EP1868269B1 - Electrode assembly - Google Patents
Electrode assembly Download PDFInfo
- Publication number
- EP1868269B1 EP1868269B1 EP06012197A EP06012197A EP1868269B1 EP 1868269 B1 EP1868269 B1 EP 1868269B1 EP 06012197 A EP06012197 A EP 06012197A EP 06012197 A EP06012197 A EP 06012197A EP 1868269 B1 EP1868269 B1 EP 1868269B1
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- European Patent Office
- Prior art keywords
- electrode arrangement
- test electrodes
- electrode
- electrodes
- spacings
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- 239000000463 material Substances 0.000 claims abstract description 22
- 239000011248 coating agent Substances 0.000 claims abstract description 18
- 238000000576 coating method Methods 0.000 claims abstract description 18
- 238000009832 plasma treatment Methods 0.000 claims abstract description 14
- 238000012360 testing method Methods 0.000 claims description 10
- 230000008719 thickening Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000012549 training Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
- H01T19/00—Devices providing for corona discharge
Definitions
- the invention relates to an electrode arrangement as a high-voltage electrode for the continuous plasma treatment or plasma coating of sheet material having a plurality of transverse to a transport direction of the web material arranged substantially parallel to each other knife electrodes.
- Such electrode arrangements are known and are widely used in the plasma treatment or plasma coating of usually electrically non-conductive sheet material, e.g. Plastic film or the like., Used. These electrodes are typically used as high-voltage electrodes with a transport roller opposite the free ends of the blade electrodes and designed as a counterelectrode.
- the plasma discharge between knife electrodes in the gas gap to the counter electrode is ignited, and the material plasma-treated or -coated.
- a plasma treatment is typically carried out without the use of precursors, in which case due to the ignited plasma only a change in the surface states of the treated material takes place in order to improve, for example, the adhesion of a later applied coating material or the like.
- a plasma coating can be carried out with such electrodes, in which case precursors are introduced into the gap or space formed between the electrodes and the web material, which supply the starting materials for the coating.
- knife electrodes are elongated, blade-like electrodes, which are generally fixed with one of their longitudinal edges in a high-voltage arrangement and form the actual discharge surface with their other longitudinal edge, such as, for example EP-A-0 095 051 known.
- the blade electrodes are arranged at the same distance between adjacent electrodes, that is, equidistant.
- the distances between adjacent blade electrodes at the edge of the electrode assembly are greater than in the center thereof.
- those regions are meant which, viewed in a transport direction of the web material, lie at the front or rear end of the electrode arrangement (cf claim 2).
- the blade electrodes are preferably arranged according to the specifications of claim 6.
- the subject of the invention is a device for the continuous plasma treatment or plasma coating of web material with the features of claim 7. It is essential here that the device contains an electrode arrangement as described above.
- Fig. 1 is a provided with an inventive electrode assembly 1 plasma treatment or coating device 10 in sections and shown schematically.
- the electrode assembly 1 is connected via a separate high voltage supply with insulators 11 relative to the rest of the device 10.
- a treatment section 12 Opposite a treatment section 12, not shown here in detail, is a transport roller designed as a counterelectrode, with which the web material to be treated or to be coated is guided through the intermediate space between this transport roller and the electrode arrangement 1.
- the plasma - in Fig. 1 not shown - is ignited between plasma treatment and plasma coating apparatus 10 and transport roller.
- the electrode assembly 1 is shown enlarged again. It contains an electrode holder 2 and a plurality, in this embodiment a total of 14, knife electrodes 3. These knife electrodes are constructed in bones in cross section with integrally formed on both longitudinal edges, in cross-section substantially circular or part-circular thickening.
- the second, formed on the free-standing edge of the blade electrode thickening forms a discharge bar 5. This discharge bar 5 is thicker or thicker in cross-section than the adjoining blade 6 of the blade electrode 3.
- the diameter of the discharge strip 5 does not have to be the same in the electrode arrangement, as a result of which strong sliding discharges at the edge and thus at the front or rear end of the electrode arrangement 1 are minimized.
