EP2001295B1 - Combinaisons de principes actifs a proprietes insecticides et acaricides - Google Patents

Combinaisons de principes actifs a proprietes insecticides et acaricides Download PDF

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Publication number
EP2001295B1
EP2001295B1 EP07723359A EP07723359A EP2001295B1 EP 2001295 B1 EP2001295 B1 EP 2001295B1 EP 07723359 A EP07723359 A EP 07723359A EP 07723359 A EP07723359 A EP 07723359A EP 2001295 B1 EP2001295 B1 EP 2001295B1
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EP
European Patent Office
Prior art keywords
spp
active compound
seed
formula
active
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EP07723359A
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German (de)
English (en)
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EP2001295A1 (fr
Inventor
Heike Hungenberg
Peter Jeschke
Reiner Fischer
Robert Velten
Thomas Schenke
Wolfram Andersch
Wolfgang Thielert
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Bayer CropScience AG
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Bayer CropScience AG
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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof

Definitions

  • the present invention relates to novel drug combinations containing at least one known compound from the class of tetronic or tetramic acids on the one hand and at least one other known active compound of formula (I) on the other hand and are very suitable for controlling animal pests such as insects and unwanted acarids.
  • Formula (II) therefore comprises the following compounds of the formula (IIa), (IIb) and (IIc) with the common names spirotetramat (IIa), spirodiclofen (IIb) and spiromesifen (IIc), the compound of the formula (IIa) in the cis configuration (cf. EP-A-01523472 ) or as a mixture of the cis and trans configuration:
  • active substance combinations containing at least one compound of the formula (I) and at least one compound of the formula (II) are synergistically active and are suitable for controlling animal pests.
  • insecticidal and acaricidal activity of the active ingredient combination according to the invention is substantially higher than the sum of the effects of the individual active ingredients. There is an unpredictable true synergistic effect and not just an effect supplement.
  • the active compound combinations according to the invention contain, in addition to at least one active substance of the formula (I), at least one of the active compounds of the formula (II).
  • the active compound combinations according to the invention preferably comprise one of the active compounds (Ia) or (Ib) and one of the active compounds of the formulas (IIa), (IIb) or (IIc).
  • Preference according to the invention is given to a mixture comprising the compound (Ia) and the compound (IIa), in particular the compound (IIa) -cis.
  • the combinations according to the invention contain an active compound of the formula (I) and an active compound of the formula (II) in the following preferred and particularly preferred mixing ratios: Preferred mixing ratio: 125: 1 to 1: 125 Particularly preferred mixing ratio: 25: 1 to 1:25
  • the mixing ratios are based on weight ratios.
  • the ratio is to be understood as the active ingredient of the formula (I): active compound of the formula (II).
  • arachnids e.g. Acarus siro, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp., Dermanyssus gallinae, Eotetranychus spp., Epitrimerus pyri, Eutetranychus spp.
  • Eriophyes spp. Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus mactans, Metatetranychus spp., Oligonychus spp., Omithodoros spp., Panonychus spp., Phyllocoptruta oleivora, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp. Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Stenotarsonemus spp., Tarsonemus spp., Tetranychus spp., Vasates lycopersici.
  • Ceuthorhynchus spp. Ceuthorhynchus spp., Cleonus mendicus, Conoderus spp., Cosmopolites spp., Costelytra zealandica, Curculio spp., Cryptorhynchus lapathi, Dermestes spp., Diabrotica spp., Epilachna spp., Faustinus cubae, Gibbium psylloides, Heteronychus arator, Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypothenemus spp., Lachnosterna consanguinea, Leptinotarsa decemlineata, Lissorhoptrus oryzophilus, Lixus spp., Lyctus spp., Meligethes aeneus, Melolontha melolontha, Migdolus spp., Mono
  • Gastropoda e.g. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Succinea spp.
  • helminths from the class of helminths, for example, Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Chabertia spp., Clonorchis spp., Cooperia spp., Dicrocoelium spp , Dictyocaulus filaria, Diphyllobothrium latum, Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Lo
  • protozoa such as Eimeria
  • Eimeria protozoa
  • Heliopeltis spp. Horcias nobilellus, Leptocorisa spp., Leptoglossus phyllopus, Lygus spp., Macropes excavatus, Miridae, Nezara spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., Psallus seriatus, Pseudacysta persea, Rhodnius spp. Sahlbergella singularis, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp.
  • Sogatella furcifera Sogatodes spp., Stictocephala festina, Tenalaphara malayensis, Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Trialeurodes vaporariorum, Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii.
