EP2129254B1 - Method for the production of a part of a hook and loop fastener together with a corresponding apparatus - Google Patents

Method for the production of a part of a hook and loop fastener together with a corresponding apparatus Download PDF

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Publication number
EP2129254B1
EP2129254B1 EP08707350.8A EP08707350A EP2129254B1 EP 2129254 B1 EP2129254 B1 EP 2129254B1 EP 08707350 A EP08707350 A EP 08707350A EP 2129254 B1 EP2129254 B1 EP 2129254B1
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EP
European Patent Office
Prior art keywords
parts
head
stem
free ends
stem parts
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EP08707350.8A
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German (de)
French (fr)
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EP2129254A1 (en
Inventor
Jan Tuma
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Gottlieb Binder GmbH and Co KG
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Gottlieb Binder GmbH and Co KG
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Priority to PL08707350T priority Critical patent/PL2129254T3/en
Publication of EP2129254A1 publication Critical patent/EP2129254A1/en
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Classifications

    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44BBUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00Fasteners of the touch-and-close type; Making such fasteners
    • A44B18/0046Fasteners made integrally of plastics
    • A44B18/0049Fasteners made integrally of plastics obtained by moulding processes
    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44BBUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00Fasteners of the touch-and-close type; Making such fasteners
    • A44B18/0023Woven or knitted fasteners
    • A44B18/0038Male or hook elements
    • A44B18/0042Male or hook elements of a mushroom type
    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44BBUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00Fasteners of the touch-and-close type; Making such fasteners
    • A44B18/0046Fasteners made integrally of plastics
    • A44B18/0061Male or hook elements
    • A44B18/0065Male or hook elements of a mushroom type
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1089Methods of surface bonding and/or assembly therefor of discrete laminae to single face of additional lamina
    • Y10T156/109Embedding of laminae within face of additional laminae
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T24/00Buckles, buttons, clasps, etc.
    • Y10T24/27Buckles, buttons, clasps, etc. including readily dissociable fastener having numerous, protruding, unitary filaments randomly interlocking with, and simultaneously moving towards, mating structure [e.g., hook-loop type fastener]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T24/00Buckles, buttons, clasps, etc.
    • Y10T24/27Buckles, buttons, clasps, etc. including readily dissociable fastener having numerous, protruding, unitary filaments randomly interlocking with, and simultaneously moving towards, mating structure [e.g., hook-loop type fastener]
    • Y10T24/2792Buckles, buttons, clasps, etc. including readily dissociable fastener having numerous, protruding, unitary filaments randomly interlocking with, and simultaneously moving towards, mating structure [e.g., hook-loop type fastener] having mounting surface and filaments constructed from common piece of material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24008Structurally defined web or sheet [e.g., overall dimension, etc.] including fastener for attaching to external surface
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24008Structurally defined web or sheet [e.g., overall dimension, etc.] including fastener for attaching to external surface
    • Y10T428/24017Hook or barb

