EP2005851B1 - Shoe, in particular safety shoe or leisure shoe with anti-static function - Google Patents

Shoe, in particular safety shoe or leisure shoe with anti-static function Download PDF

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Publication number
EP2005851B1
EP2005851B1 EP08011000A EP08011000A EP2005851B1 EP 2005851 B1 EP2005851 B1 EP 2005851B1 EP 08011000 A EP08011000 A EP 08011000A EP 08011000 A EP08011000 A EP 08011000A EP 2005851 B1 EP2005851 B1 EP 2005851B1
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Prior art keywords
shoe
electrically conductive
channel
shoe according
foregoing
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German (de)
French (fr)
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EP2005851A1 (en
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Christoph Kronwitter
Joachim Kronwitter
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Priority claimed from DE200720008914 external-priority patent/DE202007008914U1/en
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    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B7/00Footwear with health or hygienic arrangements
    • A43B7/36Footwear with health or hygienic arrangements with earthing or grounding means

Definitions

  • the invention is based on a shoe, in particular a safety shoe or a leisure shoe with an antistatic function, according to the preamble of claim 1.
  • Safety shoes are often made entirely of plastic to meet the requirements of technological properties, hygiene and safety regulations. With such plastics, safety shoes can be provided from an antibacterial material which has stain-resistant properties and is machine washable. In addition, safety shoes made of plastic have good wearing properties and are characterized by a low weight. For example, polyurethane has prevailed as a material in safety shoe technology.
  • such material can be made antistatic by appropriate composition and thus a required technological property.
  • the often associated low resistance to abrasion, to heat and insufficient cut resistance are undesirable.
  • the latter properties in particular limit the scope of such shoes considerably.
  • a shoe having a multi-layered sole comprising a midsole of antistatic material and a durable outsole, the midsole being provided with guide bridges passing through the outsole.
  • an insole for a safety shoe to reduce the electrostatic charge of the shoe wearer.
  • the insole is penetrated by electrically conductive inserts which form a conductive connection between the foot of the shoe wearer resting against the upper side of the insole and an electrically conductive outsole of the shoe.
  • the inserts are formed from plugs of electrically conductive elastomeric material, preferably rubber or rubber, which pass through the insole, are provided exclusively in the forefoot region of the insole and terminate flush with the insole.
  • the WO 2005/122814 A as well as the DE 21 47 904 A disclose a safety shoe comprising a sole with a footrest and an outsole region, the footrest being formed integrally with the sole of a plastics material, at least one continuous "channel extending from the footrest to the outsole region being provided with one electrically conductive element Material is filled.
  • the object of the invention is to provide an improved safety shoe, which has antistatic properties and is particularly simple and inexpensive to produce.
  • An inventive safety shoe or leisure shoe with anti-static function comprises a sole with a footrest and an outsole area, wherein the footrest is formed integrally with the sole of a plastic, and wherein at least one continuous, ranging from the footrest to the outsole area channel is provided, with a electrically conductive material is filled.
  • a footrest below the area is referred to, on which the foot of the user rests directly.
  • the foot of the user is in direct electrical contact with the electrically conductive material, thereby preventing a static charge of the user in a simple manner.
  • the electrically conductive material is embedded in a casting material.
  • the electrically conductive material is encapsulated or encapsulated in the channel. This allows particularly rapid and inexpensive production processes such as injection molding. In addition, in this production method of great advantage that the electrically conductive material can be flush mounted in the channel, which increases the comfort while maintaining the favorable antistatic effect.
  • the electrically conductive material may preferably comprise antistatic fibers, in particular carbon fibers or a foam which contains carbon fibers, for example coated with carbon fibers. These may be embedded in the channel such that the carbon fibers are flush with both the foot-facing surface of the footrest and the floor-facing surface of the outsole region.
  • the conductive material formed of carbon fibers is favorably barely noticeable to the user and provides the required frictional contact with the ground on the tread surface of the outsole without creating a troublesome bump.
  • the electrically conductive material is formed from electrically conductive fibers, for example electrically conductive plastic fibers and / or a plastic filled with electrically conductive particles and / or a conductive fabric.
  • the channel may be punched out of the sole region of the shoe and filled with the conductive material in the manner of a plug.
  • the channel has a diameter of less than 1 cm, preferably about 5 mm, and is arranged perpendicularly between a plane of the footrest and a plane of the outsole region.
  • the plug formed from the conductive material has a dimension adapted to the diameter of the channel.
  • a channel may be formed per shoe, which is expediently arranged in the ball area in order to ensure the most secure possible ground contact.
  • two channels per shoe may be formed, wherein a first channel in the ball area and a second channel in the heel area is arranged.
  • a plurality of channels can be provided, which are distributed over the entire outsole area.
  • a designerischer effect can be achieved in addition.
  • a plastic may be provided, preferably a cushioning and shock-absorbing foam of closed cells, which is marketed in the US under the trade name "ComtoTek".
  • the entire shoe is preferably made in one piece from this material.
  • the structure of billions of small bubbles is preferably extremely resistant and abrasion-resistant, while providing a high level of comfort for the user with long durability of the sole.
  • all the requirements for a safety shoe are met with this base material, because the shoe is dirt-repellent and easy to clean, because he machine washable.
  • the shoe is advantageously non-slip, which can be additionally reinforced by a suitable structuring on the tread.
  • shoes made of this material conveniently leave no annoying marks on floor coverings.
  • the antistatic function according to the invention offers a particularly favorable and easy to produce additional function.
  • the electrically conductive material is formed from a carrier material formed from a silicone compound, for example from a silicone rubber, into which nano-graphite or graphite dust and / or graphite fibers is introduced as an electrically conductive admixture.
  • a carrier material formed from a silicone compound, for example from a silicone rubber
  • nano-graphite or graphite dust and / or graphite fibers is introduced as an electrically conductive admixture.
  • short graphite fibers can form a favorable contact bridge to the silicone compound.
  • nano-graphite or graphite dust are particularly advantageous bonding properties with the silicone rubber.
  • the graphite fibers are mixed with the carrier material, a felting of the graphite fibers is expediently produced in order to produce a conductive structure.
  • the fibers are wetted in a little time-consuming process step, mixed with a weak binder and then mechanically mixed.
  • the blending thus prepared conveniently produces a conductive matrix.
  • the thus formed electrically conductive admixture is then incorporated before vulcanization in the mass to be vulcanized and can be introduced as one-component or as a two-component material, wherein two-component means that before further processing, a curing agent is added, while added in the one-component material no hardener becomes.
  • the thus prepared material mixture can be introduced into the channel of the shoe, in particular injected.
  • An advantage of the injection method is that the material mixture is crosslinked or vulcanized in the mold. The material mixture thus beneficially assumes the shape of the channel or the recess. Another process step in the form of a gluing the conductive plug with the sole can be advantageously saved.
  • the compound thus formed is very homogeneous and has particularly favorable connection properties in the channel or with the sole. It is particularly advantageous that the type of support material, eg silicone rubber, with the introduced electrically conductive admixture is definable in such a way that both the density and the expansion factor (modulus of elasticity) are exactly matched to the material from which the shoe is made, can be adjusted.
  • this no longer leads to unwanted loosening of the plug from the channel, because any disadvantageous differences with respect to the density ratio and the elasticity of the plug and shoe material can be compensated.
  • the plug thus formed thus holds even heavy loads when using the shoe, for example by stretching and deformation, stood and remains safe and stable in the channel. Likewise, the tightness of the shoe is guaranteed even in continuous use.
  • Another advantage is that, depending on the addition of the electrically conductive admixture of the electrical resistance and thus the conductivity of the silicone rubber is adjustable. Unlike a solid material is in the presently adjustable material mixture is no longer dependent on predetermined physical properties of the introduced electrically conductive admixture, so that a need-based customization is possible.
  • the electrical volume resistance is thus advantageously metered.
  • an electrical resistance component with a body which represents a well-defined resistance introduced in the at least partially formed from the electrically conductive material plug.
  • a commercially available electrical component can be used, which can be suitably deformed, for example by bending and / or roles that it is adapted to the size of the channel. Subsequently, it is completely enveloped by the silicone rubber carrier material mixed with the electrically conductive admixture and introduced into the channel, as described above.
  • the electrical resistance component can be embedded or encapsulated in the electrically conductive material.
  • the component is thus arranged moisture-tight in the electrically conductive silicone mixture.
  • the body of the electrical resistance component may comprise a first and a second connection part, which is guided as close as possible to the surface of the plug.
  • an electrical parallel connection is thus produced between the plug and the resistance component. It is particularly advantageous because the electrical conductivity of the shoe is precisely controlled. In a possible interruption of the electric guide bridge formed by the plug in the sole can thus be favorably prevented that the electrical conductivity decreases seamlessly. In addition, the fact that the component is arranged in the plug, the wearing comfort of the shoe is not affected.
  • Fig. 1 shows a bottom view of a sole, in particular on an outsole region 12 of a safety shoe 10 with antistatic function
  • FIG. 2 is a sectional view of a safety shoe 10 along the line II-II in Fig. 1 shown.
  • the safety shoe 10 is made of a plastic and preferably formed in one piece. Both on the outsole region 12 and on the footrest 11 not shown corrugations may be provided, which provide a better grip and a high skid resistance.
  • two continuous channels 13a and 13b are provided, which extend from the footrest 11 to the outsole region 12, wherein the channels 13a and 13b are each filled with an electrically conductive material 14.
  • the electrically conductive material 14 comprises carbon fibers.
  • the channels 13a and 13b are each arranged perpendicularly between a plane of the footrest 11 and a plane of the outsole region 12 and, together with the conductive material 14, in each case form an electrical conductivity channel.
  • Each channel 13a, 13b is each formed so that the foot of the user is in direct electrical contact with the conductivity channel and thus avoids electrostatic charging of the shoe wearer.
  • the first channel 13a is provided in the heel area 16 and the second channel 13b is provided in the ball of the foot area 17.
  • Fig. 3 shows a particularly preferred embodiment of a arranged in a channel 13 of the shoe 10 plug 22, which is at least partially formed of a conductive material 14.
  • the channel 13 is arranged perpendicularly between a plane of the footrest 11 and a plane of the outsole region 12.
  • the plug 22 is flush with its surfaces with the levels of the footrest 11 and the outsole region 12 flush.
  • the plug 22 is formed in its upper region near the footrest and the lower region close to the outer surface of a conductive material 14, which consists of a carrier material of silicone rubber, in which, for example, graphite fibers are introduced as the conductive material 14.
  • the conductive material 14 is, for example, in the amount such that the plug 22 is set to low impedance.
  • a insulating or high-resistance layer 23 into which an electrical resistance component 18 with a body 19, which represents a well-defined ohmic resistance, is introduced.
  • the electrical resistance component 18 may be formed of ceramic, a metal or a plastic.
  • a resistance of the electrical resistance component 18 is defined in a desired ESD range (Electrostatic Discharge range) adjustable.
  • the insulating layer 23 may be formed of a non-conductive silicone rubber or a sealing ring.
  • the body 19 of the electrical resistance component 18 comprises, for example, a first connection part 20 and a second connection part 21, wherein the first and the second connection part 20 and 21 may be formed from a wire or a metallic surface.
  • the insulating layer 23 can be filled with the resistance component 18 in the full width of the channel 13.
  • the resistance component 18 can also be formed from a conductive foam element.