  • Hymenoptera e.g. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
  • Orthoptera e.g. Acheta domesticus, Blatta orientalis, Blattella germanica, Gryllotalpa spp., Leucophaea maderae, Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria.
  • siphonaptera e.g. Ceratophyllus spp., Xenopsylla cheopis.
  • Symphyla e.g. Scutigerella immaculata.
  • Thysanoptera e.g. Basothrips biformis, Enneothrips flavens, Frankliniella spp., Heliothrips spp., Hercinothrips femoralis, Kakothrips spp., Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamoni, Thrips spp.
  • Thysanura e.g. Lepisma saccharina.
  • the plant parasitic nematodes include, for example, Anguina spp., Aphelenchoides spp., Belonoaimus spp., Bursaphelenchus spp., Ditylenchus dipsaci, Globodera spp., Heliocotylenchus spp., Heterodera spp., Longidorus spp., Meloidogyne spp., Pratylenchus spp., Radopholus similis, Rotylenchus spp., Trichodorus spp., Tylenchorhynchus spp., Tylenchulus spp., Tylenchulus semipenetrans, Xiphinema spp.
  • the active compound combinations according to the invention may optionally also be used in certain concentrations or application rates as herbicides, safeners, growth regulators or agents for improving plant properties, or as microbicides, for example as fungicides, antimycotics, bactericides, viricides (including anti-viral agents) or as anti-MLO agents ( Mycoplasma-like-organism) and RLO (Rickettsia-like-organism). If appropriate, they can also be used as intermediates or precursors for the synthesis of further active ingredients.
  • plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
  • Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights.
  • Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, examples of which include leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, as well as roots, tubers and rhizomes.
  • the plant parts also include crops and vegetative and generative propagation material, such as cuttings, tubers, rhizomes, offshoots and seeds.
  • the treatment according to the invention of the plants and plant parts with the active compound combinations takes place directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, evaporating, atomizing, spreading, brushing, injecting and in propagating material, in particular in seeds, further by single or multilayer coating.
  • the active compound combinations according to the invention are suitable for the treatment of seed.
  • the present invention therefore also relates, in particular, to a method for protecting seed and germinating plants from attack by pests by treating the seed with a combination of active substances according to the invention.
  • the method according to the invention for the protection of seeds and germinating plants from attack by pests comprises a method in which the seed is treated at the same time with an active compound of the formula I and an active compound of the formula II. It also includes a method in which the seed is treated at different times with an active ingredient of the formula I and an active ingredient of the formula II.
  • the invention also relates to the use of the active ingredient combinations according to the invention for the treatment of seed for the protection of the seed and the resulting plant from pests.
  • the invention relates to seed which has been treated for protection against pests with a combination of active substances according to the invention.
  • the invention also relates to seed which has been treated at the same time with an active compound of the formula I and an active compound of the formula II.
  • the invention further relates to seed which has been treated at different times with an active compound of the formula I and an active compound of the formula II.
  • the individual active compounds of the agent according to the invention can be present in different layers on the seed.
  • the layers containing an active ingredient of the formula I and an active ingredient of the formula II may optionally be separated by an intermediate layer.
  • the invention also relates to seed in which an active compound of the formula I and an active compound of the formula II are applied as a constituent of a coating or as a further layer or further layers in addition to a coating.
  • One of the advantages of the present invention is that because of the particular systemic properties of the active compound combinations according to the invention, the treatment of the seed with these active substance combinations not only the seed itself, but also the thereof Protected plants after emergence protects against pests. In this way, the immediate treatment of the culture at the time of sowing or shortly afterwards can be omitted.
  • Another advantage consists in the synergistic increase of the insecticidal activity of the active compound combinations according to the invention over the insecticidal single active substance, which goes beyond the expected efficacy of the two individually applied active ingredients. Also advantageous is the synergistic increase in the insecticidal activity of the active compound combinations according to the invention over the insecticidal single active substance, which goes beyond the expected effectiveness of the individually applied active ingredient. This allows optimization of the amount of active ingredients used
