EP2171138A2 - Spinning method - Google Patents
Spinning methodInfo
- Publication number
- EP2171138A2 EP2171138A2 EP08784791A EP08784791A EP2171138A2 EP 2171138 A2 EP2171138 A2 EP 2171138A2 EP 08784791 A EP08784791 A EP 08784791A EP 08784791 A EP08784791 A EP 08784791A EP 2171138 A2 EP2171138 A2 EP 2171138A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- cooling medium
- cooling zone
- yarn
- length
- filament bundle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
- D01D5/092—Cooling filaments, threads or the like, leaving the spinnerettes in shafts or chimneys
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
Definitions
- the present invention relates to a method of spinning a multifilament yarn of a thermoplastic material, comprising the steps of extruding the molten material through a plurality of nozzle holes of a spinneret into a multifilamentary filament bundle and wound up as a multifilament yarn after solidification, and US Pat where the filament bundle is cooled below the spinneret.
- the present invention relates to multifilament yarns, in particular polyester multifilament yarns and cords containing such polyester filament yarns.
- a method as described above is known from WO 2004/005594.
- the filament bundle is cooled below the spinneret in two stages, the filament bundle is cooled below the spinneret in a first cooling zone first by means of a Queranblasung by a gaseous cooling medium and by means of a Queranblasung opposite suction of the gaseous cooling medium, and then in a second cooling zone below the first cooling zone, the filament bundle is substantially further cooled by Diansaugung located in the vicinity of the filament bundle gaseous cooling medium.
- the method described in WO 2004/005594 causes effective cooling of the extruded filaments.
- dimensional stability means the sum of the elongation of the yarn in% after application of a specific force of 410 mN / tex ("elongation at specific tension") EAST and hot air shrinkage ("hot air shrinkage”).
- running behavior includes the number of lint per 10 kg of yarn and the number of yarn breaks per 1000 kg of yarn.
- the object of the present invention is to provide a process by which a multifilament yarn can be spun from a thermoplastic material having a high total titer, a dimensional stability at least as good as the dimensional stability of those obtained by the process of WO 2004/005594 resulting yarns, and has an acceptable running behavior.
- a method for spinning a multifilament yarn of a thermoplastic material comprising the steps of extruding the molten material through a spinneret into a multifilamentary filament bundle and wound up as a multifilament yarn after solidification, the spinneret having a plurality of of nozzle holes, and the ends of the holes at which the filaments emerge form a nozzle hole exit plane, and wherein the filament bundle beneath the spinneret in a first cooling zone first by means of at least one transverse blowing through a gaseous cooling medium and by means of a suction of the gaseous cooling medium opposite this Queranblasung is cooled, and then in a second Cooling zone below the first cooling zone, the filament bundle is further cooled by Dian- sucking located in the vicinity of the filament bundle gaseous cooling medium, characterized in that in the first cooling zone, the at least one Queranblasung the gaseous cooling medium via a Anblasumble AC length L, wherein the Anblasstrack
- the process according to the invention improves the quality of the spinning process in comparison to the process described in WO 2004/005594 in the form of a significantly reduced number of lints per 10 kg of yarn and also clearly smaller yarn breakage per 1000 kg of yarn with at least equally good dimensional stability.
- the distance BD is subdivided into an open suction path BX of length L B ⁇ , via which the gaseous cooling medium is sucked off, and into a closed path XD of length L XD , wherein the ratio LBX: L ⁇ D is in the range of 0.15: 1 to 0.5: 1.
- - or spinning a multifilament yarn having a total denier of 1800 dtex or above is possible by lowering the draw ratio, but provides a multifilament yarn having unacceptably high fluff number per 10 kg of yarn and yarn breakage per 1000 kg of yarn.
- the ratio L B ⁇ : L XD is in the range of 0.15: 1 to 0.5: 1.
- the cooling effect exerted on the filaments is insufficient and it comes to the bonding of the filaments.
- L B ⁇ : L XD which is greater than 0.5: 1, no sufficiently stable running behavior is achieved.
- the ratio LBX: L ⁇ o is in the range from 0.2: 1 to 0.4: 1, particularly preferably in the range from 0.25: 1 to 0.35: 1 and very particularly preferably in the range from 0.27: 1 to 0.33: 1.
