EP2044234B1 - Method for flexibly rolling coated steel strips - Google Patents
Method for flexibly rolling coated steel strips Download PDFInfo
- Publication number
- EP2044234B1 EP2044234B1 EP08707473.8A EP08707473A EP2044234B1 EP 2044234 B1 EP2044234 B1 EP 2044234B1 EP 08707473 A EP08707473 A EP 08707473A EP 2044234 B1 EP2044234 B1 EP 2044234B1
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- European Patent Office
- Prior art keywords
- hot
- coating
- strip
- thickness
- cold
- Prior art date
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- 238000005096 rolling process Methods 0.000 title claims description 45
- 238000000034 method Methods 0.000 title claims description 37
- 229910000831 Steel Inorganic materials 0.000 title claims description 21
- 239000010959 steel Substances 0.000 title claims description 21
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 28
- 229910052725 zinc Inorganic materials 0.000 claims description 28
- 239000011701 zinc Substances 0.000 claims description 28
- 238000000576 coating method Methods 0.000 claims description 25
- 239000011248 coating agent Substances 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 19
- 229910052751 metal Inorganic materials 0.000 claims description 18
- 239000002184 metal Substances 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 11
- 238000004381 surface treatment Methods 0.000 claims description 10
- 238000010521 absorption reaction Methods 0.000 claims description 7
- 238000003618 dip coating Methods 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 2
- 230000003466 anti-cipated effect Effects 0.000 claims 1
- 230000000630 rising effect Effects 0.000 claims 1
- 238000005246 galvanizing Methods 0.000 description 23
- 238000010438 heat treatment Methods 0.000 description 16
- 238000000137 annealing Methods 0.000 description 12
- 150000002739 metals Chemical class 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000005672 electromagnetic field Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000005269 aluminizing Methods 0.000 description 1
- 229910001566 austenite Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000019589 hardness Nutrition 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/14—Removing excess of molten coatings; Controlling or regulating the coating thickness
- C23C2/16—Removing excess of molten coatings; Controlling or regulating the coating thickness using fluids under pressure, e.g. air knives
- C23C2/18—Removing excess of molten coatings from elongated material
- C23C2/20—Strips; Plates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B37/00—Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
- B21B37/16—Control of thickness, width, diameter or other transverse dimensions
- B21B37/24—Automatic variation of thickness according to a predetermined programme
- B21B37/26—Automatic variation of thickness according to a predetermined programme for obtaining one strip having successive lengths of different constant thickness
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/62—Quenching devices
- C21D1/673—Quenching devices for die quenching
Definitions
- the invention relates to a method for flexible rolling of coated steel strips.
- a method and apparatus for refining flexibly rolled strip material is known.
- the material thickness of this strip is changed periodically to produce in a continuous process, the starting material for single boards, which has adapted material thicknesses according to the requirements of the sheet metal parts to be produced therefrom in the tape longitudinal direction.
- the strip material is first wound on a coil. A heat treatment usually takes place on the wound coil. The strip is then unwound from the coil, subjected to a surface treatment and wound up again on a coil. Only then, in a further process, the separation of individual boards and the further processing to individual sheet metal components.
- the task of DE 10 2004 023 886 A1 to propose an improved method and a device adapted thereto with which the finishing of the flexibly rolled strip material can be simplified and improved.
- the task is to be achieved in that the tape is produced as a flexible rolled strip material, is wound and then unwound from the coil and heat treated in a single continuous pass through a treatment line of annealing, quenching, preheating unit and zinc bath and hot dip galvanized.
- a continuous furnace with an annealing section and a quenching section, a preheating and a zinc bath is provided and a final Abblasdüse.
- the galvanizing takes place at 470 ° to 500 ° C, with part of the energy used for the previous heat treatment for the galvanizing process to be exploited.
- excess adhesive zinc be blown off the strip material to achieve a precisely set layer thickness, which also determines the strip thickness and should serve to control the nozzle spacing.
- From the DE 10 2005 031 461 A1 is a method for producing a microalloyed cold strip with a matched to the thickness profile property profile known, wherein a hot strip of steel is rolled with a substantially homogeneous thickness and strength to a cold strip having a substantially constant strip thickness with Abwalzgraden in the range between 5 and 60% , an annealing of the cold strip at a temperature between 500 ° and 600 ° C is performed and a second rolling of the cold strip is performed, wherein the rolling is performed flexibly such that predefined thickness profiles are set with a region of higher thickness and a region of lesser thickness and then a second annealing treatment is performed.
- Rolling process performed by a nip formed between two work rolls and the roll gap is selectively moved during the rolling process to achieve over the length of the metal strip different thicknesses.
- This flexible rolling should be characterized in that during the rolling process, the nip is selectively moved, whereby different lengths of tape sections are rolled with different tape thicknesses that can be connected to each other via different slopes.
- the aim of flexible rolling is to produce rolled products with load and weight optimized cross-sectional shapes.
- the EP 1 074 317 B1 proposes improved process control for flexible rolling to achieve a metal strip with improved flatness even with wide belts.
- EP1861517 B1 discloses a process for hot dip steel strip hot dip coating in which a hot strip is hot dip coated and the finished thickness and thickness tolerance of the hot dip coated steel strip is achieved by controlled thickness reduction in a process line mill scale wherein at least one thickness gauge in the outlet of the mill stand is reached the finished thickness is controlled and deviations from this up or down as a control signal to the employment of the rolling stand are returned to increase or reduce the thickness reduction accordingly.
- the object of the invention is to provide flexibly rolled and provided with a corrosion protection sheets for the press hardening process available, which are considerably cheaper than previously produced and uniform despite the flexible rolling in their remaining properties.
- the flexible rolling is carried out with different rolling pressures in order to produce different thicknesses of the steel strip. So far, no galvanized or otherwise coated sheets have been used for this, since the flexible rolling also affects the coating thickness of the coating.
- the possible coatings with which the flexible rolls to be rolled can be coated according to the invention are hot-dip coatings and electrolytic coatings.
- Possible hot-dip coatings are z. As hot-dip galvanized layers or mecanicaluminATOR layers but also mixed forms thereof, ie alloys of zinc and aluminum but also of zinc and other metals or aluminum and other metals.
- electrolytic coatings are, for example, electrolytically applied zinc layers, but of course other electrolytically applied metal layers are also possible.
- inventively recognized problems that the different sheet thicknesses give different heating curves over the tape length and that different zinc layer thicknesses arise as a result of the flexible rolling process are inventively achieved in that a hot strip is hot dip galvanized before flexible rolling and / or the emissivity or the degree of absorption is influenced by mechanical or chemical treatment of the zinc surface.
- a different heat absorption capacity over the strip length can be achieved.
