EP1827105A2 - Composition herbicide - Google Patents
Composition herbicideInfo
- Publication number
- EP1827105A2 EP1827105A2 EP05824391A EP05824391A EP1827105A2 EP 1827105 A2 EP1827105 A2 EP 1827105A2 EP 05824391 A EP05824391 A EP 05824391A EP 05824391 A EP05824391 A EP 05824391A EP 1827105 A2 EP1827105 A2 EP 1827105A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- prosulfocarb
- metolachlor
- composition
- crops
- mefenacet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 140
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 63
- 239000005603 Prosulfocarb Substances 0.000 claims abstract description 77
- NQLVQOSNDJXLKG-UHFFFAOYSA-N prosulfocarb Chemical compound CCCN(CCC)C(=O)SCC1=CC=CC=C1 NQLVQOSNDJXLKG-UHFFFAOYSA-N 0.000 claims abstract description 77
- 241000196324 Embryophyta Species 0.000 claims abstract description 37
- XIGAUIHYSDTJHW-UHFFFAOYSA-N mefenacet Chemical compound N=1C2=CC=CC=C2SC=1OCC(=O)N(C)C1=CC=CC=C1 XIGAUIHYSDTJHW-UHFFFAOYSA-N 0.000 claims abstract description 25
- LLQPHQFNMLZJMP-UHFFFAOYSA-N Fentrazamide Chemical compound N1=NN(C=2C(=CC=CC=2)Cl)C(=O)N1C(=O)N(CC)C1CCCCC1 LLQPHQFNMLZJMP-UHFFFAOYSA-N 0.000 claims abstract description 24
- HFEJHAAIJZXXRE-UHFFFAOYSA-N cafenstrole Chemical compound CCN(CC)C(=O)N1C=NC(S(=O)(=O)C=2C(=CC(C)=CC=2C)C)=N1 HFEJHAAIJZXXRE-UHFFFAOYSA-N 0.000 claims abstract description 20
- WVQBLGZPHOPPFO-LBPRGKRZSA-N (S)-metolachlor Chemical compound CCC1=CC=CC(C)=C1N([C@@H](C)COC)C(=O)CCl WVQBLGZPHOPPFO-LBPRGKRZSA-N 0.000 claims abstract description 18
- 239000005617 S-Metolachlor Substances 0.000 claims abstract description 18
- UNLYSVIDNRIVFJ-UHFFFAOYSA-N Piperophos Chemical compound CCCOP(=S)(OCCC)SCC(=O)N1CCCCC1C UNLYSVIDNRIVFJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- JLYFCTQDENRSOL-UHFFFAOYSA-N 2-chloro-N-(2,4-dimethylthiophen-3-yl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound COCC(C)N(C(=O)CCl)C=1C(C)=CSC=1C JLYFCTQDENRSOL-UHFFFAOYSA-N 0.000 claims abstract description 10
- WVQBLGZPHOPPFO-UHFFFAOYSA-N 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(C(C)COC)C(=O)CCl WVQBLGZPHOPPFO-UHFFFAOYSA-N 0.000 claims abstract description 10
- KZNDFYDURHAESM-UHFFFAOYSA-N 2-chloro-n-(2-ethyl-6-methylphenyl)-n-(propan-2-yloxymethyl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(COC(C)C)C(=O)CCl KZNDFYDURHAESM-UHFFFAOYSA-N 0.000 claims abstract description 10
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 claims abstract description 10
- NXQDBZGWYSEGFL-UHFFFAOYSA-N Anilofos Chemical compound COP(=S)(OC)SCC(=O)N(C(C)C)C1=CC=C(Cl)C=C1 NXQDBZGWYSEGFL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000005508 Dimethachlor Substances 0.000 claims abstract description 10
- QAHFOPIILNICLA-UHFFFAOYSA-N Diphenamid Chemical compound C=1C=CC=CC=1C(C(=O)N(C)C)C1=CC=CC=C1 QAHFOPIILNICLA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000005531 Flufenacet Substances 0.000 claims abstract description 10
- 239000005580 Metazachlor Substances 0.000 claims abstract description 10
- WXZVAROIGSFCFJ-UHFFFAOYSA-N N,N-diethyl-2-(naphthalen-1-yloxy)propanamide Chemical compound C1=CC=C2C(OC(C)C(=O)N(CC)CC)=CC=CC2=C1 WXZVAROIGSFCFJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- LVKTWOXHRYGDMM-UHFFFAOYSA-N Naproanilide Chemical compound C=1C=C2C=CC=CC2=CC=1OC(C)C(=O)NC1=CC=CC=C1 LVKTWOXHRYGDMM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000005585 Napropamide Substances 0.000 claims abstract description 10
- 239000005593 Pethoxamid Substances 0.000 claims abstract description 10
- KDWQYMVPYJGPHS-UHFFFAOYSA-N Thenylchlor Chemical compound C1=CSC(CN(C(=O)CCl)C=2C(=CC=CC=2C)C)=C1OC KDWQYMVPYJGPHS-UHFFFAOYSA-N 0.000 claims abstract description 10
- 240000008042 Zea mays Species 0.000 claims abstract description 10
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims abstract description 10
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 10
- XCSGPAVHZFQHGE-UHFFFAOYSA-N alachlor Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl XCSGPAVHZFQHGE-UHFFFAOYSA-N 0.000 claims abstract description 10
- HKPHPIREJKHECO-UHFFFAOYSA-N butachlor Chemical compound CCCCOCN(C(=O)CCl)C1=C(CC)C=CC=C1CC HKPHPIREJKHECO-UHFFFAOYSA-N 0.000 claims abstract description 10
- SCCDDNKJYDZXMM-UHFFFAOYSA-N dimethachlor Chemical compound COCCN(C(=O)CCl)C1=C(C)C=CC=C1C SCCDDNKJYDZXMM-UHFFFAOYSA-N 0.000 claims abstract description 10
- IANUJLZYFUDJIH-UHFFFAOYSA-N flufenacet Chemical compound C=1C=C(F)C=CC=1N(C(C)C)C(=O)COC1=NN=C(C(F)(F)F)S1 IANUJLZYFUDJIH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000009973 maize Nutrition 0.000 claims abstract description 10
- STEPQTYSZVCJPV-UHFFFAOYSA-N metazachlor Chemical compound CC1=CC=CC(C)=C1N(C(=O)CCl)CN1N=CC=C1 STEPQTYSZVCJPV-UHFFFAOYSA-N 0.000 claims abstract description 10
