EP1881084B1 - Manufacturing method for heat resistant aluminium alloy shaped products and heat resistant aluminium alloy shaped product - Google Patents

Manufacturing method for heat resistant aluminium alloy shaped products and heat resistant aluminium alloy shaped product Download PDF

Info

Publication number
EP1881084B1
EP1881084B1 EP07011704A EP07011704A EP1881084B1 EP 1881084 B1 EP1881084 B1 EP 1881084B1 EP 07011704 A EP07011704 A EP 07011704A EP 07011704 A EP07011704 A EP 07011704A EP 1881084 B1 EP1881084 B1 EP 1881084B1
Authority
EP
European Patent Office
Prior art keywords
shaped product
heat resistant
aluminium alloy
resistant aluminium
sectional area
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP07011704A
Other languages
German (de)
French (fr)
Other versions
EP1881084A1 (en
Inventor
Akira c/o Kobe Corporate Research Laboratories Sakae
Hideo c/o Kobe Corporate Research Laboratories Hata
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Priority to PL07011704T priority Critical patent/PL1881084T3/en
Publication of EP1881084A1 publication Critical patent/EP1881084A1/en
Application granted granted Critical
Publication of EP1881084B1 publication Critical patent/EP1881084B1/en
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C23/00Extruding metal; Impact extrusion
    • B21C23/02Making uncoated products
    • B21C23/04Making uncoated products by direct extrusion
    • B21C23/08Making wire, bars, tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C23/00Extruding metal; Impact extrusion
    • B21C23/02Making uncoated products
    • B21C23/04Making uncoated products by direct extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C23/00Extruding metal; Impact extrusion
    • B21C23/02Making uncoated products
    • B21C23/04Making uncoated products by direct extrusion
    • B21C23/08Making wire, bars, tubes
    • B21C23/085Making tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C25/00Profiling tools for metal extruding
    • B21C25/02Dies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C29/00Cooling or heating work or parts of the extrusion press; Gas treatment of work
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon

Definitions

  • the present invention relates to a manufacturing method for heat resistant aluminium alloy shaped products, heat resistant aluminium alloy shaped products, and forming apparatus for heat resistant aluminium alloy shaped products.
  • Patent Publication 1 describes suitable use of such heat resistant aluminium alloy materials for mechanical components ("components” includes “parts,” hereinbelow), such as vehicle components and engine components, for which heat resistance and lightweight property are required, and the mechanical components are formed through the step of a hot extrusion process from the heat resistant aluminium alloy materials.
  • the present invention is made to solve problems such as described above, and an object of the invention is to form well-shaped heat resistant aluminium alloy shaped products containing 50-90% vol.% of intermetallic compounds by hot extrusion while suppressing surface cracking.
  • one aspect of the present invention provides a manufacturing method for heat resistant aluminium alloy shaped products, wherein a shaped product is formed by hot extrusion of a material made of a heat resistant aluminium alloy. The hot extrusion is performed causing a temperature of the shaped product immediately after the hot extrusion to fall within a range between 350°C and below 550°C.
  • a heat resistant aluminium alloy shaped product manufactured by the manufacturing method described above.
  • surface cracking can be suppressed during the manufacture, and properties such as superior high temperature toughness, wear resistance, and fatigue resistance, can be obtained.
  • the hot extrusion of the material is performed by using a forming apparatus including a plurality of entry side ports, a single merge portion fluidly connected to the plurality of entry side ports, and a die including a shaping space fluidly connected to the merge portion.
  • the forming apparatus performs a process including the steps of dividing the compressively loaded material into parts of the material through the plurality of entry side ports, directing the parts of the material passed through the plurality of entry side ports to be merged and welded to one another, and extruding the shaped product having a hollow cross-sectional shape from the shaping space, wherein a ratio of the size of a cross-sectional area of the material prior to compressive loading thereof into the die to the size of a cross-sectional area of the shaped product is 11 or greater, the cross sectional area of the material and the cross sectional area of the shaped product being perpendicular to an extrusion direction.
  • a material to be compressive loaded into the die is divided into parts of the material through the plurality of entry side ports, the parts of the material passed through the plurality of entry side ports are merged and welded to one another, and the shaped product having a hollow cross-sectional shape is extruded from the shaping space.
  • the ratio of the size of a cross-sectional area of the material prior to compressive loading thereof into the die to the size of a cross-sectional area of the shaped product is set to 11 or greater, wherein the cross sectional area of the material and the cross sectional area of the shaped product are perpendicular to an extrusion direction.
  • a strength (tensile strength) as high as 90% or more (“at least 90%,” hereinbelow) of the strength of a non-weld portion of the shaped product can be imparted to a weld portion between the parts of the material passed through the respective entry side ports.
  • the level that the weld portion has the strength as high as at least 90% of the strength of the non-weld portion can be construed as a level not having a significant difference between the weld portion and the non-weld portion, as fluctuations in the strengths of the respective weld portion and non-weld portion are taken into account.
  • the weld portion and the non-weld portion have substantially the same strength, so that the strength of the entirety of the hollow shaped product can be caused to be close to a uniform level. Consequently, unlike a case where the strength of a weld portion is lower than the strength of a non-weld portion, such a case where the weld portion fails earlier than the non-weld portion when a load is applied can be prevented.
  • the heat resistant aluminium alloy shaped product according to the aspect of the present invention is manufactured in accordance with the manufacturing method described above.
  • the ratio of the size of the cross-sectional area of the material prior to compressive loading thereof into the die to the size of the cross-sectional area of the shaped product is set to 11 or greater, the cross sectional area of the material and the cross sectional area of the shaped product being perpendicular to the extrusion direction.
  • the shaped product includes the weld portion between the parts of the material passed through the respective entry side ports, and the non-weld portion other than the weld portion.
  • the weld portion has the strength as high as at least 90% of the non-weld portion.
  • the weld portion has the strength as high as at least 90% of the non-weld portion.
  • the level that the weld portion has the strength as high as at least 90% of the strength of the non-weld portion can be construed as the level not having the significant difference between the weld portion and the non-weld portion, as fluctuations in the strengths of the respective weld portion and non-weld portion are taken into account.
  • the weld portion and the non-weld portion have substantially the same strength, so that the strength of the entirety of the hollow shaped product can be caused to be close to a uniform level. Consequently, unlike the case where the strength of the weld portion is lower than the strength of the non-weld portion, such a case where the weld portion fails earlier than the non-weld portion when a load is applied can be prevented.
  • a forming apparatus for heat resistant aluminium alloy shaped products, according to the aspect of the present invention is used, as a prerequisite condition, for the above-described manufacturing method for shaped products.
  • the ratio of the size of the cross-sectional area of the material prior to compressive loading thereof into the die to the size of the cross-sectional area of the shaped product is set to 11 or greater, wherein the cross sectional area of the material and the cross sectional area of the shaped product are perpendicular to an extrusion direction.
  • the forming apparatus includes a container including a bore hole into which the material prior to the hot extrusion is loaded; a plurality of entry side ports fluidly connected to the bore hole; a single merge portion fluidly connected to the plurality of entry side ports; a die including a shaping space fluidly connected to the merge portion; and a stem for compressing the material present in the bore hole to compressively load the material into the die.
  • a ratio of the size of a cross-sectional area of the bore hole of the container to the size of a cross-sectional area of the shaping space is set to 11 or greater, wherein the cross sectional area of the bore hole and the cross sectional area of the shaping space are perpendicular to an extrusion direction.
  • the ratio of the size of the cross-sectional area of the bore hole of the container to the size of the cross-sectional area of the shaping space is set to 11 or greater, wherein the cross sectional area of the bore hole and the cross sectional area of the shaping space are perpendicular to the extrusion direction. Accordingly, the ratio of the size of the cross-sectional area of the material prior to compressive loading thereof into the die to the size of the cross-sectional area of the shaped product can be set to 11 or greater, wherein the cross sectional area of the material and the cross sectional area of the shaped product are perpendicular to an extrusion direction.
  • the strength as high as 90% or more (“at least 90%,” hereinbelow) of the strength of the non-weld portion of the shaped product can be imparted to the weld portion, so that the strength of the entirety of the shaped product can be caused to be close to a uniform level. Consequently, unlike a case where the strength of a weld portion is lower than the strength of a non-weld portion, such a case where the weld portion fails earlier than the non-weld portion when a load is applied can be prevented.
  • the aspect of the present invention can form well-shaped heat resistant aluminium alloy shaped products by hot extrusion while suppressing surface cracking.
  • FIG. 1 shows a manufacturing process for heat resistant aluminium alloy shaped products in accordance with a first embodiment of the present invention.
  • a heat resistant aluminium alloy used in the manufacturing process is a material that has a superior high temperature toughness, wear resistance, and fatigue resistance at a temperature of nearly 300°C.
  • the heat resistant aluminium alloy contains an aluminium-base alloy structure composed of about 50% to about 90% intermetallic compound phase in terms of the volume fraction (vf) and a metal matrix formed as the balance.
  • the heat resistant aluminium alloy has a composition that contains three elements selected from Cr, Fe, Ti, Mn, V, and Si as elements that forms the intermetallic compound phase, in which a total content of the selected three elements is in the range of about 15 mass % to about 50 mass %.
  • the intermetallic compound phase has a composition containing about 5 mass % to about 30 mass % Cr, about 1 mass % to about 20 mass % Fe, and about 1 mass % to about 15 mass % Ti, and is any one of Al-Cr, Al-Fe, and Al-Ti systems or types. According to the configuration described above, the high temperature fatigue property of the heat resistant aluminium alloy can be even more improved.
  • a shaped product 2 is formed by hot extrusion of a billet 1 (material) formed of the heat resistant aluminium alloy described above.
  • the billet 1 to be used for processing is formed by a so-called "spray forming process.”
  • the heat resistant aluminium alloy which has the above-described composition, is melted by being heated up to the range between 1250°C and 1600°C, and is cooled at a cooling rate of 100°C/h.
  • spraying of the heat resistant aluminium alloy in the melted state is started.
  • HIP hot isostatic pressing
  • the HIP processing is processing that exerts the pressure of a high pressure gas at high temperature on such a pre-form, thereby to perform defect removal from the pre-form.
  • the billet 1 to be thus created is formed in a round columnar shape.
  • hot extrusion is performed by loading the billet 1 into a forming apparatus 10.
  • the forming apparatus 10 used for hot extrusion includes a container 12, a stem 14, and a die 16.
  • the container 12 has a bore hole 12a into which the billet 1 is loaded.
  • the bore hole 12a extends along the extrusion direction of the billet 1, and has a circular cross section perpendicular to the extrusion direction.
  • the stem 14 is driven by a drive mechanism (not shown) to be extendable or retractable (or, reciprocable) along the extrusion direction.
  • the die 16 is disposed in an end portion of the bore hole 12a in the extrusion direction (right direction as viewed on FIG. 1 ).
  • the die 16 has a shaping opening 16a into which the billet 1 compressed from the bore hole 12a flows.
  • shaped products 2 having various shapes can be formed.
  • the hot extrusion is performed so that the shaped product 2 temperature immediately after the extrusion from the forming apparatus 10 falls within in the range between 350°C and below 550°C.
  • the heat resistant aluminium alloy material was actually subjected to hot extrusion, cracking occurred on the surfaces of extruded shaped products in some cases.
  • the inventor focused attention on the temperature of the material during the hot extrusion. Then, the inventor conducted experimentation to investigate the correlation between the surface cracking occurring on the shaped product 2 and the temperature of the shaped product 2 immediately after the hot extrusion.
  • a plurality of shaped products 2 were formed in the manner that a ratio of the size of a cross-sectional area of the respective billet 1 in the bore hole 12a to the size of a cross-sectional area of the respective shaped product 2 is varied in a range of between 14.5 and 65.5, in which the respective cross-sectional areas of the billet 1 and shaped product 2 are perpendicular to the extrusion direction.
  • the above-described ratio hereinbelow is referred to as an "extrusion ratio.”
  • the temperature of the respective shaped product 2 immediately after the hot extrusion from the forming apparatus 10 was measured, and whether cracking occurred on the surface of the respective shaped product 2 was observed.