- L B ⁇ of the suction path BX and the absolute length of the closed path L XD of the closed path XD is - as long as the resulting ratio L B ⁇ : L XD in the range according to the invention - within wide ranges adjustable.
- L B ⁇ has a length in the range of 5 cm to 50 cm and L ⁇ o has a length in the range of 20 cm to 150 cm.
- the process according to the invention is particularly preferably carried out with values of L BX in the range from 10 cm to 25 cm and with values of L ⁇ D in the range from 35 cm to 75 cm.
- the process according to the invention is very particularly preferably carried out with values of L BX in the range from 12 cm to 21 cm and with values of L ⁇ D in the range from 49 cm to 58 cm.
- the distance between A and B runs parallel to the nozzle hole exit plane.
- the Anblasumble AC forms an angle ⁇ and the suction line BX an angle ß, wherein the amounts of ⁇ and ß may be the same or different.
- the Anblasumble AC to the imaginary distance AB at an angle ⁇ of 60 ° to 90 ° and the suction line BX has the imaginary distance AB at an angle ß of 60 ° to 90 °.
- the Anblasumble AC to the imaginary distance AB at an angle ⁇ of 90 ° and the suction distance BX has the imaginary distance AB at an angle ß of 90 °.
- the Anblasorder AC to the imaginary line AB at an angle ⁇ of 60 ° to ⁇ 90 ° and the suction line BX has the imaginary distance AB at an angle ß of 90 °.
- the angle ⁇ which the extraction path BX forms to the imaginary path AB
- the angle ⁇ ' which the path XD forms to the imaginary path AB.
- the method according to the invention is preferably carried out so that the angles ⁇ and ⁇ 'are the same.
- the filament bundle is transversely blown through the gaseous cooling medium in the first cooling zone and cooled by means of an exhaust system located opposite the transverse blowing through the suction section BX.
- This can be done, for example, such that the filament bundle between the Anblasumble AC of length L and the suction line BX of length L B ⁇ is passed through.
- Another possibility is to divide the filament and, for example, set up in the middle between two filament streams in the first cooling zone An blowing line AC of length L, for example in the form of a perforated tube of length L.
- the method according to the invention can also be carried out in such a way that a perforated tube extending in the middle of the filament streams acts as a suction path BX of length LBX and sucks the gaseous cooling medium, which is transversely blown across the Anblasumble AC of length L from outside to inside.
- the flow velocity of the gaseous cooling medium in the first cooling zone is between 0.1 and 1 m / s. At these rates, there is a uniform cooling largely without turbulence and formation of skin / core differences in the crystallization.
- the gaseous cooling medium before it is supplied to the at least one transverse blowing in the first cooling zone, is tempered by means of a first tempering device, i. cooled or heated.
- a first tempering device i. cooled or heated.
- the second stage of cooling is carried out in the process according to the invention by means of "self-suction” ("soap-suction yarn cooling”), in which case the fuel bundle entrains the gaseous cooling medium in its environment, for example ambient air, and is further cooled It is important for the gaseous cooling medium to approach the filament bundle at least from two sides.
- the self-priming unit is formed by two perforated materials that run parallel to the filament bundle, such as perforated plates.
- the length of the plates is at least 10 cm and can be up to several meters at the top. Quite usual are lengths for this Organicansaugungssort of 30 cm to 150 cm, which are also suitable for the inventive method.
- a preferred embodiment of the method according to the invention can be carried out, wherein in the second cooling zone, the filament bundle between perforated materials, such as perforated plates, performed that the gaseous cooling medium by self-suction of the filaments of the filament bundle from two sides on the Can meet filaments.
- the filament bundle in the second cooling zone is passed through a perforated tube.
- the second cooling zone may also be configured as a "self-suction zone" to form a well having a square or rectangular footprint, the walls of the well being formed from two opposed closed plates and two opposing porous plates.
- the other porous plate having a porosity P 2 F / F2 where F 0 2 is the open area of this plate and F 2 is the total area of this plate, where the porosity of one plate Pi may be the same or different from the porosity P 2 of the other plate 2 are preferably in the range of 0.1 to 0.9, more preferably in the range of 0.2 to 0.85.
- this element which is familiar to the person skilled in the art, is between 10 and 40 cm long.
- the method according to the invention in the first cooling zone comprises at least one transverse blowing through a gaseous cooling medium.
- the first cooling zone can not only have a first transverse blowing but also a second, third, etc., transverse blowing, these transverse blows being arranged directly after the blowing line AC and having the length L in total.
