EP1960617B1 - A barrier - Google Patents

A barrier Download PDF

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Publication number
EP1960617B1
EP1960617B1 EP06831396.4A EP06831396A EP1960617B1 EP 1960617 B1 EP1960617 B1 EP 1960617B1 EP 06831396 A EP06831396 A EP 06831396A EP 1960617 B1 EP1960617 B1 EP 1960617B1
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EP
European Patent Office
Prior art keywords
barrier
foam
layer
barriers
shock
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Active
Application number
EP06831396.4A
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German (de)
French (fr)
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EP1960617A1 (en
Inventor
Ian Barnes
Bryn Thomas
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UK Secretary of State for Defence
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UK Secretary of State for Defence
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Publication of EP1960617A1 publication Critical patent/EP1960617A1/en
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Publication of EP1960617B1 publication Critical patent/EP1960617B1/en
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Classifications

    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04H—BUILDINGS OR LIKE STRUCTURES FOR PARTICULAR PURPOSES; SWIMMING OR SPLASH BATHS OR POOLS; MASTS; FENCING; TENTS OR CANOPIES, IN GENERAL
    • E04H9/00—Buildings, groups of buildings or shelters adapted to withstand or provide protection against abnormal external influences, e.g. war-like action, earthquake or extreme climate
    • E04H9/04—Buildings, groups of buildings or shelters adapted to withstand or provide protection against abnormal external influences, e.g. war-like action, earthquake or extreme climate against air-raid or other war-like actions
    • E04H9/10—Independent shelters; Arrangement of independent splinter-proof walls
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41—WEAPONS
    • F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00—Armour; Armour plates
    • F41H5/02—Plate construction
    • F41H5/04—Plate construction composed of more than one layer
    • F41H5/0471—Layered armour containing fibre- or fabric-reinforced layers
    • F41H5/0478—Fibre- or fabric-reinforced layers in combination with plastics layers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42—AMMUNITION; BLASTING
    • F42D—BLASTING
    • F42D5/00—Safety arrangements
    • F42D5/04—Rendering explosive charges harmless, e.g. destroying ammunition; Rendering detonation of explosive charges harmless
    • F42D5/045—Detonation-wave absorbing or damping means

