EP1915530A1 - Cryogenic compressor comprising a high-pressure phase separator - Google Patents

Cryogenic compressor comprising a high-pressure phase separator

Info

Publication number
EP1915530A1
EP1915530A1 EP06754048A EP06754048A EP1915530A1 EP 1915530 A1 EP1915530 A1 EP 1915530A1 EP 06754048 A EP06754048 A EP 06754048A EP 06754048 A EP06754048 A EP 06754048A EP 1915530 A1 EP1915530 A1 EP 1915530A1
Authority
EP
European Patent Office
Prior art keywords
compressor
piston
cylinder wall
chamber
opening
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP06754048A
Other languages
German (de)
French (fr)
Other versions
EP1915530B1 (en
Inventor
Robert Adler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Linde GmbH
Original Assignee
Linde GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linde GmbH filed Critical Linde GmbH
Publication of EP1915530A1 publication Critical patent/EP1915530A1/en
Application granted granted Critical
Publication of EP1915530B1 publication Critical patent/EP1915530B1/en
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B15/00Pumps adapted to handle specific fluids, e.g. by selection of specific materials for pumps or pump parts
    • F04B15/06Pumps adapted to handle specific fluids, e.g. by selection of specific materials for pumps or pump parts for liquids near their boiling point, e.g. under subnormal pressure
    • F04B15/08Pumps adapted to handle specific fluids, e.g. by selection of specific materials for pumps or pump parts for liquids near their boiling point, e.g. under subnormal pressure the liquids having low boiling points
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B23/00Pumping installations or systems
    • F04B23/02Pumping installations or systems having reservoirs
    • F04B23/021Pumping installations or systems having reservoirs the pump being immersed in the reservoir
    • F04B23/023Pumping installations or systems having reservoirs the pump being immersed in the reservoir only the pump-part being immersed, the driving-part being outside the reservoir
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B37/00Pumps having pertinent characteristics not provided for in, or of interest apart from, groups F04B25/00 - F04B35/00
    • F04B37/10Pumps having pertinent characteristics not provided for in, or of interest apart from, groups F04B25/00 - F04B35/00 for special use
    • F04B37/18Pumps having pertinent characteristics not provided for in, or of interest apart from, groups F04B25/00 - F04B35/00 for special use for specific elastic fluids
    • F04B37/20Pumps having pertinent characteristics not provided for in, or of interest apart from, groups F04B25/00 - F04B35/00 for special use for specific elastic fluids for wet gases, e.g. wet air

