Classifications

• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
  • C10M141/08—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic sulfur-, selenium- or tellurium-containing compound
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
  • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
  • C10M133/16—Amides; Imides
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
  • C10M149/12—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M149/14—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds a condensation reaction being involved
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
  • C10M2201/08—Inorganic acids or salts thereof
  • C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
  • C10M2207/02—Hydroxy compounds
  • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
  • C10M2207/028—Overbased salts thereof
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
  • C10M2207/26—Overbased carboxylic acid salts
  • C10M2207/262—Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2215/08—Amides
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
  • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
  • C10M2219/046—Overbasedsulfonic acid salts
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
  • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
  • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
  • C10N2030/52—Base number [TBN]
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2040/00—Specified use or application for which the lubricating composition is intended
  • C10N2040/25—Internal-combustion engines

Definitions

• the present invention relates to a lubricating oil or grease composition for particular use in internal combustion engines.
• EP 0 194 718 discloses lubricating oil compositions which contain one or more lubricating oils, one or more basic salts of polyvalent metals and one or more polyesters or salts thereof which are either derived from one or more hydroxycarboxylic acids of the general formula HO-X-COOH, wherein X represents a bivalent saturated or unsaturated aliphatic radical which contains at least 8 carbon atoms and in which at least 4 carbon atoms are situated between the hydroxyl group and the carboxyl group, or derived from a mixture of one or more such hydroxycarboxylic acids and one or more carboxylic acids containing no hydroxyl groups.
• a lubricating composition for particular use in internal combustion engines which lubricating composition not only suppresses internal combustion engine fouling and exhibits advantageous cleaning performance in the reduction of deposits such as sludge and varnish, but also shows surprisingly advantageous friction reduction and anti-wear properties.
• the present invention provides a lubricating composition comprising:
• R + may be a primary, secondary, tertiary or quaternary ammonium group.
• R + is preferably a quaternary ammonium group.
• A is preferably a divalent straight chain or branched hydrocarbyl group as hereafter described for formulae (I) and (II).
• A is preferably an optionally substituted aromatic, aliphatic or cycloaliphatic straight chain or branched divalent hydrocarbyl group. More preferably, A is an arylene, alkylene or alkenylene group, in particular an arylene, alkylene or alkenylene group containing in the range of from 4 to 25 carbon atoms, more preferably in the range of from 12 to 20 carbon atoms.
• said compound of formula (III) there are at least 4 carbon atoms, more preferably in the range of from 8 to 14 carbon atoms connected directly between the carbonyl group and the oxygen atom derived from the hydroxyl group.
• the optional substituents in the group A are preferably selected from hydroxy, halo or alkoxy groups, especially C 1-4 alkoxy groups.
• Y is preferably an optionally substituted hydrocarbyl group as hereinbefore described for formula (I).
• the optionally substituted hydrocarbyl group Y in formula (III) is preferably aryl, alkyl or alkenyl containing up to 50 carbon atoms, more preferably in the range of from 7 to 25 carbon atoms.
• the optionally substituted hydrocarbyl group Y may be conveniently selected from heptyl, octyl, undecyl, lauryl, heptadecyl, heptadenyl, heptadecadienyl, stearyl, oleyl and linoleyl.
• optionally substituted hydrocarbyl group Y in formula (III) herein include C 4-8 cycloalkyls such as cyclohexyl; polycycloalkyls such as polycyclic terpenyl groups which are derived from naturally occurring acids such as abietic acid; aryls such as phenyl; aralkyls such as benzyl; and polyaryls such as naphthyl, biphenyl, stibenyl and phenylmethylphenyl.
• the optionally substituted hydrocarbyl group Y in formula (III) may contain one or more functional groups such as carbonyl, carboxyl, nitro, hydroxy, halo, alkoxy, amino, preferably tertiary amino (no N-H linkages), oxy, cyano, sulphonyl and sulphoxyl.
• the majority of the atoms, other than hydrogen, in substituted hydrocarbyl groups are generally carbon, with the heteroatoms (e.g., oxygen, nitrogen and sulphur) generally representing only a minority, about 33% or less, of the total non-hydrogen atoms present.