Definitions

  • This invention relates to a passive barrier according to claim 1.
  • the blast wave caused by the explosion of a first device can impact a nearby device with enough force to detonate it or at least damage it.
  • the blast wave degrades quickly so the risk of devices being detonated falls off quickly with distance.
  • fragments of the exploded device and any other items nearby can become projectiles which radiate out from the device.
  • These fragments termed incident material, can impact a device with enough energy to detonate the device.
  • the fragments can also cause damage to the device which could render it unstable and vulnerable to detonation.
  • the blast wave can lift and/or carry objects in its path which then themselves become projectiles which can damage or detonate other devices.
  • barriers may be reactive, for example, reactive armour, or passive, which do not have active components.
  • Concrete has been employed in the past to make a passive barrier to withstand the destructive force of an explosion, such as the detonation of a bomb.
  • barriers made from concrete take time to construct and once constructed are permanent.
  • explosive devices such as missiles
  • water filled barriers Water is well known in the art for mitigating blasts.
  • a water filled barrier may comprise one or more containers filled with water which is/are placed between the explosive device(s) and the item(s) to be protected.
  • the containers overcome the previous problem as the barrier can be removed after use.
  • the barrier needs to be erected where there is an adequate water supply. In an area where a water supply is poor, then the water to fill the containers also needs to be transported.
  • the barriers are often bulky which can pose transportation problems and add to the cost of using them. Also, the act of filling the containers with water and emptying them will take time before they are useful. Once the barrier is in place it will prevent shock waves and particulates from detonating nearby explosives by acting as a shield. However, there is the possibility that the resulting blast and shock waves can move this barrier and cause it to impact the item to be protected which could result in physical damage to the item which causes it to detonate.
  • the invention provides a passive barrier according to claim 1.
  • the barrier can be used to prevent an explosion from detonating other explosives or devices nearby by protecting such devices.
  • the barrier can be placed between the missile warheads on an aeroplane, torpedoes in a submarine, between stationary vehicles carrying explosive devices or in civil or military explosives stores.
  • the barrier can also be used in a vehicle for transporting and/or storing explosives.
  • the barrier can further be used to surround a vehicle or vehicles to afford them greater protection.
  • the barrier advantageously comprises at least one layer of a shock absorbing material covered at least on two opposing faces by a material which is robust in normal use but which is capable of fragmenting when exposed to an explosion.
  • the layer of shock absorbing material is advantageously a foam material and more advantageously a polyethylene foam. Even more advantageously the layer is made of Plastazote® which is a closed-cell, cross-linked polyethylene foam produced by Zotefoams plc.
  • a suitable material for the layers covering the shock absorbing material is fibre glass, advantageously a high strength composite fibre glass such as S2-glass® which is used under licence from NP Aerospace. This material is capable of disintegrating into innocuous fragments upon an impact but is otherwise structurally rigid making it an ideal material for use in the barrier.
  • the dimensions of the fibreglass layers are chosen so as to be strong enough to withstand the initial shock wave and slow down the fragments resulting from an explosion.
  • the barrier may be of a thickness to prevent fragment perforation through the barrier, but this is not an essential feature of the invention.
  • the barrier may also be optimised to a thickness whereby it may not prevent all of the fragments from striking the areas to be protected but it will slow them down to such an extent that the fragments will not have enough residual energy to cause damage resulting in a further detonation.
  • the barrier may be optimised to prevent the passage of all the fragments. In all of these embodiments the barrier provides adequate protection from fragment impacts. In a first embodiment, as the barrier is bombarded with fragments it starts to delaminate. This de-lamination then means the barrier itself does not present a threat to adjacent munitions as the layers which make up the barrier are not themselves heavy enough to cause impact damage.
  • the shock wave is reflected by the composite fibre glass as there is a change in density from air to the barrier, i.e. low density to high density.
  • a percentage of the wave may enter and pass through the composite fibre glass layer.
  • the shock wave reaches the back face of the composite fibre glass, there is another reflection of the wave as there is another change in material density.
  • Some of the remaining force of the wave may pass through the foam layer and the process of wave reflection starts again when the wave encounters the second composite fibre glass layer.
  • the foam prevents one fibreglass layer from striking the other fibreglass layer with significant force after being struck by a blast wave by decelerating the first layer. If air were used as the low density layer, the first fibreglass layer would strike the second fibreglass layer.
