EP1871863A2 - Composition contenant des compose polyamino-polysiloxane et/ou polyammonium-polysiloxane sur un substrat - Google Patents

Composition contenant des compose polyamino-polysiloxane et/ou polyammonium-polysiloxane sur un substrat

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Publication number
EP1871863A2
EP1871863A2 EP06742529A EP06742529A EP1871863A2 EP 1871863 A2 EP1871863 A2 EP 1871863A2 EP 06742529 A EP06742529 A EP 06742529A EP 06742529 A EP06742529 A EP 06742529A EP 1871863 A2 EP1871863 A2 EP 1871863A2
Authority
EP
European Patent Office
Prior art keywords
groups
group
polysiloxane
polyammonium
polyamino
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06742529A
Other languages
German (de)
English (en)
Inventor
Roland Wagner
Sabine Nienstedt
Christopher Roos
Annette Moeller
Karl-Heinz Sockel
Karl-Heinz Staghulla
Anita Witossek
Horst Lange
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Momentive Performance Materials GmbH
Momentive Performance Materials Inc
Original Assignee
Momentive Performance Materials GmbH
Momentive Performance Materials Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Momentive Performance Materials GmbH, Momentive Performance Materials Inc filed Critical Momentive Performance Materials GmbH
Publication of EP1871863A2 publication Critical patent/EP1871863A2/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3742—Nitrogen containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/047—Arrangements specially adapted for dry cleaning or laundry dryer related applications
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups

Definitions

  • the invention relates to compositions which comprise at least one polyamino and / or polyammonium-polysiloxane compounds on a substrate, processes for their preparation and their use for textile treatment, in particular for the treatment of wet textiles after washing.
  • a method for conditioning laundry is known, wherein the wet laundry articles under heat in a clothes dryer together with a conditioning agent containing 'substrate with agitation mixed, the transition of the conditioning agent on the laundry articles during the drying takes place.
  • conditioners for example, softening and antistatic agents, bacteriostats, fungus and moth repellent are used.
  • softening and antistatic agents mention is generally made of cationic compounds such as ammonium compounds.
  • ammonium compounds are disadvantageous since they generally do not have sufficient substantivity, i. their ability to permanently grow on the fiber during conventional laundry drying is low. Attempting to improve substantivity by, for example, increasing the content of ammonium groups is usually accompanied by a deterioration of the softening properties. Furthermore, relatively high amounts of conditioning agents are required because the conditioners under the conditions of laundry drying repeatedly detach from the laundry and get into the environment by means of the dryer exhaust air.
  • compositions containing a substrate and at least one polyamino and / or polyammonium-polysiloxane compound coated on the substrate are capable of solving the above described problem.
  • Polysiloxane compounds are characterized in that they comprise on average at least one organopolysiloxane group and at least one amino and / or ammonium group.
  • the polyamino and / or polyammonium-polysiloxane compounds contain on average at least two, more preferably at least three organopolysiloxane grappenes and at least two, more preferably at least three, amino and / or ammonium clusters.
  • An organopolysiloxane according to the invention is a group having at least ⁇ two connected via an oxygen atom silicon atoms, wherein at least one of the silicon atoms having at least one bound via a carbon atom of the organic radical.
  • the polyamino and / or polyammonium-polysiloxane compounds are selected from polyamino and / or polyammonium-polysiloxane copolymer compounds.
  • Such copolymer compounds are characterized by a content of linear molecular segments with alternating organopolysiloxane Grappen and amino and / or ammonium groups. This does not exclude that the copolymer compound may be branched.
