EP2105128A2 - Styling formulations for creating a flexible hold through the use of particular waxes - Google Patents

Styling formulations for creating a flexible hold through the use of particular waxes Download PDF

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Publication number
EP2105128A2
EP2105128A2 EP09151912A EP09151912A EP2105128A2 EP 2105128 A2 EP2105128 A2 EP 2105128A2 EP 09151912 A EP09151912 A EP 09151912A EP 09151912 A EP09151912 A EP 09151912A EP 2105128 A2 EP2105128 A2 EP 2105128A2
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Prior art keywords
phase transition
wax
waxes
product according
oil
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EP09151912A
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German (de)
French (fr)
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EP2105128A3 (en
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Wiebke Grundt
Frank Hetzel
Christian Dingler
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Beiersdorf AG
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Beiersdorf AG
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • Hairdressing agents are means of temporary deformation and stabilization of the hairstyle. They are also referred to as a styling agent. This product group includes hair sprays, mousses, hair lacquers, hair gels and hair waxes.
  • Gels usually consist of a thickened aqueous or aqueous-alcoholic solution of film-forming natural or synthetic polymers. These polymers can be selected from the group of nonionic, cationic, amphoteric or anionic polymers.
  • the polymer film of gels usually hardens completely, which is why a very strong consolidation can be achieved. However, these films are very brittle and can easily be destroyed.
  • waxes achieve a flexible and not brittle, but not strong consolidation. They consist of a mixture of waxes, oils, fats and emulsifiers.
  • the polymers usually used in gels, as described above, can only form low-setting films in hair waxes, since the solidification of fats, oils and waxes is adversely affected.
  • waxes with certain physical properties have a high melting point, which results in a high firmness in the hair.
  • Such waxes are partially crystalline. The glass transition temperature of the amorphous portion is well below room temperature.
  • a product for temporary shaping and stabilization of the hairstyle in the form of a wax or a wax emulsion containing waxes, oils, fats and optionally emulsifiers characterized in that at least one wax W * the Waxes have a first order phase transition and a further phase transition at a lower temperature than the temperature of the first order phase transition and the phase transition temperature of the further phase transition is below 20 ° C, remedying the disadvantages of the prior art.
  • Such a product is suitable as a styling paste. This has a fixing, but gives no brittle stop. As a result, the hairstyle is still malleable even after fixation, so in the fixed state.
  • the Paracera MWN (INCl: Cera Microcristallina) by Paramelt has proven to be particularly suitable. This insert leads to a strong and flexible hold.
  • the further phase transition is preferably a second order phase transition. This achieves a better long-term preservation. It is further preferred if the further phase transition is a first-order phase transition.
  • the product contains 0.5 to 15% by weight of W * wax.
  • the product is emulsion-shaped and contains at least 2% by weight of an emulsifier. As a result, a better washability of the product is achieved. Furthermore, it is preferred if, in the case of an emulsion-shaped product, the aqueous phase contains alcohol. Such a formula is cheaper to manufacture.
  • the invention also includes the use of a product as described above for styling the hairstyle.
  • Ethers for example, ethoxylated / propoxylated alcohols, ethoxylated / propoxylated esters, ethoxylated / propoxylated glycerol esters, ethoxylated / propoxylated triglyceride esters, ethoxylated propoxylated lanolin, propoxylated POE ethers, and alkylpolyglycosides are useful in achieving good washability results.
  • Particularly suitable in this case are ethoxylated alcohols having 15-30 units of ethoxylation units, e.g. Eumulgin B types from Cognis.
  • the oil components can be selected from the group of esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids having a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols having a chain length of 3 to 30 carbon atoms, from the group of esters of aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols having a chain length of 3 to 30 carbon atoms.
  • ester oils can then be advantageously selected from the group isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2 Octyldodecyl palmitate, oleyl oleate.
  • the oil component can advantageously be selected from the group of branched and unbranched hydrocarbons and waxes, silicone oils, dialkyl ethers, the group of saturated or unsaturated, branched or unbranched alcohols, and fatty acid triglycerides, in particular the triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids of a chain length of 8 to 24, in particular 12 to 18 carbon atoms.
  • the fatty acid triglycerides can be selected, for example, advantageously from the group of synthetic, semi-synthetic and natural oils, for. For example, olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, palm kernel oil and the like.
  • acrylate copolymers and / or acrylate-alkyl acrylate copolymers which are sold under the trade names Carbopol 1382, Carbopol 980 and Carbopol 5984, Aqua SF-1 from NOVEON Inc. or Aculyn 33 from International Specialty Products Corp. are available.
  • copolymers of C10-30-alkyl acrylates and one or more monomers of acrylic acid, methacrylic acid or their esters, which are cross-linked with an allyl ether of sucrose or an allyl ether of pentaerythritol are advantageous.
  • compounds which carry the INCI name "Acrylates / C 10-30 Alkyl Acrylate Crosspolymer” are advantageous.
  • Particularly advantageous are those available under the trade names Pemulen TR1 and Pemulen TR2 from NOVEON Inc.
  • Suitable nonionic polymers are e.g. Homopolymers of vinylpyrrolidone, e.g. Luviskol K from BASF or homopolymers of N-vinylformamide e.g. PVF from National Starch. Further suitable polymers are copolymers of vinylpyrrolidone and vinyl acetate, e.g. Luviskol VA types from BASF, terpolymers from vinylpyrrolidone, vinyl acetate and propionate such as e.g.
  • Luviskol VAP from BASF, polyvinylcaprolactam, polyvinylamides and their salts, as well as copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate, terpolymers of vinylcaprolactam, vinylpyrrolidone and dimethylaminomethacrylate; Polysiloxanes and the like.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Cosmetics (AREA)