- the degree of absorption in a region in which the tape and / or the coating is particularly thin is set poorly, while being particularly well adjusted in the region in which the tape and / or the coating is particularly thick. Of course, appropriate intermediate levels are met.
- the zinc layer thickness is preset by means of variable adjustment of the stripping pressure or additional electromagnetic fields during hot-dip galvanizing of the hot strip , Areas that are then very flexible very flexible Thus, after being hot-dip galvanized, they have a thicker layer of zinc, while areas that remain thicker have a thinner layer of zinc.
- the corresponding different intermediate areas are also set here or are readily adjustable.
- the procedure according to the invention makes it possible to achieve a significantly more cost-efficient production of flexible rolled sheet metal automotive parts, since the transport costs of the coils for the post-galvanizing and the bell annealing usual in the prior art are eliminated.
- Wuppermann method Wuppermann method
- Fig. 2 Wuppermann method
- hitherto uncoated hot strip was usually calibrated from ordinary automotive steels, then flexibly rolled and then subjected to recrystallization annealing to reverse the microstructural changes produced by rolling.
- This recrystallization annealing usually takes place in a crucible annealing furnace, wherein the strip is previously unwound into a so-called coil and annealed as a whole coil. Subsequently, these annealed coils are transported to a galvanizing plant and there galvanized and then transported back again, cut boards and shaped components, which then yield the final product.
- a hot strip or cold strip is fed to a hot-dip galvanizing plant in which the strip is unwound from the coil, welded to the preceding strip and then passed through the galvanizing plant.
- a heating of the strip and then the known per se implementation by the galvanizing takes place.
- the stripping device produces a zinc layer with a thickness that can be applied flexibly.
- the stripping device can also be a system which acts on the zinc layer by stripping off an electromagnetic field.
- hot-dip galvanizing process can, of course, be used equally well in other hot-dip galvanizing applications, for example, fire aluminizing or hot-dip coatings of aluminum-based alloys or zinc-based alloys and alloys of other metals or more metals than zinc and aluminum.
- the layer thickness to be applied is controlled by the strength of the electrolytically active stream and / or the strip speed in the electrolytic coating bath, the control system basically also being used as the control with which the positionally accurate deviation of the different sheet thicknesses during flexible rolling is also carried out.
- the flexible rollers can follow, with the flexible rollers, as already stated, different thicknesses can be achieved exactly positioned with respect to the tape length. From the flexible rolled sheet blanks are then cut in a conventional manner, which accordingly also the predetermined Have thickness over the length or width. These boards with different thickness profiles are then used according to the invention for a press hardening.
- the press hardening can be realized by two different methods.
- the cut boards are austenitized, d. H. subjected to a heat treatment in which austenite conversion takes place depending on the steel.
- the hot board is inserted into a hot forming tool, formed in the hot forming tool to the component and cooled at the same time.
- the cooling takes place here with a temperature which is above the critical hardening temperature, so that the curing takes place simultaneously in the forming tool.
- the hardened formed board leaves the press and can optionally be reworked or is already the final product.
- mold hardening is performed instead of hot working.
- the board is cold formed.
- this cold transformation in all three spatial directions is already complete, as well as the trimming of the edges and the creation of a hole pattern.
- the board is formed with an undersize of 0.5 to 2% in all three spatial directions and then austenitized.
- the thermal expansion compensates for the under-forming by 0.5 to 2%, so that after complete heating, the formed blank has its final geometry.
- This now final geometry or final contour corresponding board is inserted into a mold hardening tool, which also has exactly the contour or geometry of the desired end component.
- the component is in the mold hardening tool at least in the field of particularly strongly shaped areas held positively, preferably held completely positive fit, cooled and cured by cooling.
- the component is removed as an end product from the mold hardening tool.
- austenitization of the boards takes place.
- the board is heated to about 900 ° to 950 ° C in the preferably used hardenable steels type 22MnB5.
- different heat profiles or heat treatment profiles also result in the sheet, which ultimately result in different temperatures over the length or width of the board. Since a complete hardening is desired, therefore, the areas with larger sheet thicknesses must at least have the austenitizing temperature. However, this leads to the fact that the thinner areas are virtually overheated.
- different temperature or heat treatment profiles of the different sheet thickness ranges of the board over the entire treatment process different hardnesses or material properties can arise.
- the surface of the strip is influenced after galvanizing and before the flexible rolling or after the flexible rolling and cutting in front of the sinker.
- the surface treatment of the tape can be done in different ways.
- the aim of the surface treatment is to influence the emissivity or the absorption of heat or heat radiation.
- a different zinc layer thickness order before rolling can also be avoided and only by the surface treatment quasi-same properties were achieved during annealing.
- this can be achieved by a matting treatment, a skin pass, d. H. a micro-contouring of the surface, or an additional coating done.
- the areas which are later thicker after flexible rolling or even after flexible rolling can be given a matted, low-reflecting or dressed surface or be provided with a temporary dark protective lacquer or with a metal oxide surface which provides a particularly good absorption of Thermal radiation and thus a good heating of the thicker areas allows.
- the same control as for the flexible rolling or the flexible galvanizing is basically used, so that the corresponding areas in their surface condition can be changed precisely and very correctly.
- the advantage of the invention is that it is possible to flexibly roll hardenable steels, which have to be subjected to a heat treatment for the hardening, and nevertheless to form them with a corrosion protection layer, whereby products having a high homogeneity with respect to the material properties are obtained.
- sheet metal components can be obtained in a considerably more favorable manner with this method.
- the invention is not limited to hardenable steels, for example of the type 22MnB5.
- the flexible galvanizing or galvanizing with flexible layer thicknesses is also applicable to steels that should not undergo further heat treatment, with success.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating With Molten Metal (AREA)
- Metal Rolling (AREA)
- Electroplating Methods And Accessories (AREA)
Description
Die Erfindung betrifft ein Verfahren zum flexiblen Walzen von beschichteten Stahlbändern.The invention relates to a method for flexible rolling of coated steel strips.
Aus der
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Walzprozesses durch einen zwischen zwei Arbeitswalzen gebildeten Walzspalt geführt und der Walzspalt während des Walzvorganges gezielt verfahren wird, um über die Länge des Metallbandes unterschiedliche Banddicken zu erzielen. Dieses flexible Walzen soll dadurch gekennzeichnet sein, dass während des Walzprozesses der Walzspalt gezielt verfahren wird, wodurch unterschiedlich lange Bandabschnitte mit unterschiedlichen Banddicken gewalzt werden, die über unterschiedliche Steigungen miteinander verbunden sein können. Das Ziel des flexiblen Walzens soll es sein, Walzprodukte mit belastungs- und gewichtsoptimierten Querschnittsformen herzustellen. Die
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Aus der Dokument
Aufgabe der Erfindung ist es, flexibel gewalzte und mit einem Korrosionsschutz versehene Bleche für das Presshärteverfahren zur Verfügung zu stellen, die erheblich günstiger als bisher herstellbare und trotz des flexiblen Walzens in ihren restlichen Eigenschaften einheitlich sind.The object of the invention is to provide flexibly rolled and provided with a corrosion protection sheets for the press hardening process available, which are considerably cheaper than previously produced and uniform despite the flexible rolling in their remaining properties.