• the hydrocarbyl group Y in formula (III) is unsubstituted or substituted by a group selected from hydroxy, halo or alkoxy group, even more preferably C 1-4 alkoxy.
• the optionally substituted hydrocarbyl group Y in formula (III) is a stearyl group, 12-hydroxystearyl group, an oleyl group or a 12-hydroxyoleyl group, and that derived from naturally occurring oil such as tall oil fatty acid.
• Z is preferably an optionally substituted divalent bridging group represented by formula (IV) wherein R 1 is hydrogen or a hydrocarbyl group and B is an optionally substituted alkylene group.
• hydrocarbyl groups that may represent R 1 include methyl, ethyl, n-propyl, n-butyl and octadecyl.
• optionally substituted alkylene groups that may represent B include ethylene, trimethylene, tetramethylene and hexamethylene.
• R + may be represented by formula (V) wherein R 2 , R 3 and R 4 may be selected from hydrogen and alkyl groups such as methyl.
• the anion X q- of the compound of formula (III) is a sulphur-containing anion. More preferably said anion is selected from sulphate and sulphonate anions.
• the one or more poly(hydroxycarboxylic acid) amide salt derivatives may be obtained by reaction of an amine and a poly(hydroxycarboxylic acid) of formula (I) Y-CO[O-A-CO] n -OH (I) wherein Y is hydrogen or optionally substituted hydrocarbyl group, A is a divalent optionally substituted hydrocarbyl group and n is from 1 to 100, preferably from 1 to 10, with an acid or a quaternizing agent.
• hydrocarbyl represents a radical formed by removal of one or more hydrogen atoms from a carbon atom of a hydrocarbon (not necessarily the same carbon atoms in case more hydrogen atoms are removed).
• Hydrocarbyl groups may be aromatic, aliphatic, acyclic or cyclic groups.
• hydrocarbyl groups are aryl, cycloalkyl, alkyl or alkenyl, in which case they may be straight-chain or branched-chain groups.
• Representative hydrocarbyl groups include phenyl, naphthyl, methyl, ethyl, butyl, pentyl, methylpentyl, hexenyl, dimethylhexyl, octenyl, cyclooctenyl, methylcyclooctenyl, dimethylcyclooctyl, ethylhexyl, octyl, isooctyl, dodecyl, hexadecenyl, eicosyl, hexacosyl, triacontyl and phenylethyl.
• hydrocarbyl optionally substituted hydrocarbyl groups optionally containing one or more "inert” heteroatom-containing functional groups.
• inert is meant that the functional groups do not interfere to any substantial degree with the function of the compound.
• the optionally substituted hydrocarbyl group Y in formula (I) herein is preferably aryl, alkyl or alkenyl containing up to 50 carbon atoms, more preferably in the range of from 7 to 25 carbon atoms.
• the optionally substituted hydrocarbyl group Y may be conveniently selected from heptyl, octyl, undecyl, lauryl, heptadecyl, heptadenyl, heptadecadienyl, stearyl, oleyl and linoleyl.
• optionally substituted hydrocarbyl group Y in formula (I) herein include C 4-8 cycloalkyls such as cyclohexyl; polycycloalkyls such as polycyclic terpenyl groups which are derived from naturally occurring acids such as abietic acid; aryls such as phenyl; aralkyls such as benzyl; and polyaryls such as naphthyl, biphenyl, stibenyl and phenylmethylphenyl.
• the optionally substituted hydrocarbyl group Y may contain one or more functional groups such as carbonyl, carboxyl, nitro, hydroxy, halo, alkoxy, tertiary amino (no N-H linkages), oxy, cyano, sulphonyl and sulphoxyl.
• the majority of the atoms, other than hydrogen, in substituted hydrocarbyl groups are generally carbon, with the heteroatoms (e.g., oxygen, nitrogen and sulphur) generally representing only a minority, about 33% or less, of the total non-hydrogen atoms present.
• the hydrocarbyl group Y in formula (I) is more preferably unsubstituted or substituted by a group selected from hydroxy, halo or alkoxy group, even more preferably C 1-4 alkoxy.
• the optionally substituted hydrocarbyl group Y in formula (I) is a stearyl group, 12-hydroxystearyl group, an oleyl group, a 12-hydroxyoleyl group or a group derived from naturally occurring oil such as tall oil fatty acid.
