EP2026916A1 - Rolling stand for producing rolled strip or sheet - Google Patents
Rolling stand for producing rolled strip or sheetInfo
- Publication number
- EP2026916A1 EP2026916A1 EP07725995A EP07725995A EP2026916A1 EP 2026916 A1 EP2026916 A1 EP 2026916A1 EP 07725995 A EP07725995 A EP 07725995A EP 07725995 A EP07725995 A EP 07725995A EP 2026916 A1 EP2026916 A1 EP 2026916A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- rolls
- contour
- bale
- function
- roll
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005096 rolling process Methods 0.000 title claims abstract description 20
- 239000002184 metal Substances 0.000 claims abstract description 5
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 230000007704 transition Effects 0.000 claims abstract description 4
- 230000000295 complement effect Effects 0.000 claims description 29
- 230000007717 exclusion Effects 0.000 claims 1
- 238000009826 distribution Methods 0.000 abstract description 16
- 238000012886 linear function Methods 0.000 abstract 2
- 238000006073 displacement reaction Methods 0.000 description 11
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000010327 methods by industry Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B13/00—Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories
- B21B13/14—Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories having counter-pressure devices acting on rolls to inhibit deflection of same under load; Back-up rolls
- B21B13/142—Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories having counter-pressure devices acting on rolls to inhibit deflection of same under load; Back-up rolls by axially shifting the rolls, e.g. rolls with tapered ends or with a curved contour for continuously-variable crown CVC
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B13/00—Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories
- B21B13/02—Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories with axes of rolls arranged horizontally
- B21B2013/025—Quarto, four-high stands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B13/00—Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories
- B21B13/02—Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories with axes of rolls arranged horizontally
- B21B2013/028—Sixto, six-high stands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B27/00—Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
- B21B27/02—Shape or construction of rolls
- B21B27/021—Rolls for sheets or strips
- B21B2027/022—Rolls having tapered ends
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B27/00—Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
- B21B27/02—Shape or construction of rolls
- B21B27/021—Rolls for sheets or strips
Definitions
- Roll mill for the production of rolled strip or sheet metal
- the invention relates to a rolling stand for the production of rolled strip or sheet metal with work rolls, which are supported on support rolls or intermediate rolls and backup rolls, wherein the work rolls and / or intermediate rolls are arranged axially displaceable against each other in the rolling stand and each working and / or intermediate roll over the entire having effective bale length, curved, describable by a trigonometric function bale contour and complement these two bale contours complementary only in a certain relative axial position of the rollers of the roller pair in the unloaded state.
- a roll stand of the generic type is already known from AT 410765 B.
- the roll bale contour of these rollers known in the art under the name SmartCrown® is mathematically describable by a modified sine function. By a suitable choice of the contour parameters, this results in a cosinusoidal idling gap, which can be influenced in its amplitude by axial displacement of the rollers.
- the object of the present invention is therefore to avoid the disadvantages of the prior art described above and to propose a rolling stand, in which to minimize inhomogeneities in the load distribution along the line of contact of the support rollers and their adjacent rollers, and in particular to reduce local load peaks in the load distribution curve and thus the duration of use To increase the rollers and the necessary regrinding intervals.
- This object is achieved in a rolling stand of the type described above in that the support rollers have a complementary bale contour and in the unloaded state, a partial or complete complement of the bale contours of the support rollers and the immediately adjacent work rolls or intermediate rolls occurs.
- this partial or complete complement of the bale contours refers to the two back-up rolls and the respective adjacent work rolls.
- this partial or complete complement of the bale contours refers to the two back-up rolls and the respective adjacent intermediate rolls.
- the shortest possible displacement stroke of the work rolls is advantageous, since both the displacement time and the plant technology to be provided for sliding guides can be kept short.
- a short displacement stroke leads to larger diameter differences over the bale length occurring with a given profile adjustment range of the work rolls than with a longer displacement stroke.
- the rolls in the roll stand are aligned according to a possible embodiment of the invention so that a complete complement of the bale contours of the backing rolls and the immediately adjacent work rolls or intermediate rolls occurs in the unshifted state of the immediately adjacent work rolls or intermediate rolls.
- R B (X) support roller radius at the point x of the axial support roller extension
- R B (x) R 0 + kr B (x) with k contour factor (k ⁇ 1)
- the complete complement of the roll bale contours results.