- the individual, adjacent blade electrodes 3 are arranged at variable distances from one another, wherein the distances between adjacent blade electrodes 3 at the outer edges of the electrode assembly 1 are greater than the spacings of adjacent blade electrodes 3 in the center of the assembly 1.
- the inventive structure of the electrode assembly 1 with substantially parallel to each other, in the transport direction of the web material to be treated or coated successively arranged knife electrodes 3 at different distances creates improved homogeneity and quality of the performed with this plasma treatment or plasma coating under this electrode assembly. 1 on the formed as a counter electrode transport roller guided through web material. This could be confirmed experimentally.
- the formation of the discharge strips 5 with the circular or partial circular shape in cross section also resulted in improved quality of the plasma coating or treatment compared to known discharge edge shapes.
- the shape of the electrode assembly 1 shown in the embodiment and the distances a to e indicated therein are not limiting, various different shapes and spacing distributions may instead be adhered to.
- the features essential to the invention are given in the claims, which are intended to define the scope of the invention or of the protection.
Landscapes
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Physics & Mathematics (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Plasma Technology (AREA)
- Ceramic Capacitors (AREA)
- Treatment Of Fiber Materials (AREA)
- Coating Apparatus (AREA)
- Chemical Vapour Deposition (AREA)
- Surgical Instruments (AREA)
- Coils Or Transformers For Communication (AREA)
- Electron Tubes For Measurement (AREA)
- Secondary Cells (AREA)
Abstract
Description
Die Erfindung betrifft eine Elektrodenanordnung als Hochspannungselektrode für die kontinuierliche Plasmabehandlung oder Plasmabeschichtung von Bahnmaterial mit einer Mehrzahl von quer zu einer Transportrichtung des Bahnmaterials angeordneten, im wesentlichen parallel zueinander stehenden Messerelektroden.The invention relates to an electrode arrangement as a high-voltage electrode for the continuous plasma treatment or plasma coating of sheet material having a plurality of transverse to a transport direction of the web material arranged substantially parallel to each other knife electrodes.
Derartige Elektrodenanordnungen sind bekannt und werden vielfältig in der Plasmabehandlung oder Plasmabeschichtung von in der Regel elektrisch nicht leitendem Bahnmaterial, z.B. Kunststofffolie oder dgl., eingesetzt. Diese Elektroden werden typischerweise als Hochspannungselektroden verwendet mit einer den freien Enden der Messerelektroden gegenüberliegenden, als Gegenelektrode ausgebildeten Transportwalze.Such electrode arrangements are known and are widely used in the plasma treatment or plasma coating of usually electrically non-conductive sheet material, e.g. Plastic film or the like., Used. These electrodes are typically used as high-voltage electrodes with a transport roller opposite the free ends of the blade electrodes and designed as a counterelectrode.
Durch die Spannungsdifferenz wird die Plasmaentladung zwischen Messerelektroden im Gasspalt zur Gegenelektrode gezündet, und das Material plasmabehandelt bzw. -beschichtet.Due to the voltage difference, the plasma discharge between knife electrodes in the gas gap to the counter electrode is ignited, and the material plasma-treated or -coated.
Eine Plasmabehandlung erfolgt dabei typischerweise ohne den Einsatz von Precursoren, wobei hier aufgrund des gezündeten Plasmas lediglich eine Veränderung der Oberflächenzustände des behandelten Materials erfolgt, um beispielsweise die Adhäsion eines später aufgebrachten Beschichtungsmaterials oder dgl. zu verbessern. In gleicher Art und Weise kann auch eine Plasmabeschichtung mit solchen Elektroden durchgeführt werden, wobei hier Precursoren in den zwischen den Elektroden und dem Bahnmaterial gebildeten Spalt bzw. Raum eingebracht werden, die die Ausgangsstoffe für die Beschichtung liefern.A plasma treatment is typically carried out without the use of precursors, in which case due to the ignited plasma only a change in the surface states of the treated material takes place in order to improve, for example, the adhesion of a later applied coating material or the like. In the same way, a plasma coating can be carried out with such electrodes, in which case precursors are introduced into the gap or space formed between the electrodes and the web material, which supply the starting materials for the coating.