- each of these Queranbla- sonne can be operated with a Anblasmenge of gaseous cooling medium, which is independently adjustable by the Anblasmengen of gaseous cooling medium, with which the respective other Queranblasoder are operated.
- each of these Queranblasonne can be operated with a temperature of the gaseous cooling medium, which is independently adjustable from the temperatures of the gaseous cooling media, with which the respective other Queranblasache operated.
- the first transverse blowing with a stream velocity V 11 the first cooling zone on the blowing section AC, a first transverse blowing and an immediately adjoining second transverse blowing, whereby the first and second transverse blowing have a total length L, and wherein the gaseous cooling medium is operated, and the second Queranblasung is operated with a flow velocity of the gaseous cooling medium V 12 , and wherein vn is different from v- ⁇ 2nd
- the first cooling zone on the Anblasumble AC a first Queranblasung and an immediately adjoining second transverse blowing, wherein the first and second Queranblasung in sum have the length L, and wherein the first Queranblasung is operated with a temperature Tu of the gaseous cooling medium and the second Queranblasung is operated at a temperature Ti 2 of the gaseous cooling medium, and where Tu is different from Ti 2 .
- the method according to the invention can also be carried out in such a way that the filament bundle is further cooled in the second cooling zone by self-suction of gaseous cooling medium located in the vicinity of the filament bundle, wherein the gaseous cooling medium is heated before entry into the second cooling zone.
- a gaseous cooling medium is used to cool the filament bundle.
- the gaseous cooling medium used is preferably air and / or an inert gas, such as nitrogen or argon, where either the same or different gaseous streams are used in the first and second cooling zones Cooling media can be used.
- the process of the invention takes place after cooling of the filament bundle in the second cooling zone and before winding a single or multi-stage drawing of the filaments.
- the process of the invention is preferably a continuous spin-draw
- stretching is to be understood here as meaning all customary methods familiar to the person skilled in the art in order to distort the filaments, for example by godets, individually or in duos, or the like
- drawing refers both to draw ratios greater than 1 and to ratios which are smaller than 1.
- the latter ratios are familiar to the person skilled in the art under the concept of relaxation and smaller than 1 may well side by side.
- the total draw ratio is usually calculated from the ratio of the draw speed to the filament spin speed, i. the speed with which the filament bundles leave the cooling zones and are fixed on the first pair of godets of the drawing device.
- a typical constellation is, for example, a spinning speed of 2760 m / min, a stretching speed of 6000 m / min, an additional relaxation following the stretching of 0.5%, i. a speed of the last godet of 5970 m / min. This results in a total draw ratio of 2.17.
- speeds of at least 2000 m / min are preferred for winding, in particular of at least 2500 m / min.
- speed of the process there are no limits to the speed of the process within the framework of the technically feasible.
- about 8000 m / min, more preferably 6500 m / min is preferred for the upper speed range during winding.
- the drafting devices upstream and behind the cooling zones can still be a known chute.
- thermoplastic material to be used in the process according to the invention is preferably selected from a group comprising thermoplastic polymers, which group may contain polyester, polyamide, polyolefin or mixtures or copolymers of these polymers.
- thermoplastic material used in the process according to the invention consists essentially of polyethylene terephthalate.
- FIG. 1 shows a schematic cross section of an exemplary apparatus for carrying out the method according to the invention:
- a multifilament yarn that is, a filament bundle 2 is spun by a plurality of nozzle holes whose ends form a die hole exit plane.
- the filament bundle 2 is blown with a device for Queranblasung I with gaseous cooling medium.
- the Queranblasung takes place via a Anblasumble AC of length L, wherein A the upper nozzle holes facing the beginning and C forms the lower end of the Anblasumble AC facing away from the nozzle holes.
- the points A and C respectively denote the upper and lower ends of the first cooling zone.
- a distance BD is arranged, which has a nozzle holes facing the beginning of B and facing away from the nozzle holes end D.
- a and B are arranged so that the distance AB between A and B is parallel to the nozzle hole exit plane.
- the angle ⁇ between the imaginary distance AB and the Anblasumble AC is 90 °.
- the angle ⁇ between the imaginary distance AB and the distance BD is also 90 °.