Abstract

Product (I) in the form of a wax or a wax emulsion comprises a wax, an oil, a fat and optionally an emulsifier, where: at least one of waxes has a wax phase transition of first order and a further phase transition at a lower temperature than the temperature of the phase transition of first order; and the phase transition temperature of the further phase transition is less than 20[deg] C.

Description

Frisiermittel sind Mittel zur temporären Verformung und Stabilisierung der Frisur. Sie werden auch als Stylingmittel bezeichnet. Zu dieser Produktgruppe zählen Haarsprays, Schaumfestiger, Haarlacke, Haargele und auch Haarwachse.Hairdressing agents are means of temporary deformation and stabilization of the hairstyle. They are also referred to as a styling agent. This product group includes hair sprays, mousses, hair lacquers, hair gels and hair waxes.

Gele bestehen üblicherweise aus einem verdicktem wässrigen bzw. wässrig-alkoholischen Lösung von filmbildenden natürlichen oder synthetischen Polymeren. Diese Polymere können aus der Gruppe der nichtionischen, kationischen, amphoteren oder anionischen Polymeren ausgewählt werden. Der Polymerfilm von Gelen härtet meist vollständig aus, weshalb eine sehr starke Festigung erzielt werden kann. Diese Filme sind jedoch sehr spröde und lassen sich leicht zerstören.Gels usually consist of a thickened aqueous or aqueous-alcoholic solution of film-forming natural or synthetic polymers. These polymers can be selected from the group of nonionic, cationic, amphoteric or anionic polymers. The polymer film of gels usually hardens completely, which is why a very strong consolidation can be achieved. However, these films are very brittle and can easily be destroyed.

Handelsübliche Wachse erzielen eine flexible und nicht spröde, aber nicht starke Festigung. Sie bestehen aus einer Mischung von Wachsen, Ölen, Fetten und Emulgatoren.Commercial waxes achieve a flexible and not brittle, but not strong consolidation. They consist of a mixture of waxes, oils, fats and emulsifiers.

Die üblicherweise in Gelen eingesetzten Polymere, wie oben beschrieben, können in Haar-Wachsen nur gering festigende Filme ausbilden, da die Festigung von Fetten, Ölen und Wachsen negativ beeinflusst wird.The polymers usually used in gels, as described above, can only form low-setting films in hair waxes, since the solidification of fats, oils and waxes is adversely affected.

Es wurde nun überraschenderweise festgestellt, dass durch die Auswahl von Wachsen mit bestimmten physikalischen Eigenschaften eine starke und gleichzeitig flexible Festigung erzielt werden kann. Diese Wachse besitzen einen hohen Schmelzpunkt, wodurch eine hohe Festigung im Haar erzielt wird. Gleichzeitig müssen sie einen amorphen Anteil besitzen, wodurch sie bei Raumtemperatur flexibel sind. Solche Wachse sind teilkristallin. Dabei liegt die Glasübergangstemperatur des amorphen Anteils deutlich unter Raumtemperatur.It has now surprisingly been found that by selecting waxes with certain physical properties a strong and at the same time flexible strengthening can be achieved. These waxes have a high melting point, which results in a high firmness in the hair. At the same time, they must have an amorphous content, making them flexible at room temperature. Such waxes are partially crystalline. The glass transition temperature of the amorphous portion is well below room temperature.