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  • Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

The shoe consists of a sole with a foot rest and outer sole area (12). The foot rest is formed as single piece with the sole which is made up of plastic. An integrated channel (13) is provided extending from the foot rest up to the outer sole area, which is filled with an electrically conducting material (14).

Description

Die Erfindung geht aus von einem Schuh, insbesondere einem Sicherheitsschuh oder einem Freizeitschuh mit einer Antistatikfunktion, nach dem Oberbegriff des Anspruchs 1.The invention is based on a shoe, in particular a safety shoe or a leisure shoe with an antistatic function, according to the preamble of claim 1.

Sicherheitsschuhe werden oft zur Gänze aus Kunststoff gefertigt, um den Anforderungen an technologische Eigenschaften, an die Hygiene sowie den Sicherheitsbestimmungen gerecht zu werden. Mit derartigen Kunststoffen können Sicherheitsschuhe aus einem antibakteriellen Material bereitgestellt werden, das schmutzabweisende Eigenschaften aufweist und waschmaschinengeeignet ist. Zudem haben Sicherheitsschuhe aus Kunststoff günstige Trageeigenschaften und zeichnen sich durch ein geringes Eigengewicht aus. Beispielsweise hat sich Polyurethan als Werkstoff in der Sicherheitsschuhtechnik durchgesetzt.Safety shoes are often made entirely of plastic to meet the requirements of technological properties, hygiene and safety regulations. With such plastics, safety shoes can be provided from an antibacterial material which has stain-resistant properties and is machine washable. In addition, safety shoes made of plastic have good wearing properties and are characterized by a low weight. For example, polyurethane has prevailed as a material in safety shoe technology.

