Classifications

• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
  • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
  • C09K5/16—Materials undergoing chemical reactions when used
  • C09K5/18—Non-reversible chemical reactions
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
  • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
  • B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
  • B65D81/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within the package
  • B65D81/3484—Packages having self-contained heating means, e.g. heating generated by the reaction of two chemicals
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F24—HEATING; RANGES; VENTILATING
  • F24V—COLLECTION, PRODUCTION OR USE OF HEAT NOT OTHERWISE PROVIDED FOR
  • F24V30/00—Apparatus or devices using heat produced by exothermal chemical reactions other than combustion
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
  • F25D2331/00—Details or arrangements of other cooling or freezing apparatus not provided for in other groups of this subclass
  • F25D2331/80—Type of cooled receptacles
  • F25D2331/805—Cans
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
  • F25D5/00—Devices using endothermic chemical reactions, e.g. using frigorific mixtures
  • F25D5/02—Devices using endothermic chemical reactions, e.g. using frigorific mixtures portable, i.e. adapted to be carried personally

Definitions

• the present invention relates generally to containers that include an internal module that adds heat to or removes heat from a material, such as a food, beverage, medicine, or the like, in the surrounding container.
• Containers may have integral modules for warming materials in the container, such as sake, coffee, or soup. Examples of such self-heating containers are disclosed in U.S. Pat. Nos. 5,461,867; 5,626,022; and 6,351,953 issued to Scudder et al. All patents, patent applications and other publications referenced in this application are hereby incorporated by reference herein in their entirety.
• Such containers typically include an outer can or body, in which the food or beverage is sealed, and an inner can or thermic module that contains two chemical reactants that are stable when separated from one another but, when they mix in response to actuation of the thermic module by a user, produce an exothermic reaction or, alternatively, an endothermic reaction and thereby heat or cool the contents of the container.
• the containers must go through a sterilization process called ''retort.”
• ''retort a sterilization process
• the retort process consists of subjecting the container and food contents to high temperatures and pressures.
• the container and contents are placed in a chamber for several minutes at 252 degrees Fahrenheit and two bars of pressure. Accordingly, the containers must be designed to withstand the retort process and still function properly.
• the heating or cooling module (thermic module) is typically attached at one end of the cylindrical container body, and the elongated cylindrical reaction chamber portion of the module extends into the container body. This elongated portion functions as both a chamber in which to contain the reaction and a heat-exchanger for transferring heat between it and the surrounding contents of the container body.
• the thermic module has two chambers, each of which contains one of the chemical reactants. separated by a breakable barrier such as metal foil or a thin plastic film. Typically, one of the reactants is a liquid, and the other is in a solid powdered or granular form. Calcium oxide (commonly known as limestone) and water are examples of two reactants known to produce an exothermic reaction to heat the contents in such containers.
• a cap containing the liquid reactant is disposed in the end of the thermic module attached to the container body.
• At one end of the cap is an actuator button that a user may press to initiate the heating or cooling.
• the barrier seals the other end of the cap.
• the cap has a pushrod or similar prong-like member that extends from the actuator button nearly to the barrier. Depressing the actuator button forces the prong into the barrier, puncturing it and thereby allowing the liquid reactant to flow into the solid reactant in the reaction chamber.
• the heat produced by the resulting exothermic reaction or absorbed by the resulting endothermic reaction is transferred between the reaction chamber of the thermic module and the contents of the container body by conduction.
• Exothermic reactions also typically generate a gas and/or steam, which is allowed to escape through vents in the end of the container.
• the user inverts the container and, when the contents have reached the desired temperature, consumes the contents.
• the second end of the container body has a seal or closure, such as a conventional beverage can pull-tab, that may be opened and through which the user may consume the heated or cooled contents.
• a portion of the thermic module such as the elongated cylindrical reaction chamber, may be unitarily formed with the outer can, as illustrated, for example, in U.S. Pat. No. 3,970,068, issued to Sato, and U.S. Pat. No. 5,088,870, issued to Fukuhara et al.
• the unitary container body is formed by providing a metal cylinder that is open at one end and closed at the other, and punching or deep-drawing a cavity in the closed end.
• a cap containing the liquid reactant is attached to the open end of the cavity.
• the elongated cylindrical reaction chamber may be separately formed and then attached to the container body by another manufacturing step. It would be desirable to provide an economical and reliable method for manufacturing this latter type of container.
• the wall of the elongated reaction chamber separates the reaction chamber from the material contained in the container which is heated or cooled. This wall acts as an insulator which can slow the heating or cooling of the material by the thermic module.
• the chambers in response to the retort process, have suffered excessive deformation and cracking and have shown an inability to return to their expanded shape after being compressed during retort.
• the retort process also has the potential to cause weakening or failure of the bond holding the breakable barrier separating the two chambers of the thermic module.
• the breakable barrier is typically heat sealed to a circular top edge of one chamber of the thermic module. During retort, the pressure of air expanding under the barrier tends to push the barrier upward into a dome shape which can cause the bond to weaken or detach.