Klassische Wachse, die überwiegend eine rein kristalline Struktur besitzen haben sich als ungeeignet herausgestellt. Ein Beispiel für solche ungeeigneten Wachse ist Micro Care 114 von Paramelt (Cera Microcristallina) (Sorge ist der BDF-Name). Als geeignet haben sich Kesterwachs K80 P von Koster Keunen (C18-38 Alkyl Hydroxystearoyl Stearate), Micro-La 9743 von Paramelt, Ceresine Isco Care 126 von Paramelt und Paracera MWN von Paramelt (Cera Microcristallina) herausgestellt. Dies sind teilkristalline Wachse.Classic waxes, which predominantly possess a purely crystalline structure, have proven to be unsuitable. An example of such unsuitable waxes is Micro Care 114 from Paramelt (Cera Microcristallina) (concern is the BDF name). Suitable Kester wax K80 P from Koster Keunen (C18-38 alkyl hydroxystearoyl stearates), Micro-La 9743 of Paramelt, Ceresine Isco Care 126 by Paramelt and Paracera MWN by Paramelt (Cera Microcristallina). These are semi-crystalline waxes.

Es hat sich für den Fachmann überraschend und nicht vorhersehbar herausgestellt, dass ein Produkt zur temporären Verformung und Stabilisierung der Frisur in Form eines Wachses oder einer Wachsemulsion enthaltend Wachse, Öle, Fette und ggf. Emulgatoren, dadurch gekennzeichnet, dass mindestens ein Wachs W* der Wachse einen Phasenübergang erster Ordnung und einen weiteren Phasenübergang bei geringerer Temperatur als der Temperatur des Phasenübergangs erster Ordnung aufweist und die Phasenübergangstemperatur des weiteren Phasenübergangs unterhalb von 20°C liegt, den Nachteilen des Standes der Technik abhilft. Ein solches Produkt eignet sich als Stylingpaste. Diese wirkt fixierend, gibt aber keinen spröden Halt. Dadurch ist die Frisur auch nach der Fixierung, also im fixierten Zustand noch formbar. Es können zusätzlich klassische fixierende Polymere enthalten sein. Diese bilden normalerweise allein eingesetzt einen spröden Film aus. Da diese aber in Kombination mit Fetten und Ölen nicht ihren typischen Polymerfilm ausbilden können, dienen sie nur zur Unterstützung der Fixierwirkung des eingesetzten Wachses. Es kann aber auch auf klassische fixierende Polys verzichtet werden. Als besonders geeignet hat sich das Paracera MWN (INCl: Cera Microcristallina) von der Firma Paramelt herausgestellt. Dieser Einsatz führt zu einem starken und gleichzeitig flexiblen Halt. Bevorzugt ist der weitere Phasenübergang ein Phasenübergang zweiter Ordnung. Dadurch wird ein besserer Langzeithalt erreicht. Weiter bevorzugt ist es wenn der weitere Phasenübergang ein Phasenübergang erster Ordnung ist.It has turned out, surprisingly and unpredictably to a person skilled in the art, that a product for temporary shaping and stabilization of the hairstyle in the form of a wax or a wax emulsion containing waxes, oils, fats and optionally emulsifiers, characterized in that at least one wax W * the Waxes have a first order phase transition and a further phase transition at a lower temperature than the temperature of the first order phase transition and the phase transition temperature of the further phase transition is below 20 ° C, remedying the disadvantages of the prior art. Such a product is suitable as a styling paste. This has a fixing, but gives no brittle stop. As a result, the hairstyle is still malleable even after fixation, so in the fixed state. It may additionally contain classical fixing polymers. These usually form a brittle film when used alone. Since these can not form their typical polymer film in combination with fats and oils, they only serve to support the fixing effect of the wax used. But it can also be dispensed with classical fixing polys. The Paracera MWN (INCl: Cera Microcristallina) by Paramelt has proven to be particularly suitable. This insert leads to a strong and flexible hold. The further phase transition is preferably a second order phase transition. This achieves a better long-term preservation. It is further preferred if the further phase transition is a first-order phase transition.

In diesem Fall fixiert das Produkt besser, klebt aber auch stärker.In this case, the product fixes better, but also sticks stronger.