  • the active compound combinations according to the invention can be used in particular also in transgenic seed, wherein the plants resulting from this seed are capable of expressing a protein directed against pests.
  • certain pests can already be detected by the expression of e.g. insecticidal protein are controlled, and are additionally protected by the active compound combinations according to the invention from damage.
  • the active compound combinations according to the invention are suitable for the protection of seed of any plant variety as already mentioned above, which is used in agriculture, in the greenhouse, in forests or in horticulture.
  • these are corn, peanut, canola, rapeseed, poppy, soybean, cotton, turnip (eg sugarbeet and fodder beet), rice, millet, wheat, barley, oats, rye, sunflower, tobacco, potatoes or vegetables ( eg tomatoes, cabbage).
  • the active compound combinations according to the invention are likewise suitable for the treatment of the seed of fruit plants and vegetables as already mentioned above. Of particular importance is the treatment of the seeds of maize, soya, cotton, wheat and canola or rapeseed.
  • transgenic seed with a combination of active substances according to the invention is of particular importance.
  • the heterologous genes in transgenic seed can come from microorganisms such as Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma, Clavibacter, Glomus or Gliocladium .
  • the present invention is particularly useful for the treatment of transgenic seed containing at least one heterologous gene derived from Bacillus sp. and whose gene product shows activity against corn borer and / or corn rootworm. Most preferably, this is a heterologous gene derived from Bacillus thuringiensis .
  • the active ingredient combination according to the invention is applied to the seed alone or in a suitable formulation.
  • the seed is treated in a condition that is so stable that no damage occurs during the treatment.
  • the treatment of the seed can be done at any time between harvesting and sowing.
  • seed is used which has been separated from the plant and freed from flasks, shells, stems, hull, wool or pulp.
  • the amount of the active ingredient combination and / or other additives applied to the seed is chosen so that germination of the seed is not impaired or the resulting plant is not damaged. This is especially important for active ingredients, which can show phytotoxic effects in certain application rates.
  • the active compound combinations can be converted into the customary formulations, such as solutions, emulsions, wettable powders, water- and oil-based suspensions, powders, dusts, pastes, soluble powders, soluble granules, scattering granules, suspension-emulsion concentrates, active substance-impregnated natural products, active ingredient-impregnated synthetic substances, fertilizers and microencapsulation in polymeric substances.
  • customary formulations such as solutions, emulsions, wettable powders, water- and oil-based suspensions, powders, dusts, pastes, soluble powders, soluble granules, scattering granules, suspension-emulsion concentrates, active substance-impregnated natural products, active ingredient-impregnated synthetic substances, fertilizers and microencapsulation in polymeric substances.
  • formulations are prepared in a known manner, e.g. by mixing the active compounds with extenders, ie liquid solvents and / or solid carriers, if appropriate using surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents.
  • extenders ie liquid solvents and / or solid carriers
  • surface-active agents ie emulsifiers and / or dispersants and / or foam-forming agents.
  • Excipients which can be used are those which are suitable for imparting special properties to the active substance combination itself and / or preparations derived therefrom (for example spray liquor, seed dressing), such as certain technical properties and / or also particular biological properties.
  • Typical auxiliaries are: extenders, solvents and carriers.
  • Suitable extenders include, for example, water, polar and non-polar organic chemical liquids, for example from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (which may also be substituted, etherified and / or esterified ketones (such as acetone, cyclohexanone), esters (including fats and oils) and (poly) ethers, simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, sulfones and sulfoxides (such as dimethyl sulfoxide).
  • aromatic and non-aromatic hydrocarbons such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes
  • alcohols and polyols which may also be substituted, etherified and / or
  • Suitable liquid solvents are essentially: aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g.
  • Petroleum fractions mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethyl sulfoxide, and water.
  • Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids may be used in the formulations.
  • Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • additives may be fragrances, mineral or vegetable optionally modified oils, waxes and nutrients (also trace nutrients), such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • Stabilizers such as cold stabilizers, preservatives, antioxidants, light stabilizers or other chemical and / or physical stability-improving agents may also be present.