Die Aufgabe wird mit einem Verfahren mit den Merkmalen des Anspruchs 1 gelöst.The object is achieved by a method having the features of claim 1.
Weitere vorteilhafte Weiterbildungen sind in Unteransprüchen gekennzeichnet.Further advantageous developments are characterized in subclaims.
Wie aus dem Stand der Technik schon bekannt, wird beim flexiblen Walzen mit unterschiedlichen Walzdrücken gearbeitet, um unterschiedliche Dicken des Stahlbandes herzustellen. Bislang wurden hierfür keine verzinkten oder in sonstiger Weise beschichteten Bleche verwendet, da sich das flexible Walzen auch auf die Schichtdicke der Beschichtung auswirkt. Zudem wurde bei der Erfindung als Problem erkannt, dass die unterschiedlichen Blechdicken nach dem flexiblen Walzen bei nachfolgenden Aufheizverfahren, insbesondere für das Presshärten, bei dem eine aufgeheizte Platine in ein Warmumformwerkzeug eingelegt und dort umgeformt wird, oder ein Bauteil umgeformt wird, anschließend aufgeheizt und in einem Formwerkzeug formgehärtet wird, unterschiedliche Aufheizkurven für die verschiedenen Bleckdicken ergibt. Dies ist problematisch, da durch die unterschiedlichen Aufheizkurven auch unterschiedliche Temperaturen resultieren, wodurch die Materialeigenschaften je nach Blechdicke variieren.As already known from the prior art, the flexible rolling is carried out with different rolling pressures in order to produce different thicknesses of the steel strip. So far, no galvanized or otherwise coated sheets have been used for this, since the flexible rolling also affects the coating thickness of the coating. In addition, it was recognized in the invention as a problem that the different sheet thicknesses after flexible rolling in subsequent heating, in particular for press hardening, in which a heated board is placed in a hot forming tool and formed there, or a component is formed, then heated and in a mold is hardened, different heating curves results for the different Bleckdicken. This is problematic, since the different heating curves also result in different temperatures, as a result of which the material properties vary depending on the sheet thickness.
Die möglichen Beschichtungen, mit denen erfindungsgemäß die flexibel zu walzenden Bänder beschichtet sein können, sind Schmelztauchbeschichtungen und elektrolytische Beschichtungen. Mögliche Schmelztauchbeschichtungen sind z. B. feuerverzinkte Schichten oder feueraluminierte Schichten aber auch Mischformen hieraus, d. h. Legierungen aus Zink und Aluminium aber auch aus Zink und anderen Metallen oder Aluminium und anderen Metallen.The possible coatings with which the flexible rolls to be rolled can be coated according to the invention are hot-dip coatings and electrolytic coatings. Possible hot-dip coatings are z. As hot-dip galvanized layers or feueraluminierte layers but also mixed forms thereof, ie alloys of zinc and aluminum but also of zinc and other metals or aluminum and other metals.
Mögliche elektrolytische Beschichtungen sind beispielsweise elektrolytisch aufgebrachte Zinkschichten aber selbstverständlich sind auch andere elektrolytisch aufgebrachte Metallschichten möglich.Possible electrolytic coatings are, for example, electrolytically applied zinc layers, but of course other electrolytically applied metal layers are also possible.
Wenn nachfolgend von Zinkschichten oder feuerverzinkten Schichten gesprochen wird, steht dies lediglich stellvertretend auch für die anderen oben genannten möglichen Schichten.When speaking of zinc layers or hot-dip galvanized layers below, this is merely representative of the other possible layers mentioned above.
Die erfindungsgemäß erkannten Probleme, dass die unterschiedlichen Blechdicken unterschiedliche Aufheizkurven über die Bandlänge ergeben und, dass verschiedene Zinkschichtdicken in Folge des flexiblen Walzprozesses entstehen, werden erfindungsgemäß dadurch gelöst, dass ein Warmband vor dem flexiblen Walzen feuerverzinkt wird und/oder die Emissivität bzw. der Absorptionsgrad durch mechanische oder chemische Behandlung der Zinkoberfläche beeinflusst wird. Durch diese Einstellung der Emissivität/des Absorptionsgrades kann eine unterschiedliche Wärmeaufnahmefähigkeit über die Bandlänge erzielt werden. Beispielsweise wird der Absorptionsgrad in einem Bereich, in dem das Band und/oder die Beschichtung besonders dünn ist, schlecht eingestellt, während er in dem Bereich, in dem das Band und/oder die Beschichtung besonders dick ist, besonders gut eingestellt wird. Selbstverständlich werden entsprechende Zwischenstufen eingehalten.The inventively recognized problems that the different sheet thicknesses give different heating curves over the tape length and that different zinc layer thicknesses arise as a result of the flexible rolling process are inventively achieved in that a hot strip is hot dip galvanized before flexible rolling and / or the emissivity or the degree of absorption is influenced by mechanical or chemical treatment of the zinc surface. By this adjustment of the emissivity / the degree of absorption, a different heat absorption capacity over the strip length can be achieved. For example, the degree of absorption in a region in which the tape and / or the coating is particularly thin is set poorly, while being particularly well adjusted in the region in which the tape and / or the coating is particularly thick. Of course, appropriate intermediate levels are met.
Um unterschiedliche Zinkschichtdicken in Folge des flexiblen Walzprozesses auszugleichen, so dass alle Blechteile nach dem flexiblen Walzen von einer Zinkschicht einheitlicher Dicke bedeckt sind und somit auch einheitliche Korrosionsschutzeigenschaften aufweisen, wird beim Feuerverzinken des Warmbandes die Zinkschichtdicke mittels variabler Einstellung des Abstreifdruckes bzw. zusätzlichen elektromagnetischen Feldern voreingestellt. Bereiche, die anschließend flexibel sehr dünn ausgewalzt werden, besitzen somit nach dem Feuerverzinken eine dickere Zinkschicht, während Bereiche, die dicker verbleiben, eine dünnere Zinkschicht besitzen. Selbstverständlich werden auch hier die entsprechenden unterschiedlichen Zwischenbereiche eingestellt bzw. sind ohne Weiteres einstellbar.To compensate for different zinc layer thicknesses as a result of the flexible rolling process, so that all sheet metal parts are covered by a zinc layer of uniform thickness after flexible rolling and thus also have uniform corrosion protection properties, the zinc layer thickness is preset by means of variable adjustment of the stripping pressure or additional electromagnetic fields during hot-dip galvanizing of the hot strip , Areas that are then very flexible very flexible Thus, after being hot-dip galvanized, they have a thicker layer of zinc, while areas that remain thicker have a thinner layer of zinc. Of course, the corresponding different intermediate areas are also set here or are readily adjustable.