Bei den sogenannten Messerelektroden handelt es sich um langgestreckte, klingenähnliche Elektroden, die in der Regel mit einer ihrer Längskanten in einer Hochspannungsanordnung festgelegt sind und mit ihrer anderen Längskante die eigentliche Entladungsfläche bilden, wie z.B aus
Bei den bisher bekannten vergleichbaren Elektrodenanordnungen werden die Messerelektroden in gleichem Abstand zwischen benachbarten Elektroden, also äquidistant, angeordnet.In the previously known comparable electrode arrangements, the blade electrodes are arranged at the same distance between adjacent electrodes, that is, equidistant.
In von der Anmelderin durchgeführten Versuchen hat sich gezeigt, dass mit solchen Elektrodenanordnungen erzielte Plasmabehandlungs- bzw. Plasmabeschichtungsergebnisse hinsichtlich der Homogenität noch verbesserungswürdig sind. Insbesondere stellen Gleitentladungen entlang der Materialoberfläche vielfach eine starke, inhomogene, thermische Belastung des Materials dar, die den Einsatz eines Elektrodensystems oft gegrenzt. Entsprechend stellte sich den Erfindern die Aufgabe, die bekannten Elektrodenanordnungen zu verbessern, um ein verbessertes Behandlungs- bzw. Beschichtungsergebnis auf dem plasmabehandelten bzw. plasmabeschichteten Bahnmaterial zu erzielen.In tests carried out by the Applicant, it has been found that plasma treatment or plasma coating results achieved with such electrode arrangements are in need of improvement in terms of homogeneity. In particular, sliding discharges along the material surface often represent a strong, inhomogeneous, thermal load on the material, which often limits the use of an electrode system. Accordingly, the inventors had the task of improving the known electrode arrangements in order to achieve an improved treatment or coating result on the plasma-treated or plasma-coated web material.
Am Ende einer langen und ausgedehnten Versuchsreihe hat sich überraschend herausgestellt, dass sich eine solchermaßen angestrebte Verbesserung dann erzielen lässt, wenn wie im kennzeichnenden Teil des Anspruches 1 angegeben die Abstände benachbarter Messerelektroden anders als im bekannten Stand der Technik unterschiedlich sind. Die physikalische Ursache für die beobachtete Verbesserung ist bisher nicht vollständig geklärt und noch Gegenstand weitergehender Untersuchungen. Entscheidend für die Verbesserung scheint jedoch zu sein, dass die neue Anordnung der Messerelektroden die Vorteile eines großen Messerabstandes hinsichtlich der Problematik der Gleitentladungen mit den Vorteilen eines geringeren Messerabstandes hinsichtlich der spezifischen elektrischen Belastbarkeit kombiniert.At the end of a long and extensive series of experiments, it has surprisingly been found that such an improvement can be achieved if, as indicated in the characterizing part of
Bevorzugt sind die Abstände benachbarter Messerelektroden am Rand der Elektrodenanordnung größer als in deren Zentrum. Mit Rand der Elektrodenanordnung sind dabei diejenigen Bereiche gemeint, die in einer Transportrichtung der Bahnmaterials gesehen am vorderen bzw. hinteren Ende der Elektrodenanordnung liegen (vgl. Anspruch 2).Preferably, the distances between adjacent blade electrodes at the edge of the electrode assembly are greater than in the center thereof. With the edge of the electrode arrangement, those regions are meant which, viewed in a transport direction of the web material, lie at the front or rear end of the electrode arrangement (cf claim 2).
Als geeignete Abstände zwischen den benachbarten Messerelektroden haben sich am Rand der Elektrodenanordnung Abstände zwischen 8 und 12 mm, im Zentrum der Elektrodenanordnung zwischen 2 und 6 mm erwiesen (Anspruch 3).Distances between 8 and 12 mm, at the center of the electrode arrangement between 2 and 6 mm, have proven to be suitable spacings between the adjacent measuring electrodes at the edge of the electrode arrangement (claim 3).
