EP1926376A1 - Melanges fongicides a base de triazoles - Google Patents

Melanges fongicides a base de triazoles

Info

Publication number
EP1926376A1
EP1926376A1 EP06793222A EP06793222A EP1926376A1 EP 1926376 A1 EP1926376 A1 EP 1926376A1 EP 06793222 A EP06793222 A EP 06793222A EP 06793222 A EP06793222 A EP 06793222A EP 1926376 A1 EP1926376 A1 EP 1926376A1
Authority
EP
European Patent Office
Prior art keywords
formula
compound
mixtures
epoxiconazole
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06793222A
Other languages
German (de)
English (en)
Inventor
Martin Semar
Dieter Strobel
Jens Bruns
Reinhard Stierl
Frank Werner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP1926376A1 publication Critical patent/EP1926376A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

Definitions

  • the present invention relates to fungicidal mixtures containing
  • the invention relates to a method for controlling harmful fungi with mixtures of the compound I with at least one of the compounds II to V and the use of the compound I with at least one of the compounds II to V for the preparation of such mixtures and compositions containing these mixtures.
  • Epoxiconazole of the formula I and its use as a crop protection agent is described in EP-B 0 196 038.
  • Difenconazole of the formula IM is known from EP-A 0 1 12 284.
  • Hexaconazole of the formula IV is described in DE-A 30 42 303. Bromuconazole of Formula V is described in Pesticide Manual, 12th Ed. (2000), page 1 14 described.
  • the present inventions were mixtures as an object that show an improved action against harmful fungi, especially for certain indications with reduced total amount of applied drugs.
  • the mixtures defined above were found. It has also been found that, with simultaneous simultaneous or separate application of the compounds I and of an active compound II or, when using the compounds I and an active compound II, harmful fungi can be controlled better successively than with the individual compounds (synergistic mixtures).
  • the compounds I can be used as a synergist for a variety of different drugs. By simultaneous joint or separate application of the compound I with an active compound II, the fungicidal activity is increased to a superadditive extent.
  • the compounds I to V are capable of forming salts or adducts with inorganic or organic acids or with metal ions.
  • inorganic acids are hydrohalic acids such as hydrogen fluoride, hydrogen chloride, hydrogen bromide and hydrogen iodide, sulfuric acid, phosphoric acid and nitric acid.
  • suitable organic acids are formic acid, carbonic acid and alkanoic acids, such as acetic acid, trifluoroacetic acid, trichloroacetic acid and propionic acid, and also glycolic acid, thiocyanic acid, lactic acid, succinic acid, citric acid, benzoic acid, cinnamic acid, oxalic acid, alkylsulfonic acids (sulfonic acids having straight-chain or branched alkyl radicals having 1 to 20 carbon atoms), Arylsulfonic acids or - disulfonic acids (aromatic radicals such as phenyl and naphthyl which carry one or two sulfonic acid groups), alkylphosphonic acids (phosphonic acids with straight-chain or branched alkyl radicals having 1 to 20 carbon atom
  • the metal ions are, in particular, the ions of the elements of the second main group, in particular calcium and magnesium, the third and fourth main groups, in particular aluminum, tin and lead, and the first to eighth transition groups, in particular chromium, manganese, iron, cobalt, nickel, Copper, zinc and others. Particularly preferred are the metal ions of the elements of the subgroups of the fourth period.
  • the metals can be present in the various valences that belong to them.
  • the mixtures of the compound I and of an active compound II, or the simultaneous joint or separate use of the compound I and an active compound II are distinguished by an outstanding activity against a broad spectrum of phytopathogenic fungi, in particular from the class of the Ascomycetes, Deuteromycetes , Peronosporomycetes (syn. Oomycetes) and Basidiomycetes. They are partially systemically effective and can be used in crop protection as pickling, foliar and soil fungicides.
  • Cochliobolus species on corn, cereals, rice e.g. Cochliobolus sativus on cereals, Cochliobolus miyabeanus on rice
  • Drechslera species Pyrenophora species on maize, cereals, rice and turf, e.g. D.teres to barley or D. tritici-repentis to wheat
  • Fusarium and Verticillium species on various plants e.g. F. graminearum or F. culmorum on cereal or F. oxysporum on a variety of plants.
  • Plants such as e.g. tomatoes
  • Michrodochium nivale on cereals • Mycosphaerella species on cereals, bananas and peanuts, e.g. M. granicola on wheat or M.fijiensis on bananas
  • Peronospora species on cabbage and bulbous plants such as P. brassicae on cabbage or P. destructor on onion
  • Phytophthora species on various plants such as P. capsici on peppers, Plasmopara viticola on grapevines,
  • Pseudoperonospora on various plants e.g. P. cubensis on cucumber or P. humili on hops