Definitions

  • the invention relates to a compressor, in particular a compressor for cryogenic media, preferably for liquid hydrogen, comprising a compressor chamber surrounded by a cylinder wall, in which a compressor piston is moved linearly, a suction and a pressure valve, which are arranged in the region of the lower end position of the compressor piston are, and a liquid space at least partially surrounding the compressor space.
  • cryogenic media is to be understood below to mean so-called cryogenic liquids, in particular liquid hydrogen, liquefied natural gas, liquid nitrogen, liquid oxygen and other liquefied gases.
  • Compressors of all kinds are well known from the prior art. What they all have in common is that the medium to be compressed is fed into a compression chamber via a spring-loaded suction valve, compressed and then withdrawn from the compression chamber via a pressure valve.
  • the spring force of the spring used for closing a suction valve - in this case r is are preferably coil springs - is that a defined closure of the suction valve is achieved, so the suction valve is pressed into its valve seat and is closed thereby so chosen as a rule.
  • the object of the present invention is to provide a generic compressor, in particular a generic compressor for cryogenic media, in which the aforementioned disadvantages can be avoided.
  • a generic compressor which is characterized in that the cylinder wall has at least one opening, which corresponds to the liquid space, and at least one opening, through which gaseous medium can be discharged from the compressor space, with the openings at Locations of the cylinder wall are arranged, which are run over by the compressor piston.
  • the openings are designed in the form of one and / or more slots
  • the opening (s) through which gaseous medium can be discharged from the compressor chamber is or are operatively connected to a gas discharge line
  • the openings are arranged at locations on the cylinder wall which are only released by the compressor piston when it has arrived directly before its upper end position or in its upper end position.
  • the suction valve has at least one recess on its surface facing the compressor piston, the recess being designed in such a way that a vacuum is created between the suction valve and the compressor piston.
  • a compressor chamber R surrounded by a cylinder wall 1 is provided within a compressor housing V: in this a compressor piston K is moved linearly back and forth or up and down.
  • the two reversal points of the compressor piston K are referred to below as the lower and upper end positions of the compressor piston K.
  • a suction valve S which is loaded by a spring 5 and a spring-loaded pressure valve D which is only shown schematically. Both valves are pressed into their valve seats by means of the forces generated by the springs and thereby closed.
  • the compressor chamber R or the cylinder wall 1 are at least partially surrounded by a liquid chamber F, which is formed by the liquid medium to be compressed.
  • a gas volume or space G is formed above this liquid space F.
  • openings 2 and 3 are now provided.
  • one of the openings 2 corresponds to the liquid space, while gaseous medium can be discharged from the compressor space R via the other opening 3.
  • this gaseous medium is discharged from the compressor chamber R via a gas discharge line 4.
  • the gas produced by the suction process via the opening 2 can now be the Leave the compressor chamber R via the opening 3 and be replaced by the flowing liquid medium. This leads to an increase in the delivery rate and a reduction in the specific compression work.
  • the gas compressed by means of the piston K leaves the compression chamber R when the pressure valve D is open via the gas discharge line 6 and is then fed to a consumer via a high-pressure line.
  • the two openings 2 and 3 are preferably in the form of one and / or more slots.
  • the openings 2 and 3 are preferably arranged at locations on the cylinder wall 1 which are or will only be run over by the compressor piston K when it has reached the top end position or end position.
  • the compressor piston K is shown in its upper end position.
  • the two openings 2 and 3 are now released, so that liquid medium to be compressed can flow from the liquid space F into the compressor space R via the opening 2 (represented by the arrows drawn in parallel).
  • This inflowing liquid medium supplements the quantity of liquid F 'already in the compressor chamber R, which results from the liquid medium flowing in via the suction valve S during the suction tract.
  • the gaseous medium G ′ formed during the suction cycle can escape from the compressor chamber R via the opening 3 or the gas discharge line 4. This escape of the gaseous medium is supported by the liquid medium flowing in via the opening 2, since the gaseous medium G ′ located in the compression space R is displaced from the compression space R by the inflowing liquid medium.
  • Compressor piston K facing surface has at least one recess; this is designed such that a vacuum is created between the suction valve S and the compressor piston K.
  • the shape of the depression (s) to be provided on the surface of the suction valve S facing the compressor piston K can in principle be chosen as desired; the only thing that ultimately matters is that a vacuum is formed between suction valve S and compressor piston K. It is also possible to provide only one or more wells.
  • Compressor space increases, which results in a higher delivery rate of the compressor according to the invention.
  • a reduction in the specific compressor capacity based on the amount of the pumped or compressed medium can thus be achieved.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Compressor (AREA)
  • Details Of Reciprocating Pumps (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
  • Compressors, Vaccum Pumps And Other Relevant Systems (AREA)

Abstract

An apparatus and method for compressing a cryogenic media is disclosed. A compressor includes a compressor chamber surrounded by a cylinder wall in which a compressor piston is moved in a linear manner, a suction valve and a pressure valve, which are arranged in the region of the lower end position of the compressor piston, and a liquid chamber which at least partially surrounds the compressor chamber. The cylinder wall defines at least one opening, which corresponds to the liquid chamber, and at least one opening, via which the gaseous medium can be extracted from the compressor chamber, where the openings are located at points on the cylinder wall that are passed by the compressor piston.