Problematisch bei Schuhen aus einem derartigen Kunststoff sind die elektrostatische Aufladung des Schuhträgers sowie die Gefahr elektrischer Kurzschluss-Ströme durch den Schuhträger. Die damit einhergehenden Entladungen sind für den Schuhträger unangenehm und teilweise schmerzhaft. Besonders beim Arbeiten mit Halbleitern, Mikro-Chips, und anderen empfindlichen Bauteilen können statische Entladungen sogar schwerwiegende Folgen bis zur Bauteilzerstörung haben. Auch im Gesundheitsbereich wird mit sensitiven Geräten, insbesondere im OP-Bereich, gearbeitet, wo statische Entladungen zu Fehlfunktionen führen und Störungen mit fatalen Folgen hervorrufen können.The problem with shoes made of such a plastic, the electrostatic charge of the shoe wearer and the risk of electrical short-circuit currents through the shoe wearer. The associated discharges are uncomfortable for the wearer and sometimes painful. Especially when working with semiconductors, micro-chips, and other sensitive components, static discharges can even have serious consequences until component destruction. In the health sector too, sensitive devices are being used, especially in the surgical area, where static discharges can lead to malfunctions and cause disturbances with fatal consequences.

Zur Meidung von derartigen Entladungen kann ein solcher Werkstoff durch entsprechende Zusammensetzung antistatisch gemacht werden und dadurch eine geforderte technologische Eigenschaft aufweisen. Unerwünscht sind hingegen die häufig damit einhergehende geringe Widerstandsfähigkeit gegenüber Abriebbeanspruchung, gegenüber Hitze und die unzureichende Schnittfestigkeit. Gerade die letztgenannten Eigenschaften schränken aber den Anwendungsbereich derartiger Schuhe erheblich ein.To avoid such discharges such material can be made antistatic by appropriate composition and thus a required technological property. However, the often associated low resistance to abrasion, to heat and insufficient cut resistance are undesirable. However, the latter properties in particular limit the scope of such shoes considerably.

In der Gebrauchsmusterschrift DE 26 10 170 U1 beispielsweise wird ein Schuh mit einer mehrschichtigen Sohle vorgeschlagen, die eine Zwischensohle aus antistatischem Werkstoff sowie eine widerstandsfähige Laufsohle umfasst, wobei die Zwischensohle mit durch die Laufsohle hindurch tretenden Leitbrücken versehen ist.In the utility model DE 26 10 170 U1 For example, a shoe is proposed having a multi-layered sole comprising a midsole of antistatic material and a durable outsole, the midsole being provided with guide bridges passing through the outsole.

In der Gebrauchsmusterschrift DE 35 16 916 U1 ist eine Innensohle für einen Sicherheitsschuh zur Verringerung der elektrostatischen Aufladung des Schuhträges beschrieben. Die Innensohle wird von elektrisch leitenden Einsätzen durchsetzt, die eine leitende Verbindung zwischen dem auf der Oberseite der Innensohle anliegenden Fuß des Schuhträgers und einer elektrisch leitenden Laufsohle des Schuhs bilden. Es wird vorgeschlagen, dass die Einsätze aus Pfropfen aus elektrisch leitendem elastomeren Material, vorzugsweise Kautschuk oder Gummi, gebildet sind, welche die Innensohle durchsetzen, ausschließlich im VorderFuß-Bereich der Innensohle vorgesehen sind und bündig mit der Innensohle abschließen.In the utility model DE 35 16 916 U1 is described an insole for a safety shoe to reduce the electrostatic charge of the shoe wearer. The insole is penetrated by electrically conductive inserts which form a conductive connection between the foot of the shoe wearer resting against the upper side of the insole and an electrically conductive outsole of the shoe. It is proposed that the inserts are formed from plugs of electrically conductive elastomeric material, preferably rubber or rubber, which pass through the insole, are provided exclusively in the forefoot region of the insole and terminate flush with the insole.

Die WO 2005/122814 A wie auch die DE 21 47 904 A offenbaren einen Sicherheitsschuh, umfassend eine Sohle mit einer Fußauflage und einen Außensohlenbereich, wobei die Fußauflage einstückig mit der Sohle aus einem Kunststoff ausgebildet ist, wobei wenigstens ein durchgängiger" von der Fußauflage bis zum Außensohlenbereich reichender Kanal vorgesehen ist, der mit eine,m elektrisch leitfähigen Material gefüllt ist.The WO 2005/122814 A as well as the DE 21 47 904 A disclose a safety shoe comprising a sole with a footrest and an outsole region, the footrest being formed integrally with the sole of a plastics material, at least one continuous "channel extending from the footrest to the outsole region being provided with one electrically conductive element Material is filled.

Die Herstellung derartiger Schuhe bzw. Innensohlen zur Herstellung von Schuhen mit antistatischer Wirkung ist jedoch aufwändig und somit kostenintensiv.The production of such shoes or insoles for the production of shoes with antistatic effect, however, is complicated and thus costly.

Aufgabe der Erfindung ist es, einen verbesserten Sicherheitsschuh bereitzustellen, der antistatische Eigenschaften aufweist und besonders einfach und kostengünstig herstellbar ist.The object of the invention is to provide an improved safety shoe, which has antistatic properties and is particularly simple and inexpensive to produce.

Die Aufgabe wird erfindungsgemäß durch die Merkmale des Hauptanspruchs gelöst. Günstige Ausgestaltungen und Vorteile der Erfindung ergeben sich aus den weiteren Ansprüchen und der Beschreibung.The object is achieved by the features of the main claim. Favorable embodiments and advantages of the invention will become apparent from the other claims and the description.

