EP2170772A1 - Coagulant au titane pour la purification et la désinfection d'eau naturelle et usée, procédé sûr pour le produire et procédé pour l'utiliser - Google Patents

Coagulant au titane pour la purification et la désinfection d'eau naturelle et usée, procédé sûr pour le produire et procédé pour l'utiliser

Info

Publication number
EP2170772A1
EP2170772A1 EP07861071A EP07861071A EP2170772A1 EP 2170772 A1 EP2170772 A1 EP 2170772A1 EP 07861071 A EP07861071 A EP 07861071A EP 07861071 A EP07861071 A EP 07861071A EP 2170772 A1 EP2170772 A1 EP 2170772A1
Authority
EP
European Patent Office
Prior art keywords
water
coagulant
titanium
aluminium
titanium coagulant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP07861071A
Other languages
German (de)
English (en)
Other versions
EP2170772A4 (fr
Inventor
Vladimir Prokofievich Rodak
Vladimir Vitalievich Muliak
Georgii Michailovich Isaev
Azat Ravmerovich Habibullin
Svetlana Valerianovna Shishkina
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sittec Closed Joint Stock Co (Sittec CJSC)
Original Assignee
Sittec Closed Joint Stock Co (Sittec CJSC)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sittec Closed Joint Stock Co (Sittec CJSC) filed Critical Sittec Closed Joint Stock Co (Sittec CJSC)
Priority to EP12190649A priority Critical patent/EP2567943A1/fr
Publication of EP2170772A1 publication Critical patent/EP2170772A1/fr
Publication of EP2170772A4 publication Critical patent/EP2170772A4/fr
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/001—Runoff or storm water
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007—Contaminated open waterways, rivers, lakes or ponds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/04—Disinfection

