EP1841899A1 - Method and device for producing an alkali metal hypochlorite solution - Google Patents
Method and device for producing an alkali metal hypochlorite solutionInfo
- Publication number
- EP1841899A1 EP1841899A1 EP06700215A EP06700215A EP1841899A1 EP 1841899 A1 EP1841899 A1 EP 1841899A1 EP 06700215 A EP06700215 A EP 06700215A EP 06700215 A EP06700215 A EP 06700215A EP 1841899 A1 EP1841899 A1 EP 1841899A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- brine solution
- solution
- concentration
- electrolysis cell
- current
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
- C02F1/4674—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation with halogen or compound of halogens, e.g. chlorine, bromine
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/26—Chlorine; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46133—Electrodes characterised by the material
Definitions
- the invention relates to a process for the preparation of an alkali metal hypochlorite solution, in particular a sodium hypochlorite solution, in which an undivided electrolysis cell is supplied with a brine solution having a specific volumetric flow and with a specific salt concentration.
- the invention further relates to a device for producing an alkali metal hypochlorite solution, in particular a sodium hypochlorite
- Solution comprising at least one undivided electrolysis cell, means for supplying a brine solution having a certain volume flow and a certain salt concentration in the electrolysis cell, and with a DC voltage source for generating a current through the electrolysis cell.
- Such systems are offered by the company Wallace & Tiernan GmbH, Günzburg, under the name OSEC-S® and OSEC-B®.
- the brine concentration in the electrolysis cell is measured by evaluating the voltage across the electrodes and the flowing current. From this, a conductivity-proportional signal is generated which is used to control a saturated saline dosing pump.
- a diaphragm-free electrolysis cell in which the ratio to the effective anode area and the effective cathode area in the electrolytic cell is at least 1, 5: 1 or greater.
- the electrolytic cell is additionally cooled in order to reduce the amount of sodium chlorate formed.
- the invention has for its object to provide a method and apparatus for producing a Alkalimetallhypochloritans, whereby the simplest possible, trouble-free and low-maintenance construction is guaranteed and yet sufficient concentration of alkali metal hypochlorite solution can be produced.
- This object is achieved by a process for the preparation of an alkali metal hypochlorite solution, in particular a sodium hypochlorite solution, in which an undivided electrolysis a brine solution is supplied with a certain volume flow and with a certain salt concentration, and wherein the current strength is set such that the concentration of chlorate obtained during the electrolysis to a maximum of 1, 5 g / l, preferably to a maximum of 1 g / l, is particularly preferably limited to a maximum of 0, 6 g / l.
- the object of the invention is further achieved by a device for producing a Alkalimetallhypochloritans, in particular a Natriumhypochloritans, with at least one undivided electrolysis cell, means for supplying a brine solution with a certain volume flow and a certain salt concentration in the electrolytic cell, and with a DC voltage source for generating a Current through the electrolytic cell, wherein the current is set so tightly that the concentration of accumulating during electrolysis chlorate to a maximum of 1, 5 g / l, preferably limited to a maximum of 1 g / l, more preferably to a maximum of 0, 6 g / l is.
- the production of an alkali metal hypochlorite solution with fixed parameters can be advantageously carried out by limiting the concentration of chlorate obtained during electrolysis by a fixed current.
- concentration of active Chlorine increases only disproportionately with increasing the current strength beyond a certain value, while at the same time the production of undesirable chlorate as a byproduct increases disproportionately.
- the method can be operated in this way with fixed operating parameters without the expense of a special scheme in such a favorable manner that an advantageous continuous operation is guaranteed with low maintenance.
- the current is set between 2 and 6 amps, preferably between 2 and 4, 5 amps, more preferably between 2, 5 and 3, 5 amps.
- the brine solution is prepared with a constant salt concentration by mixing a saturated brine solution with water.
- the desired input concentration of the electrolytic cell with salt solution can be set to a favorable value in a particularly simple manner. Since the starting product used is a saturated salt solution which is mixed with water, preferably with deionized water or drinking water, a suitable concentration of the salt solution supplied to the electrolysis cell can be ensured without additional control effort.