  • the polyamino- and / or polyammonium-polysiloxane copolymer compounds are characterized in that they have at least one, preferably on average at least two, more preferably on average at least three repeat units of the formula (I) :
  • Q is selected from the group consisting of: -NR.-, -N + R 2 -
  • each R is hydrogen or a monovalent organic radical
  • V is selected from the group consisting of V 1 , V 2 and V 3 , wherein
  • V 2 is selected from 2-valent, straight-chain, cyclic or branched, saturated, unsaturated or aromatic
  • Hydrocarbon radicals having up to 1000 carbon atoms (wherein the carbon atoms of the polysiloxane radical Z 2 defined below are not included), optionally one or more groups selected from
  • R 2 represents hydrogen, a monovalent, straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 100 carbon atoms and having one or more groups selected from -O-, -NH-, -C (O) - and -C (S) -, and optionally by one or more substituents selected from the group consisting of a hydroxyl group, an optionally substituted, preferably containing one or more nitrogen atoms heterocyclic group, amino, alkylamino,
  • Polyetheresterresten may be substituted, wherein when several groups -CONR 2 , they may be the same or different,
  • radical V 2 optionally by one or more hydroxyl groups and / or by
  • R and R ' may be the same or different and each represents an organic group, may be substituted, and
  • the radical V 2 is at least one group -Z 2 - of the formula
  • R 1 may be the same or different and is selected from the group consisting of: Ci to C 22 alkyl, fluoro (Ci-Ci 0 ) alkyl, C 6 -C 0 -aryl and -W-Si (OR) 3- a (R ') a, wherein R, R' and V are as defined above, and W is -O- or a divalent, straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical up to 100 carbon atoms, which may contain one or more groups - C (O) -, -O-, -NH-, -S-, and may optionally be substituted by hydroxy groups, and
  • V 1 is selected from divalent, straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radicals having up to 1000 carbon atoms, optionally one or more groups selected from
  • R 2 is as defined above, wherein the groups R 2 in the groups V 1 and V 2 may be the same or different,
  • -C (O) -, -C (S) - and -Z 1 - may contain, wherein -Z 1 - a group of the formula
  • radical V 1 optionally by one or more hydroxyl groups and / or by
  • R and R ' may be the same or different each other and each represents an organic group, may be substituted, and
  • V 3 is a trivalent or higher, straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 1000 carbon atoms, optionally one or more groups selected from
  • Z 3 wherein Z 3 is a tri- or higher organopolysiloxane unit, may contain, and
  • a is an integer from 0 to 2 and R and R 'may be the same or different and each represents an organic radical, may be substituted, may be substituted, with the proviso that said polysiloxane compound contains at least one group -Z 1 -, -Z 2 - or Z 3 , that the tri- and tetravalent radicals Q serve either the branching of the main chain formed from Q and V such that the Valences that do not serve for attachment in the backbone, further branches formed from [QV] units, or the tri- and tetravalent residues Q saturate with residues V 3 within a linear backbone without forming a branch, and wherein the from ammonium groups resulting positive charges are neutralized by organic or inorganic acid anions.
  • These copolymer compounds have a particularly high substantivity with high plasticizing effect.
  • the substituents R in the groups Q comprise one or more radicals R 0 , where R 0 is a polyalkylene oxide-containing organic radical.
  • R 0 is a polyalkylene oxide-containing organic radical.
  • Polyamino and / or polyammonium-polysiloxane copolymer compounds characterized in that the molar ratio R 0 : Q from 0.001 to 2, more preferably from 0.01 to 1, more preferably 0.05 to 0.8. If the molar ratio is less than 0.001, the hydrophilicity is too low. An optimal coordination of softness and hydrophilicity succeeds in the range from 0.05 to 0.8.
  • the radical R ° preferably represents a group of the formula (III):
  • X represents a single bond or a divalent, straight-chain, branched or cyclic hydrocarbon radical having up to 20 carbon atoms, which may optionally contain nitrogen and / or oxygen, and X is connected via a carbon atom to the nitrogen atom of Q,
  • E is a polyalkylene oxide radical of the formula
  • Y represents hydrogen or a monovalent, straight-chain, branched or cyclic, saturated, unsaturated or aromatic hydrocarbon radical having up to 24 carbon atoms, which may contain oxygen and / or nitrogen and / or halogen and is bonded to the group E via a carbon atom.
  • R 0 is a group of the formula (III) in which - E - represents a group of the formula (IV):
  • Y is preferably selected from H or straight-chain, cyclic, branched C 1 - to C 22 -alkyl, alkenyl, alkynyl, fluoro (C 1 -C 10) -alkyl and C 6 -C 10 -aryl aryl radicals.