Definitions

  • Titanium coagulant for natural and waste water purification and disinfection, safe method for producing thereof, and method for utilizing thereof
  • the invention relates to the field of ecology, particularly to the technology of natu- ral water purification and disinfection during water conditioning and physical-and- chemical wastewater treatment from toxic compounds of natural and technogenic origin involving various coagulants, and it could be used for human state improvement and health maintenance and for environment protection, and it could be referred as well to the high- priority strategic development line "Nation health".
  • coagulants among which the most commonly encountered for natural and waste water are coagulants containing aluminium, particularly aluminium sulfate, aluminium oxychloride and sodium aluminate, wherein aluminium sulfate is the most often used [I].
  • the high level of purification and disinfection of natural and waste water cannot be achieved using these coagulants, since the main their disadvantage consists in significant amount of rest aluminium in purified water.
  • coagulant based on aluminium [2] being calcium hydrocarboalumi- nate in the form of gray- white homogenous powder.
  • Calcium hydrocarboaluminate is jpro- prised as a coproduct in manufacturing alumina by means of hydrochemical synthesizing calcium from alkali-carboaluminate solutions and lime in complex processing of nepheli- nes.
  • high cost of nepheline being of rare occurrence in nature than, for instance, bauxites affects the high cost of the coagulant itself.
  • granulated material composition [3] containing the catalyst based on Mn (II) and adsorbent based on ferrous, magnesium, manganese and silicon oxides.
  • the known composition has insufficiently high capability for disinfecting and discoloring water being treated.
  • the known coagulant has insufficiently high level of purification.
  • the coagulant for purifying natural and waste water [5] being the closest one to the proposed invention by the achievable technical result and selected as the prior art.
  • the coagulant comprises compounds of aluminium, calcium oxide, silicon oxide, ferrous oxide, magnesium oxide, and sulfur dioxide.
  • Disadvantages of the known coagulant consist in achieving insufficiently high level of purification and instability of decontamination properties thereof.
  • Known in the background are methods for producing the coagulant for natural and waste water purification.
  • Known is the method for producing the coagulant of aluminium sulfate from aluminium hydroxide, which method being based on decomposing aluminium hydroxide with sulfuric acid and crystallizing the formed product [6, pp. 48-53].
  • this method requires expensive and scarce source material of aluminium hydroxide being the half-finished product in producing alumina.
  • Disadvantages of the known method for producing the coagulant for natural and waste water purification consist in high cost and scarcity thereof, since, in order for pro- ducing such a coagulant, nepheline is used as the mineral, being of rare occurrence in nature than, for instance, bauxites, which affects the high cost of the obtained finished product, and the known method (as a whole) is as well labor-intensive and expensive.
  • Known in the background are also methods for utilizing the coagulant.
  • Disadvantages of the known method consists in insufficiently high efficiency of water purification at low temperatures, a probability of water aggressivity, as well as a salt background of water being purified. All these factors, as a whole, results in reducing water network and conduit life cycle and in reducing their flow capacity.
  • the technical result achieved in the invention is common for the whole group of the claimed invention aspects (titanium coagulant for natural and waste water purification and disinfection, safe method for producing thereof, and method for utilizing thereof) and consists in: increasing the efficiency for purifying and disinfecting natural and waste water not less the level corresponding to the enforceable standard [8, 9], when water alkalinity and hydrogen index are not reduced as well as sulfate content in water is not increased; and, as a whole, reducing the cost of the whole technological cycle beginning from producing the new coagulant, as well as decreasing the labor intensity in purifying and disinfecting potable water.
  • the indicated technical result is achieved using a new titanium coagulant for natu- ral and waste water purification and disinfection, which coagulant comprising compositions of oxides, hydroxides, sulfates, oxy hydrosulfates, and oxy hydrochlorides of titanium, silicon and aluminium, and which in accordance with the invention comprising further compositions of silicon, sulfur, ferrous, calcium, chlorine, and wherein the ingredients being taken in ratio: water no more than 7.4 weight %, aluminium oxide no more than 76.5 weight %, titanium oxide no less than 10.6 weight %, silicon oxide no less than 5.0 weight %, and sulfur, ferrous, calcium, chlorine accounting for no more than 0.5 weight %.
  • a safe method for producing the titanium coagulant for natural and waste water purification and disinfection which method including steps of: providing a flotation concentrate from ore by any known enrichment method or combination thereof; torrefying subsequently the coagulant; and preparing a mixture therefrom, in which method in accordance with the invention: the step of torrefy- ing is carried out until obtaining a roasted flotation concentrate with titanium dioxide no less than 50 % and silicon dioxide no less than 25 %; the mixture is prepared on the basis of the flotation concentrate, charred coal and lignosulfonates, which mixture being briquet- ted and chloridized at a temperature of no less than 600 °C and cleaned subsequently, after which the obtained mixture of liquid chlorides being subjected to synthesis; drying the obtained paste-like titanium coagulant at a temperature of no more than 135 °C, thus obtaining the powdered titanium coagulant, after which this titanium coagulant being obtained in pelletized and/
  • the indicated technical result is achieved by a new method for utilizing the titanium coagulant for natural and waste water purification and disinfection in accordance with the first embodiment, which method including a step of adding to water being purified the titanium coagulant in the form of water suspension, wherein, in accordance with the claimed invention, the obtained titanium coagulant is added to water being purified in the form of water suspension of 10 to 50 % solution in amount of no less than 5 mg/L on powdered titanium coagulant basis, and an intense mixing is performed no less than 1 minute.
  • this technical result in accordance with the first embodiment of utilizing the titanium coagulant for natural and waste water purification and disinfection is achieved by that a mixture of powdered aluminium sulfate, and/or aluminium oxychloride, and/or aluminium hydroxychloride being mixed in advance with the titanium coagulant at a ratio of 50 % : 50 % is added in addition to water being purified.
  • this technical result in accordance with the first embodiment of utilizing the titanium coagulant for natural and waste water purification and disinfection is achieved by that a water solution of flocculants at a ratio of no more than 0.5 % in relation to the titanium coagulant is added in addition to water being purified.
  • the indicated technical result in accordance with the first embodiment of utilizing the titanium coagulant for natural and waste water purification and disinfection is achieved by that superflac, or praestol, or polyacrylamide (PAA), or water-soluble cationic polymer (WSCP), or polyelectrolyte, or magnafioc (anionic flocculant); WSCP- polyelectrolyte; polydiallyldi-methylammonium chloride.