Description

Beschreibung description
Kryoverdichter mit HochdruckphasentrennerCryogenic compressor with high pressure phase separator
Die Erfindung betrifft einen Verdichter, insbesondere einen Verdichter für kryogene Medien, vorzugsweise für flüssigen Wasserstoff, aufweisend einen von einer Zylinderwand umgebenen Verdichterraum, in dem ein Verdichterkolben linear bewegt wird, ein Saug- und ein Druckventil, die im Bereich der unteren Endlage des Verdichterkolbens angeordnet sind, und einen den Verdichterraum zumindest teilweise umgebenden Flüssigkeitsraum.The invention relates to a compressor, in particular a compressor for cryogenic media, preferably for liquid hydrogen, comprising a compressor chamber surrounded by a cylinder wall, in which a compressor piston is moved linearly, a suction and a pressure valve, which are arranged in the region of the lower end position of the compressor piston are, and a liquid space at least partially surrounding the compressor space.
Unter dem Begriff "kryogene Medien" seien nachfolgend sog. tiefkalte Flüssigkeiten, insbesondere flüssiger Wasserstoff, verflüssigtes Erdgas, flüssiger Stickstoff, flüssiger Sauerstoff und andere verflüssigte Gase zu verstehen.The term “cryogenic media” is to be understood below to mean so-called cryogenic liquids, in particular liquid hydrogen, liquefied natural gas, liquid nitrogen, liquid oxygen and other liquefied gases.
Verdichter jeglicher Art sind aus dem Stand der Technik hinlänglich bekannt. Ihnen allen ist gemein, dass über ein federbelastetes Saugventil das zu verdichtende Medium in einen Verdichterraum geführt, verdichtet und anschließend über ein Druckventil aus dem Verdichterraum abgezogen wird.Compressors of all kinds are well known from the prior art. What they all have in common is that the medium to be compressed is fed into a compression chamber via a spring-loaded suction valve, compressed and then withdrawn from the compression chamber via a pressure valve.
Die Federkraft der für das Schließen eines Saugventiles verwendeten Feder - hierbei r handelt es sich vorzugsweise um Schraubenfedern - wird im Regelfall so gewählt, dass ein definiertes Schließen des Saugventiles erreicht wird, das Saugventil also in seinen Ventilsitz gedrückt und dadurch verschlossen wird.The spring force of the spring used for closing a suction valve - in this case r is are preferably coil springs - is that a defined closure of the suction valve is achieved, so the suction valve is pressed into its valve seat and is closed thereby so chosen as a rule.
Während des Saugtaktes des Verdichters - dabei wird der Verdichterkolben von der unteren in die obere Endlage bewegt - müssen die Federkraft und in Abhängigkeit von der Anordnung des Saugventiles (zumindest teilweise) dessen Gewichtskraft durch das in den Verdichterraum einströmende Medium überwunden werden.During the suction stroke of the compressor - the compressor piston is moved from the lower to the upper end position - the spring force and depending on the arrangement of the suction valve (at least partially) its weight must be overcome by the medium flowing into the compressor chamber.
Insbesondere dann, wenn mittels des Verdichters ein kryogenes Medium, wie beispielsweise flüssiger Wasserstoff, angesaugt wird, kommt es aufgrund der bisher verwendeten Saugventilkonstruktionen zu nicht unerheblichen Verlusten bzgl. der Förderleistung, da das über das Saugventil in den Verdichterraum eintretende Medium beim Überwinden der vorbeschriebenen Kräfte des Saugventiles zumindest teilweise verdampft.In particular, if a cryogenic medium, such as liquid hydrogen, is sucked in by means of the compressor, the suction valve designs used to date lead to considerable losses in terms of the delivery capacity, since the medium entering the compressor chamber via the suction valve evaporates at least partially when overcoming the above-described forces of the suction valve.
Dies hat zur Folge, dass sich der Flüssiganteil des zu verdichtenden Mediums verringert, woraus eine Verringerung der Förderleistung und eine Erhöhung der spezifischen Verdichterleistung resultieren.This has the consequence that the liquid portion of the medium to be compressed is reduced, which results in a reduction in the delivery capacity and an increase in the specific compressor capacity.
Aufgabe der vorliegenden Erfindung ist es, einen gattungsgemäßen Verdichter, insbesondere einen gattungsgemäßen Verdichter für kryogene Medien, anzugeben, bei dem die vorgenannten Nachteile vermieden werden können.The object of the present invention is to provide a generic compressor, in particular a generic compressor for cryogenic media, in which the aforementioned disadvantages can be avoided.
Zur Lösung dieser Aufgabe wird ein gattungsgemäßer Verdichter vorgeschlagen, der dadurch gekennzeichnet ist, dass die Zylinderwand wenigstens eine Öffnung, die mit dem Flüssigkeitsraum korrespondiert, und wenigstens eine Öffnung, über die gasförmiges Medium aus dem Verdichterraum abgeführt werden kann, aufweist, wobei die Öffnungen an Stellen der Zylinderwand angeordnet sind, die von dem Verdichterkolben überfahren werden.To solve this problem, a generic compressor is proposed, which is characterized in that the cylinder wall has at least one opening, which corresponds to the liquid space, and at least one opening, through which gaseous medium can be discharged from the compressor space, with the openings at Locations of the cylinder wall are arranged, which are run over by the compressor piston.
Weitere vorteilhafte Ausgestaltungen des erfindungsgemäßen Verdichters sind dadurch gekennzeichnet, dassFurther advantageous embodiments of the compressor according to the invention are characterized in that
die Ausbildung der Öffnungen in Form eines und/oder mehrerer Schlitze erfolgt,the openings are designed in the form of one and / or more slots,
die Öffnung(en), über die gasförmiges Medium aus dem Verdichterraum abgeführt werden kann, mit einer Gasabführleitung in Wirkverbindung steht bzw. stehen,the opening (s) through which gaseous medium can be discharged from the compressor chamber is or are operatively connected to a gas discharge line,
