EP1903096A1 - Reinigungsprodukt in fester Form für Glasoberflächen eines Fahrzeugs - Google Patents
Reinigungsprodukt in fester Form für Glasoberflächen eines Fahrzeugs Download PDFInfo
- Publication number
- EP1903096A1 EP1903096A1 EP07356122A EP07356122A EP1903096A1 EP 1903096 A1 EP1903096 A1 EP 1903096A1 EP 07356122 A EP07356122 A EP 07356122A EP 07356122 A EP07356122 A EP 07356122A EP 1903096 A1 EP1903096 A1 EP 1903096A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- product
- sodium
- ingredient
- cleaning
- vehicle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 23
- 239000007787 solid Substances 0.000 title claims abstract description 15
- 239000008188 pellet Substances 0.000 claims abstract description 24
- 239000004615 ingredient Substances 0.000 claims abstract description 18
- 230000008014 freezing Effects 0.000 claims abstract description 13
- 238000007710 freezing Methods 0.000 claims abstract description 13
- 239000007864 aqueous solution Substances 0.000 claims abstract description 11
- 238000004090 dissolution Methods 0.000 claims abstract description 10
- 239000000243 solution Substances 0.000 claims abstract description 10
- 239000012459 cleaning agent Substances 0.000 claims abstract description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 12
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 11
- 239000001632 sodium acetate Substances 0.000 claims description 10
- 235000017281 sodium acetate Nutrition 0.000 claims description 10
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 9
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 8
- 235000011152 sodium sulphate Nutrition 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 6
- 239000004327 boric acid Substances 0.000 claims description 5
- 150000002191 fatty alcohols Chemical class 0.000 claims description 5
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 5
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 5
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 4
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 4
- 239000003086 colorant Substances 0.000 abstract description 2
- 208000006558 Dental Calculus Diseases 0.000 abstract 1
- 239000000047 product Substances 0.000 description 35
- 150000001875 compounds Chemical class 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011521 glass Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000007937 lozenge Substances 0.000 description 3
- 235000010603 pastilles Nutrition 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 2
- 229940043264 dodecyl sulfate Drugs 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 235000011056 potassium acetate Nutrition 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000003826 tablet Substances 0.000 description 2
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000037406 food intake Effects 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- -1 sodium acetate and Chemical class 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- NEUOBESLMIKJSB-UHFFFAOYSA-J tetrasodium;tetraacetate Chemical compound [Na+].[Na+].[Na+].[Na+].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O NEUOBESLMIKJSB-UHFFFAOYSA-J 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0052—Gas evolving or heat producing compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
Definitions
- the invention relates to a glass surface cleaning product, especially a vehicle, of the type comprising at least one cleaning agent, the product being in solid form and being adapted to form an aqueous cleaning solution.
- Glazed surfaces refer to both the windshield and the side and rear windows of a land, rail, sea or air vehicle.
- pellets are known to be diluted in deionized water.
- US-A-4,502,892 describes such a lozenge that is effervescent.
- This pellet has a composition that lowers the freezing point of the aqueous solution to about -10 ° C.
- This pellet comprises a phosphate salt, potentially polluting.
- the invention proposes, alternatively, an effective product in any season, directly usable in the windshield washer reservoir and avoiding any risk of overturning when filling the tank, while avoiding the use of a phosphate salt.
- the subject of the invention is a cleaning product for glazed surfaces, in particular of a vehicle, of the type comprising at least one cleaning agent, the product being in solid form and being adapted to form an aqueous cleaning solution.
- the ingredient, which is in solid form and is suitable for lowering the freezing point of the aqueous solution to below 0 ° C comprises sodium acetate in concentrations of 25 to 50% by weight relative to the total mass and sodium sulphate in concentrations of 5 to 11% by weight relative to the total mass.
- this product in solid form and easy to implement, allows use in both summer and winter by limiting the risk of freezing the solution, while avoiding the environmental problems related to phosphate.
- a vehicle whether it is a motor vehicle of the car, bus or truck type, of a rail vehicle, such as a power car or a wagon, of an aircraft or a ship
- the surfaces glazed, whether front, rear or side, are exposed to soiling such as dust and / or film road.
- soiling such as dust and / or film road.
- the vehicles are therefore equipped with a device for cleaning at least some parts of these glazed surfaces.
- a device comprises, in addition to windscreen wiper blades, a reservoir for a cleaning liquid. This tank supplies pressurized liquid wiper blades. It is frequent that in winter the outlets of the liquid are obstructed by ice. This ice is formed by the solidification of the cleaning liquid.
- the glass surface cleaning product object of the invention is, before its implementation in the windshield washer reservoir, in a solid and compact form.