- CSWIKHNSBZVWNQ-UHFFFAOYSA-N pethoxamide Chemical compound CCOCCN(C(=O)CCl)C(=C(C)C)C1=CC=CC=C1 CSWIKHNSBZVWNQ-UHFFFAOYSA-N 0.000 claims abstract description 10
- MFOUDYKPLGXPGO-UHFFFAOYSA-N propachlor Chemical compound ClCC(=O)N(C(C)C)C1=CC=CC=C1 MFOUDYKPLGXPGO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 240000007594 Oryza sativa Species 0.000 claims abstract description 5
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 5
- 235000009566 rice Nutrition 0.000 claims abstract description 5
- 235000013339 cereals Nutrition 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 22
- 244000038559 crop plants Species 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 12
- YLPGTOIOYRQOHV-UHFFFAOYSA-N Pretilachlor Chemical compound CCCOCCN(C(=O)CCl)C1=C(CC)C=CC=C1CC YLPGTOIOYRQOHV-UHFFFAOYSA-N 0.000 claims description 6
- FFSSWMQPCJRCRV-UHFFFAOYSA-N quinclorac Chemical compound ClC1=CN=C2C(C(=O)O)=C(Cl)C=CC2=C1 FFSSWMQPCJRCRV-UHFFFAOYSA-N 0.000 claims description 2
- LFULEKSKNZEWOE-UHFFFAOYSA-N propanil Chemical compound CCC(=O)NC1=CC=C(Cl)C(Cl)=C1 LFULEKSKNZEWOE-UHFFFAOYSA-N 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 abstract description 46
- 239000004009 herbicide Substances 0.000 abstract description 12
- 241000209504 Poaceae Species 0.000 abstract description 4
- 244000045561 useful plants Species 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 24
- 235000019198 oils Nutrition 0.000 description 24
- 238000009472 formulation Methods 0.000 description 19
- 239000000654 additive Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000002671 adjuvant Substances 0.000 description 11
- 239000007787 solid Substances 0.000 description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 239000013543 active substance Substances 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 230000000996 additive effect Effects 0.000 description 9
- 239000004094 surface-active agent Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- -1 suspoemulsions Substances 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003112 inhibitor Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 5
- 125000005907 alkyl ester group Chemical group 0.000 description 5
- UQDUPQYQJKYHQI-UHFFFAOYSA-N methyl laurate Chemical compound CCCCCCCCCCCC(=O)OC UQDUPQYQJKYHQI-UHFFFAOYSA-N 0.000 description 5
- 239000003094 microcapsule Substances 0.000 description 5
- 239000002480 mineral oil Substances 0.000 description 5
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- 150000003839 salts Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 239000000969 carrier Substances 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
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- 238000010353 genetic engineering Methods 0.000 description 4
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- 239000010695 polyglycol Substances 0.000 description 4
- 239000003053 toxin Substances 0.000 description 4
- 231100000765 toxin Toxicity 0.000 description 4
- 108700012359 toxins Proteins 0.000 description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 description 4
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- 229920000742 Cotton Polymers 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
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- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 1
- KZOJQMWTKJDSQJ-UHFFFAOYSA-M sodium;2,3-dibutylnaphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CCCC)C(CCCC)=CC2=C1 KZOJQMWTKJDSQJ-UHFFFAOYSA-M 0.000 description 1
- 239000004550 soluble concentrate Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- PZTAGFCBNDBBFZ-UHFFFAOYSA-N tert-butyl 2-(hydroxymethyl)piperidine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCCCC1CO PZTAGFCBNDBBFZ-UHFFFAOYSA-N 0.000 description 1
- BSYVTEYKTMYBMK-UHFFFAOYSA-N tetrahydrofurfuryl alcohol Chemical compound OCC1CCCO1 BSYVTEYKTMYBMK-UHFFFAOYSA-N 0.000 description 1
- ZFXYFBGIUFBOJW-UHFFFAOYSA-N theophylline Chemical compound O=C1N(C)C(=O)N(C)C2=C1NC=N2 ZFXYFBGIUFBOJW-UHFFFAOYSA-N 0.000 description 1
- 229960000278 theophylline Drugs 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000003971 tillage Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 241001478887 unidentified soil bacteria Species 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- 239000004565 water dispersible tablet Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
Definitions
- the present invention relates to a herbicidal composition
- a herbicidal composition comprising a herbicidal active ingredient combination that is preferably suitable for the selective control of undesired vegetation like weeds (grasses and broad-leaved weeds) in crops of useful plants and in particular resistant weeds in crops of useful plants, for example in crops of rice, cereals and maize.