Durch das erfindungsgemäße Vorgehen lässt sich eine deutlich kosteneffizientere Herstellung von flexiblen gewalzten Blechautomobilteilen erzielen, da die Transportkosten der Coils zur Nachverzinkung sowie das im Stand der Technik übliche Haubenglühen wegfallen. Zudem lässt sich statt einer Stückverzinkung oder einer Schmalbandverzinkung nach dem Wuppermannverfahren (WM-FVZ, siehe
Die Erfindung wird anhand einer Zeichnung beispielhaft erläutert. Es zeigen dabei:
- Figur 1:
- ein Ablaufdiagramm zeigend schematisch die möglichen erfindungsgemäßen Verfahrensabläufe;
- Figur 2:
- ein Ablaufdiagramm zeigend schematisch den Verfahrensablauf nach dem Stand der Technik.
- FIG. 1:
- a flow chart showing schematically the possible inventive procedures;
- FIG. 2:
- a flow chart showing schematically the procedure according to the prior art.
Im Stand der Technik wurde bislang unbeschichtetes Warmband üblicherweise aus normalen Automobilstählen kalibriert, anschließend flexibel gewalzt und dann einem Rekristallisationsglühen unterzogen, um die durch das Walzen erzeugten Gefügeänderungen wieder rückgängig zu machen. Dieses Rekristallisationsglühen findet üblicherweise in einem Haubenglühofen statt, wobei das Band zuvor zu einem so genannten Coil aufgehaspelt und als ganzes Coil geglüht wird. Anschließend werden diese geglühten Coils zu einer Verzinkungsanlage transportiert und dort verzinkt und dann wieder zurück transportiert, Platinen geschnitten und Bauteile geformt, die dann das Endprodukt ergeben.In the prior art, hitherto uncoated hot strip was usually calibrated from ordinary automotive steels, then flexibly rolled and then subjected to recrystallization annealing to reverse the microstructural changes produced by rolling. This recrystallization annealing usually takes place in a crucible annealing furnace, wherein the strip is previously unwound into a so-called coil and annealed as a whole coil. Subsequently, these annealed coils are transported to a galvanizing plant and there galvanized and then transported back again, cut boards and shaped components, which then yield the final product.
Erfindungsgemäß wird ein Warmband oder Kaltband einer Feuerverzinkungsanlage zugeführt, bei der das Band vom Coil abgehaspelt, an das vorhergehende Band angeschweißt und dann durch die Verzinkungsanlage durchgeführt wird. In der Verzinkungsanlage erfolgt eine Erwärmung des Bandes und anschließend die an sich bekannte Durchführung durch das Feuerverzinkungsbad.According to the invention, a hot strip or cold strip is fed to a hot-dip galvanizing plant in which the strip is unwound from the coil, welded to the preceding strip and then passed through the galvanizing plant. In the galvanizing plant, a heating of the strip and then the known per se implementation by the galvanizing takes place.
Es ist an sich bekannt, nach dem Feuerverzinkungsbad so genannte Abstreifdüsen vorzusehen, welche die Zinkschicht auf dem frisch verzinkten Band einstellen, wobei Luft oder ein anderes Gas durch eine Breitschlitzdüse auf die noch flüssige Zinkschicht geblasen wird, so dass ein Druck auf die Zinkschicht entsteht, der das flüssige Zink entgegen der Bandlaufrichtung drückt, so dass nach der Beschichtungsdüse eine vorgegebene Schichtdicke vorliegt. Anschließend wird das Band gegebenenfalls einer Wärmebehandlung bzw. Kühlung unterworfen.It is known per se to provide after the hot-dip galvanizing so-called wiping, which adjust the zinc layer on the freshly galvanized strip, with air or another gas is blown through a slot die on the still liquid zinc layer, so that a pressure on the zinc layer is formed which presses the liquid zinc counter to the strip running direction, so that after the coating nozzle is present a predetermined layer thickness. Subsequently, the tape is optionally subjected to a heat treatment or cooling.
Erfindungsgemäß wird mit der Abstreifeinrichtung eine Zinkschicht mit einer flexibel aufzubringenden Dicke erzeugt. Die Abstreifvorrichtung kann auch eine Anlage sein, die über ein elektromagnetisches Feld abstreifend auf die Zinkschicht einwirkt.According to the invention, the stripping device produces a zinc layer with a thickness that can be applied flexibly. The stripping device can also be a system which acts on the zinc layer by stripping off an electromagnetic field.
Bei einer gegebenen Länge des Bandes, welches durch die Verzinkung geführt wird, ist von vornherein bekannt, welche Bandlängen beim nachfolgenden flexiblen Walzen dünn ausgewalzt werden und welche dicker ausgewalzt werden. Da die Walzen, die später das flexible Walzen übernehmen, auch entsprechend der Länge des Bandes angesteuert werden und zu jeder Zeit bekannt ist, welcher genaue Bandabschnitt oder welche genaue Bandlänge des genauen Coils gerade durch die Walzen läuft, wird die gleiche Steuerung verwendet, um den Abstreifdüsendruck zu verändern. Somit können in unterschiedlichen Bereichen des Bandes auch unterschiedliche Schichtdicken der Verzinkung sichergestellt werden. Z. B. wird in einem Bereich, der später besonders stark, d. h. dünn, ausgewalzt wird, der Düsendruck geringer gewählt und damit weniger Material abgestreift als in Bereichen, in denen später ein geringerer Walzgrad durchgeführt wird. Durch diese Vorgehensweise kann eine einheitliche Zinkschichtdicke über das gesamte später flexibel gewalzte Band bei dort unterschiedlichen Banddicken sichergestellt werden.For a given length of the strip, which is guided by the galvanizing, it is known from the beginning, which strip lengths are thinly rolled during subsequent flexible rolling and which are thicker rolled. Since the rollers, which later take on the flexible rolling, are also controlled according to the length of the tape and is known at any time, which exact band section or which exact band length of the exact coil is running straight through the rollers, the same control is used to change the stripping nozzle pressure. Thus, different layer thicknesses of the galvanizing can be ensured in different areas of the strip. For example, in a region which is later rolled out particularly strongly, ie, thinly, the nozzle pressure is selected to be lower and thus less material is stripped off than in areas in which a lower degree of rolling is subsequently carried out. By this procedure, a uniform zinc layer thickness over the entire later flexible rolled strip can be ensured at different thicknesses there.
