EP2184180B1 - Pen with closing cap - Google Patents
Pen with closing cap Download PDFInfo
- Publication number
- EP2184180B1 EP2184180B1 EP09167608.0A EP09167608A EP2184180B1 EP 2184180 B1 EP2184180 B1 EP 2184180B1 EP 09167608 A EP09167608 A EP 09167608A EP 2184180 B1 EP2184180 B1 EP 2184180B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cap
- pen
- sealing element
- closing cap
- shaft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K23/00—Holders or connectors for writing implements; Means for protecting the writing-points
- B43K23/08—Protecting means, e.g. caps
- B43K23/12—Protecting means, e.g. caps for pens
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
- A45D2034/002—Accessories
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D2200/00—Details not otherwise provided for in A45D
- A45D2200/10—Details of applicators
- A45D2200/1009—Applicators comprising a pad, tissue, sponge, or the like
- A45D2200/1018—Applicators comprising a pad, tissue, sponge, or the like comprising a pad, i.e. a cushion-like mass of soft material, with or without gripping means
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
- A45D34/04—Appliances specially adapted for applying liquid, e.g. using roller or ball
Definitions
- the invention relates to a pen with a cap.
- Such pens include a reservoir for storing an application fluid and an applicator tip for applying the fluid to a surface.
- the coating fluid contains a volatile solvent at room temperature, which evaporates after application, thereby allowing the coating fluid to dry or film.
- the pins include a closure cap which is detachable therefrom for use with the pin and which has a cavity for receiving the applicator tip.
- Such pins are today known in various embodiments, e.g. in the form of writing instruments such as fillers, paint or Multimarkerlixen for applying ink or paint, but recently also in the form of cosmetic equipment such as nail polish or mascara applicators for applying about a paste.
- the applicator is e.g. a brush, a sponge, a brush or a fiber or sinter tip.
- the solvent for example, water, but also solvents such as ethyl acetate, butyl acetate, propyl acetate, ethanol, isopropanol, butyl alcohol or diacetone alcohol, for example, for nail polishes conceivable.
- Solvents are classified according to volatility or volatility, which describes the tendency of a solvent to evaporate. Volatile solvents are those with an evaporation number of less than 10, medium volatile ones with an evaporation number of 10 to less than 35 and low volatility ones with 35 or more. In the context of the present patent application, solvents with evaporation numbers below 35, in particular below 10 are considered.
- the object of the present invention is to provide an o.g. Pen to improve.
- the closure cap contains a storage space and a connecting channel fluidically connecting the storage space with the cavity, wherein the storage space serves to receive a volatile at room temperature sacrificial liquid.
- the sacrificial fluid contains this at least one solvent that evaporates from the liquid phase to the gaseous phase.
- the gaseous phase of the sacrificial liquid is hereinafter referred to as sacrificial solvent.
- the sacrificial liquid thus volatilizes to a sacrificial solvent and passes through the connecting channel into the cavity, where the latter surrounds the applicator tip when the cap is attached or soaks the cavity.
- the sacrificial liquid evaporates to a sacrificial solvent.
- This embodiment of the closure cap prevents the applicator tip or the application fluid from drying on it.
- the sacrificial liquid may be or contain the solvent of the application fluid.
- the sacrificial liquid may be or contain the solvent of the application fluid. In the plugged state of the cap so that the order fluid is surrounded with its own solvent, which, however, comes partly from the storage space.
- the vapor pressure of the sacrificial liquid or of the sacrificial solvent should be comparable or higher than the corresponding value of the application fluid or its components, ie the boiling point should be lower.
- the closure cap contains a sealing element which is movable between a sealing position closing the connecting channel and an opening position releasing the connecting channel.
- the sealing element is in this case movement-coupled to its movement between the opening and sealing position with a protruding into the cavity of the closure cap portion of the shaft of the pin.
- this shaft section moves the sealing element and releases or closes the connecting channel.
- the sealing element is mounted axially displaceably in the cap.
- the axial movement is a generally occurring when putting on or removing the pen cap basic movement. If the sealing element in the cap is also mounted axially displaceable, the Aufsteck- or Abzieh Gay or relative movement between the pin shaft and cap can be easily implemented by a simple movement coupling in the axial movement of the sealing element in the cap.
- the sealing element comprises a wall space delimiting the storage space from the cavity.
- the wall segment only leaves at least one longitudinal section of the connection channel free, so that it can extend through the wall segment or past it.
- the sealing member also includes a driver element cooperating with the shaft portion facing the cap opening to engage the shaft portion there. In other words, therefore, during the attachment or removal operation of the closure cap, the carrier element is moved by the shaft section, which in turn moves the closing mechanism of the sealing element, e.g. operated in the form of a movement of the wall segment.
- the wall segment as part of the sealing element can also be mounted axially displaceable in the closure cap.
- a gap is present between the inside of the closure cap and the wall segment, which forms at least one longitudinal section of the connection channel.
- the gap may in particular be an annular gap surrounding the wall segment.
- the annular gap can then be so small interpreted in terms of its width that, for example, liquid sacrificial liquid is retained by the annular gap in the storage space and only vaporous medium, so vaporized sacrificial liquid or sacrificial solvent can pass through the annular gap to the cavity.
- the annular gap then forms a diffusion path.
- the flow cross section of the gap can be smaller than that of the remaining connection channel.
- the gap then essentially determines the flow behavior of the connection channel.
- Sizing the gap ensures that the right amount of sacrificial solvent enters the cavity just enough to protect the applicator tip from drying out.
- the gap may be an annular gap in a preferred embodiment. This is easy to accomplish in particular for rotationally symmetric pins.
- a closure element is arranged on the inside of the closure cap, which closes the gap in the closed position of the sealing element.
- the sealing element moves sealingly against the closure element during its movement.
- This closure element may be a circumferential annular projection in a particularly preferred embodiment.
- Such acts for example, particularly easy with an annular gap surrounding the wall segment together by the wall segment in the manner of a piston, leaving the annular gap in the cylindrical Cover cap slides until it reaches the ring projection, which then closes the ring gap.
- a particularly compact design of the pin results when the sealing element is at least part of an inner cap disposed within the cap.
- a corresponding inner cap can be produced, for example, by injection molding in a particularly simple and cost-effective manner, is stable and forms the cavity on its inside, and in particular can be easily axially displaceably mounted in the closure cap.
- the connecting channel or at least a part thereof can then be formed particularly easily as an opening in the inner cap.
- the inner cap can then according to a development of the above embodiment with wall segment and driver element comprise these two components.
- the remote from the cap opening bottom of the inner cap can in this case represent the wall segment.
- In this area can then be formed between inner cap and cap of the annular gap.
- the extending away from the ground wall of the inner cap can then form the driver element or include this.
- the pin comprises a first axially effective positive locking, which limits the relative movement of the sealing element and the closure cap when removing it from the shaft.
- a second the movement coupling between the sealing element and shaft portion when removing the cap causing positive engagement is formed between these two elements.
- the first form-fitting has in this case in the axial direction seen a higher strength than the second.
- the following sequence of movements can be realized when removing the pin cap: A user grips the cap and begins to unscrew it from the pin or subtract it.
- the sealing element is further held firmly on the shaft via the second positive connection, as a result of which the removal movement of the closure cap initially leads to a relative movement of the closure cap and sealing element. Only when the closure cap is pulled off far enough from the pin or sealing element that the first positive locking engages, a further relative movement between the closure cap and sealing element is prevented.
- the second form closure is first triggered, i. the sealing element releases its movement coupling to the shaft. In other words, the cap is thereby released as a whole from the shaft.
- the connecting channel is first closed in this case, so that it is already closed during the detachment of the sealing element from the shaft.
- the sealing element is first pushed back into the cap and finally locked the sealing element on the shaft.
- both form-fit connections are formed in each case by radially overlapping projections on closure element and sealing element on the one hand and / or sealing element and shaft section on the other hand.
- first positive locking a stop element, which limits the relative movement of the sealing element and the cap when removing the cap from the pin and as a second positive locking a locking element, which initially holds the sealing element when removing the cap on the shaft.
- the latching force of the locking element is smaller than the abutment force of the stop element, which is why only the second positive locking dissolves when removing the cap when the first strikes.
- the first positive connection can be formed in particular by a stop arranged on the closure cap and a projection arranged on the sealing element.
- the second positive connection can be formed by a latching lug on the shaft portion and a latching projection on the sealing element.
- the closure cap has a cover which is coupled with the sealing element in a manner which, in the released state of the closure cap, conceals a section of the closure cap adjoining the opening.
- the closure cap in this section has a holding element that locks it to the shaft, eg a screw thread, a bayonet catch or a friction or snap connection.
- the cover covers this holding element in the released state of the cap. In other words, when the cap is removed from the pin, as explained above, the sealing element is moved, which in turn, via a movement coupling, guides the cover into a position concealing the retaining element.
- the storage space contains a storage element for the sacrificial liquid.
- This can e.g. be a fiber or sintered element.
- the sacrificial liquid is stored in the storage element.
- the membrane could also be e.g. the o.g. Fill or form the diffusion gap or channel.
- the membrane can then also serve for metering the amount of solvent delivered per time or be designed accordingly.
- the storage element may be a cartridge, that is to say a container filled with sacrificial liquid.
- the cartridge can be filled before the production of the entire pen and can be used in the filled state during assembly in the cap or the storage space.
- the cartridge is eg a liquid cartridge with wick.
- appropriate protective measures in particular fire or explosion protection measures must be provided.