• the one or more poly(hydroxycarboxylic acid) amide salt derivatives are sulphur-containing poly(hydroxycarboxylic acid) amide salt derivatives.
• said one or more poly(hydroxycarboxylic acid) amide salt derivatives have a sulphur content in the range of from 0.1 to 2.0 wt.%, even more preferably in the range of from 0.6 to 1.2 wt.% sulphur, as measured by ICP-AES, based on the total weight of said poly(hydroxycarboxylic acid) amide salt derivatives.
• the poly(hydroxycarboxylic acid)s of formula (I) may be made by the interesterification of one or more hydroxycarboxylic acids of formula (II) HO-A-COOH (II) wherein A is a divalent optionally substituted hydrocarbyl group, optionally in the presence of a catalyst according to well known methods. Such methods are described, for example, in US 3 996 059 , GB 1 373 660 and GB 1 342 746 .
• the chain terminator in said interesterification may be a non-hydroxycarboxylic acid.
• the hydroxyl group in the hydroxycarboxylic acid and the carboxylic acid group in the hydroxycarboxylic acid or the non-hydroxycarboxylic acid may be primary, secondary or tertiary in character.
• the interesterification of the hydroxycarboxylic acid and the non-hydroxycarboxylic acid chain terminator may be effected by heating the starting materials, optionally in a suitable hydrocarbon solvent such as toluene or xylene, and azeotroping off the formed water.
• the reaction may be carried out at a temperature up to -250°C, conveniently at the reflux temperature of the solvent.
• the temperature employed should not be so high as to lead to dehydration of the acid molecule.
• Catalysts for the interesterification such as p-toluenesulphonic acid, zinc acetate, zirconium naphthenate or tetrabutyl titanate, may be included, with the objective of either increasing the rate of reaction at a given temperature or of reducing the temperature required for a given rate of reaction.
• A is preferably an optionally substituted aromatic, aliphatic or cycloaliphatic straight chain or branched divalent hydrocarbyl group.
• A is an arylene, alkylene or alkenylene group, in particular an arylene, alkylene or alkenylene group containing in the range of from 4 to 25 carbon atoms, more preferably in the range of from 12 to 20 carbon atoms.
• the optional substituents in the group A are preferably selected from hydroxy, halo or alkoxy groups, more preferably C 1-4 alkoxy groups.
• the hydroxyl group in the hydroxycarboxylic acids of formula (II) is preferably a secondary hydroxyl group.
• suitable hydroxycarboxylic acids are 9-hydroxystearic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, 12-hydroxy-9-oleic acid (ricinoleic acid), 6-hydroxycaproic acid, preferably 12-hydroxystearic acid.
• Commercial 12-hydroxystearic acid hydrogenated castor oil fatty acid
• the proportion which is required in order to produce a polymer or oligomer of a given molecular weight can be determined either by simple experiment or by calculation by the person skilled in the art.
• the group (-O-A-CO-) in the compounds of formulae (I) and (II) is preferably a 12-oxystearyl group, 12-oxyoleyl group or a 6-oxycaproyl group.
• Preferred poly(hydroxycarboxylic acid)s of formula (I) for reaction with amine include poly(hydroxystearic acid) and poly(hydroxyoleic acid).
• the amines which react with poly(hydroxycarboxylic acid)s of formula (I) to form poly(hydroxycarboxylic acid) amide intermediates may include those defined in WO 97/41092 .
• the amine reactant is preferably a diamine, a triamine or a polyamine.
• Preferred amine reactants are diamines selected from ethylenediamine, N,N-dimethyl-1,3-propanediamine, triamines and polyamines selected from dietheylenetriamine, triethylenetetramine, tetraethylenepentamine, pentaethylenehexamine and tris(2-aminoethyl)amine.
• the amidation between the amine reactant and the (poly(hydroxycarboxylic acid) of formula (I) may be carried out according to methods known to those skilled in the art, by heating the poly(hydroxycarboxylic acid) with the amine reactant, optionally in a suitable hydrocarbon solvent such as toluene or xylene, and azeotroping off the formed water. Said reaction may be carried out in the presence of a catalyst such as p-toluenesulphonic acid, zinc acetate, zirconium naphthenate or tetrabutyl titanate.