Bei allem ist es bevorzugt, wenn das Produkt 0,5 bis 15 Gew.-% des Wachses W* enthält.In all, it is preferable that the product contains 0.5 to 15% by weight of W * wax.

Dadurch wird ein besserer flexiblerer Halt erreicht. Besonders bevorzugt ist es, wenn das Produkt emulsionsförmig ist und wenigstens 2 Gew.% eines Emulgators enthält. Dadurch wird eine bessere Auswaschbarkeit des Produktes erreicht. Weiterhin ist es bevorzugt, wenn im Falle eines emulsionsförmigen Produktes die Wasserphase Alkohol enthält. Eine solche Formel ist preisgünstiger herzustellen. Die Erfindung umfasst auch die Verwendung eines Produktes wie oben beschrieben zur Gestaltung der Frisur.This achieves a better, more flexible hold. It is particularly preferred if the product is emulsion-shaped and contains at least 2% by weight of an emulsifier. As a result, a better washability of the product is achieved. Furthermore, it is preferred if, in the case of an emulsion-shaped product, the aqueous phase contains alcohol. Such a formula is cheaper to manufacture. The invention also includes the use of a product as described above for styling the hairstyle.

Emulgatorenemulsifiers

Besonders ist auf die Auswahl der Emulgatoren zu achten, da diese zum einen die Auswaschbarkeit des Wachses W* positiv beeinflussen sollten und andererseits die Formulierung stabilisieren müssen. Ether, beispielsweise ethoxylierte/propoxylierte Alkohole, ethoxylierte/ propoxylierte Ester, ethoxylierte/ propoxylierte Glycerinester, ethoxylierte/ propoxylierte Triglyceridester, ethoxyliertes propoxyliertes Lanolin, propoxylierte POE-Ether und Alkylpolyglycoside eignen sich um gute Auswaschbarkeitsergebnisse zu erzielen. Besonders geeignet sind in diesem Fall ethoxylierte Alkohole mit 15-30 Einheiten Ethoxylierungseinheiten z.B. Eumulgin B-Typen von Cognis.Particular attention should be paid to the choice of emulsifiers, since these should on the one hand positively influence the washability of the wax W * and on the other hand stabilize the formulation. Ethers, for example, ethoxylated / propoxylated alcohols, ethoxylated / propoxylated esters, ethoxylated / propoxylated glycerol esters, ethoxylated / propoxylated triglyceride esters, ethoxylated propoxylated lanolin, propoxylated POE ethers, and alkylpolyglycosides are useful in achieving good washability results. Particularly suitable in this case are ethoxylated alcohols having 15-30 units of ethoxylation units, e.g. Eumulgin B types from Cognis.

Öleoils

Vorteilhaft kann die Ölkomponenten gewählt werden aus der Gruppe der Ester aus gesättigten und/oder ungesättigten, verzweigten und/oder unverzweigten Alkancarbonsäuren einer Kettenlänge von 3 bis 30 C-Atomen und gesättigten und/oder ungesättigten, verzweigten und/oder unverzweigten Alkoholen einer Kettenlänge von 3 bis 30 C-Atomen, aus der Gruppe der Ester aus aromatischen Carbonsäuren und gesättigten und/oder ungesättigten, verzweigten und/oder unverzweigten Alkoholen einer Kettenlänge von 3 bis 30 C-Atomen. Solche Esteröle können dann vorteilhaft gewählt werden aus der Gruppe Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropyloleat, n-Butylstearat, n-Hexyllaurat, n-Decyloleat, Isooctylstearat, Isononylstearat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexyllaurat, 2-Hexyldecylstearat, 2-Octyldodecylpalmitat, Oleyloleat.Advantageously, the oil components can be selected from the group of esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids having a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols having a chain length of 3 to 30 carbon atoms, from the group of esters of aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols having a chain length of 3 to 30 carbon atoms. Such ester oils can then be advantageously selected from the group isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2 Octyldodecyl palmitate, oleyl oleate.