- Advantage of using a cartridge is that the filling of the cartridge can be done in a separate process step. Only in the cartridge production and only then there are the protective measures to take, which is easier to accomplish than protective measures for the entire pin production. In the actual pin assembly then no protective measures are required because the cartridge can be delivered to the assembly line in the closed state. The pin assembly is therefore still easy and inexpensive to perform.
- the cartridge must be closed in such a way that the victim's solvent can reach the cap in a controlled manner.
- Conceivable is e.g. a membrane or a sintered disc.
- the cartridge should therefore be closed when delivered to the assembly line. Either you choose the wall thickness of the cartridge at least at one point so thin that it can then be pierced during assembly in the pen and thus creates a small opening. Although sacrificial liquid can not escape through this in the flowable state, liquid vapor can escape through it. It is alternatively conceivable that in the cartridge wall, an opening is present, which is closed after filling, such as a plastic film or the like. The closure element can then also be pierced or pulled off later. Another possibility is to close the opening of the cartridge with a material that is permeable to the liquid vapor.
- Such an opening must of course also be closed, such as with a glued foil or otherwise.
- a cartridge allows a larger amount of sacrificial liquid to be accommodated in the cap.
- a storage element no kappilar effective storage material be present, since the sacrificial liquid is already held by the cartridge.
- the cartridge can be inserted into the cap or its storage space through the conventional single opening of the cap, which also serves to place these on the pin.
- the closure cap in the region of the storage space has an opening in which the cartridge rests sealingly.
- the cartridge thus forms part of the closure cap or continues it in the region of the opening.
- the cartridge can then be easily inserted from the inside or outside into the cap when mounting the pin.
- At least a part of the cartridge is made in one piece with the above-mentioned inner cap.
- this is simply possible with injection molding technology, for which the cartridge does not then have to be made a separate component.
- At least a part of the connecting channel is formed as a capillary channel.
- a closure of the channel by a sealing element is then not necessary.
- a seal between inner and outer cap can then be used e.g. firmly mounted, so not be displaced.
- the inner cap must also e.g. not be slidably mounted in the cap.
- Capillary channels which open into the storage space are then located between the inner and closure cap or a gasket and the cap which is inserted between them. The capillary channels simultaneously open into the cavity so that sacrificial solvent can evaporate from the storage space through the channels into the cavity.
- the capillary channels can also narrow in the direction of the storage space. Sacrificial liquid can then not leak from the storage space because of the directed capillary force.
- the capillary channels may be formed by grooves or flats on the outside of the seal or the inside of the closure cap or the outside of the inside cap.
- Fig. 1 shows a pin 2 with a shaft 4, of which only the front part is shown.
- a cap 6 is placed with its opening 24, since the pin is currently not used, that is in a closed or storage position.
- the shaft 4 in this case closes the opening 24.
- the shaft 4 essentially comprises a base 8 or grip body of the pin 2 forming container 8 with a reservoir 10 for aconcentrfluid 12 with a solvent 13.
- the shaft also comprises a container 8 on the end face mounted shaft portion 14, which acts as an adapter and an applicator tip 16 carries.
- the applicator tip 16 is connected via a transport channel 18 to the reservoir 10 in connection, and is used in the use of the pin 2 for application of the application fluid 12.
- the pin is constructed substantially rotationally symmetrical about a central longitudinal axis 20.
- the cap 6 is designed as an outer cap 30 and includes an inner cap 32 which is inserted in the latter.
- the inner cap 32 is shorter by about one third than the outer cap 30 Fig. 1 is the inner cap 32 in the front end 34 of the outer cap 30 maximum advanced position.
- a storage space 40 Between the bottom 36 of the outer cap and the bottom 38 of the inner cap then remains a storage space 40, in which a storage element 42 rests.
- the storage element 42 is impregnated with a sacrificial liquid 44, from which at room temperature a sacrificial solvent 45 evaporates, which is distributed in the storage space 40.
- the inner cap 32 is essentially formed by a wall section in the form of a bottom 38 and a sleeve-shaped wall adjoining the wall section, which in turn constitutes a driver element 39 for the bottom 38.
- the storage element 42 is in the interior of the outer cap 30, ie held in the storage space 40 by three - or in an alternative embodiment a plurality - over the circumference of the cap 6 distributed clamping webs 46, of which Fig. 1 only two are visible.
- the opening 48 toward the ends 48 of the clamping webs 46 simultaneously form a stop for the inner cap 32 in the direction of the arrow 50 in the in Fig. 1 shown relative position of inner 32 and outer cap 30th
- the cap 32 is dimensioned slightly smaller than the inner diameter d i of the outer cap 30 on its inner side 51 in a head region acting as a sealing element 52 with respect to its outer diameter d a of its outer side 51.
- an annular gap 56 thus remains between outer cap 30 and inner cap 32 free.
- a channel 72 is formed, which connects the storage space 40 with the cavity 22.
- Fig. 2 the corresponding ratios are shown enlarged.
- sacrificial solvent 45 passes from the storage space 40 through the annular gap 56. Victim liquid 44, however, is retained because of the small dimensions of the clear width of the annular gap 56. Sacrificial solvent 45 therefore surrounds applicator tip 16 in cavity 22 to protect it from dehydration.
- annular gap 56 is centered over three - or in an alternative embodiment several - distributed around its circumference lugs 62 and attached to the inside 51 of the outer cap 30 ring seal 64.
- the individual lugs 62 also leave space between them for the formation of the channel 72.
- the ring seal 64 also limits the gap 58 in the illustrated open position 47 to the opening 24.
- the cavity 22, in turn, is sealed by a ring seal 66 attached to the inner side 63 of the inner cap 32 and acting on the shaft section 14.
- the outer cap 30 is sealed with another annular seal 68 again relative to the shaft 4 and container 8.
- both components are provided with a portion 70 which is designed in the embodiment as a screw thread.
- the cap 6 is first released by unscrewing the portion 70.
- the annular seal 64 overcomes an inwardly projecting shoulder 69 of the inner cap 32, which is why the frictional resistance between outer cap 30 and inner cap 32 decreases abruptly.
- the outer cap 30 is then removed further in the direction of the arrow 50.
- a relative movement takes place here between the outer cap 30 and the inner cap 32, since the inner cap 32 is initially held on the shaft section 14, ie initially remains in the unchanged position relative to the shaft 4. This is accomplished by locking lugs 80 arranged on the shaft section 14 on the outside, which engage behind a corresponding latching projection 82 on the inner cap 32.
- Fig. 3 shows the corresponding detail III.
- the outer cap 30 thus moves in the direction of the arrow 50 further and further away from the inner cap 32 until the sealing element 52 leaves the longitudinal section 54 and sealingly runs onto a closure element 84 arranged on the inner side 51 of the outer cap 30, which in the exemplary embodiment is designed as a ring seal ,
- a closure element 84 arranged on the inner side 51 of the outer cap 30, which in the exemplary embodiment is designed as a ring seal .
- Solvent 44 can not evaporate uselessly beyond the now no longer sealed relative to the environment gap 58.
- the relative movement between outer cap 30 and inner cap 32 ends, since the nose 62 abuts the ring seal 64.
- the ring seal 64 thus fulfills a double purpose as a stop 65 in addition to its sealing function. Further pulling on the outer cap 30 in the direction of the arrow 50 overcomes the latching force of the locking lugs 80 out of the Locking projections 82 and thus causes their release and thus a loosening of the entire cap 6 from the shaft 4 and shaft portion 14. The force applied to the outer cap 30 while overcome the cogging force, but not the higher impact force of the nose 62 on the stop 65th Fig. 4 5 therefore shows the channel 72 or the entire cap 6 in the now achieved sealing position 49.
- Fig. 6 shows the completely dissolved cap 6.
- the storage space 40 is closed by the annular seal 84 in cooperation with the sealing element 52 of the inner cap 32 tightly opposite the now communicating with the environment cavity 22 and the gap 58 to prevent unnecessary evaporation of the sacrificial liquid 44 .
- the end portion of the inner sleeve 32 forms an apron 86. This pushes when loosening the cap 6 by the relative movement of the outer sleeve 30 and inner sleeve 32 on the inside of the portion 70 of the outer sleeve 30.
- the screw thread for example, before contact with the Applicator tip 16 and thus protected from contamination, for example with the order fluid 12.
- Fig. 7 shows again in detail VII the stop of the nose 62 on the ring seal 64th
- Fig. 8 shows a cross section through the cap 6 and in particular the concentric engagement of the storage element 42 in the clamping webs 46 of the outer cap 30th
- Fig. 9 shows in opposite to the direction of the arrow 50 pulled out inner cap 32 of the outer cap 30 whose sealing engagement in the closure element 84th
- Fig. 10 shows the distributed over the circumference of the inner cap 32 lugs 62, which serve to engage behind the annular seal 64.
- the shaft portion 14 When placing the cap 6 on the shaft 4, the shaft portion 14 first comes into contact with the inner cap 32 and exerts a force in the direction of the arrow 50, which is why a relative movement between the inner cap 32 and the outer cap 30 takes place in this direction.
- the sealing element 52 slides off the closure element 84 and releases the annular gap 56 or the channel 72. The relative movement is continued until the now released by the skirt 86 thread in section 70 engages.
- the inner cap 32 slides further into the outer cap 30 until it reaches the ends 48 of the clamping webs 46 with its bottom 38 and abuts there. Finally, then snap the locking lugs 80 behind the locking projections 82, wherein at the same time the cap 6 by means of the screw thread finally and under engagement of all seals 64,66 and 68 sealingly on the shaft 4 passes.
- Fig. 11 shows a section of an alternative cap 6.