Das oben genannte Feuerverzinkungsverfahren kann selbstverständlich in gleicher Weise auch bei anderen Schmelztauchverzinkungen mit Erfolg eingesetzt werden, beispielsweise Feueraluminierungen oder Schmelztauchbeschichtungen aus Legierungen auf Basis von Aluminium oder Legierungen auf Basis von Zink sowie Legierungen aus anderen Metallen oder mit mehr Metallen als Zink und Aluminium.The abovementioned hot-dip galvanizing process can, of course, be used equally well in other hot-dip galvanizing applications, for example, fire aluminizing or hot-dip coatings of aluminum-based alloys or zinc-based alloys and alloys of other metals or more metals than zinc and aluminum.
Bei elektrolytischen Beschichtungen wird die aufzubringende Schichtdicke über die Stärke des elektrolytisch wirksamen Stromes und/oder die Bandgeschwindigkeit im elektrolytischen Beschichtungsbad gesteuert, wobei als Steuerung grundsätzlich ebenfalls die Steuerung verwendbar ist, mit welcher auch das lagegenaue Abweichen der unterschiedlichen Blechdicken beim flexiblen Walzen durchgeführt wird.In the case of electrolytic coatings, the layer thickness to be applied is controlled by the strength of the electrolytically active stream and / or the strip speed in the electrolytic coating bath, the control system basically also being used as the control with which the positionally accurate deviation of the different sheet thicknesses during flexible rolling is also carried out.
Nach dem Beschichten, wie z. B. dem Verzinken, kann sich das flexible Walzen anschließen, wobei beim flexiblen Walzen, wie bereits ausgeführt, unterschiedliche Blechdicken exakt bezüglich der Bandlänge positioniert erzielen lassen. Aus dem flexibel gewalzten Blech werden anschließend in an sich bekannter Weise Platinen geschnitten, die dem entsprechend auch den vorgegebenen Dickenverlauf über die Länge bzw. Breite besitzen. Diese Platinen mit unterschiedlichen Dickenprofilen werden dann erfindungsgemäß für eine Presshärtung verwendet.After coating, such. As galvanizing, the flexible rollers can follow, with the flexible rollers, as already stated, different thicknesses can be achieved exactly positioned with respect to the tape length. From the flexible rolled sheet blanks are then cut in a conventional manner, which accordingly also the predetermined Have thickness over the length or width. These boards with different thickness profiles are then used according to the invention for a press hardening.
Das Presshärten kann hierbei durch zwei unterschiedliche Verfahren realisiert werden.The press hardening can be realized by two different methods.
Bei einer ersten Möglichkeit werden die geschnittenen Platinen austenitisiert, d. h. einer Wärmebehandlung unterzogen, bei der abhängig vom Stahl eine Austenitumwandlung stattfindet. Anschließend wird die heiße Platine in ein Warmumformwerkzeug eingefügt, im Warmumformwerkzeug zum Bauteil umgeformt und gleichzeitig gekühlt. Die Kühlung erfolgt hierbei mit einer Temperatur, die über der kritischen Härtetemperatur liegt, so dass im Umformwerkzeug auch zeitgleich die Härtung stattfindet. Anschließend verlässt die gehärtete umgeformte Platine die Presse und kann gegebenenfalls noch nachgearbeitet werden oder ist bereits das Endprodukt.In a first possibility, the cut boards are austenitized, d. H. subjected to a heat treatment in which austenite conversion takes place depending on the steel. Subsequently, the hot board is inserted into a hot forming tool, formed in the hot forming tool to the component and cooled at the same time. The cooling takes place here with a temperature which is above the critical hardening temperature, so that the curing takes place simultaneously in the forming tool. Subsequently, the hardened formed board leaves the press and can optionally be reworked or is already the final product.
Bei einer zweiten Ausführungsform wird anstelle einer Warmumformung eine Formhärtung durchgeführt. Beim Formhärten wird die Platine kalt umgeformt. Vorzugsweise erfolgt diese kalte Umformung in alle drei Raumrichtungen bereits vollständig, ebenso der Beschnitt der Kanten und die Erzeugung eines Lochbildes. Vorzugsweise wird die Platine mit einem Untermaß von 0,5 bis 2 % in alle drei Raumrichtungen ausgeformt und anschließend austenitisiert. Bei der Austenitisierung wird durch die Wärmedehnung die Minderausformung um 0,5 bis 2 % kompensiert, so dass nach dem vollständigen planmäßigen Erhitzen die umgeformte Platine ihre Endgeometrie besitzt. Diese nun Endgeometrie oder Endkontur entsprechende Platine wird in ein Formhärtewerkzeug eingelegt, welches ebenfalls exakt die Kontur bzw. Geometrie des gewünschten Endbauteils besitzt. Das Bauteil wird in dem Formhärtewerkzeug zumindest im Bereich der besonders stark ausgeformten Bereiche formschlüssig gehalten, vorzugsweise vollständig formschlüssig gehalten, abgekühlt und durch das Abkühlen gehärtet.In a second embodiment, mold hardening is performed instead of hot working. When hardening the board is cold formed. Preferably, this cold transformation in all three spatial directions is already complete, as well as the trimming of the edges and the creation of a hole pattern. Preferably, the board is formed with an undersize of 0.5 to 2% in all three spatial directions and then austenitized. During austenitization, the thermal expansion compensates for the under-forming by 0.5 to 2%, so that after complete heating, the formed blank has its final geometry. This now final geometry or final contour corresponding board is inserted into a mold hardening tool, which also has exactly the contour or geometry of the desired end component. The component is in the mold hardening tool at least in the field of particularly strongly shaped areas held positively, preferably held completely positive fit, cooled and cured by cooling.
Anschließend wird das Bauteil als Endprodukt aus dem Formhärtewerkzeug entnommen.Subsequently, the component is removed as an end product from the mold hardening tool.