- the invention relates also to a method of controlling weeds, which are defined as undesired vegetation in crops of useful plants and to the use of the novel composition to act where control is desired, for example, on the undesired vegetation or the locus thereof.
- the present invention provides the use of the novel composition for control of undesired vegetation, which comprises applying (i) before emergence (pre-emergence) of the undesired vegetation, (ii) after emergence (post-emergence) of the undesired vegetation, or (iii) both (i) and (ii), the composition, in a herbicidally effective amount, where control is desired, for example, on the undesired vegetation or the locus thereof.
- the compounds prosulfocarb (683), Group K3 / Inhibitors of cell division Inhibitors of VLCFAs (inhib of PDS) naproanilide (571), pretilachlor (656), napropamide (572), diphenamid (274), butachlor (100), acetochlor (5), dimethenamid (260), dimethachlor (258), alachlor (14), metolachlor (548), S-metolachlor (549), propisochlor (677), pethoxamid (627), metazachlor (524), thenylchlor (789), propachlor (667), Group K3 (tetrazolinone), fentrazamide (348), Group K3 (oxyacetamids) flufenacet (369), mefenacet (505), Group K3 (others) anilofos (31), piperophos (650) and cafenstrole (110) and agronomically acceptable salts thereof, exhibit herbicidal action, as
- variable amounts of prosulfocarb with at least one inhibitor of cell division exhibits a synergistic action that is capable of controlling, both pre-emergence and post-emergence, the majority of weeds (grasses and broad-leaved weeds) occurring especially in crops of useful plants, without appreciably damaging the useful plants, in particular ALS-resistant weeds and ACCase-resistant weeds in crops of useful plants, for example in crops of rice, cereals or maize.
- a novel herbicidal composition for the selective control of weeds which comprises a) prosulfocarb and b) at least one compound selected from the compounds of the group naproanilide, napropamide, diphenamid, butachlor, acetochlor, dimethenamid, dimethachlor, alachlor, metolachlor, S-metolachlor, propisochlor, pethoxamid, metazachlor, thenylchlor, propachlor, fentrazamide, flufenacet, mefenacet, anilofos, piperophos and cafenstrole.
- a second aspect of the present invention provides method a of controlling undesired vegetation in crops of useful plants, which comprises allowing a herbicidally effective amount of the composition defined in the first aspect to act where control is desired
- a method of controlling one or more resistant weeds selected from ALS-resistant weeds, ACCase-resistant weeds, propanil- resistant weeds, and quinclorac-resistant weeds, in crops of useful plants which comprises allowing a herbicidally effective amount of a composition to act where control is desired, wherein the herbicidal composition comprises:
- prosulfocarb and (b) at least one compound selected from the compounds of the group pretilachlor, naproanilide, napropamide, diphenamid, butachlor, acetochlor, dimethenamid, dimethachlor, alachlor, metolachlor, S-metolachlor, propisochlor, pethoxamid, metazachlor, thenylchlor, propachlor, fentrazamide, flufenacet, mefenacet, anilofos, piperophos and cafenstrole.
- the herbicidal composition consists essentially of, more preferably consists of, as active ingredient, (a) and (b) as defined herein, and optionally one or more formulation adjuvants.
- one or more further herbicidal active ingredients are present in the herbicidal composition in combination with (a) and (b).
- Combinations that are especially effective are: prosulfocarb + naproanilide, prosulfocarb + napropamide, prosulfocarb + diphenamid, prosulfocarb + butachlor, prosulfocarb + acetochlor, prosulfocarb + dimethenamid, prosulfocarb + dimethachlor, prosulfocarb + alachlor, prosulfocarb + metolachlor, prosulfocarb + S-metolachlor, prosulfocarb + propisochlor, prosulfocarb + pethoxamid, prosulfocarb + metazachlor, prosulfocarb + thenylchlor, prosulfocarb + propachlor, prosulfocarb + fentrazamide, prosulfocarb + flufenacet, prosulfocarb + mefenacet, prosulfocarb + anilofos, prosulfo
- Combinations that have been found to be very especially effective are prosulfocarb + S- metolachlor; prosulfocarb and fentrazamide; prosulfocarb and mefenacet; and prosulfocarb and cafenstrole.
- composition according to the invention comprises the mentioned active ingredients in any mixing ratio, but usually has an excess of one component over the other.
- Preferred mixing ratios of the active ingredients are from 25:1 to 1 :25.
- the rate of application may also vary within wide limits and depends upon the nature of the soil, the method of application (pre- or post-emergence; seed dressing; application to the seed furrow; no tillage application etc.), the crop plant, the weed or grass to be controlled, the prevailing climatic conditions, and other factors governed by the method of application, the specific active ingredient combination, the time of application and the target crop.