- These include pellets whose dimensions and shapes are adapted to be easily inserted into the washer reservoir, through the neck of the latter. These pellets, cylindrical, have a diameter of about 20 millimeters and a height of about 5 millimeters.
- the product is in the form of a powder.
- the product is easy to dissolve, with a concentration or in a predetermined concentration range, in a volume of water corresponding to a capacity commonly encountered for tanks of land vehicles, that is to say between 2 liters and 6 liters.
- the product is adapted to be dissolved in tap water without requiring distilled or demineralized water as the solvent.
- the product is adapted to be easily and completely dissolved in the windshield washer reservoir, without requiring stirring, heating or the addition of another ingredient to increase the dissolution.
- no undissolved solid particle must remain in the final solution because this particle may clog the product outlets.
- This cleaning product includes different ingredients. It contains at least two ingredients or compounds having a cleaning action, that is to say ingredients for removing the road film and / or dust and eliminate animal stains such as insects or bugs. bird droppings.
- an anionic surfactant-type compound for example sodium lauryl sulphate
- a nonionic surfactant-type compound for example ethoxylated fatty alcohol
- these two compounds are, in this case, associated with a sequestering type compound for complexing the limestone of the dilution water.
- a sequestering type compound for complexing the limestone of the dilution water.
- Such a compound also makes it possible to limit the risk of scaling, in the case of hard water. This is, for example, EDTA (ethylene diamine sodium tetraacetate).
- other products avoiding scale can be used, it is for example sequestering sodium nitrilotriacetate, sodium gluconate or phosphonate type.
- the anionic surfactant may be of the sulfonate type and the nonionic surfactant of the polyglucoside type.
- these compounds are chosen to be used in solid form and, in particular, be pelleted easily while having a high solubility.
- the production of pellets is carried out by techniques known per se, for example using a tablet-type device.
- At least one and preferably two ingredients or compounds are combined to lower the freezing point of the final aqueous solution below 0 ° C.
- antifreeze is added in solid form so as to avoid the formation of crystals in the final aqueous solution from 0 ° C.
- salts such as sodium acetate and, if necessary, sodium sulfate are used. At least one of these salts, in this case sodium acetate, is incorporated in a proportion of up to 50% by weight relative to the total mass.
- salts such as sodium chloride, calcium chloride or potassium acetate, in proportions ranging from 25 to 50% by weight relative to the total mass.
- concentration of salts is increased, the freezing point of the final aqueous solution is lowered accordingly.
- a concentration of 50% of sodium acetate or of potassium acetate makes it possible to lower the freezing point to -4 ° C. with a dosage of one tablet per 2 liters of water.
- the freezing point is lowered to -8 ° C with two pellets per 2 liters of water or three pellets per 2.5 liters.
- the maximum useful concentration in salts is about 1% by weight. Indeed, at high concentrations, such a cleaning product, because it is an aqueous solution with a high salt content, leaves, during cleaning, white marks on the glass surface and / or the other parts vehicle on the edge of the glass surface.
- a non-freezing solution can be obtained at up to -8 ° C using pellets containing 50% by weight of salts relative to the total mass.
- pellets whose mass is between 4.5 and 6.5 grams, preferably about 6 grams comprising 50% by weight of sodium acetate and 10% by weight of sodium sulfate.
- the recommended dosage to preserve a liquid solution at -8 ° C is three pellets of product per 2.5 liters of tap water or two tablets per 2 liters of water.
- adipic acid Alternatively, another weak acid such as adipic acid and another weak base such as sodium carbonate can be used.
- another weak acid such as adipic acid and another weak base such as sodium carbonate can be used.
- pellets dissolve directly in the windshield washer reservoir. Indeed, a dissolution in a container prior to its incorporation into the tank is possible, but in this case the risk of overturning the product when it enters the tank reappears.
- Other compounds may be incorporated into the pellet, for example it may be dyestuffs for tinting the final liquid or odorous substances to give a particular smell to the final product.
- the product pellet is adapted to be dissolved in tap water.
- Such a device makes it easy to store and handle the cleaning product without the risk of wasting the product during its incorporation into the tank.
- a bitterer can be incorporated into the lozenge to limit the risk of ingestion by a child.