- a cartridge 90 is clamped at the bottom 36 in the storage space 40 with the aid of the clamping webs 46.
- the cartridge 90 encloses with a diffusion-tight wall 94 a reservoir 92 for sacrificial liquid 44.
- the membrane or sintered disc is sealed, for example, with the wall 94 sealing.
- this contains no cartridge 90.
- the storage space 40 is then filled with sacrificial liquid 44 alone.
- the inner cap 32 is fixed, so not slidably disposed in the outer cap 30. This is e.g. accomplished by a suitable, not shown clamping device between the two partial caps.
- the channel 72 then exerts a capillary force on the sacrificial liquid 44 and tapers in the direction of the arrow 50. This prevents leakage of sacrificial liquid 44 from the storage space 40, but ensures its evaporation.
- Fig. 12 shows an alternative embodiment of a cartridge 90, wherein the wall 94 is integral with the inner cap 32 and its bottom 38 is executed.
- the membrane 96 is opposite Fig. 11 here the floor 36 faces. Because like in Fig. 11 also in Fig. 12 the cartridge 90 does not completely fill the storage space 40, in turn sacrificial solvent 45 may pass through the channel 72 into the cavity 22 in a known manner.
- FIG. 12 an alternative embodiment of the cap 6 is conceivable in which the inner cap 32 fixed, so not slidably mounted in the outer cap 30.
- the inner cap 32 fixed, so not slidably mounted in the outer cap 30.
- a channel 72 is no longer there.
- a capillary channel 106 is embedded in the bottom 38, which forms the channel 72 for the diffusion of sacrificial solvent 45 and sacrificial liquid 44, respectively. This then passes through the channel 106 directly from the storage space 40 into the cavity 22.
- the no longer required membrane 96 is replaced by a sealing wall section 108.
- Fig. 13 shows a further alternative embodiment of a cartridge 90.
- the bottom 38 of the cap 6 is provided with an opening 98, which, however, is closed by the cartridge 90 again.
- the cartridge 90 is pressed here in the assembly of the pin 2 against the direction of the arrow 50 in the outer cap 30 until it abuts sealingly with a projection 100 on a stop 102.
- the wall 94 is broken in the region of the bottom 38 and at this point a transparent window 104 is inserted. This allows an optical level control of the cartridge 90 with respect to the sacrificial liquid 44. It is also conceivable to make the entire container, ie in particular the entire wall 94, transparent.
- Fig. 14 shows an alternative embodiment of the cartridge 90 to Fig. 13 , wherein here only projection 100 and stop 102 are executed in the opposite direction, so that during assembly of the pin 2, the cartridge 90 is inserted in the direction of the arrow 50 in the outer cap 3.
Description
Die Erfindung betrifft einen Stift mit einer Verschlusskappe.The invention relates to a pen with a cap.
Derartige Stifte umfassen ein Reservoir zum Bevorraten eines Auftragsfluids und eine Applikatorspitze zum Auftragen des Fluids auf eine Oberfläche. Das Auftragsfluid enthält ein bei Raumtemperatur flüchtiges Lösungsmittel, das nach dem Auftragen verdunstet und dadurch ein Antrocknen bzw. eine Filmbildung des Auftragsfluids ermöglicht. Die Stifte umfassen eine Verschlusskappe, welche zum Gebrauch des Stiftes von diesem abnehmbar ist, und die einen zur Aufnahme der Applikatorspitze umfassenden Hohlraum aufweist.Such pens include a reservoir for storing an application fluid and an applicator tip for applying the fluid to a surface. The coating fluid contains a volatile solvent at room temperature, which evaporates after application, thereby allowing the coating fluid to dry or film. The pins include a closure cap which is detachable therefrom for use with the pin and which has a cavity for receiving the applicator tip.
Derartige Stifte sind heute in mannigfaltigen Ausführungsformen bekannt, z.B. in Form von Schreibgeräten wie Füllern, Lack- oder Multimarkerstiften zum Auftragen von Tinte oder Lack, neuerdings aber auch in Form von Kosmetikgeräten wie Nagellack- oder Maskaraapplikatoren zum Auftragen etwa einer Paste. Der Applikator ist z.B. eine Bürste, ein Schwamm, ein Pinsel oder eine Faser- oder Sinterspitze. Für das Lösungsmittel sind beispielsweise Wasser, aber auch Lösungsmittel wie Ethylacetat, Butylacetat, Propylacetat, Ethanol, Isopropanol, Butylalkohol oder Diacetonalkohol, beispielsweise für Nagellacke, denkbar.Such pins are today known in various embodiments, e.g. in the form of writing instruments such as fillers, paint or Multimarkerstiften for applying ink or paint, but recently also in the form of cosmetic equipment such as nail polish or mascara applicators for applying about a paste. The applicator is e.g. a brush, a sponge, a brush or a fiber or sinter tip. For the solvent, for example, water, but also solvents such as ethyl acetate, butyl acetate, propyl acetate, ethanol, isopropanol, butyl alcohol or diacetone alcohol, for example, for nail polishes conceivable.
Lösungsmittel werden nach Flüchtigkeit oder Volatilität bzw. Verdunstungszahl eingeteilt, die das Bestreben eines Lösungsmittels zur Verdunstung beschreibt. Leichtflüchtige Lösungsmittel sind solche mit einer Verdunstungszahl von unter 10, mittelflüchtige solche mit einer Verdunstungszahl von 10 bis unter 35 und schwerflüchtige solche mit 35 oder mehr. Im Rahmen der vorliegenden Patentanmeldung werden Lösungsmittel mit Verdunstungszahlen unter 35, insbesondere unter 10 betrachtet.Solvents are classified according to volatility or volatility, which describes the tendency of a solvent to evaporate. Volatile solvents are those with an evaporation number of less than 10, medium volatile ones with an evaporation number of 10 to less than 35 and low volatility ones with 35 or more. In the context of the present patent application, solvents with evaporation numbers below 35, in particular below 10 are considered.
Problematisch bei den beschriebenen Stiften ist, dass trotz aufgesetzter Verschlusskappe ein Eintrocknen der Applikatorspitze zu beobachten ist. Dies liegt einerseits daran, dass ein völlig gasdichter Sitz der Verschlusskappe auf den Stift mit vertretbarem Aufwand nicht zu erreichen ist. Andererseits kann vor allem bei aus Kunststoff gefertigten Verschlusskappen Lösemittel auch durch das Material der Verschlusskappe diffundieren.A problem with the described pins is that despite the attached cap drying the applicator tip is observed. This is partly due to the fact that a completely gas-tight fit of the cap on the pen with reasonable effort can not be achieved. On the other hand, solvent can also diffuse through the material of the cap especially in plastic caps.
Aus der
Aus der
Aus der
Aufgabe der vorliegenden Erfindung ist es, einen o.g. Stift zu verbessern.The object of the present invention is to provide an o.g. Pen to improve.
Die Erfindung beruht auf der generellen Idee, dass bei einem Stift der eingangs genannten Art die Verschlusskappe einen Speicherraum und einen den Speicherraum mit dem Hohlraum fluidisch verbindenden Verbindungskanal enthält, wobei der Speicherraum zur Aufnahme einer bei Raumtemperatur flüchtigen Opferflüssigkeit dient. Die Opferflüssigkeit enthält hierbei zumindest ein Lösemittel, das aus der flüssigen Phase in die gasförmige Phase verdampft. Die gasförmige Phase der Opferflüssigkeit wird im Folgenden kurz als Opferlösemittel bezeichnet.The invention is based on the general idea that in a pen of the type mentioned, the closure cap contains a storage space and a connecting channel fluidically connecting the storage space with the cavity, wherein the storage space serves to receive a volatile at room temperature sacrificial liquid. The sacrificial fluid contains this at least one solvent that evaporates from the liquid phase to the gaseous phase. The gaseous phase of the sacrificial liquid is hereinafter referred to as sacrificial solvent.
Die Opferflüssigkeit verflüchtigt sich also zu einem Opferlösemittel und gelangt durch den Verbindungskanal in den Hohlraum, wo letzteres bei aufgesetzter Verschlusskappe die Applikatorspitze umgibt bzw. den Hohlraum tränkt. Anstelle des Lösungsmittels des Auftragsfluids verdampft dann mit anderen Worten die Opferflüssigkeit zu einem Opferlösemittel. Durch diese Ausgestaltung der Verschlusskappe wird ein Eintrocknen der Applikatorspitze bzw. des Auftragsfluids an dieser verhindert.The sacrificial liquid thus volatilizes to a sacrificial solvent and passes through the connecting channel into the cavity, where the latter surrounds the applicator tip when the cap is attached or soaks the cavity. In other words, instead of the solvent of the application fluid, the sacrificial liquid evaporates to a sacrificial solvent. This embodiment of the closure cap prevents the applicator tip or the application fluid from drying on it.
