EP2192976A1 - Dispositif de production d'un oxygène singulet par irradiation d'une matière sensible à la lumière - Google Patents
Dispositif de production d'un oxygène singulet par irradiation d'une matière sensible à la lumièreInfo
- Publication number
- EP2192976A1 EP2192976A1 EP08801834A EP08801834A EP2192976A1 EP 2192976 A1 EP2192976 A1 EP 2192976A1 EP 08801834 A EP08801834 A EP 08801834A EP 08801834 A EP08801834 A EP 08801834A EP 2192976 A1 EP2192976 A1 EP 2192976A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- light
- activating chamber
- chamber
- sensitive material
- surface part
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/02—Specific form of oxidant
- C02F2305/023—Reactive oxygen species, singlet oxygen, OH radical
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
Definitions
- the present invention relates generally to a device for producing a Singlet Oxygen by irradiating a light sensitive material.
- the devices comprise a light-sensitive material provided in an activating chamber and a light source for irradiating the light-sensitive material, whereby singlet oxygen may be formed when a gas is located in the chamber.
- a device for producing singlet oxygen is known from EP 0 895 507.
- a chamber is formed having two boundary surfaces, one of these surfaces being transparent, whereas the other surface is covered by a coating made from a dye excitable by light radiation.
- the chamber has a gas inlet and a gas outlet, whereby a flow of gas can be obtained through the chamber.
- the surface coated with the dye is irradiated with light from a light source disposed adjacent to the transparent surface.
- the light source is a halogen lamp, and the transparent surface filters out a certain part of the radiation, such that a radiation having a predetermined frequency is obtained.
- This light radiation acts upon the dye disposed on the surface coated with the dye, and the oxygen flowing over this surface is brought into an excited condition for forming singlet oxygen.
- US Patent No. 6,991 ,831 is also known a device for producing singlet oxygen.
- the apparatus described in this patent comprises a housing forming a chamber, which has two opposite surfaces. One of these surfaces is transparent and the other surface is covered by a coating made from a dye excitable by light.
- the apparatus further has a light source for irradiating the surface covered with the dye through the transparent surface.
- the surface covered by the dye is formed by a substrate comprising a finely roughened surface.
- the light source is formed by light emitting diodes, whose light emission comprises a wavelength located within the range of maximum radiation absorption of the dye of the coated surface.
- a device for generating activated light is known from WO 97/43807.
- the device described in WO 97/43807 corresponds to the device described in EP 0 895 507.
- the chamber contains a gas, but has no gas inlet and no gas outlet, and in the chamber there is also provided one end of a light guide, where the light guide may be an optical fibre cable.
- the gas in the chamber is brought into an excited condition for forming singlet oxygen when light radiation acts upon the dye, and energy is released when the singlet oxygen returns to its ground state.
- the energy, which is released by this return of singlet oxygen to normal oxygen to in its ground state is 22 kcal per mol in the case of a bimolecular transition, and 11 kcal per mol in the case of a monomolecular transition. This can be observed amongst other things as light energy with wavelengths of 634,3 and 1268,7 nm, corresponding to bimolecular and monomolecular transitions from singlet state to triplet ground state.
- the released energy is transferred as a coherent light beam through the light guide.
- the dye being excitable by light radiation is only covering the back surface of the chamber, and there is no dye on the side surfaces. Furthermore, the light sources are arranged outside the chamber, and is radiated into the chamber through a transparent surface arranged opposite the dye covered back surface.
- a device for irradiating a light- sensitive material comprises: an activating chamber with an inner back surface part, an inner front surface part, and an inner side surface part connecting the inner back and front surface parts; a light-sensitive material provided in the activating chamber, said light-sensitive material being applied at least partly on the inner back surface part; and one or more light sources arranged for irradiating the light-sensitive material in the activating chamber, said one or more light sources being adapted for emitting light with a wavelength within the range of radiation absorption of the light- sensitive material.