Ein erfindungsgemäßer Sicherheitsschuh oder Freizeitschuh mit Antistatikfunktion umfasst eine Sohle mit einer Fußauflage und einen Außensohlenbereich, wobei die Fußauflage einstückig mit der Sohle aus einem Kunststoff ausgebildet ist, und wobei wenigstens ein durchgängiger, von der Fußauflage bis zum Außensohlenbereich reichender Kanal vorgesehen ist, der mit einem elektrisch leitfähigen Material gefüllt ist. Als Fußauflage wird nachfolgend der Bereich bezeichnet, auf dem der Fuß des Benutzers direkt aufliegt. Vorteilhafterweise steht der Fuß des Benutzers in direktem elektrischem Kontakt mit dem elektrisch leitfähigen Material, wodurch eine statische Aufladung des Benutzers auf einfache Art und Weise verhindert wird. Das elektrisch leitfähige Material ist in ein Gussmaterial eingebettet. Das elektrisch leitfähige Material ist im Kanal umspritzt oder umgossen. Dies erlaubt besonders rasche und günstige Produktionsverfahren wie beispielsweise Spritzgießen. Außerdem ist bei dieser Herstellungsart von großem Vorteil, dass das elektrisch leitfähige Material bündig in den Kanal eingebracht werden kann, was den Tragkomfort unter Aufrechterhaltung der günstigen antistatischen Wirkung erhöht.An inventive safety shoe or leisure shoe with anti-static function comprises a sole with a footrest and an outsole area, wherein the footrest is formed integrally with the sole of a plastic, and wherein at least one continuous, ranging from the footrest to the outsole area channel is provided, with a electrically conductive material is filled. As a footrest below the area is referred to, on which the foot of the user rests directly. Advantageously, the foot of the user is in direct electrical contact with the electrically conductive material, thereby preventing a static charge of the user in a simple manner. The electrically conductive material is embedded in a casting material. The electrically conductive material is encapsulated or encapsulated in the channel. This allows particularly rapid and inexpensive production processes such as injection molding. In addition, in this production method of great advantage that the electrically conductive material can be flush mounted in the channel, which increases the comfort while maintaining the favorable antistatic effect.

Bevorzugt kann das elektrisch leitfähige Material antistatische Fasern umfassen, insbesondere Kohlefasern oder einen Schaumstoff, der Kohlefasern enthält, z.B. mit Kohlefasern überzogen ist. Diese können in den Kanal derart eingebettet sein, dass die Kohlefasern sowohl mit der dem Fuß zugewandten Oberfläche der Fußauflage als auch an der dem Boden zugewandten Oberfläche des Außensohlenbereichs bündig abschließen. Somit ist das aus Kohlefasern gebildete leitfähige Material für den Benutzer günstigerweise kaum spürbar und stellt auf der Auftrittsfläche der Laufsohle den erforderlichen Reibekontakt mit dem Boden her, ohne dass eine störende Erhebung gebildet wird.The electrically conductive material may preferably comprise antistatic fibers, in particular carbon fibers or a foam which contains carbon fibers, for example coated with carbon fibers. These may be embedded in the channel such that the carbon fibers are flush with both the foot-facing surface of the footrest and the floor-facing surface of the outsole region. Thus, the conductive material formed of carbon fibers is favorably barely noticeable to the user and provides the required frictional contact with the ground on the tread surface of the outsole without creating a troublesome bump.

Es kann auch vorgesehen sein, dass das elektrisch leitfähige Material aus elektrisch leitfähigen Fasern, beispielsweise elektrisch leitenden Kunststofffasern und/oder einem mit elektrisch leitfähigen Partikeln gefüllten Kunststoff und/oder einem leitfähigen Gewebe gebildet ist.It can also be provided that the electrically conductive material is formed from electrically conductive fibers, for example electrically conductive plastic fibers and / or a plastic filled with electrically conductive particles and / or a conductive fabric.

Der Kanal kann aus dem Sohlenbereich des Schuhs ausgestanzt und mit dem leitfähigen Material in der Art eines Pfropfens gefüllt sein. In einer vorteilhaften Variante weist der Kanal einen Durchmesser von weniger als 1 cm, vorzugsweise etwa 5 mm, auf und ist senkrecht zwischen einer Ebene der Fußauflage und einer Ebene des Außensohlenbereichs angeordnet. Der aus dem leitfähigen Material gebildete Pfropfen weist eine Dimension auf, die an den Durchmesser des Kanals angepasst ist. Zusammen mit dem leitfähigen Material wird somit ein bevorzugter Leitfähigkeitskanal ausbildet, mit dem der Fuß des Benutzers beim bestimmungsgemäßen Tragen des Schuhs in elektrischem Kontakt steht.The channel may be punched out of the sole region of the shoe and filled with the conductive material in the manner of a plug. In an advantageous variant, the channel has a diameter of less than 1 cm, preferably about 5 mm, and is arranged perpendicularly between a plane of the footrest and a plane of the outsole region. The plug formed from the conductive material has a dimension adapted to the diameter of the channel. Thus, together with the conductive material, a preferred conductivity channel is formed with which the foot of the user is in electrical contact when the shoe is worn as intended.

In einer einfachen Ausführungsform kann ein Kanal pro Schuh ausgebildet sein, der zweckmäßigerweise im Ballenbereich angeordnet ist, um einen möglichst sicheren Bodenkontakt sicherzustellen. In einer bevorzugten Variante können zwei Kanäle pro Schuh ausgebildet sein, wobei ein erster Kanal im Ballenbereich und ein zweiter Kanal im Fersenbereich angeordnet ist.In a simple embodiment, a channel may be formed per shoe, which is expediently arranged in the ball area in order to ensure the most secure possible ground contact. In a preferred variant, two channels per shoe may be formed, wherein a first channel in the ball area and a second channel in the heel area is arranged.

Alternativ kann auch eine Vielzahl von Kanälen vorgesehen sein, die über den gesamten Außensohlenbereich verteilt sind. Bei einer regelmäßigen, musterartigen Verteilung kann dadurch zusätzlich ein designerischer Effekt erzielt werden.Alternatively, a plurality of channels can be provided, which are distributed over the entire outsole area. In a regular, pattern-like distribution, a designerischer effect can be achieved in addition.