- Such a pellet does not include phosphate, which contributes to the preservation of the environment, phosphate compounds being considered as a potential source of pollution.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Surface Treatment Of Glass (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0608269A FR2906255B1 (fr) | 2006-09-21 | 2006-09-21 | Produit de nettoyage sous forme solide des surfaces vitrees d'un vehicule |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1903096A1 true EP1903096A1 (de) | 2008-03-26 |
| EP1903096B1 EP1903096B1 (de) | 2011-03-09 |
Family
ID=37907169
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP07356122A Active EP1903096B1 (de) | 2006-09-21 | 2007-09-20 | Reinigungsprodukt in fester Form für Glasoberflächen eines Fahrzeugs |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1903096B1 (de) |
| AT (1) | ATE501239T1 (de) |
| DE (1) | DE602007012972D1 (de) |
| ES (1) | ES2361571T3 (de) |
| FR (1) | FR2906255B1 (de) |
| PT (1) | PT1903096E (de) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011096000A1 (en) | 2010-02-02 | 2011-08-11 | New Project S.R.L. | Single dose sachet with separate sections for windshield cleaner and/or antifreeze products for motor vehicles |
| EP2626408A1 (de) * | 2010-10-06 | 2013-08-14 | Caparrós Casco, Jordi | Waschmittelzusammensetzungen |
| EP3020793A1 (de) * | 2014-11-13 | 2016-05-18 | Stockmeier Chemie GmbH & Co. KG | Scheibenfrostschutzkonzentrat für kraftfahrzeuge |
| EP4015610A1 (de) * | 2020-12-16 | 2022-06-22 | Linkage Technology Development Switzerland SA | Reinigungsmittelformulierung |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104099188A (zh) * | 2013-04-03 | 2014-10-15 | 李冬可 | 一种固体玻璃水及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4400285A (en) * | 1982-04-12 | 1983-08-23 | Gancy Alan B | Water-activated exothermic chemical deicing formulations |
| US4502892A (en) * | 1978-12-27 | 1985-03-05 | Hoechst Aktiengesellschaft | Method for cleaning a glass surface with solutions of dissolved pelleted components containing high molecular weight polyphosphates, carbonates and acid-forming substances |
| DE3535516A1 (de) * | 1985-10-04 | 1987-04-09 | Fritz Buchner | Tablettenfoermiges wasch- und reinigungsmittel, verfahren zu seiner herstellung und seine verwendung |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5885949A (en) * | 1996-06-05 | 1999-03-23 | Amway Corporation | Tableted household cleaner comprising carboxylic acid, BI carbonate and polyvinyl alcohol |
| EP0881282B2 (de) * | 1997-05-27 | 2009-06-03 | The Procter & Gamble Company | Tabletten und Verfahren zu deren Herstellung |
| ES2186415T3 (es) * | 1998-10-09 | 2003-05-01 | Unilever Nv | Composiciones detergentes y para ablandar el agua. |
-
2006
- 2006-09-21 FR FR0608269A patent/FR2906255B1/fr not_active Expired - Fee Related
-
2007
- 2007-09-20 ES ES07356122T patent/ES2361571T3/es active Active
- 2007-09-20 PT PT07356122T patent/PT1903096E/pt unknown
- 2007-09-20 AT AT07356122T patent/ATE501239T1/de not_active IP Right Cessation
- 2007-09-20 DE DE602007012972T patent/DE602007012972D1/de active Active
- 2007-09-20 EP EP07356122A patent/EP1903096B1/de active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4502892A (en) * | 1978-12-27 | 1985-03-05 | Hoechst Aktiengesellschaft | Method for cleaning a glass surface with solutions of dissolved pelleted components containing high molecular weight polyphosphates, carbonates and acid-forming substances |
| US4400285A (en) * | 1982-04-12 | 1983-08-23 | Gancy Alan B | Water-activated exothermic chemical deicing formulations |
| DE3535516A1 (de) * | 1985-10-04 | 1987-04-09 | Fritz Buchner | Tablettenfoermiges wasch- und reinigungsmittel, verfahren zu seiner herstellung und seine verwendung |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011096000A1 (en) | 2010-02-02 | 2011-08-11 | New Project S.R.L. | Single dose sachet with separate sections for windshield cleaner and/or antifreeze products for motor vehicles |
| EP2626408A1 (de) * | 2010-10-06 | 2013-08-14 | Caparrós Casco, Jordi | Waschmittelzusammensetzungen |
| EP2626408A4 (de) * | 2010-10-06 | 2014-08-06 | Marti Coma Lorena | Waschmittelzusammensetzungen |
| EP3020793A1 (de) * | 2014-11-13 | 2016-05-18 | Stockmeier Chemie GmbH & Co. KG | Scheibenfrostschutzkonzentrat für kraftfahrzeuge |
| EP4015610A1 (de) * | 2020-12-16 | 2022-06-22 | Linkage Technology Development Switzerland SA | Reinigungsmittelformulierung |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1903096B1 (de) | 2011-03-09 |
| DE602007012972D1 (de) | 2011-04-21 |
| ATE501239T1 (de) | 2011-03-15 |
| ES2361571T3 (es) | 2011-06-20 |
| FR2906255B1 (fr) | 2012-10-19 |
| FR2906255A1 (fr) | 2008-03-28 |
| PT1903096E (pt) | 2011-05-23 |
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