- the activating chamber also has a gas inlet and a gas outlet.
- a device for providing or producing a singlet oxygen or a singlet oxygen- activated oxygenous gas flow comprises: an activating chamber with an inner back surface part, an inner front surface part, and an inner side surface part connecting the inner back and front surface parts, said activating chamber further having a gas inlet and a gas outlet; a light-sensitive material provided in the activating chamber, said light-sensitive material being applied at least partly on the inner back surface part; and one or more light sources arranged for irradiating the light-sensitive material in the activating chamber, said one or more light sources being adapted for emitting light with a wavelength within the range of radiation absorption of the light-sensitive material.
- the activating chamber also has a light output and a first end of a light guide being arranged at the light output, whereby activated light can be obtained from the other end of the light guide.
- a device for generating activated light comprises: an activating chamber containing a gas or a liquid, said activating chamber having an inner back surface part, an inner front surface part, and an inner side surface part connecting the inner back and front surface parts, said activating chamber further having a light output; a light-sensitive material provided in the activating chamber, said light-sensitive material being applied at least partly on the inner back surface part; one or more light sources arranged for irradiating the light-sensitive material in the activating chamber, said one or more light sources being adapted for emitting light with a wavelength within the range of radiation absorption of the light- sensitive material; and a first end of a light guide arranged at the light output, whereby activated light can be obtained from the
- the light sensitive material further is applied at least partly on the inner side surface part of the activating chamber.
- the light-sensitive material may also be applied at least partly on the inner front surface part of the activating chamber.
- the one or more light sources has/have sufficient intensity to achieve photo-sensitization with the light-sensitive material.
- the one or more light sources may be arranged at the inner front surface part. It is preferred that the one or more light sources is/are formed by light emitting diode(s).
- the light emitting diodes may be arranged on a supporting board, which board at least partly forms the front surface part of the activating chamber with the light emitting diodes arranged on the inner front surface part, whereby the light emitting diodes are extending into the activating chamber.
- the light emitting diodes used for the light source may be lead-free light emitting diodes.
- the light-sensitive material comprises a substance or dye being excitable by light.
- the substance or dye may comprise a phthalocyanine, such as a green and/or blue phthalocyanine.
- blue phthalocyanine is used for the substance or dye.
- the light emission of the light emitting diodes may be located in a spectral region in the range of 600-680 nm, such as in the range of 620-630 nm, such as about 626 nm.
- the light-sensitive material is applied on a major part or on all of the inner back surface part of the activating chamber. It is also within one or more embodiments of the invention that the light-sensitive material is applied on a major part or on all of the inner side surface part of the activating chamber. It is also within one or more embodiments of the invention that the light-sensitive material is applied on a major part or on all of the inner front surface part of the activating chamber.
- the present invention covers embodiments wherein the dimensions of the activating chamber may vary within a wide range.
- the height of the activating chamber may be in the range of 1 -500mm, such as in the range of 1- 200mm, such as in the range of 1-100mm, such as in the range of 1-50mm, such as in the range of 1-30 mm, such as in the range of 5-15 mm, such as in the range of 7-12 mm.
- the height of the activating chamber is substantially matching the extension of the light emitting diodes into the activating chamber.
- the activating chamber is circular or cylindrically shaped.
- the present invention also covers embodiments wherein the activating chamber has another form than a circular form, such as for example an elliptical form, a rectangular form, or a quadratic form.
- the area of the activating chamber is in the range of 1 mm 2 -5 m 2 .
- the width or diameter of the activating chamber is below or equal to 2m, such as below or equal to 1m, such as below or equal to 500mm, such as below or equal to 200mm, such as below or equal to 100mm, such as below or equal to 50mm, such as below or equal to 20mm. It is also within embodiments of the invention that the width or diameter of the activating chamber is in the range of 30-100 mm, such as in the range of 40-70 mm, such as about 60 mm.