- the salt concentration of the brine solution supplied to the electrolysis cell is adjusted to a value between 2 and 10 g / l, preferably between 5 and 10 g / l.
- V the flow velocity between 4 x 10 -5 m / s and 12 x 10 -5 m / s, preferably between 6 x 10 -5 m / s and 9 x 10 -5 m / s.
- the DC voltage source is preferably designed as a constant current source.
- the desired concentration of the brine solution supplied to the electrolytic cell can be adjusted either by mixing a saturated brine solution with water or by using a brine solution having a certain concentration.
- the preset brine solution metering pumps are preferably used by the constant mixing ratio or a constant flow rate is guaranteed.
- the electrodes of the electrolytic cell may for example consist of a material containing iron, mercury, stainless steel, titanium and / or platinum.
- the electrodes preferably consist of uncoated titanium.
- Figure 1 shows the relationship between current and the concentration of active chlorine or chlorate and the discharge temperature in an electrolysis cell according to the invention.
- FIG. 2 shows the relationship between the feed concentration of a sodium chloride solution fed in and the active chlorine concentration produced
- Fig. Figure 3 shows the relationship between the feed concentration of sodium hypochlorite and the concentration of active chlorine and chlorate produced and the discharge temperature
- Fig. 4 shows the relationship between the volume flow used and the concentration of generated active chlorine and chlorate and
- Fig. 5 is a simplified schematic diagram of a device according to the invention.
- the basic structure of a device according to the invention is shown in FIG. 5 and generally designated by the numeral 10.
- the apparatus 10 is used to produce a Alkalimetallhypochlorits, in particular a Natriumhypochlorits, using an electrolytic cell 12.
- the electrolysis cell 12 is fed from a brine tank 20, a saturated salt solution, which is mixed before being supplied to the electrolytic cell 12 with water from a water tank 22.
- the electrolysis cell 12 is designed as a one-piece, not divided by a membrane cell and has a housing made of PVDF.
- the electrodes 14, 16, which are made of uncoated titanium, are connected to a DC voltage source 18, which is designed as a constant current source to produce a constant current of 3 amps at a voltage of about 3.5 to 4.5 volts.
- sodium hypochlorite is formed from the aqueous sodium chloride solution upon release of hydrogen.
- the output of the electrolysis cell is connected via a line 34 to a collecting container 36.
- the sodium hypochlorite solution produced in this case is discharged to the outside via a line 38, while the hydrogen rises upwards and is discharged via an exhaust gas line 40 and diluted to a harmless concentration.
- the concentration of the electrolytic cell 12 salt solution supplied is adjusted by metering pumps 24, 26, each generating a constant volume flow.
- the first metering pump 24 sucks in the brine tank 20 saturated salt solution at a flow rate of 42 ml / h.
- the second dosing pump sucks from the water tank 22 deionized water (or drinking water) via a line 32 with a flow rate of 2.958 l / h.
- the pressure lines of the two metering pumps 24, 26 open via a common line 30 in the inflow of the electrolytic cell 12.
- the electrolytic cell 12 is thus supplied in the example shown, a volume flow of 3 l / h sodium chlorite solution, the concentration of the mixture of the saturated salt solution with deionized water is adjusted to a value of about 5 g / l.
- Fig. 5 is further indicated that the levels of the brine tank 20, the water tank 22 and the collecting container 36 are preferably monitored with a level monitoring, which may include about level sensors 42, 44, 46 and float switch (not shown).
- a level monitoring which may include about level sensors 42, 44, 46 and float switch (not shown).
- the operating parameters of the device 10 are now set such that the yield of Natriumhypochlorit trenchung is driven in a favorable range for the production of sodium hypochlorite, wherein at the same time the accumulation of undesirable chlorate is minimized.
- Fig. 1 shows the concentration of active chlorine (sodium hypochlorite, NaOCl) and of chlorate depending on different current strengths.
- the discharge temperature from the E- lektrolysezelle is applied, at a constant flow temperature of 17 0 C.
- the flow rate in the example shown is 3.5 l / h at a sodium chloride concentration of 10 g / l. All measurement results (also in the following FIGS. 2 to 4) relate to an electrolytic cell with an effective electrode area of 140 mm x 80 mm and an electrode gap of 2 mm.