  • alkylene oxide units R 0 preferably have the structure:
  • Y H or straight-chain, cyclic, branched C 1 to C 22 alkyl, alkenyl,
  • v 0 to 100 preference is given to: v 0 to 100, more preferably 0 to 70, especially 0 to 40, especially 0 to 20, w 0 to 100, particularly preferably 0 to 70, especially 0 to 40, especially 0 to 20, Y is a straight-chain, cyclic, branched Ci to Cn alkyl, alkenyl, alkynyl, or C ö -Cio aryl group, especially methyl, ethyl, isopropyl, butyl, hexyl, dodecyl,
  • Another preferred alkylene oxide unit R 0 has the structure - (C 1 -C 12) alkylene-N + R 2 EY, where C 1 -C 12 alkylene is a straight-chain, cyclic or branched one
  • Alkylene unit having 1 to 12 carbon atoms, and R, E and Y are as defined above.
  • the polysiloxane compounds which contain on average preferably at least two, preferably at least three, more preferably at least four units of the formula (I), wherein preferably on average at least two, more preferably at least three, even more preferably at least four units R 0 can be contained, and in Agents preferably at least one unit V 1 , V 2 and / or V 3 are included are preferably terminated by monofunctional groups -QR and / or -VR, ie for example by amino groups. These result from saturation of one of the two binding sites of Q or V by a monovalent group R or hydrogen, which is as defined above, and are also referred to below as V * or Q st . Instead of V *, other, unreacted reactive groups, such as epoxy or Halogenalkylgmppen stand.
  • polysiloxane compounds according to the invention which contain on average preferably at least two units of the formula (I), wherein on average preferably at least two units R 0 may be present, and on average preferably at least one unit V 1 , V 2 and / or V 3 are, for example, linear polysiloxane copolymers of the general formula (P):
  • V and at least one group V 1 or group V 2 , wherein V 1 and V 2 are as defined above.
  • V can also represent trivalent or higher valency, especially trivalent radicals V 3 .
  • Groups V 1 and V 2 in the polysiloxane compounds Wv 1 take on any value per se.
  • the case is also included in which the polysiloxane compound of the formulas (I) or (P) contains only V 2 units, ie the polysiloxane compound has the formula - [QV 2 ] -.
  • the case where the polysiloxane compound contains only V 1 units is included in the invention. In this case, however, the V 1 units must contain Z 1 siloxane units.
  • the polysiloxane compound of formulas (I) or (P) contains both V 2 and V 1 units.
  • the molar ratio of the groups V 1 and V 2 in the polysiloxane compounds of the general formulas (I) or (P) is:
  • V 2 ⁇ I.
  • linear polysiloxane compounds of the formula (I) b2w. (P) is V 2 A ⁇ 1 other than I 5 V 2 / V x is preferably ⁇ 1, more preferably ⁇ 0.9, more preferably, Wv 1 satisfies the relationship
  • the group R is preferably selected from the groups R 2 .
  • Preferred embodiments of Q are:
  • t is from 2 to 10
  • R as defined above, preferably R 2, R 2 is as defined above, and the meaning of R from the meaning of the above group R may be identical or different,
  • R 3 has the meaning of R 2 , wherein R 2 and R 3 may be the same or different, or
  • R 2 and R 3 together with the positively charged nitrogen atom form a five- to seven-membered heterocycle which may optionally additionally have one or more nitrogen, oxygen and / or sulfur atoms
  • R 5 , R 6 , R 7 may be the same or different and are selected from the group consisting of: H, halogen, hydroxyl, nitro, cyano, thiol, carboxyl, alkyl, monohydroxyalkyl, polyhydroxyalkyl, thioalkyl, cyanoalkyl, alkoxy, acyl, acetyloxy, cycloalkyl, aryl, alkylaryl, and Groups of the type -NHR W , in which R w is H, alkyl group, monohydroxyalkyl group, polyhydroxyalkyl group, acetyl group, ureido group, and in each case two of the adjacent radicals R 5 , R 6 and R 7 with the them to the heterocycle-binding carbon atoms aromatic five to Can form seven
  • Formula (I) or (V) V 2 represents a group of the formula
  • V 2 * - represents a bivalent straight, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 40 carbon atoms, optionally containing one or more groups selected from -O-, -CONH -, -CONR 2 -, wherein R 2 is as defined above, -C (O) - and -C (S) - may contain, and the radical V 2 * may optionally be substituted by one or more hydroxyl groups.