die Öffnungen an Stellen der Zylinderwand angeordnet sind, die erst dann von dem Verdichterkolben freigegeben werden, wenn dieser unmittelbar vor seiner oberen Endlage oder in seiner oberen Endlage angelangt ist.the openings are arranged at locations on the cylinder wall which are only released by the compressor piston when it has arrived directly before its upper end position or in its upper end position.
das Saugventil auf seiner dem Verdichterkolben zugewandten Fläche wenigstens eine Vertiefung aufweist, wobei die Vertiefung derart ausgebildet ist, dass zwischen dem Saugventil und dem Verdichterkolben ein Unterdruck entsteht. Der erfindungsgemäße Verdichter mit Hochdruckphaseπtrenner sowie weitere Ausgestaltungen desselben, die Gegenstände der abhängigen Patentansprüche darstellen, seien anhand des in der Figur dargestellten Ausführungsbeispieles näher erläutert. Die Figur zeigt eine seitliche schematisierte Schnittdarstellung durch eine mögliche Ausführungsform des erfindungsgemäßen Verdichters mit Hochdruckphasentrenner.the suction valve has at least one recess on its surface facing the compressor piston, the recess being designed in such a way that a vacuum is created between the suction valve and the compressor piston. The compressor according to the invention with a high-pressure phase separator and further refinements of the same, which are the subject of the dependent claims, are explained in more detail with reference to the exemplary embodiment shown in the figure. The figure shows a schematic side sectional view through a possible embodiment of the compressor according to the invention with high-pressure phase separator.
Innerhalb eines Verdichtergehäuses V ist ein von einer Zylinderwand 1 umgebener Verdichterraum R vorgesehen: In diesem wird ein Verdichterkolben K linear hin und her bzw. auf und ab bewegt. Die beiden Umkehrpunkte des Verdichterkolbens K werden nachfolgend als untere und obere Endlage des Verdichterkolbens K bezeichnet.A compressor chamber R surrounded by a cylinder wall 1 is provided within a compressor housing V: in this a compressor piston K is moved linearly back and forth or up and down. The two reversal points of the compressor piston K are referred to below as the lower and upper end positions of the compressor piston K.
Am Boden des Verdichterraumes R ist ein mittels einer Feder 5 belastetes Saugventil S und ein - lediglich schematisch dargestelltes - federbelastetes Druckventil D angeordnet. Beide Ventile werden über die mittels der Federn erzeugten Kräfte in ihre Ventilsitze gedrückt und dadurch geschlossen. Der Verdichterraum R bzw. die Zylinderwand 1 sind zumindest teilweise von einem Flüssigkeitsraum F, der durch das zu verdichtende, flüssige Medium gebildet wird, umgeben. Oberhalb dieses Flüssigkeitsraumes F ist ein Gasvolumen bzw. -räum G ausgebildet.At the bottom of the compressor chamber R there is a suction valve S which is loaded by a spring 5 and a spring-loaded pressure valve D which is only shown schematically. Both valves are pressed into their valve seats by means of the forces generated by the springs and thereby closed. The compressor chamber R or the cylinder wall 1 are at least partially surrounded by a liquid chamber F, which is formed by the liquid medium to be compressed. A gas volume or space G is formed above this liquid space F.
Zum Stand der Technik zählende Verdichterkonstruktionen weisen die in der Figur dargestellten Öffnungen 2 und 3 nicht auf. Während des Saugtaktes - dabei bewegt sich der Verdichterkolben K aus der unteren in die obere Endlage - strömt über das Saugventil S flüssiges Medium aus dem Flüssigkeitsraum F in den Verdichterraum R, wobei das flüssige Medium - wie eingangs erläutert - zumindest teilweise verdampft.Compressor designs belonging to the prior art do not have the openings 2 and 3 shown in the figure. During the suction cycle - the compressor piston K moves from the lower to the upper end position - liquid medium flows from the liquid chamber F into the compressor chamber R via the suction valve S, the liquid medium - as explained at the beginning - at least partially evaporating.
Erfindungsgemäß sind nunmehr wenigstens zwei Öffnungen 2 und 3 vorgesehen. Hierbei korrespondiert eine der Öffnungen 2 mit dem Flüssigkeitsraum, während über die andere Öffnung 3 gasförmiges Medium aus dem Verdichterraum R abgeführt werden kann. Bei dem in der Figur dargestellten Ausführungsbeispiel des erfindungsgemäßen Verdichters erfolgt dieses Abführen des gasförmigen Mediums aus dem Verdichterraum R über eine Gasabführleitung 4. Das durch den Ansaugvorgang über die Öffnung 2 entstandene Gas kann nunmehr den Verdichterraum R über die Öffnung 3 verlassen und durch nachströmendes, flüssiges Medium ersetzt werden. Dies führt zu einer Steigerung der Förderleistung und einer Senkung der spezifischen Verdichtungsarbeit.According to the invention, at least two openings 2 and 3 are now provided. Here, one of the openings 2 corresponds to the liquid space, while gaseous medium can be discharged from the compressor space R via the other opening 3. In the embodiment of the compressor according to the invention shown in the figure, this gaseous medium is discharged from the compressor chamber R via a gas discharge line 4. The gas produced by the suction process via the opening 2 can now be the Leave the compressor chamber R via the opening 3 and be replaced by the flowing liquid medium. This leads to an increase in the delivery rate and a reduction in the specific compression work.
Das mittels des Kolbens K verdichtete Gas verlässt den Verdichterraum R bei geöffnetem Druckventil D über die Gasabführleitung 6 und wird anschließend über eine Hochdruckleitung einem Verbraucher zugeführt.The gas compressed by means of the piston K leaves the compression chamber R when the pressure valve D is open via the gas discharge line 6 and is then fed to a consumer via a high-pressure line.
Die beiden Öffnungen 2 und 3 sind entsprechend einer vorteilhaften Ausgestaltung des erfindungsgemäßen Verdichters vorzugsweise in Form eines und/oder mehrerer Schlitze ausgebildet.According to an advantageous embodiment of the compressor according to the invention, the two openings 2 and 3 are preferably in the form of one and / or more slots.