  • the indicated technical result in accordance with the first embodiment of utilizing the titanium coagulant for natural and waste water purification and disinfection is achieved by that mixtures of powdered aluminium sulfate, and/or aluminium oxychlo- ride, and/or aluminium hydroxychloride being prepared in advance with the obtained titanium coagulant at a ratio of 50 % : 50 % is added in addition to water being purified.
  • this technical result in accordance with the first embodiment of utilizing the titanium coagulant for natural and waste water purification and disinfection is achieved by that a water solution of flocculants at a ratio of no more than 0.5 % in relation to the mixture of titanium coagulant with powdered aluminium sulfate and/or aluminium oxychloride and/or aluminium hydroxychloride is added in addition to water being purified.
  • the indicated technical result is achieved by a new method for utilizing the titanium coagulant for natural and waste water purification and disinfection in accordance with the second embodiment, which method including a step of adding to water being puri- fied the titanium coagulant in the form of water suspension, wherein, in accordance with the claimed invention, the obtained titanium coagulant is added to water being purified in the form of water suspension of 10 to 50 % solution in amount of no less than 5 mg/L on basis of mixture of powdered non-dechlorinated titanium dioxide used as an opacifier and disinfectant with the titanium coagulant in amount of no more 10 % in relation to the ob- tained titanium coagulant, and an intense mixing is performed no less than 1 minute.
  • the water suspension is prepared usually by adding 70 mg of water to 30 mg of the titanium coagulant, and the prepared solution is well-stirred.
  • this technical result in accordance with the second embodiment of utilizing the titanium coagulant for natural and waste water purification and disinfection is achieved by that a mixture of powdered aluminium sulfate, and/or aluminium oxychloride, and/or aluminium hydroxychloride being mixed in advance with the titanium coagulant and titanium dioxide at a ratio of 45 % : 55 % is added in addition to water being purified.
  • this technical result in accordance with the second embodiment of utilizing the titanium coagulant for natural and waste water purification and disinfection is achieved by that a water solution of flocculants at a ratio of no more than 0.5 % in relation to the mixture of the titanium coagulant and titanium dioxide is added in addition to water being purified.
  • the indicated technical result in accordance with the second embodiment of utilizing the titanium coagulant for natural and waste water purification and disinfection is achieved by that superflac, or praestol, or polyacrylamide (PAA), or water-soluble cati- onic polymer, or polyelectrolyte, or magnafioc.
  • the indicated technical result in accordance with the second embodiment of utilizing the titanium coagulant for natural and waste water purification and disinfection is achieved by that mixtures of powdered aluminium sulfate, and/or aluminium oxychloride, and/or aluminium hydroxychloride being mixed in advance with a mixture of the obtained titanium coagulant with non-dechlorinated titanium dioxide at a ratio 45 % : 55 % in relation to the mixture of the titanium coagulant with the powdered aluminium sulfate, and/or aluminum oxychloride, and/or aluminium hydroxychloride is added in addition to water being purified.
  • the non-dechlorinated titanium dioxide is formed during production of the high- quality titanium dioxide, when the stage of surface treatment thereof is necessary, which stage including two steps of:
  • the indicated technical result is achieved by that in purifying and disinfecting natural and waste water the obtained titanium coagulant can be utilized in combination with the non-dechlorinated titanium dioxide not subjected to the stage of surface treatment and acting as the water opacifier. Additionally, this technical result in accordance with the second embodiment of utilizing the titanium coagulant for natural and waste water purification and disinfection is achieved by that the claimed titanium coagulant can be used in combination with the known coagulants, flocculants and titanium dioxide.
  • the claimed titanium coagulant was tested, in various objects of potable and source water by various Russian pilot industrial-research centers and special laboratories for water conditioning, as for the level of its correspondence with sanitary, hygienic, epidemiologi- cal, and other norms prescribed by State Standards, and the quality of purified water, which results and examples of specific tests are cited below.
  • the claimed titanium coagulant has been obtained by the Applicant at the own manufacturing base during the goal-directed pilot manufacturing investigations of search- ing the most effective, from the view point of purification degree and high disinfection level of natural (potable) and waste water, safe method for producing thereof and the most quick and cheap method for utilizing the means having stable purifying properties of high- quality and useful for human health purified water.
  • the new coagulant consists of compounds which content on oxides basis is: titanium oxide - no less than 10.6 weight %, sili- con oxide - no less than 5.0 weight %, and sulfur, ferrous, calcium, chlorine accounting for no more than 0.5 weight %.
  • the tests were carried out at the industrial and storm-water sewage of machine- building plant and at the underground source of utility and drinking water supply of the Karaozersk town of the Sverdlovsk's region.
  • the results of treating underground source water of this utility and drinking water supply involving the claimed titanium coagulant containing compounds, which content on oxides basis is: titanium oxide - no less than 10.6 weight %, silicon oxide - no less than 5.0 weight %, and sulfur, ferrous, calcium, chlorine accounting for no more than 0.5 weight %, and aluminium oxychloride (AOC) "Bopak-E" showed more effective purification of the new titanium coagulant as compared with different coagulants, particularly in comparison with aluminium oxychloride in removing silicon compounds; the rest aluminium content when treating origin water with the titanium coagulant meet the norms and rules being in force, and when treating water with aluminium oxychloride the rest aluminium content is higher than the required indices, which meets the sanitary norms and rules being in force [10
  • the claimed safe method for producing the new titanium coagulant designed for natural and waste water purification and disinfection has been developed during the goal- directed pilot manufacturing investigations of searching the most effective, reliable, disinfecting, epidemiologically safe, and decontaminating means for natural (potable) and waste water, as well as the most quick and cheap method for utilizing this means for the purpose of obtaining purified water having quality stable properties, useful for human health.
  • Results of pilot manufacturing investigations made by the Applicant confirm the expediency for creating the required conditions for chlorinating the mixture based on flotation concentrate, charred coal and lignosulfonates at the temperature above 600 0 C, when the process for chlorinating silicon occurs for the purpose of the fullest recovery of com- pounds based on silicon with excluding subsequently the rectification stage from the proc- essing chain, which results, in essence, in a new technology, acceleration, cheapening and obtaining more stable and high-quality properties of water being purified.
  • the pilot manufacturing investigations for developing a safe method for producing the titanium coagulant were carried out by the Applicant under condition of maintaining the temperature in a pit furnace above 600 0 C when chlorinating the mixture based on flotation concentrate, charred coal and lignosulfonates. Later on, after purifying the obtained liquid chlorides, the rectification stage which is so necessary for separating titanium tetrachloride from silicon tetrachloride was excluded from the technology, and the mixture of silicon and titanium chlorides was subjected to synthesis.