• Another problem associated with self-heating and self-cooling containers is that a person may attempt to consume the contents before the contents have been fully heated or cooled. That the person may be displeased by the resulting temperature of the beverage or other contents is not the only effect. A perhaps more serious effect is that a self-heating container may overheat and present a burn hazard if, after the user empties it of its contents, it continues to generate heat, because the contents act as a heat sink. It would be desirable to provide a self-heating container that prevents or inhibits a user from consuming the contents before the heating reaction has completed.
• the actuator button may be protected by a foil safety seal.
• An unbroken seal assures a person that the container has not been actuated and is thus ready for use.
• the reactivity of typical chemicals such as calcium oxide may decrease if they absorb atmospheric moisture, such as could occur if the container were in storage or in transit for prolonged periods in a moist environment prior to use, and the seal inhibits exposure of the reactants to atmospheric moisture.
• the user peels the foil seal off the container and discards it. The removal of the foil seal presents a disposal problem because the user may not be within a convenient distance of a trash receptacle. It would further be desirable to minimize disposal problems associated with self-heating and self-cooling containers.
• the present invention is directed to improvements in self-heating containers which overcome these problems and deficiencies.
• the present invention relates to a container having a container body, a thermic module at one end of the body, and a closure at the other end of the body.
• the body may have any suitable generally tubular shape, such as cylindrical or can-shaped or . bottle-shaped.
• the food, beverage, medicine or other material to be heated or cooled is contained in a material cavity in the container body.
• the thermic module contains a chemical reactant that is segregated from another reactant in the container.
• the reactants mix and produce a reaction that, depending upon the reactants, either produces heat, i.e., an exothermic reaction, and thereby heats the container contents, or absorbs heat, i.e., an endothermic reaction, and thereby cools the container contents.
• a plastic thermic module body is spin-welded to a plastic container body by rotating one relative to and in contact with the other.
• the frictionally generated heat fuses or welds the contacting plastic surfaces together.
• the container body may have multiple layers, including an oxygen and flavor scalping barrier layer that inhibits oxidation and spoilage of the contents. Spin- welding the container body to the module body in this manner seals the portion of the inner layer that is exposed at the annular end of the container body between two plastic layers and thereby prevents air or moisture from seeping past the outer plastic layer and into the inner layer.
• the thermic module body has a heat exchanger portion having a pleated wall.
• the pleated design is provided with relatively large radii at the peaks and valleys of the pleats.
• the heat exchanger portion also has a plurality of circumferential grooves which longitudinally separate the pleated portions. The large radii and grooves help prevent the thermic module from failing under the pressure and temperature of the retort process.
• the container includes a movable cover mounted over the closure.
• a suitable heat-sensitive adhesive between the cover and the container inhibits movement of the cover until the temperature has reached a certain threshold.
• the adhesive bond softens when the adhesive reaches approximately that temperature.
• the cover is rotatable.
• the cover has an opening, and when the threshold temperature is reached, the user can rotate the cover until the opening is aligned with the closure. The user may then open the closure and consume the contents of the container.
• thermic module includes a seal, such as a foil disc, between an inner actuator button and an outer actuator button.
• the inner actuator button may be included in a module cap that holds the solid reactant.
• the outer actuator button has one or more apertures and also has one or more prongs directed toward the seal.
• the prong punctures the seal.
• This actuator structure eliminates the disposal problem associated with a removable foil seal.
• the pressure would force the inner actuator button against the seal.
• the seal presses against the prong and punctures it, thereby relieving the pressure through the apertures in the outer actuator button.
• the container comprises a full panel pull- off attached to the bottom of the container.
• a full panel pull-off is a removable cover like those used on canned foods and is like a typical pop-tab closure (e.g. the closure on a soft-drink or soup metal can) except that the lid part that is removable covers substantially the entire opening of the container rather than just a small opening.
• the full panel pull-off completely covers the inner actuator button and may be made of aluminum such that the actuator button cannot be pushed until the full panel pull-off is removed.
• the full-panel pull-off provides a tamper-evident seal and also protects the actuator button from being inadvertently pushed.
• the full panel pull-off may also provide a pressure safety release valve. In the event that the breakable barrier is pushed without removing the full panel pull -off, pressure will build up inside the container because the vent holes in the thermic module vent only to the interior of the full panel pull-off. If the pressure reaches a certain level, the full panel pull-off will partially open thereby relieving the pressure.
• a vent hole is provided in the sidewall at the bottom of the container.
• the vent hole is a safety feature which releases pressure from the inside of the thermic module in the event that the reaction is actuated without removing the full panel pull-off.
• the outside wall of the container body may be provided with a swirl or helical shaped groove which runs from the vent hole. Attaching the label on the surface of the container over the groove creates a conduit leading from the vent hole. In this way, steam that exits the container through the vent hole will travel in this conduit along the cooler outer surface of the container such that the steam will cool and condense.
• the thermic module may also include a filter disposed in interfering relation with the vents between the inner and outer actuator buttons to block egress of any particles of the solid reactant or the reaction product, and also absorb water (gaseous and liquid) during the reaction.
• the filter may include a disc-shaped portion between the inner and outer actuator buttons and an annular portion between flanges coupled to the actuator buttons. The disc-shaped portion may be integrally formed with the annular portion prior to assembly of the container and separated from one another along an annular perforation line during a manufacturing step in which the filter portions are inserted into the thermic module.
