and laminate thereof, and article including the laminate |
| KR20220034111A (en) * | 2019-07-16 | 2022-03-17 | 도레이 카부시키가이샤 | Spunbond Nonwovens and Laminated Nonwovens |
| KR20230156826A (en) * | 2021-03-18 | 2023-11-14 | 도레이 카부시키가이샤 | Spunbond nonwovens and laminated nonwovens, their manufacturing methods and sanitary materials |
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| JP2000008244A (en) * | 1998-06-18 | 2000-01-11 | Hagiwara Kogyo Kk | Flat yarn cloth for reinforcement lamination |
| KR100662827B1 (en) * | 1998-12-16 | 2006-12-28 | 미쓰이 가가쿠 가부시키가이샤 | Composite-fiber nonwoven fabric |
| MY139729A (en) * | 2002-11-25 | 2009-10-30 | Mitsui Chemicals Inc | Nonwoven fabric capable of being elongated and composite nonwoven fabric comprising said nonwoven fabric laminated |
-
2008
- 2008-12-10 TW TW97148048A patent/TW200934897A/en unknown
- 2008-12-15 US US12/808,009 patent/US20100261399A1/en not_active Abandoned
- 2008-12-15 EP EP08863375.5A patent/EP2229474B1/en active Active
- 2008-12-15 JP JP2010523227A patent/JP5535911B2/en active Active
- 2008-12-15 BR BRPI0819934-5A patent/BRPI0819934B1/en active IP Right Grant
- 2008-12-15 WO PCT/JP2008/073148 patent/WO2009078479A1/en active Application Filing
- 2008-12-15 CN CN2008801265290A patent/CN101939470B/en active Active
- 2008-12-15 KR KR1020107015013A patent/KR101259968B1/en active IP Right Grant
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|---|---|---|---|---|
| US5418045A (en) * | 1992-08-21 | 1995-05-23 | Kimberly-Clark Corporation | Nonwoven multicomponent polymeric fabric |
| US6454989B1 (en) * | 1998-11-12 | 2002-09-24 | Kimberly-Clark Worldwide, Inc. | Process of making a crimped multicomponent fiber web |
| US20020009941A1 (en) * | 1999-12-21 | 2002-01-24 | Kimberly-Clark Worldwide, Inc. | Fine denier multicomponent fibers |
| US20070014987A1 (en) * | 2003-08-28 | 2007-01-18 | Yoshiji Usui | Potential crimping composite fiber and method for production thereof, and fiber aggregate, and nonwoven fabric |
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| Title |
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| See also references of WO2009078479A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2011506778A (en) | 2011-03-03 |
| CN101939470B (en) | 2012-10-03 |
| KR20100090720A (en) | 2010-08-16 |
| EP2229474A4 (en) | 2011-03-02 |
| KR101259968B1 (en) | 2013-05-02 |
| BRPI0819934B1 (en) | 2019-07-09 |
| WO2009078479A1 (en) | 2009-06-25 |
| EP2229474B1 (en) | 2017-06-07 |
| TW200934897A (en) | 2009-08-16 |
| CN101939470A (en) | 2011-01-05 |
| TWI367967B (en) | 2012-07-11 |
| BRPI0819934A2 (en) | 2015-05-26 |
| US20100261399A1 (en) | 2010-10-14 |
| JP5535911B2 (en) | 2014-07-02 |
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