  • the method for producing the claimed titanium coagulant is flameproof and blast-proof.
  • the method for producing such a coagulant relates to the fourth class of hazard in accordance with the State Standard CCBT 12.1.005-76 (safe).
  • the equipment and communications sealing, as well as the supply and exhaust ventilation in accordance with the State Standard CCBT 12.4.021-75 is designed, which provides compatibility of the working zone air with the requirements of the State Standard CCBT 12.1.005-88.
  • the working personal is provided with working wear and individual protective means in accordance with the standard sanitary norms.
  • the claimed method for utilizing the new titanium coagulant for natural and waste water purification and disinfection has been developed at the Applicant's pilot manufacturing base and tested in many leading centers and research laboratories of the country for the capability of utilizing the new coagulant in optimal conditions and ratios to water being treated in order for obtaining purified water qualitatively stable in its useful properties for the human health.
  • test results have confirmed the working efficiency and technical result of the claimed titanium coagulant for natural water purification and disinfection, which coagulant has the optimal condition in a dosage of 60 mg/L and concentration of 10 % at the intense agitation during 3 minutes.
  • the test results for potable water from the tested object have confirmed the working efficiency and technical result of the claimed titanium coagulant for natural water purification and disinfection, which coagulant has the optimal condition in a dosage of 15 mg/L and concentration of 20 % at the intense agitation during 2 minutes.
  • test results in utilizing the claimed titanium coagulant for natural water purification and disinfection for needs of potable water from the tested object have confirmed its working efficiency and technical result under conditions: a dosage of 40 mg/L and concentration of 30 % at the intense agitation during 90 seconds (1.5 minutes).
  • Example 6 The technology of utilizing the claimed titanium coagulant was evaluated and tested for the purpose of potable water purification and disinfection quality (object - Moskva-river). The tests were performed in June 2007 on the base of the Moscow State unitary enterprise "MOSVODOKANAL” (MGUP “MOSVODOKANAL”) by the Center of water conditioning technology advancement at the industrial-scale plant "Mosvodo- podgotovka”. The results are shown in the Table 6.
  • test results of potable water from the tested object have confirmed the working efficiency and technical result of the method for utilizing the claimed titanium coagulant for natural water purification and disinfection for needs of potable water, which coagulant has the optimal ratio 50 % : 50 % in mixture with powdered alumin- him sulfate, the optimal condition in a dosage of 30 mg/L and concentration of 30 %.
  • the test results for potable water from the tested object have confirmed the working efficiency and technical result of the claimed method for utilizing the obtained titanium coagulant for natural water purification and disinfection, which coagulant has a ratio of the flocculant (by the example of polyacrylamide, PAA) in relation to the titanium coagulant of 0.1 %, a dosage of 15 mg/L and concentration of 20 %.
  • a ratio of the flocculant by the example of polyacrylamide, PAA
  • test results of potable water from the tested object have confirmed its working efficiency and technical result in utilizing the obtained titanium coagulant for natural water purification and disinfection, which coagulant has a ratio of the flocculant (by the example of Praestol 650 TR) in relation to the titanium coagulant of 0.1 %, a dosage of 15 mg/L and concentration of 30 %.
  • test results of potable water from the tested object have confirmed its working efficiency and technical result in utilizing the obtained titanium coagulant for natural water purification and disinfection, which coagulant has a ratio of the flocculant (by the example of Praestol 650 TR) in relation to the titanium coagulant of 0.1 %, a dosage of 15 mg/L and concentration of 40 %.
  • test results of potable water from the tested object have confirmed the working efficiency and technical result of the method for producing the claimed titanium coagulant for natural water purification and disinfection, which coagulant has the optimal ratio of titanium dioxide in amount of 5 % in relation to powdered titanium coagulant; the optimal concentration of 30 % of the input water suspension, as well as a dosage of 30 mg/L.
  • the test results of potable water from the tested object have confirmed the working efficiency and technical result of the claimed titanium coagulant for natural water purification and disinfection, which coagulant achieves the technical result at a ratio of mixture of titanium dioxide in amount of 5 %, aluminium sulfate in amount of 45 %, and titanium coagulant in amount of 50 % and concentration of 30 % of the input water suspension.
  • test results of potable water from the tested object have confirmed its working efficiency and technical result in utilizing the claimed titanium coagulant for natural water purification and disinfection for the potable quality, which coagulant has the optimal concentration of 30 % of the input water suspension at a dosage of 40 mg/L and with adding the flocculant Praestol 650 TR in the concentration of 0.15 %.
  • test results of potable water from the tested object have confirmed its working efficiency and technical result in utilizing the claimed titanium coagulant for natural water purification and disinfection for the potable quality, which coagulant has the optimal ratio of titanium dioxide in amount 5 %, alumin- ium sulfate in amount of 45 %, and titanium coagulant in amount of 50 % and the optimal concentration of 30 % of the input water suspension at a dosage of 40 mg/L and with adding the flocculant Praestol 650 TR in the concentration of 0.15 %.
  • Example 14 The technology of utilizing the claimed titanium coagulant was evaluated and tested for the purpose of potable water purification and disinfection quality (object - river Volga). The tests were performed in March 2007 on the base of the Moscow State unitary enterprise "MOSVODOKANAL” (MGUP “MOSVODOKANAL”) by the Center of water conditioning technology advancement at the industrial-scale plant "Mosvodopodgotovka”. The results are shown in the Table 14.
  • test results in utilizing the claimed titanium coagulant for natural water purif ⁇ - cation and disinfection for needs of potable water from the tested object have confirmed its working efficiency and technical result under conditions: a dosage of 40 mg/L and concentration of 30 % at the intense agitation during 90 seconds (1.5 minutes).
  • Fig. 1 and Fig. 2 show electron microscope images obtained in accordance with testing virus containing samples, particularly, feces of child having the acute gastroenteritis (the scale length is 100 nm) prior (Fig. 1) and after (Fig. 2) the contact with the tested titanium coagulant.
  • Fig. 2 shows clearly that under the influence of the titanium coagulant the rotavi- rus particles lost their outer protein coat.
  • PASTEUR an activity of the new titanium coagulant to the standard set of microbiological markers was determined.
  • the stage of evaluating the disinfecting activity was carried out at maximal dilutions of illustrative microorganisms; the test results showed positive effect of purifying ability of the claimed coagulant.
  • Example 21 Testing the safe method for producing and utilizing the claimed titanium coagulant
  • the method for producing the titanium coagulant and the coagulant generally are safe by the main hygienic indices, and control of the titanium coagulant content in purified water should be performed in accordance with the titanium and aluminium content therein pursuant to the MAC of 0.1 mg/L and 0.2 mg/L, re- spectively, established for them.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

