EP2165583A1

EP2165583A1 - Automated direct emulsion process for making printed circuits and multilayer printed circuits

Info

Publication number: EP2165583A1
Application number: EP08771412A
Authority: EP
Inventors: Steven Lee Dutton
Original assignee: Individual
Current assignee: VectraOne Technologies LLC
Priority date: 2007-06-18
Filing date: 2008-06-18
Publication date: 2010-03-24
Also published as: CN101785372A; WO2008157642A1; EP2165583A4; JP2010530646A; CN101785372B

Abstract

A method for making multilayer printed circuits includes a) coating a non-metallized substrate with a solution which creates a light sensitive surface on the substrate, b) imaging the coated substrate with a circuit design, c) developing the imaged substrate, d) directly plating the developed image onto the coated substrate, e) coating the plated substrate with a liquid photoimageable cover coat, f) imaging the coated plated substrate with a predesigned circuitry, g) developing the liquid photoimageable cover coat, and repeating steps a) through d). Steps e) through g) are then repeated followed by steps a) through d) until a desired number of layers is achieved for the multilayer circuit. The method may be automated by having a conveyer like system which automatically unrolls and directs a roll of non-metallized substrate through various coating, imaging, developing, and plating stations.

Description

AUTOMATED DIRECT EMULSION PROCESS FOR MAKING PRINTED CIRCUITS AND MULTILAYER PRINTED CIRCUITS

Field of Invention The present invention relates to printed circuit board technology and more particularly to a direct emulsion process for making multilayer printed circuits and an automated direct emulsion process for making printed circuits and multilayer printed circuits. The direct emulsion process for making multilayer circuits includes a) coating a non-metallized substrate with a solution which creates a light sensitive surface on the substrate, b) imaging the coated substrate with a circuit design, c) developing the imaged substrate, d) directly plating the developed image onto the coated substrate, e) coating the plated substrate with a liquid photoimageable cover coat, f) imaging the coated plated substrate with a predesigned circuitry, g) developing the liquid photoimageable cover coat, and repeating steps a) through d). Steps e) through g) are then repeated followed by steps a) through d) until a desired number of layers is achieved for the multilayer circuit. The present invention also relates to multilayer printed circuits which result from this method. Background of the Invention

There is an unrelenting drive in the printed circuit board industry towards higher speeds and frequencies and greater functionality while at the same time lowering costs. The universal focus on lower prices has forced fabricators to embrace lower labor cost models in new locations across the globe. The technology advances required for today's complex interconnect structures has brought with it the need for high density interconnect processes, microvias, new process/material types and thinner materials. The interconnect industry is always seeking new ways to cut labor out of the costs of a part and to improve quality. However, what is really needed is a new paradigm, a new way to create value by producing advanced interconnects that don't necessarily rely only on traditional printed circuit board processes to create vias and traces.

The drive to embrace to new printed circuit board technologies can be found in many markets and applications. Although not traditionally thought of as early adopters, modern defense/aerospace programs for high frequency antennas, device packages, and other advanced interconnects are embracing newer material systems and fabrication techniques to reduce weight and improve performance of their systems. Leading edge medical ultrasonic imaging, automotive collision avoidance, and commercial device packaging designs have similar challenges which is pushing designers and fabricators to some of the newer solutions that are being offered in the printed circuit board industry The desire for cost effective radio frequency identification tags has many companies exploring different ways to produce them Much has been wiitten recently about applying new mk jet printing technology to printed circuit board fabrication which reverses the generally accepted method for building interconnects These are both good examples of the printed circuit board industry's healthy drive towards improvement and a more certain future, whether evolutionary or revolutionaiy

Prior art processes for making printed circuits and printed circuit boards typically use a silver halide polyester based film to create an image of a desired printed circuit along with several other steps and processes for forming and developing the printed circuit A photo plotter is a piece of equipment that typically uses silver halide polyester film as the medium for imaging the design of a circuit This equipment is then used in subsequent processing to image circuits for metallization or to print and etch specifically designed circuits This is known as a print and etch process or a plate and etch process