• a catalyst such as p-toluenesulphonic acid, zinc acetate, zirconium naphthenate or tetrabutyl titanate.
• GB 1 373 660 discloses poly(hydroxycarboxylic acid) amide derivatives with amines such as 3-dimethylaminopropylamine and ethylenediamine for use as dispersing agents in dispersions of pigments in organic liquids.
• GB 2 001 083 discloses poly(hydroxycarboxylic acid) amide derivatives with poly(ethyleneimine) (PEI) having a molecular weight (MW) greater than 500 for a similar use.
• PEI poly(ethyleneimine)
• WO 95/17473 discloses poly(hydroxycarboxylic acid) amide derivatives with amines such as 3-dimethylaminopropylamine, ethylenediamine, poly(ethyleneimine) (PEI) having a molecular weight (MW) greater than 500 and amines of the formula of NH 2 -R'-N(R")-R"'-NH 2 for use in a method of preparing a non-aqueous dispersion of copper phthalocyanine.
• PEI poly(ethyleneimine)
• US 4 349 389 discloses poly(hydroxycarboxylic acid) amide derivatives with amines such as 3-dimethylaminopropylamine, poly(ethyleneimine) (PEI) having a molecular weight (MW) greater than 500 as dispersing agent in the preparation of a dispersible inorganic pigment composition.
• PEI poly(ethyleneimine)
• EP 0 164 817 discloses poly(hydroxycarboxylic acid) amide derivatives with polyamines (ethylenediamine, diethylenetriamine, etc.), aminoalcohols (diethanolamine, etc.) and ester derivatives with polyols (glycerol, etc.) for use as surfactant suitable for stabilising dispersions of solids in organic liquids and oil/water emulsions.
• the poly(hydroxycarboxylic acid) amide intermediate formed from reaction of the amine and the poly(hydroxycarboxylic acid) of formula (I) is reacted with an acid or a quaternizing agent to form a salt derivative, according to well-known methods.
• Acids that may be used to form the salt derivative may be selected from organic or inorganic acids.
• Said acids are preferably sulphur-containing organic or inorganic acids.
• said acids are selected from sulphuric acid, methanesulphonic acid and benzenesulphonic acid.
• Quaternizing agents that may be used to form the salt derivative may be selected from dimethylsulphuric acid, a dialkyl sulphate having from 1 to 4 carbon atoms, an alkyl halide such as methyl chloride, methyl bromide, aryl halide such as benzyl chloride.
• the quaternizing agent is a sulphur-containing quaternizing agent, in particular dimethylsulphuric acid or an dialkyl sulphate having from 1 to 4 carbon atoms.
• the quaternizing agent is preferably dimethyl sulphate.
• Quaternization is a well-known method in the art. For example, quaternization using dimethyl sulphate is described in US 3 996 059 , US 4 349 389 and GB 1 373 660 .
• the one or more poly(hydroxycarboxylic acid) amide salt derivatives are present in the lubricating composition of the present invention in an amount in the range of from 0.1 to 10.0 wt. %, more preferably in an amount in the range of from 0.1 to 5.0 wt. % and most preferably in an amount in the range of from 0.2 to 4.0 wt. %, based on the total weight of the lubricating composition.
• Poly(hydroxycarboxylic acid) amide salt derivatives that are preferred in the present invention are those which each have a TBN (total base number) value of less than 10 mg.KOH/g, as measured by ASTM D 4739. More preferably, the poly(hydroxycarboxylic acid) amide salt derivatives each have a TBN value of less than 5 mg.KOH/g, most preferably 2 mg.KOH/g or less, as measured by ASTM D 4739.
• poly(hydroxycarboxylic acid) amide salt derivatives that are available commercially include that available from Lubrizol under the trade designation "SOLSPERSE 17000” (a reaction product of poly(12-hydroxystearic acid) with N,N-dimethyl-1,3-propanediamine and dimethyl sulphate) and those available under the trade designations "CH-5" and "CH-7" from Shanghai Sanzheng Polymer Company.
