EP2129763B1 - Agent de traitement de surfaces dures - Google Patents

Agent de traitement de surfaces dures Download PDF

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Publication number
EP2129763B1
EP2129763B1 EP08708990A EP08708990A EP2129763B1 EP 2129763 B1 EP2129763 B1 EP 2129763B1 EP 08708990 A EP08708990 A EP 08708990A EP 08708990 A EP08708990 A EP 08708990A EP 2129763 B1 EP2129763 B1 EP 2129763B1
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EP
European Patent Office
Prior art keywords
alkyl
groups
formula
oxo
compound
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EP08708990A
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German (de)
English (en)
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EP2129763A1 (fr
Inventor
Nadine Warkotsch
Birgit Middelhauve
Marc-Steffen Schiedel
Matthias LÜKEN
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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Priority to PL08708990T priority Critical patent/PL2129763T3/pl
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2096—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/28—Heterocyclic compounds containing nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3454—Organic compounds containing sulfur containing sulfone groups, e.g. vinyl sulfones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/364—Organic compounds containing phosphorus containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723—Polyamines or polyalkyleneimines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3742—Nitrogen containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3788—Graft polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces

Definitions

  • the present invention relates to the field of hard surface treating agents, particularly to hard surface cleaners, and to agents which protect surfaces from soiling and / or facilitate the removal of soil contaminants.
  • agents have been found with which surfaces can be retrofitted and equipped in a way that can be carried out in a household so that they less easily pollute or easier to clean, at least for a certain period of use.
  • Of particular practical interest is a facilitation and improvement of cleaning and a prevention of re-soiling in the field of sanitary ware.
  • Conventional toilet detergents are often formulated acidic, for example by adding organic acids such as citric acid or sulfamic acid, so that they have a good activity against lime and urine stone.
  • copolymers which consist of at least one anionic vinyl monomer, one vinyl monomer having a quaternary ammonium group or one tertiary amino group, and a nonionic hydrophilic vinyl monomer or a polyfunctional vinyl monomer. These copolymers are useful as anti-soiling components in detergents and are effective, for example, against fecal contamination.
  • toilet cleaners for better lime solution are often after application for a long time, often several hours or even overnight, left to act on the ceramic.
  • the formulations are usually thickened to improve the adhesion to the ceramic. When prolonged exposure then forms on the surface of a film that is usually colored due to the product coloring and after drying is difficult to remove.
  • Biofilms consist of a thin layer of mucus (film), in which microorganisms (eg bacteria, algae, fungi, protozoa) are embedded. This can be not only a hygienic but also an aesthetic problem. As an antidote bactericidal substances are often used. However, this is not always unproblematic in view of the ecotoxicological properties of many of these substances and the associated limitations in their application. In addition, biofilms contribute to the formation of unpleasant-smelling substances and are therefore a source of undesirable bad odors, especially in the sanitary sector.
  • microorganisms eg bacteria, algae, fungi, protozoa
  • agents for the treatment of hard surfaces must fulfill further requirements. So it is important that after the treatment of the surface their appearance is not affected. This is in particular the preservation of the gloss of surfaces which have a gloss in the original or clean state, and the avoidance of residues of the treatment agent, for example in the form of stripes or streaks.
  • the object of the invention was therefore to remedy the above-described disadvantages of the prior art, at least partially.
  • the object was to improve the removability of faecal dirt and biofilms of hard surfaces, especially toilet ceramics, as well as the prevention of new formation of such soiling on such surfaces.
  • hard surfaces are, for example, surfaces of stone or ceramic materials, hard plastics, glass or metal. It can be hard surfaces such as walls, work surfaces, floors or sanitary items.
  • the invention relates to surfaces of ceramics, preferably sanitary ceramics, and more particularly of toilet bowls.
  • fouling means in particular, faecal dirt and / or biofilms.
  • the use of the substances of the general formula I or II improves the cleaning performance of hard surface cleaners and causes the treated or cleaned surfaces to be perceived as clean for longer.
  • Suitable polymeric substrates include, in particular, polyvinyl alcohols, polyalkylene amines such as polyethyleneimines, polyvinylamines, polyallylamines, polyethylene glycols, chitosan, polyamide-epichlorohydrin resins, polyaminostyrenes, terminally or pendant-substituted polysiloxanes, peptides, polypeptides and proteins, and mixtures thereof.
  • polyvinyl alcohols polyalkylene amines such as polyethyleneimines, polyvinylamines, polyallylamines, polyethylene glycols, chitosan, polyamide-epichlorohydrin resins, polyaminostyrenes, terminally or pendant-substituted polysiloxanes, peptides, polypeptides and proteins, and mixtures thereof.
  • the compound of formula I is preferably selected from 4-phenyloxycarbonyloxymethyl-2-oxo-1,3-dioxotan, 4- (4-Phenyloxycarbonyloxy) butyl-2-oxo-1,3-dioxolane, 2-oxo-1,3-dioxolan-4-yl-methyl, 2-oxo-1,3-dioxolan-4-yl-methyl, 4- (2-oxo-1,3-dioxolan-4-yl) -butyl acrylate, 4- (2-oxo-1,3-dioxolan-4-yl) butyl methacrylate, 4- (Vinylsulfonylethyloxy) -butyl-2-oxo-1,3-dioxolane and mixtures thereof.