- the distance BD is subdivided into an open suction path BX of length L B X, via which the gaseous cooling medium is sucked off with a suction device II, and into a closed path XD of length L X D, the ratio L B ⁇ : L ⁇ D im Range from 0.15: 1 to 0.5: 1.
- the second cooling zone is defined on the left by a perforated plate which forms a self-priming path CE of length L C E, via which the filament bundle 2 sucks gaseous cooling medium solely by its movement.
- the second cooling zone is defined on the right by a further perforated plate, which forms a self-suction path DF of length L D F, via which the filament bundle 2 also sucks gaseous cooling medium solely by its movement. The subsequent stretching and winding of the spun multifilament to the second cooling zone is not shown.
- the upper limit of the total titre can assume arbitrarily large values, as will be explained in the following:
- the nozzle hole exit plane mentioned at the beginning can be embodied as part of a spinneret plate which has a Has length and a width. By extending the spinneret plate in the width, it is in principle possible to spider arbitrarily large total titers by means of the method according to the invention.
- an upper limit on the total denier of the polyester multifilament yarn which is in the range of 1800 dtex to 5000 dtex, and preferably in the range of 2000 dtex to 3600 dtex.
- the polyester multifilament yarn has a breaking strength of more than 60 cN / tex, particularly preferably more than 65 cN / tex.
- the number of lint is less than 500 per 10 kg of yarn, more preferably less than 250 per 10 kg of yarn.
- the polyester multifilament yarn has a yarn breakage rate of less than 25 per 1000 kg of yarn, more preferably less than 10 per 1000 kg of yarn.
- the polyester multifilament yarn according to the invention is preferably characterized in that the yarn has a breaking strength T in mN / tex and an elongation at break E in%, the product consisting of the breaking strength T and the third root of the breaking elongation E, T ⁇ E 1/3 , at least 1600 mN% 1/3 / tex and preferably between 1600 and 1800 mN% 1/3 / tex.
- the measurements of the breaking strength T and the elongation at break E for the determination of the parameter T * E 1/3 are carried out in accordance with ASTM 885 and are otherwise known to the person skilled in the art.
- the number of lint per 10 kg of yarn is determined with the ENKA Tecnica FR V.
- the determination of the thread breaks per 1000 kg of yarn is done by counting.
- the EAST is measured according to ASTM 885 and the HAS is also determined according to ASTM 885, with the proviso that the measurement is carried out at 180 ° C., at 5 mN / tex and over a measuring period of 2 minutes.
- the o.g. Polyester multifilament yarn is particularly well suited for technical applications, especially for use in tire cord.
- An undoped cord made of the polyester multifilament yarn according to the invention has a value of at least 1375 mN% 1/3 / tex, preferably up to 1800 mN% 1/3 / tex for the product T »E 1/3 . Therefore, such an undoped cord is also part of the present invention.
- the present invention includes a dipped cord comprising a polyester multifilament yarn produced by the process according to the invention, the cord having a retention capacity Rt after dipping and characterized by the quality factor Qf, ie the product of T * E 1/3 of the polymer. estermultifilamentgarns and Rt of the cordes, is greater than 1350 mN% 1/3 / tex and preferably up to 1800 mN% 1/3 / tex.
- the retention capacity is the dimensionless quotient of the breaking strength of the cord after dipping and the breaking strength of the threads.
- the method is also well suited for the production of technical yarns.
- the settings necessary for the spinning of technical yarns in particular the choice of the nozzle and the length of the heating tube, are known to the person skilled in the art.
- Example 1 Preparation of polyethlene terephthalate multifilament yarns having a yarn count of 2220 dtex
- the erupted filament bundle first passes through a heating tube, then through the first cooling zone directly adjoining the heating tube and through the second cooling zone directly adjoining the first cooling zone.
- the first cooling zone on a Anblasumble which is divided into a first Queranblasung and immediately thereafter in a second Queranbla- solution, by means of which the filament bundle is transversely blown with air of different temperature and flow velocity.
- the first Queranblasung opposite and immediately after the heating tube is an open suction of certain length, through which the cross-blown air is sucked off with a certain suction. Immediately after the suction line follows a closed route of certain length.
- the second cooling zone follows, which is formed by a shaft comprising two opposing porous plates with different porosity, one plate below the Anblasstracke the first cooling zone and the second plate below the suction of the first cooling zone is arranged.
- the filament bundle is cooled by the air which it sucks as a result of its movement through the porous plates. Table 1 summarizes the spinning and cooling conditions.