  • the result of the experimentation is shown in FIG. 2 .
  • the temperature of the shaped product 2 immediately after the hot extrusion varies depending upon factors, such as the temperature of the billet 1 prior to loading thereof into the bore hole 12a of the container 12, the amount of heat loss from the billet 1, the temperature of the container 12, and processing heat occurring during the extrusion. Nevertheless, however, the temperature of a shaped product 2 immediately after the hot extrusion can be adjusted by adjusting a heating temperature of a billet 1 prior to loading thereof into the bore hole 12a of the container 12. More specifically, the temperature of a shaped product 2 immediately after the hot extrusion is once actually measured. As a result, when the temperature of the shaped product 2 is higher than the 550°C, the heating temperature of a corresponding billet 1 is reduced.
  • hot extrusion is performed to set a temperature condition, and the heating temperature of a billet 1 is adjusted in accordance with the temperature of a corresponding shaped product 2 immediately after the hot extrusion.
  • the temperature of the shaped product 2 immediately after the hot extrusion can easily be adjusted to fall within the range between 350°C and below 550°C.
  • a well-shaped shaped product 2 of the heat resistant aluminium alloy can be formed by performing the hot extrusion causing the temperature of the shaped product 2 immediately after the hot extrusion to fall within the range of range between 350°C and below 550°C.
  • FIG. 3 shows the manufacturing process according to the second embodiment.
  • the manufacturing method according to the second embodiment is capable of forming hollow shaped products 22 of various shapes correspondingly to the shapes of shaping spaces S.
  • the hollow shaped products 22 include, for example, a rectangularly columnar hollow shaped product 22a and a hollow shaped product 22c of a shape in which a space inside a rectangular column is partitioned by a partition wall into two spaces formed along the long-side direction.
  • a rectangularly columnar hollow shaped product 22a and a hollow shaped product 22c of a shape in which a space inside a rectangular column is partitioned by a partition wall into two spaces formed along the long-side direction.
  • the second embodiment will be described herebelow with reference to the case of forming the rectangularly columnar hollow shaped product 22a.
  • a billet 1 formed by a spray forming process from heat resistant aluminium alloy is loaded in to a forming apparatus 30, and is subjected to hot extrusion, thereby to form the hollow shaped product 22a.
  • the forming apparatus 30 includes a container 32, a stem 32, a die 36, and a die holder 38.
  • the configurations of the container 32 and the stem 34 are similar to those of the container 12 and the stem 14, respectively, in the first embodiment.
  • the stem 34 which is driven by a drive mechanism (not shown), is provided in a bore hole 32a of the container 32 to be extendable or retractable therein along the extrusion direction of the billet 1.
  • the die holder 38 is disposed in an end portion in the extrusion direction of the billet 1 in alignment with the container 32, and is fixedly attached in the position.
  • the die holder 38 has a holding opening 38a through-formed along the extrusion direction of the billet 1, and the die 36 is fitted therein to be held by the holding opening 38a.
  • the die 36 includes male and female dies 40 and 41.
  • the male and female dies 40 and 41 are provided in that order along the extrusion direction of the billet 1, in which the male die 40 is fitted or coupled into the female die 41.
  • the male die 40 has a plurality of entry ports 40a (entry side ports) through-formed along the extrusion direction.
  • the plurality of entry ports 40a are fluidly connected to the bore hole 32a of the container 32.
  • the billet 1 compressed by the stem 34 from the bore hole 32a of the container 32 is divided through the respective entry ports 40a into parts 1a of the material (see FIG. 5 ), and the parts 1a of the material, which have been divided through the respective entry ports 40a, are compressively loaded for extrusion.
  • the male die 40 further has a protruding portion 40b protruding along the extrusion direction of the billet 1.
  • An end portion of the protruding portion 40b on the side of the female die 41 has a rectangular cross sectional plane perpendicular to the extrusion direction in correspondence to an interior space of the hollow shaped product 22a.
  • the female die 41 includes a single merge portion 41a fluidly connected to the plurality of entry ports 40a of the male die 40, and a forming opening 41b fluidly connected to the merge portion 41a.
  • the merge portion 41a of the merge portion 41a causes fluid communication between the entry ports 40a and the forming opening 41b.
  • the shaping opening 41b has a cross sectional plane perpendicular to the extrusion direction in correspondence to the peripheral shape of the hollow shaped product 22a.
  • the protruding portion 40b of the male die 40 is inserted into the shaping opening 41b in the state where a clearance exists between the protruding portion 40b and an inner wall surface of the shaping opening 41b.
  • the shaping space S (see FIG. 3 ) having a rectangular frame shape corresponding to the rectangularly columnar shape of the hollow shaped product 22a.
  • the shaping space S is fluidly connected to the merge portion 41a.
  • the billet 1 is compressively loaded by the stem 34 into the respective entry ports 40a from the bore hole 32a of the container 32 and is divided therethrough into the parts 1a of the material (see FIG. 5 ).
  • the parts 1a of the material flow out of the respective entry ports 40a.
  • the parts 1a of the material flowed past the respective entry ports 40a are merged and welded to one another in the merge portion 41a, whereby an integral material 1b is formed (see FIG. 5 ).
  • the material 1b is extruded through the shaping space S (see FIG. 3 ), whereby the rectangularly columnar hollow shaped product 22a is formed.
  • the heating temperature of the billet 1 prior to loading thereof into the bore hole 32a of the container 32 is adjusted, thereby to perform hot extrusion causing the temperature of the hollow shaped product 22 immediately after the hot extrusion to fall within the range between 350°C and below 550°C.
  • the extrusion ratio is set to 11 or greater. More specifically, the ratio of the size of a cross-sectional area of the billet 1 prior to compressive loading thereof into the die 36 (i.e., in the state where the billet 1 present inside the bore hole 32a of the container 32) to the size of a cross-sectional area of the hollow shaped product 22a is set to 11 or greater, in which the respective cross-sectional areas of the billet 1 and hollow shaped product 22a are perpendicular to the extrusion direction.
  • the size of the cross sectional area of the hollow shaped product 22a perpendicular to the extrusion direction corresponds to the size of the cross sectional area of the shaping space S perpendicular to the extrusion direction.
  • the size of the cross sectional area, which is perpendicular to the extrusion direction, of the billet 1 prior to loading thereof into the die 36 corresponds to the size of the cross sectional area of the bore hole 32a perpendicular to the extrusion direction.
  • setting is made so that the extrusion ratio is 11 or greater.
  • the size of the cross sectional area of the shaping space S is adjusted by adjusting the outside diameter of the protruding portion 40b of the male die 40 and the inside diameter of the shaping opening 41b of the shaping opening 41b.
  • the size of the cross sectional area of the bore hole 32a is adjusted by adjusting the diameter of the bore hole 32a.
  • the interior of the hollow shaped product 22a includes weld portions 22d of the parts 1a of the material passed through the respective entry ports 40a, and non-weld portions 22e other than the weld portions 22d (see FIG. 5 ).
  • the weld portions 22d are disposed in respective angular portions of the hollow shaped product 22a, and are formed in the entirety of the hollow shaped product 22a in the extrusion direction. In many cases, portions corresponding to the weld portions 22d are inferior in strength to portions corresponding to the non-weld portions 22e.
  • the weld portion 22d can fail earlier than the non-weld portion when a load is applied during the use of the hollow shaped product 22a.
  • the inventor focused attention on the extrusion ratio in the hot extrusion, and carried out experimentation to investigate the correlation between the strength of the weld portions 22d and the extrusion ratio.
  • tensile strength testing In the tensile strength testing, tensile forces along opposite directions were applied to the end portions of the test piece 50 positioned on both sides thereof with the weld portion 22d located therebetween until the test piece 50 is broken, in which the maximum strength was measured.
  • the tensile strength testing was performed in the state of the test piece 50 heated at 300°C. The testing was performed on three test pieces 50 in units of the condition of each extrusion ratio, and average values of the results were calculated. The results are shown in FIG. 7 .
  • the strength of the weld portion 22d is shown in terms of the rate (%) with respect to the tensile strength of the non-weld portions 22e.
  • the weld portion 22d has a tensile strength as high as 90% or more ("at least 90%,” hereinbelow) of the tensile strength of the non-weld portion 22e.
  • the level that the weld portion 22d has the tensile strength as high as at least 90% of the tensile strength of the non-weld portion 22e can be construed as a level not having a significant difference between the weld portion 22d and the non-weld portion 22e, as fluctuations in the strengths of the respective weld portion 22d and non-weld portion 22e are taken into account.
  • the tensile strength of the weld portion 22d is only about 50% of the tensile strength of the weld portion 22d. That is, it can be known that, in the case of the aforementioned extrusion ratio, the tensile strength of the weld portion 22d is significantly low, compared to the tensile strength of the non-weld portion 22e.
  • the tensile strength of the weld portion 22d of the hollow shaped product 22a can be increased to be substantially the same as that of the non-weld portion 22e of the hollow shaped product 22a in accordance with the extrusion ratio set to 11 or greater.
  • the hot extrusion is performed causing the hollow shaped material 22 immediately after the hot extrusion to fall within the range between 350°C and below 550°C. Consequently, similar effects to those in the first embodiment can be obtained in that surface cracking can be suppressed and hence a well-shaped hollow shaped product 22 of the heat resistant aluminium alloy can be formed.
  • the ratio (extrusion ratio) of the size of the cross-sectional area, which is perpendicular to the extrusion direction, of the billet 1 prior to compressive loading thereof into the die 36 to the size of a cross-sectional area, perpendicular to the extrusion direction, of the hollow shaped product 22a is 11 or greater.
  • the tensile strength as high as at least 90% of the tensile strength of the non-weld portion 22e of the hollow shaped product 22a that is, substantially the same tensile strength as the tensile strength of the non-weld portion 22e, can be imparted to the weld portion 22d of the hollow shaped product 22a.
  • the strength of the entirety of the hollow shaped product 22a can be caused to be close to a uniform level. Consequently, unlike the case where the strength of the weld portion 22d is lower than the strength of the non-weld portion 22e, such a case where the weld portion 22d fails earlier than the non-weld portion when a load is applied can be prevented.
  • the die 36 including the separately configured the male die 40 and the female die 41 is used.
  • a die formed from integrated female dies 40 and 41 may be used.
  • the second embodiment has been described with reference to the case where the hollow shaped products 22 having the hollow cross sectional shapes are formed, but there are no limitations thereto.
  • a shaped product having a shape in which an opening is formed along the extrusion direction in a part of the shaped product (such as the hollow shaped product 22), and a shaped product including a hollow cross sectional shape portion only in a partial region may be formed.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Extrusion Of Metal (AREA)
  • Heat Treatments In General, Especially Conveying And Cooling (AREA)
  • Furnace Charging Or Discharging (AREA)
  • Powder Metallurgy (AREA)