  • the formulations generally contain between 0.01 and 98% by weight of active ingredient, preferably between 0.5 and 90%.
  • the active compound combinations according to the invention can be present in commercially available formulations as well as in the formulations prepared from these formulations in admixture with other active ingredients, such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances or herbicides.
  • active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances or herbicides.
  • the insecticides include, for example, phosphoric acid esters, carbamates, carboxylic esters, chlorinated hydrocarbons, phenylureas, microorganism-produced substances and the like.
  • the active compound combinations according to the invention may also be present when used as insecticides in their commercial formulations as well as in the formulations prepared from these formulations in admixture with synergists.
  • Synergists are compounds that increase the effect of the active ingredients without the added synergist itself having to be active.
  • the active substance content of the application forms prepared from the commercial formulations can vary within wide ranges.
  • the active ingredient concentration of the use forms may be from 0.00000001 up to 95% by weight of active compound, preferably between 0.00001 and 1% by weight.
  • the application is done in a custom forms adapted to the application forms.
  • plants and their parts can be treated.
  • wild-type or plant species obtained by conventional biological breeding methods such as crossing or protoplast fusion
  • plant cultivars and their parts are treated.
  • transgenic plants and plant cultivars obtained by genetic engineering if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated.
  • the terms "parts” or “parts of plants” or “plant parts” have been explained above.
  • Plant varieties are understood as meaning plants having new traits which have been bred by conventional breeding, by mutagenesis or by recombinant DNA techniques. These can be varieties, biotypes and genotypes.
  • the treatment according to the invention may also give rise to superadditive ("synergistic") effects.
  • superadditive for example, reduced application rates and / or extensions of the spectrum of action and / or an increase in the effect of the substances and agents usable in the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering power facilitated harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or machinability of harvested products that go beyond the actual expected effects.
  • the preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits").
  • traits are better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or soil salinity, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher harvest value of the harvested products , higher shelf life and / or workability of the harvested products.
  • Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, such as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active substances.
  • transgenic plants are the important crops such as cereals (wheat, rice), corn, soybeans, potatoes, sugar beets, tomatoes, peas and other vegetables, cotton, tobacco, oilseed rape and fruit plants (with the fruits apples, pears, citrus fruits and Grapes), with special emphasis on maize, soya, potato, cotton, tobacco and oilseed rape.
  • Traits which are particularly emphasized are the increased defense of the plants against insects, arachnids, nematodes and snails by toxins which are formed in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (for example by the genes CryIA (a) , CryIA (b), CryIA (c), CryIIA, CryIIIA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CryIF and their combinations) in the plants (hereinafter "Bt plants”).
  • Traits also highlight the increased resistance of plants to fungi, bacteria and viruses by systemic acquired resistance (SAR), systemin, phytoalexins, elicitors and resistance genes and correspondingly expressed proteins and toxins. Traits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene). The genes which confer the desired properties (“traits”) can also occur in combinations with one another in the transgenic plants.
  • SAR systemic acquired resistance
  • PAT phosphinotricin
  • Bt plants are maize varieties, cotton varieties, soybean varieties and potato varieties which are sold under the trade names YIELD GARD® (eg corn, cotton, soya), KnockOut® (eg maize), StarLink® (eg maize), Bollgard® ( Cotton), Nucotn® (cotton) and NewLeaf® (potato).
  • YIELD GARD® eg corn, cotton, soya
  • KnockOut® eg maize
  • StarLink® eg maize
  • Bollgard® Cotton
  • Nucotn® cotton
  • NewLeaf® potato
  • herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties, which are sold under the trade names Roundup Ready® (tolerance to glyphosate eg corn, cotton, soy), Liberty Link® (tolerance to phosphinotricin, eg rapeseed), IMI® (tolerance against imidazolinone) and STS® (tolerance to sulfonylureas eg corn).
  • Roundup Ready® tolerance to glyphosate eg corn, cotton, soy
  • Liberty Link® tolerance to phosphinotricin, eg rapeseed
  • IMI® tolerance against imidazolinone
  • STS® tolerance to sulfonylureas eg corn
  • Clearfield® varieties eg corn