Eine weitere Verbesserung des Entladungsbildes der Elektrodenanordnung bzw. der mit dieser zu erzielenden Plasmabehandlungs- bzw. Plasmabeschichtungsergebnisse ließ sich erzielen, wenn die freistehenden Kanten der Messerelektroden entsprechend der in Anspruch 4 genannten vorteilhaften Weiterbildung mit im Querschnitt im wesentlichen kreis- bzw. teilkreisförmigen Entladungsleisten versehen waren. Diese Ausbildung der Entladungsleisten bei Messerelektroden, so hat sich herausgestellt, ergibt nicht nur bei der erfindungsgemäß mit Messerelektroden mit divergierenden Abständen versehenen Elektrodenanordnung, sondern auch bei solchen Elektrodenanordnungen mit Messerelektroden in äquidistanter Anordnung ein verbessertes Ergebnis. Die Ausbildung der Entladungskanten stellt insoweit und für sich genommen eine eigenständige Erfindung dar. Dabei müssen die Krümmungsradien der Entladungskanten nicht durchgehend gleich sein, sondern können im Gegenteil mit Vorteil innerhalb der Elektrodenanordnung differieren (vgl. Anspruch 5). So werden starke Gleitentladungen am Rand und somit am vorderen bzw. hinteren Ende der Elektrodenanordnung 1 minimiert.A further improvement of the discharge pattern of the electrode assembly or the plasma treatment or plasma coating results to be achieved with this could be achieved if the freestanding edges of the blade electrodes were provided in accordance with the advantageous development mentioned in claim 4 with substantially circular or part-circular discharge strips in cross-section , This training of the discharge strips at Messerelektroden, so has been found, not only results in the inventively provided with knife electrodes with diverging intervals electrode assembly, but also in such electrode assemblies with knife electrodes in equidistant arrangement an improved result. The formation of the discharge edges in this respect and taken by itself is an independent invention. The radii of curvature of the discharge edges need not be the same throughout, but on the contrary can advantageously differ within the electrode arrangement (see claim 5). Thus, strong sliding discharges are minimized at the edge and thus at the front or rear end of the
Um einen gleich bleibenden Abstand zwischen den Entladungskanten der Messerelektroden und der Oberfläche der Plasma zu behandelnden bzw. Plasma zu beschichtenden Materialbahn beizubehalten, sind die Messerelektroden vorzugsweise entsprechend den Vorgaben des Anspruchs 6 angeordnet.In order to maintain a constant distance between the discharge edges of the blade electrodes and the surface of the plasma to be treated or plasma-coated material web, the blade electrodes are preferably arranged according to the specifications of
Gegenstand der Erfindung ist schließlich noch eine Vorrichtung zur kontinuierlichen Plasmabehandlung oder Plasmabeschichtung von Bahnmaterial mit den Merkmalen des Anspruches 7. Hier ist wesentlich, dass die Vorrichtung eine wie oben beschriebene Elektrodenanordnung enthält.Finally, the subject of the invention is a device for the continuous plasma treatment or plasma coating of web material with the features of claim 7. It is essential here that the device contains an electrode arrangement as described above.
Weitere Vorteile und Merkmale der Erfindung ergeben sich aus der nachfolgenden Beschreibung eines Ausführungsbeispiels anhand der beigefügten Figuren. Dabei zeigen:
- Fig. 1
- eine schematische Ansicht einer erfindungsgemäßen Elektrodenanordnung der kontinuierlichen Plasmabehandlung bzw. -beschichtung von Bahnmaterial; und
- Fig. 2
- eine vergrößerte Darstellung der erfindungsgemäßen Elektrodenanordnung.
- Fig. 1
- a schematic view of an electrode assembly according to the invention of the continuous plasma treatment or coating of sheet material; and
- Fig. 2
- an enlarged view of the electrode assembly according to the invention.