One example of a prior art process for forming printed circuit boards includes the steps of creating a CAD/CAM design, sending data relating to the design to a photo plotter, photo plotting to a silver halide polyester film, developing an image from the sent data, cieating intermediate tools, scrubbing or cleaning substrate for imaging, coating the substrate with a dry film, imaging the substrate with the design, developing the image, etching the image, and then stripping the remaining dry film This prior art process requires several steps and has limitations on the imaging, developing, and etching of fine line images With this process, fine line imaging can be consistently performed down to 003 inches Imaging of much finer lines, for example imaging fine lines down to 0025 inches, creates a problem and is inconsistent when using this prior art process In addition, laminate must be purchased with copper adhered to a panel and this type of processing has inherent issues with undercutting and rough edges which can create "lossy" issues for high speed RF applications In other words, with this process, any rough protrusions or undercutting act like small antennas and the signal travel speed is reduced or lost during high frequency applications High frequency applications require smooth images and very thm copper

In addition, newer mk jet technology, while certain to provide some cost benefits to fabricators, still suffers from some uncertainty related to electπcal performance, reliability, and cost It also remains to be seen if the promise of cost effective ink jet based circuit fabrication can be realized in volume roll-to-roll technology.

Accordingly, there is a need for a new method for making multilayer printed circuits which facilitates fine line imaging while reducing the costs of traditional printed circuit board processes for flex, rigid, or rigid-flex constructions. In addition, an automated method for making multilayer printed circuits and multilayer circuit interconnects is needed which will eliminate many of the steps used in prior art processes (such as, for example, laminating, etching coppei, or drilling vias) while still enabling the creation of multilayer printed circuits with fine line imaging below 2 microns having very flat non-rough surfaces without undercut.

Summary of the Invention

The present invention is directed to a method for making multilayer printed circuits which eliminates the need for several processing steps used in prior art processes The method for making multilayer printed circuits in accordance with the present invention includes the steps of a) coating a non-metallized substrate with a solution which creates a light sensitive surface on the substrate, b) imaging the coated substrate with a circuit design, c) developing the imaged substrate, d) directly plating the developed image onto the coated substrate, e) coating the plated substrate with a liquid photoimageable cover coat, f) imaging the coated plated substrate with a predesigned circuitry, g) developing the liquid photoimageable cover coat, and repeating steps a) through d) Steps e) through g) are then repeated followed by steps a) through d) until a desired number of layers is achieved for the multilayer circuit. The imaged substrates are developed and processed to create a resulting printed circuit without the need for additional printing of dry film, developing of dry film and etching processes. In one exemplary embodiment, the step of coating a non-metallized substrate includes coating the non-metallized substrate with a ferric oxalate and palladium emulsion In another exemplary embodiment, the step of coating a non-metallized substrate includes coating the non-metallized substrate with a silver based emulsion.

The non-metallized substrate may include, but is not limited to, the following materials a liquid crystal polymer, a polyimide, a ceramic, a ceramic filled, a glass, a filled polytetrafluoroethylene, an unfilled polytetrafluoroethylene, a polytetrafluoroethylene woven glass, and a polytetrafluoroethylene non woven glass which is coated and an image of the desired circuit is then plated directly onto the coated substrate. The step of imaging the coated substrate may include exposing the surface of the coated substrate to at least one of an ultraviolet light, a laser photo plotter, direct collimation imaging, and laser direct imaging. The present invention is also directed to a multilayer printed circuit that is made in accordance with the above-described method where the multilayer printed circuit includes fine line images down to 2 microns, and in particular fine line images down to 2 microns with very thin copper