- the active ingredient mixture according to the invention can generally be applied at a rate of 0.05 to 7 kg of active ingredient mixture per hectare, preferably at a rate of 1 to 5 kg of active ingredient mixture per hectare.
- the invention relates also to a method for the selective control of grasses and weeds in crops of useful plants, which comprises treating the useful plants or the area under cultivation or the locus thereof simultaneously or at different times with the compositions according to the invention.
- Crops of useful plants in which the composition according to the invention can be used include especially rice.
- the term "crops" is to be understood as also including crops that have been rendered tolerant to herbicides or classes of herbicides (for example ALS, GS, EPSPS, PPO and HPPD inhibitors) as a result of conventional methods of breeding or genetic engineering.
- herbicides or classes of herbicides for example ALS, GS, EPSPS, PPO and HPPD inhibitors
- An example of a crop that has been rendered tolerant e.g. to imid- azolinones, such as imazamox, by conventional methods of breeding is Clearfield® summer rape (Canola).
- crops that have been rendered tolerant to herbicides by genetic engineering methods include e.g.
- the weeds to be controlled may be both monocotyledonous and dicotyledonous weeds, such as, for example, Alisma spp, Leptochloa chinensis, Stellaria, Nasturtium, Agrostis, Digitaria, Avena, Setaria, Sinapis, Lolium, Solanum, Echinochloa and especially Echinochloa crus- galli or Echinochloa oryzicola, Scirpus and especially Scirpus juncoides, Monochoria and especially Monochoria vaginalis, Sagittaria and especially Sagittaria pygmea, Bromus, Alopecurus, Sorghum, Rottboellia, Cyperus and especially Cyperus iria, Abutilon, Sida, Xanthium, Amaranthus, Chenopodium
- Crops are also to be understood as being those which have been rendered resistant to harmful insects by genetic engineering methods, for example Bt maize (resistant to European corn borer), Bt cotton (resistant to cotton boll weevil) and also Bt potatoes (resistant to Colorado beetle).
- Bt maize are the BM 76 maize hybrids of NK® (Syngenta Seeds).
- the Bt toxin is a protein that is formed naturally by Bacillus thuringiensis soil bacteria. Examples of toxins and transgenic plants able to synthesise such toxins are described in EP-A-451 878, EP-A-374 753, WO 93/07278, WO 95/34656, WO 03/052073 and EP-A-427 529.
- transgenic plants that contain one or more genes which code for an insecticidal resistance and express one or more toxins are KnockOut® (maize), Yield Gard® (maize), NuCOTI N33B® (cotton), Bollgard® (cotton), NewLeaf® (potatoes), NatureGard® and Protexcta®.
- Plant crops and their seed material can be resistant to herbicides and at the same time also to insect feeding ("stacked" transgenic events). Seed can, for example, have the ability to express an insecticidally active Cry3 protein and at the same time be glyphosate-tolerant.
- the term "crops" is to be understood as also including crops obtained as a result of conventional methods of breeding or genetic engineering which contain so-called output traits (e.g. improved flavour, storage stability, nutritional content).
- Areas under cultivation are to be understood as including land where the crop plants are already growing as well as land intended for the cultivation of those crop plants.
- compositions according to the invention can be used in unmodified form.
- the compositions according to the invention are, however, generally formulated in a variety of way using formulation adjuvants, such as carriers, solvents and surface-active substances.
- the formulations can be in various physical forms, for example in the form of dusting powders, gels, wettable powders, water-dispersible granules, water-dispersible tablets, effervescent compressed tablets, emulsifiable concentrates, microemulsifiable concentrates, oil-in-water emulsions, oil flowables, aqueous dispersions, oily dispersions, suspoemulsions, capsule suspensions, emulsifiable granules, soluble liquids, water-soluble concentrates (with water or a water-miscible organic solvent as carrier), impregnated polymer films or in other forms known, for example, from the Manual on Development and Use of FAO Specifications for Plant Protection Products, 5th Edition, 1999.
- the formulations can be prepared, for example, by mixing the active ingredients with formulation adjuvants in order to obtain compositions in the form of finely divided solids, granules, solutions, dispersions or emulsions.
- the active ingredients can also be formulated with other adjuvants, for example finely divided solids, mineral oils, vegetable oils, modified vegetable oils, organic solvents, water, surface-active substances or combinations thereof.
- the active ingredients can also be contained in very fine microcapsules consisting of a polymer. Microcapsules contain the active ingredients in a porous carrier. This enables the active ingredients to be released into their surroundings in controlled amounts (e.g. slow release). Microcapsules usually have a diameter of from 0.1 to 500 microns.
- the active ingredients contain active ingredients in an amount of about from 25 to 95 % by weight of the capsule weight.
- the active ingredients can be present in the form of a monolithic solid, in the form of fine particles in solid or liquid dispersion or in the form of a suitable solution.
- the encapsulating membranes comprise, for example, natural and synthetic gums, cellulose, styrene-butadiene copolymers, polyacrylonitrile, polyacrylate, polyester, polyamides, polyureas, polyurethane or chemically modified polymers and starch xanthates or other polymers that are known to the person skilled in the art in this connection.
- the formulation adjuvants suitable for the preparation of the compositions according to the invention are known perse.