  • Puccinia species on various plants e.g. P. triticina, P. striformins, P. hordei or P.graminis on cereals, or P. asparagi on asparagus
  • Venturia species scab
  • apples and pears like. e.g. V. inaequalis to apple.
  • the mixtures of the compounds I and of an active compound II are particularly suitable for controlling harmful fungi from the class of the Peronosporomycetes (syn. Oomycetes), such as Peronospora species, Phytophthora species, Plasmopara viticola and Pseudoperonospora species, in particular the corresponding species mentioned above.
  • Peronosporomycetes such as Peronospora species, Phytophthora species, Plasmopara viticola and Pseudoperonospora species, in particular the corresponding species mentioned above.
  • the mixtures of compounds I and II are also suitable for controlling harmful fungi in the protection of materials (eg wood, paper, paint dispersions, fibers or fabrics) and in the protection of stored products.
  • harmful fungi Ascomycetes such as Ophiostoma spp., Ceratocystis spp., Aureosidium pullulans, Sclerophoma spp., Chaetomium spp., Humicola spp., Petriella spp., Trichurus spp .; Basidiomycetes such as Coniophora spp., Coriolus spp., Gloeophlum spp., Lentinus spp., Pleurotus spp., Poria spp., Serpula spp.
  • Tyromyces spp. Deuteromycetes such as Aspergillus spp., Cladosporium spp., Penicillium spp., Trichodo- spp. ma spp., Alternaria spp., Paecilomyces spp. and Zygomycetes such as Mucor spp., moreover, in the protection of the following yeasts: Candida spp. and Saccharomyces cerevisae.
  • the compounds I are used by treating the fungi or the plants, seeds, materials or the soil to be protected against fungal attack with a fungicidally effective amount of the active ingredients.
  • the application can be done both before and after the infection of the materials, plants or seeds by the fungi.
  • the compounds I and active compounds II can be applied simultaneously together or separately or in succession, the sequence in the case of separate application generally having no effect on the control result.
  • the pure active ingredients I and at least one of the active ingredients II to V which can be further active against harmful fungi or against other pests such as insects, spider animals or nematodes or herbicidal or growth-regulating agents or fertilizers.
  • Active substances II to V for use. Under certain circumstances, however, mixtures of compound I with two or optionally several active components may be advantageous.
  • the compound I and the active compound II are usually employed in a weight ratio of from 100: 1 to 1: 100, preferably from 20: 1 to 1:20, in particular from 10: 1 to 1:10.
  • the compound I and the active ingredient IM are usually employed in a weight ratio of 100: 1 to 1: 100, preferably 20: 1 to 1:20, in particular 10: 1 to 1:10.
  • the compound I and the active ingredient IV are usually used in a weight ratio of 100: 1 to 1: 100, preferably 20: 1 to 1:20, in particular 10: 1 to 1:10 applied.
  • the compound I and the active ingredient V are usually used in a weight ratio of 100: 1 to 1: 100, preferably 20: 1 to 1:20, in particular 10: 1 to 1:10 applied.
  • the further active components are added to compound I in a ratio of from 20: 1 to 1:20.
  • the application rates of the mixtures according to the invention, especially in agricultural crops, depending on the nature of the compound and the desired effect at 5 g / ha to 2000 g / ha, preferably 20 to 900 g / ha, in particular 50 to 750 g / ha.
  • the application rates for the compound I are accordingly generally 1 to 1000 g / ha, preferably 10 to 900 g / ha, in particular 20 to 750 g / ha.
  • the application rates for the active compound II are accordingly generally from 1 to 2000 g / ha, preferably from 10 to 1500 g / ha, in particular from 40 to 1000 g / ha.
  • the application rates for the active ingredient IM are correspondingly generally 1 to 2000 g / ha, preferably 10 to 1500 g / ha, in particular 40 to 1000 g / ha.
  • the application rates for the active ingredient IV are correspondingly generally 1 to 2000 g / ha, preferably 10 to 1500 g / ha, in particular 40 to 1000 g / ha.
  • the application rates for the active ingredient V are correspondingly generally 1 to 2000 g / ha, preferably 10 to 1500 g / ha, in particular 40 to 1000 g / ha.
  • application rates of mixture of 1 to 1000 g / 100 kg of seed preferably 1 to 750 g / 100 kg, in particular 5 to 500 g / 100 kg, are generally used.
  • the method for controlling harmful fungi is carried out by the separate or combined application of compound I and at least one of the active ingredients II to V or a mixture of compound I and at least one of the active ingredients II to V by spraying or dusting the seeds, the plants or the soil before or after sowing the plants or before or after emergence of the plants.
  • the mixtures according to the invention or the compound I and at least one of the active compounds II to V can be converted into the customary formulations, e.g. Solutions, emulsions, suspensions, dusts, powders, pastes and granules.