• the two reactants producing the thermal reaction are specially designed calcium oxide particles and water.
• the calcium oxide particles are sized and shaped to optimize the heating profile of the container.
• the particles also comprise additives to affect the reaction.
• the water is purified and selected additives are included in the water to modify the reaction with the calcium oxide particles to optimize the heating profile of the container. The ration of water to calcium oxide is also pre-determined to produce the desired heating profile.
• FIG. 1 is a side view of a container of the present invention
• FIG. 2 is a bottom view of the container
• FIG. 3 is a top view of the container with the cap in the closed position
• FIG. 4 is a view similar to FIG. 3, with the cap rotated to the opened position; .
• FIG. 5 is an exploded perspective view of the elements of the container;
• FIG. 6 is a sectional view taken on line 6—6 of FIG. 1 ;
• FIG. 7 is a similar sectional view showing the container after actuation
• FIG. 8 is a sectional view taken on line 8-18 of FIG. 1;
• FIG. 9 illustrates the manufacturing step of blow-molding the plastic body elements of the container;
• FIG. 10 illustrates the manufacturing step of separating the elements from one another following blow-molding
• FIGS. 1 IA-C respectively illustrate the sequence of manufacturing steps that comprise spin-welding the container body to the module body.
• FIG. 12 is an exploded perspective view of the elements of another container in accordance with the present invention.
• FIG. 13 is a sectional view of the container of FIG. 12.
• FIG. 14 is a perspective view of the reactant barrier attached to the module cap of the container of FIG 12.
• FIG. 15 is a graph of transient temperature curves for calcium oxide particles of various sieve sizes.
• FIG. 16 is a graph of transient temperature curves for calcium oxide particles of various sieve sizes.
• FIG. 17 is a graph of transient temperature curves for calcium oxide particles of various sieve sizes.
• FIG. 18 is a graph of transient temperature curves for calcium oxide particles of various sieve sizes.
• FIG. 19 is a graph of reaction / temperature curves for various ratios of water to calcium oxide.
• FIG. 20 is a graph of reaction / temperature curves for various ratios of water to calcium oxide.
• FIG. 21 is a table of mineral components in water that should not be exceeded.
• FIG.22 is a table of additives which may be added to the calcium oxide
• a container 10 includes a container body 12, a thermic module body 14, and a thermic module cap 16.
• module body 14 has an elongated heat-exchanger portion that extends into container body 16. The interior of this portion defines a reaction chamber in which the reaction occurs that heats (or, in alternative embodiments of the invention, cools) the beverage or other contents 18.
• the heat-exchanger portion has a corrugated or pleated wall to increase surface area and, as a result, heat transfer. Although in the illustrated embodiment the wall is corrugated or pleated, in other embodiments the wall may have other suitable geometries.
• Module cap 16 is press-fit in the open end of module body 14.
• An endcap 20 with a pop-tab closure 22 of the type commonly used in beverage cans is crimped over the other end of container body 12 in the manner of a conventional beverage can.
• Module cap 16 is of unitary construction and is made of a semi-rigid plastic, such as high density polyethylene. Module cap 16 has a disc-shaped or dome-shaped inner actuator button 24 and a cylindrical prong 26 with an elongated notch 28. A breakable reactant barrier 30 made of metal foil is adhesively attached to the open end of module cap 16 to seal the water or other liquid reactant 32 inside.
• Module cap 16 has multiple vent channels 34 distributed around its outside surface. When module cap 16 is fit in the open end of module body 14, each of vent channels 34 provides a channel through which gas can escape during the reaction. Vent channels 34 extend longitudinally along the outside surface of the body portion of module cap 16, change direction to extend radially along the lower surface of the flange portion 36 of module cap 16, change direction again to extend longitudinally along the outside cylindrical surface of flange portion 36, and change direction again to extend radially along the upper surface of flange portion 36. This long, narrow, zig-zag path of channels 34 inhibits escape of particles of the calcium oxide or other solid reactant 38 while allowing gas to vent.
• a filter ring 40 is sandwiched between flange portion 36 and thermic module body 14. Filter ring 40 further prevents solid particles from escaping through vent channels 34 while allowing gases to vent unimpeded.
• Filter ring 40 may be made of any suitable filter material such as synthetic sponge, open-cell foamed rubber, or any woven or fibrous materials such as paper and cloth. A suitable material is commercially available from Filter Material Corporation of Wisconsin under the product number AC20.
• An outer actuator assembly 40 is attached to the end of container body 12 and, as best illustrated in FIG. 2, includes a ring portion 44 and an outer actuator button 46.
• the ring of squares shown around the outer periphery of ring portion 44 in FIG. 2 are
• Outer actuator button 46 is supported on at least three but preferably four spline-shaped fingers 48, suspending it in a resiliently deflectable manner within the interior of ring portion 44.
• Outer actuator button 46, fingers 48 and ring portion 44 are preferably unitarily formed as a molded plastic part.
• the concentric rings shown within outer actuator button 46 in FIG. 2 are surface features that provide a factional grip for user's finger when actuating the container as described below.
• a filter disc 50 preferably made of the same material as filter ring 40, is sandwiched between outer actuator assembly 42 and inner actuator button 24.
• filter ring 40 provides an adequate filter by itself
• filter disc 50 may be included in certain embodiments of the invention to further enhance filtering.
• An advantage in manufacturing economy may be achieved in such embodiments by forming filter ring 40 and filter disc 50 as a unitary part with perforations between them, and handling them as a unitary part until they are separated during the manufacturing step in which they are assembled into container 10.
• outer actuator assembly 42 further includes an breakable actuator barrier 52.
• Breakable actuator barrier 52 is preferably made of metal foil that is adhesively attached to the end of an annular cuff portion 54 projecting from the interior periphery of ring portion 44.
• Three pointed projections 56 extend from the underside of outer actuator button 46 toward actuator barrier 52.