Ferner kann die Ölkomponente vorteilhaft gewählt werden aus der Gruppe der verzweigten und unverzweigten Kohlenwasserstoffe und -wachse, der Silkonöle, der Dialkylether, der Gruppe der gesättigten oder ungesättigten, verzweigten oder unverzweigten Alkohole, sowie der Fettsäuretriglyceride, namentlich der Triglycerinester gesättigter und/oder ungesättigter, verzweigter und/oder unverzweigter Alkancarbonsäuren einer Kettenlänge von 8 bis 24, insbesondere 12 bis 18 C-Atomen. Die Fettsäuretriglyceride können beispielsweise vorteilhaft gewählt werden aus der Gruppe der synthetischen, halbsynthetischen und natürlichen Öle, z. B. Olivenöl, Sonnenblumenöl, Sojaöl, Erdnußöl, Rapsöl, Mandelöl, Palmöl, Kokosöl, Palmkernöl und dergleichen mehr.Furthermore, the oil component can advantageously be selected from the group of branched and unbranched hydrocarbons and waxes, silicone oils, dialkyl ethers, the group of saturated or unsaturated, branched or unbranched alcohols, and fatty acid triglycerides, in particular the triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids of a chain length of 8 to 24, in particular 12 to 18 carbon atoms. The fatty acid triglycerides can be selected, for example, advantageously from the group of synthetic, semi-synthetic and natural oils, for. For example, olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, palm kernel oil and the like.

Verdickerthickener

Erfindungsgemäß besonders bevorzugt sind Acrylat-Copolymere und/oder Acrylat-Alkylacrylat-Copolymere, welche unter den Handelbezeichnungen Carbopol 1382, Carbopol 980 und Carbopol 5984, Aqua SF-1 von der NOVEON Inc. bzw. als Aculyn 33 von International Specialty Products Corp. erhältlich sind.Particularly preferred according to the invention are acrylate copolymers and / or acrylate-alkyl acrylate copolymers which are sold under the trade names Carbopol 1382, Carbopol 980 and Carbopol 5984, Aqua SF-1 from NOVEON Inc. or Aculyn 33 from International Specialty Products Corp. are available.

Ferner vorteilhaft sind Copolymere aus C10-30-Alkylacrylaten und einem oder mehreren Monomeren der Acrylsäure, der Methacrylsäure oder deren Ester, die kreuzvernetzt sind mit einem Allylether der Saccharose oder einem Allylether des Pentaerythrit.
Vorteilhaft sind hier Verbindungen, die die INCI-Bezeichnung "Acrylates/C 10-30 Alkyl Acrylate Crosspolymer" tragen. Insbesondere vorteilhaft sind die unter den Handelsbezeichnungen Pemulen TR1 und Pemulen TR2 bei der NOVEON Inc. erhältlichen.Also advantageous are copolymers of C10-30-alkyl acrylates and one or more monomers of acrylic acid, methacrylic acid or their esters, which are cross-linked with an allyl ether of sucrose or an allyl ether of pentaerythritol.
Here, compounds which carry the INCI name "Acrylates / C 10-30 Alkyl Acrylate Crosspolymer" are advantageous. Particularly advantageous are those available under the trade names Pemulen TR1 and Pemulen TR2 from NOVEON Inc.

Nichtionische FilmbildnerNonionic film formers

Geeignete nichtionische Polymere sind z.B. Homopolymere des Vinylpyrrolidons, z.B. Luviskol K von BASF oder Homopolymere des N-Vinylformamids z.B. PVF von National Starch. Weitere geeignete Polymere sind Copolymerisate aus Vinylpyrrolidon und Vinylacetat z.B. Luviskol VA Typen von BASF, Terpolymere aus Vinylpyrrolidon, Vinylacetat und Propionat wie z.B. Luviskol VAP von BASF, Polyvinylcaprolactam, Polyvinylamide und deren Salze sowie Copolymere aus Vinylpyrrolidon und Dimethylaminoethylmethacrylat, Terpolymere aus Vinylcaprolactam, Vinylpyrrolidon und Dimethylaminomethacrylat; Polysiloxane und dergleichen mehr.Suitable nonionic polymers are e.g. Homopolymers of vinylpyrrolidone, e.g. Luviskol K from BASF or homopolymers of N-vinylformamide e.g. PVF from National Starch. Further suitable polymers are copolymers of vinylpyrrolidone and vinyl acetate, e.g. Luviskol VA types from BASF, terpolymers from vinylpyrrolidone, vinyl acetate and propionate such as e.g. Luviskol VAP from BASF, polyvinylcaprolactam, polyvinylamides and their salts, as well as copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate, terpolymers of vinylcaprolactam, vinylpyrrolidone and dimethylaminomethacrylate; Polysiloxanes and the like.