The present invention is also directed to an automated method for making a multilayer printed circuit which includes the steps of a) providing a roll of non-metallized substrate which is automatically unrolled and diiected through a number of coating, imaging, developing and plating stations, b) coating at least one of a top surface and bottom surface of the non-metallized substrate with a solution which creates a light sensitive surface on the substrate in a first coating station, c) imaging at least one of a top and bottom surface of the coated substrate with at least one predesigned circuitry by exposing at least one of the top and bottom surfaces of the coated substrate to a light source in a first imaging station, d) developing at least one of a top and bottom surface of the imaged substrate with one or more chemistries m a first developing station, e) directly plating at least one of a top and bottom surface of the developed image onto the substrate in a first plating station, f) coating at least one of a top and bottom surface of the plated substrate with a liquid photoimageable cover coat in a second coating station, g) imaging at least one of a top and bottom surface of the coated plated substrate with at least one predesigned circuitry by exposing at least one of the top and bottom surfaces of the coated plated substrate to a light source in a second imaging station, h) developing at least one of a top and bottom surface of the imaged liquid photoimageable cover coat in a second developing station, i) coating at least one of a top and bottom surface of the developed liquid photoimageable cover coat image with a solution in the first coating station, and j) repeating steps c) through e) Steps f) through i) are then repeated followed by steps c) through e) until a desired number of layers is achieved for the multilayer printed circuit. The automated method for making a multilayei printed circuit may also include the step of tool punching the non-metallized substrate prior to the step of coating the non- metallized substrate in order to aid in alignment of multiple layers of the multilayered printed circuit. The step of coating at least one of a top surface and a bottom surface of the non-metallized substrate may include coating the non-metallized substrate with a ferric oxalate and palladium emulsion and the step of coating at least one of a top and bottom surface of the developed liquid photoimageable cover coat image may include coating the developed liquid photoimageable cover coat image with a ferric oxalate and palladium emulsion Other coating solutions may also be used including, but not limited to, a silver nitrate based liquid, a silver chloride based with citric acid and a photosensitive gelatin, an iron based material, a chrome copper based material, a chrome nickel based material, an immersion gold material, and a platinum based material used m conjunction with palladium. The automated method for making a multilayer printed circuit may also include automatically umolling the ioll of non-metallized substrate and directing it through a number of coating, imaging, developing and plating stations via a conveyer like system that passes through various stations. The present invention also includes multilayer circuits made in accordance with the automated method for making a multilayer circuit of the present invention.

The present invention also includes an automated system for making a multilayer printed circuit which includes a first coating station containing a solution which creates a light sensitive surface on a substrate, a first imaging station containing at least one light source, a first developing station containing one or more chemistries, a first plating station containing an electroless solution, a second coating station containing a liquid photoimageable cover coat solution, a second imaging station containing at least one source of light, a second developing station containing one or more chemistries, a third coating station containing a solution which creates a light sensitive surface on a substrate, a third imaging station containing at least one light source, a third developing station containing one or more chemistries, and a second plating station containing an electroless solution. The first and third coating stations preferably contain a ferric oxalate and palladium emulsion or a silvei based emulsion but may also include a number of other solutions including, but not limited to, a silver nitrate based liquid, a silver chloride based with citric acid and a photosensitive gelatin, an iron based material, a chrome copper based material, a chrome nickel based material, an immeision gold material, and a platinum based material used in conjunction with palladium Brief Description of the Drawings

The present invention will hereinafter be described m conjunction with the appended drawing figures, wheiem like numerals denote like elements, and

Fig 1 is a schematic showing the prior art conventional piocess for laminating copper to a substrate,

Fig 2 is a flow chart depicting a prior art process for making printed circuits and printed circuit boards,

Fig 3 is a flow chart depicting an exemplary embodiment of the method of the present invention for fabricating printed circuits and printed circuit boards, Fig 4 is a flow chart depicting another exemplary embodiment of the method of the present invention for fabricating printed circuits and printed circuit boaids,

Fig 5 is a flow chart depicting yet another exemplary embodiment of the method of the present invention for fabricating printed circuits and printed circuit boards,

Fig 6 is a schematic showing an automated method for making a multilayer pπnted circuit in accordance with the present invention,

Fig 7 is a perspective view of a multilayer printed circuit made in accordance with the method foi making a multilayer circuit of the present invention, and