  • the use can be carried out as part of a process for the treatment of a hard surface such that bringing one or more of the substances used according to the invention, in particular in the presence of a surfactant, in contact with the surface.
  • the invention likewise provides a method for treating a hard surface, in which the surface is brought into contact with a composition according to the invention.
  • This process can be carried out as a stand-alone treatment process for the surface, in particular to provide it with dirt-repellent properties.
  • the surface is treated with a preferably aqueous agent which additionally contains at least one surfactant in addition to at least one of the above-described substances used according to the invention.
  • the surfactant is selected so that it can not interact in an undesired manner with the substances used according to the invention.
  • the process according to the invention is carried out in such a way that the one or more compound (s) of the general formula (I) and / or II and / or the polymer obtained by reacting a polymeric substrate which has functional groups which are hydroxy , primary and secondary amino groups are selected, with one or more compound (s) of general formula (I) I and / or II is available, and the surfactant are distributed over the surface and rinsed off either after a contact time of 1 to 10 minutes or to be left to dry.
  • the bringing into contact takes place at a temperature of 5 to 50 ° C, in particular 15 to 35 ° C.
  • the process according to the invention represents a purification process which serves to clean the surface.
  • the compound (s) of general formula (I) and / or II and / or the polymer obtained by reacting a polymeric substrate having functional groups selected from hydroxy, primary and secondary amino groups with one or more several compound (s) of the general formula (I) I and / or II, are brought in a particularly preferred embodiment of the method according to the invention as a component (s) of an aqueous surfactant-containing cleaning agent with the surface in contact.
  • the agents may contain at least one ingredient selected from the group comprising acids, thickeners and non-aqueous solvents.
  • the agent according to the invention is preferably a cleaning agent, in particular a cleaning agent for ceramics, more preferably sanitary ceramics.
  • a further embodiment of the invention therefore relates to a method for improving the removability of fecal dirt and / or biofilms in flush toilets, in which an agent according to the invention, in particular a detergent according to the invention, is distributed over the surface and either after an exposure time of, for example, 1 to 10 Rinsed for a few minutes or allowed to dry.
  • compositions according to the invention may contain customary other constituents of agents, in particular detergents, for the treatment of hard surfaces, provided that they do not interact in an undesired manner with the substances used according to the invention.
  • Suitable other constituents besides acids, thickeners and nonaqueous solvents are, for example, film formers, antimicrobial agents, builders, corrosion inhibitors, complexing agents, alkalis, preservatives, bleaches, enzymes and fragrances and dyes.
  • film formers for example, film formers, antimicrobial agents, builders, corrosion inhibitors, complexing agents, alkalis, preservatives, bleaches, enzymes and fragrances and dyes.
  • further ingredients should be included, preferably 0.01 to 30 wt .-%, in particular 0.2 to 15 wt .-%.
  • compositions according to the invention contain at least one surfactant which is selected from the anionic, nonionic, amphoteric and cationic surfactants and mixtures thereof.
  • Suitable anionic surfactants are preferably C 8 -C 18 -alkylbenzenesulfonates, in particular having about 12 C atoms in the alkyl moiety, C 8 -C 20 -alkanesulfonates, C 8 -C 18 -monoalkyl sulfates, C 8 -C 18 -alkyl polyglycol ether sulfates 2 to 6 ethylene oxide units (EO) in the ether portion and sulfosuccinic mono- and di-C 8 -C 18 alkyl esters.
  • C 8 -C 18 -alkylbenzenesulfonates in particular having about 12 C atoms in the alkyl moiety
  • C 8 -C 20 -alkanesulfonates C 8 -C 18 -monoalkyl sulfates
  • C 8 -C 18 - ⁇ -olefinsulfonates sulfonated C 8 -C 18 -fatty acids, in particular dodecylbenzenesulfonate, C 8 -C 22 -Carbonklareamidethersulfate, C 8 -C 18 -Alkylpolyglykolethercarboxylate, C 8 -C 18 -N-Acyltauride , C 8 -C 18 -N sarcosinates and C 8 -C 18 -alkyl isethionates or mixtures thereof.
  • the anionic surfactants are preferably used as sodium salts, but may also be present as other alkali or alkaline earth metal salts, for example magnesium salts, and in the form of ammonium or mono-, di-, tri- or tetraalkylammonium salts, in the case of the sulfonates also in the form their corresponding acid, eg dodecylbenzenesulfonic acid.
  • examples of such surfactants are sodium cocoalkyl sulfate, sodium sec-alkanesulfonate having about 15 carbon atoms and sodium dioctylsulfosuccinate.
  • Sodium fatty alkyl sulfates and fatty alkyl + 2EO ether sulfates having 12 to 14 C atoms have proven particularly suitable.
  • C 8 -C 18 -alcohol polyglycol ethers ie ethoxylated and / or propoxylated alcohols having 8 to 18 C atoms in the alkyl moiety and 2 to 15 ethylene oxide (EO) and / or propylene oxide units (PO), C 8 - are especially nonionic surfactants.
  • C 18 -carboxylic acid polyglycol esters having 2 to 15 EO, for example tallow fatty acid + 6-EO esters, ethoxylated fatty acid amides having 12 to 18 C atoms in the fatty acid part and 2 to 8 EO, long-chain amine oxides having 14 to 20 C atoms and long-chain alkylpolyglycosides with 8 to mention 14 carbon atoms in the alkyl moiety and 1 to 3 glycoside units.