Definitions

  • the invention relates to a method for producing an adhesive closure part, comprising at least one plastic material, in which a support member having a plurality of projecting handle parts with individual head parts is connected such that at least a part of said handle parts whose free ends in touching or immersing plant with an investment side of each assignable headboard come, which are still present at least in the partially liquid or partially plasticized state during the connection process of handle parts and assignable headboards and the headboards are fully cured after the connection.
  • the invention further relates to a device for producing an adhesive closure part with the method.
  • Adjacent adhesive closure parts which are also attributed to the mechanical fastening elements, form a closure which can be repeatedly opened and closed with complementary closure parts, wherein hooks or mushroom-like closure parts interact with loop-like closure elements of another adhesive closure part to form the adhesive closure. Solutions are also known in which the same adhesive closure elements of two different adhesive closure parts interact with one another (hermaphroditic closure).
  • the US 2003/0126724 A1 discloses a fastener closure member having a sheet-like support member and a plurality of handle parts, which are arranged as projections on the support member and each composed of a soft, elastic-flexible resin material and a hard, solid resin material.
  • each of the shaft of the stem part of the hard resin or plastic material and its upper part may be formed from the soft resin or plastic material.
  • the US Pat. No. 6,180,205 B1 a manufacturing method using a forming roller, in which a band-like support member is connectable to a plurality of relatively large dimensionable hook closure elements.
  • the shaping roller has hook-shaped form recesses on its outer circumference, in which plastic material is pressed in through a first extruder device in order to fill the mold. Excess plastic material on the outer peripheral side of the forming roll is removed by means of a Schneidabtrag Rhein, which is referred to in technical language as a doctor blade.
  • the carrier part material is then applied by means of a second extruder device arranged downstream in the direction of manufacture, and with the hook-shaped closure parts during the Cooling process of the roller firmly connected.
  • a peel roller then removes the finished closure from the former. Due to the hook geometry, this can lead to difficulties during the demolding process and, furthermore, during the production process, a relatively high proportion of plastic waste arises due to the use of said doctor blade.
  • the adhesive closure part produced in this way which is intended in particular to serve as a closure for baby and incontinence diapers, is relatively stiff and, to that extent, still leaves desires open with regard to the closure characteristic.
  • the hooking means produced in a conventional manner consist of individual handle parts, at whose free ends plate-like interlocking heads are present.
  • the materials forming the additional headers are applied to the hooking heads via an applicator roll.
  • the typically used acrylate material has a similar consistency and viscosity as honey and forms a kind of application bath between the applicator roll and a counter-roller and can be passed from there successively from the applicator roll to the adhesive closure part.
  • the surface tension of the acrylate material is selected to provide some form of drop formation with the result that the headers form hemispherical caps on the hooking heads.
  • Energy is supplied to the hooking heads, for example in the form of UV radiation and / or in the form of heat.
  • the invention has the object to further improve the known solutions while maintaining their advantages, especially at low production costs to provide a functionally reliable adhesive closure, which is adjustable in its wide behavior of its behavior.
  • This object is achieved by a method having the features of patent claim 1 and a device having the features of claim 4.
  • the method according to the invention serves to produce an adhesive closure part, preferably consisting of at least one plastic material, characterized in that head part material is provided in a molding tool having a multiplicity of individual mold recesses configured in accordance with the respective head geometry, and in that the free ends of the stem parts when approached on or at the time of introduction into the mold recesses touch the at least partially liquid or partially plasticized plant sides of the head parts and / or immerse in the head part material.
  • a device has been found in which for the individual head parts a mold is present with a variety of mold cavities corresponding to the respective head geometry and with a feeder for the already finished support member with the handle parts whose free Ends are inserted by means of the feed device in the mold recesses.
  • stem and head parts consist of different plastic materials, in particular the stem parts are formed from a thermoplastic material and the head parts made of acrylate.
  • the relatively hard acrylate material for the respective head part allows a robust Unterhakungsdorfkeit for the loops of a corresponding adhesive closure part, so that an adhesive closure constructed in this way allows very high adhesion and peel strength values.
  • the inventive method is based on the manufacturing device according to the Fig. 1 explained in more detail.
  • the inventive method is used to produce a designated as a whole with 10 adhesive closure part, in which a band-shaped support member 12 is connected to a plurality of projecting stem parts 14 with individual head parts 16 such that at least a portion of said stem parts 14 whose free ends 18 in touching or immersion plant come with a plant side 20 of each assignable head part 16.
  • a band-shaped support member 12 is connected to a plurality of projecting stem parts 14 with individual head parts 16 such that at least a portion of said stem parts 14 whose free ends 18 in touching or immersion plant come with a plant side 20 of each assignable head part 16.
  • a mold designated as a whole with 22 is provided with a plurality of individual mold recesses 24, which correspond in terms of their design to the respective head geometry.
  • the mold recesses 24 are part of a circulating in the manner of a conveyor belt forming belt 26, wherein the mold recesses 24 of the upper run are filled with plastic material and the lower run substantially the empty mold recesses 24 leads.
  • the mold recesses 24 are in turn in the transverse and longitudinal direction of the forming belt 24 - in regular or irregular distribution - multiple available.
  • a feed device designated as a whole by 28 is provided for the already finished carrier part 12 with the handle parts 14, the free ends 18 of which can be introduced into the mold recesses 24 by means of the feed device 28.
  • the feed device 28 has a kind of supply roll 30, from which the stem part closure material can be unwound.
  • the strip material can perform the mold 22 and the complete adhesive product is at the end on a designated 34 transport roller for further transport wound.
  • the individual transport and management facilities were omitted; likewise, the heating and cooling devices for the manufacturing device are not shown.
  • the transport direction of the mold 22 and feed device 28 is represented by the arrow 36.
  • the mold recesses 24 are open to the outside, so freely accessible from there, wherein for filling the mold recesses 24 of the mold 22, a filling device 38 is used, which, without being specified, may be a conventional extruder application device; however, preferably represents a droplet applicator that does not completely fill the mold recesses 24 to the free edge with plastic material without the mold recesses 24 overflowing.
  • the filling device 38 may also be designed in the manner of a doctoring device for the plastic material, with excess plastic material being removable from the upper side of the strip by means of the so-called doctor blade device (not shown).
  • the curing device 40 may be a common heat source, but also a UV emitter and the like. If an acrylate material is used for the head parts 16, the curing device 40 is preferably a UV radiation source.
  • Adhesive closure parts produced by the method shown using the device described, are enlarged in the FIGS. 2 and 3 reproduced, wherein the head parts 16 as shown in the Fig. 2 are designed to be substantially flat towards their free end side, which allows them to form very narrow or thin-lipped with respect to their environmental edge; unlike the closure solution after the Fig. 3 in which the top side of the head part 16 shown is curved in a convex manner, so that this head part 16 ends towards the surrounding edge 42 with a thicker wall than the solution according to FIG Fig. 2 , Both solutions have in common that the head part 16 consists of an acrylate material, whereas the stem part preferably consists of a thermoplastic material, in particular of polyamide, polypropylene or polyethylene. Other material combinations are possible here.
  • the carrier part 12 itself can also consist of a multi-extrusion layer arrangement or have a film-like, elastically extensible character.
  • the said head parts 16 can form spherically shaped, outwardly smooth shell bodies seen from above; but here are also realizations in polygonal shape, especially in hexagonal shape possible. By using acrylate material for the head parts 16, these also form a kind of edge protection towards their environmental edge 42, which in turn benefits the longevity of the overall closure.

Landscapes

  • Slide Fasteners, Snap Fasteners, And Hook Fasteners (AREA)

Description

Die Erfindung betrifft ein Verfahren zum Herstellen eines Haftverschlussteils, bestehend aus mindestens einem Kunststoffmaterial, bei dem ein Trägerteil mit einer Vielzahl an vorstehenden Stielteilen mit einzelnen Kopfteilen derart verbunden wird, dass zumindest bei einem Teil der genannten Stielteile deren freie Enden in berührende oder eintauchende Anlage mit einer Anlageseite des jeweils zuordenbaren Kopfteils kommen, wobei beim Verbindungsvorgang von Stielteilen und zuordenbaren Kopfteilen diese noch zumindest im teilflüssigen oder teilplastifizierten Zustand vorliegen und die Kopfteile erst nach der Verbindung vollständig ausgehärtet werden. Die Erfindung betrifft des Weiteren eine Vorrichtung zum Herstellen eines Haftverschlussteils mit dem Verfahren.The invention relates to a method for producing an adhesive closure part, comprising at least one plastic material, in which a support member having a plurality of projecting handle parts with individual head parts is connected such that at least a part of said handle parts whose free ends in touching or immersing plant with an investment side of each assignable headboard come, which are still present at least in the partially liquid or partially plasticized state during the connection process of handle parts and assignable headboards and the headboards are fully cured after the connection. The invention further relates to a device for producing an adhesive closure part with the method.