BeispieleExamples

Folgende Handelsprodukte wurden eingesetzt: Carbomer Carbopol 98 Lubrizol Advanced Materials Cera Microcristallina Micro Care 114 von Paramelt Cera Microcristallina2 Paracera MWN von Paramelt Cera Microcristallina + Paraffinum Liquidum Merkur 717 Sasol Wax Paraffin Tafelparaffin Vollraffinat 1A weiss Past.; Schümann Sasol Beeswax Bienenwachs weiss (Art.2956);Kahl Emulsion INCl 1 2 3 4 5 6 7 Ceteareth-20 4,5 4,5 2,5 2 Sorbitanstearate 2 3 Ceteth-20 2 3 4 Stearinsäure 0,5 1 Glycerylstearate 2 PEG-40 Hydrogenated Castor Oil Dilaureth-4 Natriumphosphat 2 Xanthan Gum 0,3 0,3 0,3 0,3 0,3 0,3 0,3 Acrylates/C10-30 Alkyl Acrylate Cross-polymer 0,3 0,3 0,3 0,3 0,3 0,3 0,3 Acrylates/ Beheneth-25 Methacrylate Copo-lymer Carbomer 0,3 0,3 0,3 0,3 0,3 0,3 0,3 Hydroxyethylcellulose Polyquaternium-68 5 Polyquaternium-11 3 PVP/VA 5 2 PVP 6 2,5 2,5 2 2 4 Cera Microcristallina + Paraffinum Liquidum 9 5 12 5 8,5 5 8,5 Cera Microcristallina 4 3 2 3 4 3 4 Cetearyl Alcohol 1 3 2 1 3 3 3 Cera Microcristallina2 2 2 7 15 2 5 7 Lanolin Wax 5 C18-38 Alkyl Hydroxystearoyl Stearate 7 Ceresinwachs Beeswax 6 Paraffin 8 Paraffinum Liquidum 3 2 1 2 - 2 1 Dimethicone 2 Cyclomethicone 1 C12-15 Alkyl Benzoate 2 1 1 2 1 2 Trisodium EDTA 0,5 0,5 0,5 0,5 0,5 0,5 0,5 Glycerin 2 5 2 5 2 5 2 Alcohol Denat. 12 8 12 8 12 8 12 Parfuem, Lichtschutz, Konservierung, pH-Einstellung q.s. q.s. q.s. q.s. q.s. q.s. q.s. Wirkstoffe q.s. q.s. q.s. q.s. q.s. q.s. q.s. Aqua ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 INCI 8 9 10 11 12 13 14 15 Ceteareth-20 2 4,5 2 4,5 2 4,5 Sorbitanstearate 3 2 Ceteth-20 2 4 2 4 Stearinsäure 1 0,5 Glycerylstearate 2 2 PEG-40 Hydrogenated Castor Oil Dilaureth-4 Natriumphosphat Xanthan Gum 0,3 0,2 0,3 0,2 Acrylates/C10-30 Alkyl Acrylate Cross-polymer 0,2 0,3 0,3 0,2 0,3 Acrylates/ Beheneth-25 Methacrylate Copo-lymer 0,3 0,2 0,2 Carbomer 0,3 0,3 0,3 0,3 Hydroxyethylcellulose 0,2 0,2 Polyquaternium-68 Polyquaternium-11 PVP/VA PVP 4 5 3 2 3,5 5 2 4 Cera Microcristallina + Paraffinum Liquidum 8,5 2 12 9 8,5 8,5 9 9 Cera Microcristallina 4 - 2 3 4 4 3 2 Cetearyl Alcohol 3 3 1 2 3 3 1 1 Cera Microcristallina2 7 4 12 15 2 2 2 5 Lanolin Wax 5 C18-38 Alkyl Hydroxystearoyl Stearate 7 Ceresinwachs 4 Beeswax 6 Paraffin 8 Paraffinum Liquidum 1 4 2 3 1 2 4 3 Dimethicone 1 Cyclomethicone 2 C12-15 Alkyl Benzoate 5 2 1 2 2 1 2 2 Trisodium EDTA 0,5 0,5 0,5 0,5 0,5 0,5 0,5 0,5 Glycerin 2 5 2 5 2 2 5 2 Alcohol Denat. 12 8 5 - 12 5 12 8 Parfuem, Lichtschutz, Konservierung, pH- Einstellung q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. Wirkstoffe q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. Aqua ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 Wasserfreie Systeme (Stylig-Wachse) 1 2 Cera Micocristallina2 15 12 Paraffin - 5 Cetyl Palmitate 2 - Cetearyl Alcohol + PEG-40 Castor Oil + Sodium Cetearyl Sulfate 7 7 Glyceryl Stearate Citrate 3 3 Oleth-5 3 3 Parfum, Wirkstoffe q.s. q.s. Cera