Die Öffnungen 2 und 3 sind vorzugsweise an Stellen der Zylinderwand 1 angeordnet, die erst dann von dem Verdichterkolben K überfahren sind bzw. werden, wenn dieser unmittelbar vor seiner oberen Endlage oder in seiner Endlage angelangt ist.The openings 2 and 3 are preferably arranged at locations on the cylinder wall 1 which are or will only be run over by the compressor piston K when it has reached the top end position or end position.
In der Figur sei der Verdichterkolben K in seiner oberen Endlage dargestellt. Die beiden Öffnungen 2 und 3 sind nunmehr freigegeben, so dass über die Öffnung 2 zu verdichtendes, flüssiges Medium aus dem Flüssigkeitsraum F in den Verdichterraum R einströmen kann (dargestellt durch die parallel gezeichneten Pfeile). Dieses einströmende flüssige Medium ergänzt die bereits im Verdichterraum R befindliche Flüssigkeitsmenge F', die aus dem über das Saugventil S während des Saugtraktes einströmenden flüssigen Medium resultiert.In the figure, the compressor piston K is shown in its upper end position. The two openings 2 and 3 are now released, so that liquid medium to be compressed can flow from the liquid space F into the compressor space R via the opening 2 (represented by the arrows drawn in parallel). This inflowing liquid medium supplements the quantity of liquid F 'already in the compressor chamber R, which results from the liquid medium flowing in via the suction valve S during the suction tract.
Über die Öffnung 3 bzw. die Gasabführleitung 4 kann das während des Saugtaktes gebildete gasförmige Medium G' aus dem Verdichterraum R entweichen. Dieses Entweichen des gasförmigen Mediums wird durch das über die Öffnung 2 einströmende flüssige Medium unterstützt, da durch das einströmende flüssige Medium das im Verdichterraum R befindliche gasförmige Medium G' aus dem Verdichterraum R verdrängt wird.The gaseous medium G ′ formed during the suction cycle can escape from the compressor chamber R via the opening 3 or the gas discharge line 4. This escape of the gaseous medium is supported by the liquid medium flowing in via the opening 2, since the gaseous medium G ′ located in the compression space R is displaced from the compression space R by the inflowing liquid medium.
Im Gegensatz zu den bis dato bekannten Verdichterkonstruktionen muss der zwangsläufig entstehende Gasanteil G' des zu verdichtenden Mediums nunmehr nicht mehr mitverdichtet werden, da er vor der Verdichtung aus dem Verdichterraum R abgeführt werden kann. Durch das Vorsehen der Öffnung 2, die mit dem Flüssigkeitsraum F korrespondiert, wird nunmehr sicher gestellt, dass der Verdichterraum R vor der Verdichtung vollständig mit flüssigem Medium F' befüllt wird.In contrast to the previously known compressor designs, the inevitable gas fraction G 'of the medium to be compressed no longer has to be compressed, since it can be removed from the compression chamber R before compression. By providing the opening 2, which with the Liquid space F corresponds, it is now ensured that the compressor space R is completely filled with liquid medium F 'before compression.
In der Figur nicht dargestellt ist eine weitere vorteilhafte Ausgestaltung des erfindungsgemäßen Verdichters, gemäß der das Saugventil S auf seiner demNot shown in the figure is a further advantageous embodiment of the compressor according to the invention, according to which the suction valve S on its
Verdichterkolben K zugewandten Fläche wenigstens eine Vertiefung aufweist; diese ist hierbei derart ausgebildet, dass zwischen dem Saugventil S und dem Verdichterkolben K ein Unterdruck entsteht.Compressor piston K facing surface has at least one recess; this is designed such that a vacuum is created between the suction valve S and the compressor piston K.
Bewegt sich der Verdichterkolben K nunmehr während des Saugtaktes nach oben, wird das Saugventil S aufgrund des entstandenen Unterdruckes zwischen ihm und dem Verdichterkolben K von diesem bewegt bzw. angehoben.If the compressor piston K now moves upwards during the suction cycle, the suction valve S is moved or raised by the latter because of the negative pressure which has developed between it and the compressor piston K.
Die Form der auf der dem Verdichterkolben K zugewandten Fläche des Saugventiles S vorzusehenden Vertiefung(en) kann im Prinzip beliebig gewählt werden; entscheidend ist letztendlich nur, dass es zur Ausbildung eines Unterdruckes zwischen Saugventil S und Verdichterkolben K kommt. Auch können lediglich eine oder aber auch mehrere Vertiefungen vorgesehen werde.The shape of the depression (s) to be provided on the surface of the suction valve S facing the compressor piston K can in principle be chosen as desired; the only thing that ultimately matters is that a vacuum is formed between suction valve S and compressor piston K. It is also possible to provide only one or more wells.
Mittels der vorbeschriebenen Erfindung wird erreicht, dass der Flüssiganteil imBy means of the above-described invention it is achieved that the liquid portion in the
Verdichterraum ansteigt, woraus eine höhere Förderleistung des erfindungsgemäßen Verdichters resultiert. Somit kann eine Verringerung der spezifischen Verdichterleistung bezogen auf die Menge des geförderten bzw. verdichteten Mediums erzielt werden.Compressor space increases, which results in a higher delivery rate of the compressor according to the invention. A reduction in the specific compressor capacity based on the amount of the pumped or compressed medium can thus be achieved.
Die mit dem erfindungsgemäßen Verdichter verbundenen Vorteile werden durch eine gegenüber dem Stand der Technik geringfügig kompliziertere Verdichterkonstruktion erkauft; die mit ihr verbundenen Mehrkosten werden jedoch durch die erreichten Vorteile mehr als kompensiert. The advantages associated with the compressor according to the invention are paid for by a compressor construction which is slightly more complicated than in the prior art; however, the additional costs associated with it are more than offset by the advantages achieved.

