EP1983259A2 - Gestufte Kohlezuführung zur Verlässlichkeit und Emissionsreduktion eines Boilers - Google Patents
Gestufte Kohlezuführung zur Verlässlichkeit und Emissionsreduktion eines Boilers Download PDFInfo
- Publication number
- EP1983259A2 EP1983259A2 EP07112706A EP07112706A EP1983259A2 EP 1983259 A2 EP1983259 A2 EP 1983259A2 EP 07112706 A EP07112706 A EP 07112706A EP 07112706 A EP07112706 A EP 07112706A EP 1983259 A2 EP1983259 A2 EP 1983259A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- coal
- type
- zone
- burner
- combustion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003245 coal Substances 0.000 title claims abstract description 155
- 238000002347 injection Methods 0.000 title abstract description 8
- 239000007924 injection Substances 0.000 title abstract description 8
- 230000009467 reduction Effects 0.000 title description 5
- 238000002485 combustion reaction Methods 0.000 claims description 40
- 150000001875 compounds Chemical class 0.000 claims description 27
- 238000009841 combustion method Methods 0.000 claims description 24
- 239000003513 alkali Substances 0.000 claims description 14
- 239000002802 bituminous coal Substances 0.000 claims description 11
- 150000001805 chlorine compounds Chemical class 0.000 claims description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 8
- 239000000460 chlorine Substances 0.000 claims description 8
- 229910052801 chlorine Inorganic materials 0.000 claims description 8
- 238000003860 storage Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 30
- 238000010248 power generation Methods 0.000 abstract description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 29
- 230000015572 biosynthetic process Effects 0.000 description 11
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 10
- 229910052753 mercury Inorganic materials 0.000 description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 7
- 239000002245 particle Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000003546 flue gas Substances 0.000 description 5
- 230000001965 increasing effect Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- LWJROJCJINYWOX-UHFFFAOYSA-L mercury dichloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229960002523 mercuric chloride Drugs 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- -1 ash particles Chemical compound 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C6/00—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion
- F23C6/04—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection
- F23C6/045—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with staged combustion in a single enclosure
- F23C6/047—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with staged combustion in a single enclosure with fuel supply in stages
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D1/00—Burners for combustion of pulverulent fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2201/00—Staged combustion
- F23C2201/10—Furnace staging
- F23C2201/101—Furnace staging in vertical direction, e.g. alternating lean and rich zones
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2201/00—Staged combustion
- F23C2201/30—Staged fuel supply
- F23C2201/301—Staged fuel supply with different fuels in stages
Definitions
- the present invention relates to the field of power generation.
- the invention relates to a staged-coal injection procedure for coal-fired boilers used for power generation.
- PRB coal is relatively low in cost, has a low sulfur content, and is in reliable supply. It also has a higher reactivity than eastern bituminous coal due to a lower fixed carbon-to-volatile ratio. This results in lower NOx and UBC emissions.
- the volatile portion of PRB coal carries a significant amount of nitrogen, and under staged combustion, the volatiles are released early in the combustion process and burned in the overfire air zone, resulting in a lower potential to form NOx.
- PRB coal has a higher moisture content, a lower energy content, and a different ash composition than eastern bituminous coal.
- the higher moisture content and lower energy content results in the need to burn larger quantities of PRB coal than eastern bituminous coal to produce the same amount of energy.
- Blending PRB coal and eastern bituminous coal provides the added energy content of the eastern bituminous coal, the lower NOx and UBC emissions of PRB coal, and a reduction in ash deposition.
- boiler tube fireside corrosion can be a significant problem due to the formation of alkali chloride compounds which attach to the boiler tube surface, especially in a reducing environment such as that caused by staged combustion. The deposition of these compounds also subtracts from the formation of oxidized mercury (HgCl 2 ), which is important to facilitate the downstream removal of mercury. By minimizing the formation of alkali chlorides, more chloride may be available to form mercuric chloride in the flue gas.
- UBC unburned carbon
- a coal combustion method including the steps of combusting a first type of coal in a first zone of a furnace, and combusting a second type of coal in a second zone of the furnace, the second zone being at a position above the first zone.
- the first type of coal has a high alkali content.
- the second type of coal has a high chlorine content.
- the method includes the steps of feeding the first type of coal to fed to a first burner for combustion in the first zone of the furnace, and feeding the second type of coal to a second burner for combustion in the second zone of the furnace.
- the first burner is optimized to combust the first type of coal and the second burner is optimized to combust the second type of coal.