Als Grundmaterial für den Schuh kann ein Kunststoff vorgesehen sein, bevorzugt aus einem dämpfenden und schockabsorbierenden Schaum aus geschlossenen Zellen, der in den USA unter dem Markennamen "ComtoTek" vertrieben wird. Der gesamte Schuh ist bevorzugt einstückig aus diesem Material hergestellt. Die Struktur aus Milliarden von kleinen Blasen ist vorzugsweise extrem resistent und abriebsfest und bietet bei langer Haltbarkeit der Sohle gleichzeitig einen hohen Tragekomfort für den Benutzer. Hinzu kommt günstigerweise, dass die Schuhe nur ein geringes Eigengewicht von etwa 180g pro Paar in Größe M aufweist. Gleichzeitig werden mit diesem Grundmaterial sämtliche Erfordernisse an einen Sicherheitsschuh erfüllt, denn der Schuh ist schmutzabweisend und einfach zu reinigen, weil er waschmaschinenfest ist. Darüber hinaus ist der Schuh vorteilhafterweise rutschsicher, was zusätzlich durch eine geeignete Strukturierung auf der Lauffläche verstärkt werden kann. Zudem hinterlassen Schuhe aus diesem Material günstigerweise keine lästigen Striemen auf Bodenbelägen. Die erfindungsgemäße Antistatikfunktion bietet eine besonders günstige und einfach herstellbare Zusatzfunktion.As the base material for the shoe, a plastic may be provided, preferably a cushioning and shock-absorbing foam of closed cells, which is marketed in the US under the trade name "ComtoTek". The entire shoe is preferably made in one piece from this material. The structure of billions of small bubbles is preferably extremely resistant and abrasion-resistant, while providing a high level of comfort for the user with long durability of the sole. In addition, it is favorable that the shoes have only a low weight of about 180g per pair in size M. At the same time all the requirements for a safety shoe are met with this base material, because the shoe is dirt-repellent and easy to clean, because he machine washable. In addition, the shoe is advantageously non-slip, which can be additionally reinforced by a suitable structuring on the tread. In addition, shoes made of this material conveniently leave no annoying marks on floor coverings. The antistatic function according to the invention offers a particularly favorable and easy to produce additional function.

In einer bevorzugten Weiterbildung ist das elektrisch leitfähige Material aus einem aus einer Silikonverbindung gebildeten Trägermaterial, beispielsweise aus einem Silikonkautschuk, gebildet, in das Nano-Graphit bzw. Graphitstaub und/oder Graphitfasern als elektrisch leitfähige Beimischung eingebracht wird. Insbesondere kurze Graphitfasern können eine günstige Kontaktbrücke zu der Silikonverbindung bilden. Denkbar ist auch das Einbringen von Nano-Graphit bzw. Graphitstaub. Dabei weisen Graphitfasern besonders vorteilhafte Verbindungseigenschaften mit dem Silikonkautschuk auf.In a preferred embodiment, the electrically conductive material is formed from a carrier material formed from a silicone compound, for example from a silicone rubber, into which nano-graphite or graphite dust and / or graphite fibers is introduced as an electrically conductive admixture. In particular, short graphite fibers can form a favorable contact bridge to the silicone compound. Also conceivable is the introduction of nano-graphite or graphite dust. In this case, graphite fibers have particularly advantageous bonding properties with the silicone rubber.

Bevor die Graphitfasern mit dem Trägermaterial vermengt werden, wird zweckmäßigerweise eine Verfilzung der Graphitfasern hergestellt, um eine leitfähige Struktur herzustellen. Vorteilhafterweise werden dabei in einem wenig zeitaufwändigen Verfahrensschritt die Fasern genetzt, mit einem schwachen Bindemittel versetzt und anschließend mechanisch vermengt. Durch die so hergestellte Vermengung wird günstigerweise eine leitfähige Matrix hergestellt. Die so gebildete elektrisch leitfähige Beimischung wird anschließend vor der Vulkanisation in die zu vulkanisierende Masse eingearbeitet und kann als einkomponentiges oder als zweikomponentiges Material eingebracht werden, wobei zweikomponentig bedeutet, dass vor der Weiterverarbeitung noch ein Härter zugesetzt wird, während bei dem einkomponentigen Material kein Härter zugesetzt wird.Before the graphite fibers are mixed with the carrier material, a felting of the graphite fibers is expediently produced in order to produce a conductive structure. Advantageously, the fibers are wetted in a little time-consuming process step, mixed with a weak binder and then mechanically mixed. The blending thus prepared conveniently produces a conductive matrix. The thus formed electrically conductive admixture is then incorporated before vulcanization in the mass to be vulcanized and can be introduced as one-component or as a two-component material, wherein two-component means that before further processing, a curing agent is added, while added in the one-component material no hardener becomes.

Anschließend kann die so zubereitete Materialmischung in den Kanal des Schuhs eingebracht, insbesondere eingespritzt, werden. Vorteilhaft bei dem Einspritzverfahren ist, dass die Materialmischung in der Form vernetzt bzw. vulkanisiert. Die Materialmischung nimmt somit günstigerweise die Form des Kanals bzw. der Ausnehmung an. Ein weiterer Verfahrensschritt in Form eines Verklebens des leitfähigen Pfropfens mit der Sohle kann dabei vorteilhafterweise eingespart werden. Zudem ist die so ausgebildete Verbindung sehr homogen und weist besonders günstige Verbindungseigenschaften in dem Kanal bzw. mit der Sohle auf. Besonders vorteilhaft ist, dass die Art des Trägermaterials, z.B. Silkonkautschuk, mit der eingebrachten elektrisch leitfähigen Beimischung in der Art definierbar ist, dass sowohl die Dichte als auch der Dehnungsfaktor (E-Modul) exakt auf das Material, aus dem der Schuh gefertigt ist, angepasst werden kann. Vorteilhafterweise kommt es dadurch nicht mehr zu einem ungewollten Lösen des Pfropfens aus dem Kanal, weil etwaige nachteilige Differenzen bezüglich des Dichteverhältnisses und der Elastizität von Pfropfen- und Schuhmaterial ausgeglichen werden können. Der so gebildete Pfropfen hält somit selbst starken Beanspruchungen bei Benutzung des Schuhs, beispielsweise durch Dehnen und Verformen, stand und verbleibt sicher und stabil im Kanal. Ebenso ist die Dichtigkeit des Schuhs auch in Dauergebrauch gewährleistet.Subsequently, the thus prepared material mixture can be introduced into the channel of the shoe, in particular injected. An advantage of the injection method is that the material mixture is crosslinked or vulcanized in the mold. The material mixture thus beneficially assumes the shape of the channel or the recess. Another process step in the form of a gluing the conductive plug with the sole can be advantageously saved. In addition, the compound thus formed is very homogeneous and has particularly favorable connection properties in the channel or with the sole. It is particularly advantageous that the type of support material, eg silicone rubber, with the introduced electrically conductive admixture is definable in such a way that both the density and the expansion factor (modulus of elasticity) are exactly matched to the material from which the shoe is made, can be adjusted. Advantageously, this no longer leads to unwanted loosening of the plug from the channel, because any disadvantageous differences with respect to the density ratio and the elasticity of the plug and shoe material can be compensated. The plug thus formed thus holds even heavy loads when using the shoe, for example by stretching and deformation, stood and remains safe and stable in the channel. Likewise, the tightness of the shoe is guaranteed even in continuous use.