Dahingehende Haftverschlussteile, die man auch den mechanischen Befestigungselementen zurechnet, bilden mit komplementär ausgebildeten Haftverschlussteilen einen immer wieder neu zu öffnenden und zu schließenden Verschluss aus, wobei Haken oder pilzkopfartige Verschlußteile mit schlingenartigen Verschlusselementen eines anderen Haftverschlussteils unter Bildung des Haftverschlusses zusammenwirken. Auch sind Lösungen bekannt, bei denen gleiche Haftverschlusselemente zweier verschiedener Haftverschlussteile miteinander zusammenwirken (hermaphroditischer Verschluss). Die US 2003/0126724 A1 offenbart ein Haftverschlussteil mit einem flächenartigen Trägerteil und einer Vielzahl von Stielteilen, welche als Vorsprünge auf dem Trägerteil angeordnet sind und jeweils aus einem weichen, elastisch-flexiblen Harzmaterial und einem harten, festen Harzmaterial zusammengesetzt sind. Hierbei können jeweils der Schaft des Stielteils aus dem harten Harz- bzw. Kunststoffmaterial und sein Oberteil aus dem weichen Harz- bzw. Kunststoffmaterial ausgebildet sein.Adjacent adhesive closure parts, which are also attributed to the mechanical fastening elements, form a closure which can be repeatedly opened and closed with complementary closure parts, wherein hooks or mushroom-like closure parts interact with loop-like closure elements of another adhesive closure part to form the adhesive closure. Solutions are also known in which the same adhesive closure elements of two different adhesive closure parts interact with one another (hermaphroditic closure). The US 2003/0126724 A1 discloses a fastener closure member having a sheet-like support member and a plurality of handle parts, which are arranged as projections on the support member and each composed of a soft, elastic-flexible resin material and a hard, solid resin material. Here, each of the shaft of the stem part of the hard resin or plastic material and its upper part may be formed from the soft resin or plastic material.

Ferner ist es durch die DE 699 22 264 T2 bekannt, ein bandartiges Trägerteil mit einer Vielzahl an vorstehenden Stielteilen einem Formgebungsspalt zwischen beheizbaren Formwalzen zuzuführen, in den über eine Extrudereinrichtung ein zusätzliches Formgebungsband aus Kunststoffmaterial zuführbar ist, das als eigentliches Formwerkzeug mit Formausnehmungen die warmen Stielenden der Stielteile zu Kopfteilen umformt, um dergestalt ein pilzkopfartiges Haftverschlussteil zu erhalten. Da die genannten Kopfteile bei der bekannten Lösung aus dem Kunststoffmaterial der Stielteile gebildet werden, fallen insoweit die Kopfteile wegen des geringen Materialeintrages in der zur Verhakung zur Verfügung stehenden freien und mithin überstehenden Kopffläche gering aus, was sich nachteilig auf die benötigten Haftkräfte auswirkt.Furthermore, it is through the DE 699 22 264 T2 known to supply a belt-like support member having a plurality of projecting stem parts of a forming gap between heatable forming rollers, in which an extruder over an additional shaping belt made of plastic material can be fed, which transforms the actual stem shape ends of the stem parts of the stem parts to head parts as the actual mold with Formausnehmt to a mushroom-like To obtain adhesive closure part. Since the head parts mentioned are formed in the known solution of the plastic material of the stem parts fall so far the head parts because of the low material input in the available for hooking free and thus protruding head surface of low, which adversely affects the required adhesive forces.

Demgegenüber schlägt die US 6 180 205 B1 ein Herstellverfahren vor unter Einsatz einer Formgebungswalze, bei der ein bandartiges Trägerteil mit einer Vielzahl an relativ groß dimensionierbaren Hakenverschlusselementen verbindbar ist. Hierzu weist die Formgebungswalze an ihrem Außenumfang hakenförmige Formausnehmungen auf, in die über eine erste Extrudereinrichtung Kunststoffmaterial formausfüllend hineingedrückt wird. Überschüssiges Kunststoffmaterial auf der Außenumfangsseite der Formgebungswalze wird mittels einer Schneidabtrageinrichtung, die man fachsprachlich als Doktor-Blade bezeichnet, abgetragen. Mittels einer in Herstellrichtung nachgeordneten zweiten Extrudereinrichtung wird dann das Trägerteilmaterial aufgebracht und mit den hakenförmigen Verschlussteilen während des Abkühlprozesses der Walze fest verbunden. Eine Abziehwalze entfernt dann das fertige Verschlussteil von der Formgebungseinrichtung. Aufgrund der Hakengeometrie kann es hierbei zu Schwierigkeiten während des Entformungsvorganges kommen und des Weiteren entsteht beim Herstellvorgang ein relativ hoher Anteil an Kunststoffabfall bedingt durch den Einsatz der genannten Doktor-Blade.In contrast, the US Pat. No. 6,180,205 B1 a manufacturing method using a forming roller, in which a band-like support member is connectable to a plurality of relatively large dimensionable hook closure elements. For this purpose, the shaping roller has hook-shaped form recesses on its outer circumference, in which plastic material is pressed in through a first extruder device in order to fill the mold. Excess plastic material on the outer peripheral side of the forming roll is removed by means of a Schneidabtrageinrichtung, which is referred to in technical language as a doctor blade. The carrier part material is then applied by means of a second extruder device arranged downstream in the direction of manufacture, and with the hook-shaped closure parts during the Cooling process of the roller firmly connected. A peel roller then removes the finished closure from the former. Due to the hook geometry, this can lead to difficulties during the demolding process and, furthermore, during the production process, a relatively high proportion of plastic waste arises due to the use of said doctor blade.