- the current intensity is now limited according to the invention in such a way that the chlorate concentration in the effluent is less than 1.5 g / l, preferably less than 1.0 g / l, more preferably less than 0.6 g / l or 0.5 g / l. l is. This can be achieved with a current that is preferably set between 2, 5 and 3.5 ampere, optimally to 3 amps.
- Fig. 2 the influence of the inlet concentration of NaCl on the active chlorine content is shown in the sequence, wherein a current of 3 amps was used.
- Fig. 3 shows that with an increase in the salt content, the chlorate formation increases disproportionately.
- Fig. FIG. 3 shows the concentration of active chlorine and of chlorate in the effluent and how the discharge temperature of the electrolysis cell as a function of the inflow concentration of NaCl (current 3 A). It is therefore a compromise between the chlorine yield on the one hand and the chlorate formation that should be avoided on the other.
- the feed concentration is set to a value between 2 and 10 g / l, preferably to 5 g / l.
- 4 shows the influence of the volume flow of salt solution supplied on the concentration of active chlorine and chlorate in the effluent, wherein a feed concentration of 10 g / l NaCl was used (current 3 A).
- the optimum volume flow with which the electrolytic cell is to operate depends on the geometric dimensions of the cell.
- the dimensions of the cell used are 140 x 80 mm electrode area at a distance of 2 mm.
- the volume flow and the cell size are functionally linked to one another, since with larger cells the throughput (and the yield) increases proportionally as a function of the ion migration rate.
- the device according to the invention is characterized by its particularly simple and reliable construction and works despite the absence of a control device in an optimal range in which the formation of chlorate is minimized and yet a sufficiently high sodium hypochlorite concentration is achieved.
- the temperature was taken into account merely by limiting the current intensity (discharge temperature increases with increased current intensity). Cooling measures can thus be avoided.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005004063A DE102005004063A1 (en) | 2005-01-21 | 2005-01-21 | Method and apparatus for producing an alkali metal hypochlorite solution |
PCT/EP2006/000060 WO2006077016A1 (en) | 2005-01-21 | 2006-01-05 | Method and device for producing an alkali hypochlorite solution |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1841899A1 true EP1841899A1 (en) | 2007-10-10 |
Family
ID=36283675
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06700215A Ceased EP1841899A1 (en) | 2005-01-21 | 2006-01-05 | Method and device for producing an alkali metal hypochlorite solution |
Country Status (4)
Country | Link |
---|---|
US (1) | US20080017519A1 (en) |
EP (1) | EP1841899A1 (en) |
DE (1) | DE102005004063A1 (en) |
WO (1) | WO2006077016A1 (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102006058454B4 (en) * | 2006-12-12 | 2012-01-26 | Joachim Sautter | Process for the electrolytic production of a weak sodium hypochlorite solution with differential pressure-controlled pH and redox control by means of electrolytic membrane cells of water (H2O) and common salt (NaCl) |
GB2448494A (en) * | 2007-03-01 | 2008-10-22 | Giovanni Del Signore | Sodium hypochlorite production |
DE102007023085A1 (en) | 2007-05-16 | 2007-10-25 | Alldos Eichler Gmbh | Device for the production of aqueous chlorine dioxide, comprises a reactor with reaction area, and level determination device having switching point that is operationally coupled with a control unit |
DE202009016240U1 (en) | 2009-11-27 | 2010-04-29 | Weihmann, Andreas, Dipl.-Designer | Water recovery system technology |