- a coal combustion method includes the steps of providing a first type of coal including a selected first compound; providing a second type of coal including a selected second compound; combusting the first type of coal in a first zone of a furnace; and combusting the second type of coal in a second zone of the furnace.
- the first and second zones are positioned so as to substantially prevent the first compound from combining with the second compound during combustion of the first and second types of coals.
- the first compound is an alkali compound and the second compound is a chloride compound.
- the method includes the steps of feeding the first type of coal to a first burner for combustion in the first zone and feeding the second type of coal to a second burner for combustion in the second zone.
- the method includes the step of providing combustion air to the first burner and second burner. According to another preferred embodiment of the invention, the amount of combustion air provided to the first burner is less than the amount of air provided to the second burner.
- the method includes the step of providing overfire air in a third zone of the furnace to aid in complete combustion of the first type of coal and second type of coal.
- a coal combustion method includes the steps of providing a boiler having a furnace section, a first burner positioned in a first zone of the furnace section, and a second burner positioned in a second zone of the furnace section.
- the method further includes the steps of feeding a first type of coal including a selected first compound to the first burner, combusting the first type of coal in a first zone of the furnace section, feeding a second type of coal to the second burner, and combusting the second type of coal in a second zone of the furnace section.
- the first compound is consumed in the first zone so as to be substantially unavailable for reaction in the second zone.
- the first type of coal is a Powder River Basin coal.
- the first compound is an alkali compound.
- the second type of coal is an eastern bituminous coal.
- the second compound is a chloride compound.
- the method includes the step of feeding the first type of coal from a first storage hopper to a first pulverizer where the first type of coal is pulverized.
- the method includes the step of feeding the second type of coal from a second storage hopper to a second pulverizer where the second type of coal is pulverized.
- the method includes the step of providing a combustion air to the first burner, second burner, and an overfire port.
- the amount of combustion air provided to the first burner is less than the amount of air provided to the second burner.
- the overfire port introduces combustion air into a third zone of the furnace to aid in complete combustion of the first and second types of coal.
- Figure 1 shows a prior art staged-coal boiler
- Figure 2 shows a staged-coal boiler adapted to use a staging procedure according to an embodiment of the invention.
- Figure 3 is schematic of the staging procedure for the staged-coal boiler of Figure 1.
- the boiler 10 includes a hopper 11 for storing and feeding coal to a pulverizer 12, a blower 13 for delivering the pulverized coal and transport air (primary air) mix and secondary combustion air to a burner 16, a furnace section 17 for combusting the coal therein, a boiler tube section 18 for absorbing heat created by the combustion of the coal to create steam, and an economizer and bag section 20 for cooling the flue gas exiting the furnace section 17 and collecting ash particles.
- a hopper 11 for storing and feeding coal to a pulverizer 12
- a blower 13 for delivering the pulverized coal and transport air (primary air) mix and secondary combustion air to a burner
- a furnace section 17 for combusting the coal therein
- a boiler tube section 18 for absorbing heat created by the combustion of the coal to create steam
- an economizer and bag section 20 for cooling the flue gas exiting the furnace section 17 and collecting ash particles.
- the boiler 10 uses an air staging procedure by introducing overfire air through an overfire air port 14 into the furnace section 17 in a region above the burner 16.
- combustion air provided by blower 13 is separated into primary (for coal transport), secondary (main burner), and tertiary (overfire) air flows. This encourages complete burnout and the formation of N2 instead of NOx.
- the combustion air may be separated into 70%-90% primary and secondary air and 10%-30% overfire or tertiary air.
- the primary and secondary air is mixed with the coal at the burner to produce a relatively low temperature, oxygen deficient, fuel rich zone that creates moderate amounts of NOx.
- the overfire or tertiary air is injected above the combustion zone where combustion is completed at an increased flame volume that limits the production of NOx.
- a staged-coal boiler adapted to use a staging procedure is illustrated and shown generally at reference numeral 100. While the staging procedure is being discussed with a pulverized coal-type boiler, it should be appreciated that the staging procedure may be used with other suitable boilers, and that the pulverized coal-type boiler is being used as an example boiler for discussion purposes only.
- the boiler 100 includes a pair of coal hoppers 110 and 111 for storing and feeding coal to pulverizers 112 and 113, respectively.
- the pulverizers 112 and 113 pulverize the coal for delivery to burners 114 and 115.
- the coal is delivered to the burners 114 and 115 by a portion of the forced air from blowers 117 and 118 where the coal is mixed with the air from the blowers 117 and 118 in the burners 114 and 115 to combust the coal within a furnace section 120 of the boiler 100.