• the star-shaped or x-shaped surface feature centered at the middle one of projections 56 reinforces outer actuator button 46 but is not otherwise significant to the invention.
• lid 58 is mounted over endcap 20 and the end of container body 12.
• Lid 58 has two apertures 60 and 62.
• lid 58 is mounted to the end of container body 12 with patches or spots of heat-sensitive adhesive (labeled "A") having an adhesion strength that, generally speaking, decreases with an increase in temperature.
• a range of such heat-sensitive adhesives are commercially available with various specifications.
• One parameter that can typically be specified is the threshold temperature at which the adhesive loses (or, conversely, achieves) substantial adhesion strength. Suitable adhesives are manufactured by National Starch and Chemical of Illinois under the product numbers 34-2780 and 70-4467.
• cap 58 Before a user actuates container 10, cap 58 is in the position shown in FIG. 3. In this position aperture 60 is not aligned with pop-tab closure 22 and thus prevents a user from opening closure 22. Also, in this position aperture 62 is not aligned with the sealed opening 64 through which beverage 18 can be consumed. When container 10 heats and the adhesive reaches the threshold temperature, it loses sufficient adhesion strength that a user can move cap 58. The user rotates cap 58 until it is in the position shown in FIG. 4, as indicated by the arrow. In this position aperture 60 is aligned with pop-tab closure 22, thereby allowing the user to open it.
• aperture 62 is aligned with the sealed opening through which the user can consume the beverage.
• opening pop-tab closure 22 breaks the seal and allows a user to drink beverage 18 through the resulting opening.
• the user's lips contact the relatively cool plastic of cap 58 rather than the potentially very hot metal of endcap 20.
• the adhesive maintains substantial adhesion when its temperature is below about 100 degrees Fahrenheit (38 Celsius) and loses substantial adhesion when its temperature exceeds said this threshold.
• the preferred adhesive noted above that is manufactured by National Starch and Chemical has this property.
• substantially adhesion refers to the inability of a user to rotate lid 58 by exerting no more than the normal amount of torque that a person typically exerts when opening ajar or other screw-top food or beverage container without the assistance of tools.
• outer actuator button 46 To actuate container 10, the user depresses outer actuator button 46 by exerting a force upon it in the general direction of the longitudinal axis of container 10. As noted above, actuator button 46 is suspended by fingers 48, which resiliently deflect to allow button 46 to move in this axial direction. The force exerted upon outer actuator button 46 urges its projections 56 into actuator barrier 52, puncturing it. The force further urges outer actuator button 46 toward inner actuator button 24, which in turn is urged in the same axial direction. Inner actuator button 24 is flexible and responds to the force by popping or snapping inwardly toward reactant barrier 30.
• prong 26 punctures reactant barrier 30.
• Water 32 flows through punctured reactant barrier 30 and mixes with solid reactant 38 in the reaction chamber, i.e., the interior of the elongated portion of thermic module body 14.
• Notch 28 in prong 26 facilitates the flow of water 18 into the reaction chamber.
• the resulting exothermic reaction produces heat, which is transferred to beverage 18 by conduction through the pleated wall of the heat-exchanger portion of thermic module body 14.
• other reactants may be selected that give rise to an endothermic reaction when mixed.
• Gas or steam produced in the reaction escapes the reaction chamber through vent channels 34, but any solid particles are filtered out by filter ring 40 or filter disc 50. Note that the inherent saturation of filter ring 40 and filter disc 50 by the escaping steam may enhance this filtration.
• the gas or steam that passes through filter ring 40 or filter disc 50 passes through the punctured actuator barrier 52 and exits container 10 through the spaces between fingers 48.
• the user can then invert container 10 and wait until the reaction heats beverage 18, which typically occurs within about five minutes in a container 10 having a capacity of 10 fluid ounces (296 ml) of water or comparable beverage such as coffee or tea.
• beverage 18 is heated to the temperature at which it is to be consumed, the adhesive has loosened sufficiently to allow the user to rotate cap 58.
• Patches or spots of a suitable lubricant (labeled "L" in FIG. 8) are interspersed with the adhesive patches so that when cap 58 is rotated the lubricant smears and prevents the adhesive from re-adhering cap 58 as it begins to cool and also allows the user to more easily rotate cap 58.
• the lubricant is preferably food-grade or approved for incidental food contact by the appropriate governmental authority, such as the Food and Drug Administration in the United States.
• the user then opens pop- tab closure 22 as described above and consumes beverage 18.
• the method of manufacturing container 10 may include the steps illustrated in FIGS. 9, 10 and 1 IA-C.
• the manufacturing method is an important aspect of the invention because it addresses several problems.
• Container body 12 and thermic module body 14 are preferably made of multiple layers, including an oxygen-barrier layer, to maintain the freshness and stability of beverage 18 or other contents.
• Such multiple-layer plastic container technology is familiar to persons of skill in the art to which the invention relates and is described in, for example, Blow Molding Handbook, edited by Donald Rosato and Dominick Rosato, Hanser Publishers.
• a multiple-head blow-molding machine such as that illustrated in FIG. 9 can be used to produce multiple-layer plastic containers.
• the machine positions a suitable mold 66 beneath the blow-molding head (known as a W. Mueller head), extrudes the plastic resin layers simultaneously, and then injects air to conform the plastic to the contours of the mold cavity. The machine then cools the mold, opens it, removes the molded part, and repeats the process.
• a suitable blow-molding machine is commercially available from B&W of Berlin, Germany under the name/Model No. DE3000. Although this machine can work with two or more molds simultaneously, this aspect is not particularly relevant to the manufacturing method of the present invention.
• mold 66 is configured to produce one container body 12 and one thermic module body 14 as a single unitarily molded part. As illustrated in FIG. 10, a static trimming machine cuts this part at three places to separate it into container body 12, thermic module body 14, and two moyles 16 and 18. As known in the art, a moyle is excess or scrap material that may be included in a molded part to facilitate molding and handling.