Fig 8 is a chart comparing the process steps for making a multilayer printed circuit using prior art conventional pπnted circuit board processing and direct emulsion processing of the piesent invention

Detailed Description of Examplary Embodiments

Methods of the present invention for fabricating printed circuits and printed circuit boards generally include providing a non-metallized substrate, coating the non-metallized substrate, and imaging of a circuit design directly onto the coated substrate The imaged substrate may then be developed with one or more chemistries and processed by subjecting it to an electroless solution in order to create a printed circuit or printed circuit board having a metal image It should be understood by those skilled in the art that any type of non- metallized substrate may be used as long as the substrate is uniform for imaging In addition, those skilled in the art will understand that a number of photosensitive chemicals may be used to coat the surface of the non-metallized substrate and that a variety of chemistries may be used to develop the imaged substrate Fig 1 is a schematic showing the prior art conventional process 10 for laminating copper to a substrate. A large lamination press 12 is used to laminate copper 14 to a substrate 16 thereby creating or inducing stress into the material during the lamination cycle. This laminated material contracts or shrinks as it is exposed to heat during conventional printed circuit board processes. The shrinking of the laminated material is unpredictable over the size of the panel or sheet of laminated material. Therefore, a process or method for making printed circuit boards which does not require the use of an initial metal laminated substrate is preferable

Fig 2 shows a flow chart 20 which depicts an exemplary prior art process for forming printed circuits and printed circuit boards. The method begins with a copper clad laminate material in step 22 which is then chemically cleaned and laminated with a dry film resist m step 24. The chemical cleaning and dry film resist lamination induce further stress into the copper clad laminate. A circuit is created with a CAD/CAM design in step 26 and the data relating to the circuit design is sent to a laser photo plotter in step 28. Next, in step 29, the circuit design is photo plotted to a silver master and diazo working film such as, for example, a silver halide polyester film. A photo image of the circuit is created on the copper clad laminate with a dry film resist in step 30 using the silver and diazo film or laser direct imaging of the circuit design. Following imaging of the circuit design on the copper clad laminate, the image of the circuit design is developed in step 31 using an aqueous dry film developer After the image is developed on the copper clad laminate in step 31 , the copper clad laminate is etched and stripped in step 32 to create a metal image of the circuit design. The etched imaged laminate is then ready for oxide and lamination processing in step 33 to create a printed circuit.

Developing the imaged circuit on the copper clad laminate using aqueous dry film developer in step 31 creates a by product 36 which must be removed from the process Spent chemicals 37 from step 31 also need to be waste treated thereby resulting in increased costs and increased process times for making printed circuits In addition, spent etchant 38 iesulting fiom etching and stripping the copper clad laminate m step 32 must be hauled away and chemicals 39 spent from this step must also be waste treated These too add to the increased costs and increased process times for making printed circuits. Furthermore, the etching or subtractive process m step 32 allows for undercut and the inability to reach the line width and feature technology required for some applications. Features typically need to get down to less than 25 microns which is difficult to repeat using the subtractive process. Also, all layers in a printed circuit need to be registered from top to bottom and this is difficult to do with conventional prior art printed circuit board processing due to all of the stress placed in the laminate during the dry film imaging in step 31 and the etching process in step 32.

Turning now to Fig. 3, a flow chart 40 is shown which depicts an exemplary embodiment of the method of the present invention for fabricating a printed circuit or printed circuit board. First, a non-metallized substrate is coated in step 41. Then, in step 42, a circuit design is created. The data relating to the circuit design is then sent to a photo plotter or direct imaging equipment in step 43 and the image relating to the circuit design is directly plotted on the coated non-metallized substrate in step 44. Unlike prior art processes, the image is not plotted to an intermediate silver halide polyester film or diazo. The plotted or direct image of the circuit design is then developed in step 45 and the developed image is then processed in step 46 without the need for intermediate developing and etching processes.