• SOLSPERSE 17000 a reaction product of poly(12-hydroxystearic acid) with N,N-dimethyl-1,3-propanediamine and dimethyl sulphate
• the one or more anti-wear additives in the lubricating composition of the present invention are preferably present in an amount in the range of from 0.01 to 10.0 wt. %, based on the total weight of the lubricating composition.
• the one or more anti-wear additives present in the lubricating composition may comprise zinc dithiophosphates.
• the or each zinc dithiophosphate may be selected from zinc dialkyl-, diaryl- or alkylaryl-dithiophosphates.
• Preferred zinc dithiophosphates are those that may be conveniently represented by formula (VI): wherein R 5 to R 8 may be the same or different and are each a primary alkyl group containing from 1 to 20 carbon atoms preferably from 3 to 12 carbon atoms, a secondary alkyl group containing from 3 to 20 carbon atoms, preferably from 3 to 12 carbon atoms, an aryl group or an aryl group substituted with an alkyl group, said alkyl substituent containing from 1 to 20 carbon atoms preferably 3 to 18 carbon atoms.
• R 5 to R 8 may be the same or different and are each a primary alkyl group containing from 1 to 20 carbon atoms preferably from 3 to 12 carbon atoms, a secondary alkyl group containing from 3 to 20 carbon atoms, preferably from 3 to 12 carbon atoms, an aryl group or an aryl group substituted with an alkyl group, said alkyl substituent containing from 1 to 20 carbon atoms preferably 3 to
• Zinc dithiophosphate compounds in which R 5 to R 8 are all different from each other can be used alone or in admixture with zinc dithiophosphate compounds in which R 5 to R 8 are all the same.
• the or each zinc dithiophosphate used in the present invention is a zinc dialkyl dithiophosphate.
• Examples of zinc dithiophosphates which are commercially available include those available ex. Lubrizol Corporation under the trade designations “Lz 677A”, “Lz 1095”, “Lz 1097”, “Lz 1370”, “Lz 1371”, “Lz 1373” and “Lz 1395", those available ex. Chevron Oronite under the trade designations “OLOA 260”, “OLOA 262”, “OLOA 267” and “OLOA 269R”, and those available ex. Afton Chemical under the trade designation "HITEC 7169” and "HITEC 7197".
• the lubricating composition according to the present invention preferably comprises in the range of from 0.01 to 10.0 wt. % of zinc dithiophosphates, based on total weight of the lubricating composition.
• Additional or alternative anti-wear additives may be conveniently used in the lubricating composition of the present invention.
• the lubricating composition further comprises one or more detergents, in particular one or more salicylate, phenate or sulphonate detergents.
• Said detergents are preferably selected from alkali metal or alkaline earth metal salicylate, phenate or sulphonate detergents. Calcium and magnesium salicylates, phenates and sulphonates are particularly preferred.
• Said detergents are preferably used in amounts in the range of 0.05 to 12.5 wt. %, more preferably from 1.0 to 9.0 wt. % and most preferably in the range of from 2.0 to 5.0 wt. %, based on the total weight of the lubricating composition.
• base oil used in the present invention there are no particular limitations regarding the base oil used in the present invention, and various conventional known mineral oils and synthetic oils may be conveniently used.
• the base oil used in the present invention may conveniently comprise mixtures of one or more mineral oils and/or one or more synthetic oils.
• Mineral oils include liquid petroleum oils and solvent-treated or acid-treated mineral lubricating oil of the paraffinic, naphthenic, or mixed paraffinic/naphthenic type which may be further refined by hydrofinishing processes and/or dewaxing.
• Naphthenic base oils have low viscosity index (VI) (generally 40-80) and a low pour point.
• Such base oils are produced from feedstocks rich in naphthenes and low in wax content and are used mainly for lubricants in which colour and colour stability are important, and VI and oxidation stability are of secondary importance.
• Paraffinic base oils have higher VI (generally >95) and a high pour point. Said base oils are produced from feedstocks rich in paraffins, and are used for lubricants in which VI and oxidation stability are important.
• Fischer-Tropsch derived base oils may be conveniently used as the base oil in the lubricating composition of the present invention, for example, the Fischer-Tropsch derived base oils disclosed in EP 0 776 959 , EP 0 668 342 , WO 97/21788 , WO 00/15736 , WO 00/14188 , WO 00/14187 , WO 00/14183 , WO 00/14179 , WO 00/08115 , WO 99/41332 , EP 1 029 029 , WO 01/18156 and WO 01/57166 .