L'invention concerne le domaine de l'écologie, en particulier la technologie de purification d'eau naturelle pendant l'adoucissement de l'eau et le traitement physico-chimique des eaux usées pour éliminer les composés toxiques d'origines naturelle et technologique impliquant divers coagulants, et elle pourrait être utilisée pour l'amélioration des conditions de vie humaine et la préservation de la santé et la protection de l'environnement. L'invention revendiquée se distingue fondamentalement de l'art antérieur par l'obtention du nouveau coagulant pour la purification d'eau naturelle et la désinfection à haut niveau. Le résultat technique consiste en l'obtention d'une eau potable de haute qualité avec des propriétés qui sont stables pendant une longue période de temps pour obtenir la purification efficace d'eau usée fiable et à long terme dans l'objectif de fournir une sécurité écologique pour l'homme et l'environnement. Au bout de 30 minutes d'action désinfectante du coagulant au titane, la suppression nette de l'activité infectieuse des rotavirus humain, et du virus de l'hépatite A a lieu, ainsi qu'un impact de suppression drastique sur les noravirus.
EP07861071A 2007-07-02 2007-11-29 Coagulant au titane pour la purification et la désinfection d'eau naturelle et usée, procédé sûr pour le produire et procédé pour l'utiliser Ceased EP2170772A4 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12190649A EP2567943A1 (fr) 2007-07-02 2007-11-29 Coagulant de titane pour purification et désinfection d'eaux naturelles et usées et procédé d'utilisation associé