  • the linear polysiloxane copolymer according to the invention may have the following repeating units:
  • the comb-like introduction of hydrophilic side groups R 0 makes it possible to increase the proportion of the plasticizing properties contributing group V 2 with constant hydrophilicity. Conversely, given a proportion of plasticizing groups V 2, it is possible to increase the hydrophilicity by introducing the group R 0 .
  • linear polysiloxane copolymers In the regular compound in which, for example, one of the group -Q-JV'-QJ x -responding prepolymer with V 2 corresponding monomer units in a molar ratio of 1: 1 is reacted, the linear polysiloxane copolymers can be represented as follows:
  • x may be 2 to 2000 and is the mean of the distribution and y is also an average and is 2 to 1000.
  • the polysiloxane polymers according to the invention preferably have the formula
  • y ' is from 2 to 1000, more preferably from 3 to 500, even more preferably from 4 to 200.
  • Polysiloxane copolymers are characterized by having substantially no interlinked -V 2 -Q units, or with others
  • two -V 2 -Q units are always interrupted by at least one -V ⁇ Q unit.
  • Q units are monomers corresponding to monomer units corresponding to V 1 and monomer units corresponding to V 2 in the ratio Qf (V 1 + V 2 ), with, for example
  • the linear polysiloxane copolymers can be prepared as follows:
  • V is the ratio V 2 / V ! then> 1 is.
  • the groups V 1 and V 2 are statistically distributed over the copolymer chain. In contrast to the linear polysiloxane copolymers prepared by the regular compound, this
  • Copolymer also have adjacent -QV 2 units.
  • Polysiloxane compound of the formula (I) or (P), the group V 1 is selected from divalent, straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radicals having up to 600, preferably up to 400, carbon atoms which optionally have one or more groups,
  • R 1 is Ci-Cis-alkyl, which may be optionally substituted with one or more fluorine atoms, or phenyl, and ⁇ . 2 as defined above.
  • the group Q is selected from:
  • R 2 is preferably H or alkyl, preferably having 1 to 6 carbon atoms
  • R 3 is preferably H, alkyl, preferably having 1 to 6 carbon atoms, or R 0 .
  • R 1 Ci to Cis-alkyl, in particular methyl, ethyl, trifluoropropyl and phenyl,
  • ni 20 to 400, more preferably 20 to 300, especially 20 to 200. In a further preferred embodiment, ni is between 20 and 50 or between 80 and 200. The number ni is the average degree of polymerization of M n of the diorganosiloxy units in the Group Z 2 .
  • ⁇ . 2 0 to 15, more preferably 0 to 10, especially 0 to 5, more particularly 0.
  • the number ⁇ . 2 is the average degree of polymerization of M n of the diorganosiloxy units in the group Z 1 .
  • V 2 * for a divalent straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical with up to 16 Carbon atoms which may contain one or more groups selected from -O-, -CONH-, -CONR 2 -, wherein R 2 is as defined above, -C (O) -, -C (S) - and having a or more hydroxyl groups may be substituted. Even more preferably, -V 2 * - is selected from groups of the formulas:
  • -CH CHCH 2 -
  • -CH CHCH 2 CH 2 -
  • -CH CHCH 2 OC (O) CH 2 -
  • -CH CHCH 2 OC (O) CH 2 CH 2 -
  • CH 3 -CH CHCH 2 (OCH 2 CH 2 ) V (OCH 2 CH) WOC (O) CH 2 -
  • CH 3 -CH CHCH 2 CH 2 (OCH 2 CH 2) v (OCH 2 CH) w OC (O) CH 2 CH 2 -
  • -CH CHCH 2 -
  • -CH CHCH 2 CH 2 -
  • V 1 preferably represents ⁇ -R 9 -, in which R 9 represents a divalent, saturated or mono- or polyunsaturated, straight-chain or branched hydrocarbon radical having from 2 to 25 carbon atoms, - (CH 2 ) u C (O) O - [(CH 2 CH 2 O) q - (CH 2 CH (CH 3 ) O) r ] -C (O) (CH 2 ) u -
  • R 10 is an aromatic group, - [CH 2 CH 2 O] q - [CH 2 CH (CH 3 ) O] r -CH 2 CH 2 -, ⁇ -CH (CH 3) CH 2 O [CH 2 CH 2 O] q - [CH 2 CH (CH 3) O] r -CH 2 CH (CH 3) -
  • V 1 -CH 2 CH (OH) CH 2 OCH 2 CH (OH) CH 2 OCH 2 CH (OH) CH 2 OCH 2 CH (OH) CH 2 - and -CH 2 CH (OH) CH 2 O- [CH 2 CH 2 O] q - [CH 2 CH (CH 3 ) O] r -CH 2 CH (OH) CH 2 -
  • u is from 1 to 3
  • q and r is from 0 to 200, preferably from 0 to 100, more preferably from 0 to 70 and particularly preferably 0 to Is 40, and q + r> 0.