  • the application form depends on the respective purpose; It should in any case ensure a fine and uniform distribution of the compound according to the invention.
  • the formulations are prepared in a known manner, for example by stretching the active ingredient with solvents and / or excipients, if desired with use of emulsifiers and dispersants.
  • Suitable solvents / auxiliaries are essentially: - water, aromatic solvents (eg Solvesso products, xylene), paraffins (eg petroleum fractions), alcohols (eg methanol, butanol, pentanol, benzyl alcohol), ketones (eg cyclohexanone, gamma-butyrolactone), pyrrolidones (NMP, NOP), Acetates (glycol diacetate), glycols, dimethyl fatty acid amides, fatty acids and fatty acid esters.
  • solvent mixtures can also be used
  • Excipients such as ground natural minerals (e.g., kaolins, clays, talc, chalk) and ground synthetic minerals (e.g., fumed silica, silicates); Emulsifiers such as nonionic and anionic emulsifiers (for example polyoxyethylene fatty alcohol ethers, alkyl sulfonates and arylsulfonates) and dispersants such as lignin-sulphite liquors and methylcellulose.
  • ground natural minerals e.g., kaolins, clays, talc, chalk
  • ground synthetic minerals e.g., fumed silica, silicates
  • Emulsifiers such as nonionic and anionic emulsifiers (for example polyoxyethylene fatty alcohol ethers, alkyl sulfonates and arylsulfonates) and dispersants such as lignin-sulphite liquors and methylcellulose.
  • the surface-active substances used are alkali metal, alkaline earth metal, ammonium salts of lignin sulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalenesulfonic acid, alkylarylsulfonates, alkyl sulfates, alkyl sulfonates, fatty alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers, and condensation products of sulfonated naphthalene and naphthalene derivatives with formaldehyde , Condensation products of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenol polyglycol ethers, tributylphenyl
  • mineral oil fractions of medium to high boiling point such as kerosine or diesel oil, coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, e.g. Toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes or their derivatives, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, strong polar solvents, e.g. Dimethylsulfoxide, N-methylpyrrolidone or water into consideration.
  • mineral oil fractions of medium to high boiling point such as kerosine or diesel oil, coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, e.g. Toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes or their derivative
  • Powders, dispersants and dusts may be prepared by mixing or co-grinding the active substances with a solid carrier.
  • Granules for example coated, impregnated and homogeneous granules, can be prepared by binding the active compounds to solid carriers.
  • Solid carriers are, for example, mineral earths, such as silica gels, silicates, talc, kaolin, Attaclay, limestone, lime, chalk, bolus, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulfate, magnesium oxide, ground plastics, fertilizers, such as ammonium sulfate, ammonium phosphate , Ammonium nitrate, ureas and vegetable products such as cereal flour, bark, wood and nutshell flour, cellulose powder and other solid carriers.
  • mineral earths such as silica gels, silicates, talc, kaolin, Attaclay, limestone, lime, chalk, bolus, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulfate, magnesium oxide, ground plastics, fertilizers
  • the formulations generally contain between 0.01 and 95 wt .-%, preferably between 0.1 and 90 wt .-% of the active ingredients.
  • the active ingredients are used in a purity of 90% to 100%, preferably 95% to 100% (according to NMR spectrum).
  • formulations are: 1. Products for dilution in water
  • a compound according to the invention 20 parts by weight of a compound according to the invention are dissolved in 70 parts by weight of cyclohexanone with the addition of 10 parts by weight of a dispersant, e.g. Polyvinylpyrrolidone dissolved. Dilution in water gives a dispersion.
  • a dispersant e.g. Polyvinylpyrrolidone dissolved. Dilution in water gives a dispersion.
  • the active ingredient content is 20% by weight
  • a compound according to the invention 15 parts by weight of a compound according to the invention are dissolved in 75 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). Dilution in water results in an emulsion.
  • the formulation has an active ingredient content of 15% by weight.
  • a compound according to the invention 25 parts by weight of a compound according to the invention are dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight).
  • This mixture is added to 30 parts by weight of water by means of an emulsifying machine (e.g., Ultraturax) and made into a homogeneous emulsion. Dilution in water results in an emulsion.
  • the formulation has an active ingredient content of 25% by weight.