Another, more detailed exemplary embodiment of the present invention for fabricating printed circuits and printed circuit boards is shown in Fig. 4 by flow chart 50. First, a non-metallized pre -tooled substrate is provided in step 48 which is then coated in step 51. The non-metallized pre-tooled substrate may comprise any substrate or bonding film known in the industry of printed circuit board technology as long as the substrate is flat and uniform for imaging. For example, the non-metallized substrate may be a liquid crystal polymer, a polyimide, a flat glass plate, a polyethylene terephthalate, a filled polytetrafluoroethylene, a unfilled polytetrafluoroethylene, a polytetrafluoroethylene woven glass, a polytetrafluoroethylene non woven glass, a low temperature cofired ceramic (LTCC), and a high temperature cofired ceramic (HTCC). The substrates may be woven or non woven and ceramic filled or unfilled. In addition, a number of known products may also be used as the non-metallized substrate including products known as KAPTON, SPEED BOARD C, ULTRALAM, FR4 EPOXIES, MULTIFUNCTIONAL EPOXIES, BT EPOXIES, LCP, and DUROID. The non-metallized pre-tooled substrate is coated in step 51 with a photosensitive chemical that is suitable for laser imaging. Such chemicals may include, but are not limited to, a silver nitrate based liquid, a silver chloride based with citric acid and photosensitive gelatin, an iron based material, a chrome copper based material, a chrome nickel based material, an electroless nickel, an immersion gold, a platinum based material, and palladium based material

The coated substrate is then baked until dry in step 49 In one exemplary embodiment, the coated substrate is baked at 40 degrees Celsius in a conventional oven or a conveyor oven for approximately 20 to 30 minutes The circuitry for the printed circuit or printed circuit board is then designed m step 52 and the data relating to the circuit design is sent to a photo plotter oi laser direct imaging in step 54 Next, the circuitry design is imaged onto the coated substrate using the photo plotter oi laser direct imager m step 56 and the tooling m the coated substrate is used as a reference guide during the imaging In contrast to pπoi ait processes, a silver halide polyester film is not used for imaging Instead, the coated substrate is placed directly on the photo plotter or laser direct imager for imaging As a result, the method of the present invention for fabricating printed circuits and printed circuit boaids eliminates the need for a number of products, steps, and procedures including the need foi silver film, diazo film, dry film, liquid dry films, collimated or non-colhmated UV light sources, hot roll vacuum lamination, developing and etching and stripping of standard printed circuit boards, and waste treatment chemicals along with associated overhead and direct and indirect laboi costs

In the exemplary method shown in Fig 4, the image substrate is then developed with chemistries m step 58 Here, chemistries such as any paper type developer like KODAK DEKTOL or NGS NAT 540 and FIXER NAT 750 may be used or EDTA based developer Finally, the developed image is processed in step 60 with a copper bath to create the resulting punted circuit or printed circuit board This may include any standard electroless copper plating process used for circuit board hole metallization that is known in the art

A flow chart 70 depicting yet another exemplary embodiment of the method of the present invention for fabricating printed circuits and printed circuit boards is shown in Fig 5 The process begins with an unclad substrate in step 72 The unclad substrate is then prepaied with a direct emulsion process chemistry m step 74 Step 74 involves coating the unclad (or non-metallized) substrate with a solution which creates a light sensitive surface on the substrate The solution preferably comprises a ferric oxalate and palladium emulsion oi a silver based emulsion However, the solution may also include, but is not limited to, the following a silvei nitrate based liquid, a silver chloride based with citric acid and a photosensitive gelatin, an iron based material, a chrome copper based material, a chrome nickel based material, an immersion gold material, and a platinum based material used in conjunction with palladium.