In
In
Der Durchmesser der Entladungsleiste 5 muss in der Elektrodenanordnung nicht gleich sein, wodurch starke Gleitentladungen am Rand und somit am vorderen bzw. hinteren Ende der Elektrodenanordnung 1 minimiert werden.The diameter of the
Die einzelnen, benachbarten Messerelektroden 3 sind mit variablen Abständen zueinander angeordnet, wobei die Abstände zwischen benachbarten Messerelektroden 3 an den äußeren Rändern der Elektrodenanordnung 1 größer sind als die Abstände benachbarter Messerelektroden 3 im Zentrum der Anordnung 1.The individual,
In diesem Beispiel sind insgesamt fünf verschiedene Abstände vorgesehen und in der Figur mit den Ziffern a bis e bezeichnet, wobei die Abstände von a bis e jeweils kleiner werden. In einem Ausführungsbeispiel können die Abstände a bis e z.B. wie folgt gebildet sein:
- a = 10 mm
- b = 9 mm
- c = 8 mm
- d = 7 mm
- e = 6 mm
- a = 10 mm
- b = 9 mm
- c = 8 mm
- d = 7 mm
- e = 6 mm
Der erfindungsgemäße Aufbau der Elektrodenanordnung 1 mit sich im wesentlichen parallel zueinander erstreckenden, in Transportrichtung des zu behandelnden bzw. zu beschichtenden Bahnmaterials hintereinander angeordneten Messerelektroden 3 in unterschiedlichem Abstand schafft eine verbesserte Homogenität und Qualität der mit dieser durchgeführten Plasmabehandlung bzw. Plasmabeschichtung des unter dieser Elektrodenanordnung 1 auf der als Gegenelektrode ausgebildeten Transportwalze hindurch geführten Bahnmaterials. Dies konnte experimentell bestätigt werden. Auch die Ausbildung der Entladungsleisten 5 mit der Kreis- bzw. Teilkreisform im Querschnitt ergab eine gegenüber bekannter Entladungskantenformen verbesserte Qualität der Plasmabeschichtung bzw. -behandlung.The inventive structure of the
Die in dem Ausführungsbeispiel gezeigte Form der Elektrodenanordnung 1 und die dort angegebenen Abstände a bis e sind nicht beschränkend, es können stattdessen diverse unterschiedliche Formen und Abstandsverteilungen eingehalten werden. Die erfindungswesentlichen Merkmale sind in den Ansprüchen wiedergegeben, welche den Umfang der Erfindung bzw. des Schutzes definieren sollen.The shape of the
- 11
- Elektrodenanordnungelectrode assembly
- 22
- Elektrodenhalterelectrode holder
- 33
- Messerelektrodediameter electrode
- 44
- Verdickungthickening
- 55
- Entladungsleistedischarge strip
- 66
- Klingeblade
- 1010
- Plasmabehandlungs- bzw. beschichtungsvorrichtungPlasma treatment or coating device
- 1111
- Isolatorinsulator
- 1212
- Behandlungsstrecketreatment section
- aa
- Abstanddistance
- bb
- Abstanddistance
- cc
- Abstanddistance
- dd
- Abstanddistance
- ee
- Abstanddistance
Claims (7)
- Electrode arrangement as a high voltage electrode for the continuous plasma treatment or plasma coating of sheet material with a plurality of mutually substantially parallel test electrodes (3) positioned transversely to a sheet material feed direction, characterized in that the spacings (a-e) between adjacent test electrodes (3) vary.
- Electrode arrangement according to claim 1, characterized in that the spacings (a) between adjacent test electrodes (3) at the edge of electrode arrangement (1) are greater than the spacings (e) of adjacent test electrodes (3) in the centre thereof.
- Electrode arrangement according to claim 2, characterized in that the maximum spacings (a) between adjacent test electrodes (3) at the edge of the electrode arrangement (1) are between 8 and 12 mm and the minimum spacings (e) between adjacent test electrodes (3) in the centre of the electrode arrangement (1) are between 2 and 6 mm.
- Electrode arrangement according to one of the preceding claims, characterized in that the free standing edges of the test electrodes (3) have a cross-sectionally substantially circular or pitch circular discharge strip (5), which is preferably thickened compared with the blade (6) connected thereto.