  • the barrier comprises a polyurethane layer surrounding an S2 fibre glass layer
  • the S2 fibreglass layer may be comprised of an S2 glass- foam-S2 glass structure as previously described.
  • Impact resistant polyurethane foams are advantageous and are commercially available from General Plastics. The polyurethane layers and S2 glass will delaminate under the force of a blast and/or impact by incident material.
  • an explosion mitigating barrier can be formed entirely of an impact resistant polyurethane foam. This foam collapses in on itself when impacted by blast fragments and therefore slows down their passage.
  • a preferred foam is LAST-A-FOAM ® produced by General Plastics.
  • the barrier may be formed of an aluminium honeycomb structure. Such a structure is capable of slowing down blast fragments as much energy is absorbed in crushing a honeycomb structure.
  • This embodiment has the advantage that the barrier has relatively little mass so it is not able to transmit sufficient energy upon impact to detonate an explosive device but which is capable of decelerating blast fragments.
  • the thickness of the layers used can be optimised for their required use. It is desirable to have a balance between the barrier being thick enough to perform its function adequately but which has a minimum mass so that it will not cause detonations if moved by the blast wave to impact a device.
  • the shape of the barrier may be selected to direct the shock waves and blast fragments in a particular direction. The man skilled in the art would know how to do this within the confines of the geometry of a given situation. Such shapes may be, for example, substantially planar, curved, cylindrical or diamond shaped.
  • the barrier can be of any size which provides protection and which is capable of being moved and transported with ease. If a greater length or height barrier is required than that of a single barrier, then a plurality of barriers can be placed side by side and/or on top of one another until the desired length and/or height is achieved. In another advantageous embodiment of the invention, the barrier is configured so that it can interlock with other barriers of the invention.
  • This feature gives the user the option of constructing a barrier of greater length and/or height which may be more suitable for use in environments where a large area needs to be protected, for example separating missiles on aeroplanes or providing a dividing wall between stores of explosive materials.
  • the barrier may be formed with a foot so that it can stand up without support. Alternatively, it may be placed in a holder to ensure stability or it may be suspended proximate to the item to be protected, for example, from the underside of a wing of an aeroplane.
  • the stand, holder or suspender can be made of any suitable material which may also have blast attenuating properties. The stand, holder or suspender can also be weighted, if required, to provide greater stability.
  • the barrier 10 comprises multiple layers 12 and 14. Layers 12 and 14 are held together with fixings, such as glue or clips, which maintain the integrity of the barrier before exposure to a blast but which do not prevent the barrier from delaminating in the event of a blast. Layer 12 is comprised of S2-glass ® panels and layer 14 is comprised of Plastazote®.
  • Fig. 2 shows the barrier 10' in a curved configuration which is shaped so as to provide increased protection to an explosive device, D or the surrounding area. If the device, D is the item which is to be exploded, the explosion will be partially contained by the curved nature of the barrier 10'. If the device, D, is the item to be protected, then it will be protected from explosions occurring directly to the left of it (as shown in the figure) and also partially from above.
  • Fig 3 shows the barrier 10" in another curved configuration wherein the barrier shrouds at least a portion of the explosive device D.
  • a configuration is useful where there are explosive devices proximate to one another, for example, on an aeroplane or in a torpedo store.
  • Fig. 4 shows the barrier of the invention in use in a military situation.
  • the barrier 10 is placed under the belly of an aeroplane 20 in between the missiles 16. Further barriers 10 are placed between neighbouring missiles on the aeroplane.
  • the missiles 18 on the end of the wing of the aeroplane are shrouded by barriers 10" having a curved configuration which follows the contours of the device to be protected. Further barriers can be placed adjacent the aeroplane to protect neighbouring objects such as other aeroplanes, missiles, store areas/rooms or personnel 26.
  • Figure 5 shows a further embodiment of the barrier which comprises a polyurethane layer 50 on two opposing faces of an S2 glass layer 52.
  • the polyurethane layers are triangular in shape so as to deflect the blast wave and blast fragments (shown by arrows) away from the device D to be protected.
  • both polyurethane layers are triangular in shape which provides protection for devices at either end on the apex in case one of the devices detonates.
  • the barrier may be permanently or moveably fixed in place by any suitable means to provide protection.
  • the barrier technology has been proven to protect a 155mm shell placed behind the barrier of fig. 1 from being detonated sympathetically by the detonation of a 155mm shell the other side of the barrier.