- the first cooling zone is transverse-blown; Li 1 length of the first transverse blowing in the first cooling zone; T- I2 temperature of the air, with which the filament bundle in the second
- the first cooling zone is transverse-blown; LI 2 length of the second transverse blowing in the first cooling zone; L B ⁇ length of the open suction line BX in the first cooling zone; L ⁇ D Length of the closed track XD in the first cooling zone; V / t extraction capacity, with which the air in the first cooling zone is sucked through the open suction section BX of length L B ⁇ ; Pi porosity of the porous plate in the second cooling zone below the
- the multifilament is bundled and passed through a tube in a drawing device, thus stretching and winding the multifilament with the draw ratios shown in Table 2 at a draw speed of 6000 m / min, thereby producing single-stage polyethylene terephthalate multifilament yarns with a yarn titer of 2200 dtex, whose lint and breaking strengths, T * E 1/3 values and dimensional stabilities Ds are also listed in Table 2 (see yarns Nos. 1-8).
- Table 2 Draw ratios, draw speeds v s , breaking strengths T, T * E 1/3 values, flow numbers and Ds values of the polyethylene terephthalate multifilament yarn No. 1-8 according to the invention and the comparative polyethylene terephthalate multifilament yarns No. V1-V6
- the comparison of the lint numbers of the yarns 1-6 produced according to the invention with the lint numbers of the comparison yarns V1-V6 shows that the process according to the invention leads to yarns with a significantly smaller number of lint and thus to a significantly improved running behavior of the multifilament leads.
- the reduction of the number of lint in this example is between 7% (compare yarn 1 with comparative yarn V1) and 86% (compare yarn 5 with comparison yarn V5).
- the dimensional stability Ds of the yarns produced according to the invention is at most 11.0% and is, under otherwise identical conditions, equal to or even better than Ds of comparative yarns V1-V6.
- the yarns 7 and 8 produced according to the invention show that it is possible with the process according to the invention to produce yarns having a yarn denier of 2200 dtex, high strength and a number of lint, which permits continuous spinning.
- the attempt to set a draw ratio of 2.150 under the conditions of the comparative example at a stretching speed of 6000 m / min leads to such an intensive bonding of the filaments that continuous spinning is impossible. This applies first of all to the attempt to set a stretch ratio of 2.175 under the conditions mentioned.
- the yarns 6 and 8 produced according to the invention show that with the process according to the invention, when a suitable draw ratio is selected, it is possible to bring the T E 1/3 values into the preferred range of at least 1600 mN% 1/3 / tex.
- Example 2 Preparation of polyethlene terephthalate multifilament yarns having a yarn denier of 1670 dtex
- the spun filament bundles pass through a heating tube as in Example 1, then through the immediately following first cooling zone and through the immediately following second cooling zone.
- Table 3 spinning and cooling conditions
- Table 4 Draw ratios, draw speeds v s , breaking strengths T 1 T E 1/3 values, flow numbers and D s values of the polyethylene terephthalate multifilament yarns No. 1-9 according to the invention and the comparative polyethylene terephthalate multifilament yarns No. V1-V9
- Example 3 Preparation of polyethlene terephthalate multifilament yarns having a denier of 1440 dtex
- the spun filament bundles pass through a heating tube, then through the directly adjoining first cooling zone and through the immediately following second cooling zone.
- Table 5 summarizes the spinning and cooling conditions, the spinning and cooling parameters having the same meaning as in Example 1.
- the multifilament is bundled and passed through a tube in a drawing apparatus, thus drawing and winding the multifilament with the draw ratios shown in Table 6 at a draw speed of 6000 m / min, thereby producing single-stage polyethylene terephthalate multifilament yarns with a yarn titer of 1440 dtex, whose lint and breaking strengths, T E 1/3 values and dimensional stabilities Ds are also listed in Table 6 (see yarns Nos. 1-9).