- a complete completion of the roll bale contours is no longer possible.
- the contour factor may be greater or less than 1.
- bale ends of the rolls are usually chamfered and thus have an exemption in these edge regions.
- Exemptions of this type are already known from EP 0 258 482 A1 or EP 1 228 818 A2. These exemptions are formed in contoured roll bales in marginal areas with increasing towards the edge bale radius by a cylindrical bale end, as shown in EP 0 258 482 A1 or may be formed in rolls with cylindrical roll bale contour by a cone-shaped edge region, as for example in the EP 1 228 818 A2 is shown and described.
- the bale contour of the work rolls or of the intermediate rolls or of the support rolls in at least one of Edge regions of their longitudinal extent chamfers, which form in this border areas corrected bale contours, which result by subtracting any mathematical chamfering function of the contour function, the slope of the bale contour and the slope of the corrected bale contour in the transition point from the bale contour to the corrected bale contour are the same.
- FIG. 1 is a schematic representation of a four-high stand with contoured work rolls and cylindrical support rolls according to the prior art
- FIG. 2 shows the typical load distribution between work rolls and support rolls in a four-high stand according to FIG. 1, FIG.
- Fig. 3 is a schematic representation of a four-high stand with contoured work rolls and complementary back-up rolls according to the invention.
- FIG. 4 shows the typical load distribution between work rolls and support rolls in a four-high stand with the roll formation according to the invention according to FIG. 3, FIG.
- FIG. 5 is a schematic representation of a six-high stand with contoured backup rolls and complementary intermediate rolls according to the invention
- Fig. 7 shows the inventive contour of the upper support roller with a circular chamfer compared with a bale contour according to the prior art.
- FIGS. 1 to 4 the load distribution between back-up rolls and work rolls in a roll bale contour according to the prior art is compared with the load distribution between back-up rolls and work rolls in a roll bale contour according to the invention using the example of a four-high stand.
- the axially displaceable work rolls 1 each have a bale contour 3 that can be described by a modified sine function. These bale contours 3 complement each other in a certain relative axial position of the rolls of the pair of work rolls complementary.
- the work rolls 1 are supported by support rollers 2, which have a cylindrical bale contour 4 and are supported on the work rolls acting rolling forces.
- the load distribution between the upper work roll 1 and the upper support roll 2 is shown in Figure 2 for this case of roll barrel design, where the specific force between the rolls is plotted over the bale length and on the one hand load peaks in the edge region and, on the other hand, maximum and minimum values corresponding to the sinusoidal Contouring occur. For four selected values of the maximum relative axial displacement (displacement stroke) of the work rolls relative to each other, load distribution curves are shown.
- FIG. 3 shows a schematic representation of the roll arrangement in a four-high stand with work rolls 1 and support rolls 2.
- the axially displaceable work rolls 1 each have a bale contour 3 which can be described by a modified sine function, these bale contours being complementary in a specific relative axial position of the work rolls complete.
- the two support rollers 2 also have a complementary complementary bale contour 4, which is also formed by a modified sine function, the bale contours of the adjacent, cooperating work roll 1 and support roller 2 completely complement each other in an unloaded state.
- the load distribution between the upper work roll 1 and the upper backup roll 2 is shown in FIG. 4 for this case of the roll bale design. Load peaks in the edge area appear differently depending on the axial displacement. Altogether it shows over the rolling ball course at the However, the invention already a basic equalization of the load distribution.
- FIG. 5 shows, in a schematic arrangement, the roller arrangement in a six-high stand with work rolls 1, intermediate rolls 5 and support rolls 2, the work rolls being supported on the support rolls via the intermediate rolls.
- the work rolls 1 are equipped with a cylindrical bale contour 3.
- the bale contour of the work rolls can also be oriented to the bale contour of the adjacent intermediate rolls.
- the intermediate rollers 5 have a bale contour 6 that can be described by a modified sine function.
- the support rollers 2 have a bale contour 4 that can be described by a sine function.
- the bale contours 4 of the support rollers 2 and the bale contour of the intermediate rollers 5 complement each other completely in the unshifted axial position of the axially adjustable intermediate rollers 5 in the unloaded state.
- FIG. 7 shows the course of the roll bale contour 7 of a back-up roll or intermediate roll or work roll over the length of the bale.