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • General Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Environmental & Geological Engineering (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)
  • Laminated Bodies (AREA)

Description

  • This invention relates to a passive barrier according to claim 1.
  • It is known that if an explosive device is detonated, it can detonate another explosive device nearby through the effect of the blast wave generated, and/or by the impact of fragments of the exploded item. In a situation where there are many explosives or explosive devices within a close proximity of one another it is essential to protect as many items as possible from the risk of being detonated by a nearby explosion.
  • After the detonation of a device, there are three principal mechanisms which may cause an explosion of another device, termed a sympathetic explosion. Firstly, the blast wave caused by the explosion of a first device can impact a nearby device with enough force to detonate it or at least damage it. However, the blast wave degrades quickly so the risk of devices being detonated falls off quickly with distance. Secondly, fragments of the exploded device and any other items nearby can become projectiles which radiate out from the device. These fragments, termed incident material, can impact a device with enough energy to detonate the device. The fragments can also cause damage to the device which could render it unstable and vulnerable to detonation. Thirdly, the blast wave can lift and/or carry objects in its path which then themselves become projectiles which can damage or detonate other devices.
  • It is known to use a barrier in a situation where explosives are stored or where there is the possibility that an explosion could occur. Such barriers may be reactive, for example, reactive armour, or passive, which do not have active components. Concrete has been employed in the past to make a passive barrier to withstand the destructive force of an explosion, such as the detonation of a bomb. However, barriers made from concrete take time to construct and once constructed are permanent. In a conflict situation, for example, it is required that explosive devices, such as missiles, are moved around and therefore the concrete barriers which have been built become disused and further barriers need to be constructed elsewhere. It is evident that this practice requires much time and material. One solution to this problem has been to use water filled barriers. Water is well known in the art for mitigating blasts. A water filled barrier may comprise one or more containers filled with water which is/are placed between the explosive device(s) and the item(s) to be protected. The containers overcome the previous problem as the barrier can be removed after use. However, the barrier needs to be erected where there is an adequate water supply. In an area where a water supply is poor, then the water to fill the containers also needs to be transported. The barriers are often bulky which can pose transportation problems and add to the cost of using them. Also, the act of filling the containers with water and emptying them will take time before they are useful. Once the barrier is in place it will prevent shock waves and particulates from detonating nearby explosives by acting as a shield. However, there is the possibility that the resulting blast and shock waves can move this barrier and cause it to impact the item to be protected which could result in physical damage to the item which causes it to detonate.
  • Document US 5814 250 discloses a passive barrier comprising the features of the preamble of the independent claim 1.
  • It is an object of the present invention to provide a barrier which is quick and easy to put in place and remove, and which provides adequate shielding from an explosion and which does not itself become a projectile capable of detonating an explosive device in the event of a blast.
  • Accordingly, the invention provides a passive barrier according to claim 1.
  • Although the invention can be employed in close proximity to explosives and explosive devices such as bombs and missiles it is not limited to such use.
  • The barrier can be used to prevent an explosion from detonating other explosives or devices nearby by protecting such devices. For example, the barrier can be placed between the missile warheads on an aeroplane, torpedoes in a submarine, between stationary vehicles carrying explosive devices or in civil or military explosives stores. The barrier can also be used in a vehicle for transporting and/or storing explosives. The barrier can further be used to surround a vehicle or vehicles to afford them greater protection. These uses are purely for illustration and do not restrict the scope of use of the invention.
  • The barrier advantageously comprises at least one layer of a shock absorbing material covered at least on two opposing faces by a material which is robust in normal use but which is capable of fragmenting when exposed to an explosion.
  • The layer of shock absorbing material is advantageously a foam material and more advantageously a polyethylene foam. Even more advantageously the layer is made of Plastazote® which is a closed-cell, cross-linked polyethylene foam produced by Zotefoams plc.
  • A suitable material for the layers covering the shock absorbing material is fibre glass, advantageously a high strength composite fibre glass such as S2-glass® which is used under licence from NP Aerospace. This material is capable of disintegrating into innocuous fragments upon an impact but is otherwise structurally rigid making it an ideal material for use in the barrier.
  • The dimensions of the fibreglass layers are chosen so as to be strong enough to withstand the initial shock wave and slow down the fragments resulting from an explosion. The barrier may be of a thickness to prevent fragment perforation through the barrier, but this is not an essential feature of the invention. The barrier may also be optimised to a thickness whereby it may not prevent all of the fragments from striking the areas to be protected but it will slow them down to such an extent that the fragments will not have enough residual energy to cause damage resulting in a further detonation. Alternatively, the barrier may be optimised to prevent the passage of all the fragments. In all of these embodiments the barrier provides adequate protection from fragment impacts. In a first embodiment, as the barrier is bombarded with fragments it starts to delaminate. This de-lamination then means the barrier itself does not present a threat to adjacent munitions as the layers which make up the barrier are not themselves heavy enough to cause impact damage.