Im Hohlraum addieren sich also die Dampfdrücke des Lösungsmittels der Auftragsflüssigkeit und der Dampfdruck der Opferflüssigkeit. Die Gas- bzw. Dampfphase im Hohlraum der Verschlusskappe wird somit sowohl aus der Opferflüssigkeit als auch aus dem Lösungsmittel der Auftragsflüssigkeit geliefert. Dementsprechend geht eine Leckage aufgrund einer Undichtigkeit zwischen Verschlusskappe und Stiftschaft zu Lasten des Lösungsmittels der Auftragsflüssigkeit und der Opferflüssigkeit. Auf diese Weise wird erreicht, dass die Applikatorspitze selbst nicht eintrocknen kann bzw. das Eintrocknen zeitlich verzögert wird. Zum Anderen ist ein Eindicken der Auftragsflüssigkeit aufgrund Lösungsmittelverlustes verhindert bzw. verzögert.In the cavity, therefore, add the vapor pressures of the solvent of the coating liquid and the vapor pressure of the sacrificial liquid. The gas or vapor phase in the cavity of the closure cap is thus supplied both from the sacrificial liquid and from the solvent of the application liquid. Accordingly, leakage due to leakage between the cap and pen shank is at the expense of the solvent of the application liquid and the sacrificial liquid. In this way it is achieved that the applicator tip itself can not dry or the drying is delayed in time. On the other hand, thickening of the application liquid due to solvent loss is prevented or delayed.
Die Opferflüssigkeit kann das Lösungsmittel des Auftragsfluids sein bzw. enthalten. Im aufgesteckten Zustand der Abdeckkappe ist damit das Auftragsfluid mit seinem eigenen Lösungsmittel umgeben, welches jedoch zum Teil aus dem Speicherraum stammt.The sacrificial liquid may be or contain the solvent of the application fluid. In the plugged state of the cap so that the order fluid is surrounded with its own solvent, which, however, comes partly from the storage space.
Ein Verdampfen von Lösungsmittel aus dem Auftragsfluid bzw. Eintrocknen der Applikatorspitze ist so besonders wirkungsvoll vermieden.Evaporation of solvent from the coating fluid or drying of the applicator tip is thus particularly effectively avoided.
Generell sollte der Dampfdruck der Opferflüssigkeit bzw. des Opferlösemittels dem entsprechenden Wert des Auftragsfluids bzw. dessen Komponenten vergleichbar oder höher sein, also der Siedepunkt geringer.In general, the vapor pressure of the sacrificial liquid or of the sacrificial solvent should be comparable or higher than the corresponding value of the application fluid or its components, ie the boiling point should be lower.
Gemäß der Erfindung enthält die Verschlusskappe ein Dichtelement, das zwischen einer den Verbindungskanal verschließenden Dichtstellung und einer den Verbindungskanal freigebenden Öffnungsstellung bewegbar ist. Das Dichtelement ist hierbei zu seiner Bewegung zwischen Öffnungs- und Dichtstellung mit einem in den Hohlraum der Verschlusskappe ragenden Abschnitt des Schaftes des Stifts bewegungsgekoppelt. Mit anderen Worten bewegt dieser Schaftabschnitt beim Aufsetzen bzw. Abziehen der Abdeckkappe durch die Bewegungskopplung das Dichtelement und gibt den Verbindungskanal frei bzw. verschließt diesen. So ist im aufgesetztem Zustand der Verschlusskappe der Verbindungskanal geöffnet, so dass sich - wie oben beschrieben - Opferflüssigkeit verflüchtigen und zur Applikatorspitze gelangen kann. Bei abgenommener Verschlusskappe steht der Hohlraum mit der Umgebung in Verbindung. Durch den geschlossenen Verbindungskanal gelangt aber dann kein Opferlösemittel zum Hohlraum und von dort in die Umgebung. Eine unnötige Freisetzung sich verflüchtigender Opferflüssigkeit in die Umgebung ist also verhindert. Diese bzw. das Opferlösemittel verbleibt in dem nun von der Außenumgebung abgeschlossenen Speicherraum. Da die Betätigung durch den Stiftschaft erfolgt, bleibt die Stiftspitze mechanisch unbelastet. Dies ist z.B. für feine Faserspitzen wichtig, die nicht deformiert werden dürfen.According to the invention, the closure cap contains a sealing element which is movable between a sealing position closing the connecting channel and an opening position releasing the connecting channel. The sealing element is in this case movement-coupled to its movement between the opening and sealing position with a protruding into the cavity of the closure cap portion of the shaft of the pin. In other words, when the cover cap is put on or removed by the movement coupling, this shaft section moves the sealing element and releases or closes the connecting channel. Thus, in the attached state of the closure cap, the connection channel is opened, so that - as described above - the sacrificial liquid can volatilize and reach the tip of the applicator. When the cap is removed, the cavity communicates with the environment. But then no sacrificial solvent passes through the closed connection channel to the cavity and from there into the environment. An unnecessary release of volatilizing sacrificial fluid into the environment is therefore prevented. This or the victim solvent remains in the now closed from the outside environment storage space. Since the actuation is done by the pen shaft, the pen tip remains mechanically unloaded. This is important, for example, for fine fiber tips that must not be deformed.
Gemäß der Erfindung ist das Dichtelement in der Kappe axial verschiebbar gelagert. Die Axialbewegung ist eine generell beim Aufsetzen bzw. Abziehen der Stiftkappe erfolgende Grundbewegung. Wenn das Dichtelement in der Verschlusskappe ebenfalls axial verschiebbar gelagert ist, lässt sich die Aufsteck- bzw. Abziehbewegung oder Relativbewegung zwischen Stiftschaft und Verschlusskappe leicht durch eine einfache Bewegungskopplung in die Axialbewegung des Dichtelements in der Verschlusskappe umsetzen.According to the invention, the sealing element is mounted axially displaceably in the cap. The axial movement is a generally occurring when putting on or removing the pen cap basic movement. If the sealing element in the cap is also mounted axially displaceable, the Aufsteck- or Abziehbewegung or relative movement between the pin shaft and cap can be easily implemented by a simple movement coupling in the axial movement of the sealing element in the cap.
Gemäß der Erfindung umfasst das Dichtelement ein den Speicherraum vom Hohlraum abgrenzendes Wandsegment. Das Wandsegment lässt hierbei lediglich zumindest einen Längsabschnitt des Verbindungskanals frei, damit sich dieser durch das Wandsegment oder an diesem vorbei erstrecken kann. Das Dichtelement umfasst außerdem ein mit dem Schaftabschnitt zusammenwirkendes Mitnehmerelement, das der Kappenöffnung zugewandt ist, um dort mit dem Schaftabschnitt in Eingriff zu treten. Mit anderen Worten wird also beim Aufsteck- bzw. Abziehvorgang der Verschlusskappe das Mitnehmerelement vom Schaftabschnitt bewegt, welches wiederum den Verschließmechanismus des Dichtelements, z.B. in Form einer Bewegung des Wandsegments betätigt. Das Wandsegment als Teil des Dichtelements kann ebenfalls axial verschiebbar in der Verschlusskappe gelagert sein.According to the invention, the sealing element comprises a wall space delimiting the storage space from the cavity. In this case, the wall segment only leaves at least one longitudinal section of the connection channel free, so that it can extend through the wall segment or past it. The sealing member also includes a driver element cooperating with the shaft portion facing the cap opening to engage the shaft portion there. In other words, therefore, during the attachment or removal operation of the closure cap, the carrier element is moved by the shaft section, which in turn moves the closing mechanism of the sealing element, e.g. operated in the form of a movement of the wall segment. The wall segment as part of the sealing element can also be mounted axially displaceable in the closure cap.
Gemäß der Erfindung ist zwischen der Innenseite der Verschlusskappe und dem Wandsegment ein Spalt vorhanden, der zumindest einen Längsabschnitt des Verbindungskanals bildet. Der Spalt kann hierbei insbesondere ein das Wandsegment umgebender Ringspalt sein. Der Ringspalt kann dann bezüglich seiner Weite so gering ausgelegt werden, dass z.B. flüssige Opferflüssigkeit durch den Ringspalt im Speicherraum zurückgehalten wird und nur dampfförmiges Medium, also verdampfte Opferflüssigkeit bzw. Opferlösemittel durch den Ringspalt zum Hohlraum gelangen kann. Der Ringspalt bildet dann eine Diffusionsstrecke.According to the invention, a gap is present between the inside of the closure cap and the wall segment, which forms at least one longitudinal section of the connection channel. In this case, the gap may in particular be an annular gap surrounding the wall segment. The annular gap can then be so small interpreted in terms of its width that, for example, liquid sacrificial liquid is retained by the annular gap in the storage space and only vaporous medium, so vaporized sacrificial liquid or sacrificial solvent can pass through the annular gap to the cavity. The annular gap then forms a diffusion path.
Insbesondere kann dabei der Strömungsquerschnitt des Spalts geringer sein als der des restlichen Verbindungkanals. Der Spalt bestimmt dann wesentlich das Strömungsverhalten des Verbindungskanals. So kann z.B. durch Dimensionierung des Spalts sichergestellt werden, dass die richtige Menge Opferlösemittel gerade schnell genug in den Hohlraum gelangt, um die Applikatorspitze vor Austrockung zu schützen.In particular, the flow cross section of the gap can be smaller than that of the remaining connection channel. The gap then essentially determines the flow behavior of the connection channel. Thus, e.g. Sizing the gap ensures that the right amount of sacrificial solvent enters the cavity just enough to protect the applicator tip from drying out.
Der Spalt kann in einer bevorzugten Ausführungsform ein Ringspalt sein. Dieser ist insbesondere für rotationssymmetrische Stifte einfach zu bewerkstelligen.The gap may be an annular gap in a preferred embodiment. This is easy to accomplish in particular for rotationally symmetric pins.
Bei Vorhandensein eines entsprechenden Spalts ist bei einer weiteren bevorzugten Ausführungsform ein Verschlusselement an der Innenseite der Verschlusskappe angeordnet, welches in der Schließstellung des Dichtelements den Spalt verschließt. Mit anderen Worten fährt das Dichtelement bei seiner Bewegung gegen das Verschlusselement dichtend an.In the presence of a corresponding gap, in a further preferred embodiment, a closure element is arranged on the inside of the closure cap, which closes the gap in the closed position of the sealing element. In other words, the sealing element moves sealingly against the closure element during its movement.