  • Trimenopon spp. Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp.
  • Nematocerina and Brachycerina e.g. Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota spp , Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Glossina spp., Chrysomyia spppp
  • siphonaptrida e.g. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.
  • heteropterid e.g. Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.
  • Actinedida Prostigmata
  • Acaridida eg Acarapis spp.
  • Cheyletiella spp. Cheyletiella spp., Ornitrocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp.
  • Tyrophagus spp. Caloglyphus spp., Hypodectes Spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.
  • the active compound combinations according to the invention are also suitable for controlling arthropods which are farm animals, such as e.g. Cattle, sheep, goats, horses, pigs, donkeys, camels, buffaloes, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as e.g. Dogs, cats, caged birds, aquarium fish and so-called experimental animals, such. Hamsters, guinea pigs, rats and mice.
  • arthropods are farm animals, such as e.g. Cattle, sheep, goats, horses, pigs, donkeys, camels, buffaloes, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as e.g. Dogs, cats, caged birds, aquarium fish and so-called experimental animals, such. Hamsters, guinea pigs, rats and mice.
  • the application of the active compound combinations according to the invention takes place in the veterinary sector and in animal husbandry in a known manner by enteral administration in the form of, for example, tablets, capsules, infusions, drenches, granules, pastes, boluses, the feed-through process, suppositories, by parenteral administration, as by injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), implants, by nasal application, by dermal application in the form of, for example, diving or bathing (dipping), spraying, pouring (pour-on and spot-on ), washing, powdering and with the aid of active substance-containing moldings, such as collars, ear tags, tail marks, limb bands, halters, marking devices, etc.
  • enteral administration in the form of, for example, tablets, capsules, infusions, drenches, granules, pastes, boluses, the feed-through process, suppositories
  • parenteral administration as by
  • the active ingredient combinations When used for livestock, poultry, pets, etc., the active ingredient combinations may be used as formulations (for example, powders, emulsions, flowables) containing the active ingredients in an amount of 1 to 80% by weight, directly or after 100 to 10,000 dilution or use as a chemical bath.
  • formulations for example, powders, emulsions, flowables
  • the active compound combinations according to the invention have a high insecticidal activity against insects which destroy industrial materials.
  • Non-living materials such as preferably plastics, adhesives, glues, papers and cardboard, leather, wood, wood processing products and paints.
  • the ready-to-use agents may optionally contain further insecticides and optionally one or more fungicides.
  • the active compound combinations according to the invention can be used to protect against fouling of objects, in particular of hulls, sieves, nets, structures, quayside facilities and signal systems, which come into contact with seawater or brackish water.
  • active compound combinations according to the invention can be used alone or in combinations with other active substances as antifouling agents.
  • Application is in aerosols, non-pressurized sprays, e.g. Pump and atomizer sprays, fog machines, foggers, foams, gels, evaporator products with evaporator plates made of cellulose or plastic, liquid evaporators, gel and membrane evaporators, propeller driven evaporators, energy-less or passive evaporation systems, moth papers, moth sacs and moth gels, as granules or dusts, in scattered edema or bait stations.
  • Pump and atomizer sprays e.g. Pump and atomizer sprays, fog machines, foggers, foams, gels, evaporator products with evaporator plates made of cellulose or plastic, liquid evaporators, gel and membrane evaporators, propeller driven evaporators, energy-less or passive evaporation systems, moth papers, moth sacs and moth gels, as granules or dusts, in scattered edema or bait stations.
  • a synergistic effect is always present in insecticides when the effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
  • Solvent 7 Parts by weight of dimethylformamide emulsifier: 2 Parts by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves Brassica oleracea
  • the green peach aphid Myzus persicae
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • the determined kill values are calculated according to the Colby formula (see page 1).
  • Solvent 7 Parts by weight of dimethylformamide emulsifier: 2 Parts by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves Brassica oleracea
  • Cabbage leaves Brassica oleracea
  • active compound of the desired concentration are treated by being dipped into the preparation of active compound of the desired concentration and are populated with larvae of the horseradish leaf beetle ( Phaedon cochleariae ) while the leaves are still moist.
  • the kill is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed.
  • the determined kill values are calculated according to the Colby formula (see page 1).