  • Whilst the inventors do not wish to be bound by this theory, they believe that the first embodiment of the barrier works in the following way. The shock wave is reflected by the composite fibre glass as there is a change in density from air to the barrier, i.e. low density to high density. A percentage of the wave may enter and pass through the composite fibre glass layer. When the shock wave reaches the back face of the composite fibre glass, there is another reflection of the wave as there is another change in material density. Some of the remaining force of the wave may pass through the foam layer and the process of wave reflection starts again when the wave encounters the second composite fibre glass layer. The foam prevents one fibreglass layer from striking the other fibreglass layer with significant force after being struck by a blast wave by decelerating the first layer. If air were used as the low density layer, the first fibreglass layer would strike the second fibreglass layer.
  • In a further embodiment, the barrier comprises a polyurethane layer surrounding an S2 fibre glass layer, the S2 fibreglass layer may be comprised of an S2 glass- foam-S2 glass structure as previously described. Impact resistant polyurethane foams are advantageous and are commercially available from General Plastics. The polyurethane layers and S2 glass will delaminate under the force of a blast and/or impact by incident material.
  • In a still further embodiment, an explosion mitigating barrier can be formed entirely of an impact resistant polyurethane foam. This foam collapses in on itself when impacted by blast fragments and therefore slows down their passage. A preferred foam is LAST-A-FOAM ® produced by General Plastics.
  • In yet a further embodiment, the barrier may be formed of an aluminium honeycomb structure. Such a structure is capable of slowing down blast fragments as much energy is absorbed in crushing a honeycomb structure. This embodiment has the advantage that the barrier has relatively little mass so it is not able to transmit sufficient energy upon impact to detonate an explosive device but which is capable of decelerating blast fragments.
  • The thickness of the layers used can be optimised for their required use. It is desirable to have a balance between the barrier being thick enough to perform its function adequately but which has a minimum mass so that it will not cause detonations if moved by the blast wave to impact a device.
  • The shape of the barrier may be selected to direct the shock waves and blast fragments in a particular direction. The man skilled in the art would know how to do this within the confines of the geometry of a given situation. Such shapes may be, for example, substantially planar, curved, cylindrical or diamond shaped. The barrier can be of any size which provides protection and which is capable of being moved and transported with ease. If a greater length or height barrier is required than that of a single barrier, then a plurality of barriers can be placed side by side and/or on top of one another until the desired length and/or height is achieved. In another advantageous embodiment of the invention, the barrier is configured so that it can interlock with other barriers of the invention. This will be achieved by any suitable means such as tongue and groove formations, dovetails or finger joints on the edges of the barrier. This feature gives the user the option of constructing a barrier of greater length and/or height which may be more suitable for use in environments where a large area needs to be protected, for example separating missiles on aeroplanes or providing a dividing wall between stores of explosive materials.
  • The barrier may be formed with a foot so that it can stand up without support. Alternatively, it may be placed in a holder to ensure stability or it may be suspended proximate to the item to be protected, for example, from the underside of a wing of an aeroplane. The stand, holder or suspender can be made of any suitable material which may also have blast attenuating properties. The stand, holder or suspender can also be weighted, if required, to provide greater stability.
  • The present invention will now be described with reference to the following drawings:
    • Fig. 1 shows a profile view of a first embodiment of the invention
    • Fig. 2 shows a profile view of a second embodiment of the invention
    • Fig. 3 shows a profile view of a third embodiment of the invention
    • Fig. 4 shows the barrier of Fig. 1 and 3 in use in, a military situation
    • Fig. 5 shows a plan view of a further embodiment of the invention
  • In an advantageous embodiment as shown in fig. 1 it can be seen that the barrier 10 comprises multiple layers 12 and 14. Layers 12 and 14 are held together with fixings, such as glue or clips, which maintain the integrity of the barrier before exposure to a blast but which do not prevent the barrier from delaminating in the event of a blast. Layer 12 is comprised of S2-glass ® panels and layer 14 is comprised of Plastazote®.
  • Fig. 2 shows the barrier 10' in a curved configuration which is shaped so as to provide increased protection to an explosive device, D or the surrounding area. If the device, D is the item which is to be exploded, the explosion will be partially contained by the curved nature of the barrier 10'. If the device, D, is the item to be protected, then it will be protected from explosions occurring directly to the left of it (as shown in the figure) and also partially from above.
  • Fig 3 shows the barrier 10" in another curved configuration wherein the barrier shrouds at least a portion of the explosive device D. Such a configuration is useful where there are explosive devices proximate to one another, for example, on an aeroplane or in a torpedo store.
  • Fig. 4 shows the barrier of the invention in use in a military situation. The barrier 10 is placed under the belly of an aeroplane 20 in between the missiles 16. Further barriers 10 are placed between neighbouring missiles on the aeroplane. The missiles 18 on the end of the wing of the aeroplane are shrouded by barriers 10" having a curved configuration which follows the contours of the device to be protected. Further barriers can be placed adjacent the aeroplane to protect neighbouring objects such as other aeroplanes, missiles, store areas/rooms or personnel 26.
  • Figure 5 shows a further embodiment of the barrier which comprises a polyurethane layer 50 on two opposing faces of an S2 glass layer 52. The polyurethane layers are triangular in shape so as to deflect the blast wave and blast fragments (shown by arrows) away from the device D to be protected. In fig. 5, both polyurethane layers are triangular in shape which provides protection for devices at either end on the apex in case one of the devices detonates.
  • Whilst a three layer barrier is shown in the drawings, a barrier comprising five or more layers is also possible.
  • Whilst the feature of the barrier being moveable is important it is also envisaged that the barrier may be permanently or moveably fixed in place by any suitable means to provide protection.
  • Trials have shown that a sympathetic explosion of a 1000lb (453,59 kg) general purpose bomb can be mitigated with a shroud barrier (shown in the figures as 10") comprising two 15-20mm fibreglass outer layers laminated on 12-15mm of expanded closed-cell cross-linked polyethylene foam. The weight of a 1350mm x 340mm x 60mm panel is 50 to 60kg.
  • The barrier technology has been proven to protect a 155mm shell placed behind the barrier of fig. 1 from being detonated sympathetically by the detonation of a 155mm shell the other side of the barrier.