- the blowers also provide overfire air through an overfire air port 125 for complete burnout. Heat created by the burners 114 and 115 in the furnace section 120 is absorbed by a boiler tube section 121 to create steam. Flue gas, including ash particles, exits the furnace section 120 and into an economizer and bag section 124 where the flue gas is cooled and the ash particles are collected.
- the boiler 100 uses a combination of air staging, like that discussed with reference to Figure 1, and fuel staging to minimize Nox formation, fireside corrosion and mercury (by maximizing mercury oxidation and PRB based carbon). This is done by injecting different types of coal at different levels/stages of the furnace section 120 as well as controlling the coal feed rates and size distribution.
- coal hopper 110 contains a higher chloride coal "C1" (such as eastern bituminous coal) and coal hopper 111 contains a more reactive coal "C2" with higher alkali and lower chloride content (such as PRB coal).
- the higher chlorine coal C1 is delivered to pulverizer 112 where it is pulverized and delivered via a portion of the blower air to burner 114 for combustion.
- the more reactive coal C2 is delivered to pulverizer 113 where it is pulverized and delivered by a portion of the blower air to burner 115 for combustion.
- the more reactive coal C2 with higher alkali but low chlorine content is injected at a lower, deeper staged level of the furnace section 120 while the higher chloride coal C1 is injected into an upper staged level of the furnace section 120.
- the separation of the chlorides and alkali compounds can be seen in the flow of ash particles "AP1" and "AP2" of coals C1 and C2, respectively.
- the ash particles AP2 deposit on a lower section of a waterwall 123 of the furnace section 120 and the ash particles AP1 deposit on a higher section of the waterwall 123.
- Flue gas flows "F1", “F2”, and "F3" are also shown exiting the furnace section 120.
- the amount of combustion air being used in the burners 114 and 115 is also different at the lower and upper staged levels of the furnace section 120.
- the amount of air “A2" used in burner 115 to combust the more reactive coal C2 is lower than the amount of air "A1" used in burner 114 to combust the higher chlorine coal.
- overfire air "A3" is injected into the furnace section 120 in a region above the burners 114 and 115 to encourage complete burnout and the formation of N 2 instead of NOx.
- the problem of NOx production associated with higher chloride coals may be minimized by replacing a portion of the higher chloride coal with more reactive coal.
- the amount of energy per unit weight of coal may be increased by replacing a portion of the more reactive coal with the higher chloride coal.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Combustion Of Fluid Fuel (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/557,733 US20080105176A1 (en) | 2006-11-08 | 2006-11-08 | Staged-coal injection for boiler reliability and emissions reduction |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1983259A2 true EP1983259A2 (de) | 2008-10-22 |
EP1983259A3 EP1983259A3 (de) | 2009-01-21 |
Family
ID=39358638
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07112706A Withdrawn EP1983259A3 (de) | 2006-11-08 | 2007-07-18 | Gestufte Kohlezuführung zur Verlässlichkeit und Emissionsreduktion eines Boilers |
Country Status (3)
Country | Link |
---|---|
US (1) | US20080105176A1 (de) |
EP (1) | EP1983259A3 (de) |
CA (1) | CA2593918A1 (de) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL2001797C2 (nl) * | 2008-07-14 | 2010-01-18 | Essent En Produktie B V | Werkwijze voor het verbranden van een tweede vaste brandstof in combinatie met een eerste vaste brandstof. |
US8286594B2 (en) * | 2008-10-16 | 2012-10-16 | Lochinvar, Llc | Gas fired modulating water heating appliance with dual combustion air premix blowers |
US8517720B2 (en) | 2008-10-16 | 2013-08-27 | Lochinvar, Llc | Integrated dual chamber burner |
CN101963352B (zh) * | 2010-10-25 | 2011-12-21 | 南京航空航天大学 | 双旋流煤粉燃烧器 |
US9097436B1 (en) | 2010-12-27 | 2015-08-04 | Lochinvar, Llc | Integrated dual chamber burner with remote communicating flame strip |