Durch die WO 2006/099000 A2 ist es weiter bekannt, eine bandartige Fördereinrichtung auf ihrer Obertrumseite mit Tröpfchen aus Kunststoffmaterial zu besprühen, wobei das Kunststoffmaterial sich aufgrund seiner Oberflächenspannung zu halbkugelförmigen Schalenkörpern formt, die dann an ihrer Wölbungsoberseite mit einem bandartigen Trägerteil unter Bildung des Haftverschlussteils fest verbunden werden. In Fortgestaltung dieser Lösung ist es auch möglich, in der Art von verdickten Stielteilen ein bandartiges Trägerteil zuzuführen, das auf seiner Oberseite bereits körnchenförmige Agglomerate als Stielteile trägt, auf die dann die halbschalenförmigen Kopfteile aufsetzbar sind. Das derart hergestellte Haftverschlussteil, das insbesondere als Verschluss für Baby- und Inkontinenzwindeln dienen soll, ist jedoch relativ steif ausgebildet und läßt insoweit noch Wünsche im Hinblick auf die Verschlusscharakteristik offen. Durch die US 2006/0220271 A1 ist eine vergleichbare Lösung bekannt, die jedoch zur Herstellung der halbschalenförmigen Verschlusselemente ein Formwerkzeug in Form einer Formwalze mit entsprechenden Formausnehmungen anstelle eines Bandes vorsieht. Ein Herstellen von Stielteilen zwischen Kopfteilen und Trägerteil erfolgt mit dieser bekannten Lösung insoweit nicht.By the WO 2006/099000 A2 It is also known to spray a ribbon-like conveyor on its upper strand side with droplets of plastic material, wherein the plastic material forms due to its surface tension to hemispherical shell bodies, which are then firmly connected at its top of curvature with a band-like support member to form the adhesive closure part. In further development of this solution, it is also possible to supply a band-like support member in the manner of thickened stem parts, which already carries on its upper side granular agglomerates as stem parts, on which then the half-shell-shaped head parts are placed. However, the adhesive closure part produced in this way, which is intended in particular to serve as a closure for baby and incontinence diapers, is relatively stiff and, to that extent, still leaves desires open with regard to the closure characteristic. By the US 2006/0220271 A1 a comparable solution is known, however, which provides for the production of the half-shell-shaped closure elements, a molding tool in the form of a molding roll with corresponding Formausnehmungen instead of a band. A manufacture of stem parts between the head parts and the carrier part does not take place with this known solution.

Durch das amerikanische Patent 5 785 784 ist ein Herstellverfahren bekannt zum Herstellen eines bandartigen Trägerteils, auf dem sich eine Vielzahl an vorstehenden Stielteilen befindet. In einem nachgeordneten Herstellschritt werden die freien Stielenden erwärmt, die sich dann aufgrund der Oberflächenspannung des Kunststoffmaterials zu einem insbesondere halbkugelförmigen Kopfteil verdicken. Sofern in Fortsetzung der bekannten Lösung die derart herstellbaren Kopfteile mittels eines sog. Kalanderwalzverfahrens nachverformt werden, entstehen insoweit zwar verbreiterte Kopfteilgeometrien; die im Hinblick auf den geringen Materialeintrag aber immer noch relativ klein dimensioniert sind und nur in Richtung der früheren Walzrichtung verbreitert sind.By the American patent 5,785,784 For example, a manufacturing method is known for producing a band-like carrier part on which a plurality of projecting handle parts is located. In a subsequent manufacturing step, the free ends of the stems are heated, which then become one in particular due to the surface tension of the plastic material thicken hemispherical headboard. If, in continuation of the known solution, the headers which can be produced in this way are subsequently deformed by means of a so-called calender rolling process, broadened headboard geometries are produced to that extent; but still relatively small in terms of the low material input and are only widened in the direction of the earlier rolling direction.

Ein Verfahren der eingangs genannten Art ist aus US 2004/0134045 A1 bekannt geworden. Bei dem bekannten Verfahren zur Herstellung eines Haftverschlussteils mit einer Vielzahl von einstückig mit einem Träger ausgebildeten Verhakungsmitteln in Form von endseitig Verhakungsköpfe aufweisenden Stielteilen werden die Verhakungsköpfe zumindest teilweise mit jeweils einem zusätzlichen Kopfteil aus einem Zusatzwerkstoff versehen. Dadurch, dass das jeweilige zusätzliche Kopfteil aus einer duroplastischen Formmasse als Zusatzwerkstoff gebildet wird, ist ein Haftverschlusssystem geschaffen, das zum einen hohen Temperaturen und mechanischen Beanspruchungen standhalten kann und zum anderen bei entsprechender Ausgestaltung zu besseren Haft- und Schälfestigkeitswerten führt.A method of the type mentioned is out US 2004/0134045 A1 known. In the known method for producing a Haftverschlussteils with a plurality of integrally formed with a carrier Verhakungsmitteln in the form of end interlocking heads having stem parts, the Verhakungsköpfe are at least partially provided with in each case an additional head part of a filler material. The fact that the respective additional head part is formed from a thermosetting molding material as a filler material, a Haftverschlusssystem is created, which can withstand high temperatures and mechanical stresses on the one hand and on the other with appropriate design leads to better adhesion and peel strength values.

Die in herkömmlicher Weise hergestellten Verhakungsmittel bestehen aus einzelnen Stielteilen, an deren freie Enden plattenartige Verhakungsköpfe vorhanden sind. Die die zusätzlichen Kopfteile bildenden Werkstoffe werden über eine Auftragswalze auf die Verhakungsköpfe aufgebracht. Der typischerweise eingesetzte Acrylatwerkstoff weist eine ähnliche Konsistenz und Viskosität wie Honig auf und bildet eine Art Auftragsbad zwischen der Auftragswalze und einer Gegenwalze aus und kann von dort sukzessive von der Auftragswalze an das Haftverschlussteil weitergegeben werden. Die Oberflächenspannung, des Acrylatmaterials ist derart gewählt, dass eine Art Tropfenbildung erreicht wird mit der Folge, dass die Kopfteile halbkugelförmige Kappen auf den Verhakungsköpfen ausbilden. Zum Aushärten des die zusätzlichen Kopfteile bildenden Zusatzwerkstoffes wird zweckmäßigerweise den Verhakungsköpfen Energie zugeführt, beispielsweise in Form von UV-Strahlung und/oder in Form von Wärme.The hooking means produced in a conventional manner consist of individual handle parts, at whose free ends plate-like interlocking heads are present. The materials forming the additional headers are applied to the hooking heads via an applicator roll. The typically used acrylate material has a similar consistency and viscosity as honey and forms a kind of application bath between the applicator roll and a counter-roller and can be passed from there successively from the applicator roll to the adhesive closure part. The surface tension of the acrylate material is selected to provide some form of drop formation with the result that the headers form hemispherical caps on the hooking heads. For curing of the additional head parts forming additional material is expediently Energy is supplied to the hooking heads, for example in the form of UV radiation and / or in the form of heat.