- liquid carriers there may be used: water, toluene, xylene, petroleum ether, vegetable oils, acetone, methyl ethyl ketone, cyclohexanone, acid anhydrides, acetonitrile, acetophenone, amyl acetate, 2-butanone, butylne carbonate, chlorobenzene, cyclohexane, cyclohexanol, alkyl esters of acetic acid, diacetone alcohol, 1 ,2-dichloropropane, diethanolamine, p-diethylbenzene, diethylene glycol, diethylene glycol abietate, diethylene glycol butyl ether, diethylene glycol ethyl ether, diethylene glycol methyl ether, N,N-dimethylformamide, dimethyl sulfoxide, 1 ,4-dioxane
- Water is generally the carrier of choice for the dilution of the concentrates.
- Suitable solid carriers are, for example, talc, titanium dioxide, pyrophyllite clay, silica, attapulgite clay, kieselguhr, limestone, calcium carbonate, bentonite, calcium montomorillonite, cottonseed husks, wheatmeal, soybean flour, pumice, wood flour, ground walnut shells, lignin and similar materials, as described, for example, in CFR 180.1001 . (c) & (d).
- a large number of surface-active substances can advantageously be used both in solid and in liquid formulations, especially in those formulations which can be diluted with a carrier prior to use.
- Surface-active substances may be anionic, cationic, non-ionic or polymeric and they may be used as emulsifiying, wetting or suspending agents or for other purposes.
- Typical surface-active substances include, for example, salts of alkyl sulfates, such as diethanolammonium lauryl sulfate; salts of alkylarylsulfonates, such as calcium dodecyl- benzenesulfonate; alkylphenol-alkylene oxide addition products, such as nonylphenol ethoxylate; alcohol-alkylene oxide addition products, such as tridecyl alcohol ethoxylate; soaps, such as sodium stearate; salts of alkylnaphthalenesulfonat.es, such as sodium dibutylnaphthalenesulfonate; dialkyl esters of sulfosuccinate salts, such as sodium di(2- ethylhexyl)sulfosuccinate
- Further adjuvants which can usually be used in pesticidal formulations include crystallisation inhibitors, viscosity-modifying substances, suspending agents, dyes, anti-oxidants, foaming agents, light absorbers, mixing aids, anti-foams, complexing agents, neutralising or pH- modifying substances and buffers, corrosion-inhibitors, fragrances, wetting agents, absorption improvers, micronutrients, plasticisers, glidants, lubricants, dispersants, thickeners, anti-freezes, microbiocides and also liquid and solid fertilisers.
- the formulations may also comprise additional active substances, for example further herbicides, herbicide safeners, plant growth regulators, fungicides or insecticides.
- compositions according to the invention can additionally include an additive comprising an oil of vegetable or animal origin, a mineral oil, alkyl esters of such oils or mixtures of such ' oils and oil derivatives.
- the amount of oil additive used in the composition according to the invention is generally from 0.01 to 10 %, based on the spray mixture.
- the oil additive can be added to the spray tank in the desired concentration after the spray mixture has been prepared.
- Preferred oil additives comprise mineral oils or an oil of vegetable origin, for example rapeseed oil, olive oil or sunflower oil, emulsified vegetable oil, such as AMIGO® (Rh ⁇ ne-Poulenc Canada Inc.), alkyl esters of oils of vegetable origin, for example the methyl derivatives, or an oil of animal origin, such as fish oil or beef tallow.
- a preferred additive contains, for example, as active components essentially 80 % by weight alkyl esters of fish oils and 15 % by weight methylated rapeseed oil, and also 5 % by weight of customary emulsifiers and pH modifiers.
- Especially preferred oil additives comprise alkyl esters of C 8 -C 22 fatty acids, especially the methyl derivatives of Ci 2 -C 18 fatty acids, for example, the methyl esters of lauric acid, palmitic acid and oleic acid, being important; those esters are known as methyl laurate (CAS-111-82-0), methyl palmitate (CAS-112-39-0) and methyl oleate (CAS-112-62-9) respectively.
- a preferred fatty acid methyl ester derivative is Emery® 2230 or 2231 (Cognis GmbH).
- Those and other oil derivatives are also known from the Compendium of Herbicide Adjuvants, 5th Edition, Southern Illinois University, 2000.
- the application and action of the oil additives can be further improved by combining them with surface-active substances, such as non-ionic, anionic or cationic surfactants.
- surface-active substances such as non-ionic, anionic or cationic surfactants.
- suitable anionic, non-ionic and cationic surfactants are listed on pages 7 and 8 of WO 97/34485.
- Preferred surface-active substances are anionic surfactants of the dodecyl- benzylsulfonate type, especially the calcium salts thereof, and also non-ionic surfactants of the fatty alcohol ethoxylate type. Special preference is given to ethoxylated C 12 -C 22 fatty alcohols having a degree of ethoxylation of from 5 to 40.
- Examples of commercially available surfactants are the Genapol types (Clariant AG).
- silicone surfactants especially polyalkyl-oxide-modified heptamethyltrisiloxanes, which are commercially available e.g. as Silwet L-77®, and also perfluorinated surfactants.
- concentration of surface-active substances in relation to the total additive is generally from 1 to 30 % by weight.
- oil additives that consist of mixtures of oils or mineral oils or derivatives thereof with surfactants are Edenor ME SU®, Turbocharge® (Syngenta AG, CH) and Actipron® (BP Oil UK Limited, GB).