Als weiterer Vorteil kommt hinzu, dass je nach Zugabe der elektrisch leitfähigen Beimischung der elektrische Widerstand und somit die Leitfähigkeit des Silikonkautschuks einstellbar ist. Anders als bei einem Festmaterial ist man bei der vorliegend einstellbaren Materialmischung nicht mehr auf vorgegebene physikalische Eigenschaften der einzubringenden elektrisch leitfähigen Beimischung angewiesen, so dass eine bedarfsgerechte individuelle Anpassung möglich ist. Der elektrische Durchgangswiderstand ist somit vorteilhafterweise dosierbar.Another advantage is that, depending on the addition of the electrically conductive admixture of the electrical resistance and thus the conductivity of the silicone rubber is adjustable. Unlike a solid material is in the presently adjustable material mixture is no longer dependent on predetermined physical properties of the introduced electrically conductive admixture, so that a need-based customization is possible. The electrical volume resistance is thus advantageously metered.

Bevorzugt wird ein Anteil von weniger als 10 Gew.% (Gewichtsprozent) der elektrisch leitfähigen Beimischung, insbesondere an Graphitfasern, in das Silikonmaterial eingebracht, besonders bevorzugt 1 - 3 Gew.%, Im Bereich von elektrisch leitfähigen Schuhen, die einen geringeren elektrischen Widerstand aufweisen als antistatische Schuhe, kann dieser Gewichtsanteil noch stärker variieren.A proportion of less than 10% by weight (weight percent) of the electrically conductive admixture, in particular of graphite fibers, is preferably introduced into the silicone material, more preferably 1-3% by weight, in the range of electrically conductive shoes having a lower electrical resistance As antistatic shoes, this weight percentage can vary even more.

In einer besonders bevorzugten Ausführungsform ist in dem zumindest teilweise aus dem elektrisch leitfähigen Material gebildeten Pfropfen ein elektrisches Widerstandsbauteil mit einem Körper, der einen genau definierten Widerstand darstellt, eingebracht. Hierfür kann ein handelsübliches elektrisches Bauteil verwendet werden, das geeignet verformt sein kann, beispielsweise durch Umbiegen und/oder Rollen, dass es an die Größe des Kanals angepasst ist. Anschließend wird es komplett von dem mit der elektrisch leitfähigen Beimischung versetzten Trägermaterial aus Silikonkautschuk umhüllt und in den Kanal eingebracht, wie oben beschrieben ist. Besonders bevorzugt kann das elektrische Widerstandsbauteil in das elektrisch leitfähige Material eingebettet oder gekapselt sein. Vorteilhafterweise ist das Bauteil somit feuchtedicht in der elektrisch leitfähigen Silikonmischung angeordnet. Der Körper des elektrischen Widerstandsbauteils kann ein erstes und ein zweites Anschlussteil umfassen, das möglichst nahe an die Oberfläche des Pfropfens geführt ist. Vorteilhafterweise wird somit eine elektrische Parallelschaltung zwischen dem Pfropfen und dem Widerstandsbauteil hergestellt. Besonders vorteilhaft daran ist, dass die elektrische Leitfähigkeit des Schuhs punktgenau steuerbar ist. Bei einer etwaigen Unterbrechung der durch den Pfropfen gebildeten elektrischen Leitbrücke in der Sohle kann somit günstigerweise verhindert werden, dass die elektrische Leitfähigkeit übergangslos abfällt. Außerdem wird dadurch, dass das Bauteil in dem Pfropfen angeordnet ist, der Tragkomfort des Schuhs nicht beeinträchtigt.In a particularly preferred embodiment, in the at least partially formed from the electrically conductive material plug, an electrical resistance component with a body which represents a well-defined resistance introduced. For this purpose, a commercially available electrical component can be used, which can be suitably deformed, for example by bending and / or roles that it is adapted to the size of the channel. Subsequently, it is completely enveloped by the silicone rubber carrier material mixed with the electrically conductive admixture and introduced into the channel, as described above. Particularly preferably, the electrical resistance component can be embedded or encapsulated in the electrically conductive material. Advantageously, the component is thus arranged moisture-tight in the electrically conductive silicone mixture. The body of the electrical resistance component may comprise a first and a second connection part, which is guided as close as possible to the surface of the plug. Advantageously, an electrical parallel connection is thus produced between the plug and the resistance component. It is particularly advantageous because the electrical conductivity of the shoe is precisely controlled. In a possible interruption of the electric guide bridge formed by the plug in the sole can thus be favorably prevented that the electrical conductivity decreases seamlessly. In addition, the fact that the component is arranged in the plug, the wearing comfort of the shoe is not affected.

Die Erfindung ist nachfolgend beispielhaft, ohne Beschränkung der Allgemeinheit, anhand von in Zeichnungen dargestellten Ausführungsbeispielen näher erläutert.The invention is described below by way of example, without limitation of generality, with reference to exemplary embodiments illustrated in drawings.

Es zeigen:

Fig.1
eine Unteransicht auf eine Laufsohle einer besonders günstigen Ausführungsform des erfindungsgemäßen Schuhs ,
Fig. 2
eine Schnittdarstellung gem. der Linie A-A in Fig. 1; und
Fig. 3
eine besonders bevorzugte Ausführungsform eines in einen Kanal des Schuhs angeordneten Pfropfens.
Show it:
Fig.1
a bottom view of an outsole of a particularly favorable embodiment of the shoe according to the invention,
Fig. 2
a sectional view acc. the line AA in Fig. 1 ; and
Fig. 3
a particularly preferred embodiment of a arranged in a channel of the shoe plug.

In den folgenden Figuren sind funktionell gleich wirkende Elemente jeweils mit gleichen Bezugszeichen beziffert.In the following figures, functionally identical elements are numbered with the same reference numerals.

Fig. 1 zeigt eine Unteransicht auf eine Sohle, insbesondere auf einen Außensohlenbereich 12 eines Sicherheitsschuhs 10 mit Antistatikfunktion, und in Fig. 2 ist eine Schnittdarstellung eines Sicherheitsschuhs 10 entlang der Linie II-II in Fig. 1 dargestellt. Fig. 1 shows a bottom view of a sole, in particular on an outsole region 12 of a safety shoe 10 with antistatic function, and in FIG. 2 is a sectional view of a safety shoe 10 along the line II-II in Fig. 1 shown.

Der Sicherheitsschuh 10 ist aus einem Kunststoff gefertigt und vorzugsweise einstückig ausgebildet. Sowohl auf dem Außensohlenbereich 12 als auch auf der Fußauflage 11 können nicht dargestellte Riffelungen vorgesehen sein, die für einen besseren Halt bzw. eine hohe Rutschfestigkeit sorgen.The safety shoe 10 is made of a plastic and preferably formed in one piece. Both on the outsole region 12 and on the footrest 11 not shown corrugations may be provided, which provide a better grip and a high skid resistance.