• the static trimming machine includes rollers (not shown) that bear against moyle 16 and rotate the part, as indicated by the arrow. The machine rotates the part against a hot knife blade 68 that can be extended for cutting and then retracted. Knife blade 68 separates or cuts moyle 16 from the remainder of the part.
• the same or a similar machine performs a similar cutting operation that separates moyle 18.
• the use of a static trimming machine is important to the manufacturing process because it leaves a smooth surface at the flange-like end of thermic module portion 14 to facilitate the welding step described below. While the blow-molding and cutting steps are believed to be important steps of the overall manufacturing process described herein, attention should be focused upon the step in which thermic module body 14 is attached to container body 12 by spin-welding, as illustrated in FIGS. 1 IA-C.
• Spin-welding is a method familiar to persons of skill in the art, by which the plastic of two parts fuses as a result of friction induced by spinning or rotating one part relative to the other.
• a suitable spin- welding machine is commercially available from TA Systems of Michigan.
• thermic module body 14 is inserted into the end of container body 12, and the resulting assembly is placed over a cylindrical tubular support (not shown) of the machine.
• the machine has a rotary head that lowers into contact with the flang-like surface of module body 14.
• the machine applies pressure that maintains module body 14 firmly in contact with container body 12.
• the head then begins rotating or spinning while maintaining that pressure.
• the rotating head spins module body 14 with respect to container body 12, which is kept stationary by the support on which it is mounted, as a result of the frictional engagement between the rotating head and the flange-like portion of module body 14.
• module body 14 and container body 12 fuses or welds them together. It is significant that pressure is applied before rotation begins and is maintained until the parts have fused because this sequence results in a more precise weld.
• the cutting step of the process exposes the cross-section of layers, such as the oxygen and flavor scalping barrier layer, in container body 12 and module body 14. While the layers are very thin and difficult to see with the unaided eye, they are sufficiently exposed that they are susceptible to degradation by atmospheric moisture and oxygen.
• Spin-welding is highly advantageous because, unlike other potential methods for attaching these parts to one another, spin- welding in the manner described above seals the exposed ends of container body 12 and module body 14, thereby inhibiting atmospheric moisture, oxygen or other contaminants from contacting and consequently degrading the oxygen barrier or other sensitive layers of container body 12. Also, the smooth and square surface left by the rotary cutter is more readily sealed by the spin- welding; spin- welding a jagged or uneven edge may not completely seal the sensitive interior layers.
• Outer actuator assembly 42 may be spin- welded to the end of container body 12 as well.
• the ring of square recesses on its surface facilitates engagement by a spin- welding head having a corresponding ring of square protuberances (not shown).
• FIG. 12 illustrates another container 100 in accordance with the present invention.
• Many of the features and elements of the container 100 are the same or substantially similar to the features and elements of the container 10 described above.
• the present invention contemplates that many of the features of the container 100 can be substituted for the features in the container 10, and vice versa. Accordingly, it should be understood that any one or more features of container 100 and container 10 can be substituted for analogous features in the other container within the scope of the present invention without describing in detail each and every combination herein.
• the container 100 includes a container body 112, a thermic module body 114, and a thermic module cap 116.
• the module body 114 has an elongated heat-exchanger portion 115 that extends into container body 112. The interior of this portion defines a reaction chamber in which the reaction occurs that heats (or, in alternative embodiments of the invention, cools) the beverage or other contents 1 18.
• a first reactant 132 is contained in the thermic module cap 116.
• a second reactant 138 is contained the thermic module body 114.
• the two reactants are separated by a breakable reactant barrier 130.
• one of the reactants is a liquid, such as water, and the other reactant is in a solid powdered or granular form, such as calcium oxide.
• the heat-exchanger portion 115 of the module body 114 has a corrugated or pleated wall to increase surface area and, as a result, heat transfer.
• the wall is corrugated or pleated, in other embodiments the wall may have other suitable geometries.
• the thinner the wall of the heat exchanger portion 115 the faster the heat transfer between the reactants 132 and 138 and the beverage 118.
• the wall is made very thin, preferably having a thickness between 0.004 inches and 0.012 inches.
• the peaks 117 and valleys 119 of the pleats have generous radii, preferably greater than 0.05 inches, more preferably greater than 0.06 inches.
• the large radii of the peaks 117 and valleys 119 prevents the thin walls from failing during the retort process.
• two circular grooves 121 and 123 are provided.
• the grooves 121 and 123 facilitate folding at the grooves when the heat exchanger portion 1 15 is subjected to pressure as during the retort process. The folding helps prevent the thin walls of the heat exchanger portion 115 from creasing and cracking.
• the pointed end of the conical end of the heat exchanger portion has a thickened rib 125 extending therefrom. The rib 125 helps reduce deformation of the cone during the retort process.
• the module cap 1 16 is press-fit in the open end of module body 114.
• Module cap 1 16 is of unitary construction and is made of a semi-rigid plastic, such as high density polyethylene.
• the breakable reactant barrier 130 preferably made of metal foil, is attached to the open end of module cap 116 to seal the water or other liquid reactant 132 inside.
• the reactant barrier 130 may be attached to the open end of module cap 1 16 by thermal bonding, ultrasonic bonding, use of an adhesive or any other suitable method.
• Module cap 116 has a disc-shaped or dome-shaped actuator button 124 and a cylindrical prong 126 with an elongated notch 128.
• An adapter puck 127 may also be provided to prevent the granular reactant 138 from falling into the bottom of module cap 116. Some reactants 138 may burn a hole through the bottom of the module cap 116.