  • surfactants examples include oleyl-cetyl-alcohol with 5 EO, nonylphenol with 10 EO, lauric acid diethanolamide, Kokosalkyldimethylaminoxid and Kokosalkylpolyglucosid with an average of 1.4 glucose units.
  • Particular preference is given to using C 8-18 -fatty alcohol polyglycol ethers having in particular 2 to 8 EO, for example C 12 -fatty alcohol + 7-EO ether, and C 8-10 -alkyl polyglucosides having 1 to 2 glycoside units.
  • Suitable amphoteric surfactants are, for example, betaines of the formula (R iii ) (R iv ) (R v ) N + CH 2 COO - , in which R iii is an alkyl radical optionally interrupted by hetero atoms or heteroatom groups having 8 to 25, preferably 10 to 21 carbon atoms and R iv and R v are identical or different alkyl radicals having 1 to 3 carbon atoms, in particular C 10 -C 18 -alkyl-dimethylcarboxymethylbetain and C 11 -C 17 -alkylamidopropyl-dimethylcarboxymethylbetain.
  • Suitable cationic surfactants include the quaternary ammonium compounds of the formula (R vi) (R vii) (R viii) (R ix) N + X - in which R VI to R ix four identical or different, in particular two long and two short-chain, alkyl radicals and X - are an anion, in particular a halide ion, for example, didecyl-dimethyl-ammonium chloride, alkyl-benzyl-didecyl-ammonium chloride and mixtures thereof.
  • the surfactant component comprises only one or more anionic surfactants, preferably C 8 -C 18 -alkyl sulfates and / or C 8 -C 18 -alkyl ether sulfates, and / or one or more nonionic surfactants, preferably C 8-18 Fatty alcohol polyglycol ethers having 2 to 8 EO and / or C 8-10 alkyl polyglucosides having 1 to 2 glycoside units.
  • compositions according to the invention preferably comprise surfactants in amounts of from 0.01 to 30% by weight, in particular from 0.2 to 15% by weight, in each case based on the total weight of the composition.
  • compositions of the invention may further contain one or more acids.
  • Suitable acids are in particular organic acids such as formic acid, acetic acid, citric acid, glycolic acid, lactic acid, succinic acid, adipic acid, malic acid, tartaric acid and gluconic acid or amidosulfonic acid.
  • organic acids such as formic acid, acetic acid, citric acid, glycolic acid, lactic acid, succinic acid, adipic acid, malic acid, tartaric acid and gluconic acid or amidosulfonic acid.
  • hydrochloric acid, sulfuric acid, phosphoric acid and nitric acid or mixtures thereof Particular preference is given to acids selected from the group comprising amidosulfonic acid, citric acid, lactic acid and formic acid. They are preferably used in amounts of 0.01 to 30 wt .-%, particularly preferably 0.2 to 15 wt .-%.
  • an agent according to the invention contains a thickening agent.
  • a thickening agent for this purpose, in principle, all viscosity regulators used in detergents and cleaning agents in the prior art into consideration, such as organic natural thickeners (agar, carrageenan, tragacanth, gum arabic, alginates, pectins, polyoses, guar flour, locust bean gum, starch, dextrins , Gelatin, casein), organic modified natural products (carboxymethylcellulose and other cellulose ethers, hydroxyethyl and propylcellulose and the like, core flour ethers), organic fully synthetic thickeners (polyacrylic and polymethacrylic compounds, vinyl polymers, polycarboxylic acids, polyethers, polyimines, polyamides) and inorganic thickeners (polysilicic acids, clay minerals such as montmorillonites, zeolites, silicas).
  • organic natural thickeners agar, carrageenan, tragacanth, gum arab
  • polyacrylic and polymethacrylic compounds include the high molecular weight homopolymers of acrylic acid crosslinked with a polyalkenyl polyether, in particular an allyl ether of sucrose, pentaerythritol or propylene (INCI name according to the International Dictionary of Cosmetic Ingredients of The Cosmetic, Toiletry, and Fragrance Association (US Pat. CTFA): carbomers), also referred to as carboxyvinyl polymers.
  • polyacrylic acids are obtainable inter alia from Fa. 3V Sigma under the tradename Polygel ® such as Polygel ® DA, and by the company.
  • Carbopol ® such as Carbopol ® 940 (molecular weight about 4,000,000), Carbopol ® 941 (molecular weight approximately 1,250,000) or Carbopol ® 934 (molecular weight approximately 3,000,000).
  • acrylic acid copolymers are included: (i) Copolymers of two or more monomers from the group of acrylic acid, methacrylic acid and their simple, preferably with C 1-4 alkanols formed esters (INCI acrylates copolymer), such as the copolymers of methacrylic acid acrylate, butyl acrylate and methyl methacrylate (CAS name according to Chemical Abstracts service: 25035-69-2) or of butyl acrylate and methyl methacrylate (CAS 25852-37-3) and, for example, by the company Rohm & Haas under the trade names Aculyn ® and Acusol.