Ausgehend von diesem Stand der Technik stellt sich die Erfindung die Aufgabe, die bekannten Lösungen unter Beibehalten ihrer Vorteile weiter zu verbessern, insbesondere bei geringen Herstellkosten einen funktionssicheren Haftverschluss zu schaffen, der in weiten Bereichen von seinem Verschlussverhalten her einstellbar ist. Eine dahingehende Aufgabe löst ein Verfahren mit den Merkmalen des Patentanspruches 1 und eine Vorrichtung mit den Merkmalen des Anspruches 4.Based on this prior art, the invention has the object to further improve the known solutions while maintaining their advantages, especially at low production costs to provide a functionally reliable adhesive closure, which is adjustable in its wide behavior of its behavior. This object is achieved by a method having the features of patent claim 1 and a device having the features of claim 4.

Das erfindungsgemäße Verfahren dient dem Herstellen eines Haftverschlussteils, vorzugsweise bestehend aus mindestens einem Kunststoffmaterial, das dadurch charakterisiert ist, dass Kopfteilmaterial in einem Formwerkzeug mit einer Vielzahl von einzelnen, entsprechend der jeweiligen Kopfgeometrie ausgestalteten Formausnehmungen bereitgestellt wird, und dass die freien Enden der Stielteile bei Heranführung an oder bei Einführung in die Formausnehmungen die noch zumindest teilflüssigen bzw. teilplastifizierten Anlageseiten der Kopfteile berühren und/oder in das Kopfteilmaterial eintauchen.The method according to the invention serves to produce an adhesive closure part, preferably consisting of at least one plastic material, characterized in that head part material is provided in a molding tool having a multiplicity of individual mold recesses configured in accordance with the respective head geometry, and in that the free ends of the stem parts when approached on or at the time of introduction into the mold recesses touch the at least partially liquid or partially plasticized plant sides of the head parts and / or immerse in the head part material.

Durch das nachträgliche Aufsetzen von separat hergestellten Kopfteilen auf die freie Endseite der zuordenbaren Stielteile lassen sich in sehr weiten Bereichen verschiedene Materialkomponenten von Stielteilen mit Kopfteilen kombinieren und ebenso lassen sich verschiedene Geometrien für Kopfund/oder die Stielteile definieren. Aufgrund der Vielzahl an Kombinationsmöglichkeiten läßt sich somit bei dem derart hergestellten Haftverschlussteil eine Vielzahl von technischen Parametern einstellen. Das erfindungsgemäße Verfahren ist darüber hinaus funktionssicher in der Anwendung und kostengünstig realisierbar.By the subsequent placement of separately manufactured head parts on the free end side of the assignable handle parts can be combined in a wide range of different material components of handle parts with headboards and also different geometries for head and / or the handle parts can be defined. Due to the large number of possible combinations, a multiplicity of technical parameters can thus be set for the adhesive closure part produced in this way. The inventive method is also reliable in the application and cost feasible.

Als besonders wirtschaftlich zum Durchführen des Verfahrens hat sich dabei eine Vorrichtung erwiesen, bei der für die einzelnen Kopfteile ein Formwerkzeug vorhanden ist mit einer Vielzahl an Formausnehmungen, die der jeweiligen Kopfgeometrie entsprechen und mit einer Zuführeinrichtung für das bereits fertige Trägerteil mit den Stielteilen, deren freie Enden mittels der Zuführeinrichtung in die Formausnehmungen einführbar sind.As particularly economical to carry out the method, a device has been found in which for the individual head parts a mold is present with a variety of mold cavities corresponding to the respective head geometry and with a feeder for the already finished support member with the handle parts whose free Ends are inserted by means of the feed device in the mold recesses.

Ein besonders funktionsgerechtes und mechanisch robustes Haftverschlussteil ergibt sich dann, sofern Stiel- und Kopfteile aus voneinander verschiedenen Kunststoffmaterialien bestehen, insbesondere die Stielteile aus einem thermoplastischen Kunststoff gebildet sind und die Kopfteile aus Acrylatmaterial bestehen. Das relativ harte Acrylatmaterial für das jeweilige Kopfteil erlaubt eine widerstandsfähige Unterhakungsmöglichkeit für die Schlingen eines korrespondierenden Haftverschlussteils, so dass ein derart aufgebauter Haftverschluss sehr große Haft- und Schälfestigkeitswerte ermöglicht.A particularly functional and mechanically robust adhesive closure part results then, provided that stem and head parts consist of different plastic materials, in particular the stem parts are formed from a thermoplastic material and the head parts made of acrylate. The relatively hard acrylate material for the respective head part allows a robust Unterhakungsmöglichkeit for the loops of a corresponding adhesive closure part, so that an adhesive closure constructed in this way allows very high adhesion and peel strength values.

Weitere vorteilhafte Ausführungsformen der erfindungsgemäßen Lösung sind Gegenstand der sonstigen Unteransprüche.Further advantageous embodiments of the solution according to the invention are the subject of the other dependent claims.