- dash-dotted lines 8, 9 known from the prior art possibilities of chamfering a roller in the end regions are shown to avoid high edge pressures.
- the chamfering according to the dotted line 8 produces a cylindrical end portion and the chamfering corresponding to the dotted line 9 a cone-shaped end portion of the rollers, in both cases a kink 10 in the contour over the bale length occurs, which forms a circumferential edge on the roller.
- An improvement in the Loading conditions result from a chamfer gradually approaching chamfer, resulting in both sides of a corrected bale contour, which is illustrated by the dotted lines 11 and 12.
- both curves have the same slope as the tangent t.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
- Metal Rolling (AREA)
- Rolling Contact Bearings (AREA)
- Milling Processes (AREA)
- Straightening Metal Sheet-Like Bodies (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Control Of Metal Rolling (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL07725995T PL2026916T3 (en) | 2006-06-14 | 2007-06-13 | Rolling stand for producing rolled strip or sheet |
SI200731046T SI2026916T1 (en) | 2006-06-14 | 2007-06-13 | Rolling stand for producing rolled strip or sheet |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT10212006 | 2006-06-14 | ||
PCT/EP2007/005218 WO2007144162A1 (en) | 2006-06-14 | 2007-06-13 | Rolling stand for producing rolled strip or sheet |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2026916A1 true EP2026916A1 (en) | 2009-02-25 |
EP2026916B1 EP2026916B1 (en) | 2012-08-01 |
Family
ID=38430512
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07725995A Active EP2026916B1 (en) | 2006-06-14 | 2007-06-13 | Rolling stand for producing rolled strip or sheet |
EP07725994.3A Active EP2026915B2 (en) | 2006-06-14 | 2007-06-13 | Rolling stand for producing rolled strip or sheet |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07725994.3A Active EP2026915B2 (en) | 2006-06-14 | 2007-06-13 | Rolling stand for producing rolled strip or sheet |
Country Status (12)
Country | Link |
---|---|
US (2) | US8413476B2 (en) |
EP (2) | EP2026916B1 (en) |
CN (2) | CN101466483B (en) |
AT (1) | ATE488309T1 (en) |
BR (2) | BRPI0713145A2 (en) |
DE (1) | DE502007005682D1 (en) |
ES (2) | ES2392357T3 (en) |
PL (2) | PL2026915T5 (en) |
RU (2) | RU2428268C2 (en) |
SI (2) | SI2026916T1 (en) |
UA (2) | UA93090C2 (en) |
WO (2) | WO2007144161A1 (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2026916B1 (en) | 2006-06-14 | 2012-08-01 | Siemens VAI Metals Technologies GmbH | Rolling stand for producing rolled strip or sheet |
DE102009021414A1 (en) * | 2008-12-17 | 2010-07-01 | Sms Siemag Aktiengesellschaft | Roll stand for rolling a particular metallic Guts |
DE102010014867A1 (en) * | 2009-04-17 | 2010-11-18 | Sms Siemag Ag | Method for providing at least one work roll for rolling a rolling stock |
AT509107B1 (en) * | 2009-12-10 | 2011-09-15 | Siemens Vai Metals Tech Gmbh | ROLLING MILL FOR THE PRODUCTION OF ROLLING BAND |
WO2011094552A1 (en) * | 2010-02-01 | 2011-08-04 | The Timken Company | Unified rolling and bending process for large roller bearing cages |
DE102010029598A1 (en) * | 2010-06-01 | 2011-12-01 | ACHENBACH BUSCHHüTTEN GMBH | Back-up roll and thus equipped roll stand |
CN102397874A (en) * | 2010-09-16 | 2012-04-04 | 鞍钢股份有限公司 | Method for prolonging service life of high-speed steel roller |