RU2474758C1 (ru) * | 2011-10-10 | 2013-02-10 | Общество с ограниченной ответственностью "Политехэнерго" | Способ регулирования температуры газов на выходе из камеры сгорания вихревой топки и вихревая топка |
CN102494333B (zh) * | 2011-11-14 | 2014-09-03 | 上海锅炉厂有限公司 | 一种燃用无烟煤的单火球四角直流燃烧器 |
US9464805B2 (en) | 2013-01-16 | 2016-10-11 | Lochinvar, Llc | Modulating burner |
RU2582722C2 (ru) * | 2013-08-05 | 2016-04-27 | Евгений Михайлович Пузырёв | Вихревая топка |
CN103486571A (zh) * | 2013-09-18 | 2014-01-01 | 江苏太湖锅炉股份有限公司 | 一种双燃料锅炉 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4259911A (en) * | 1979-06-21 | 1981-04-07 | Combustion Engineering, Inc. | Fluidized bed boiler feed system |
WO2001094843A1 (en) * | 2000-06-08 | 2001-12-13 | Clearstack Combustion Corporation | Low nitrogen oxides emissions using three stages of fuel oxidation and in-situ furnace flue gas recirculation |
US20030143128A1 (en) * | 2002-01-25 | 2003-07-31 | Lanier William Steven | Process and system to reduce mercury emission |
US20050036926A1 (en) * | 2003-08-14 | 2005-02-17 | General Electric Company | Mercury reduction system and method in combustion flue gas using coal blending |
EP1533019A1 (de) * | 2003-11-18 | 2005-05-25 | General Electric Company | Verfahren zur Quecksilberreduzierung in Rauchgasen durch gestufte Luftzufuhr |
US20050147549A1 (en) * | 2004-01-06 | 2005-07-07 | General Electric Company | Method and system for removal of NOx and mercury emissions from coal combustion |
US20060008757A1 (en) * | 2004-07-06 | 2006-01-12 | Zamansky Vladimir M | Methods and systems for operating low NOx combustion systems |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4480560A (en) * | 1983-12-09 | 1984-11-06 | International Coal Refining Company | Pneumatic conveying of pulverized solvent refined coal |
JPH02272207A (ja) * | 1988-09-10 | 1990-11-07 | Kansai Electric Power Co Inc:The | 水管式ボイラとその燃焼方法 |
US5364421A (en) * | 1991-07-31 | 1994-11-15 | Ziegler Coal Holding Company | Coal blends having improved ash viscosity |
US5327726A (en) * | 1992-05-22 | 1994-07-12 | Foster Wheeler Energy Corporation | Staged furnaces for firing coal pyrolysis gas and char |
US6699029B2 (en) * | 2001-01-11 | 2004-03-02 | Praxair Technology, Inc. | Oxygen enhanced switching to combustion of lower rank fuels |
US6604474B2 (en) * | 2001-05-11 | 2003-08-12 | General Electric Company | Minimization of NOx emissions and carbon loss in solid fuel combustion |
CA2410725C (en) * | 2001-11-16 | 2008-07-22 | Hitachi, Ltd. | Solid fuel burner, burning method using the same, combustion apparatus and method of operating the combustion apparatus |
-
2006
- 2006-11-08 US US11/557,733 patent/US20080105176A1/en not_active Abandoned
-
2007
- 2007-07-18 CA CA002593918A patent/CA2593918A1/en not_active Abandoned
- 2007-07-18 EP EP07112706A patent/EP1983259A3/de not_active Withdrawn
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4259911A (en) * | 1979-06-21 | 1981-04-07 | Combustion Engineering, Inc. | Fluidized bed boiler feed system |
WO2001094843A1 (en) * | 2000-06-08 | 2001-12-13 | Clearstack Combustion Corporation | Low nitrogen oxides emissions using three stages of fuel oxidation and in-situ furnace flue gas recirculation |
US20030143128A1 (en) * | 2002-01-25 | 2003-07-31 | Lanier William Steven | Process and system to reduce mercury emission |
US20050036926A1 (en) * | 2003-08-14 | 2005-02-17 | General Electric Company | Mercury reduction system and method in combustion flue gas using coal blending |
EP1533019A1 (de) * | 2003-11-18 | 2005-05-25 | General Electric Company | Verfahren zur Quecksilberreduzierung in Rauchgasen durch gestufte Luftzufuhr |
US20050147549A1 (en) * | 2004-01-06 | 2005-07-07 | General Electric Company | Method and system for removal of NOx and mercury emissions from coal combustion |
US20060008757A1 (en) * | 2004-07-06 | 2006-01-12 | Zamansky Vladimir M | Methods and systems for operating low NOx combustion systems |
Also Published As
Publication number | Publication date |
---|---|
CA2593918A1 (en) | 2008-05-08 |
EP1983259A3 (de) | 2009-01-21 |
US20080105176A1 (en) | 2008-05-08 |
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