  • ICI acrylates copolymer such as the copolymers of methacrylic acid acrylate, butyl acrylate and methyl methacrylate (CAS name according to Chemical Abstracts service: 25035-69-2) or of butyl acrylate and methyl methacrylate (CAS 25852-37-3) and, for example, by the company Rohm &
  • Tego ® and from Degussa (Goldschmidt) under the trade name Tego ® polymer are available, for example the anionic non-associative polymers Aculyn ® 22, Aculyn ® 28, Aculyn ® 33 (crosslinked), Acusol ® 810, Acusol ® 823 and Acusol ® 830 ( CAS 25852-37-3); (ii) crosslinked high molecular weight acrylic acid copolymers, such as those crosslinked with an allyl ether of sucrose or pentaerythritol copolymers of C 10-30 alkyl acrylates with one or more monomers selected from the group of acrylic acid, methacrylic acid and their simple, preferably with C 1-4 alkanols formed, esters (INCI acrylates / C10-30 alkyl acrylate crosspolymer) and which are obtainable for example from the company.
  • Carbopol ® examples hydrophobized ETD 2623 and Carbopol ® 1382 (INCI acrylates / C10 30 alkyl acrylate Crosspolymer) and Carbopol AQUA ® 30 (formerly Carbopol ® EX 473).
  • Further thickeners are the polysaccharides and heteropolysaccharides, in particular the polysaccharide gums, for example gum arabic, agar, alginates, carrageenans and their salts, guar, guar gum, tragacanth, gellan, Ramzan, dextran or xanthan and their derivatives, for example propoxylated guar, and also their mixtures.
  • polysaccharide thickeners such as starches or cellulose derivatives
  • starches or cellulose derivatives may alternatively or preferably be used in addition to a polysaccharide gum, for example starches of various origins and starch derivatives, for example hydroxyethyl starch, starch phosphate esters or starch acetates, or carboxymethylcellulose or its sodium salt, methyl, ethyl, hydroxyethyl, Hydroxypropyl, hydroxypropyl methyl or hydroxyethyl methyl cellulose or cellulose acetate.
  • starches of various origins and starch derivatives for example hydroxyethyl starch, starch phosphate esters or starch acetates, or carboxymethylcellulose or its sodium salt, methyl, ethyl, hydroxyethyl, Hydroxypropyl, hydroxypropyl methyl or hydroxyethyl methyl cellulose or cellulose acetate.
  • a particularly preferred polysaccharide thickener is the microbial anionic heteropolysaccharide xanthan gum, which is produced by Xanthomonas campestris and some other species under aerobic conditions with a molecular weight of 2-15 ⁇ 10 6, and for example, by Fa. Kelco under the trade names Keltrol ® and Kelzan ® or from Rhodia is available under the trade name Rhodopol ®. As thickeners also phyllosilicates can be used become.
  • Laponite ® magnesium or sodium-magnesium phyllosilicates from Solvay Alkali, in particular the Laponite ® RD or Laponite ® RDS, and the magnesium silicates Süd-Chemie, especially the Optigel ® SH.
  • the agent according to the invention contains from 0.01 to 30% by weight, in particular from 0.2 to 15% by weight, of a thickener, preferably of a polysaccharide thickener, for example xanthan gum.
  • compositions according to the invention may contain solvents, in particular water and / or non-aqueous solvents, preferably water-soluble organic solvents.
  • solvents include, for example, lower alcohols and / or ether alcohols, which are understood as lower alcohols in the context of this invention straight-chain or branched C 1-6 alcohols.
  • the alcohols used are in particular ethanol, isopropanol and n-propanol.
  • ether alcohols are sufficiently water-soluble compounds having up to 10 carbon atoms in the molecule into consideration.
  • ether alcohols examples include ethylene glycol monobutyl ether, propylene glycol monobutyl ether, diethylene glycol monobutyl ether, propylene glycol monotertiary butyl ether and propylene glycol monoethyl ether, of which in turn, ethyl diglycol monobutyl ether and propylene glycol monobutyl ether are preferred.
  • ethanol is used as the solvent.
  • Solvents may be included in the detergent in amounts of 0.01 to 30% by weight, preferably 0.2 to 15% by weight.
  • compositions according to the invention can furthermore contain film formers which can contribute to a better wetting of the surface.
  • film formers which can contribute to a better wetting of the surface.
  • the film former is selected from the group comprising polyethylene glycol, polyethylene glycol derivatives and mixtures thereof, preferably having a molecular weight between 200 and 20,000,000, more preferably between 5,000 and 200,000.
  • the film former is advantageously used in amounts of from 0.01 to 30% by weight, in particular from 0.2 to 15% by weight.
  • Compositions according to the invention may furthermore comprise one or more antimicrobial active ingredients, preferably in an amount of from 0.01 to 1% by weight, in particular from 0.05 to 0.5% by weight, particularly preferably from 0.1 to 0.3 wt .-%.
  • antimicrobial agents from the groups of alcohols, aldehydes, antimicrobial acids or their salts, carboxylic acid esters, acid amides, phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, oxygen, nitrogen acetals and formals, benzamidines, isothiazoles and their derivatives such as isothiazolines and isothiazolinones, phthalimide derivatives, pyridine derivatives, antimicrobial surface active compounds, guanidines, antimicrobial amphoteric compounds, quinolines, 1,2-dibromo-2,4-dicyanobutane, iodo-2-propynyl-butyl-carba
  • preferred Antimicrobial agents are preferably selected from the group comprising ethanol, n-propanol, i-propanol, 1,3-butanediol, phenoxyethanol, 1,2-propylene glycol, glycerol, undecylenic acid, citric acid, lactic acid, benzoic acid, salicylic acid, thymol, 2-benzyl 4-chlorophenol, 2,2'-methylenebis (6-bromo-4-chlorophenol), 2,4,4'-trichloro-2'-hydroxydiphenyl ether, N- (4-chlorophenyl) -N- (3 , 4-dichlorophenyl) urea, N, N '- (1,10-decanediyldi-1-pyridinyl-4-ylidene) bis (1-octan-amine) dihydrochloride, N, N'-bis (4 -Chlorophenyl) -3,12-diimino-2,4,11,13
  • Preferred antimicrobial surface-active quaternary compounds contain an ammonium, sulfonium, phosphonium, iodonium or arsonium group.