Dieses Verschlusselement kann in einer besonders bevorzugten Ausführungsform ein umlaufender Ringvorsprung sein. Ein solcher wirkt z.B. besonders einfach mit einem das Wandsegment umgebenden Ringspalt zusammen, indem das Wandsegment nach Art eines Kolbens unter Freilassung des Ringspalts in der zylinderförmigen Abdeckkappe gleitet, bis dieses auf den Ringvorsprung auffährt, der dann den Ringspalt verschließt.This closure element may be a circumferential annular projection in a particularly preferred embodiment. Such acts, for example, particularly easy with an annular gap surrounding the wall segment together by the wall segment in the manner of a piston, leaving the annular gap in the cylindrical Cover cap slides until it reaches the ring projection, which then closes the ring gap.
Eine besonders kompakte Ausgestaltung des Stiftes ergibt sich, wenn das Dichtelement zumindest Teil einer innerhalb der Verschlusskappe angeordneten Innenkappe ist. Eine entsprechende Innenkappe kann beispielsweise spritzgusstechnisch besonders einfach und kostengünstig hergestellt werden, ist dabei stabil und bildet an ihrer Innenseite den Hohlraum und kann insbesondere einfach axial verschiebbar in der Verschlusskappe gelagert werden. Der Verbindungskanal oder zumindest ein Teil dessen kann dann besonders einfach als Durchbrechung in der Innenkappe gebildet sein.A particularly compact design of the pin results when the sealing element is at least part of an inner cap disposed within the cap. A corresponding inner cap can be produced, for example, by injection molding in a particularly simple and cost-effective manner, is stable and forms the cavity on its inside, and in particular can be easily axially displaceably mounted in the closure cap. The connecting channel or at least a part thereof can then be formed particularly easily as an opening in the inner cap.
Die Innenkappe kann dann auch gemäß einer Weiterbildung der oben genannten Ausführungsform mit Wandsegment und Mitnehmerelement diese beiden Bauteile umfassen. Der von der Kappenöffnung abgewandte Boden der Innenkappe kann hierbei das Wandsegment darstellen. In diesem Bereich kann dann zwischen Innenkappe und Verschlusskappe der Ringspalt gebildet sein. Die sich vom Boden wegerstreckende Wandung der Innenkappe kann dann das Mitnehmerelement bilden bzw. dieses beinhalten.The inner cap can then according to a development of the above embodiment with wall segment and driver element comprise these two components. The remote from the cap opening bottom of the inner cap can in this case represent the wall segment. In this area can then be formed between inner cap and cap of the annular gap. The extending away from the ground wall of the inner cap can then form the driver element or include this.
In einer weiteren bevorzugten Ausführungsform der Erfindung umfasst der Stift einen ersten axial wirksamen Formschluss, der die Relativbewegung von Dichtelement und Verschlusskappe beim Abnehmen dieser vom Schaft begrenzt. Ein zweiter, die Bewegungskopplung zwischen Dichtelement und Schaftabschnitt beim Abziehen der Verschlusskappe bewirkender Formschluss ist zwischen diesen beiden Elementen gebildet. Der erste Formschluss weist hierbei in Axialrichtung gesehen eine höhere Festigkeit auf als der zweite.In a further preferred embodiment of the invention, the pin comprises a first axially effective positive locking, which limits the relative movement of the sealing element and the closure cap when removing it from the shaft. A second, the movement coupling between the sealing element and shaft portion when removing the cap causing positive engagement is formed between these two elements. The first form-fitting has in this case in the axial direction seen a higher strength than the second.
Durch eine entsprechende Ausgestaltung des Stiftes lässt sich beim Abnehmen der Stiftkappe folgender Bewegungsablauf realisieren: Ein Benutzer greift die Verschlusskappe und beginnt diese vom Stift abzuschrauben bzw. abzuziehen. Hierbei wird das Dichtelement über den zweiten Formschluss weiterhin fest am Schaft gehalten, wodurch die Abziehbewegung der Verschlusskappe zunächst zu einer Relativbewegung von Verschlusskappe und Dichtelement führt. Erst wenn die Verschlusskappe soweit vom Stift bzw. Dichtelement abgezogen ist, dass der erste Formschluss greift, ist eine weitere Relativbewegung zwischen Verschlusskappe und Dichtelement verhindert. Durch weiteres Aufwenden von Kraft bei der Abziehbewegung auf die Verschlusskappe wird jedoch zuerst der zweite Formschluss ausgelöst, d.h. das Dichtelement löst seine Bewegungskopplung zum Schaft. Mit anderen Worten wird dadurch die Verschlusskappe als Ganzes vom Schaft gelöst.By a corresponding design of the pin, the following sequence of movements can be realized when removing the pin cap: A user grips the cap and begins to unscrew it from the pin or subtract it. In this case, the sealing element is further held firmly on the shaft via the second positive connection, as a result of which the removal movement of the closure cap initially leads to a relative movement of the closure cap and sealing element. Only when the closure cap is pulled off far enough from the pin or sealing element that the first positive locking engages, a further relative movement between the closure cap and sealing element is prevented. However, by further applying force in the peel-off motion on the closure cap, the second form closure is first triggered, i. the sealing element releases its movement coupling to the shaft. In other words, the cap is thereby released as a whole from the shaft.
Durch die entsprechende Relativbewegung zwischen Verschlusskappe und Dichtelement wird in diesem Fall zuerst der Verbindungskanal verschlossen, so dass dieser bereits beim Ablösen des Dichtelements vom Schaft verschlossen ist. Beim Aufstecken der Verschlusskappe auf den Stift wird zunächst das Dichtelement wieder in die Verschlusskappe zurückgeschoben und abschließend das Dichtelement am Schaft verrastet.By the corresponding relative movement between the closure cap and the sealing element, the connecting channel is first closed in this case, so that it is already closed during the detachment of the sealing element from the shaft. When attaching the cap on the pin, the sealing element is first pushed back into the cap and finally locked the sealing element on the shaft.
In einer bevorzugten Ausführungsform sind beide Formschlüsse jeweils durch sich radial überlappende Vorsprünge an Verschlusselement und Dichtelement einerseits bzw. Dichtelement und Schaftabschnitt andererseits gebildet.In a preferred embodiment, both form-fit connections are formed in each case by radially overlapping projections on closure element and sealing element on the one hand and / or sealing element and shaft section on the other hand.
Denkbar ist z.B. als erster Formschluss ein Anschlagelement, welches die Relativbewegung von Dichtelement und Verschlusskappe beim Abnehmen der Verschlusskappe vom Stift begrenzt und als zweiter Formschluss ein Rastelement, welches das Dichtelement beim Abnehmen der Verschlusskappe zunächst am Schaft hält. Die Rastkraft des Rastelementes ist hierbei kleiner als die Anschlagkraft des Anschlagelements, weshalb sich beim Abziehen der Verschlusskappe nur der zweite Formschluss löst, wenn der erste anschlägt.It is conceivable, e.g. as the first positive locking a stop element, which limits the relative movement of the sealing element and the cap when removing the cap from the pin and as a second positive locking a locking element, which initially holds the sealing element when removing the cap on the shaft. The latching force of the locking element is smaller than the abutment force of the stop element, which is why only the second positive locking dissolves when removing the cap when the first strikes.
Der erste Formschluss kann insbesondere durch einen an der Verschlusskappe angeordneten Anschlag und einen am Dichtelement angeordneten Vorsprung gebildet sein. Der zweite Formschluss kann durch eine Rastnase am Schaftabschnitt und einen Rastvorsprung am Dichtelement gebildet sein. Eine derartige Lösung ist z.B. spritzgusstechnisch leicht zu realisieren.The first positive connection can be formed in particular by a stop arranged on the closure cap and a projection arranged on the sealing element. The second positive connection can be formed by a latching lug on the shaft portion and a latching projection on the sealing element. Such a solution is e.g. injection molding technically easy to implement.
In einer weiteren bevorzugten Ausführungsform verfügt die Verschlusskappe über eine mit dem Dichtelement bewegungsgekoppelte Abdeckung, die im gelösten Zustand der Verschlusskappe einen an die Öffnung anschließenden Abschnitt der Verschlusskappe verdeckt. In der Regel verfügt die Verschlusskappe in diesem Abschnitt über ein diese am Schaft arretierendes Halteelement, z.B. ein Schraubgewinde, einen Bajonettverschluss oder eine Reib- oder Schnappverbindung. Die Abdeckung verdeckt dann dieses Halteelement im gelösten Zustand der Verschlusskappe. Mit anderen Worten wird beim Abziehen der Verschlusskappe vom Stift wie oben erläutert das Dichtelement bewegt, welches wiederum über eine Bewegungskopplung die Abdeckung in eine das Halteelement verdeckende Position führt. Beim späteren Aufsetzen der Verschlusskappe auf den Stift ist also das Halteelement zunächst verdeckt, weshalb dieses, also z.B. das Gewinde, nicht mit Auftragsfluid verschmutzt werden kann. Durch die Aufsteckbewegung und die entsprechende Bewegungskopplung mit dem Dichtelement wird die Abdeckung während des Aufsteckens der Verschlusskappe vom Halteelement weg bewegt, so dass das Halteelement schließlich am Stift greifen kann, um die Verschlusskappe an diesem zu arretieren.In a further preferred embodiment, the closure cap has a cover which is coupled with the sealing element in a manner which, in the released state of the closure cap, conceals a section of the closure cap adjoining the opening. As a rule, the closure cap in this section has a holding element that locks it to the shaft, eg a screw thread, a bayonet catch or a friction or snap connection. The cover then covers this holding element in the released state of the cap. In other words, when the cap is removed from the pin, as explained above, the sealing element is moved, which in turn, via a movement coupling, guides the cover into a position concealing the retaining element. During subsequent placement of the cap on the pin so the holding element is initially hidden, which is why this, so for example the Thread, can not be contaminated with application fluid. By Aufsteckbewegung and the corresponding movement coupling with the sealing element, the cover is moved during the attachment of the cap from the holding element, so that the holding element can finally engage the pin to lock the cap on this.