• the adapter puck 127 includes an annular disc portion which fits inside the module cap 116 and a plurality of prongs 129 extending perpendicularly from both sides of the disc portion. The prongs 129 extending toward the barrier 130 improve the breakage of the barrier 130 when the thermic module is actuated to puncture the breakable reactant barrier 130.
• the reactant barrier 130 may be attached to just the top annular surface of the open end of module cap 1 16, it is preferable that the reactant barrier 130 extend over the open end and down the side of the outer wall of the module cap 116 as shown in FIG. 14. Where the reactant barrier 130 is attached to the module cap 116 by thermal bonding, the thermal bonding process forms a radius on the outer edge of the top annular surface. The radiused edge further improves the bonding of the reactant barrier 130 to the module cap 1 16. When the container 100 is subjected to the retort process, pressure tends to push the barrier 130 upwards away from the top of the module cap 116. By sealing the barrier 130 to the side of the outer wall of the module cap 116 creates a much stronger adhesive seal by increasing the shear strength of the bond.
• Module cap 116 has a plurality of ribs 134 protruding from the upper and lower surfaces of the flange portion 136 of module cap 1 16.
• the ribs 134 create channels between the flange portion 136 and the surrounding structure for venting pressure.
• the outer wall of the module cap is also provided with ribs 135 to create a vent channel between the outer surface of the module cap 116 and inner surface of the module body 14.
• vent spaces extend longitudinally along the outside surface of the body portion of module cap 116, change direction to extend radially along the lower surface of the flange portion 136 of module cap 1 16, change direction again to extend longitudinally along the outside cylindrical surface of flange portion 136, and change direction again to extend radially along the upper surface of flange portion 136.
• This long, narrow, zigzag path of channels inhibits escape of particles of the calcium oxide or other solid reactant 138 while allowing gas to vent.
• a filter ring 140 is sandwiched between flange portion 136 and thermic module body 114. Filter ring 140 further prevents solid particles from escaping through the vent channels while allowing gases to vent.
• Filter ring 140 may be made of any suitable filter material such as synthetic sponge, open-cell foamed rubber, or any woven or fibrous materials such as paper and cloth. A suitable material is commercially available from Filter Material Corporation of Wisconsin under the product number AC20.
• the container 100 has a full panel pull-off 146 attached to the bottom end of the container body 112.
• the full panel pull-off 146 may be attached to the container body 112 by crimping, or any other suitable method.
• the full panel pull-off 146 may be attached to the bottom of the module cap 116.
• the full panel pull-off 146 is a removable lid of the type commonly used on canned foods and is like a typical pop-tab closure (e.g. the closure on a soft-drink aluminum can) except that the removable lid part covers substantially the entire opening of the container rather than just a small opening.
• the full panel pull-off 146 completely covers the opening at the bottom end of the container body 112.
• the pull-off 146 also covers the actuator button 124.
• the pull-off 146 preferably comprises a closure with a weakened region in a circular-shape along which the pull-off lid 141 breaks away from the remainder of the pull-off structure.
• the pull-off 146 is made of a material having sufficient strength, rigidity and thickness such that the actuator button 124 cannot be pushed without removing the pull-off 146, except in the case of extreme misuse or mishandling.
• the pull-off may be made of aluminum or other material having similar strength and rigidity.
• the pull-off Hd 141 is connected to a pull-ring 144 which is lifted and then pulled away from the pull-off lid 141 to remove the pull-off lid 141.
• the pull-off lid 141 breaks away from the rest of the pull-off 146 along the weakened region, it cannot be replaced once it is removed.
• the full-panel pull- off 146 provides an excellent tamper-evident seal while also making the container 100 less susceptible to vandalism while on store shelves.
• the pull-off 146 also functions as a pressure safety release valve. In the event that the reactant barrier 130 is pushed without removing the pull-off 146, pressure will build up inside the container because the vent channels in the thermic module cap 116 vent only to the interior of the pull- off 146. If the pressure reaches a certain level, the weakened region of the pull-off 146 will partially rupture thereby relieving the pressure.
• a vent hole 131 may be provided in the sidewall of the bottom of the thermic module body 1 14.
• the vent hole 131 provides a vent path from the reaction chamber to the outside atmosphere. Similar to the safety pressure relief function of the pull-off 146 described above, the vent hole 131 releases pressure from the reaction chamber in the event that the thermic reaction is inadvertently actuated without removing the pull-off 146.
• a coiled groove 133 may be molded into the outside wall of the container 112.
• the groove 133 starts at the location of the vent hole 131 and extends in a coil shape around and up the outside wall of the container 112.
• a label (not shown) is adhesively mounted over the outside wall of the container, a conduit is formed by the label and the groove 133. Steam that exits the vent hole 131 will travel through the conduit formed by the groove 133 and the label along the cooler outer surface of the container 112 causing the steam to cool and
• the label (not shown) may be formed of a plasti-shield labeling material or other insulating material such as a thin sheet of styrofoam. This reduces the amount of heat that a person feels in their hands when they are consuming a hot food or beverage from the container 112.
• the label can be pre -printed prior to adhesive application to the outside wall of the container 112.
• An endcap 120 with a pop-tab closure 122 of the type commonly used in beverage cans is crimped over the other top of container body 112 in the manner of a conventional beverage can.
• a lid 158 is mounted over endcap 120 and the end of container body 112. Lid 158 has two apertures 160 and 162.
• the lid 158 is mounted to the end of container body 112 with patches or spots of heat-sensitive adhesive (labeled "A") as shown in FIG. 8 for container 10) having an adhesion strength that decreases when heated to a specific threshold release temperature.
• A heat- sensitive adhesive
• patches or spots of a suitable lubricant are interspersed with the adhesive patches so that when cap 158 is rotated the lubricant smears and prevents the adhesive from re-adhering cap 158 as it begins to cool and also allows the user to more easily rotate cap 158.