Abstract

A manufacturing method for heat resistant aluminium alloy shaped products forms a shaped product by performing hot extrusion of a material (billet) made of a heat resistant aluminium alloy. The hot extrusion is performed causing a temperature of the shaped product immediately after the hot extrusion to fall within a range between 350°C and below 550°C.

Description

    BACKGROUND OF THE INVENTION 1. Field of the Invention
  • The present invention relates to a manufacturing method for heat resistant aluminium alloy shaped products, heat resistant aluminium alloy shaped products, and forming apparatus for heat resistant aluminium alloy shaped products.
  • 2. Description of the Related Art
  • Conventionally, heat resistant aluminium alloy materials having superior high temperature toughness, wear resistance, and high temperature fatigue property ("fatigue resistance," hereinbelow) are known (see Patent Publication 1 ( Japanese Unexamined Patent Application Publication No. 2006-104561 ), for example).
  • Patent Publication 1 describes suitable use of such heat resistant aluminium alloy materials for mechanical components ("components" includes "parts," hereinbelow), such as vehicle components and engine components, for which heat resistance and lightweight property are required, and the mechanical components are formed through the step of a hot extrusion process from the heat resistant aluminium alloy materials.
  • However, although heat resistant aluminium alloy materials equivalent to those disclosed in Patent Publication 1 were actually subjected to hot extrusion process, surface cracking occurred on materials depending on processing conditions.
  • SUMMARY OF THE INVENTION
  • The present invention is made to solve problems such as described above, and an object of the invention is to form well-shaped heat resistant aluminium alloy shaped products containing 50-90% vol.% of intermetallic compounds by hot extrusion while suppressing surface cracking.
  • As a consequence of an extensive research and study conducted to achieve the object of the present invention, the inventor discovered that surface cracking can be suppressed when hot extrusion is performed so that the shaped product temperature immediately after extrusion falls within a predetermined temperature range.
    Accordingly, one aspect of the present invention provides a manufacturing method for heat resistant aluminium alloy shaped products, wherein a shaped product is formed by hot extrusion of a material made of a heat resistant aluminium alloy. The hot extrusion is performed causing a temperature of the shaped product immediately after the hot extrusion to fall within a range between 350°C and below 550°C.
  • By the hot extrusion thus performed causing the temperature of the shaped product immediately after the hot extrusion to fall within the range between 350°C and below 550°C, well-shaped heat resistant aluminium alloy shaped products can be formed by hot extrusion while suppressing surface cracking.
  • According to the aspect of the present invention, there is further provided a heat resistant aluminium alloy shaped product manufactured by the manufacturing method described above. For the shaped product, surface cracking can be suppressed during the manufacture, and properties such as superior high temperature toughness, wear resistance, and fatigue resistance, can be obtained.
  • Preferably, in the manufacturing method for heat resistant aluminium alloy shaped products, the hot extrusion of the material is performed by using a forming apparatus including a plurality of entry side ports, a single merge portion fluidly connected to the plurality of entry side ports, and a die including a shaping space fluidly connected to the merge portion. In this case, the forming apparatus performs a process including the steps of dividing the compressively loaded material into parts of the material through the plurality of entry side ports, directing the parts of the material passed through the plurality of entry side ports to be merged and welded to one another, and extruding the shaped product having a hollow cross-sectional shape from the shaping space, wherein a ratio of the size of a cross-sectional area of the material prior to compressive loading thereof into the die to the size of a cross-sectional area of the shaped product is 11 or greater, the cross sectional area of the material and the cross sectional area of the shaped product being perpendicular to an extrusion direction.
  • As a consequence of the extensive research and study, the inventor discovered the following. Reference is now made to a case where, as described above, a material to be compressive loaded into the die is divided into parts of the material through the plurality of entry side ports, the parts of the material passed through the plurality of entry side ports are merged and welded to one another, and the shaped product having a hollow cross-sectional shape is extruded from the shaping space. In this case, the ratio of the size of a cross-sectional area of the material prior to compressive loading thereof into the die to the size of a cross-sectional area of the shaped product is set to 11 or greater, wherein the cross sectional area of the material and the cross sectional area of the shaped product are perpendicular to an extrusion direction. Thereby, a strength (tensile strength) as high as 90% or more ("at least 90%," hereinbelow) of the strength of a non-weld portion of the shaped product can be imparted to a weld portion between the parts of the material passed through the respective entry side ports.
    The level that the weld portion has the strength as high as at least 90% of the strength of the non-weld portion can be construed as a level not having a significant difference between the weld portion and the non-weld portion, as fluctuations in the strengths of the respective weld portion and non-weld portion are taken into account. As such, it can be construed that the weld portion and the non-weld portion have substantially the same strength, so that the strength of the entirety of the hollow shaped product can be caused to be close to a uniform level. Consequently, unlike a case where the strength of a weld portion is lower than the strength of a non-weld portion, such a case where the weld portion fails earlier than the non-weld portion when a load is applied can be prevented.
  • The heat resistant aluminium alloy shaped product according to the aspect of the present invention is manufactured in accordance with the manufacturing method described above. In the manufacturing method, the ratio of the size of the cross-sectional area of the material prior to compressive loading thereof into the die to the size of the cross-sectional area of the shaped product is set to 11 or greater, the cross sectional area of the material and the cross sectional area of the shaped product being perpendicular to the extrusion direction. The shaped product includes the weld portion between the parts of the material passed through the respective entry side ports, and the non-weld portion other than the weld portion. The weld portion has the strength as high as at least 90% of the non-weld portion.
  • As described above, in the heat resistant aluminium alloy shaped product, the weld portion has the strength as high as at least 90% of the non-weld portion. The level that the weld portion has the strength as high as at least 90% of the strength of the non-weld portion can be construed as the level not having the significant difference between the weld portion and the non-weld portion, as fluctuations in the strengths of the respective weld portion and non-weld portion are taken into account. As such, it can be construed that the weld portion and the non-weld portion have substantially the same strength, so that the strength of the entirety of the hollow shaped product can be caused to be close to a uniform level. Consequently, unlike the case where the strength of the weld portion is lower than the strength of the non-weld portion, such a case where the weld portion fails earlier than the non-weld portion when a load is applied can be prevented.
  • A forming apparatus for heat resistant aluminium alloy shaped products, according to the aspect of the present invention is used, as a prerequisite condition, for the above-described manufacturing method for shaped products. In the manufacturing method, the ratio of the size of the cross-sectional area of the material prior to compressive loading thereof into the die to the size of the cross-sectional area of the shaped product is set to 11 or greater, wherein the cross sectional area of the material and the cross sectional area of the shaped product are perpendicular to an extrusion direction. The forming apparatus includes a container including a bore hole into which the material prior to the hot extrusion is loaded; a plurality of entry side ports fluidly connected to the bore hole; a single merge portion fluidly connected to the plurality of entry side ports; a die including a shaping space fluidly connected to the merge portion; and a stem for compressing the material present in the bore hole to compressively load the material into the die. In the forming apparatus, a ratio of the size of a cross-sectional area of the bore hole of the container to the size of a cross-sectional area of the shaping space is set to 11 or greater, wherein the cross sectional area of the bore hole and the cross sectional area of the shaping space are perpendicular to an extrusion direction.
  • Thus, in the forming apparatus, the ratio of the size of the cross-sectional area of the bore hole of the container to the size of the cross-sectional area of the shaping space is set to 11 or greater, wherein the cross sectional area of the bore hole and the cross sectional area of the shaping space are perpendicular to the extrusion direction. Accordingly, the ratio of the size of the cross-sectional area of the material prior to compressive loading thereof into the die to the size of the cross-sectional area of the shaped product can be set to 11 or greater, wherein the cross sectional area of the material and the cross sectional area of the shaped product are perpendicular to an extrusion direction. Thereby, the strength as high as 90% or more ("at least 90%," hereinbelow) of the strength of the non-weld portion of the shaped product can be imparted to the weld portion, so that the strength of the entirety of the shaped product can be caused to be close to a uniform level. Consequently, unlike a case where the strength of a weld portion is lower than the strength of a non-weld portion, such a case where the weld portion fails earlier than the non-weld portion when a load is applied can be prevented.
    As described above, the aspect of the present invention can form well-shaped heat resistant aluminium alloy shaped products by hot extrusion while suppressing surface cracking.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • In the accompanying drawings:
    • FIG. 1 is an explanatory view of a manufacturing process for heat resistant aluminium alloy shaped products in accordance with a first embodiment of the present invention;
    • FIG. 2 is a correlation diagram showing the correlation between an immediate post-extrusion shaped product temperature and shaped-material surface cracking in the manufacturing process of the first embodiment;