  • Preferred variants of V 1 are structures of the formula:
  • O-CH 2 C CCH 2 -OC (O) CH 2 CH 2 CH 2 -,
  • a, b and c may be the same or different and from 1 to 40,
  • R 1 is in each case as defined above.
  • Z 3 -containing branching unit V 3 is, for example:
  • the polysiloxanes used according to the invention may contain units R °, which are preferably incorporated into the polymer by suitable alkylation reactions of primary, secondary or tertiary monoamino-functionalized polyalkylene oxides with reactively functionalized siloxane precursors.
  • the primary mono functionalized Jeffamine ® M series (Huntsman Corp.) are preferably used.
  • the primary mono-amino-functionalized polyalkylene oxides are first alkylated in an upstream reaction with the reactive-functionalized siloxanes, preferably epoxysiloxanes, to form tertiary amines. These precursors are incorporated into the siloxane block copolymer in the subsequent polymer formation reaction.
  • the reactive-functionalized siloxanes preferably epoxysiloxanes
  • polyalkylene oxide units are intended to terminate the siloxane block polymers in a controlled manner
  • secondary or tertiary amino-functionalized polyalkylene oxide units can be prepared by pre-reaction of the primarily monofunctionalized polyalkylene oxides with alkylating agents, for example monoepoxides such as isopropyl glycidyl ether or dimethyl sulfate.
  • the monofunctionally bonded hydrophilic element R 0 can be introduced into the polyquaternary polysiloxane copolymers used according to the invention in order to increase the hydrophilicity in a targeted manner. This leads to both Increased hydrophilicity of the polysiloxane copolymers themselves according to the invention, so that, for example, a facilitated transition into the moisturizing takes place, as well as to increase the hydrophilicity of the treated with the compositions of the invention textiles, which leads for example to an improved moisture absorption of textiles.
  • alternating polysiloxane-quat block copolymers which can be used according to the invention are described, for example, in DE OS 3340708, US Pat. No. 6,240,929, EP 282720, DE OS 10036533, WO 02/10257, WO 02/10259, WO 03/078504, WO 2004/041912, WO 2004 / 042136 and application PCT / EP 2004/050472.
  • the polyamino used in the invention and / or polyammonium-polysiloxane compounds may be solid or liquid at 25 0 C.
  • the substrate is generally a solid support material (at room temperature (25 ° C.) and preferably up to the decomposition temperature) which is capable of absorbing the polyamino and / or polyammonium-polysiloxane compounds and, in particular, among them Discharge conditions of laundry drying again. Therefore, it is preferably a porous material.
  • the substrates may be, for example, layered, bag-like, or in compact layers. Also, solid non-deformable, porous substrates are applicable, such as granules, which in turn may be enclosed in wipes. Particularly preferably, the substrate is in the form of a layered material.
  • spongy or fibrous materials such as fiber fabrics, non-woven fabrics, paper towels are preferred.
  • the substrate material can accommodate the polyamino and / or polyammonium-polysiloxane compounds.
  • Preferred materials are natural or synthetic fibers, such as those based on cellulose, such as cotton, furthermore wool, sisal, linen, cellulose esters, polyols. vinyl compounds, polyolefins, polyamides, polyurethanes, polyesters.
  • Sponge-like materials may for example consist of polyurethanes.
  • compositions according to the invention suitably contain from 0.01 to 20% by weight, preferably from 0.1 to 10% by weight, more preferably from 0.3 to 5% by weight, of the polyamino and / or polyammonium-polysiloxane compounds, based on the total weight of the composition.
  • the composition according to the invention may contain at least one further textile treatment agent.