A circuit is created with a CAD/CAM design in step 76 and the data relating to the circuit design is sent to a laser photo plotter in step 78. Next, m step 79, the circuit design is photo plotted to a silver master and diazo working film. The coated substrate from step 74 is then imaged with the circuit design in step 80 by exposing the surface of the coated substrate to a light source such as, for example, an ultraviolet source, a laser photo plotter, direct collimation imaging, or lasei direct imaging. Once the surface is exposed to light, the iron material from the ferric oxalate and palladium emulsion darkens or oxidizes thereby allowing the palladium particles to adhere to these exposed sites. The now exposed iron/palladium site remains and the unexposed areas are washed (developed) away leaving a darkened image on the substrate. The imaged substrate is developed with one or more chemistries in step 81 which may include a low cost developer for the direct emulsion process chemistry used in step 74. Other chemistries may also be used such as any paper type developer like KODAK DEKTOL or NGS NAT 540 and FIXER NAT 750 may be used or EDTA based developer. In step 82, the developed image is directly plated onto the substrate. Step 82 of diiectly plating the developed image onto the substrate may include the step of passing the developed substrate through an electroless solution to enable a metal to adhere to the developed image thereby creating a metal image on the substrate. The imaged and plated laminate is then ready for oxide and lamination processing in step 83 to create a printed circuit.

Unlike the prior art conventional process for making printed circuits described with reference to Fig 2 above, the method for making printed circuit boards in accordance with the present invention and described with reference to Fig. 3 creates efficiencies and eliminates waste thereby reducing costs and process times for making printed circuits. For example, the developing solution (chemistry) used in step 81 can be reclaimed 86 and no etching is lequired 88 when the developed image is directly plated onto the substrate in step 82 Furthermore, eliminating the need for copper on the substrate and the need for dry film, dry film coating, dry film developing, etching and dry film stripping significantly reduces stress in the laminate thereby improving registration of the layers from top to bottom. This also eliminates the need for all associated costs for each of these processes and the subsequent waste disposal of any by products generated in the etching process Potential applications for the direct emulsion process of the present invention for making printed circuits include, but are not limited to, chip packaging, defense/aerospace including phased array and planar array antennas, high frequency components, high speed/frequency flex interconnects including board to board interconnects, medical devices including implantable medical devices, automotive, and down hole and pipeline monitoring electronics.

Fig. 6 is a schematic showing an automated method 100 for making a multilayer printed circuit in accordance with the present invention. A roll of non-metallized substrate 102 is passed through a first station 104 where the non-metallized substrate is tool punched to aid in aligning multiple layers of a multi-layered printed circuit. The tool punched non- metallized substrate is then coated in station 106 with a solution which creates a light sensitive surface on the substrate. The non-metallized substrate may be spray coated on its top and/or bottom surface with the coating solution. The coated substrate is then imaged in station 108 with a pre-designed circuitry by exposing the surface of the coated substrate to a light source. Both the top and/or bottom surfaces of the coated substrate may be imaged. The imaged substrate is then developed with one or more chemistries at station 110 where both the top and/or bottom surfaces of the imaged substrate may be developed. The developed image is plated directly onto the substrate in station 112 by passing the developed image through an electroless solution. The plated substrate is then coated with a liquid photoimageable cover coat at station

1 14 and the coated plated substrate is then imaged with a predesigned circuitry in station 1 16 by exposing the surface of the coated plated substrate to a light source. The liquid photoimageable cover coat is then developed in station 118 with one or more chemistries. The liquid photoimageable cover coat may be developed from both a top and/or bottom surface. The developed liquid photoimageable cover coat is then coated in step 120 with a solution which creates a light sensitive surface. The coated liquid photoimageable cover coat is then imaged with a predesigned circuitry in station 122 by exposing the surface of the coated liquid photoimageable cover coat to a light source. The imaged coated liquid photoimageable cover coat is then developed from a top and/or bottom surface in station 124 with one or more chemistries. The resulting developed layer is then passed through an electroless solution to plate the circuit and complete processing of the second layer. These steps may then be repeated until a desired number of layers is achieved for the multilayered printed circuit The method may be automated by automatically unrolling the roll of non metallized substrate 102 and directing the roll of non-metallized substrate through a number of various coating, imaging, developing, and plating stations using a conveyer-like means