Wie bereits ausgeführt, findet eine Austenitisierung der Platinen statt. Hierbei wird die Platine bei den vorzugsweise verwendeten härtbaren Stählen vom Typ 22MnB5 auf etwa 900° bis 950°C erhitzt. Dadurch, dass die Platine unterschiedliche Blechdicken besitzt, entstehen auch im Blech unterschiedliche Wärmeverläufe bzw. Wärmebehandlungsprofile, welche letztlich in unterschiedlichen Temperaturen über die Länge bzw. Breite der Platine resultieren. Da eine vollständige Härtung angestrebt wird, müssen somit auch die Bereiche mit größeren Blechdicken zumindest die Austenitisierungstemperatur aufweisen. Dies führt jedoch dazu, dass die dünneren Bereiche quasi überhitzt werden. Durch diese unterschiedlichen Temperatur- bzw. Wärmebehandlungsprofile der unterschiedlichen Blechdickenbereiche der Platine über den gesamten Behandlungsprozess können unterschiedliche Härten bzw. Materialeigenschaften entstehen.As already stated, austenitization of the boards takes place. In this case, the board is heated to about 900 ° to 950 ° C in the preferably used hardenable steels type 22MnB5. Because the board has different sheet thicknesses, different heat profiles or heat treatment profiles also result in the sheet, which ultimately result in different temperatures over the length or width of the board. Since a complete hardening is desired, therefore, the areas with larger sheet thicknesses must at least have the austenitizing temperature. However, this leads to the fact that the thinner areas are virtually overheated. As a result of these different temperature or heat treatment profiles of the different sheet thickness ranges of the board over the entire treatment process, different hardnesses or material properties can arise.
Um dies zu verhindern bzw. zu vermindern, wird nach dem Verzinken und vor dem flexiblen Walzen oder nach dem flexiblen Walzen und vor dem Platinen schneiden die Oberfläche des Bandes beeinflusst.In order to prevent or reduce this, the surface of the strip is influenced after galvanizing and before the flexible rolling or after the flexible rolling and cutting in front of the sinker.
Die Oberflächenbehandlung des Bandes kann auf unterschiedliche Weisen erfolgen. Ziel der Oberflächenbehandlung ist es, die Emissivität bzw. die Absorption von Wärme bzw. von Wärmestrahlung zu beeinflussen. Hierdurch kann ein unterschiedlicher Zinkschichtdickeauftrag vor dem Walzen auch vermieden werden und lediglich durch die Oberflächebehandlung quasi gleiche Eigenschaften beim Glühen erzielt wurden.The surface treatment of the tape can be done in different ways. The aim of the surface treatment is to influence the emissivity or the absorption of heat or heat radiation. As a result, a different zinc layer thickness order before rolling can also be avoided and only by the surface treatment quasi-same properties were achieved during annealing.
Erfindungsgemäß kann dies durch eine Mattierungsbehandlung, ein Dressieren, d. h. eine Mikrokonturierung der Oberfläche, oder eine zusätzliche Beschichtung erfolgen.According to the invention, this can be achieved by a matting treatment, a skin pass, d. H. a micro-contouring of the surface, or an additional coating done.
Es ist somit möglich, die Bereiche, die beim flexiblen Walzen besonders stark gewalzt werden und später einen dünneren Bereich des Bandes ergeben, besonders stark reflektierend oder emittierend auszubilden, um beim Erhitzen für die Austenitisierung möglich wenig Wärme aufzunehmen.It is thus possible to form the regions which are particularly strongly rolled during flexible rolling and later produce a thinner region of the strip, in particular highly reflective or emitting form, in order to absorb a small amount of heat when heating for austenitizing.
Die Bereiche, die später nach dem flexiblen Walzen oder schon nach dem flexiblen Walzen dicker sind, können eine mattierte, wenig reflektierende bzw. dressierte Oberfläche erhalten oder mit einem temporären dunklen Schutzlack oder mit einer Metalloxid-Oberfläche versehen sein, welche eine besonders gute Aufnahme von Wärmestrahlung und somit eine gute Durchwärmung der dickeren Bereiche ermöglicht.The areas which are later thicker after flexible rolling or even after flexible rolling can be given a matted, low-reflecting or dressed surface or be provided with a temporary dark protective lacquer or with a metal oxide surface which provides a particularly good absorption of Thermal radiation and thus a good heating of the thicker areas allows.
Für die Oberflächenbehandlung wird grundsätzlich die gleiche Steuerung wie für das flexible Walzen oder das flexible Verzinken verwendet, so dass lagegenau und sehr korrekt die entsprechenden Bereiche in ihrer Oberflächenbeschaffenheit verändert werden können.For the surface treatment, the same control as for the flexible rolling or the flexible galvanizing is basically used, so that the corresponding areas in their surface condition can be changed precisely and very correctly.
Vorteil der Erfindung ist es, dass es gelingt, härtbare Stähle, die für die Härtung einer Wärmebehandlung unterzogen werden müssen, flexibel gewalzt und dennoch mit einer Korrosionsschutzschicht auszubilden, wobei Produkte mit einer großen Homogenität bezüglich der Materialeigenschaften erzielt werden. Zudem können mit diesem Verfahren in erheblich günstigerer Weise Blechbauteile erzielt werden.The advantage of the invention is that it is possible to flexibly roll hardenable steels, which have to be subjected to a heat treatment for the hardening, and nevertheless to form them with a corrosion protection layer, whereby products having a high homogeneity with respect to the material properties are obtained. In addition, sheet metal components can be obtained in a considerably more favorable manner with this method.
Die Erfindung ist hierbei nicht auf härtbare Stähle, beispielsweise vom Typ 22MnB5 beschränkt. Das flexible Verzinken bzw. Verzinken mit flexiblen Schichtdicken ist auch bei Stählen, die keine weitere Wärmebehandlung erfahren sollen, mit Erfolg anwendbar.The invention is not limited to hardenable steels, for example of the type 22MnB5. The flexible galvanizing or galvanizing with flexible layer thicknesses is also applicable to steels that should not undergo further heat treatment, with success.
Zudem ist es möglich, bei Stählen, die nach dem flexiblen Walzen einer Glühung unterzogen werden sollen, um ursprüngliche Materialeigenschaften wiederherzustellen, die flexibel gewalzten Stähle mit der erfindungsgemäßen flexiblen Verzinkung durch eine Kontiglühe zu führen, wobei durch die unterschiedlich eingestellten Emissivitäten der Oberflächen auch im Kontiglühverfahren eine sehr exakte homogene Materialeigenschaftenverteilung erzielt wird.In addition, it is possible for steels which are to be subjected to an annealing after flexible rolling in order to restore original material properties, to guide the flexibly rolled steels with the flexible galvanizing according to the invention by a continuous annealing, wherein the differently adjusted emissivities of the surfaces also in the continuous annealing a very exact homogeneous material properties distribution is achieved.
Claims (11)
- Method of producing a sheet metal part, wherein a hot- or cold-rolled strip is hot-dip coated or electrolytically coated and the hot- or cold-rolled strip thus coated is subjected to a flexible rolling process wherein, during the flexible rolling process, different roll pressures are used to create different sheet thicknesses of the flexibly rolled steel strip, characterised in that, geared to the sheet thickness after the flexible rolling and/or geared to the roll pressure during flexible rolling, the coating is applied with differing thickness, and depending on the roll pressure, with anticipated rising roll pressure the coating thickness during the coating process is greater before rolling and/or before or after flexible rolling the coating is subjected to mechanical or chemical surface treatment in the form of matting, cold-finishing or an additional coating to set a desired emissivity or heat absorption capacity.