  • fabric treatment agents include, for example, other softening and antistatic agents other than those used in the present invention, bacteriostats, antifungal and mothproofing agents, deodorants, fragrances, ironing aids, anti-caking agents, etc. These may be used in amounts of up to 20% by weight .-% be contained in the composition of the invention.
  • composition of the invention may contain one or more solvents, such as water or alcohols.
  • the invention further relates to a process for the preparation of the composition according to the invention, which comprises applying at least one polyamino and / or polyammonium-polysiloxane compound to the substrate.
  • the application can be carried out in a manner known per se (see, for example, US Pat. No. 3,442,692), for example by impregnation, spraying, etc., if appropriate using solvents.
  • the end user is provided with the polyamino and / or polyammonium-polysiloxane compounds optionally in admixture with further ingredients in liquid form for application to a separately provided solid substrate, and the end user the inventive Composition by impregnation of the solid substrate with the provided liquid composition immediately before the application itself manufactures.
  • the invention further relates to a method for the treatment of textiles, which comprises contacting the inventive composition with the textiles. Preference is given to the composition of the invention with the still moist, resulting from the textile laundry textiles preferably at temperatures of more than 25 0 C, preferably brought using commercial clothes dryer in contact. Accordingly, the invention further relates to the use of the composition according to the invention for the treatment of textiles made of natural or synthetic fibers. The invention further relates to the use of polyamino and / or polyammonium-polysiloxane copolymer compounds for the production of solid textile treatment agents, in particular for the production of substrate-based textile treatment agents.
  • solid means that the outer application form does not substantially change during application to the textiles, which is ensured in particular by the use of a solid support, as defined above.
  • Washing tests are carried out in a Miele Novotronic W526. Washing conditions: 95 0 C, short cycle, 2x rinse, soft dosage of the freshener in the second rinse, spin at 1200 U / min Drying: 24 hours drying canvas.
  • the cloths equipped according to the invention receive an overall grade of +0.58.
  • the sinking of the drops onto the cloth not equipped according to the invention takes place on average after 1 second and is visibly delayed with respect to the cloths provided according to the invention.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Silicon Polymers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne des compositions qui comprennent au moins un composé polyamino-polysiloxane et/ou polyammonium-polysiloxane sur un substrat. L'invention concerne également des procédés pour la production de ces compositions ainsi que l'utilisation de ces dernières pour le traitement de textiles, notamment pour le traitement de textiles humides après le lavage.
EP06742529A 2005-03-30 2006-03-30 Composition contenant des compose polyamino-polysiloxane et/ou polyammonium-polysiloxane sur un substrat Withdrawn EP1871863A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005014312A DE102005014312A1 (de) 2005-03-30 2005-03-30 Zusammensetzung enhaltend Polyamino- und/oder Polyammonium-Polysiloxan-Verbindungen auf einem Substrat
PCT/EP2006/002911 WO2006103076A2 (fr) 2005-03-30 2006-03-30 Composition contenant des compose polyamino-polysiloxane et/ou polyammonium-polysiloxane sur un substrat

Publications (1)

Publication Number Publication Date
EP1871863A2 true EP1871863A2 (fr) 2008-01-02

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Country Link
US (1) US20080194785A1 (fr)
EP (1) EP1871863A2 (fr)
JP (1) JP2008537985A (fr)
CN (1) CN101151358A (fr)
DE (1) DE102005014312A1 (fr)
WO (1) WO2006103076A2 (fr)

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DE10316662A1 (de) * 2003-04-11 2004-11-11 Ge Bayer Silicones Gmbh & Co. Kg Reaktive Amino- und/oder Ammonium-Polysiloxanverbindungen
DE102005018315B4 (de) * 2005-04-20 2017-11-16 Rudolf Gmbh & Co. Kg Chemische Fabrik Wässrige Zubereitungen auf Basis von carboxyfunktionellen Organopolysiloxan-Polyammonium-Copolymeren und deren Verwendung auf cellulosischen Substraten
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US20080194785A1 (en) 2008-08-14
JP2008537985A (ja) 2008-10-02
WO2006103076A3 (fr) 2006-12-21
DE102005014312A1 (de) 2006-10-19
CN101151358A (zh) 2008-03-26

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