  • 50 parts by weight of a compound according to the invention are finely ground with the addition of 50 parts by weight of dispersants and wetting agents and prepared by means of industrial equipment (for example extrusion, spray tower, fluidized bed) as water-dispersible or water-soluble granules. Dilution in water results in a stable dispersion or solution of the active ingredient.
  • the formulation has an active ingredient content of 50% by weight.
  • WP, SP Water-Dispersible and Water-Soluble Powders
  • 75 parts by weight of a compound according to the invention are ground in a rotor-stator mill with the addition of 25 parts by weight of dispersing and wetting agents and silica gel. Dilution in water results in a stable dispersion or solution of the active ingredient.
  • the active ingredient content of the formulation is 75% by weight.
  • 0.5 parts by weight of a compound according to the invention are finely ground and combined with 99.5 parts by weight of carriers. Common processes are extrusion, spray drying or fluidized bed. This gives a granulate for direct application with an active ingredient content of 0.5 wt .-%.
  • the active compounds can be used as such, in the form of their formulations or the application forms prepared therefrom, for example in the form of directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dusts, scattering agents, granules by spraying, atomizing, dusting, Scattering or pouring are applied.
  • the forms of application depend entirely on the intended use; In any case, they should ensure as far as possible the finest distribution of the active compounds according to the invention.
  • Aqueous application forms can be prepared from emulsion concentrates, pastes or wettable powders (wettable powders, oil dispersions) by adding water.
  • the substances for the preparation of emulsions, pastes or oil dispersions, can be homogenized in water by means of wetter, tackifier, dispersant or emulsifier. But it can also be made of effective substance wetting, adhesion, dispersing or emulsifying and possibly solvent or oil concentrates, which are suitable for dilution with water.
  • the active compound concentrations in the ready-to-use preparations can be varied within wide ranges. In general, they are between 0.0001 and 10%, preferably between 0.01 and 1%.
  • the active ingredients can also be used with great success in the ultra-low-volume (ULV) process, it being possible to apply formulations containing more than 95% by weight of active ingredient or even the active ingredient without additives.
  • UUV ultra-low-volume
  • wetting agents To the active ingredients oils of various types, wetting agents, adjuvants, possibly also immediately before use (tank mix), are added. These agents are usually admixed to the compositions according to the invention in a weight ratio of 1: 100 to 100: 1, preferably 1:10 to 10: 1.
  • the compound I and at least one of the active ingredients II to V or the mixtures or the corresponding formulations are used by removing the harmful fungi, the plants, seeds, soils, surfaces, materials or spaces having a fungicidally effective amount the mixture, or the compound I and at least one of the active ingredients II to V in separate application, treated.
  • the application can be made before or after the attack by the harmful fungi.
  • the efficiency (W) is calculated according to the formula of Abbot as follows:
  • ⁇ corresponds to the fungal infestation of the treated plants in% and ⁇ corresponds to the fungal infestation of the untreated (control) plants in%
  • the infestation of the treated plants corresponds to that of the untreated control plants; at an efficiency of 100, the treated plants have no infestation.
  • the expected efficiencies for drug combinations were determined according to the Colby formula (Colby, SR (Calculating synergistic and antagonistic responses of herbicidal combinations, Weeds, 5, p 20 - 22, 1967) and compared with the observed efficiencies.
  • the active ingredient epoxiconazole and triticonazole was used as a commercial formulation.
  • the stock solution is pipetted into a microtiter plate (MTP) and diluted with an aqueous malt-based mushroom nutrient medium to the stated active substance concentration. This was followed by the addition of an aqueous spore suspension of Pyricularia oryzae.
  • MTP microtiter plate
  • the plates were placed in a water vapor saturated chamber at temperatures of 18 ° C. With an absorbance photometer, the MTPs were measured at 405 nm on the 7th day after inoculation. The measured parameters were consistent with the growth of drug-free
  • Efficiency 0 is the same infestation as in the untreated control, efficiency 100 is 0% infestation.
  • the expected efficiencies for drug combinations were determined according to the Colby formula (Colby, SR (Calculating synergistic and antagonistic responses of herbicidal combinations, Weeds, 5, p 20 - 22, 1967) and compared with the observed efficiencies.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pretreatment Of Seeds And Plants (AREA)