In einer weiteren bevorzugten Ausführungsform der Erfindung enthält der Speicherraum ein Speicherelement für die Opferflüssigkeit. Dies kann z.B. ein Faser- oder Sinterelement sein. Innerhalb des Speicherraums ist dann die Opferflüssigkeit im Speicherelement bevorratet.In a further preferred embodiment of the invention, the storage space contains a storage element for the sacrificial liquid. This can e.g. be a fiber or sintered element. Within the storage space then the sacrificial liquid is stored in the storage element.
Denkbar ist aber auch, den Speicherraum durch eine semipermeable Membran zu verschließen, um so ein Rückhaltevolumen für die Opferflüssigkeit zu schaffen. Die Membran könnte auch z.B. den o.g. Diffusionsspalt bzw. -kanal ausfüllen oder diesen bilden. Die Membran kann dann auch zur Dosierung der pro Zeit abgegebenen Menge an Lösungsmittel dienen bzw. entsprechend ausgelegt werden.It is also conceivable to close the storage space by a semi-permeable membrane in order to create a retention volume for the sacrificial liquid. The membrane could also be e.g. the o.g. Fill or form the diffusion gap or channel. The membrane can then also serve for metering the amount of solvent delivered per time or be designed accordingly.
Das Speicherelement kann in einer bevorzugten Ausführungsform eine Kartusche, also ein mit Opferflüssigkeit gefüllter Behälter sein. So muss nicht die gesamte Verschlusskappe, sondern lediglich die Kartusche zur Aufbewahrung der Opferflüssigkeit geeignet, z.B. entsprechend materialverträglich ausgestaltet sein. Außerdem ergibt sich der Vorteil, dass die Kartusche bereits vor Fertigung des gesamten Stiftes gefüllt werden kann und im gefüllten Zustand bei der Montage in die Verschlusskappe bzw. den Speicherraum eingesetzt werden kann. Die Kartusche ist hierbei z.B. eine Flüssigkeitskartusche mit Docht.In a preferred embodiment, the storage element may be a cartridge, that is to say a container filled with sacrificial liquid. Thus, not the entire cap, but only the cartridge for storing the sacrificial liquid suitable, eg designed to be compatible with materials. In addition, there is the advantage that the cartridge can be filled before the production of the entire pen and can be used in the filled state during assembly in the cap or the storage space. The cartridge is eg a liquid cartridge with wick.
Die als Opferflüssigkeit in Frage kommenden organischen Lösungsmittel besitzen einen hohen Dampfdruck, sind oft gesundheitsschädlich und vor allen Dingen leicht entzündbar. Beim Umgang mit derartigen Stoffen müssen entsprechende Schutzmaßnahmen, insbesondere Brand- oder Explosionsschutzmaßnahmen vorgesehen werden. Vorteil bei der Verwendung einer Kartusche ist, dass das Befüllen der Kartusche in einem separaten Verfahrensschritt erfolgen kann. Nur bei der Kartuschenfertigung und nur dort sind dann auch die Schutzmaßnahmen zu treffen, was einfacher zu bewerkstelligen ist als Schutzmaßnahmen für die gesamte Stiftfertigung. Bei der eigentlichen Stiftmontage sind dann keine Schutzmaßnahmen mehr erforderlich, weil die Kartusche im geschlossenen Zustand an das Montageband angeliefert werden kann. Die Stiftmontage ist daher weiterhin einfach und unaufwändig durchzuführen. Die Kartusche muss so verschlossen werden, dass das Opferlösemittel kontrolliert in die Verschlusskappe gelangen kann. Denkbar ist hier z.B. eine Membran oder eine gesinterte Scheibe.The organic solvents which are suitable as sacrificial liquid have a high vapor pressure, are often harmful to health and, above all, highly flammable. When handling such substances appropriate protective measures, in particular fire or explosion protection measures must be provided. Advantage of using a cartridge is that the filling of the cartridge can be done in a separate process step. Only in the cartridge production and only then there are the protective measures to take, which is easier to accomplish than protective measures for the entire pin production. In the actual pin assembly then no protective measures are required because the cartridge can be delivered to the assembly line in the closed state. The pin assembly is therefore still easy and inexpensive to perform. The cartridge must be closed in such a way that the victim's solvent can reach the cap in a controlled manner. Conceivable here is e.g. a membrane or a sintered disc.
Die Kartusche sollte also bei der Anlieferung an das Montageband geschlossen sein. Entweder man wählt die Wandstärke der Kartusche zumindest an einer Stelle so dünn, dass sie dann bei der Montage im Stift angestochen werden kann und dadurch eine kleine Öffnung entsteht. Durch diese kann dann Opferflüssigkeit zwar nicht im fließfähigen Zustand, wohl aber Flüssigkeitsdampf entweichen. Denkbar ist alternativ, dass in der Kartuschenwand eine Öffnung vorhanden ist, die nach Befüllen verschlossen wird, etwa durch eine Kunststofffolie oder dergleichen. Das Verschlusselement kann dann später ebenfalls durchstochen oder abgezogen werden. Eine weitere Möglichkeit besteht darin, die Öffnung der Kartusche mit einem Material zu verschließen, das für den Flüssigkeitsdampf durchlässig ist.The cartridge should therefore be closed when delivered to the assembly line. Either you choose the wall thickness of the cartridge at least at one point so thin that it can then be pierced during assembly in the pen and thus creates a small opening. Although sacrificial liquid can not escape through this in the flowable state, liquid vapor can escape through it. It is alternatively conceivable that in the cartridge wall, an opening is present, which is closed after filling, such as a plastic film or the like. The closure element can then also be pierced or pulled off later. Another possibility is to close the opening of the cartridge with a material that is permeable to the liquid vapor.
Eine derartige Öffnung muss natürlich ebenfalls verschlossen sein, etwa mit einer angeklebten Folie oder auf sonstige Weise.Such an opening must of course also be closed, such as with a glued foil or otherwise.
Ein weiterer Vorteil einer Kartusche ist, dass sich so eine größere Menge an Opferflüssigkeit in der Verschlusskappe unterbringen lässt. Innerhalb der Kartusche muss nämlich - z.B. im Gegensatz zur Verwendung eines Speicherelements - kein kappilar wirksames Speichermaterial vorhanden sein, da die Opferflüssigkeit bereits durch die Kartusche gehalten ist.Another advantage of a cartridge is that it allows a larger amount of sacrificial liquid to be accommodated in the cap. Within the cartridge, namely - e.g. in contrast to the use of a storage element - no kappilar effective storage material be present, since the sacrificial liquid is already held by the cartridge.
Die Kartusche kann in die Verschlusskappe bzw. deren Speicherraum durch die herkömmliche einzige Öffnung der Verschlusskappe, welche auch zum Aufsetzen dieser auf den Stift dient, eingebracht werden. Denkbar ist jedoch auch in einer alternativen Ausführungsform, dass die Verschlusskappe im Bereich des Speicherraums eine Durchbrechung aufweist, in der die Kartusche dichtend einliegt. Die Kartusche bildet mit anderen Worten somit einen Teil der Verschlusskappe bzw. setzt diese im Bereich der Durchbrechung fort. Die Kartusche kann dann bei der Montage des Stiftes leicht von innen oder außen in die Verschlusskappe eingesetzt werden. Auch ist es z.B. möglich, in der Kartusche selbst ein Sichtfenster anzubringen, welches dann als Teil der Verschlusskappe sichtbar ist und eine Kontrolle der Menge an noch vorhandener Opferflüssigkeit ermöglicht.The cartridge can be inserted into the cap or its storage space through the conventional single opening of the cap, which also serves to place these on the pin. However, it is also conceivable in an alternative embodiment that the closure cap in the region of the storage space has an opening in which the cartridge rests sealingly. In other words, the cartridge thus forms part of the closure cap or continues it in the region of the opening. The cartridge can then be easily inserted from the inside or outside into the cap when mounting the pin. Also, it is e.g. possible to install in the cartridge itself a viewing window, which is then visible as part of the cap and allows control of the amount of sacrificial liquid still present.
In einer alternativen Ausführungsform ist zumindest ein Teil der Kartusche einstückig mit der oben genannten Innenkappe ausgeführt. Dies ist beispielsweise spritzgusstechnisch einfach möglich, für die Kartusche muss dann nicht ein separates Bauteil angefertigt werden.In an alternative embodiment, at least a part of the cartridge is made in one piece with the above-mentioned inner cap. For example, this is simply possible with injection molding technology, for which the cartridge does not then have to be made a separate component.