- the said surface-active substances may also be used in the formulations alone, that is to say without oil additives.
- an organic solvent to the oil additive/surfactant mixture can contribute to a further enhancement of action.
- Suitable solvents are, for example,
- Solvesso® (ESSO) and Aromatic Solvent® (Exxon Corporation).
- concentration of such solvents can be from 10 to 80 % by weight of the total weight.
- oil additives which may be in admixture with solvents, are described, for example, in US-A-4 834 908.
- a commercially available oil additive disclosed therein is known by the name MERGE® (BASF Corporation).
- a further oil additive that is preferred according to the invention is SCORE® (Syngenta Crop Protection Canada).
- formulations of alkylpyrrolidones (e.g. Agrimax®) to be added to the spray mixture.
- Formulations of synthetic latices such as, for example, polyacrylamide, polyvinyl compounds or poly-1-p-menthene (e.g. Bond®, Courier® or Emerald®) can also be used. Solutions that contain propionic acid, for example Eurogkem Pen-e-trate®, can also be mixed into the spray mixture as activity-enhancing agents.
- the herbicidal formulations generally contain from 0.1 to 99 % by weight, especially from 0.1 to 95 % by weight, of an active ingredient mixture of the compositions according to the invention and from 1 to 99.9 % by weight of a formulation adjuvant, which preferably includes from 0 to 25 % by weight of a surface-active substance.
- a formulation adjuvant which preferably includes from 0 to 25 % by weight of a surface-active substance.
- Emulsifiable concentrates active ingredient mixture: 1 to 95 %, preferably 60 to 90 % surface-active agent: 1 to 30 %, preferably 5 to 20 % liquid carrier: balance
- Dusts active ingredient mixture: 0.1 to 10 %, preferably 0.1 to 5 % solid carrier: 99.9 to 90 %, preferably 99.9 to 99 %
- Suspension concentrates active ingredient mixture: 5 to 75 %, preferably 10 to 50 % surface-active agent: 1 to 40 %, preferably 2 to 30 % water: balance
- Wettable powders active ingredient mixture: 0.5 to 90 %, preferably 1 to 80 % surface-active agent: 0.5 to 20 %, preferably 1 to 15 % solid carrier: balance
- Granules active ingredient mixture: 0.1 to 30 %, preferably 0.5 to 15 % solid carrier: 99.9 to 70 %, preferably 99,5 to 85 %
- Emulsifiable concentrates a) b) c) d) active ingredient mixture 5% 10% 25 % 50% calcium dodecylbenzene- sulfonate 6% 8% 6 % 8% castor oil polyglycol ether 4% 4 % 4%
- Emulsions of any desired concentration can be prepared from such concentrates by dilution with water.
- the solutions are suitable for application in the form of microdrops.
- Wettable powders a) b) c) d) active ingredient mixture 5% 25% 50 % 80% sodium lignosulfonate 4% - 3' % - sodium lauryl sulfate 2% 3% - 4% sodium diisobutylnaphthalene- sulfonate - 6% 5' % 6% octylphenol polyglycol ether - 1 % 2' % -
- the finely ground active ingredient is applied uniformly, in a mixer, to the carrier moistened with polyethylene glycol. Non-dusty coated granules are obtained in this manner.
- Ready-to-use dusts are obtained by mixing the active ingredient with the carriers and grinding the mixture in a suitable mill.
- Suspension concentrates a) b) c) d) active ingredient mixture 3% 10% 25% 50% ethylene glycol 5% 5% 5% nonylphenol polyglycol ether - 1 % 2% -
- the finely ground active ingredient is intimately mixed with the adjuvants, yielding a suspension concentrate from which suspensions of any desired concentration can be prepared by dilution with water. It is often more practical for the active ingredients present in the compositions according to the invention to be formulated separately and then to be combined in the applicator in the desired mixing ratio in the form of a "tank mixture", optionally with a diluent such as water, shortly before application.
- the active ingredients present in the compositions according to the present invention are formulated together (known as pre-mix or formulated product).
- test compounds exhibit good results.
- the field tests are carried out in water-saturated ground standing under about 5 cm of water (saturated conditions).
- the herbicides both on their own and in admixture, are applied to the test plants under water-saturated ground conditions using a back spray.
- the rates of application depend on the optimum concentrations ascertained under field conditions.
- Y percentage herbicidal action on treatment with a compound (B) at a rate of application of q kg per hectare, compared with the untreated control.