  • antimicrobially effective essential oils can be used, which at the same time provide for a scenting of the cleansing agent.
  • particularly preferred antimicrobial agents are selected from the group comprising salicylic acid, quaternary surfactants, in particular benzalkonium chloride, peroxo compounds, in particular hydrogen peroxide, alkali metal hypochlorite and mixtures thereof.
  • Water-soluble and / or water-insoluble builders can be used in the compositions according to the invention.
  • Water-soluble builders are preferred because they tend to be less likely to leave insoluble residues on hard surfaces.
  • Typical builders which may be present in the invention are the low molecular weight polycarboxylic acids and their salts, the homopolymeric and copolymeric polycarboxylic acids and their salts, the citric acid and its salts, the carbonates, phosphates and silicates.
  • Water-insoluble builders include the zeolites, which may also be used, as well as mixtures of the aforementioned builders.
  • Suitable corrosion inhibitors are, for example, the following substances named according to INCI: cyclohexylamines, diammonium phosphates, dilithium oxalates, dimethylamino methylpropanol, dipotassium oxalates, dipotassium phosphates, disodium phosphates, disodium pyrophosphates, disodium tetrapropenyl succinates, hexoxyethyl diethylammonium, phosphates, nitromethanes, potassium silicates, sodium aluminates, Sodium Hexametaphosphate, Sodium Metasilicate, Sodium Molybdate, Sodium Nitrites, Sodium Oxalate, Sodium Silicate, Stearamidopropyl Dimethicone, Tetrapotassium Pyrophosphate, Tetrasodium Pyrophosphate, Triisopropanolamine.
  • Chelants also called sequestering agents, are ingredients that are capable of complexing and inactivating metal ions to prevent their adverse effects on the stability or appearance of the agents, for example clouding.
  • it is important to complex the incompatible with numerous ingredients calcium and magnesium ions of water hardness.
  • the complexation of the ions of heavy metals such as iron or copper delays the oxidative decomposition of the finished agents.
  • the complexing agents support the cleaning effect.
  • Suitable examples are the following according to INCI designated complexing agent: Aminotrimethylene, Phosphonic Acid, Beta-Alanine Diacetic Acid, Calcium Disodium EDTA, Citric Acid, Cyclodextrin, Cyclohexanediamine Tetraacetic Acid, Diammonium Citrate, Diammonium EDTA, Diethylenetriamine Pentamethylene Phosphonic Acid, Dipotassium EDTA, Disodium Azacycloheptane Diphosphonate, Disodium EDTA, Disodium Pyrophosphate, EDTA, E -tidronic Acid, Galactic Acid, Gluconic Acid, Glucuronic Acid, HEDTA, Hydroxypropyl Cyclodextrin, Methyl Cyclodextrin, Pentapotassium Triphosphate, Pentasodium Aminotrimethylene Phosphonate, Pentasodium Ethylenediamine Tetramethylene Phosphonate, Pentasodium Pentetate, Penta
  • alkalis it is also possible for alkalis to be present.
  • Suitable bases in agents according to the invention are preferably those from the group of alkali metal and alkaline earth metal hydroxides and carbonates, in particular sodium carbonate or sodium hydroxide.
  • ammonia and / or alkanolamines having up to 9 C atoms in the molecule preferably the ethanolamines, in particular monoethanolamine.
  • Preservatives may also be included in compositions of the invention. As such, essentially the substances mentioned in the antimicrobial agents can be used.
  • the agents may further contain bleaching agents.
  • Suitable bleaching agents include peroxides, peracids and / or perborates, particularly preferred is hydrogen peroxide.
  • Sodium hypochlorite is less suitable for acidic detergents due to the release of toxic chlorine gas vapors, but can be used in alkaline detergents.
  • a bleach activator may be included in addition to the bleaching agent.
  • the agent according to the invention may also contain enzymes, preferably proteases, lipases, amylases, hydrolases and / or cellulases. They may be added to the composition in any form established in the art. These include liquid or gel agents in particular solutions of the enzymes, advantageously as concentrated as possible, low in water and / or added with stabilizers. Alternatively, the enzymes can be encapsulated, for example by spray drying or extrusion of the enzyme solution together with a, preferably natural, polymer or in the form of capsules, for example those in which the enzymes are entrapped as in a solidified gel or in core-shelled form. Type in which an enzyme-containing core is coated with a water, air and / or chemical impermeable protective layer.
  • capsules are applied by methods known per se, for example by shaking or rolling granulation or in fluid-bed processes.
  • granules for example by applying polymeric film-forming agent, low in dust and storage stable due to the coating.
  • enzyme stabilizers may be present in enzyme-containing agents in order to protect an enzyme contained in an agent according to the invention from damage such as, for example, inactivation, denaturation or decomposition, for example by physical influences, oxidation or proteolytic cleavage.