In einer alternativen Ausführungsform ist zumindest ein Teil des Verbindungskanals als kapillarer Kanal ausgebildet. Ein Verschluss des Kanals durch ein Dichtelement ist dann nicht unbedingt nötig. Eine Dichtung zwischen Innen- und Außenkappe kann dann z.B. fest montiert, also nicht verschiebbar sein. Auch die Innenkappe muss z.B. nicht verschiebbar in der Verschlusskappe gelagert sein. Zwischen Innen- und Verschlusskappe bzw. einer zwischen diesen einliegenden Dichtung und der Kappe befinden sich dann kapillare Kanäle, die in den Speicherraum münden. Die kapillaren Kanäle münden gleichzeitig in den Hohlraum, so dass Opferlösemittel aus dem Speicherraum durch die Kanäle in den Hohlraum verdampfen kann.In an alternative embodiment, at least a part of the connecting channel is formed as a capillary channel. A closure of the channel by a sealing element is then not necessary. A seal between inner and outer cap can then be used e.g. firmly mounted, so not be displaced. The inner cap must also e.g. not be slidably mounted in the cap. Capillary channels which open into the storage space are then located between the inner and closure cap or a gasket and the cap which is inserted between them. The capillary channels simultaneously open into the cavity so that sacrificial solvent can evaporate from the storage space through the channels into the cavity.
Die kapillaren Kanäle können sich hierbei auch in Richtung auf den Speicherraum hin verengen. Opferflüssigkeit kann dann wegen der gerichteten kapillaren Kraft nicht aus dem Speicherraum auslaufen.The capillary channels can also narrow in the direction of the storage space. Sacrificial liquid can then not leak from the storage space because of the directed capillary force.
Die kapillaren Kanäle können durch Nuten oder Abflachungen an der Außenseite der Dichtung oder der Innenseite der Verschlusskappe oder der Außenseite der Innenkappe gebildet werden.The capillary channels may be formed by grooves or flats on the outside of the seal or the inside of the closure cap or the outside of the inside cap.
Für eine weitere Beschreibung der Erfindung wird auf die Ausführungsbeispiele der Zeichnungen verwiesen. Es zeigen, jeweils in einer schematischen Prinzipskizze:
- Fig. 1
- einen Stift mit aufgesetzter Verschlusskappe,
- Fig. 2
- das Detail II aus
Fig. 1 , - Fig. 3
- das Detail III aus
Fig. 1 - Fig. 4
- den Stift aus
Fig. 1 beim Abziehen der Verschlusskappe, - Fig. 5
- das Detail V aus
Fig. 4 , - Fig. 6
- die vollständig vom Stift abgezogene Verschlusskappe aus
Fig. 1 , - Fig. 7
- das Detail VII aus
Fig. 6 , - Fig. 8-10
- Schnitte durch die Positionen VIII, XI und X in
Fig. 4 , - Fig. 11
- einen Stift mit Kartusche als Speicherelement,
- Fig. 12
- eine an der Innenkappe angeformte Kartusche,
- Fig. 13
- eine durchbrochene Verschlusskappe mit von außen eingesetzter Kartusche,
- Fig. 14
- eine von innen eingesetzte Kartusche.
- Fig. 1
- a pin with attached cap,
- Fig. 2
- the detail II off
Fig. 1 . - Fig. 3
- the detail III off
Fig. 1 - Fig. 4
- the pen off
Fig. 1 when removing the cap, - Fig. 5
- the detail V off
Fig. 4 . - Fig. 6
- the cap completely removed from the pen
Fig. 1 . - Fig. 7
- the detail VII off
Fig. 6 . - Fig. 8-10
- Sections through positions VIII, XI and X in
Fig. 4 . - Fig. 11
- a pen with cartridge as storage element,
- Fig. 12
- a molded on the inner cap cartridge,
- Fig. 13
- a perforated cap with cartridge inserted from the outside,
- Fig. 14
- a cartridge inserted from the inside.
Die Kappe 6 ist im Ausführungsbeispiel als Außenkappe 30 gestaltet und beinhaltet eine in dieser einliegende Innenkappe 32. In axialer Richtung der Mittelängsachse 20 des Stiftes 2 ist die Innenkappe 32 um etwa ein Drittel kürzer als die Außenkappe 30. In
Das Speicherelement 42 ist im Innenraum der Außenkappe 30, d.h. im Speicherraum 40 durch drei - oder in einer alternativen Ausführungsform mehrere - über den Umfang der Kappe 6 verteilte Klemmstege 46 gehalten, von denen in
Die Kappe 32 ist in einem als Dichtelement 52 wirkenden Kopfbereich bezüglich ihres Außendurchmessers da ihrer Außenseite 53 etwas kleiner dimensioniert als der Innendurchmesser di der Außenkappe 30 an ihrer Innenseite 51. In einem Längsabschnitt 54 bleibt so zwischen Außenkappe 30 und Innenkappe 32 ein Ringspalt 56 frei. Durch den Ringspalt 56, einen sich an diesen anschließenden Spalt 58 und eine - oder in einer alternativen Ausführungsform mehrere - Bohrungen 60 in der Innenkappe 32 ist ein Kanal 72 gebildet, der den Speicherraum 40 mit dem Hohlraum 22 verbindet.The
In
Zur Aufrechterhaltung des Ringspalts 56 bzw. zur konzentrischen Lagerung der Innenkappe 32 in der Außenkappe 30 ist diese über drei - oder in einer alternativen Ausführungsform mehrere - an ihrem Umfang verteilte Nasen 62 und eine an der Innenseite 51 der Außenkappe 30 angebrachte Ringdichtung 64 zentriert. Die einzelnen Nasen 62 lassen außerdem zwischen sich Raum zur Bildung des Kanals 72 frei. Die Ringdichtung 64 begrenzt hierbei außerdem den Spalt 58 in der gezeigten Öffnungsstellung 47 zur Öffnung 24 hin. Der Hohlraum 22 wiederum ist durch eine an der Innenseite 63 der Innenkappe 32 angebrachte, auf den Schaftabschnitt 14 wirkende Ringdichtung 66 abgedichtet. Zusätzlich ist die Außenkappe 30 mit einer weiteren Ringdichtung 68 nochmals gegenüber dem Schaft 4 bzw. Container 8 abgedichtet. Zur sicheren Befestigung der Kappe 6 auf dem Schaft 4 sind beide Bauteile mit einem Abschnitt 70 versehen, der im Ausführungsbeispiel als Schraubgewinde ausgeführt ist.To maintain the
Zur Benutzung des Stiftes 2 wird die Kappe 6 zunächst durch Abschrauben vom Abschnitt 70 gelöst. Hierdurch überwindet die Ringdichtung 64 einen nach innen vorspringenden Absatz 69 der Innenkappe 32, weshalb sich der Reibungswiderstand zwischen Außenkappe 30 und Innenkappe 32 sprunghaft verringert. Die Außenkappe 30 wird dann weiter in Richtung des Pfeils 50 abgezogen. Zunächst findet hierbei eine Relativbewegung zwischen Außenkappe 30 und Innenkappe 32 statt, da die Innenkappe 32 zunächst am Schaftabschnitt 14 gehalten ist, also zum Schaft 4 zunächst in unveränderter Position verbleibt. Dies ist bewerkstelligt durch am Schaftabschnitt 14 außen angeordnete Rastnasen 80, welche einen entsprechenden Rastvorsprung 82 an der Innenkappe 32 hintergreifen.
Die Außenkappe 30 bewegt sich also in Richtung des Pfeils 50 immer weiter von der Innenkappe 32 ab, bis das Dichtelement 52 den Längsabschnitt 54 verlässt und dichtend auf ein an der Innenseite 51 der Außenkappe 30 angeordnetes Verschlusselement 84 aufläuft, das im Ausführungsbeispiel als Ringdichtung ausgeführt ist. Die entsprechende Situation ist in
Beim Aufsetzen der Kappe 6 auf den Schaft 4 gelangt zunächst der Schaftabschnitt 14 in Berührung mit der Innenkappe 32 und übt auf diese eine Kraft in Richtung des Pfeils 50 aus, weshalb in dieser Richtung eine Relativbewegung zwischen Innenkappe 32 und Außenkappe 30 stattfindet. Das Dichtelement 52 gleitet vom Verschlusselement 84 ab und gibt den Ringspalt 56 bzw. den Kanal 72 frei. Die Relativbewegung wird solange fortgesetzt, bis das nun von der Schürze 86 wieder freigegebene Gewinde im Abschnitt 70 in Eingriff tritt. Durch das Aufschrauben der Kappe 6 auf den Schaft 4 gleitet schließlich die Innenkappe 32 weiter in die Außenkappe 30, bis sie mit ihren Boden 38 die Enden 48 der Klemmstege 46 erreicht und dort anschlägt. Zuletzt rasten dann die Rastnasen 80 hinter die Rastvorsprüngen 82, wobei gleichzeitig die Kappe 6 mit Hilfe des Schraubgewindes endgültig und unter Eingriff sämtlicher Dichtungen 64,66 und 68 dichtend auf den Schaft 4 gelangt.When placing the
Da das Mitnehmerelement 39 der Innenhülse 32 sowohl die beim Abziehvorgang benutzten Rastnasen 62 als auch die Rastvorsprünge 82 trägt, verursacht dieses die Bewegung des Bodens 38.Since the
In einer alternativen Ausführungsform einer Kappe 6 enthält diese keine Kartusche 90. Der Speicherraum 40 ist dann alleine mit Opferflüssigkeit 44 gefüllt. Bei dieser Ausführungsform ist die Innenkappe 32 fest, also nicht verschiebbar in der Außenkappe 30 angeordnet. Dies ist z.B. durch eine geeignete, nicht dargestellte Klemmvorrichtung zwischen beiden Teilkappen bewerkstelligt. Der Kanal 72 übt dann auf die Opferflüssigkeit 44 eine Kapillarkraft aus und verjüngt sich in Richtung des Pfeils 50. Hierdurch ist ein Austreten von Opferflüssigkeit 44 aus dem Speicherraum 40 verhindert, deren Verdunstung jedoch sichergestellt.In an alternative embodiment of a
Auch gemäß
In einer alternativen Ausführungsform ist die Wand 94 im Bereich des Bodens 38 aufgebrochen und an dieser Stelle ein durchsichtiges Fenster 104 eingesetzt. Dieses erlaubt eine optische Füllstandskontrolle der Kartusche 90 bezüglich der Opferflüssigkeit 44. Denkbar ist auch, den gesamten Behälter, also insbesondere die gesamte Wand 94 durchsichtig zu gestalten.In an alternative embodiment, the
Claims (16)
- Pen (2) having a shaft (4) comprising a reservoir (10) and an applicator tip (16) for an application fluid (12), having the application fluid (12), which contains a solvent (13) which is volatile at room temperature, and having a closing cap (6) which is set on the shaft (4) and which has a cavity (22) which receives the applicator tip (16), wherein this contains a storage space (40) to receive a fugitive liquid (44) which is volatile at room temperature and a connection channel (72) which fluidically connects the storage space (40) to the cavity (22), wherein the closing cap (6) contains a sealing element (52) which is able to be displaced axially between a sealing position which closes the connection channel (72) and an open position which releases the connection channel (72), wherein the sealing element (52) is moveably coupled to a shaft section (14) of the shaft (4) which projects into the cavity (22) of the closing cap (6) for its movement in the opening and/or closing direction, characterised in that the sealing element (52) comprises a wall segment (38), which delimits the storage space (40) of the cavity (22), whilst leaving free at least one longitudinal section of the connection channel (72), and a carrier element (39) which interacts with the shaft section (14) and is facing towards the cap opening (24), wherein a gap (56) is present between the closing cap (6) and the wall segment (38), said gap (56) forming at least one longitudinal section of the connection channel (72) and wherein the gap (56) is closed by a closing element (84) arranged on the inner side (51) of the closing cap (6) in the closed position of the sealing element (52).