Abstract

L'invention concerne des mélanges fongicides constitués (1) d'époxiconazole de formule (I) ou de ses sels ou produits d'addition et (2) de triticonazole de formule (II) ou (3) de difenconazole de formule (III) ou (4) d'hexaconazole de formule (IV) ou (5) de bromuconazole de formule (V) dans des quantités garantissant un effet synergique, un procédé de lutte contre des champignons parasites à l'aide de mélanges constitués d'un composé (I) et d'au moins un principe actif (II), l'utilisation d'un composé (I) avec des principes actifs (II) pour produire des mélanges de ce type ainsi que des agents contenant lesdits mélanges.
EP06793222A 2005-09-14 2006-09-05 Melanges fongicides a base de triazoles Withdrawn EP1926376A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005044037 2005-09-14
PCT/EP2006/066010 WO2007031437A1 (fr) 2005-09-14 2006-09-05 Melanges fongicides a base de triazoles

Publications (1)

Publication Number Publication Date
EP1926376A1 true EP1926376A1 (fr) 2008-06-04

Family

ID=37199163

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06793222A Withdrawn EP1926376A1 (fr) 2005-09-14 2006-09-05 Melanges fongicides a base de triazoles

Country Status (11)

Country Link
US (1) US20090270255A1 (fr)
EP (1) EP1926376A1 (fr)
JP (1) JP2009509936A (fr)
CN (1) CN101262767A (fr)
AR (1) AR056068A1 (fr)
AU (1) AU2006290811B2 (fr)
BR (1) BRPI0615840A2 (fr)
CA (1) CA2623595A1 (fr)
EA (3) EA014411B1 (fr)
UA (1) UA90017C2 (fr)
WO (1) WO2007031437A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2192837B1 (fr) * 2007-09-18 2017-05-10 Basf Se Mélanges fongicides de triticonazole et de difénoconazole
CN101743972A (zh) * 2010-01-22 2010-06-23 青岛奥迪斯生物科技有限公司 一种含有氟环唑和苯醚甲环唑的高效杀菌组合物
WO2023139352A1 (fr) * 2022-01-19 2023-07-27 UPL Corporation Limited Combinaisons fongicides et procédés de lutte contre des champignons phytopathogènes

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Publication number Priority date Publication date Assignee Title
US4432989A (en) * 1980-07-18 1984-02-21 Sandoz, Inc. αAryl-1H-imidazole-1-ethanols
US5266585A (en) * 1981-05-12 1993-11-30 Ciba-Geigy Corporation Arylphenyl ether derivatives, compositions containing these compounds and use thereof
CA1271764A (fr) * 1985-03-29 1990-07-17 Stefan Karbach Azolylmethyloxiranes; leur preparation et leur utilisation pour la protection de cultures
EP0370951B1 (fr) * 1988-11-18 1993-08-11 Ciba-Geigy Ag Agents microbicides
US5250559A (en) * 1988-11-18 1993-10-05 Ciba-Geigy Corporation Microbicidal compositions
FR2663195A1 (fr) * 1990-06-13 1991-12-20 Rhone Poulenc Agrochimie Procede de traitement fongicide foliaire au moyen d'un triazole et composition fongicide pour mettre en óoeuvre le procede.
US5714507A (en) * 1994-07-01 1998-02-03 Janssen Pharmaceutica, N.V. Synergistic compositions containing metconazole and another triazole
FR2751173B1 (fr) * 1996-07-16 1998-08-28 Rhone Poulenc Agrochimie Composition fongicide a base de 2 composes de type triazole
EP2289322B1 (fr) * 2002-03-07 2012-07-18 Basf Se Mélanges fongicides à base de triazoles

Non-Patent Citations (1)

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Title
See references of WO2007031437A1 *

Also Published As

Publication number Publication date
AU2006290811A1 (en) 2007-03-22
EA015703B1 (ru) 2011-10-31
CA2623595A1 (fr) 2007-03-22
EA200800682A1 (ru) 2008-10-30
EA015733B1 (ru) 2011-10-31
BRPI0615840A2 (pt) 2012-12-18
EA014411B1 (ru) 2010-12-30
EA201000183A1 (ru) 2010-06-30
CN101262767A (zh) 2008-09-10
EA201000184A1 (ru) 2010-06-30
WO2007031437A1 (fr) 2007-03-22
AR056068A1 (es) 2007-09-19
JP2009509936A (ja) 2009-03-12
AU2006290811B2 (en) 2011-11-03
US20090270255A1 (en) 2009-10-29
UA90017C2 (ru) 2010-03-25

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