  • Suitable enzyme stabilizers are in particular: benzamidine hydrochloride, borax, boric acids, boronic acids or their salts or esters, especially derivatives with aromatic groups, for example substituted phenylboronic acids or their salts or esters; Peptide aldehydes (oligopeptides with reduced C-terminus), amino alcohols such as mono-, di-, triethanol- and -propanolamine and mixtures thereof, aliphatic carboxylic acids up to C12, such as succinic acid, other dicarboxylic acids or salts of said acids; end-capped fatty acid amide alkoxylates; lower aliphatic alcohols and especially polyols, for example glycerol, ethylene glycol, propylene glycol or sorbitol; and reducing agents and antioxidants such as sodium sulfite and reducing sugars.
  • benzamidine hydrochloride borax, boric acids, boronic acids or their salts or esters, especially derivatives with aromatic
  • stabilizers for example the combination of polyols, boric acid and / or borax, the combination of boric acid or borate, reducing salts and succinic acid or other dicarboxylic acids or the combination of boric acid or borate with polyols or polyamino compounds and with reducing salts.
  • the agent according to the invention may finally contain one or more fragrances and / or one or more dyes.
  • dyes both water-soluble and oil-soluble dyes can be used, on the one hand the compatibility with other ingredients, such as bleaches, is observed and on the other hand, the dye used should not be substantive to the surfaces, especially compared to toilet ceramics, even with prolonged exposure , The choice of suitable perfume is also limited only by possible interactions with the other detergent components.
  • compositions according to the invention can be carried out in a customary manner by mixing the components contained in the composition in a suitable manner.
  • Agents according to the invention which are preferably designed as cleaning agents, find application in the treatment of hard surfaces, in particular sanitary ceramics. They can be used to remove dirt from hard surfaces and to reduce the re-contamination of these surfaces, as well as to allow faster and more thorough cleaning of soiled surfaces.
  • means according to the invention are used for improved removal of fecal dirt and / or biofilms from the surfaces of flush toilets and / or for reducing the re-soiling of such surfaces with fecal dirt and / or biofilms.
  • the agent is spread over the surface and either rinsed after an exposure time of preferably 1 to 10 minutes or left to dry. After treating the surface in this manner, fecal soiling is easier to remove, often without the aid of mechanical aids such as a toilet brush. In addition, any dried-up detergent residues can be rinsed off more easily.
  • one of the toilet-cleaner formulations E1-E3 according to the invention or the comparison formulation V1 was then applied, distributed over a wide area, allowed to act for 5 minutes and rinsed off. Thereafter, an artificial Hurkalschmutz (mixture of bacterial biomass, fiber from plant cell wall material, glycerol and an aqueous solution, according to the patent DE 103 57 232 B3 ), allowed to dry for 30 minutes and rinsed off. While 80% of the faeces contamination were still present when using the comparative formulation V1 not according to the invention, more than half of the fecal dirt could already be removed on surfaces cleaned with the agents E1-E3 with one rinse, after the second rinse the dirt was 100% away.
  • an artificial Grekalschmutz mixture of bacterial biomass, fiber from plant cell wall material, glycerol and an aqueous solution, according to the patent DE 103 57 232 B3
  • one of the toilet cleaner formulations E1-E3 according to the invention or the comparison formulation V1 was applied after the pre-cleaning described above, distributed over a wide area and allowed to act for three hours. Thereafter, a flat blue film was observed on the toilet inner wall for all formulations. After rinsing the toilet, in the case of cleaner V1 not according to the invention, 90% of the original surface was covered with a visible blue film of cleaner formulation, whereas no visible film was present when using formulations E1, E2 and E3 according to the invention.
  • E4 to E6 were prepared as examples of non-thickened formulations, which also contained the polymer used in the invention, and a comparative solution V2.

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Abstract

La présente invention concerne l'utilisation de composés de formules générales (I) et (II) et de polymères obtenus par mise en réaction de tels composés avec des substrats polymères comportant des groupes fonctionnels sélectionnés parmi des groupes hydroxy et des groupes amino primaires et secondaires, pour traiter des surfaces dures. La surface traitée est ainsi protégée contre un encrassement et/ou il est plus facile d'éliminer les salissures de la surface.