• cap 158 Before a user actuates container 100, cap 158 is in the same position shown in FIG. 3 for the container 10. In this position aperture 160 is not aligned with pop-tab closure 122 and thus prevents a user from opening closure 122. Also, in this position aperture 162 is not aligned with the sealed opening 164 through which beverage 118 can be
• an indicator may be provided on the surface container 100 which shows when the beverage 118 has reached the desired temperature.
• the indicator can be a label having a thermochromatic ink which changes color when it reaches a predetermined temperature.
• the ink can be the Kromathermic Type 44 red available from Kromacorp International which turns from pink to white when heated to a predetermined temperature.
• cap 158 When container 100 heats and the adhesive reaches the release temperature, it loses sufficient adhesion strength that a user can rotate cap 158. The user rotates cap 158 until it is in the same position shown in FIG. 4 for container 10, as indicated by the arrow. In this position aperture 160 is aligned with pop-tab closure 122, thereby allowing the user to open it. Also, in this position aperture 162 is aligned with the sealed opening through which the user can consume the beverage. As in a conventional soft drink can, opening pop-tab closure 122 breaks the seal and allows a user to drink beverage 118 through the resulting opening. The user's lips contact the relatively cool plastic of cap 158 rather than the potentially very hot metal of endcap
• One of the reactants 132 or 138 may comprise specially designed calcium oxide particles.
• the porosity of the calcium oxide particles can greatly effect how volatile a particle will react when water is added.
• the processing of calcium oxide involves cooking it at 1000 degrees Fahrenheit which drives off moisture and gases that are naturally found in the material. This release creates pores in the material.
• the cooking time can be increased to a point where the pores will start to close back up in a process call a hard burn. By subjecting the particles to a proper amount of hard burn, the volatility of the reaction with water can be reduced to a more desirable level.
• the size of the calcium oxide particles has an effect on how reactive that particle is.
• a group of small particles has more surface area that one large particle of equal weight. The greater the surface area, the faster and more thorough the particle will react when mixed with water.
• FIGS. 15-18 show transient temperature curves for particles of various sieve sizes ranging from a 1 A inch mesh (largest particle) through sieve #30 (smallest particle). In general, the curves show that smaller particles will heat up faster and also attain a higher maximum temperature. Accordingly, particles of various sizes may be chosen to produce the desired heating profile for the specific application for the container 100. For an application such as heating coffee or soup, a preferred distribution of particles sizes is:
• Additives can also be added to the calcium oxide to increase or decrease the reaction rate.
• the additives work by several different methods, including chemically, mechanically, or physically altering the interface of the calcium oxide with the water.
• reaction ratio i.e. the ration of the calcium oxide to water.
• the standard ratio is 4 parts calcium oxide to one part water, by mass.
• Different reaction / temperature curves can be obtained by varying the ratio of calcium oxide to water. For example, it is possible to maximize the peak energy produced by any one size of particle or porosity of a particle.
• the ratio can also be altered to slightly increase or decrease the overall rate of the reaction.
• the graphs of FIGS. 19-20 show the reaction / temperature curves for various ratios of water to calcium oxide. It can be seen that increasing the amount of water to 1.15 parts per 4 parts calcium oxide by mass (i.e. +15% H2O in FIG. 20), the fastest reaction is obtained and also the most energy of the ratios tested.
• the water comprising the other reactant 132 or 138 may also be modified to optimize its use in the present invention.
• the water quality is a critical component. Any chlorine in the water may cause the breakable barrier 130 to corrode and fail. Minute deviations in water quality can adversely affect the thermal reaction with the calcium oxide. Trace mineral components in the water should not exceed the concentrations shown on the table in FIG. 21. Additives may also be added to the water to modify the reaction and improve the compatibility of the water with the other materials of the container. A list of possible additives and their properties is included in the table of FIG. 22.
• the user To actuate container 100, the user first removes the full panel pull-off 146 by lifting the pull-ring 144 and removing the pull-off lid 141. The user then depresses the actuator button 124 by exerting a force upon it in the general direction of the longitudinal axis of container 100. The force exerted upon the actuator button 124 causes it to snap or pop inwardly toward the reactant barrier 130.
• the first reactant 132 generally a liquid reactant, flows through punctured reactant barrier 30 and mixes with the solid reactant 38 in the reaction chamber, i.e., the interior of the elongated portion of thermic module body 114.
• the notch 128 in prong 126 facilitates the flow of water 132 into the reaction chamber.
• the resulting exothermic reaction produces heat, which is transferred to beverage 118 by conduction through the pleated wall of the heat-exchanger portion of thermic module body 14.
• other reactants may be selected that give rise to an endothermic reaction when mixed.
• the user can then invert container 100 and wait until the reaction heats beverage 18, which typically occurs within about five minutes in a container 100 having a capacity of 10 fluid ounces (296 ml) of water or comparable beverage such as coffee or tea.
• the adhesive has loosened sufficiently to allow the user to rotate cap 158.
• Patches or spots of a suitable lubricant (labeled "L" in FIG. 8) are interspersed with the adhesive patches so that when cap 158 is rotated the lubricant smears and prevents the adhesive from re-adhering cap 158 as it begins to cool and also allows the user to more easily rotate cap 158.
• the lubricant is preferably food- grade or approved for incidental food contact by the appropriate governmental authority, such as the Food and Drug Administration in the United States.
• the user then opens pop-tab closure 122 as described above and consumes beverage 118.
• the method of manufacturing container 100 may include the same steps described above for container 10, except where the structure of the containers 100 and 10 differ.