- Table B1 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and S-metolachlor at 10 days after application (10 DAA):
- Table B2 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and S-metolachlor at 10 days after application (10 DAA):
- Table B3 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and S-metolachlor at 22 days after application (22 DAA):
- Table B4 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and S-metolachlor at 22 days after application (22 DAA):
- Table B5 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and S-metolachlor at 22 days after application (22 DAAV
- Table B6 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and S-metolachlor at 22 days after application (22 DAA):
- Table B7 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and S-metolachlor at 22 days after application (22 DAA):
- Table B8 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and fentrazamide at 10 days after application (10 DAA):
- Table B10 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and fentrazamide at 10 days after application (10 DAA):
- Table B11 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and fentrazamide at 10 days after application (10 DAA):
- Table B12 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and fentrazamide at 10 days after application (10 DAA):
- Table B13 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and fentrazamide at 10 days after application H O DAA):
- Table B14 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and fentrazamide at 22 days after application (22 DAA):
- Table B15 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and fentrazamide at 22 days after application (22 DAA):
- Table B16 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and fentrazamide at 22 days after application (22 DAA):
- Table B17 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and fentrazamide at 22 days after application (22 DAAV
- Table B18 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and fentrazamide at 22 days after application (22 DAA):
- Table B19 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and fentrazamide at 22 days after application (22 DAA):
- Table B20 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and fentrazamide at 22 days after application (22 DAA):
- Table B21 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and mefenacet at 10 days after application (10 DAA):
- Table B22 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and mefenacet at 10 days after application (10 DAA):
- Table B23 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and mefenacet at 10 days after application (10 DAA):
- Table B24 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and mefenacet at 10 days after application (10 DAA):
- Table B25 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and mefenacet at 10 days after application (10 DAA):
- Table B26 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and mefenacet at 10 days after application (10 DAA):
- Table B27 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and mefenacet at 22 days after application (22 DAAV
- Table B28 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and mefenacet at 22 days after application (22 DAA):
- Table B29 Post-emergence herbicidal action of the composition according to the invention comprisinq prosulfocarb and mefenacet at 22 days after application (22 DAA):
- Table B30 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and mefenacet at 22 days after application (22 DAA):
- Table B31 Post-emergence herbicidal action of the composition according to the invention comprisinq prosulfocarb and mefenacet at 22 days after application (22 DAA):
- Table B32 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and mefenacet at 22 davs after application (22 DAA):
- Table B33 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and mefenacet at 22 davs after application (22 DAA):
- Table B34 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and mefenacet at 22 davs after application (22 DAA):
- Table B35 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and cafenstrole at 10 days after application (10 DAA):
- Table B36 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and cafenstrole at 10 days after application (10 DAA):
- Table B37 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and cafenstrole at 10 days after application (10 DAA):
- Table B38 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and cafenstrole at 22 days after application (22 DAA):
- Table B39 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and cafenstrole at 22 days after application (22 DAA):
- Table B40 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and cafenstrole at 22 days after application (22 DAA):
- Table B41 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and cafenstrole at 22 days after application (22 DAAV
- Table B42 Post-emergence herbicidal action of the composition according to the invention comprising prosulfocarb and cafenstrole at 22 days after application (22 DAA):
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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Abstract
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05824391A EP1827105B1 (fr) | 2004-12-17 | 2005-12-15 | Composition herbicide |
PL05824391T PL1827105T3 (pl) | 2004-12-17 | 2005-12-15 | Kompozycja herbicydowa |
EP08022183A EP2039249A3 (fr) | 2004-12-17 | 2005-12-15 | Composition herbicide |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04029973 | 2004-12-17 | ||
EP05824391A EP1827105B1 (fr) | 2004-12-17 | 2005-12-15 | Composition herbicide |