Claims (8)

  1. Agent pour le traitement d'une surface dure, contenant
    a) un ou plusieurs composé(s) de la/des formule(s) générale(s) I et/ou II
    Figure imgb0004
     où
    R représente C1-C12-alkylène ;
    k représente un nombre supérieur à 0,
    X représente CO-CH=CH2, CO-C(CH3)=CH2, CO-O-aryle, C2-C6-alkylène-SO2-CH=CH2 ou CO-NH-R1 et R1 représente C1-C30-alkyle, C1-C30-halogénoalkyle, C1-C30-hydroxyalkyle, C1-C6-alkyloxy-C1-C30-alkyle, C1-C6-alkylcarbonyloxy-C1-C30-alkyle, amino-C1-C30-alkyle, mono(C1-C6-alkyl)amino-C1-C30-alkyle ou di(C1-C6-alkyl)amino-C1-C30-alkyle, ammonio-C1-C30-alkyle, polyoxyalkylène-C1-C30-alkyle, polysiloxanyl-C1-C30-alkyle, (méth)acryloyloxy-C1-C30-alkyle, sulfono-C1-C30-alkyle, phosphono-C1-C30-alkyle, di(C1-C6-alkyl)phosphono-C1-C30-alkyle, phosphonato-C1-C30-alkyle, di(C1-C6-alkyl)phosphonato-C1-C30-alkyle ou un radical saccharide, cette signification n'existant pour X dans la formule I que lorsque k vaut 1, ou
    X pour le cas où k représente un nombre supérieur à 1,
    (i) représente le radical d'une polyamine, à laquelle la partie de formule entre parenthèses est reliée via des groupes (CO)NH, ou
    (ii) représente une structure polymère à laquelle la partie de formule se trouvant entre parenthèses est liée via des groupes (CO), NH-C2-C6-alkylène-O(CO) ou (CO)-O-C2-C6-alkylène-O(CO), ou
    (iii) représente une structure polymère à laquelle la partie de formule se trouvant entre parenthèses est liée via des groupes (CO)-polysiloxanyl-C1-C30-alkyle, et/ou un polymère qui peut être obtenu par transformation d'un substrat polymère qui dispose de groupes fonctionnels qui sont choisis parmi les groupes hydroxy, les groupes amino primaires et secondaires, avec un ou plusieurs composé(s) de la/des formule(s) générale(s) I et/ou II,
    b) au moins un agent tensioactif et
    c) le cas échéant de l'eau et/ou d'autres constituants usuels compatibles avec les autres composants d'agents de traitement ou de nettoyage de surfaces, en contenant au moins un constituant choisi dans le groupe comprenant les acides, les épaississants et les solvants non aqueux.
  2. Agent selon la revendication 1, caractérisé en ce qu'il contient un ou plusieurs composé(s) de la/des formule(s) générale(s) I et/ou II et/ou un polymère qui peut être obtenu par transformation d'un substrat polymère qui dispose de groupes fonctionnels qui sont choisis parmi les groupes hydroxy, les groupes amino primaires et secondaires, avec un ou plusieurs composé(s) de la/des formule(s) générale(s) I et/ou II, en des quantités de 0,01 à 50% en poids, de préférence de 0,2 à 15% en poids et en particulier de 0,5 à 5% en poids, par rapport au poids total de l'agent.
  3. Agent selon la revendication 1 ou 2, caractérisé en ce qu'il s'agit d'un agent de nettoyage, avant tout pour la céramique, en particulier la céramique sanitaire.
  4. Agent selon l'une quelconque des revendications 1 à 3, caractérisé en ce que le substrat polymère est choisi dans le groupe comprenant les poly(alcools vinyliques), les polyalkylène-amines, telles que les polyéthylène-imines, les polyvinylamines, les polyallylamines, les polyéthylèneglycols, le chitosane, les résines de polyamide-épichlorhydrine, les polyaminostyrènes ; les polysiloxanes, les peptides, les polypeptides et les protéines substitués par des groupes aminoalkyle en position terminale ou comme groupes latéraux ; ainsi que leurs mélanges.
  5. Agent selon l'une quelconque des revendications 1 à 4, caractérisé en ce que le substrat polymère est choisi parmi les polyéthylène-imines présentant un poids moléculaire dans la plage de 5000 à 100 000, les composés de formule NH2-[CH2]m-(Si(CH3)2O)n-Si(CH3)2-[CH2]o-R', m =1 à 10, de préférence 1 à 5, de manière particulièrement préférée 1 à 3, n valant 1 à 50, de préférence 30 à 50, o = 0 à 10, de préférence 1 à 5, de manière particulièrement préférée 1 à 3 et R' = H, C1-22-alkyle, un groupe amino ou ammonium et les composés de formule NH2-[CH(CH3)-CH2O]l-[CH2-CH2O]m-[CH2-CH(CH3)O]n-R", I, m et n valant, indépendamment les uns des autres, des nombres de 0 à 50, à condition que la somme I + m + n = 5 à 100, en particulier 10 à 50, de préférence 10 à 30, de manière particulièrement préférée 10 à 20, et R" = H, un groupe C1-22-alkyle, C1-22-aminoalkyle ou C1-22-ammoniumalkyle, et leurs mélanges.
  6. Agent selon l'une quelconque des revendications 1 à 5, caractérisé en ce que le composé de formule I est choisi parmi
    le 4-phényloxycarbonyloxyméthyl-2-oxo-1,3-dioxolane,
    le 4-(4-phényloxycarbonyloxy)butyl-2-oxo-1,3-dioxolane,
    l'acrylate de 2-oxo-1,3-dioxolan-4-ylméthyle,
    le méthacrylate de 2-oxo-1,3-dioxolan-4-ylméthyle,
    l'acrylate de 4-(2-oxo-1,3-dioxolan-4-yl)-butyle,
    le méthacrylate de 4-(2-oxo-1,3-dioxolan-4-yl)-butyle,
    le 4-(vinylsulfonyléthyloxy)-butyl-2-oxo-1,3-dioxolane et leurs mélanges.
  7. Procédé pour le traitement d'une surface dure, dans lequel la surface est mise en contact avec un agent selon l'une quelconque des revendications 1 à 6.