A perspective view of a multilayer printed circuit 130 made in accordance with the method of the present invention for making a multilayer circuit is shown in Fig 7 The multilayer printed circuit 130 includes a bottom layer comprised of a non-metallized substrate and alternating layers of a direct emulsion chemistry 134 which creates a light sensitive suiface and a liquid photoimageable cover 136 The alternating layeis of direct emulsion chemistry 134 and liquid photoimageable cover 136 are positioned above the non- metallized substrate 132 and include direct emulsion features 138 such as the stacked vias shown in Fig 7

Finally, Fig 8 is a chart comparing the process steps for making a multilayer printed circuit using pπor art conventional printed circuit board processing and direct emulsion processing in accordance with the present invention It will be understood that the foregoing description is of preferred exemplary embodiments of the invention and that the invention is not limited to specific forms shown or described herein Various modifications may be made in the design, arrangement, order, and types of steps disclosed herein for making and using the invention without departing from the scope of the invention as expressed in the appended claims

Claims

1. A method for making a multilayer printed circuit comprising the steps of: a) coating a non-metallized substrate with a solution which creates a light sensitive surface on the substrate; b) imaging the coated substrate with a predesigned circuitry by exposing the surface of the coated substrate to a light source, c) developing the imaged substrate with one or more chemistries, d) directly plating the developed image onto the substrate; e) coating the plated substrate with a liquid photormageable cover coat, f) imaging the coated plated substrate with a predesigned circuitry by exposing the surface of the coated plated substrate to a light source; g) developing the liquid photoimageable cover coat; and h) repeating steps a) through d).

2 The method of claim 1 further comprising the step of repeating steps e) through g) followed by steps a) through d) until a desired number of layers is achieved for the multilayer printed circuit

3 The method of claim 1 further comprising the step of tool punching the non- metallized substrate prior to the step of coating the non-metallized substrate in order to aid in alignment of multiple layers of the multilayered printed circuit.

4. The method of claim 1 further comprising the step of pretreating the non-metallized substrate prior to the step of coating the non-metallized substrate.

5. The method of claim 1 further comprising the step of air drying the coated substrate prior to the step of imaging the coated substrate

6 The method of claim 1 wherein the step of coating a non-metallized substrate comprises the step of coating the non-metallized substrate with a ferric oxalate and palladium emulsion.

7 The method of claim 1 wherein the step of coating a non-metalhzed substrate comprises the step of coating the non-metallized substrate with a silver based emulsion

8 The method of claim 1 wherein the non-metalhzed substrate comprising the first layer of the multilayer printed circuit board comprises at least one of a liquid crystal polymer, a polyimide, a polyethylene terephthalate, a filled polytetrafluoroethylene, an unfilled polytetrafluoroethylene, a polytetiafluoioethylene woven glass, a polytetrafluoroethylene non woven glass, a low temperaruie cofiied ceramic, and a high tempeiatuie cofired ceiamic

9 The method of claim 1 wherein the step of imaging the coated substrate and the step of imaging the plated coated substrate each comprise the step of imaging the coated substrate by exposing the surface of the coated substrate to at least one of an ultraviolet light, a laser photo plotter, direct collimation imaging, and laser direct imaging

10 The method of claim 1 wherein the step of directly plating the developed image onto the substrate comprises the step of passing the developed substrate through an electroless solution to enable copper to adhere to the developed image thereby creating a copper image on the substrate

11 The method of claim 1 wherein the step of diiectly plating the developed image onto the substrate comprises the step of passing the developed substrate through an electroless solution to enable at least one of gold and a nickel-gold composition to adhere to the developed image thereby creating a metallized image on the substrate

12 A multilayer printed circuit made in accordance with claim 1

13 The multilayei printed ciicuit of claim 12 wherein the multilayer printed circuit compiises fine line images below 2 micions