• Synthetic processes enable molecules to be built from simpler substances or to have their structures modified to give the precise properties required.
• Synthetic oils include hydrocarbon oils such as olefin oligomers (PAOs), dibasic acid esters, polyol esters, and dewaxed waxy raffinate. Synthetic hydrocarbon base oils sold by the Shell Group under the designation "XHVI” (trade mark) may be conveniently used.
• PAOs olefin oligomers
• XHVI XHVI
• the base oil is constituted from mineral oils and/or synthetic oils which contain more than 80% wt of saturates, preferably more than 90 % wt., as measured according to ASTM D2007.
• the base oil contains less than 1.0 wt. %, preferably less than 0.1 wt. % of sulphur, calculated as elemental sulphur and measured according to ASTM D2622, ASTM D4294, ASTM D4927 or ASTM D3120.
• the viscosity index of the base oil is more than 80, more preferably more than 120, as measured according to ASTM D2270.
• the total amount of base oil incorporated in the lubricating composition of the present invention is preferably present in an amount in the range of from 60 to 92 wt. %, more preferably in an amount in the range of from 75 to 90 wt. % and most preferably in an amount in the range of from 75 to 88 wt. %, with respect to the total weight of the lubricating composition.
• the lubricating composition has a kinematic viscosity in the range of from 2 to 80 mm 2 /s at 100 °C, more preferably in the range of from 3 to 70 mm 2 /s, most preferably in the range of from 4 to 50 mm 2 /s.
• the base oil as contained in the lubricating composition may contain or be compounded with one or more thickeners such as metallic soaps, organic substances or inorganic substances, for example, lithium soaps, lithium complex soaps, sodium terephthalate, urea/urethane compounds and clays.
• thickeners such as metallic soaps, organic substances or inorganic substances, for example, lithium soaps, lithium complex soaps, sodium terephthalate, urea/urethane compounds and clays.
• the lubricating composition of the present invention may further comprise additional additives such as antioxidants, dispersants, friction modifiers, viscosity index improvers, pour point depressants, corrosion inhibitors, defoaming agents and seal fix or seal compatibility agents.
• additional additives such as antioxidants, dispersants, friction modifiers, viscosity index improvers, pour point depressants, corrosion inhibitors, defoaming agents and seal fix or seal compatibility agents.
• Antioxidants that may be conveniently used include those selected from the group of aminic antioxidants and/or phenolic antioxidants.
• said antioxidants are present in an amount in the range of from 0.1 to 5.0 wt. %, more preferably in an amount in the range of from 0.3 to 3.0 wt. %, and most preferably in an amount of in the range of from 0.5 to 1.5 wt. %, based on the total weight of the lubricating composition.
• aminic antioxidants which may be conveniently used include alkylated diphenylamines, phenyl- ⁇ -naphthylamines, phenyl- ⁇ -naphthylamines and alkylated ⁇ -naphthylamines.
• Preferred aminic antioxidants include dialkyldiphenylamines such as p,p'-dioctyl-diphenylamine, p,p'-di- ⁇ -methylbenzyl-diphenylamine and N-p-butylphenyl-N-p'-octylphenylamine, monoalkyldiphenylamines such as mono-t-butyldiphenylamine and mono-octyldiphenylamine, bis(dialkylphenyl)amines such as di-(2,4-diethylphenyl)amine and di(2-ethyl-4-nonylphenyl)amine, alkylphenyl-1-naphthylamines such as octylphenyl-1-naphthylamine and n-t-dodecylphenyl-1-naphthylamine, 1-naphthylamine, arylnaph
• Preferred aminic antioxidants include those available under the following trade designations: "Sonoflex OD-3" (ex. Seiko Kagaku Co.), “Irganox L-57” (ex. Ciba Specialty Chemicals Co.) and phenothiazine (ex. Hodogaya Kagaku Co.).