    • FIG. 3 is an explanatory view of a manufacturing process of a heat resistant aluminium alloy hollow shaped product in accordance with a second embodiment of the present invention;
    • FIG. 4 is a view showing the state where the hollow shaped product is extruded by a forming apparatus used in the manufacturing process shown in FIG. 3;
    • FIG. 5 is a perspective view showing the shape of the material in the forming apparatus in accordance with the second embodiment;
    • FIG. 6 is an explanatory view of a sampling method for sampling (cutting) a test specimen for tensile strength testing from the hollow shaped product; and
    • FIG. 7 is a correlation diagram showing the correlation between weld portions of the hollow shaped product and the tensile strength.
    DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • Embodiments of the present invention will be described in detail with reference to the accompanying drawings.
  • (First Embodiment)
  • FIG. 1 shows a manufacturing process for heat resistant aluminium alloy shaped products in accordance with a first embodiment of the present invention. A heat resistant aluminium alloy used in the manufacturing process is a material that has a superior high temperature toughness, wear resistance, and fatigue resistance at a temperature of nearly 300°C. The heat resistant aluminium alloy contains an aluminium-base alloy structure composed of about 50% to about 90% intermetallic compound phase in terms of the volume fraction (vf) and a metal matrix formed as the balance. Further, the heat resistant aluminium alloy has a composition that contains three elements selected from Cr, Fe, Ti, Mn, V, and Si as elements that forms the intermetallic compound phase, in which a total content of the selected three elements is in the range of about 15 mass % to about 50 mass %.
  • Preferably, the intermetallic compound phase has a composition containing about 5 mass % to about 30 mass % Cr, about 1 mass % to about 20 mass % Fe, and about 1 mass % to about 15 mass % Ti, and is any one of Al-Cr, Al-Fe, and Al-Ti systems or types. According to the configuration described above, the high temperature fatigue property of the heat resistant aluminium alloy can be even more improved.
  • In the manufacturing process according to the first embodiment, a shaped product 2 is formed by hot extrusion of a billet 1 (material) formed of the heat resistant aluminium alloy described above. In this case, the billet 1 to be used for processing is formed by a so-called "spray forming process." In the spray forming process, the heat resistant aluminium alloy, which has the above-described composition, is melted by being heated up to the range between 1250°C and 1600°C, and is cooled at a cooling rate of 100°C/h. When being cooled down to a range between 900°C and 1200°C, spraying of the heat resistant aluminium alloy in the melted state is started. Then, particulate matter of the sprayed heat resistant aluminium alloy is deposited, thereby to create a pre-form. Then, HIP (hot isostatic pressing) processing is performed on the pre-form in a sealed vacuum vessel, whereby the billet 1 is created. The HIP processing is processing that exerts the pressure of a high pressure gas at high temperature on such a pre-form, thereby to perform defect removal from the pre-form. The billet 1 to be thus created is formed in a round columnar shape.
  • In the manufacturing process according to the first embodiment, hot extrusion is performed by loading the billet 1 into a forming apparatus 10. The forming apparatus 10 used for hot extrusion includes a container 12, a stem 14, and a die 16.
  • The container 12 has a bore hole 12a into which the billet 1 is loaded. The bore hole 12a extends along the extrusion direction of the billet 1, and has a circular cross section perpendicular to the extrusion direction. In the bore hole 12a, the stem 14 is driven by a drive mechanism (not shown) to be extendable or retractable (or, reciprocable) along the extrusion direction. The die 16 is disposed in an end portion of the bore hole 12a in the extrusion direction (right direction as viewed on FIG. 1). The die 16 has a shaping opening 16a into which the billet 1 compressed from the bore hole 12a flows. The billet 1 present in the bore hole 12a is compressed by the stem 14, thereby to extrude the solid shaped product 2 corresponding to the shape of the shaping opening 16a of the die 16. In the manufacturing process according to the first embodiment, shaped products 2 having various shapes, such as planar and angled columnar shaped products 2 shown in FIG. 1, can be formed.
  • In the hot extrusion according to the first embodiment, the hot extrusion is performed so that the shaped product 2 temperature immediately after the extrusion from the forming apparatus 10 falls within in the range between 350°C and below 550°C. When the heat resistant aluminium alloy material was actually subjected to hot extrusion, cracking occurred on the surfaces of extruded shaped products in some cases. In order to solve the problems of such surface cracking, the inventor focused attention on the temperature of the material during the hot extrusion. Then, the inventor conducted experimentation to investigate the correlation between the surface cracking occurring on the shaped product 2 and the temperature of the shaped product 2 immediately after the hot extrusion.
  • In the experimentation, a plurality of shaped products 2 were formed in the manner that a ratio of the size of a cross-sectional area of the respective billet 1 in the bore hole 12a to the size of a cross-sectional area of the respective shaped product 2 is varied in a range of between 14.5 and 65.5, in which the respective cross-sectional areas of the billet 1 and shaped product 2 are perpendicular to the extrusion direction. The above-described ratio hereinbelow is referred to as an "extrusion ratio." Then, the temperature of the respective shaped product 2 immediately after the hot extrusion from the forming apparatus 10 was measured, and whether cracking occurred on the surface of the respective shaped product 2 was observed. The result of the experimentation is shown in FIG. 2.
  • As seen from FIG. 2, in hot extrusion causing the temperature of the respective shaped product 2 immediately after the hot extrusion to reach 550°C, well-shaped shaped products was not able to be formed as surface cracking occurred on the respective shaped products 2. However, in hot extrusion causing the temperature of the respective shaped product 2 immediately after the hot extrusion to be below 550°C, well-shaped shaped products 2 were able to be formed without surface cracking. In hot extrusion causing the temperature of a shaped product 2 immediately after the hot extrusion to be below 350°C, deformability of the billet 1 is excessively low, therefore making it difficult to extrude the shaped product 2 from the forming apparatus 10. Consequently, it was known that surface cracking can be suppressed and hence a well-shaped shaped product 2 of the heat resistant aluminium alloy can be formed by performing the hot extrusion causing the temperature of the shaped product 2 immediately after the hot extrusion to fall within the range of range between 350°C and below 550°C.
  • The temperature of the shaped product 2 immediately after the hot extrusion varies depending upon factors, such as the temperature of the billet 1 prior to loading thereof into the bore hole 12a of the container 12, the amount of heat loss from the billet 1, the temperature of the container 12, and processing heat occurring during the extrusion. Nevertheless, however, the temperature of a shaped product 2 immediately after the hot extrusion can be adjusted by adjusting a heating temperature of a billet 1 prior to loading thereof into the bore hole 12a of the container 12. More specifically, the temperature of a shaped product 2 immediately after the hot extrusion is once actually measured. As a result, when the temperature of the shaped product 2 is higher than the 550°C, the heating temperature of a corresponding billet 1 is reduced. Thus, hot extrusion is performed to set a temperature condition, and the heating temperature of a billet 1 is adjusted in accordance with the temperature of a corresponding shaped product 2 immediately after the hot extrusion. Thereby, the temperature of the shaped product 2 immediately after the hot extrusion can easily be adjusted to fall within the range between 350°C and below 550°C.
  • As described above, according to the first embodiment, surface cracking can be suppressed and hence a well-shaped shaped product 2 of the heat resistant aluminium alloy can be formed by performing the hot extrusion causing the temperature of the shaped product 2 immediately after the hot extrusion to fall within the range of range between 350°C and below 550°C.
  • Further, for the heat resistant aluminium alloy shaped product 2 manufactured by the manufacturing method according to the first embodiment, superior high temperature toughness, wear resistance, and fatigue resistance can be obtained.
  • (Second Embodiment)
  • A second embodiment of the present invention will be described herebelow.
    The manufacturing method for heat resistant aluminium alloy shaped products is different from the manufacturing method according to the first embodiment in that, as shown in FIG. 3, shaped products 22, respectively, having hollow cross sectional shapes (which hereinbelow will be referred to as "hollow shaped product 22a") are continually extruded.
    FIG. 3 shows the manufacturing process according to the second embodiment. The manufacturing method according to the second embodiment is capable of forming hollow shaped products 22 of various shapes correspondingly to the shapes of shaping spaces S. The hollow shaped products 22 include, for example, a rectangularly columnar hollow shaped product 22a and a hollow shaped product 22c of a shape in which a space inside a rectangular column is partitioned by a partition wall into two spaces formed along the long-side direction. However, the second embodiment will be described herebelow with reference to the case of forming the rectangularly columnar hollow shaped product 22a.
  • Similarly as in the first embodiment, in the second embodiment, a billet 1 formed by a spray forming process from heat resistant aluminium alloy is loaded in to a forming apparatus 30, and is subjected to hot extrusion, thereby to form the hollow shaped product 22a. The forming apparatus 30 includes a container 32, a stem 32, a die 36, and a die holder 38. The configurations of the container 32 and the stem 34 are similar to those of the container 12 and the stem 14, respectively, in the first embodiment.
    The stem 34, which is driven by a drive mechanism (not shown), is provided in a bore hole 32a of the container 32 to be extendable or retractable therein along the extrusion direction of the billet 1.
  • The die holder 38 is disposed in an end portion in the extrusion direction of the billet 1 in alignment with the container 32, and is fixedly attached in the position. The die holder 38 has a holding opening 38a through-formed along the extrusion direction of the billet 1, and the die 36 is fitted therein to be held by the holding opening 38a.