Claims

Patentansprüche Claims
1. Verdichter, insbesondere Verdichter für kryogene Medien, vorzugsweise für flüssigen Wasserstoff, aufweisend einen von einer Zylinderwand umgebenen Verdichterraum, in dem ein Verdichterkolben linear bewegt wird, ein Saug- und ein Druckventil, die im Bereich der unteren Endlage des Verdichterkolbens angeordnet sind, und einen den Verdichterraum zumindest teilweise umgebenden Flüssigkeitsraum, dadurch gekennzeichnet, dass die Zylinderwand (1 ) wenigstens eine Öffnung (2), die mit dem Flüssigkeitsraum (F) korrespondiert, und wenigstens eine Öffnung (3), über die gasförmiges Medium aus dem Verdichterraum (R) abgeführt werden kann, aufweist, wobei die Öffnungen (2, 3) an Stellen der Zylinderwand (1 ) angeordnet sind, die von dem Verdichterkolben (K) überfahren werden.1. Compressor, in particular compressor for cryogenic media, preferably for liquid hydrogen, comprising a compressor chamber surrounded by a cylinder wall, in which a compressor piston is moved linearly, a suction and a pressure valve, which are arranged in the region of the lower end position of the compressor piston, and a liquid space at least partially surrounding the compressor space, characterized in that the cylinder wall (1) has at least one opening (2) which corresponds to the liquid space (F) and at least one opening (3) through which gaseous medium from the compressor space (R ) can be removed, the openings (2, 3) being arranged at locations on the cylinder wall (1) which are run over by the compressor piston (K).
2. Verdichter nach Anspruch 1 , dadurch gekennzeichnet, dass die Öffnungen (2, 3) in Form eines und/oder mehrerer Schlitze ausgebildet sind.2. Compressor according to claim 1, characterized in that the openings (2, 3) are designed in the form of one and / or more slots.
3. Verdichter nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass die Öffnung(en) (3), über die gasförmiges Medium aus dem Verdichterraum (R) abgeführt werden kann, mit einer Gasabführleitung (4) in Wirkverbindung steht bzw. stehen.3. Compressor according to claim 1 or 2, characterized in that the opening (s) (3), via which gaseous medium can be discharged from the compressor chamber (R), is or are operatively connected to a gas discharge line (4).
4. Verdichter nach einem der vorhergehenden Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Öffnungen (2, 3) an Stellen der Zylinderwand (1 ) angeordnet sind, die erst dann von dem Verdichterkolben (K) freigegeben werden, wenn dieser unmittelbar vor seiner oberen Endlage oder in seiner oberen Endlage angelangt ist.4. Compressor according to one of the preceding claims 1 to 3, characterized in that the openings (2, 3) are arranged at locations on the cylinder wall (1) which are only released by the compressor piston (K) when it is immediately in front of it has reached the upper end position or in its upper end position.
5. Verdichter nach einem der vorhergehenden Ansprüche 1 bis 4, dadurch gekennzeichnet, dass das Saugventil (S) auf seiner dem Verdichterkolben (K) zugewandten Fläche wenigstens eine Vertiefung aufweist, wobei die Vertiefung derart ausgebildet ist, dass zwischen dem Saugventil (S) und dem Verdichterkolben (K) ein Unterdruck entsteht. 5. Compressor according to one of the preceding claims 1 to 4, characterized in that the suction valve (S) on its surface facing the compressor piston (K) has at least one depression, the depression being designed such that between the suction valve (S) and a vacuum is created in the compressor piston (K).
EP06754048A 2005-06-17 2006-06-01 Cryogenic compressor comprising a high-pressure phase separator Not-in-force EP1915530B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005028200A DE102005028200A1 (en) 2005-06-17 2005-06-17 Cryo-compressor with high-pressure phase separator
PCT/EP2006/005241 WO2006133813A1 (en) 2005-06-17 2006-06-01 Cryogenic compressor comprising a high-pressure phase separator