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2007124531/15A RU2007124531A (ru) 2007-07-02 2007-07-02 Коагулянт титановый для очистки и обеззараживания природных и сточных вод, безопасный способ его получения и способ использования
PCT/RU2007/000669 WO2009005393A1 (fr) 2007-07-02 2007-11-29 Coagulant au titane pour la purification et la désinfection d'eau naturelle et usée, procédé sûr pour le produire et procédé pour l'utiliser

Publications (2)

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EP2170772A1 true EP2170772A1 (fr) 2010-04-07
EP2170772A4 EP2170772A4 (fr) 2011-05-04

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EP07861071A Ceased EP2170772A4 (fr) 2007-07-02 2007-11-29 Coagulant au titane pour la purification et la désinfection d'eau naturelle et usée, procédé sûr pour le produire et procédé pour l'utiliser

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EP (2) EP2567943A1 (fr)
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CN101811799A (zh) * 2010-03-31 2010-08-25 杨欣 城市河流水域生态环境综合治理系统
CN103241814B (zh) * 2013-04-26 2014-11-19 西安石油大学 一种复合光催化絮凝剂的制备方法
CN104944547B (zh) * 2015-06-05 2017-04-12 南京大学 一种TiO2基混凝剂及其应用

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US20020000138A1 (en) * 2000-04-18 2002-01-03 Ling Zhou TiO2 compounds obtained from a high silica content ore

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