- Pen (2) according to claim 1, in which the gap (56) has a lower flow cross-section than the remaining connection channel (72).
- Pen (2) according to claim 1 or 2, in which the gap (56) is an annular gap.
- Pen (2) according to one of the preceding claims, in which the closing element (84) is a circumferential annular projection.
- Pen (2) according to one of the preceding claims, in which the sealing element (52) is part of an inner cap (32) arranged inside the closing cap (6).
- Pen (2) according to claim 5, in which the wall segment (38) forms the base and the carrier element (39) forms the inner cap (32).
- Pen (2) according to one of the preceding claims, having a first positive locking which limits the relative movement (50) of the sealing element (52) and closing cap (6) when removing the closing cap (6) and acts axially, and having a second positive locking which causes the moveable coupling between sealing element (52) and the shaft section (14) when removing the closing cap (6), wherein the first positive locking, seen in the axial direction, has a greater strength than the second positive locking.
- Pen (2) according to claim 7, in which first or second positive locking is formed by radially overlapping projections on the closing cap (6) and sealing element (52) or sealing element (52) and shaft section (14).
- Pen (2) according to claim 8, in which the first positive locking is formed by a stop (65) of the closing cap (6) and a projection (62) of the sealing element (52), and the second positive locking is formed by a locking catch (80) on the shaft section (14) and a locking projection (82) on the sealing element (52).
- Pen (2) according to one of the preceding claims, having a cover element (86) which is moveably coupled to the sealing element (52) and which covers a section (70) of the closing cap (6) which connects to the opening (24), in the released state thereof.
- Pen (2) according to claim 10 in connection with claim 5, in which the cover element (86) is the end section of the inner cap (32) which faces towards the opening (24).
- Pen (2) according to one of the preceding claims, in which the storage space (40) contains a storage element (42) for the fugitive liquid (44).
- Pen (2) according to claim 12, in which the storage element (42) is a cartridge (90).
- Pen (2) according to claim 13, in which the closing cap (6) has a perforation (98) in the region of the storage space (40), in which the cartridge (90) is enclosed.
- Pen (2) according to claim 13 in connection with claim 5, in which at least one part of the cartridge (90) is designed in one piece with the inner cap (32).
- Pen (2) according to one of the preceding claims, in which at least one part of the connection channel (72) is formed as a capillary channel (106).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008041282.1A DE102008041282B4 (en) | 2008-08-15 | 2008-08-15 | Pen with cap |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2184180A2 EP2184180A2 (en) | 2010-05-12 |
EP2184180A3 EP2184180A3 (en) | 2012-09-12 |
EP2184180B1 true EP2184180B1 (en) | 2015-02-25 |
Family
ID=41566815
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09167608.0A Not-in-force EP2184180B1 (en) | 2008-08-15 | 2009-08-11 | Pen with closing cap |
Country Status (4)
Country | Link |
---|---|
US (1) | US8282302B2 (en) |
EP (1) | EP2184180B1 (en) |
DE (1) | DE102008041282B4 (en) |
ES (1) | ES2534236T3 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102009001927B3 (en) | 2009-03-27 | 2010-10-28 | Faber-Castell Ag | Pen-shaped applicator |
DE102011120943A1 (en) * | 2011-12-14 | 2013-06-20 | M. Heyer GmbH Applikator- Systeme | lacquer pen |
EP2657041B1 (en) * | 2012-04-26 | 2016-07-13 | Faber-Castell AG | Refill cap for marker pens and cosmetic capillary systems |
EP2662753B1 (en) * | 2012-05-09 | 2018-10-17 | Stepover GmbH | Pen barrel for holding a pen |
ES2596239T3 (en) | 2013-01-21 | 2017-01-05 | Faber- Castell Ag | Applicator |
US10286724B1 (en) | 2016-01-27 | 2019-05-14 | Christian John James Moore | Writing instrument with locking cap |
US10532600B1 (en) | 2016-01-27 | 2020-01-14 | Christian John James Moore | Writing instrument with locking cap |
US10244843B2 (en) * | 2017-05-19 | 2019-04-02 | Zhuhai Ding Rong Plastic Products Co., Ltd | Cosmetic container having a fibrous applicator |
DE102019101651A1 (en) * | 2019-01-23 | 2020-07-23 | 3lmed GmbH | Application system with improved seal |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2547803A (en) * | 1947-01-23 | 1951-04-03 | Adams Philip | Pen cap |
DE1901668U (en) * | 1964-04-30 | 1964-10-01 | Wolfgang Dipl Ing Muthesius | DRYING PROTECTION FOR INK WRITING AND DRAWING DEVICES. |
US3475103A (en) * | 1969-01-27 | 1969-10-28 | Rapidograph Inc | Stylographic pen cap with built-in hygrometer |
DE2756505A1 (en) * | 1977-12-19 | 1979-06-21 | Faber Castell A W | DEVICE FOR RECEIVING INDEX WRITING DEVICES |
DD206548A1 (en) * | 1981-08-07 | 1984-02-01 | Ahrens Hans Joachim | COVER FOR DISPENSER UNITS |
DE3441435A1 (en) * | 1984-01-19 | 1985-08-01 | Pelikan Ag, 3000 Hannover | Cap of a writing implement |
US4748990A (en) * | 1986-05-28 | 1988-06-07 | Avon Products, Inc. | Cosmetic applicator |
DE3641389C1 (en) * | 1986-12-04 | 1988-01-28 | Schwan Stabilo Schwanhaeusser | Application device |
DE8814492U1 (en) * | 1988-11-21 | 1989-03-02 | A. W. Faber-Castell Gmbh & Co, 8504 Stein, De | |
JPH0625221Y2 (en) * | 1991-04-12 | 1994-07-06 | タケミ株式会社 | Applicator for volatile high viscosity liquid |
WO1998019576A1 (en) * | 1996-11-06 | 1998-05-14 | Nathan Kay | A fluid applicator and dispensing system for controlling fluid and vapor flow |
US5971647A (en) * | 1998-05-12 | 1999-10-26 | Loulourgas; Demetre | Writing device cap |
JP3662447B2 (en) * | 1999-03-15 | 2005-06-22 | 壽印刷紙工株式会社 | Liquid container cap |
JP2001048219A (en) * | 1999-08-09 | 2001-02-20 | Kotobuki Insatsu Shiko Kk | Liquid container |
DE202005005043U1 (en) * | 2005-03-30 | 2006-08-10 | Schwan-Stabilo Cosmetics Gmbh & Co. Kg | applicator |
GB2446541B (en) * | 2005-11-30 | 2010-05-05 | Zebra Co Ltd | Ink replenishment cartridge and encapsulated fiber type writing instrument using ink replenishment cartridge |
-
2008
- 2008-08-15 DE DE102008041282.1A patent/DE102008041282B4/en not_active Expired - Fee Related
-
2009
- 2009-08-11 ES ES09167608.0T patent/ES2534236T3/en active Active
- 2009-08-11 EP EP09167608.0A patent/EP2184180B1/en not_active Not-in-force
- 2009-08-17 US US12/542,245 patent/US8282302B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
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US20100040404A1 (en) | 2010-02-18 |
DE102008041282A1 (en) | 2010-02-25 |
EP2184180A3 (en) | 2012-09-12 |
EP2184180A2 (en) | 2010-05-12 |
DE102008041282B4 (en) | 2017-01-19 |
ES2534236T3 (en) | 2015-04-20 |
US8282302B2 (en) | 2012-10-09 |
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