DE102012212532B4 (en) | 2012-07-18 | 2016-12-15 | Achenbach Buschhütten GmbH & Co. KG | Roll stand with contoured rolls |
US10226188B2 (en) | 2013-08-23 | 2019-03-12 | Covidien Lp | Systems and methods for monitoring blood pressure |
EP3108978B1 (en) * | 2015-06-26 | 2019-02-20 | DANIELI & C. OFFICINE MECCANICHE S.p.A. | Rolling stand and rolling method |
EP3124130A1 (en) * | 2015-07-28 | 2017-02-01 | Primetals Technologies Austria GmbH | Roller grinder for targeted prevention of quarter waves |
DE102016222987A1 (en) * | 2016-11-22 | 2018-05-24 | Sms Group Gmbh | Method of grinding the contour of the bale of a roll |
CN113319128B (en) * | 2021-06-15 | 2021-12-14 | 北京科技大学 | Variable contact working roll and roll shape design method thereof |
Family Cites Families (28)
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JPS517635B2 (en) * | 1971-12-10 | 1976-03-09 | ||
JPS55103201A (en) | 1979-01-31 | 1980-08-07 | Nippon Kokan Kk <Nkk> | Rolling method for steel sheet |
JPS5630014A (en) | 1979-08-17 | 1981-03-26 | Kobe Steel Ltd | Rolling mill |
DE3213496A1 (en) | 1982-04-10 | 1983-10-20 | SMS Schloemann-Siemag AG, 4000 Düsseldorf | ROLLING MILLS WITH AXIAL SLIDING ROLLS |
US4519233A (en) * | 1980-10-15 | 1985-05-28 | Sms Schloemann-Siemag Ag | Roll stand with noncylindrical rolls |
DE3038865C1 (en) | 1980-10-15 | 1982-12-23 | SMS Schloemann-Siemag AG, 4000 Düsseldorf | Roll stand with axially movable rolls |
JPS5956905A (en) † | 1982-09-28 | 1984-04-02 | Kawasaki Steel Corp | Six-stages rolling mill for temper rolling |
DE3602698A1 (en) | 1985-04-16 | 1986-10-16 | SMS Schloemann-Siemag AG, 4000 Düsseldorf | ROLLING MILLS WITH AXIAL SLIDING ROLLS |
DE3620197A1 (en) | 1986-06-16 | 1987-12-17 | Schloemann Siemag Ag | ROLLING MILL FOR PRODUCING A ROLLING GOOD, ESPECIALLY A ROLLING STRIP |
DE3624241C2 (en) * | 1986-07-18 | 1996-07-11 | Schloemann Siemag Ag | Method for operating a rolling mill for producing a rolled strip |
DE3712043C2 (en) * | 1987-04-09 | 1995-04-13 | Schloemann Siemag Ag | Roll stand with axially displaceable rolls |
EP0401685B2 (en) | 1989-06-05 | 2000-03-08 | Kawasaki Steel Corporation | Multi-roll cluster rolling apparatus |
JPH0313218A (en) * | 1989-06-09 | 1991-01-22 | Kawasaki Steel Corp | Rolling mill |
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CN1062495C (en) * | 1995-11-10 | 2001-02-28 | 东北重型机械学院南校 | Roller shape of axial movement capable of changing roll pass concavity and shape |
RU2115493C1 (en) | 1997-06-04 | 1998-07-20 | Акционерное общество Новолипецкий металлургический комбинат | Roll assembly of four-high sheet rolling stand |
US6119500A (en) * | 1999-05-20 | 2000-09-19 | Danieli Corporation | Inverse symmetrical variable crown roll and associated method |
JP2001252705A (en) | 2000-03-10 | 2001-09-18 | Kobe Steel Ltd | Rolling mill and rolling method |
DE10037004B4 (en) | 2000-07-29 | 2004-01-15 | Sms Demag Ag | Roll stand for belt edge-oriented shifting of the intermediate rolls in a 6-roll stand |
DE10039035A1 (en) | 2000-08-10 | 2002-02-21 | Sms Demag Ag | Roll stand with a pair of CVC rolls |
DE10102821A1 (en) | 2001-01-23 | 2002-07-25 | Sms Demag Ag | Rolling mill used for producing planar strips comprises working rollers and support rollers axially arranged in a roll stand |
JP3747786B2 (en) * | 2001-02-05 | 2006-02-22 | 株式会社日立製作所 | Rolling method and rolling equipment for plate rolling machine |
EP1249801A1 (en) | 2001-04-12 | 2002-10-16 | Siemens Aktiengesellschaft | Differential, threshold-dependent behaviour of prepaid services |