• phenolic antioxidants which may be conveniently used include C7-C9 branched alkyl esters of 3,5-bis(1,1-dimethyl-ethyl)-4-hydroxy-benzenepropanoic acid, 2-t-butylphenol, 2-t-butyl-4-methylphenol, 2-t-butyl-5-methylphenol, 2,4-di-t-butylphenol, 2,4-dimethyl-6-t-butylphenol, 2-t-butyl-4-methoxyphenol, 3-t-butyl-4-methoxyphenol, 2,5-di-t-butylhydroquinone, 2,6-di-t-butyl-4-alkylphenols such as 2,6-di-t-butylphenol, 2,6-di-t-butyl-4-methylphenol and 2,6-di-t-butyl-4-ethylphenol, 2,6-di-t-butyl-4-alkoxyphenols such as 2,6-di-t-butyl
• Preferred phenolic antioxidants include those available under the following trade designations: "Irganox L-135" (ex. Ciba Specialty Chemicals Co.), “Yoshinox SS” (ex. Yoshitomi Seiyaku Co.), “Antage W-400” (ex. Kawaguchi Kagaku Co.), “Antage W-500” (ex. Kawaguchi Kagaku Co.), “Antage W-300” (ex. Kawaguchi Kagaku Co.), “Irganox L-109" (ex. Ciba Speciality Chemicals Co.), “Tominox 917” (ex. Yoshitomi Seiyaku Co.), “Irganox L-115" (ex.
• Ciba Speciality Chemicals Co. Ciba Speciality Chemicals Co.
• Sudilizer GA80 Ex. Sumitomo Kagaku
• Antage RC ex. Kawaguchi Kagaku Co.
• Irganox L-101 ex. Ciba Speciality Chemicals Co.
• Yoshinox 930 ex. Yoshitomi Seiyaku Co.
• the lubricating composition of the present invention may comprise mixtures of one or more phenolic antioxidants with one or more aminic antioxidants.
• the lubricating compositions of the present invention may additionally contain an ash-free dispersant which is preferably admixed in an amount in the range of from 5 to 15 wt. %, based on the total weight of the lubricating composition.
• ash-free dispersants examples include the polyalkenyl succinimides and polyalkenyl succininic acid esters disclosed in Japanese Laid-Open Patent Application Nos. JP 53-050291 A , JP 56-120679 A , JP 53-056610 A and JP 58-171488 A .
• Preferred dispersants include borated succinimides.
• viscosity index improver improvers which may conveniently be used in the lubricating composition of the present invention include the styrene-butadiene copolymers, styrene-isoprene stellate copolymers and the polymethacrylate copolymer and ethylene-propylene copolymers. Dispersant-viscosity index improvers may be used in the lubricating composition of the present invention.
• Such viscosity index improver improvers may be conveniently employed in an amount in the range of from 1 to 20 wt. %, based on the total weight of the lubricating composition.
• Polymethacrylates may be conveniently employed in the lubricating compositions of the present invention as effective pour point depressants.
• compounds such as alkenyl succinic acid or ester moieties thereof, benzotriazole-based compounds and thiodiazole-based compounds may be conveniently used in the lubricating composition of the present invention as corrosion inhibitors.
• Compounds such as polysiloxanes, dimethyl polycyclohexane and polyacrylates may be conveniently used in the lubricating composition of the present invention as defoaming agents.
• seal fix or seal compatibility agents include, for example, commercially available aromatic esters.
• the lubricating compositions of the present invention may be conveniently prepared by admixing the one or more poly(hydroxycarboxylic acid) amide salt derivatives and, optionally, one or more anti-wear additives, one or more detergents and further additives that are usually present in lubricating compositions, for example as herein before described, with mineral and/or synthetic base oil.
• the present invention provides a method of improving friction reduction and/or anti-wear properties, preferably in an internal combustion engine, which method comprises lubricating (preferably said internal combustion engine) with the lubricating composition according to the present invention.
• the present invention provides the use of the lubricating composition according to the present invention in order to improve friction reduction and/or anti-wear properties, preferably in an internal combustion engine.
• lubricating composition may also be suitably used for other uses than in an internal combustion engine, where friction reduction and anti-wear properties play a role.
• Table 1 indicates the composition of the lubricating oil compositions that were tested; the amounts of the components are given in wt.%.
• IVSAC GF-4" specification lubricant and "API SG/CD” specification lubricant available from SOPUS products and Shell Lubricants, respectively.