  • The die 36 includes male and female dies 40 and 41. The male and female dies 40 and 41 are provided in that order along the extrusion direction of the billet 1, in which the male die 40 is fitted or coupled into the female die 41. With reference to FIG. 4, the male die 40 has a plurality of entry ports 40a (entry side ports) through-formed along the extrusion direction. The plurality of entry ports 40a are fluidly connected to the bore hole 32a of the container 32. The billet 1 compressed by the stem 34 from the bore hole 32a of the container 32 is divided through the respective entry ports 40a into parts 1a of the material (see FIG. 5), and the parts 1a of the material, which have been divided through the respective entry ports 40a, are compressively loaded for extrusion. The male die 40 further has a protruding portion 40b protruding along the extrusion direction of the billet 1. An end portion of the protruding portion 40b on the side of the female die 41 has a rectangular cross sectional plane perpendicular to the extrusion direction in correspondence to an interior space of the hollow shaped product 22a.
  • The female die 41 includes a single merge portion 41a fluidly connected to the plurality of entry ports 40a of the male die 40, and a forming opening 41b fluidly connected to the merge portion 41a. The merge portion 41a of the merge portion 41a causes fluid communication between the entry ports 40a and the forming opening 41b. The shaping opening 41b has a cross sectional plane perpendicular to the extrusion direction in correspondence to the peripheral shape of the hollow shaped product 22a. The protruding portion 40b of the male die 40 is inserted into the shaping opening 41b in the state where a clearance exists between the protruding portion 40b and an inner wall surface of the shaping opening 41b. By the protruding portion 40b of the male die 40 and the inner wall surface of the shaping opening 41b of the female die 41, the shaping space S (see FIG. 3) having a rectangular frame shape corresponding to the rectangularly columnar shape of the hollow shaped product 22a. The shaping space S is fluidly connected to the merge portion 41a.
  • In the configuration thus formed, the billet 1 is compressively loaded by the stem 34 into the respective entry ports 40a from the bore hole 32a of the container 32 and is divided therethrough into the parts 1a of the material (see FIG. 5). In this state, the parts 1a of the material flow out of the respective entry ports 40a. Then, the parts 1a of the material flowed past the respective entry ports 40a are merged and welded to one another in the merge portion 41a, whereby an integral material 1b is formed (see FIG. 5). The material 1b is extruded through the shaping space S (see FIG. 3), whereby the rectangularly columnar hollow shaped product 22a is formed. Similarly as in the manufacturing method according to the first embodiment, in the manufacturing method according to the second embodiment, the heating temperature of the billet 1 prior to loading thereof into the bore hole 32a of the container 32 is adjusted, thereby to perform hot extrusion causing the temperature of the hollow shaped product 22 immediately after the hot extrusion to fall within the range between 350°C and below 550°C.
  • For the hot extrusion according to the second embodiment, the extrusion ratio is set to 11 or greater. More specifically, the ratio of the size of a cross-sectional area of the billet 1 prior to compressive loading thereof into the die 36 (i.e., in the state where the billet 1 present inside the bore hole 32a of the container 32) to the size of a cross-sectional area of the hollow shaped product 22a is set to 11 or greater, in which the respective cross-sectional areas of the billet 1 and hollow shaped product 22a are perpendicular to the extrusion direction. The size of the cross sectional area of the hollow shaped product 22a perpendicular to the extrusion direction corresponds to the size of the cross sectional area of the shaping space S perpendicular to the extrusion direction. In addition, the size of the cross sectional area, which is perpendicular to the extrusion direction, of the billet 1 prior to loading thereof into the die 36 corresponds to the size of the cross sectional area of the bore hole 32a perpendicular to the extrusion direction. As such, in design stages, setting is made so that the extrusion ratio is 11 or greater. More specifically, in the stage of design of the die 36, the size of the cross sectional area of the shaping space S is adjusted by adjusting the outside diameter of the protruding portion 40b of the male die 40 and the inside diameter of the shaping opening 41b of the shaping opening 41b. In addition, in the stage of the container 32, the size of the cross sectional area of the bore hole 32a is adjusted by adjusting the diameter of the bore hole 32a.
  • The interior of the hollow shaped product 22a includes weld portions 22d of the parts 1a of the material passed through the respective entry ports 40a, and non-weld portions 22e other than the weld portions 22d (see FIG. 5). The weld portions 22d are disposed in respective angular portions of the hollow shaped product 22a, and are formed in the entirety of the hollow shaped product 22a in the extrusion direction. In many cases, portions corresponding to the weld portions 22d are inferior in strength to portions corresponding to the non-weld portions 22e. If the strength of a weld portion 22d is excessively lower than the strength of a non-weld portions 22e, the weld portion 22d can fail earlier than the non-weld portion when a load is applied during the use of the hollow shaped product 22a. In order to suppress reduction in the strength of the weld portions 22d, the inventor focused attention on the extrusion ratio in the hot extrusion, and carried out experimentation to investigate the correlation between the strength of the weld portions 22d and the extrusion ratio.
  • In the experimentation, a plurality of hollow shaped products 22a of the type shown in FIG. 6, in each of which a weld portion 22d is formed in a central portion with respect to the width direction. In this case, hot extrusion was performed similarly as in the manufacturing process so that the hollow shaped product 22a immediately after the hot extrusion is 530°C, and the plurality of hollow, shaped products 22a were formed by varying the extrusion ratio.
    With reference to FIG. 6, respective test pieces 50 were sampled (cut) from respective hollow shaped products 22a including the weld portions 22d, and were subjected to tensile strength testing. In the tensile strength testing, tensile forces along opposite directions were applied to the end portions of the test piece 50 positioned on both sides thereof with the weld portion 22d located therebetween until the test piece 50 is broken, in which the maximum strength was measured. The tensile strength testing was performed in the state of the test piece 50 heated at 300°C. The testing was performed on three test pieces 50 in units of the condition of each extrusion ratio, and average values of the results were calculated. The results are shown in FIG. 7. In FIG. 7, the strength of the weld portion 22d is shown in terms of the rate (%) with respect to the tensile strength of the non-weld portions 22e.
  • It can be known from FIG. 7, in the hollow shaped product 22a manufactured in accordance with the extrusion ratio set to the 11 or greater, the weld portion 22d has a tensile strength as high as 90% or more ("at least 90%," hereinbelow) of the tensile strength of the non-weld portion 22e. The level that the weld portion 22d has the tensile strength as high as at least 90% of the tensile strength of the non-weld portion 22e can be construed as a level not having a significant difference between the weld portion 22d and the non-weld portion 22e, as fluctuations in the strengths of the respective weld portion 22d and non-weld portion 22e are taken into account.
    In comparison to the above, it can be known from FIG. 7 that in the hollow shaped product 22a manufactured in accordance with the extrusion ratio set to 7, the tensile strength of the weld portion 22d is only about 50% of the tensile strength of the weld portion 22d. That is, it can be known that, in the case of the aforementioned extrusion ratio, the tensile strength of the weld portion 22d is significantly low, compared to the tensile strength of the non-weld portion 22e. Thus, it was known that the tensile strength of the weld portion 22d of the hollow shaped product 22a can be increased to be substantially the same as that of the non-weld portion 22e of the hollow shaped product 22a in accordance with the extrusion ratio set to 11 or greater.
  • As described above, also in the second embodiment, the hot extrusion is performed causing the hollow shaped material 22 immediately after the hot extrusion to fall within the range between 350°C and below 550°C. Consequently, similar effects to those in the first embodiment can be obtained in that surface cracking can be suppressed and hence a well-shaped hollow shaped product 22 of the heat resistant aluminium alloy can be formed.
  • Further, according to the second embodiment, the ratio (extrusion ratio) of the size of the cross-sectional area, which is perpendicular to the extrusion direction, of the billet 1 prior to compressive loading thereof into the die 36 to the size of a cross-sectional area, perpendicular to the extrusion direction, of the hollow shaped product 22a is 11 or greater. Thereby, the tensile strength as high as at least 90% of the tensile strength of the non-weld portion 22e of the hollow shaped product 22a, that is, substantially the same tensile strength as the tensile strength of the non-weld portion 22e, can be imparted to the weld portion 22d of the hollow shaped product 22a. As such, the strength of the entirety of the hollow shaped product 22a can be caused to be close to a uniform level. Consequently, unlike the case where the strength of the weld portion 22d is lower than the strength of the non-weld portion 22e, such a case where the weld portion 22d fails earlier than the non-weld portion when a load is applied can be prevented.
  • The embodiments are disclosed above by way of examples in all respects and should not be construed to be restrictive. The scope of the present invention is not defined by description of the embodiments, but is defined only by the appended claims. Further, it is to be understood that definitions or meanings equivalent to those in the claims and all modifications and/or alterations within the scope defined therein are included in the present invention.
  • For example, in the second embodiment, the die 36 including the separately configured the male die 40 and the female die 41 is used. However, there are no limitations to this type, but a die formed from integrated female dies 40 and 41 may be used.
  • Further, the second embodiment has been described with reference to the case where the hollow shaped products 22 having the hollow cross sectional shapes are formed, but there are no limitations thereto. For example, a shaped product having a shape in which an opening is formed along the extrusion direction in a part of the shaped product (such as the hollow shaped product 22), and a shaped product including a hollow cross sectional shape portion only in a partial region may be formed.