- Method according to claim 1, characterised in that the coating thickness is set by the level of pressure of the gas flow in jet finishing nozzles of a hot-dip coating station.
- Method according to claim 1, characterised in that the coating thickness is set by a change in the electrolytically effective current strength and/or the line speed in the electrolytic bath.
- Method according to claim 1 or 2, characterised in that the coating thickness is set by means of an electromagnetic process or additionally by an electromagnetic process.
- Method according to any of the preceding claims, characterised in that the surface is coated so as to be matt or reflective or coloured or is cold-finished.
- Method according to any of the preceding claims, characterised in that, to control the coating thickness on the strip and/or to control the surface treatment, that control is used which is necessary to carry out the flexible rolling with exact positioning on the strip.
- Method according to any of the preceding claims, characterised in that a hardenable steel is used as steel material.
- Method according to any of the preceding claims, characterised in that a steel of type 22MnB5 is used.
- Method according to any of the preceding claims characterised in that, from the flexibly rolled steel material, formed depending on the steel material thickness with different coating thickness and/or surface treatments, circuit boards are cut and then austenitised, the austenitised hot circuit boards are hot-worked and cooled in the hot working tool and hardened by the cooling.
- Method according to any of claims 1 to 8, characterised in that circuit boards are cut from the flexibly rolled steel strip provided with a coating geared to the sheet thickness and if applicable with a surface treatment, and the circuit boards are then cold-worked, wherein the cold-worked circuit boards are then austenitised and the austenitised hot-worked circuit boards are placed in a press hardening tool, wherein the press hardening tool corresponds substantially to the contour or geometry of an end component and the hot-worked circuit board is held positively, cooled and hardened in the press hardening tool, at least in heavily worked areas.
- Method according to any of the preceding claims, characterised in that the coating applied is a hot-dip coating of zinc or based on zinc or a hot-dip coating of of aluminium or based on aluminium or an electrolytic coating of zinc or based on zinc.
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PCT/EP2008/000786 WO2008113426A2 (en) | 2007-03-22 | 2008-01-31 | Method for flexibly rolling coated steel strips |
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Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040138114A1 (en) | 2002-07-08 | 2004-07-15 | Genentech, Inc. | Compositions and methods for the treatment of immune related diseases |
KR101504370B1 (en) | 2007-02-23 | 2015-03-19 | 타타 스틸 이즈무이덴 베.뷔. | Method of thermomechanical shaping a final product with very high strength and a product produced thereby |
EP2171102B1 (en) * | 2007-07-19 | 2017-09-13 | Muhr und Bender KG | A strip of steel having a variable thickness in length direction |
JP2010533788A (en) * | 2007-07-19 | 2010-10-28 | コラス・スタール・ベー・ブイ | Method for annealing steel strips of varying thickness in the length direction |
EP2025771A1 (en) * | 2007-08-15 | 2009-02-18 | Corus Staal BV | Method for producing a coated steel strip for producing taylored blanks suitable for thermomechanical shaping, strip thus produced, and use of such a coated strip |
DE102009016852A1 (en) * | 2009-04-08 | 2010-10-14 | Bayerische Motoren Werke Aktiengesellschaft | Process for the preparation of heat-treated sheet metal parts from a steel sheet material with a corrosion protection coating and such sheet metal part |
DE102009050997B4 (en) * | 2009-10-28 | 2017-07-13 | Volkswagen Ag | Method and forming device for producing a form-hardened component |
DE102009051673B3 (en) * | 2009-11-03 | 2011-04-14 | Voestalpine Stahl Gmbh | Production of galvannealed sheets by heat treatment of electrolytically finished sheets |
ES2858225T3 (en) * | 2010-12-24 | 2021-09-29 | Voestalpine Stahl Gmbh | Procedure for producing tempered structural elements |
DE102011007937B4 (en) * | 2011-01-03 | 2015-09-10 | Benteler Automobiltechnik Gmbh | Method for producing a structural component of a motor vehicle body |
DE102012110972B3 (en) * | 2012-11-14 | 2014-03-06 | Muhr Und Bender Kg | A method of making a product from flexibly rolled strip material and product from flexibly rolled strip material |
EP2824213A1 (en) * | 2013-07-12 | 2015-01-14 | Voestalpine Stahl GmbH | Method for improving adherence to a steel sheet with a protective coating |
DE102014109315C5 (en) * | 2014-07-03 | 2022-02-24 | Thyssenkrupp Ag | Process for manufacturing metal profiles |
EP3265241B1 (en) * | 2015-03-06 | 2023-10-25 | Magna International Inc. | Tailored material properties using infrared radiation and infrared absorbent coatings |
DE102017110864B3 (en) | 2017-05-18 | 2018-10-18 | Voestalpine Metal Forming Gmbh | Method and device for producing hardened sheet steel components with different sheet thicknesses |
US11177763B2 (en) * | 2017-06-14 | 2021-11-16 | Thomas E. RUSSELL | Metallurgical steel post design for solar farm foundations and increased guardrail durability |
EP3790999B1 (en) * | 2018-05-08 | 2023-08-09 | Tata Steel IJmuiden B.V. | Variably rolled steel strip, sheet or blank and production method therefor |
CN108913867B (en) * | 2018-06-20 | 2019-12-24 | 银邦金属复合材料股份有限公司 | Method and system for continuously producing aluminum/stainless steel composite material |
DE102018118015A1 (en) * | 2018-07-25 | 2020-01-30 | Muhr Und Bender Kg | Process for producing a hardened steel product |
FR3088860B1 (en) | 2018-11-27 | 2020-10-30 | Psa Automobiles Sa | VEHICLE INCLUDING AN EXTERNAL OPENING CONTROL SCREWED ON AN ASPECT ELEMENT |
FR3097494B1 (en) | 2019-06-21 | 2024-06-07 | Psa Automobiles Sa | VEHICLE WING WITH FUSE ZONE FOR PROGRAMMED DEFORMATION |