In dem Außensohlenbereich 12 sind zwei durchgängige, von der Fußauflage 11 bis zum Außensohlenbereich 12 reichende Kanäle 13a und 13b vorgesehen, wobei die Kanäle 13a und 13b jeweils mit einem elektrisch leitfähigen Material 14 gefüllt sind. Das elektrisch leitfähige Material 14 umfasst Kohlefasern. Die Kanäle 13a und 13b sind jeweils senkrecht zwischen einer Ebene der Fußauflage 11 und einer Ebene des Außensohlenbereichs 12 angeordnet ist und bilden zusammen mit dem leitfähigen Material 14 jeweils einen elektrischen Leitfähigkeitskanal aus. Jeder Kanal 13a, 13b ist jeweils so ausgebildet, dass der Fuß des Benutzers in direktem elektrischem Kontakt mit dem Leitfähigkeitskanal steht und somit eine elektrostatische Aufladung des Schuhträgers vermeidet.In the outsole region 12, two continuous channels 13a and 13b are provided, which extend from the footrest 11 to the outsole region 12, wherein the channels 13a and 13b are each filled with an electrically conductive material 14. The electrically conductive material 14 comprises carbon fibers. The channels 13a and 13b are each arranged perpendicularly between a plane of the footrest 11 and a plane of the outsole region 12 and, together with the conductive material 14, in each case form an electrical conductivity channel. Each channel 13a, 13b is each formed so that the foot of the user is in direct electrical contact with the conductivity channel and thus avoids electrostatic charging of the shoe wearer.

In einer bevorzugten Ausführungsform ist der erste Kanal 13a im Fersenbereich 16 und der zweite Kanal 13b im Fußballenbereich 17 vorgesehen.In a preferred embodiment, the first channel 13a is provided in the heel area 16 and the second channel 13b is provided in the ball of the foot area 17.

Fig. 3 zeigt eine besonders bevorzugte Ausführungsform eines in einem Kanal 13 des Schuhs 10 angeordneten Pfropfens 22, der zumindest teilweise aus einem leitfähigen Material 14 gebildet ist. Der Kanal 13 ist senkrecht zwischen einer Ebene der Fußauflage 11 und einer Ebene des Außensohlenbereichs 12 angeordnet. Der Pfropfen 22 schließt mit seinen Oberflächen mit den Ebenen der Fußauflage 11 und des Außensohlenbereichs 12 bündig ab. Der Pfropfen 22 ist in seinem oberen, fußauflagennahen Bereich und unteren, außensohlennahen Bereich aus einem leitfähigen Material 14 gebildet, das aus einem Trägermaterial aus Silikonkautschuk besteht, in das als leitfähiges Material 14 z.B. Graphitfasern eingebracht sind. Das leitfähige Material 14 ist, z.B. in der Menge so bemessen, dass der Pfropfen 22 niederohmig eingestellt ist. In einem mittleren Bereich des Pfropfens 22 ist eine isolierende oder hochohmige Schicht 23 angeordnet, in die ein elektrisches Widerstandsbauteil 18 mit einem Körper 19, der einen genau definierten ohmschen Widerstand darstellt, eingebracht ist. Das elektrische Widerstandsbauteil 18 kann aus Keramik, einem Metall oder auch aus einem Kunststoff gebildet sein. Ein Widerstand des elektrischen Widerstandsbauteils 18 ist in einem gewünschten ESD-Bereich (Electro-Static-Discharge-Bereich) definiert einstellbar. Die isolierende Schicht 23 kann aus einem nicht leitfähigen Silikonkautschuk oder einem Dichtungsring gebildet sein. Der Körper 19 des elektrischen Widerstandsbauteils 18 umfasst z.B. ein erstes Anschlussteil 20 und ein zweites Anschlussteil 21, wobei das erste und das zweite Anschlussteil 20 und 21 aus einem Draht oder einer metallischen Oberfläche gebildet sein können. Mit dieser Anordnung kann eine elektrische Parallelschaltung zwischen dem Pfropfen 22 und dem elektrischen Widerstandsbauteil 18 hergestellt werden, wodurch die elektrische Leitfähigkeit des Schuhs 10 durch das Widerstandsbauteil 18 punktgenau steuerbar ist. Bei einer etwaigen Unterbrechung der durch den Pfropfen 22 gebildeten Leitbrücke kann somit günstigerweise verhindert werden, dass die elektrische Leitfähigkeit übergangslos abfällt. Fig. 3 shows a particularly preferred embodiment of a arranged in a channel 13 of the shoe 10 plug 22, which is at least partially formed of a conductive material 14. The channel 13 is arranged perpendicularly between a plane of the footrest 11 and a plane of the outsole region 12. The plug 22 is flush with its surfaces with the levels of the footrest 11 and the outsole region 12 flush. The plug 22 is formed in its upper region near the footrest and the lower region close to the outer surface of a conductive material 14, which consists of a carrier material of silicone rubber, in which, for example, graphite fibers are introduced as the conductive material 14. The conductive material 14 is, for example, in the amount such that the plug 22 is set to low impedance. In a central region of the plug 22 is a insulating or high-resistance layer 23, into which an electrical resistance component 18 with a body 19, which represents a well-defined ohmic resistance, is introduced. The electrical resistance component 18 may be formed of ceramic, a metal or a plastic. A resistance of the electrical resistance component 18 is defined in a desired ESD range (Electrostatic Discharge range) adjustable. The insulating layer 23 may be formed of a non-conductive silicone rubber or a sealing ring. The body 19 of the electrical resistance component 18 comprises, for example, a first connection part 20 and a second connection part 21, wherein the first and the second connection part 20 and 21 may be formed from a wire or a metallic surface. With this arrangement, an electrical parallel connection between the plug 22 and the electrical resistance component 18 can be produced, as a result of which the electrical conductivity of the shoe 10 can be precisely controlled by the resistance component 18. In a possible interruption of the guide bridge formed by the plug 22 can thus be conveniently prevented that the electrical conductivity drops seamlessly.

In einer günstigen Variante kann die isolierende Schicht 23 in der vollen Breite des Kanals 13 mit dem Widerstandsbauteil 18 ausgefüllt sein. Das Widerstandbauteil 18 kann auch aus einem leitfähigen Schaumstoffelement gebildet sein. Somit liegen variablere Ausgestaltungsmöglichkeiten vor.In a favorable variant, the insulating layer 23 can be filled with the resistance component 18 in the full width of the channel 13. The resistance component 18 can also be formed from a conductive foam element. Thus, there are more variable design options.