Microcristallina + Paraffinum Liquidum ad 100 ad 100 The following commercial products were used: Carbomer Carbopol 98 Lubrizol Advanced Materials Cera Microcristallina Micro Care 114 from Paramelt Cera Microcristallina 2 Paracera MWN from Paramelt Cera Microcristallina + Paraffin Liquidum Mercury 717 Sasol Wax paraffin Paraffin wax Vollraffinat 1A white Past .; Schümann Sasol Beeswax Beeswax white (art.2956); <B> emulsion </ b> INCI 1 2 3 4 5 6 7 Ceteareth-20 4.5 4.5 2.5 2 sorbitan 2 3 Ceteth-20 2 3 4 stearic acid 0.5 1 glyceryl 2 PEG-40 Hydrogenated Castor Oil Dilaureth-4 sodium phosphate 2 Xanthan gum 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Acrylates / C10-30 alkyl acrylate cross-polymer 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Acrylates / Beheneth-25 Methacrylate Copolyer Carbomer 0.3 0.3 0.3 0.3 0.3 0.3 0.3 hydroxyethyl Polyquaternium-68 5 Polyquaternium-11 3 PVP / VA 5 2 PVP 6 2.5 2.5 2 2 4 Cera Microcristallina + Paraffinum Liquidum 9 5 12 5 8.5 5 8.5 Cera Microcristallina 4 3 2 3 4 3 4 Cetearyl Alcohol 1 3 2 1 3 3 3 Cera Microcristallina 2 2 2 7 15 2 5 7 Lanolin wax 5 C18-38 alkyl hydroxystearoyl stearates 7 ceresin Beeswax 6 paraffin 8th Paraffin Liquidum 3 2 1 2 - 2 1 Dimethicone 2 Cyclomethicone 1 C12-15 alkyl benzoates 2 1 1 2 1 2 Trisodium EDTA 0.5 0.5 0.5 0.5 0.5 0.5 0.5 glycerin 2 5 2 5 2 5 2 Alcohol Denat. 12 8th 12 8th 12 8th 12 Perfumes, sunscreen, preservative, pH adjustment qs qs qs qs qs qs qs drugs qs qs qs qs qs qs qs Aqua ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 INCI 8th 9 10 11 12 13 14 15 Ceteareth-20 2 4.5 2 4.5 2 4.5 sorbitan 3 2 Ceteth-20 2 4 2 4 stearic acid 1 0.5 glyceryl 2 2 PEG-40 Hydrogenated Castor Oil Dilaureth-4 sodium phosphate Xanthan gum 0.3 0.2 0.3 0.2 Acrylates / C10-30 alkyl acrylate cross-polymer 0.2 0.3 0.3 0.2 0.3 Acrylates / Beheneth-25 Methacrylate Copolyer 0.3 0.2 0.2 Carbomer 0.3 0.3 0.3 0.3 hydroxyethyl 0.2 0.2 Polyquaternium-68 Polyquaternium-11 PVP / VA PVP 4 5 3 2 3.5 5 2 4 Cera Microcristallina + Paraffinum Liquidum 8.5 2 12 9 8.5 8.5 9 9 Cera Microcristallina 4 - 2 3 4 4 3 2 Cetearyl Alcohol 3 3 1 2 3 3 1 1 Cera Microcristallina 2 7 4 12 15 2 2 2 5 Lanolin wax 5 C18-38 alkyl hydroxystearoyl stearates 7 ceresin 4 Beeswax 6 paraffin 8th Paraffin Liquidum 1 4 2 3 1 2 4 3 Dimethicone 1 Cyclomethicone 2 C12-15 alkyl benzoates 5 2 1 2 2 1 2 2 Trisodium EDTA 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 glycerin 2 5 2 5 2 2 5 2 Alcohol Denat. 12 8th 5 - 12 5 12 8th Perfume, sunscreen, preservation, pH adjustment qs qs qs qs qs qs qs qs drugs qs qs qs qs qs qs qs qs Aqua ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 1 2 Cera Micocristallina 2 15 12 paraffin - 5 Cetyl palmitate 2 - Cetearyl Alcohol + PEG-40 Castor Oil + Sodium Cetearyl Sulfate 7 7 Glyceryl Stearate Citrate 3 3 Oleth-5 3 3 Perfume, active ingredients qs qs Cera Microcristallina + Paraffinum Liquidum ad 100 ad 100