14 Λn automated method for making a multilayer printed circuit comprising the steps of a) providing a roll of non-metallized substrate which is automatically unrolled and dnected through a numbei of coating, imaging, developing and platmg stations, b) coating at least one of a top surface and bottom surface of the non-metallized substrate with a solution which creates a light sensitive surface on the substrate in a first coating station, c) imaging at least one of a top and bottom surface of the coated substrate with at least one predesigned circuitry by exposing at least one of the top and bottom surfaces of the coated substrate to a light source in a first imaging station, d) developing at least one of a top and bottom surface of the imaged substrate with one or more chemistries m a first developing station, e) directly plating at least one of a top and bottom surface of the developed image onto the substiate m a first plating station, f) coating at least one of a top and bottom surface of the plated substrate with a liquid photo imageable cover coat in a second coating station, g) imaging at least one of a top and bottom surface of the coated plated substrate with at least one predesigned circuitry by exposing at least one of the top and bottom surfaces of the coated plated substrate to a light source in a second imaging station, h) developing at least one of a top and bottom surface of the imaged liquid photoiniageable cover coat in a second developing station, and i) coating at least one of a top and bottom surface of the developed liquid photoimageable cover coat image with the solution in the first coating station, and j) repeating steps c) through e)

15 The method of claim 14 further comprising the step of repeating steps f) through i) followed by steps c) through e) until a desned number of layers is achieved for the multilayer printed circuit

16 The method of claim 14 fuither compiismg the step of tool punching the non- metallized substrate prior to the step of coating the non-metallized substrate m order to aid in alignment of multiple layers of the multilayeied printed circuit

17 The method of claim 14 wherein the step of coating at least one of a top surface and bottom surface of the non-metallized substrate comprises the step of coating the non- metallized substrate with a ferric oxalate and palladium emulsion and the step of coating at least one of a top and bottom surface of the developed liquid photoimageable cover coat image comprises the step of coating the developed liquid photoimageable cover coat image with a ferric oxalate and palladium emulsion

18 The method of claim 14 wherein the step of coating at least one of a top surface and bottom suiface of the non metallized substrate comprises the step of coating the non- metallized substrate with a silvei based emulsion and the step of coating at least one of a top and bottom surface of the developed liquid photoimageable cover coat image comprises the step of coating the developed liquid photoimageable cover coat image with a silver based emulsion

19 The method of claim 14 wherein the non-metallized substrate comprises at least one of a liquid crystal polymei, a polyimide, a polyethylene terephthalate, a filled polytetrafluoroethylene, an unfilled polytetrafluoroethylene, a polytetrafluoroethylene woven glass, a polytetrafluoroethylene non woven glass, a low temperature cofired ceramic, and a high temperature cofired ceramic

20 The method of claim 14 wherein the step of imaging at least one of a top and bottom surface of the coated substrate and the step of imaging at least one of a top and bottom surface of the coated plated substrate each comprises the step of exposing at least one of the top and bottom surface of the coated substrate or at least one of the top and bottom surface of the coated plated substrate to at least one of an ultraviolet light, a laser photo plotter, direct colhmation imaging, and laser direct imaging

21 The method of claim 14 wherein the step of directly plating at least one of a top and bottom surface of the developed image onto the substrate comprises the step of passing the developed substrate through an electroless solution to enable a metal to adhere to the developed image thereby creating a metal image on the substrate and/or the liquid photoimageable cover coat.

22. The method of claim 14 wherein the roll of non-metallized substrate is automatically unrolled and directed through a number of coating, imaging, developing and plating stations via a conveyer like system that passes through the various stations.

23. A multilayer printed circuit made in accordance with claim 14.

24. The multilayer printed circuit of claim 22 wherein the printed circuit comprises fine line images below 2 microns.

25. A system for making a multilayer printed circuit comprising: a fust coating station containing a solution which creates a light sensitive surface on a substrate; a first imaging station containing at least one light source; a first developing station containing one or more chemistries; a first plating station containing an electroless solution; a second coating station containing a liquid photoimageable cover coat solution; a second imaging station containing at least one source of light; a second developing station containing one or more chemistries; a third coating station containing a solution which creates a light sensitive surface on a substrate; a third imaging station containing at least one light source; a third developing station containing one or more chemistries; and a second plating station containing an electroless solution.

26. The system of claim 25 further comprising a conveyer means for automatically directing a roll of non-metallized substrate through the multiple stations.