AT410765B (en) | 2001-09-12 | 2003-07-25 | Voest Alpine Ind Anlagen | Roll stand for the production of rolled strip |
JP2005052864A (en) | 2003-08-04 | 2005-03-03 | Ishikawajima Harima Heavy Ind Co Ltd | Strip manufacturing facility |
DE10359402A1 (en) | 2003-12-18 | 2005-07-14 | Sms Demag Ag | Optimized shift strategies as a function of bandwidth |
WO2007014161A2 (en) | 2005-07-22 | 2007-02-01 | Sustainable Solutions, Inc. | Cotton fiber particulate and method of manufacture |
EP2026916B1 (en) | 2006-06-14 | 2012-08-01 | Siemens VAI Metals Technologies GmbH | Rolling stand for producing rolled strip or sheet |
-
2007
- 2007-06-13 EP EP07725995A patent/EP2026916B1/en active Active
- 2007-06-13 UA UAA200900146A patent/UA93090C2/en unknown
- 2007-06-13 EP EP07725994.3A patent/EP2026915B2/en active Active
- 2007-06-13 CN CN2007800221746A patent/CN101466483B/en active Active
- 2007-06-13 RU RU2009100920/02A patent/RU2428268C2/en active
- 2007-06-13 SI SI200731046T patent/SI2026916T1/en unknown
- 2007-06-13 AT AT07725994T patent/ATE488309T1/en active
- 2007-06-13 RU RU2009100918/02A patent/RU2442669C2/en active
- 2007-06-13 DE DE502007005682T patent/DE502007005682D1/en active Active
- 2007-06-13 SI SI200730509T patent/SI2026915T2/en unknown
- 2007-06-13 ES ES07725995T patent/ES2392357T3/en active Active
- 2007-06-13 ES ES07725994.3T patent/ES2355948T5/en active Active
- 2007-06-13 WO PCT/EP2007/005217 patent/WO2007144161A1/en active Application Filing
- 2007-06-13 BR BRPI0713145-3A patent/BRPI0713145A2/en not_active IP Right Cessation
- 2007-06-13 US US12/304,937 patent/US8413476B2/en not_active Expired - Fee Related
- 2007-06-13 CN CN2007800218283A patent/CN101511498B/en active Active
- 2007-06-13 UA UAA200815031A patent/UA92946C2/en unknown
- 2007-06-13 US US12/304,952 patent/US8881569B2/en not_active Expired - Fee Related
- 2007-06-13 WO PCT/EP2007/005218 patent/WO2007144162A1/en active Application Filing
- 2007-06-13 PL PL07725994T patent/PL2026915T5/en unknown
- 2007-06-13 PL PL07725995T patent/PL2026916T3/en unknown
- 2007-06-13 BR BRPI0713147-0A patent/BRPI0713147A2/en not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
See references of WO2007144162A1 * |
Also Published As
Publication number | Publication date |
---|---|
BRPI0713147A2 (en) | 2012-03-20 |
RU2009100918A (en) | 2010-07-20 |
UA92946C2 (en) | 2010-12-27 |
SI2026915T2 (en) | 2018-01-31 |
EP2026915B1 (en) | 2010-11-17 |
ES2392357T3 (en) | 2012-12-10 |
ES2355948T3 (en) | 2011-04-01 |
RU2442669C2 (en) | 2012-02-20 |
US8413476B2 (en) | 2013-04-09 |
ATE488309T1 (en) | 2010-12-15 |
PL2026915T5 (en) | 2018-08-31 |
US20090314047A1 (en) | 2009-12-24 |
US8881569B2 (en) | 2014-11-11 |
CN101466483A (en) | 2009-06-24 |
UA93090C2 (en) | 2011-01-10 |
WO2007144161A1 (en) | 2007-12-21 |
BRPI0713145A2 (en) | 2012-03-20 |
US20100031724A1 (en) | 2010-02-11 |
EP2026915B2 (en) | 2017-09-27 |
SI2026916T1 (en) | 2012-11-30 |
PL2026915T3 (en) | 2011-04-29 |
CN101511498B (en) | 2011-06-15 |
CN101511498A (en) | 2009-08-19 |
PL2026916T3 (en) | 2012-12-31 |
ES2355948T5 (en) | 2018-02-14 |
RU2428268C2 (en) | 2011-09-10 |
CN101466483B (en) | 2011-06-15 |
EP2026916B1 (en) | 2012-08-01 |
EP2026915A1 (en) | 2009-02-25 |
DE502007005682D1 (en) | 2010-12-30 |
SI2026915T1 (en) | 2011-03-31 |
RU2009100920A (en) | 2010-07-20 |
WO2007144162A1 (en) | 2007-12-21 |
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