BezugszeichenlisteLIST OF REFERENCE NUMBERS

1010
Sicherheitsschuhsafety Shoe
1111
Fußauflagefootrest
1212
AußensohlenbereichOutsole area
13a, 13b13a, 13b
Kanalchannel
1414
leitfähiges Materialconductive material
1616
Fersenbereichheel
1717
Fußballenbereichfootball field
1818
elektrisches Widerstandsbauteilelectrical resistance component
1919
Körperbody
2020
erstes Anschlusselementfirst connection element
2121
zweites Anschlusselementsecond connection element
2222
PfropfenGraft
2323
isolierende Schichtinsulating layer

Claims (12)

  1. Shoe (10), in particular a safety shoe or leisure shoe with anti-static function, comprising a sole having a foot support (11) and an exterior sole region (12), wherein the foot support (11) is formed together with the sole from a single piece of plastic material, wherein at least one continuous channel (13, 13a, 13b) extends from the foot support (11) through to the exterior sole region (12) and is filled with an electrically conductive material (14), characterised in that the electrically conductive material (14) is enclosed in the channel (13, 13a, 13b) by injection moulding or casting.
  2. Shoe according to Claim 1, characterised in that the electrically conductive material (14) is embedded in a casting material.
  3. Shoe according to one of the foregoing claims, characterised in that the channel (13, 13a, 13b) is formed in such a way that the foot of the user is in electrical contact with the channel (13, 13a, 13b).
  4. Shoe according to one of the foregoing claims, characterised in that two channels (13a, 13b) are formed, whereby the first channel (13a) is formed in the area of the heel (16) and the second channel (13b) is formed in the area of the ball of the foot (17).
  5. Shoe according to one of the foregoing claims, characterised in that several channels (13, 13a, 13b) are distributed over the whole of the exterior sole region (12).
  6. Shoe according to one of the foregoing claims, characterised in that the electrically conductive material (14) incorporates carbon fibres.
  7. Shoe according to one of the foregoing claims, characterised in that the electrically conductive material (14) consists of a plastic material filled with electrically conductive particles.
  8. Shoe according to one of the foregoing claims, characterised in that the electrically conductive material (14) consists of a carrier material composed of a silicone compound, into which an additive of electrically conductive graphite fibres and/or graphite dust has been incorporated.
  9. Shoe according to Claim 8, characterised in that the silicone compound that incorporates the graphite fibres and/or the graphite dust is vulcanised in the channel.
  10. Shoe according to one of Claims 8 or 9, characterised in that a proportion of less than 10% by weight, preferably of 1-3% by weight, of electrically conductive additive, particularly graphite fibres, is incorporated in the silicone compound.
  11. Shoe according to one of the foregoing claims, characterised in that an electrical resistor component (18) with a precisely defined ohmic resistance is incorporated in the plugs (22) that consist at least in part of electrically conductive material (14).
  12. Shoe according to one of the foregoing claims, characterised in that the material for the shoe (10) consists of a plastic material.
EP08011000A 2007-06-20 2008-06-18 Shoe, in particular safety shoe or leisure shoe with anti-static function Active EP2005851B1 (en)

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DE200720008914 DE202007008914U1 (en) 2007-06-20 2007-06-20 Shoe, in particular safety shoe with anti-static function
DE202008002745U DE202008002745U1 (en) 2007-06-20 2008-02-27 Shoe, in particular safety shoe or leisure shoe with anti-static function

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EP2005851B1 true EP2005851B1 (en) 2011-12-07

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CN104095345A (en) * 2014-06-27 2014-10-15 苏州市景荣科技有限公司 Anti-static positioning shoes with removable heels
WO2015100463A2 (en) 2014-01-02 2015-07-09 Huber Ski-Con Kg Anti-static sports equipment, sports system having an anti-static function and sports clothing system for a sports system
DE102019000109A1 (en) * 2019-01-09 2020-07-09 Kastriot Merlaku Device against muscle spasm

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EP2873339A1 (en) * 2013-11-18 2015-05-20 Wolfstar Clean room shoe sole
BE1022952B1 (en) * 2015-05-18 2016-10-21 Wolfstar Bvba Clean room shoe sole
WO2018039699A1 (en) 2016-08-30 2018-03-08 Ansell Limited Conductive soles for protective suits

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DE1983455U (en) * 1967-12-02 1968-04-11 Broederna Sandgrens Traetoffel SHOE.
DE2147904A1 (en) * 1971-09-24 1973-03-29 Reuter Maschinen Antistatic shoe - with cylindrical electrically conductive elements in the sole
DE2610170A1 (en) 1976-03-11 1977-09-22 Walter Huth SHOE, IN PARTICULAR SAFETY AND WORK SHOES, WITH ANTISTATIC SOLE
TR18700A (en) * 1977-02-21 1977-06-23 Y M Muehendisi Halit Fethi Cor CONDUCTIVE FOOT CLOTHES
DE8516916U1 (en) 1985-06-10 1985-07-25 Steinacker & Hartmann GmbH, 8860 Nördlingen Inner sole for a safety shoe
ES2093567B1 (en) * 1995-06-08 1997-07-01 Abad Rodriguez Francisco BIOELECTRIC DISCHARGER.
ITSV20040027A1 (en) * 2004-06-18 2004-09-18 Tn & Co Di Lucio Righetto ANTI-STATIC FOOTWEAR

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015100463A2 (en) 2014-01-02 2015-07-09 Huber Ski-Con Kg Anti-static sports equipment, sports system having an anti-static function and sports clothing system for a sports system
US10143262B2 (en) 2014-01-02 2018-12-04 Markus HARML Anti-static sports equipment, sports system having an anti-static function and sports clothing system for a sports system
EP3622841A1 (en) 2014-01-02 2020-03-18 Markus Harml Sports garment system with antistatic function for sports system
CN104095345A (en) * 2014-06-27 2014-10-15 苏州市景荣科技有限公司 Anti-static positioning shoes with removable heels
CN104095345B (en) * 2014-06-27 2015-12-30 谢雅聪 The dismountable antistatic shoe with positioning function of a kind of heel of a shoe
DE102019000109A1 (en) * 2019-01-09 2020-07-09 Kastriot Merlaku Device against muscle spasm

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DE202008002745U1 (en) 2008-05-08
ATE536110T1 (en) 2011-12-15

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