Landscapes

• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Physics & Mathematics (AREA)
• Thermal Sciences (AREA)
• Combustion & Propulsion (AREA)
• Mechanical Engineering (AREA)
• General Chemical & Material Sciences (AREA)
• General Engineering & Computer Science (AREA)
• Materials Engineering (AREA)
• Organic Chemistry (AREA)
• Life Sciences & Earth Sciences (AREA)
• Food Science & Technology (AREA)
• Closures For Containers (AREA)
• Cookers (AREA)
• Packages (AREA)
• Package Specialized In Special Use (AREA)

Applications Claiming Priority (1)

Publications (1)

Family

ID=37024075

Family Applications (1)

Country Status (10)

Cited By (1)

Families Citing this family (6)

Family Cites Families (13)

• 2005
  • 2005-03-17 AU AU2005329458A patent/AU2005329458A1/en not_active Abandoned
  • 2005-03-17 BR BRPI0520015-6A patent/BRPI0520015A2/pt not_active IP Right Cessation
  • 2005-03-17 EP EP05729743A patent/EP1866581A1/en not_active Withdrawn
  • 2005-03-17 EA EA200702005A patent/EA200702005A1/ru unknown
  • 2005-03-17 WO PCT/US2005/008840 patent/WO2006101482A1/en active Application Filing
  • 2005-03-17 CN CNA2005800491341A patent/CN101142456A/zh active Pending
  • 2005-03-17 MX MX2007011330A patent/MX2007011330A/es not_active Application Discontinuation
  • 2005-03-17 CA CA002605359A patent/CA2605359A1/en not_active Abandoned
  • 2005-03-17 JP JP2008501852A patent/JP2008535546A/ja active Pending
• 2007
  • 2007-09-17 IL IL185995A patent/IL185995A0/en unknown

Non-Patent Citations (1)

Also Published As

Similar Documents

Legal Events