CN111069331A (en) * | 2019-12-18 | 2020-04-28 | 南京工程学院 | Device and method for controlling shape gradient of ultrahigh-strength steel |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1675134A (en) * | 1924-10-04 | 1928-06-26 | Henry A Roemer | Metal-coated sheet and method of making the same |
US3251710A (en) * | 1963-03-04 | 1966-05-17 | Inland Steel Co | Apparatus and method for automatically controlling the removal of excess coating from running lengths of material |
US3667425A (en) * | 1971-03-01 | 1972-06-06 | Inland Steel Co | Apparatus for controlling coating thickness |
DE2345157C2 (en) * | 1973-09-07 | 1975-09-18 | August Thyssen-Huette Ag, 4100 Duisburg | Device for stripping metal when hot-metallizing metal strips |
US4390377A (en) * | 1981-01-12 | 1983-06-28 | Hogg James W | Novel continuous, high speed method of galvanizing and annealing a continuously travelling low carbon ferrous wire |
JPS5811770A (en) * | 1981-07-14 | 1983-01-22 | Nippon Steel Corp | Manufacture of molten aluminum plated steel plate with excellent corrosion resistance and plating adhesion |
JPH02254147A (en) * | 1989-03-27 | 1990-10-12 | Sumitomo Metal Ind Ltd | Method for controlling coating weight on hot dip metal coated steel sheet |
JPH02298244A (en) * | 1989-05-12 | 1990-12-10 | Nkk Corp | Method for continuously plating metal strip with molten metal |
JPH02298246A (en) * | 1989-05-12 | 1990-12-10 | Nkk Corp | Method for continuously plating metal strip with molten metal |
US5174822A (en) * | 1991-01-03 | 1992-12-29 | National Steel Corporation | Steel strip annealing and coating apparatus |
CA2085143C (en) * | 1991-12-13 | 1997-03-04 | Tomohiro Marui | Method and apparatus for process control of material emitting radiation |
JPH05165534A (en) * | 1991-12-13 | 1993-07-02 | Kawasaki Steel Corp | Method and device for process controlling |
JPH05164619A (en) * | 1991-12-16 | 1993-06-29 | Kawasaki Steel Corp | Continuous-material process controlling apparatus using radiation |
JP2799275B2 (en) * | 1993-02-26 | 1998-09-17 | 株式会社日立製作所 | Plating equipment and its operation method |
JPH111779A (en) * | 1997-06-11 | 1999-01-06 | Katayama Tokushu Kogyo Kk | Production of battery can forming material, and battery can forming material produced by this method |
DE19731124C1 (en) * | 1997-07-19 | 1999-01-21 | Schloemann Siemag Ag | Method and device for producing coated hot and cold strip |
ATE286789T1 (en) * | 1999-08-06 | 2005-01-15 | Muhr & Bender Kg | METHOD FOR FLEXIBLE ROLLING A METAL STRIP |
EP1074317B1 (en) | 1999-08-06 | 2005-02-16 | Muhr und Bender KG | Method for flexibly rolling a metal strip |
FR2807070B1 (en) * | 2000-03-28 | 2002-05-17 | Delot Process Sa | METHOD AND DEVICE FOR MAKING A METAL COATING ON AN OBJECT COMING OUT OF A BATH OF MELTED METAL |
DE10041280C2 (en) | 2000-08-22 | 2003-03-06 | Muhr & Bender Kg | Method and device for flexible rolling of a metal strip |
DE10049660B4 (en) * | 2000-10-07 | 2005-02-24 | Daimlerchrysler Ag | Method for producing locally reinforced sheet-metal formed parts |
JP4690558B2 (en) * | 2001-01-19 | 2011-06-01 | 新日本製鐵株式会社 | Ni-plated steel sheet for alkaline manganese battery positive electrode can excellent in battery characteristics and manufacturing method |
DE50101564D1 (en) * | 2001-09-29 | 2004-04-01 | Achenbach Buschhuetten Gmbh | Process for presetting and controlling the flatness of the strip during flexible one-way and reversing rolling of a strip-shaped material web |
JP2003268520A (en) * | 2002-03-08 | 2003-09-25 | Nippon Steel Corp | METHOD OF PRODUCING HOT DIP Sn-Zn PLATED STEEL HAVING EXCELLENT CORROSION RESISTANCE |
JP2004002918A (en) * | 2002-05-31 | 2004-01-08 | Sheng Yu Steel Co Ltd | Apparatus for continuously hot-dip plating steel strip |
DE10307184B3 (en) * | 2003-02-20 | 2004-04-08 | Benteler Automobiltechnik Gmbh | Production of hardened components used as aluminum vehicle parts comprises heating a metal sheet plate to a hardening temperature, hot deforming, configuring into a final shape, and hardening |
DE10333165A1 (en) * | 2003-07-22 | 2005-02-24 | Daimlerchrysler Ag | Production of press-quenched components, especially chassis parts, made from a semi-finished product made from sheet steel comprises molding a component blank, cutting, heating, press-quenching, and coating with a corrosion-protection layer |
KR100834555B1 (en) * | 2003-07-29 | 2008-06-02 | 뵈스트알파인 스탈 게엠베하 | Method for producing hardened parts from sheet steel |
JP4517687B2 (en) * | 2004-03-11 | 2010-08-04 | Jfeスチール株式会社 | Method for producing galvanized steel sheet |
DE102004023886B4 (en) * | 2004-05-12 | 2007-04-12 | Muhr Und Bender Kg | Method and device for finishing flexibly rolled strip material |
DE102005013103A1 (en) * | 2005-03-18 | 2006-09-28 | Sms Demag Ag | Controlled thickness reduction in hot-dip coated hot rolled steel strip and equipment used in this case |
JP4688100B2 (en) * | 2005-04-22 | 2011-05-25 | 日新製鋼株式会社 | Manufacturing method of Cu plated steel sheet for electrical contacts |
DE102005031461A1 (en) * | 2005-07-04 | 2007-01-11 | Bilstein Gmbh & Co. Kg | Method for producing micro alloyed cold rolled strip with varying thickness by two rolling and tempering processes |
-
2007
- 2007-03-22 DE DE102007013739A patent/DE102007013739B3/en active Active
-
2008
- 2008-01-31 WO PCT/EP2008/000786 patent/WO2008113426A2/en active Application Filing
- 2008-01-31 US US12/532,118 patent/US8522586B2/en active Active
- 2008-01-31 ES ES08707473T patent/ES2431939T3/en active Active
- 2008-01-31 JP JP2009553929A patent/JP5226017B2/en active Active
- 2008-01-31 EP EP08707473.8A patent/EP2044234B1/en active Active
Also Published As
Publication number | Publication date |
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EP2044234A2 (en) | 2009-04-08 |
WO2008113426A3 (en) | 2009-03-19 |
ES2431939T3 (en) | 2013-11-28 |
US20110132052A1 (en) | 2011-06-09 |
DE102007013739B3 (en) | 2008-09-04 |
JP5226017B2 (en) | 2013-07-03 |
JP2010521588A (en) | 2010-06-24 |
WO2008113426A2 (en) | 2008-09-25 |
US8522586B2 (en) | 2013-09-03 |
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