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pretreatment Of Seeds And Plants (AREA)

Abstract

L'invention concerne de nouvelles combinaisons de principes actifs qui contiennent au moins un composé connu de la classe des acides tétroniques ou des acides tétramiques, ainsi qu'au moins un autre principe actif connu de formule (I) dans laquelle R a les significations indiquées dans la description. Ces combinaisons permettent de lutter efficacement contre des animaux nuisibles tels que des insectes et des acariens indésirables.

Claims (12)

  1. Associations de substances actives, contenant au moins un composé de formule (I)
    Figure imgb0017
     dans laquelle
    R représente le groupe méthyle ou cyclopropyle,
    et au moins un composé choisi parmi le groupe constitué par spirotétramate (IIa), spirodiclofen (IIb) et spiromésifen (IIc) :
    Figure imgb0018
    Figure imgb0019
    Figure imgb0020
  2. Utilisation d'associations de substances actives, telles que définies dans la revendication 1, pour la lutte contre des ravageurs animaux.
  3. Procédé pour la lutte contre des ravageurs animaux, caractérisé en ce qu'on fait agir des associations de substances actives, telles que définies dans la revendication 1, sur des ravageurs animaux et/ou leur habitat et/ou des semences.
  4. Procédé selon la revendication 3, caractérisé en ce qu'on fait agir une substance active de formule I et une substance active de formule II en même temps sur des semences.
  5. Procédé selon la revendication 3, caractérisé en ce qu'on fait agir une substance active de formule I et une substance active de formule II à des moments différents sur des semences.
  6. Procédé pour la fabrication de produits insecticides et acaricides, caractérisé en ce qu'on mélange des associations de substances actives, telles que définies dans la revendication 1, avec des diluants et/ou des substances tensioactives.
  7. Utilisation d'une association de substances actives selon la revendication 1, pour le traitement de semences.
  8. Utilisation d'associations de substances actives selon la revendication 1, pour le traitement de plantes transgéniques.
  9. Utilisation selon la revendication 7, pour le traitement de semences de plantes transgéniques.
  10. Semence, qui contient une association de substances actives selon la revendication 1.
  11. Semence selon la revendication 10, qui a été traitée en même temps par une substance active de formule I et une substance active de formule II.
  12. Semence selon la revendication 10, qui a été traitée à des moments différents par une substance active de formule I et une substance active de formule II.
EP07723359A 2006-03-29 2007-03-19 Combinaisons de principes actifs a proprietes insecticides et acaricides Not-in-force EP2001295B1 (fr)

Applications Claiming Priority (2)

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DE102006014480A DE102006014480A1 (de) 2006-03-29 2006-03-29 Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
PCT/EP2007/002390 WO2007112845A1 (fr) 2006-03-29 2007-03-19 Combinaisons de principes actifs à propriétés insecticides et acaricides

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EP (1) EP2001295B1 (fr)
JP (1) JP2009531349A (fr)
KR (1) KR20080106351A (fr)
CN (1) CN101410013B (fr)
AR (1) AR060132A1 (fr)
AT (1) ATE518421T1 (fr)
BR (1) BRPI0709796A2 (fr)
DE (1) DE102006014480A1 (fr)
ES (1) ES2368792T3 (fr)
MX (1) MX2008012301A (fr)
TW (1) TW200812489A (fr)
WO (1) WO2007112845A1 (fr)