- the light output may be provided at the inner back surface part or at the inner side surface part. It is also within an embodiment of the second aspect of the invention that the activating chamber is sealed. For embodiments of the invention having a light output, the invention also covers embodiments, wherein an oxygenous gas or liquid is provided in the activating chamber.
- the second aspect of the invention further covers embodiments, wherein the activating chamber besides having a light output also has a gas inlet and a gas outlet to provide an oxygenous gas-flow through the activating chamber.
- the activating chamber besides having a light output also has a gas inlet and a gas outlet to provide an oxygenous gas-flow through the activating chamber.
- means may be provided for closing and opening of the gas inlet of the activating chamber and/or means may be provided for closing and opening of the gas outlet of the activating chamber. It is also within one or more embodiments of the second aspect of the invention that means are provided for closing and opening of the light output of the activating chamber.
- an optical fibre cable is used as the light guide.
- the inner opening of the gas inlet and the gas outlet of the chamber may have an area in the range of 1 - 785000 mm 2 . It is also within embodiments of the invention that the inner opening of the gas inlet and the gas outlet have a width or diameter in the range of 2-20mm, such as in the range of 2-10mm, such as about 5 mm.
- At least part of the inner back surface part has a roughened or finely roughened or porous surface. It is also within one or more embodiments of the invention that at least part of the inner side surface part has a roughened or finely roughened or porous surface. It is also within one or more embodiments of the invention that at least part of the inner front surface part has a roughened or finely roughened surface.
- the invention also covers embodiments wherein the light-sensitive material is unevenly applied at least partly to one or more of the inner surface parts.
- the invention also covers one or more embodiments wherein the light-sensitive material is applied at least partly to one or more of the inner surface parts by brushing to thereby obtain an unevenly distribution of the light-sensitive material.
- the invention also covers one or more embodiments wherein the activating chamber is formed in a chamber housing.
- the chamber housing may be of a plastic material such as polyvinyl chloride, PVC.
- PVC polyvinyl chloride
- foamed polyvinyl chloride is used for the chamber housing.
- a system for providing a singlet oxygen-activated oxygenous gas flow comprises a device for irradiating a light-sensitive material according to one or more of the embodiments having an activating chamber with a gas inlet and a gas outlet, where the system further comprises: a device or pump with an air inlet and an air outlet connected to the gas inlet of the activating chamber for forwarding air or gas to the activating chamber, and a gas transportation arrangement or tube connected to the gas outlet of the activating chamber for distribution of the activated air.
- a humidifier system or bottle is connected to the air inlet of the pump or device for forwarding air to the activating chamber, whereby humidified air can be forwarded to the activating chamber.
- a system for providing a singlet oxygen-activated oxygenous gas flow comprising a device for irradiating a light-sensitive material according to one or more of the embodiments of the invention having an activating chamber with a gas inlet and a gas outlet, where the system further comprises: a humidifier system or bottle with an air inlet and an air outlet for producing humidified air to be passed through said air outlet, a device or pump connected to the air outlet of the humidifier system or bottle and connected to the gas inlet of the activating chamber for forwarding humidified air to the activating chamber, and a gas transportation arrangement or tube connected to the gas outlet of the activating chamber for distribution of the activated air.
- the pump is adapted to provide an air/gas through flow up to 100 m 3 per minute.
- the systems of the invention may also be adapted to provide an air/gas through flow of 3-5 litres per minute or of 4 litres per minute.