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Artificial Filaments (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08784791.9A EP2171138B1 (en) | 2007-07-21 | 2008-07-16 | Spinning method |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07014367 | 2007-07-21 | ||
EP08784791.9A EP2171138B1 (en) | 2007-07-21 | 2008-07-16 | Spinning method |
PCT/EP2008/005783 WO2009012916A2 (en) | 2007-07-21 | 2008-07-16 | Spinning method |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2171138A2 true EP2171138A2 (en) | 2010-04-07 |
EP2171138B1 EP2171138B1 (en) | 2013-05-15 |
Family
ID=38961131
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08784791.9A Not-in-force EP2171138B1 (en) | 2007-07-21 | 2008-07-16 | Spinning method |
Country Status (10)
Country | Link |
---|---|
US (2) | US7842208B2 (en) |
EP (1) | EP2171138B1 (en) |
JP (1) | JP5455902B2 (en) |
KR (1) | KR20100040731A (en) |
CN (1) | CN101981239B (en) |
BR (1) | BRPI0814657A2 (en) |
CA (1) | CA2694041A1 (en) |
RU (1) | RU2459892C2 (en) |
WO (1) | WO2009012916A2 (en) |
ZA (1) | ZA201000399B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2524981A1 (en) | 2011-05-18 | 2012-11-21 | Api Institute | Dimensionally stable polyester yarn and preparation thereof |
KR101283213B1 (en) | 2011-12-15 | 2013-07-05 | 현대자동차주식회사 | A management system and method for ethernet communication network in vehicle |
CN103233283B (en) * | 2013-04-27 | 2016-01-06 | 可隆(南京)特种纺织品有限公司 | High-strength height stretches the manufacture method of polyester tire tire cord, tire cord and cord fabric thread |
CN103556242A (en) * | 2013-11-14 | 2014-02-05 | 苏州千色纺化纤有限公司 | Processing device for producing textile thread made of polyester fiber |
CN106149069B (en) * | 2016-08-15 | 2018-08-07 | 宁波大发化纤有限公司 | A kind of flow regulating barrels of fiber cooling ring blowing apparatus |
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JPH07189025A (en) * | 1993-12-24 | 1995-07-25 | Unitika Ltd | Method for cooling melt-spun polyamide filament yarn |
KR100441899B1 (en) * | 1994-12-23 | 2004-10-14 | 아코르디스 인더스트리얼 파이버즈 비.브이. | Process for manufacturing continuous polyester filament yarn |
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EP0826802B1 (en) * | 1996-08-28 | 2001-11-28 | B a r m a g AG | Process and device for spinning multifilament yarns |
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2008
- 2008-07-16 CA CA2694041A patent/CA2694041A1/en not_active Abandoned
- 2008-07-16 US US12/452,666 patent/US7842208B2/en not_active Expired - Fee Related
- 2008-07-16 BR BRPI0814657-8A2A patent/BRPI0814657A2/en not_active IP Right Cessation
- 2008-07-16 EP EP08784791.9A patent/EP2171138B1/en not_active Not-in-force
- 2008-07-16 WO PCT/EP2008/005783 patent/WO2009012916A2/en active Application Filing
- 2008-07-16 KR KR1020107001503A patent/KR20100040731A/en not_active Application Discontinuation
- 2008-07-16 JP JP2010517297A patent/JP5455902B2/en not_active Expired - Fee Related
- 2008-07-16 CN CN2008801077145A patent/CN101981239B/en not_active Expired - Fee Related
- 2008-07-16 RU RU2010106200/05A patent/RU2459892C2/en not_active IP Right Cessation
-
2010
- 2010-01-19 ZA ZA201000399A patent/ZA201000399B/en unknown
- 2010-07-08 US US12/805,043 patent/US20100269478A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
---|
See references of WO2009012916A2 * |
Also Published As
Publication number | Publication date |
---|---|
JP5455902B2 (en) | 2014-03-26 |
US20100269478A1 (en) | 2010-10-28 |
WO2009012916A2 (en) | 2009-01-29 |
JP2010534283A (en) | 2010-11-04 |
ZA201000399B (en) | 2010-10-27 |
KR20100040731A (en) | 2010-04-20 |
WO2009012916A3 (en) | 2009-06-18 |
WO2009012916A4 (en) | 2009-08-06 |
RU2010106200A (en) | 2011-08-27 |
CA2694041A1 (en) | 2009-01-29 |
EP2171138B1 (en) | 2013-05-15 |
BRPI0814657A2 (en) | 2015-02-18 |
US20100186364A1 (en) | 2010-07-29 |
CN101981239B (en) | 2013-03-06 |
RU2459892C2 (en) | 2012-08-27 |
US7842208B2 (en) | 2010-11-30 |
CN101981239A (en) | 2011-02-23 |
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