  8. Procédé selon la revendication 7, caractérisé
    en ce ledit un ou lesdits plusieurs composé(s) de la/des formule(s) générale(s) I et/ou II et/ou le polymère qui peut être obtenu par transformation d'un substrat polymère qui dispose de groupes fonctionnels qui sont choisis parmi les groupes hydroxy, les groupes amino primaires et secondaires, avec un ou plusieurs composé(s) de la/des formule(s) générale(s) I et/ou II, ainsi que l'agent tensioactif sont étalés sur la surface et soit éliminés par rinçage après un temps d'action de 1 à 10 minutes, soit on les laisse sécher.
EP08708990A 2007-04-03 2008-02-14 Agent de traitement de surfaces dures Not-in-force EP2129763B1 (fr)

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Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2660389C (fr) 2006-08-07 2014-12-02 The University Of Montana Procede de preparation d'acides organiques par le biais de l'oxydation al'aide d'acide nitrique
US20090250653A1 (en) * 2006-08-07 2009-10-08 Kiely Donald E Hydroxycarboxylic Acids and Salts
EP2209835A2 (fr) 2007-11-15 2010-07-28 The University Of Montana Agents formant gel d'hydroxypolyamide
EP2336750B1 (fr) * 2009-12-10 2016-04-13 The Procter & Gamble Company Procédé de mesure de la capacité d'enlèvement de taches d'un produit de nettoyage
ES2548772T3 (es) * 2009-12-10 2015-10-20 The Procter & Gamble Company Producto para lavavajillas y uso del mismo
EP2333040B2 (fr) * 2009-12-10 2019-11-13 The Procter & Gamble Company Composition de détergent
EP2333041B1 (fr) * 2009-12-10 2013-05-15 The Procter & Gamble Company Procédé et utilisation d'une composition pour lave-vaisselle
EP2333039B2 (fr) * 2009-12-10 2020-11-11 The Procter & Gamble Company Procédé et utilisation d'une composition pour lave-vaisselle
RU2016130012A (ru) 2010-11-11 2018-12-07 Ривертоп Реневаблс Ингибирующая коррозию композиция
ES2548405T3 (es) * 2011-04-21 2015-10-16 Rivertop Renewables, Inc. Composición fijadora de calcio
EP2721138A1 (fr) * 2011-06-17 2014-04-23 Reckitt Benckiser N.V. Composition
EP2925826A1 (fr) 2012-11-28 2015-10-07 Rivertop Renewables Compositions abaissant le point de congélation et inhibant la corrosion
US9346736B2 (en) 2013-03-13 2016-05-24 Rivertop Renewables, Inc. Oxidation process
US9670124B2 (en) 2013-03-13 2017-06-06 Rivertop Renewables, Inc. Nitric acid oxidation process
WO2014159694A1 (fr) 2013-03-13 2014-10-02 Rivertop Renewables, Inc. Procédés perfectionnés d'oxydation à l'acide nitrique
ES2744403T3 (es) 2013-03-15 2020-02-25 Lubrizol Advanced Mat Inc Copolímeros de ácido itacónico
CN105073967A (zh) * 2013-03-26 2015-11-18 宝洁公司 用于清洁硬质表面的清洁组合物
WO2015042013A1 (fr) 2013-09-18 2015-03-26 Lubrizol Advanced Materials, Inc. Polymères linéaires stables
ES2823562T3 (es) 2014-03-14 2021-05-07 Lubrizol Advanced Mat Inc Polímeros y copolímeros de ácido itacónico
KR20170054453A (ko) 2014-09-10 2017-05-17 바스프 에스이 캡슐화 세정 조성물
US20180030389A1 (en) * 2016-07-29 2018-02-01 Amit Garyali Multi-Purpose Cleaner System
IT201800004475A1 (it) * 2018-04-13 2019-10-13 Composizione detergente

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008119831A2 (fr) * 2007-04-03 2008-10-09 Henkel Ag & Co. Kgaa Agent de lavage anti-gris

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001049293A (ja) * 1999-08-06 2001-02-20 Lion Corp 洗浄剤組成物
JP2001294890A (ja) * 2000-04-17 2001-10-23 Lion Corp 香料補助組成物
JP2001300286A (ja) * 2000-04-20 2001-10-30 Lion Corp 分解性界面活性剤
MXPA03008106A (es) * 2001-03-07 2003-12-12 Procter & Gamble Composicion topica que comprende un agente cosmetico enlazante a base de imidocarbonato ciclico.
DE10246140A1 (de) * 2002-10-01 2004-04-15 Basf Ag Umsetzungsprodukte von 2-Propylheptanol mit1-Halogen-2,3-epoxypropanen und 1-Hydroxy-2,3-epoxypropan
DE10246139A1 (de) * 2002-10-01 2004-04-15 Basf Ag Alkylglycidolcarbonate als Co-Tenside
DE10357232B3 (de) 2003-12-09 2005-06-30 Henkel Kgaa Artifizielle Fäkalanschmutzung
EP1541568A1 (fr) 2003-12-09 2005-06-15 Deutsches Wollforschungsinstitut an der Rheinisch-Westfälischen Technischen Hochschule Aachen e.V. Carbonates et urées cycliques et réactifs pour la modification de biomolecules, polymères et surfaces
WO2006005358A1 (fr) 2004-07-10 2006-01-19 Henkel Kommanditgesellschaft Auf Aktien Compositions de nettoyage contenant des copolymeres

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008119831A2 (fr) * 2007-04-03 2008-10-09 Henkel Ag & Co. Kgaa Agent de lavage anti-gris

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US20100041574A1 (en) 2010-02-18

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