Publications (2)

Publication Number Publication Date
EP1915530A1 true EP1915530A1 (en) 2008-04-30
EP1915530B1 EP1915530B1 (en) 2009-01-28

Family

ID=36655093

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06754048A Not-in-force EP1915530B1 (en) 2005-06-17 2006-06-01 Cryogenic compressor comprising a high-pressure phase separator

Country Status (6)

Country Link
US (1) US20080213110A1 (en)
EP (1) EP1915530B1 (en)
JP (1) JP4988726B2 (en)
AT (1) ATE422026T1 (en)
DE (2) DE102005028200A1 (en)
WO (1) WO2006133813A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4840644B2 (en) * 2006-02-22 2011-12-21 株式会社ミクニ Plunger pump
EP2604840A1 (en) * 2011-12-16 2013-06-19 Astrium GmbH Conveyor device for cryogenic liquids
CN106979135B (en) * 2017-03-30 2018-07-03 宁波胜杰康生物科技有限公司 Cryogen pump group part
US10774820B2 (en) 2017-11-13 2020-09-15 Caterpillar Inc. Cryogenic pump
DE102017222381A1 (en) * 2017-12-11 2019-06-13 Robert Bosch Gmbh LPG pump and method for operating a LPG pump

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2054710A (en) * 1934-05-01 1936-09-15 Okada Jiro Low temperature liquid pump
US2730957A (en) * 1949-04-16 1956-01-17 Union Carbide & Carbon Corp Apparatus for pumping a volatile liquid
US2888879A (en) * 1953-09-30 1959-06-02 Union Carbide Corp Immersion pump for liquefied gases
US2931313A (en) * 1955-06-24 1960-04-05 Joy Mfg Co Pump
US3083648A (en) * 1959-02-25 1963-04-02 Superior Air Products Co Liquefied gas pump
US3252291A (en) * 1963-04-04 1966-05-24 Bendix Balzers Vacuum Inc Cryo-pumps
US3212280A (en) * 1963-11-22 1965-10-19 Air Prod & Chem Volatile liquid pumping system
US3263622A (en) * 1964-06-01 1966-08-02 Jr Lewis Tyree Pump
FR1464689A (en) * 1965-10-11 1967-01-06 Radiotechnique Improvements to pumps for liquefied gas
US3986796A (en) * 1972-07-06 1976-10-19 Moiroux Auguste F Direct action compressor fitted with a one-piece piston
US4156584A (en) * 1976-07-19 1979-05-29 Carpenter Technology Corporation Liquid cryogen pump
US4266404A (en) * 1979-08-06 1981-05-12 Letcher T. White Method and apparatus for conserving waste energy
US4441587A (en) * 1980-01-14 1984-04-10 Patten Kenneth S Internal combustion engine or pumping device
US4396362A (en) * 1980-10-31 1983-08-02 Union Carbide Corporation Cryogenic reciprocating pump
AU564301B2 (en) * 1981-08-13 1987-08-06 Commonwealth Scientific And Industrial Research Organisation Reciprocatory piston and cylinder machine
US4811558A (en) * 1981-10-13 1989-03-14 Baugh Benton F System and method for providing compressed gas
EP0250613B1 (en) * 1986-06-23 1991-07-17 Leybold Aktiengesellschaft Cryopump and method of operating this cryopump
DE3621727A1 (en) * 1986-06-28 1988-01-14 Deutsche Forsch Luft Raumfahrt PISTON PUMP FOR CRYOGENIC LIQUIDS
US5398591A (en) * 1993-01-22 1995-03-21 Omega Systems, Inc. Distillate fuel oil/air-fired, rapid-fire cannon
US5638776A (en) * 1993-02-04 1997-06-17 Raynor; Gilbert E. Internal combustion engine
US5702238A (en) * 1996-02-06 1997-12-30 Daniel Cecil Simmons Direct drive gas compressor with vented distance piece
NL1010144C2 (en) * 1998-09-21 2000-03-22 Doornes Transmissie Bv Continuously variable transmission.
BR9805280A (en) * 1998-11-24 2000-06-06 Brasil Compressores Sa Reciprocating compressor with linear motor
DE10000675C2 (en) * 2000-01-11 2001-11-15 Otten Ernst Wilhelm Linear feedthrough, device and method for the highly productive generation of highly nuclear-polarized helium-3 gas
US6584791B2 (en) * 2001-04-05 2003-07-01 Bristol Compressors, Inc. Pressure equalization system and method
US6663350B2 (en) * 2001-11-26 2003-12-16 Lewis Tyree, Jr. Self generating lift cryogenic pump for mobile LNG fuel supply system
JP2004019544A (en) * 2002-06-17 2004-01-22 Nec Kansai Ltd Chemical pump with bubble-releasing mechanism
US7381035B2 (en) * 2004-04-14 2008-06-03 Nordson Corporation Piston pump with check shaft
DE102005024888A1 (en) * 2005-05-31 2006-12-07 Linde Ag Cryo compressor with laterally arranged pressure valve
US7410348B2 (en) * 2005-08-03 2008-08-12 Air Products And Chemicals, Inc. Multi-speed compressor/pump apparatus
US7603858B2 (en) * 2007-05-11 2009-10-20 Lawrence Livermore National Security, Llc Harmonic engine