- Electrode arrangement according to claim 4, characterized in that the circular or pitch circular edges of the test electrodes have different radii of curvature within an electrode arrangement.
- Electrode arrangement according to one of the preceding claims, characterized in that a connecting line along the free standing edges of the test electrodes (3) is curved in the feed direction in accordance with the outer contour of a feed roller forming a counterelectrode and placed on electrode arrangement (1).
- Device for the continuous plasma treatment or plasma coating of sheet material with an electrode arrangement (1) according to one of the claims 1 to 6 and having a feed roller forming a counterelectrode facing the same.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE502006001508T DE502006001508D1 (en) | 2006-06-13 | 2006-06-13 | electrode assembly |
EP06012197A EP1868269B1 (en) | 2006-06-13 | 2006-06-13 | Electrode assembly |
DK06012197T DK1868269T3 (en) | 2006-06-13 | 2006-06-13 | Electrode arrangement |
AT06012197T ATE407468T1 (en) | 2006-06-13 | 2006-06-13 | ELECTRODE ARRANGEMENT |
US12/303,454 US7859180B2 (en) | 2006-06-13 | 2007-06-01 | Electrode arrangement |
PCT/EP2007/004851 WO2007144075A1 (en) | 2006-06-13 | 2007-06-01 | Electrode arrangement |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06012197A EP1868269B1 (en) | 2006-06-13 | 2006-06-13 | Electrode assembly |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1868269A1 EP1868269A1 (en) | 2007-12-19 |
EP1868269B1 true EP1868269B1 (en) | 2008-09-03 |
Family
ID=36930326
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06012197A Active EP1868269B1 (en) | 2006-06-13 | 2006-06-13 | Electrode assembly |
Country Status (6)
Country | Link |
---|---|
US (1) | US7859180B2 (en) |
EP (1) | EP1868269B1 (en) |
AT (1) | ATE407468T1 (en) |
DE (1) | DE502006001508D1 (en) |
DK (1) | DK1868269T3 (en) |
WO (1) | WO2007144075A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9831070B1 (en) | 2017-06-15 | 2017-11-28 | Enercon Industries Corporation | Surface treater with expansion electrode arrangement |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3133193A (en) * | 1962-01-22 | 1964-05-12 | Du Pont | Corona discharge apparatus for the surface treatment of plastic resins |
CA1042605A (en) | 1977-06-07 | 1978-11-21 | Evin Industries Ltd. | Outerwear |
DE3219538A1 (en) * | 1982-05-25 | 1983-12-01 | Softal Electronic GmbH, 2000 Hamburg | DEVICE FOR THE ELECTRICAL PRE-TREATMENT OF NON-CONDUCTIVE FILMS |
DE3622737C1 (en) * | 1986-07-05 | 1987-10-08 | Klaus Kalwar | Process for the corona treatment of web-like materials and device for carrying out the process |
DE9102438U1 (en) * | 1991-03-01 | 1992-06-25 | Röhm GmbH, 6100 Darmstadt | Low pressure plasma generator |
AU2001247685A1 (en) * | 2000-03-30 | 2001-10-15 | Tokyo Electron Limited | Method of and apparatus for tunable gas injection in a plasma processing system |
-
2006
- 2006-06-13 EP EP06012197A patent/EP1868269B1/en active Active
- 2006-06-13 AT AT06012197T patent/ATE407468T1/en not_active IP Right Cessation
- 2006-06-13 DK DK06012197T patent/DK1868269T3/en active
- 2006-06-13 DE DE502006001508T patent/DE502006001508D1/en active Active
-
2007
- 2007-06-01 US US12/303,454 patent/US7859180B2/en active Active
- 2007-06-01 WO PCT/EP2007/004851 patent/WO2007144075A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
US7859180B2 (en) | 2010-12-28 |
US20090200911A1 (en) | 2009-08-13 |
EP1868269A1 (en) | 2007-12-19 |
ATE407468T1 (en) | 2008-09-15 |
WO2007144075A1 (en) | 2007-12-21 |
DE502006001508D1 (en) | 2008-10-16 |
DK1868269T3 (en) | 2009-01-12 |
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