Claims (7)

Produkt zur temporären Verformung und Stabilisierung der Frisur in Form eines Wachses oder einer Wachsemulsion enthaltend Wachse, Öle, Fette und ggf. Emulgatoren, dadurch gekennzeichnet, dass mindestens ein Wachs W* der Wachse einen Phasenübergang erster Ordnung und einen weiteren Phasenübergang bei geringerer Temperatur als der Temperatur des Phasenübergangs erster Ordnung aufweist und die Phasenübergangstemperatur des weiteren Phasenübergangs unterhalb von 20 °C liegt.Product for temporary shaping and stabilization of the hairstyle in the form of a wax or a wax emulsion containing waxes, oils, fats and possibly emulsifiers, characterized in that at least one wax wax W * of the waxes a first order phase transition and a further phase transition at a lower temperature than that Temperature of the first order phase transition and the phase transition temperature of the further phase transition is below 20 ° C. Produkt nach Patentanspruch 1 dadurch gekennzeichnet, dass der weitere Phasenübergang ein Phasenübergang zweiter Ordnung ist.Product according to claim 1, characterized in that the further phase transition is a second order phase transition. Produkt nach Patentanspruch 1 dadurch gekennzeichnet, dass der weitere Phasenübergang ein Phasenübergang erster Ordnung ist.Product according to claim 1, characterized in that the further phase transition is a first-order phase transition. Produkt nach einem der vorangehenden Patentansprüche dadurch gekennzeichnet, dass es 0,5 bis 15 Gew.-% des Wachses W* enthält.Product according to one of the preceding claims, characterized in that it contains 0.5 to 15 wt .-% of the wax W *. Produkt nach einem der vorangehenden Patentansprüche dadurch gekennzeichnet, dass es emulsionsförmig ist und wenigstens 2 Gew.-% eines Emulgators enthält.Product according to one of the preceding claims, characterized in that it is emulsion-shaped and contains at least 2 wt .-% of an emulsifier. Produkt nach einem der vorangehenden Patentansprüche dadurch gekennzeichnet, dass es emulsionsförmig ist und die Wasserphase Alkohol enthält.Product according to one of the preceding claims, characterized in that it is emulsion-shaped and the water phase contains alcohol. Verwendung eines Produktes nach wenigstens einem der vorangehenden Patentansprüche zur Gestaltung der Frisur.Use of a product according to at least one of the preceding claims for the design of the hairstyle.
EP09151912.4A 2008-03-25 2009-02-03 Styling formulations for creating a flexible hold through the use of particular waxes Ceased EP2105128A3 (en)

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WO2011076566A1 (en) * 2009-12-23 2011-06-30 Henkel Ag & Co. Kgaa Emulsion for keratin-containing fibres, containing at least one anionic polymer having a thickening effect, at least one non-ionic hair-strengthening polymer, at least one ester oil, at least one wax, and water
WO2012168120A3 (en) * 2011-06-08 2013-02-07 Henkel Ag & Co. Kgaa Lightweight styling agents
WO2013079259A3 (en) * 2011-11-28 2013-09-06 Henkel Ag & Co. Kgaa Shine-producing hair treatment agent
EP2882498B1 (en) 2012-08-13 2017-08-30 Henkel AG & Co. KGaA Agent and method for the temporary deformation of keratin fibres

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Publication number Priority date Publication date Assignee Title
WO2011076566A1 (en) * 2009-12-23 2011-06-30 Henkel Ag & Co. Kgaa Emulsion for keratin-containing fibres, containing at least one anionic polymer having a thickening effect, at least one non-ionic hair-strengthening polymer, at least one ester oil, at least one wax, and water
WO2012168120A3 (en) * 2011-06-08 2013-02-07 Henkel Ag & Co. Kgaa Lightweight styling agents
WO2013079259A3 (en) * 2011-11-28 2013-09-06 Henkel Ag & Co. Kgaa Shine-producing hair treatment agent
US9849076B2 (en) 2011-11-28 2017-12-26 Henkek AG & Co. KGaA Shine-producing hair treatment agent
EP2882498B1 (en) 2012-08-13 2017-08-30 Henkel AG & Co. KGaA Agent and method for the temporary deformation of keratin fibres

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