AU2010200965B2 (en) * | 2010-03-12 | 2014-05-01 | Empire Technology Development Llc | Brine discharge assembly |
WO2012023901A1 (en) * | 2010-08-17 | 2012-02-23 | Empire Technology Development Llc | Brine disposal system for a brine source |
US20120228149A1 (en) * | 2011-03-09 | 2012-09-13 | Miox Corporation | Electrochemical Generation of Quaternary Ammonium Compounds |
WO2013131102A1 (en) * | 2012-03-02 | 2013-09-06 | Miox Corporation | Waste to product on site generator |
WO2016094591A1 (en) | 2014-12-09 | 2016-06-16 | Miox Corporation | Methods for the direct electrolytic production of stable, high concentration aqueous halosulfamate or halosulfonamide solutions |
CN107747108A (en) * | 2017-11-21 | 2018-03-02 | 北京金惠昌科技发展有限公司 | A kind of device and method of the concentration of electrolyte of detection in real time |
DE102020001704A1 (en) | 2020-03-13 | 2021-09-16 | Bundesrepublik Deutschland, vertr. durch das Bundesministerium der Verteidigung, vertr. durch das Bundesamt für Ausrüstung, Informationstechnik und Nutzung der Bundeswehr | Process for processing a permeate in a mobile water treatment plant |
DE102020116916A1 (en) | 2020-06-26 | 2021-12-30 | Aquama Sàrl | Device and method for producing a cleaning fluid |
CA3194567A1 (en) * | 2020-10-08 | 2022-04-14 | Joshua Griffis | The process of using demineralized water for chlorate reduction in on-site brine electrochlorination systems |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1114329A (en) * | 1977-02-18 | 1981-12-15 | Nobutaka Goto | Process for producing sodium hypochlorite |
US4329215A (en) * | 1980-06-13 | 1982-05-11 | Frank Scoville | Sodium hypochorite production and storage system |
DE3138438C2 (en) * | 1981-09-26 | 1984-07-05 | W.C. Heraeus Gmbh, 6450 Hanau | Electrolytic cell |
DE3215767A1 (en) * | 1982-04-28 | 1983-11-03 | Karl Dr. 6000 Frankfurt Hrska | Arrangement having an electrolysis cell for disinfection of water |
US4510026A (en) * | 1983-11-16 | 1985-04-09 | Panclor S.A. | Process for electrolysis of sea water |
DE3410489A1 (en) | 1984-03-22 | 1985-09-26 | Heraeus Elektroden GmbH, 6450 Hanau | METHOD AND DEVICE, IN PARTICULAR FOR DISINFECTING WATER |
DE3430616A1 (en) * | 1984-08-20 | 1986-02-27 | Siemens Ag | Process and apparatus for sterilising drinking water |
DE3704955A1 (en) * | 1987-02-17 | 1988-08-25 | Roemer Technik Gmbh | Electrolyser |
JP3319887B2 (en) * | 1994-10-05 | 2002-09-03 | クロリンエンジニアズ株式会社 | Method for producing hypochlorite |
CA2204941C (en) * | 1996-05-21 | 2002-04-02 | Paul F. Fulmer | Method and apparatus for optimizing electrolytic production of a halogen in a water treatment system |
GB2334968A (en) | 1998-03-03 | 1999-09-08 | Univ Northumbria Newcastle | Apparatus and method for the electrolytic production of hypochlorite |
CA2315355C (en) * | 1999-08-06 | 2011-12-20 | Sterilox Medical (Europe) Limited | Electrochemical treatment of an aqueous solution |
US20020139689A1 (en) * | 2001-02-01 | 2002-10-03 | Vadim Zolotarsky | Electrode coating and method of use in a reverse polarity electrolytic cell |
US20070007146A1 (en) * | 2005-07-07 | 2007-01-11 | Severn Trent Water Purification, Inc. | Process for producing hypochlorite |
-
2005
- 2005-01-21 DE DE102005004063A patent/DE102005004063A1/en not_active Withdrawn
-
2006
- 2006-01-05 EP EP06700215A patent/EP1841899A1/en not_active Ceased
- 2006-01-05 WO PCT/EP2006/000060 patent/WO2006077016A1/en active Application Filing
-
2007
- 2007-07-19 US US11/879,962 patent/US20080017519A1/en not_active Abandoned
Non-Patent Citations (2)
Title |
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None * |
See also references of WO2006077016A1 * |
Also Published As
Publication number | Publication date |
---|---|
US20080017519A1 (en) | 2008-01-24 |
WO2006077016A1 (en) | 2006-07-27 |
DE102005004063A1 (en) | 2006-07-27 |
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