Im Folgenden wird die erfindungsgemäße Lösung anhand eines Ausführungsbeispiels nach der Zeichnung näher erläutert. Dabei zeigen in prinzipieller und nicht maßstäblicher Darstellung die

Fig. 1
einen Teil der erfindungsgemäßen Herstellvorrichtung; und
Fig. 2 und 3
in Seitenansicht verschiedene Ausführungsformen des herstellbaren Haftverschlussteils.
In the following, the solution according to the invention is explained in more detail using an exemplary embodiment according to the drawing. This show in principle and not to scale representation of the
Fig. 1
a part of the manufacturing device according to the invention; and
FIGS. 2 and 3
in side view, various embodiments of the producible adhesive closure part.

Im Folgenden wird das erfindungsgemäße Verfahren anhand der Herstellvorrichtung nach der Fig. 1 näher erläutert. Das erfindungsgemäße Verfahren dient dem Herstellen eines als Ganzes mit 10 bezeichneten Haftverschlussteils, bei dem ein bandförmiges Trägerteil 12 mit einer Vielzahl an vorstehenden Stielteilen 14 mit einzelnen Kopfteilen 16 derart verbunden wird, dass zumindest bei einem Teil der genannten Stielteile 14 deren freie Enden 18 in berührende oder eintauchende Anlage mit einer Anlageseite 20 des jeweils zuordenbaren Kopfteils 16 kommen. Beim Einsatz des erfindungsgemäßen Verfahrens ist vorgesehen, dass beim eigentlichen Verbindungsvorgang von Stielteilen 14 mit den zuordenbaren Kopfteilen 16 diese noch zumindest in teilflüssigem oder teilplastifiziertem Zustand vorliegen und die Kopfteile 16 erst nach der Verbindung vollständig ausgehärtet werden. Die freien Enden 18 der Stielteile 14 berühren also die noch zumindest teilflüssigen Anlageseiten 20 der Kopfteile 16 oder tauchen gar bevorzugt in das Kopfteilmaterial hinein, um dergestalt die Verbindung dann im später ausgehärteten Zustand der Kopfteile 16 sicherstellen zu können.In the following, the inventive method is based on the manufacturing device according to the Fig. 1 explained in more detail. The inventive method is used to produce a designated as a whole with 10 adhesive closure part, in which a band-shaped support member 12 is connected to a plurality of projecting stem parts 14 with individual head parts 16 such that at least a portion of said stem parts 14 whose free ends 18 in touching or immersion plant come with a plant side 20 of each assignable head part 16. When using the method according to the invention it is provided that during the actual connection process of handle parts 14 with the assignable head parts 16, these are still present at least in partially liquid or teilplastifiziertem state and the head parts 16 are completely cured after the connection. The free ends 18 of the handle parts 14 thus touch the still at least partially liquid Anlageseiten 20 of the head parts 16 or even dive preferably in the headboard material in order to ensure the compound in the later cured state of the head parts 16 can.

Für die Formgebung der einzelnen Kopfteile 16 ist ein als Ganzes mit 22 bezeichnetes Formwerkzeug vorgesehen mit einer Vielzahl an einzelnen Formausnehmungen 24, die von ihrer Ausgestaltung her der jeweiligen Kopfgeometrie entsprechen. Die Formausnehmungen 24 sind Bestandteil eines in der Art eines Transportbandes umlaufenden Formgebungsbandes 26, wobei die Formausnehmungen 24 des Obertrums mit Kunststoffmaterial befüllt werden und das Untertrum im wesentlichen die leeren Formausnehmungen 24 führt. Die Formausnehmungen 24 sind wiederum in Querund Längsrichtung des Formgebungsbandes 24 - in regel-oder unregelmäßiger Verteilung - mehrfach vorhanden.For the shaping of the individual head parts 16, a mold designated as a whole with 22 is provided with a plurality of individual mold recesses 24, which correspond in terms of their design to the respective head geometry. The mold recesses 24 are part of a circulating in the manner of a conveyor belt forming belt 26, wherein the mold recesses 24 of the upper run are filled with plastic material and the lower run substantially the empty mold recesses 24 leads. The mold recesses 24 are in turn in the transverse and longitudinal direction of the forming belt 24 - in regular or irregular distribution - multiple available.

Ferner ist eine als Ganzes mit 28 bezeichnete Zuführeinrichtung vorgesehen für das bereits fertige Trägerteil 12 mit den Stielteilen 14, deren freie Enden 18 mittels der Zuführeinrichtung 28 in die Formausnehmungen 24 einführbar sind. Hierfür weist die Zuführeinrichtung 28 eine Art Vorratsrolle 30 auf, von der das Stielteil-Verschlussmaterial abwickelbar ist. Über entsprechende Umlenkrollen 32 läßt sich das Bandmaterial dem Formwerkzeug 22 zuführen und das komplette Haftverschlussprodukt ist am Ende auf eine mit 34 bezeichnete Transportrolle zum Weitertransport aufwickelbar. Der einfacheren Darstellung wegen wurde auf die einzelnen Transport- und Führungseinrichtungen verzichtet; ebenso sind die Heiz- und Kühleinrichtungen für die Herstellvorrichtung nicht aufgezeigt. Die Transportrichtung von Formwerkzeug 22 und Zuführeinrichtung 28 ist jedoch mit dem Pfeil 36 wiedergegeben.Furthermore, a feed device designated as a whole by 28 is provided for the already finished carrier part 12 with the handle parts 14, the free ends 18 of which can be introduced into the mold recesses 24 by means of the feed device 28. For this purpose, the feed device 28 has a kind of supply roll 30, from which the stem part closure material can be unwound. About appropriate Pulleys 32, the strip material can perform the mold 22 and the complete adhesive product is at the end on a designated 34 transport roller for further transport wound. For the sake of simplicity, the individual transport and management facilities were omitted; likewise, the heating and cooling devices for the manufacturing device are not shown. However, the transport direction of the mold 22 and feed device 28 is represented by the arrow 36.