• IVSAC GF-4" is a 5W30 engine oil
• API SG/CD 15W40 engine oil.
• Poly(hydroxycarboxylic acid) amide salt derivatives according to the present invention that were used in testing were products available commercially from Shanghai Sanzheng Polymer Company under the trade designations "CH-5" and "CH-7".
• CH-5" and CH-7 products both have a TBN value of approximately 1.9 mg.KOH, as measured by ASTM D 4739. Furthermore, "CH-5" product and “CH-7” product have sulphur contents of approximately 0.95 wt.% and 0.86 wt.%, respectively, as measured by ICP-AES.
• SOLSPERSE 11200 A comparative product which was a poly(hydroxycarboxylic acid) derivative that is not according to the teaching of the present invention.
• SOLSPERSE 11200 is commercially available from Lubrizol under the trade designation "SOLSPERSE 11200”.
• SOLSPERSE 11200" product has a TBN value of approximately 35 mg.KOH/g, as measured by ASTM D 4739 and a sulphur content of ⁇ 0.01 wt. %, as measured by ICP-AES. TABLE 1 Component (wt. %) Example 1 Example 2 Example 3 Comp. Ex. 1 Comp. Ex. 2 Comp. Ex. 3 Comp. Ex.
• test methodology used is described in amongst others H. Ji et al., "Zinc-dialkyl-dithiophosphate antiwear films: dependence on contact pressure and sliding speed", Wear 258 (2005) 789-799 ; and G. Pereira et al., "A variable temperature mechanical analysis of ZDDP-derived antiwear films formed on 52100 steel", Wear 262 (2007) 461-470 .
• RASER1 friction and wear measurements were made using a Cameron Flint TE77 reciprocating wear and friction test machine (available from Phoenix Tribology Ltd, Newbury, England) modified to produce a contact between one reciprocating component and a rotating component, similar to a Reciprocating Amsler machine (as described in e.g. SAE paper 952473 of October 1995).
• a difference between the RASER1 and the Reciprocating Amsler rig concerns the contact geometry.
• the Reciprocating Amsler rig involves a line-contact between the contacting components, whilst for the RASER1, however, the block specimen representing the cam follower is barrelled in the direction orthogonal to the direction of motion, so that the contact geometry is elliptical. This enables a higher contact pressure to be produced from a given applied load. Nevertheless, the contact conditions of the test are still based around those of the pivoted valve-train systems used as the basis of the Reciprocating Amsler rig.
• test specimens as used in the RASER1 test were both made of hardened steel, with the disc specimen having the greater hardness and roughness, so that most wear occured on the block specimen.
• the rotating and reciprocating components were operated in loaded contact with each other, while partially immersed in a temperature-controlled oil bath.
• the maximum Hertzian pressure of the contact was 0.64 GPa.
• the surface velocity of the disc was 1.1 m.s -1 , while the block motion varied sinusoidally with an amplitude of 0.47 m.s -1 .
• the test involved two temperature stages, firstly at 40°C oil temperature for 2 hours, then at 100°C oil temperature for a further 2 hours.
• the humidity was maintained at a dew-point of 25°C during the low temperature stage; it was not controlled during the high temperature stage.
• Table 3 The conditions are also indicated in Table 3 below.
• Example 3 Comp. Ex. 2 Comp. Ex. 3 Comp. Ex. 4 Friction coefficient (after stage 2) 0.083 0.095 0.090 0.105 Friction reduction [%] 12.6 - 5.2 -10.5 (increase) Wear (average end stroke) [mm] 1.21 1.45 1.45 1.33 Wear reduction [%] 16.6 - - 8.3 Wear (mid stroke) [mm] 0.87 0.97 0.99 0.87 Wear reduction [%] 10.3 - -2.1 (increase 10.3
• Comparative Example 3 Although the friction coefficient in the case of Comparative Example 3 (using "SOLSPERSE 11200") was also reduced compared with Comparative Example 2 (but in a far lesser extent than in the case of Example 3), Comparative Example 3 resulted in a neutral (end stroke) or negative (mid stroke) wear effect.
• Comparative Example 4 (“SAP 230") resulted in some wear reduction, but showed an increase in friction when compared with Comparative Example 2.

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