Claims (3)

  1. A manufacturing method for heat resistant aluminium alloy shaped products, wherein:
    a shaped product is formed by hot extrusion of a material made of a heat resistant aluminium alloy which contains an aluminum-base alloy structure composed of 50% to 90% intermetallic compound phase in terms of the volume fraction (vf) and an aluminium metal matrix formed as the balance, and wherein
    the heat resistant aluminum alloy has a composition that contains three elements selected from Cr, Fe, Ti, Mn, V, and Si as elements that form the intermetallic compound phase in which a total content of the selected three elements is in the range of 15 mass% to 50 mass%; and the hot extrusion is performed causing a temperature of the shaped product immediately after the hot extrusion to fall within a range between 350°C and below 550°C, for suppressing surface cracking.
  2. A heat resistant aluminium alloy shaped product manufactured by the manufacturing method as claimed in claim 1.
  3. The manufacturing method for heat resistant aluminium alloy shaped products, as claimed in claim 1, wherein:
    the hot extrusion of the material is performed by using a forming apparatus including a plurality of entry side ports, a single merge portion fluidly connected to the plurality of entry side ports, and a die including a shaping space fluidly connected to the merge portion; the forming apparatus performs a process including the steps of dividing the loaded material to be compressive loaded into the die into parts of the material through the plurality of entry side ports, directing the parts of the material passed through the plurality of entry side ports to be merged and welded to one another, and extruding the shaped product having a hollow cross-sectional shape from the shaping space, wherein a ratio of the size of a cross-sectional area of the material prior to compressive loading thereof into the die to the size of a cross-sectional area of the shaped product is set to 11 or greater, the cross sectional area of the material and the cross sectional area of the shaped product being perpendicular to an extrusion direction.
EP07011704A 2006-07-18 2007-06-14 Manufacturing method for heat resistant aluminium alloy shaped products and heat resistant aluminium alloy shaped product Not-in-force EP1881084B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL07011704T PL1881084T3 (en) 2006-07-18 2007-06-14 Manufacturing method for heat resistant aluminium alloy shaped products and heat resistant aluminium alloy shaped product

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2006195724A JP5010196B2 (en) 2006-07-18 2006-07-18 Heat-resistant aluminum alloy shape manufacturing method, heat-resistant aluminum alloy shape material and heat-resistant aluminum alloy shape forming apparatus

Publications (2)

Publication Number Publication Date
EP1881084A1 EP1881084A1 (en) 2008-01-23
EP1881084B1 true EP1881084B1 (en) 2010-10-06

Family

ID=38582097

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07011704A Not-in-force EP1881084B1 (en) 2006-07-18 2007-06-14 Manufacturing method for heat resistant aluminium alloy shaped products and heat resistant aluminium alloy shaped product

Country Status (6)