Wie die Darstellung nach der Fig. 1 weiter zeigt, sind die Formausnehmungen 24 nach außen hin offen, also von dort aus frei zugänglich, wobei zum Befüllen der Formausnehmungen 24 des Formwerkzeuges 22 eine Fülleinrichtung 38 dient, die, ohne näher spezifiziert zu werden, eine übliche Extruderauftrageinrichtung sein kann; bevorzugt jedoch eine Tröpfchenauftragvorrichtung darstellt, die die Formausnehmungen 24 nicht ganz bis zum freien Rand mit Kunststoffmaterial befüllt, ohne dass die Formausnehmungen 24 überlaufen. Die Fülleinrichtung 38 kann jedoch auch in der Art einer Aufrakelvorrichtung für das Kunststoffmaterial ausgebildet sein, wobei überschüssiges Kunststoffmaterial von der Bandoberseite mittels der sog. Doktor-Blade-Einrichtung (nicht dargestellt) entfernbar ist.As the presentation after the Fig. 1 Further, the mold recesses 24 are open to the outside, so freely accessible from there, wherein for filling the mold recesses 24 of the mold 22, a filling device 38 is used, which, without being specified, may be a conventional extruder application device; however, preferably represents a droplet applicator that does not completely fill the mold recesses 24 to the free edge with plastic material without the mold recesses 24 overflowing. However, the filling device 38 may also be designed in the manner of a doctoring device for the plastic material, with excess plastic material being removable from the upper side of the strip by means of the so-called doctor blade device (not shown).

Zum Herstellen der festen Verbindung zwischen den Stielteilen 14 und den Kopfteilen 16 dient wiederum eine nicht näher spezifizierte Aushärteinrichtung 40, die vorzugsweise am Ende des Verbindungsvorganges angeordnet ist, und zwar kurz vor der Stelle, bevor in Richtung des Pfeiles 36 gesehen, das fertige Haftverschlussprodukt aus dem Formwerkzeug 22 entfernt in Richtung der Transportrolle 34 abtransportiert wird. In Abhängigkeit des jeweils eingesetzten Kunststoffmaterials kann die Aushärteinrichtung 40 eine übliche Wärmequelle sein, aber auch ein UV-Strahler und dergleichen mehr. Sofern für die Kopfteile 16 ein Acrylatwerkstoff eingesetzt ist, ist die Aushärteinrichtung 40 bevorzugt eine UV-Strahlungsquelle.To produce the firm connection between the handle parts 14 and the head parts 16 again serves a unspecified curing device 40, which is preferably arranged at the end of the connection process, and shortly before the point, as seen in the direction of arrow 36, the finished adhesive product the mold 22 away in the direction of the transport roller 34 is removed. Depending on the plastic material used in each case, the curing device 40 may be a common heat source, but also a UV emitter and the like. If an acrylate material is used for the head parts 16, the curing device 40 is preferably a UV radiation source.

Haftverschlussteile, hergestellt nach dem aufgezeigten Verfahren unter Einsatz der beschriebenen Vorrichtung, sind vergrößert in den Fig. 2 und 3 wiedergegeben, wobei die Kopfteile 16 gemäß der Darstellung nach der Fig. 2 zu ihrer freien Endseite hin im wesentlichen eben ausgebildet sind, was es erlaubt, diese betreffend ihren Umgebungsrand sehr schmal- oder dünnlippig auszubilden; im Gegensatz zu der Verschlusslösung nach der Fig. 3, bei der die Oberseite des gezeigten Kopfteils 16 konvex gekrümmt ist, so dass dieses Kopfteil 16 zum Umfassungsrand 42 hin dickwandiger ausläuft als die vorstehend beschriebene Lösung nach der Fig. 2. Beiden Lösungen ist gemein, dass der Kopfteil 16 aus einem Acrylatwerkstoff besteht, wohingegen das Stielteil bevorzugt aus einem thermoplastischen Kunststoffwerkstoff besteht, insbesondere aus Polyamid, Polypropylen oder Polyethylen. Andere Werkstoffkombinationen sind hier möglich.Adhesive closure parts, produced by the method shown using the device described, are enlarged in the FIGS. 2 and 3 reproduced, wherein the head parts 16 as shown in the Fig. 2 are designed to be substantially flat towards their free end side, which allows them to form very narrow or thin-lipped with respect to their environmental edge; unlike the closure solution after the Fig. 3 in which the top side of the head part 16 shown is curved in a convex manner, so that this head part 16 ends towards the surrounding edge 42 with a thicker wall than the solution according to FIG Fig. 2 , Both solutions have in common that the head part 16 consists of an acrylate material, whereas the stem part preferably consists of a thermoplastic material, in particular of polyamide, polypropylene or polyethylene. Other material combinations are possible here.

Es ist für einen Durchschnittsfachmann auf dem Gebiet der Verschlusstechnologie überraschend, dass er hier für Pilzkopfverschlusssysteme beliebige Kopfteile 16 mit beliebigem Stielteilmaterial 14 verbinden kann, um so in einem weiten Anwendungsbereich funktionale Haftverschlüsse anbieten zu können. Wie insbesondere die Fig. 2 zeigt, brauchen auch nicht alle Stielteile 14 mit einem Kopfteil 16 versehen zu sein und in besonderen Anwendungsfällen wäre es auch möglich, zwei und mehr Stielteile 14 mit nur einem Kopfteil 16 endseitig zu versehen (nicht dargestellt). Des Weiteren wäre es möglich, in Abhängigkeit der Ausbildung der Formausnehmungen 24 Verschlusssysteme zu schaffen, die beispielsweise die Kopfgeometrien der Verschlusselemente von Fig. 2 und Fig. 3 nach vorgebbaren Mustern miteinander kombinieren. Im Übrigen hat es sich gezeigt, dass sich mit dem erfindungsgemäßen Verfahren sehr glatte und harte Kopfteile 16 erhalten lassen, was den Verschluss als Ganzes schont und zu sehr langlebigen Haftverschlussteilsystemen führt.It is surprising to a person of ordinary skill in the field of closure technology that, for mushroom top closure systems, he can connect any desired head parts 16 to any stem part material 14 in order to be able to offer functional adhesive closures in a wide range of applications. How the particular Fig. 2 shows, not all stem parts 14 need to be provided with a head part 16 and in special cases it would also be possible to provide two and more stem parts 14 with only one head part 16 end (not shown). Furthermore, it would be possible, depending on the design of the mold recesses 24, to provide closure systems which, for example, control the head geometries of the closure elements of Fig. 2 and Fig. 3 combine according to specifiable patterns. Incidentally, it has been shown that very smooth and hard head parts 16 can be obtained with the method according to the invention, which protects the closure as a whole and leads to very long-lasting adhesive closure subsystems.