- Fig. 1 is a perspective bottom view of a chamber housing holding an activating chamber to be used for a device according to an embodiment of the first aspect of the invention
- Fig. 2 is a perspective top view of the chamber housing of Fig. 1 without light sources
- Figs. 3a and 3b are perspective bottom and side views of a supporting circuit board holding a number of light emitting diodes used as light sources for devices according to embodiments of the first and second aspect of the invention
- Fig. 4 is a side view showing a device according to an embodiment of the first aspect of the invention, where the supporting circuit board of Figs. 3a and 3b is arranged on top of the activating chamber with the light emitting diodes extending into the chamber,
- Fig. 5 is a perspective bottom view of a chamber housing holding an activating chamber of a device according to an embodiment of the second aspect of the invention
- Fig. 6 is a perspective top view of the chamber housing of Fig. 5 without light sources
- Fig. 7 is a side view showing a device according to a first embodiment of the second aspect of the invention, where the supporting circuit board of Figs. 3a and 3b is arranged on top of the activating chamber with the light emitting diodes extending into the chamber,
- Fig. 8 is a side view showing a device according to a second embodiment of the second aspect of the invention, where the supporting circuit board of Figs. 3a and 3b is arranged on top of the activating chamber with the light emitting diodes extending into the chamber, and
- Fig. 9 illustrates a system including a device according to an embodiment of the first aspect of the invention for providing activated air to a user.
- Fig. 1 is a perspective bottom view of a chamber housing holding an activating chamber A, which can be used in a device for providing a singlet oxygen according to an embodiment of the first aspect of the present invention.
- the chamber A is formed in a chamber housing having an upper chamber part and a lower bottom part. Both the upper chamber part and the lower bottom part have outer width, length, and height of: 75 mm, 75 mm, and 10 mm.
- the dotted area in Fig. 1 indicates the space in which the chamber A is formed in the upper chamber part of the chamber housing.
- the chamber A is closed at the bottom side by the bottom part of the chamber housing, and the inner surface of the bottom part forms an inner back surface part of the activating chamber A.
- Two 10 mm plates of foamed polyvinyl chloride are used for the upper chamber part and the lower bottom part of the chamber housing.
- Fig. 2 is a perspective top view of the chamber housing of Fig. 1 without light sources.
- the activating chamber A is open at the top of the chamber housing with an inner side surface part formed in the upper chamber part of the chamber housing and connecting the inner back surface part of the chamber with the front surface part of the chamber.
- the upper chamber part of the chamber housing also holds a gas inlet B1 and a gas outlet B2, both extending from the exterior of the housing to the inner side surface part.
- the diameter of the gas inlet and outlet B1 , B2 may be about 5 mm.
- the diameter of the activating chamber A is about 50 mm, and the inner height of the activating chamber is 10 mm.
- the area of the inner back surface part will be about 19,6 cm 2
- the area of the inner side surface part will be about 15,7 cm 2 .
- the volume of the activating chamber will be about 19, 6 cm 3 .
- the total area covered by both the inner back surface part and the inner side surface part will be about 35,3 cm 2 , which is much larger than the area of the inner back surface part alone.
- the present invention also covers embodiments in which the activating chamber has a smaller or larger diameter, such as for example 40 mm or 60 mm.
- a light-sensitive material is applied at the inner back surface part of the activating chamber, and it may cover substantially all of the inner back surface part. It is however preferred that the light-sensitive material is also applied at the inner side surface part of the activating chamber, and it may cover substantially all of the inner side surface part, whereby the total area being active to light radiation is much larger than the light active area of the prior art chambers, in which only the inner back surface part of the chamber is provided with a light-sensitive material.
- the inner back surface part and the inner side surface part are at least partly having a roughened or finely roughened or porous surface to further increase the total surface to be covered by the light-sensitive material.
- the light-sensitive material is a dye, which comprises a phthalocyanine.
- the dye may comprise a green or blue phthalocyanine, such as BASF Heliogen® blau L 7080 or BASF Heliogen® green L 8730.
- BASF Heliogen® blau L 7080 is used. The dye is brushed without pressure on the inner surfaces to further obtain an even larger light active surface.
- Figs. 3a and 3b are perspective bottom and side views of a supporting circuit board 31 holding a number of the light emitting diodes D used as light sources.