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2006133813A1 *

Also Published As

Publication number Publication date
JP2008544135A (en) 2008-12-04
EP1915530B1 (en) 2009-01-28
JP4988726B2 (en) 2012-08-01
WO2006133813A1 (en) 2006-12-21
US20080213110A1 (en) 2008-09-04
DE102005028200A1 (en) 2006-12-21
ATE422026T1 (en) 2009-02-15
DE502006002758D1 (en) 2009-03-19

Similar Documents

Publication Publication Date Title
EP1915530B1 (en) Cryogenic compressor comprising a high-pressure phase separator
DE202008001458U1 (en) High pressure valve assembly
EP0927305A1 (en) Piston pump
DE3005608A1 (en) PISTON PUMP
EP1650434B1 (en) Multi-stage piston type compressor with reduced power input during idle running
EP2670971A2 (en) Pump unit for a high-pressure pump
DE102013210036A1 (en) High pressure pump for a fuel injection system
WO2007137941A1 (en) Radial piston pump for supplying fuel at high pressure to an internal combustion engine
EP1886023B1 (en) Cryocompressor having a laterally arranged pressure valve
AT265498B (en) Device for stepless regulation of the delivery rate on piston compressors
WO2006133814A1 (en) Cryocompressor suction valve
WO1998009079A1 (en) Inlet valve with a choke effect and multi-stage piston vacuum pump
DE10219007B4 (en) Reduction valve for compressed gas
DE4107846A1 (en) Liquid gas pump for use with cryogenic hydrogen@ in vehicle - is acted on by pressure from nitrogen@ reservoir behind compression piston
DE102005024105A1 (en) Intake valve for a compressor, using cryogenic media, is structured so that the sum of the weight force and the closing spring force virtually equal zero to prevent looses of media and delivery performance
DE102007027950A1 (en) Rotatable internal combustion engine with external compressor
WO2007076917A1 (en) Arrangement for compressing cryogenic fluids
DE254590C (en)
DE102017222204A1 (en) Fuel delivery device for cryogenic fuels
DE102014216282A1 (en) Piston pump with mechanical stroke stop for diaphragm spring
WO2006128580A1 (en) Cryocompressor having a double pressure valve
DE102021118962A1 (en) Control flow control valve for scroll compressors
DE78806C (en) Hydraulic press with two-room accumulator
DE625953C (en) Fuel injection device for internal combustion engines
DE96580C (en)

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20071018

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

DAX Request for extension of the european patent (deleted)
GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: LINDE AG

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REF Corresponds to:

Ref document number: 502006002758

Country of ref document: DE

Date of ref document: 20090319

Kind code of ref document: P

NLV1 Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090509

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

RAP2 Party data changed (patent owner data changed or rights of a patent transferred)

Owner name: LINDE AG

REG Reference to a national code

Ref country code: IE

Ref legal event code: FD4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090629

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090528

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090428

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

BERE Be: lapsed

Owner name: LINDE A.G.

Effective date: 20090630

26N No opposition filed

Effective date: 20091029

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090428

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090601

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20100601

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090630

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090601

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100630

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090729

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100601

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090128

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 11

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 12

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20180522

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20180411

Year of fee payment: 13

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 502006002758

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190630