In Abhängigkeit der Tiefe der zum Einsatz gebrachten Formausnehmungen 24 des Formwerkzeuges 22 lassen sich gegebenenfalls auch unterschiedlich hohe Längen für die Stielteile 14 realisieren, so dass dann die Kopfteile 16 in unterschiedlichen Niveauhöhen bezogen auf das bandartige Trägerteil 12 enden. Das Trägerteil 12 selbst kann auch aus einer Mehrextrusionslagenanordnung bestehen oder folienartigen, elastisch dehnbaren Charakter haben. Die genannten Kopfteile 16 können von oben her gesehen sphärische, nach außen hin glatte Schalenkörper ausbilden; es sind hier aber auch Realisierungen in Mehreckform, insbesondere in Sechseckform möglich. Durch Einsatz von Acrylatmaterial für die Kopfteile 16 bilden diese auch zu ihrem Umgebungsrand 42 hin eine Art Kantenschutz aus, was wiederum der Langlebigkeit des Gesamtverschlusses zugute kommt.Depending on the depth of the used mold recesses 24 of the molding tool 22 can also be realized if necessary, different lengths for the stem parts 14, so that then the head parts 16 in different heights in relation to the ribbon-like support member 12 ends. The carrier part 12 itself can also consist of a multi-extrusion layer arrangement or have a film-like, elastically extensible character. The said head parts 16 can form spherically shaped, outwardly smooth shell bodies seen from above; but here are also realizations in polygonal shape, especially in hexagonal shape possible. By using acrylate material for the head parts 16, these also form a kind of edge protection towards their environmental edge 42, which in turn benefits the longevity of the overall closure.

Claims (5)

  1. A method for producing an adhesive fastener part (10) made of at least one plastic material,
    - wherein a backing part (12) with a plurality of projecting stem parts (14) is connected to individual head parts (16) such that in at least some of said stem parts (14) the free ends (18) of the latter are in contiguous or embedded contact with a contact side (20) of the respectively assignable head part (16),
    - during the process of connecting the stem parts (14) and the assignable head parts (16) the latter still being at least in the partially liquid or partially plasticised state and the head parts (16) only being completely cured after connection,
    - characterised in that the head part material is prepared in a moulding tool (22) that has a plurality of individual mould recesses (24) configured according to the respective head geometry, and
    - that the free ends (18) of the stem parts (14) come into contact with the still at least partially liquid or partially plasticised contact sides (20) of the head parts (16) and/or are embedded in the head part material when moved towards or introduced into the mould recesses (24).
  2. The method according to Claim 1, characterised in that stem parts (14) and head parts (16) are made of plastic materials that are different from one another.
  3. The method according to Claim 2, characterised in that the stem parts (14) are formed from a thermoplastic and the head parts (16) are made of acrylate material.
  4. An apparatus for producing an adhesive fastener part by means of a method according to any of Claims 1 to 3, a backing part (12) with a plurality of projecting stem parts (14) being able to be connected to individual head parts (16) such that in at least some of said stem parts (14) the free ends (18) of the latter are in contiguous or embedded contact with a contact side (20) of the respectively assignable head part (16), and during the process of connecting the stem parts (14) and the assignable head parts (16) the latter still being at least in the partially liquid or partially plasticised state and the head parts (16) only being able to be completely cured after connection to a curing device (40), characterised in that the head part material can be provided by a filling device (38) in a moulding tool (22) that has a plurality of individual mould recesses (24) configured according to the respective head geometry, that the free ends (18) of the stem parts (14) can come into contact with the still at least partially liquid or partially plasticised contact sides (20) of the head parts (16) and/or the free ends (18) of the stem parts (14) can be embedded in the head part material when moved towards or introduced into the mould recesses (24), and that for the individual head parts (16) the moulding tool (22) is provided with the plurality of mould recesses (24) which correspond to the respective head geometry, and with a supply device (28) for the already finished backing part (12) with the stem parts (14) the free ends (18) of which can be introduced into the mould recesses (24) by means of the supply device (28).
  5. The apparatus according to Claim 4, characterised in that the moulding tool (22) is formed by a revolving moulding belt (26) which includes the mould recesses (24) which are freely accessible from the outside.
EP08707350.8A 2007-03-30 2008-01-29 Method for the production of a part of a hook and loop fastener together with a corresponding apparatus Active EP2129254B1 (en)

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DE102007015441A DE102007015441A1 (en) 2007-03-30 2007-03-30 Method for producing an adhesive closure part together with the device and subsequently produced adhesive closure part
PCT/EP2008/000646 WO2008119407A1 (en) 2007-03-30 2008-01-29 Method for the production of an adhesive closure device together with apparatus and adhesive closure device produced accordingly

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DE102007015441A1 (en) 2008-10-02
PT2129254E (en) 2014-10-20
JP2010522588A (en) 2010-07-08
ES2520043T3 (en) 2014-11-11
US20100095489A1 (en) 2010-04-22
PL2129254T3 (en) 2015-03-31
EP2129254A1 (en) 2009-12-09
DK2129254T3 (en) 2014-12-08
JP5205445B2 (en) 2013-06-05
US8388880B2 (en) 2013-03-05
WO2008119407A1 (en) 2008-10-09

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