- the supporting circuit board has a width equal to the width of the chamber housing, that is 75 mm, and the length is 98 nm in order to have place for the electronic circuitry 32 used for driving the light emitting diodes D.
- six light emitting diodes D are used and arranged to extend outwardly from the circuit board 31.
- light emitting diodes from Avago Technologies of type HLMP-Ed31 -SV000 with a wavelength of 626 nm are used.
- the circuit board 31 is arranged on top of the activating chamber A, to thereby provide an inner front surface part of the chamber A.
- Fig. 4 is a side view showing a device according to an embodiment of the first aspect of the invention, where the supporting circuit board of Figs. 3a and 3b is arranged on top of the activating chamber A with the light emitting diodes D extending into the chamber A. It is noted that lead-free diodes are used, whereby it is only the light emitting part of the diodes, which extends into the chamber A.
- the chamber housing is formed of an upper chamber part holding the gas inlet and outlet B1 , B2, and a lower bottom part.
- the light emitting diodes D By having the light emitting diodes D arranged inside the activating chamber A, the light radiated by the diodes D will hit both the inner back surface part and the inner side surface part of the activating chamber A, to thereby activate the dye on these surface parts.
- Fig. 5 is a perspective bottom view of a chamber housing according to a first embodiment of the second aspect of the invention holding an activating chamber A
- Fig. 6 is a perspective top view of the chamber housing holding the chamber A.
- the activating chamber A in Figs. 5 and 6 holds a gas, in which singlet oxygen may be generated, when light radiation acts upon a dye on the chamber surfaces.
- the chamber housing of Figs. 5 and 6 is similar to the chamber housing in Figs. 1 and 2, with the exception that there are no gas inlet and outlet, B1 and B2 of Fig. 2, but at the centre of the bottom of the chamber housing a light output C is provided, see Fig.
- Fig. 7 is a side view illustrating the fully assembled device of the first embodiment of the second aspect of the invention, using the chamber housing of Figs. 5 and 6, and with the supporting circuit board of Figs. 3a and 3b arranged on top of the activating chamber with the light emitting diodes extending into the chamber A.
- One end of a light guide E is inserted in the light output C, with the light guide E ending at the inner back surface of the activating chamber A.
- the activating chamber A is hermetically sealed, so that no air can enter into or out of the chamber A.
- the length of the cable is 1 ,5 m and the diameter is 3 mm.
- the device illustrated in Fig. 7 is operated by having the light emitting diodes radiating the dye on the inner back surface part and the inner side surface part of the activating chamber, whereby the oxygen being part of the gas in the chamber is brought into an excited condition and forming singlet oxygen.
- the formed singlet oxygen quickly returns to normal oxygen in its ground state, by which transition energy is released, including light energy with a wavelength of 634,5 nm.
- the generated light is transferred as a coherent light beam through the optical fibre cable, and the outer end of the fibre cable may be directed to a user to be treated with the light.
- the second aspect of the present invention further covers a second embodiment for generating activated light.
- a side view of such a device is shown if Fig. 8.
- the device of Fig. 8 holds a chamber housing being a combination of the chamber housings of Figs. 1 and 2 and Figs. 5 and 6.
- the upper chamber part of the chamber housing holds a gas inlet B1 and a gas outlet B2, and at the centre of the bottom of the chamber housing a light output C is provided.
- the supporting circuit board of Figs. 3a and 3b is arranged on top of the activating chamber with the light emitting diodes extending into the chamber A.
- One end of a light guide E is inserted in the light output C 1 with the light guide E ending at the inner back surface of the activating chamber A.
- the device of Fig. 8 may further have means for closing an opening of the light output C within the activating chamber. When the light output is closed, the device of Fig. 8 can be operated as the device shown in Fig. 4.
- the device of Fig. 8 may also be provided with means for closing and opening of the gas inlet and outlet B1 , B2 of the activating chamber.
- the device of Fig. 8 can be operated as the device of Fig. 7.