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DE102007045922A1 (de) * 2007-09-26 2009-04-02 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
EP2090168A1 (fr) * 2008-02-12 2009-08-19 Bayer CropScience AG Méthode destinée à l'amélioration de la croissance des plantes
EP2090167A1 (fr) * 2008-02-13 2009-08-19 Bayer CropScience AG Utilisation de dérivés d'acide tétramique pour lutter contre les zooparasites par traitement des troncs, branches, fleurs et bourgeons
US20110071220A1 (en) * 2008-03-27 2011-03-24 Bayer Cropscience Ag Use of Tetronic Acid Derivatives for Fighting Insects and Red Spider Mites by Watering on the Ground, Droplet Application or Immersion Application
EP2227951A1 (fr) * 2009-01-23 2010-09-15 Bayer CropScience AG Utilisation des composés d'énaminocarbonyle de combattre des virus transmis par les insectes
EP2232995A1 (fr) * 2009-03-25 2010-09-29 Bayer CropScience AG Procédé destiné à l'utilisation améliorée du potentiel de production de plantes transgéniques
AP3073A (en) * 2009-03-25 2014-12-31 Bayer Cropscience Ag Active ingredient combinations with insecticidal and acaricidal properties
CN101606521B (zh) * 2009-07-20 2012-12-05 深圳诺普信农化股份有限公司 一种增效杀螨剂
JP5614125B2 (ja) * 2010-06-28 2014-10-29 住友化学株式会社 有害節足動物防除組成物及び有害節足動物の防除方法
EP2648515A1 (fr) * 2010-12-09 2013-10-16 Bayer Intellectual Property GmbH Mélanges pesticides présentant des propriétés améliorées
BR112013014270A2 (pt) * 2010-12-09 2017-10-24 Bayer Ip Gmbh misturas inseticidas com propriedades aperfeiçoadas
PL2720543T3 (pl) 2011-06-14 2019-03-29 Bayer Cropscience Ag Zastosowanie związku enaminokarbonylowego w kombinacji ze środkiem kontroli biologicznej
CN102870793B (zh) * 2012-10-08 2014-01-22 谢玲艳 一种含螺虫乙酯和螺威的复配农药制剂及应用

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DE1953544A1 (de) 1969-10-24 1971-06-24 Winter & Sohn Ernst Halterung fuer Diamantwerkzeuge
EP0539588A1 (fr) * 1990-07-05 1993-05-05 Nippon Soda Co., Ltd. Derive d'amine
DE4216814A1 (de) * 1991-07-16 1993-01-21 Bayer Ag 3-aryl-4-hydroxy-(delta)(pfeil hoch)3(pfeil hoch)-dihydrofuranon- und 3-aryl-4-hydroxy-(delta)(pfeil hoch)3(pfeil hoch)-dihydrothiophenon-derivate
PL201168B1 (pl) * 1996-08-05 2009-03-31 Bayer Ag Podstawione fenyloketoenole, sposób wytwarzania tych związków, związki pośrednie, pestycydy i zastosowanie związków
DE19948590A1 (de) 1999-10-08 2001-04-12 Bayer Ag Wirkstoffkombination mit fungiziden und akariziden Eigenschaften
DE19953544A1 (de) * 1999-11-08 2001-05-10 Bayer Ag Wirkstoffkombinationen mit fungiziden und akariziden Eigenschaften
DE10013914A1 (de) * 2000-03-21 2001-09-27 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE10015310A1 (de) * 2000-03-28 2001-10-04 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE10017881A1 (de) 2000-04-11 2001-10-25 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE10035012A1 (de) * 2000-07-19 2002-01-31 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE102004047922A1 (de) * 2004-10-01 2006-04-06 Bayer Cropscience Ag Wirkstoffe für die Saatgutbehandlung

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US20100167923A1 (en) 2010-07-01
MX2008012301A (es) 2008-10-09
WO2007112845A1 (fr) 2007-10-11
CN101410013B (zh) 2013-03-20
ES2368792T3 (es) 2011-11-22
JP2009531349A (ja) 2009-09-03
EP2001295A1 (fr) 2008-12-17
TW200812489A (en) 2008-03-16
KR20080106351A (ko) 2008-12-04
DE102006014480A1 (de) 2007-10-04
ATE518421T1 (de) 2011-08-15
CN101410013A (zh) 2009-04-15
AR060132A1 (es) 2008-05-28
US8105979B2 (en) 2012-01-31

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