Country Link
EP (1) EP1881084B1 (en)
JP (1) JP5010196B2 (en)
AT (1) ATE483831T1 (en)
DE (1) DE602007009604D1 (en)
HK (1) HK1117203A1 (en)
PL (1) PL1881084T3 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7955533B2 (en) 2005-03-02 2011-06-07 Eastman Chemical Company Process for the preparation of transparent shaped articles
US7959998B2 (en) 2005-03-02 2011-06-14 Eastman Chemical Company Transparent, oxygen-scavenging compositions containing polyesters comprising a cyclobutanediol and articles prepared therefrom
US7964258B2 (en) 2005-03-02 2011-06-21 Eastman Chemical Company Transparent, oxygen-scavenging compositions and articles prepared therefrom
US7955674B2 (en) 2005-03-02 2011-06-07 Eastman Chemical Company Transparent polymer blends containing polyesters comprising a cyclobutanediol and articles prepared therefrom
US7959836B2 (en) 2005-03-02 2011-06-14 Eastman Chemical Company Process for the preparation of transparent, shaped articles containing polyesters comprising a cyclobutanediol
US7968164B2 (en) 2005-03-02 2011-06-28 Eastman Chemical Company Transparent polymer blends and articles prepared therefrom
US7786252B2 (en) 2005-03-02 2010-08-31 Eastman Chemical Company Preparation of transparent multilayered articles
US8557950B2 (en) 2005-06-16 2013-10-15 Grupo Petrotemex, S.A. De C.V. High intrinsic viscosity melt phase polyester polymers with acceptable acetaldehyde generation rates
US7838596B2 (en) 2005-09-16 2010-11-23 Eastman Chemical Company Late addition to effect compositional modifications in condensation polymers
CN103042063B (en) * 2012-12-21 2015-04-15 烟台首钢东星结晶器有限公司 Small square embryo crystallizer square tube manufacturing method

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60196219A (en) * 1984-03-16 1985-10-04 Showa Alum Corp Production of wear resistant alluminum alloy extrudate
JPS62188738A (en) * 1986-02-15 1987-08-18 Honda Motor Co Ltd Structural member made of sintered al or al alloy and its production
JPH0762199B2 (en) * 1987-05-07 1995-07-05 株式会社神戸製鋼所 A1-based alloy
GB9308171D0 (en) * 1993-04-21 1993-06-02 Alcan Int Ltd Improvements in or related to the production of extruded aluminium-lithium alloys
JPH09271834A (en) * 1996-04-05 1997-10-21 Nippon Light Metal Co Ltd Extrusion die of aluminum hollow member
JP3324444B2 (en) * 1997-05-14 2002-09-17 日本軽金属株式会社 Manufacturing method of extruded aluminum material with excellent bending workability
JP2001020047A (en) * 1999-07-05 2001-01-23 Toyota Autom Loom Works Ltd Stock for aluminum alloy forging and its production
JP3668063B2 (en) * 1999-08-27 2005-07-06 株式会社神戸製鋼所 Hollow profile extrusion dies and hollow profile
JP4587588B2 (en) * 2001-03-28 2010-11-24 住友軽金属工業株式会社 Aluminum alloy extruded material with excellent axial crushing characteristics and method for producing the same
JP4092306B2 (en) * 2003-05-23 2008-05-28 株式会社神戸製鋼所 Hollow light metal member extrusion method, hollow extrusion die, and hollow light metal extrusion member
ATE549104T1 (en) * 2003-05-23 2012-03-15 Kobe Steel Ltd METHOD FOR EXTRUDING A HOLLOW LIGHT METAL ELEMENT
JP4704720B2 (en) * 2004-10-08 2011-06-22 株式会社神戸製鋼所 Heat-resistant Al-based alloy with excellent high-temperature fatigue properties

Also Published As

Publication number Publication date
EP1881084A1 (en) 2008-01-23
DE602007009604D1 (en) 2010-11-18
PL1881084T3 (en) 2011-03-31
ATE483831T1 (en) 2010-10-15
JP5010196B2 (en) 2012-08-29
JP2008023532A (en) 2008-02-07
HK1117203A1 (en) 2009-01-09

Similar Documents

Publication Publication Date Title
EP1881084B1 (en) Manufacturing method for heat resistant aluminium alloy shaped products and heat resistant aluminium alloy shaped product
EP2104577B1 (en) Apparatus and method for extruding micro-channel tubes
EP2283166B1 (en) Aluminum alloy heat exchanger extruded tubes
CN109280820A (en) It is a kind of for the high-strength aluminum alloy of increasing material manufacturing and its preparation method of powder
US20110236721A1 (en) Steel compositions, methods of forming the same, and articles formed therefrom
KR20120123387A (en) Systems and methods for forming and processing alloy ingots
EP3384060B1 (en) Highly rigid thin sheet metal for car body
CN101304822A (en) A multi-alloy monolithic extruded structural member and method of producing thereof
CN109317667B (en) Preparation method of hybrid aluminum-based composite pipe
US8499606B2 (en) Refractory metal pots
EP1372884B1 (en) Closed die forging method and yoke produced by the method
Naseri et al. EBSD characterization of nano/ultrafine structured Al/Brass composite produced by severe plastic deformation
Leoni et al. High temperature tensile properties of AA6082 filler wire used for solid-state joining
US20220049346A1 (en) Sputtering Target and Method for Producing Same
EP3859048A1 (en) Sputtering target and method for producing same
Hartlieb High integrity diecasting for structural applications
JPH11314051A (en) Water ejecting device and production of hollow member
Smirnova et al. Liquid phase fabrication technology of layered Ti/Al composite.
Sandnes et al. Using the Hybrid Metal Extrusion & Bonding (HYB) Process for Butt Welding of 4 mm Plates of AA6082-T6
Rahmatabadi et al. Evaluation of Microstructure and Mechanical Properties of Al5052/Cu Multi-Layered Composite Fabricated by the ARB Process
Shashank Rao et al. Preliminary studies on friction welding of sintered P/M steel preforms to wrought mild steel
da Silva Junior et al. Fabrication of AA3303 aluminum alloy by powder metallurgy techniques consolidated by sintering
SAS-BOCA et al. The properties of bimetallic multi-layer (C45 and S235JR) and the multi-layer steel made by forging
EP1637246A1 (en) Method of extruding hollow light metal member, die for extruding hollow light metal, and memeber for extruding hollow light metal
Pawłowska Analysis of the Possibility of Obtaining Aviation Profiles from 7039 Aluminum Alloy in the Extrusion Process

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA HR MK YU

17P Request for examination filed

Effective date: 20080703

17Q First examination report despatched

Effective date: 20080801

AKX Designation fees paid

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1117203

Country of ref document: HK

RTI1 Title (correction)

Free format text: MANUFACTURING METHOD FOR HEAT RESISTANT ALUMINIUM ALLOY SHAPED PRODUCTS AND HEAT RESISTANT ALUMINIUM ALLOY SHAPED PRODUCT

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 602007009604

Country of ref document: DE

Date of ref document: 20101118

Kind code of ref document: P

REG Reference to a national code

Ref country code: HK

Ref legal event code: GR

Ref document number: 1117203

Country of ref document: HK

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20101006

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

LTIE Lt: invalidation of european patent or patent extension

Effective date: 20101006

REG Reference to a national code

Ref country code: PL

Ref legal event code: T3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110206

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110207

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110106

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110107

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110117

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

26N No opposition filed

Effective date: 20110707

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602007009604

Country of ref document: DE

Effective date: 20110707

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20110614

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110630

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110614

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110614

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110614

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101006

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 10

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 11

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 12

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20200602

Year of fee payment: 14

Ref country code: CZ

Payment date: 20200529

Year of fee payment: 14

Ref country code: FR

Payment date: 20200512

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PL

Payment date: 20200403

Year of fee payment: 14

Ref country code: IT

Payment date: 20200512

Year of fee payment: 14

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602007009604

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210614

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20220101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210614

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210614