- B2 humidified air may be brought into the activating chamber, before the closing of B1 and B2.
- the present invention also covers a system using a device of the first or second aspects of the invention, wherein the activating chamber has a gas inlet B1 and a gas outlet B2.
- a device may be used for providing activated air to a user, and an embodiment of such a device is illustrated in Fig. 9.
- the system 90 of Fig. 9 comprises an air activating device 91 according to Fig. 4 or Fig. 8 having an activating chamber with a gas inlet 92 and a gas outlet 93.
- the system is connected to a humidifier bottle 94 having an air inlet and an air outlet for producing humidified air to be passed to the air outlet, which air outlet is connected to the air inlet 96 of a pump 95, which pump 95 has an air outlet 97 connected via a silicone tube to the gas inlet 92 of the device 91.
- the gas outlet 93 of the device 91 is via a silicone tube connected to the output connector 98 of the system 90, from which connector 98 a tube may pass the activated air to a user, which may inhale the activated air.
- the pump is adapted to provide an air or gas through flow of 3-5 litres per minute or 4 litres per minute.
- the air being passing the activating device 91 may obtain a humidity level in the range of at least 85%, depending on the humidity and temperature of the ambient air. It should be understood that the present invention also covers a system similar to the system of Fig. 9, but without the humidifier bottle 94. It has however been found that using moist air gives a better treatment result.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Abstract
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08801834A EP2192976A1 (fr) | 2007-09-07 | 2008-09-04 | Dispositif de production d'un oxygène singulet par irradiation d'une matière sensible à la lumière |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07017555 | 2007-09-07 | ||
EP08801834A EP2192976A1 (fr) | 2007-09-07 | 2008-09-04 | Dispositif de production d'un oxygène singulet par irradiation d'une matière sensible à la lumière |
PCT/EP2008/007231 WO2009030477A1 (fr) | 2007-09-07 | 2008-09-04 | Dispositif de production d'un oxygène singulet par irradiation d'une matière sensible à la lumière |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2192976A1 true EP2192976A1 (fr) | 2010-06-09 |
Family
ID=40242649
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08801834A Withdrawn EP2192976A1 (fr) | 2007-09-07 | 2008-09-04 | Dispositif de production d'un oxygène singulet par irradiation d'une matière sensible à la lumière |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP2192976A1 (fr) |
WO (1) | WO2009030477A1 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010017892A1 (de) * | 2010-04-21 | 2011-10-27 | Kirsten Klemm | Verfahren und Vorrichtung zur Sauerstoff-Anregung vom Triplett- zum Singulett-Zustand |
GB201018204D0 (en) * | 2010-10-28 | 2010-12-15 | Soe Health Ltd | Apparatus for producing singlet oxygen |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NO304735B1 (no) * | 1996-02-07 | 1999-02-08 | Singlet Oxygen Technologies As | Apparat for aa tilveiebringe en singlettoksygen-aktivert oksygenholdig gasstroem |
NO305059B1 (no) * | 1996-05-15 | 1999-03-29 | Singlet Oxygen Technologies As | FremgangsmÕte samt anordning til frembringelse av lys med aktiverende virkning, sµrlig biologisk virksomt lys |
US20040076559A1 (en) * | 1998-08-05 | 2004-04-22 | Franz Brucker | Device and method for the production of singlet oxygen |
DE10048153A1 (de) * | 2000-09-28 | 2002-04-25 | Natural Energy Solutions Ag | Vorrichtung zur Erzeugung von Singulett-Sauerstoff |
-
2008
- 2008-09-04 WO PCT/EP2008/007231 patent/WO2009030477A1/fr active Application Filing
- 2008-09-04 EP EP08801834A patent/EP2192976A1/fr not_active Withdrawn
Non-Patent Citations (1)
Title |
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See references of WO2009030477A1 * |
Also Published As
Publication number | Publication date |
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WO2009030477A1 (fr) | 2009-03-12 |
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