Claims (10)

  1. A passive barrier (10) comprising mitigating means for mitigating explosive blast waves, the mitigating means being transportable prior to being impacted by explosive blast waves and fragmenting when impacted by explosive blast waves, wherein the mitigating means comprises:
    a foam-comprising, a shock-absorbing layer (14) having opposed first and second outer faces; the passive barrier being characterised in that said mitigating means further comprises
    a first layer of fragmentable fibreglass (12) affixed directly to at least part of the first outer face of the shock-absorbing layer (14) to form a first structurally-rigid external layer; and
    a second layer of fragmentable fibreglass (12) affixed directly to at least part of the second outer face of the shock-absorbing layer (14) to form a second structurally-rigid external layer.
  2. A barrier (10) according to claim 1 wherein the foam is a polyethylene foam.
  3. A barrier (10) according to claim 2 wherein the foam is expandable polyethylene foam.
  4. A barrier (10) according to claim 1 wherein the foam is an impact-resistant polyurethane foam.
  5. A barrier (10) according to claim 1 wherein the barrier is further configured to interlock with one or more barriers.
  6. A barrier (10) according to claim 1 wherein the barrier is substantially planar.
  7. A barrier (10) according to claim 1 wherein at least part of the barrier is curved.
  8. A barrier (10) according to claim 1 wherein the barrier is retained in position by means of a foot, holder or by suspension following placement proximate the source of explosive blast waves.
  9. A plurality of barriers according to claim 1 wherein the passage of all fragments is prevented.
  10. A vehicle (20) comprising a barrier (10) according to claim 1.
EP06831396.4A 2005-12-17 2006-12-18 A barrier Active EP1960617B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0525727.4A GB0525727D0 (en) 2005-12-17 2005-12-17 A barrier
PCT/GB2006/004722 WO2007068954A1 (en) 2005-12-17 2006-12-18 A barrier

Publications (2)

Publication Number Publication Date
EP1960617A1 EP1960617A1 (en) 2008-08-27
EP1960617B1 true EP1960617B1 (en) 2015-08-05

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EP06831396.4A Active EP1960617B1 (en) 2005-12-17 2006-12-18 A barrier

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US (1) US20080264245A1 (en)
EP (1) EP1960617B1 (en)
CN (1) CN101331283A (en)
AU (2) AU2006325424A1 (en)
BR (1) BRPI0620007A2 (en)
CA (2) CA2634060A1 (en)
GB (1) GB0525727D0 (en)
IL (1) IL192216A0 (en)
RU (1) RU2448322C2 (en)
WO (1) WO2007068954A1 (en)
ZA (2) ZA200805571B (en)

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BRPI0620007A2 (en) 2011-10-25
CN101331283A (en) 2008-12-24
GB0525727D0 (en) 2006-01-25
WO2007068954A1 (en) 2007-06-21
IL192216A0 (en) 2008-12-29
CA2671534A1 (en) 2008-06-26
AU2007336057A1 (en) 2008-06-26
ZA200805571B (en) 2011-02-23
RU2008127179A (en) 2010-01-27
ZA200903782B (en) 2010-03-31
CA2634060A1 (en) 2007-06-21
EP1960617A1 (en) 2008-08-27
RU2448322C2 (en) 2012-04-20
US20080264245A1 (en) 2008-10-30
AU2006325424A1 (en) 2007-06-21

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