PCT/EP2005/013510 WO2006063835A2 (fr) | 2004-12-17 | 2005-12-15 | Composition herbicide |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08022183A Division EP2039249A3 (fr) | 2004-12-17 | 2005-12-15 | Composition herbicide |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1827105A2 true EP1827105A2 (fr) | 2007-09-05 |
EP1827105B1 EP1827105B1 (fr) | 2009-02-25 |
Family
ID=35840567
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08022183A Withdrawn EP2039249A3 (fr) | 2004-12-17 | 2005-12-15 | Composition herbicide |
EP05824391A Active EP1827105B1 (fr) | 2004-12-17 | 2005-12-15 | Composition herbicide |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08022183A Withdrawn EP2039249A3 (fr) | 2004-12-17 | 2005-12-15 | Composition herbicide |
Country Status (17)
Country | Link |
---|---|
EP (2) | EP2039249A3 (fr) |
JP (1) | JP5053861B2 (fr) |
KR (1) | KR101317659B1 (fr) |
CN (1) | CN101080172B (fr) |
AR (1) | AR052050A1 (fr) |
AT (1) | ATE423466T1 (fr) |
AU (1) | AU2005315777B2 (fr) |
DE (1) | DE602005012986D1 (fr) |
EA (2) | EA200901394A1 (fr) |
ES (1) | ES2320790T3 (fr) |
GT (1) | GT200500371A (fr) |
MY (1) | MY158017A (fr) |
NZ (1) | NZ555746A (fr) |
PL (1) | PL1827105T3 (fr) |
TW (1) | TWI383749B (fr) |
UA (1) | UA89210C2 (fr) |
WO (1) | WO2006063835A2 (fr) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011082964A1 (fr) * | 2009-12-17 | 2011-07-14 | Bayer Cropscience Ag | Produits herbicides contenant du flufénacet |
WO2011082956A2 (fr) * | 2009-12-17 | 2011-07-14 | Bayer Cropscience Ag | Agents herbicides contenant du flufénacet |
WO2011082955A2 (fr) * | 2009-12-17 | 2011-07-14 | Bayer Cropscience Ag | Agents herbicides contenant du flufénacet |
WO2012029446A1 (fr) | 2010-09-01 | 2012-03-08 | 株式会社エス・ディー・エス バイオテック | Inhibiteur de croissance des bourgeons axillaires du tabac et procédé d'inhibition correspondant |
CN104604917B (zh) * | 2013-11-04 | 2016-05-04 | 南京华洲药业有限公司 | 一种含麦草畏与唑草胺的除草组合物及其应用 |
CN105851028A (zh) * | 2016-05-20 | 2016-08-17 | 潍坊中农联合化工有限公司 | 苄草丹与高效二甲噻草胺复配除草剂 |
CN110367270A (zh) * | 2019-07-10 | 2019-10-25 | 山东省联合农药工业有限公司 | 一种含苄草丹、吡氟酰草胺和氟噻草胺的除草组合物及其应用 |
EP4205547A3 (fr) * | 2021-12-29 | 2023-10-11 | UPL Corporation Limited | Combinaisons herbicides |
EP4295684A1 (fr) * | 2022-06-22 | 2023-12-27 | Adama Agan Ltd. | Composition herbicide agrochimique |
EP4295686A1 (fr) * | 2022-06-22 | 2023-12-27 | Adama Agan Ltd. | Composition herbicide agrochimique |
CN116569928A (zh) * | 2023-03-09 | 2023-08-11 | 上海市农业科学院 | 一种防除抗性杂草的除草组合物及其应用 |
CN116806835A (zh) * | 2023-06-28 | 2023-09-29 | 上海市农业科学院 | 一种防除抗性杂草的除草组合物及其应用 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5637203B2 (fr) * | 1973-02-20 | 1981-08-29 | ||
JPS51115924A (en) * | 1975-04-02 | 1976-10-13 | Kumiai Chem Ind Co Ltd | A herbicide composition |
BR8600161A (pt) | 1985-01-18 | 1986-09-23 | Plant Genetic Systems Nv | Gene quimerico,vetores de plasmidio hibrido,intermediario,processo para controlar insetos em agricultura ou horticultura,composicao inseticida,processo para transformar celulas de plantas para expressar uma toxina de polipeptideo produzida por bacillus thuringiensis,planta,semente de planta,cultura de celulas e plasmidio |
US4834908A (en) | 1987-10-05 | 1989-05-30 | Basf Corporation | Antagonism defeating crop oil concentrates |
EP0374753A3 (fr) | 1988-12-19 | 1991-05-29 | American Cyanamid Company | Toxines insecticides, gènes les codant, anticorps les liant, ainsi que cellules végétales et plantes transgéniques exprimant ces toxines |
EP0427529B1 (fr) | 1989-11-07 | 1995-04-19 | Pioneer Hi-Bred International, Inc. | Lectines larvicides, et résistance induite des plantes aux insectes |
UA48104C2 (uk) | 1991-10-04 | 2002-08-15 | Новартіс Аг | Фрагмент днк, який містить послідовність,що кодує інсектицидний протеїн, оптимізовану для кукурудзи,фрагмент днк, який забезпечує направлену бажану для серцевини стебла експресію зв'язаного з нею структурного гена в рослині, фрагмент днк, який забезпечує специфічну для пилку експресію зв`язаного з нею структурного гена в рослині, рекомбінантна молекула днк, спосіб одержання оптимізованої для кукурудзи кодуючої послідовності інсектицидного протеїну, спосіб захисту рослин кукурудзи щонайменше від однієї комахи-шкідника |
US5530195A (en) | 1994-06-10 | 1996-06-25 | Ciba-Geigy Corporation | Bacillus thuringiensis gene encoding a toxin active against insects |
DE69706530T2 (de) | 1996-03-15 | 2002-04-18 | Syngenta Participations Ag, Basel | Herbizide synergistische zusammensetzung und verfahren zur unkrautbekämpfung |
ES2128984B1 (es) * | 1996-05-24 | 2000-02-01 | Bayer Ag | Herbicidas a base de heteroariloxi-acetamidas para el empleo en el cultivo de arroz. |
JP2002080460A (ja) * | 2000-07-06 | 2002-03-19 | Nippon Bayer Agrochem Co Ltd | 除草性テトラゾール誘導体 |
CO5380003A1 (es) * | 2001-10-05 | 2004-03-31 | Syngenta Participations Ag | Composicion herbicida sinergica que comprende pretilachlor y prosulfocarb |
AU2002361696A1 (en) | 2001-12-17 | 2003-06-30 | Syngenta Participations Ag | Novel corn event |
TW200305368A (en) * | 2001-12-19 | 2003-11-01 | Basf Ag | Herbicidal mixtures based on 7-pyrazolylbenzoxazoles |
EP1545212B1 (fr) * | 2002-08-08 | 2008-10-29 | Syngenta Participations AG | Composition herbicide |
-
2005
- 2005-12-15 CN CN2005800432184A patent/CN101080172B/zh active Active
- 2005-12-15 DE DE602005012986T patent/DE602005012986D1/de active Active
- 2005-12-15 GT GT200500371A patent/GT200500371A/es unknown
- 2005-12-15 PL PL05824391T patent/PL1827105T3/pl unknown
- 2005-12-15 WO PCT/EP2005/013510 patent/WO2006063835A2/fr active Application Filing
- 2005-12-15 UA UAA200707827A patent/UA89210C2/ru unknown
- 2005-12-15 EA EA200901394A patent/EA200901394A1/ru unknown
- 2005-12-15 MY MYPI20055910A patent/MY158017A/en unknown
- 2005-12-15 ES ES05824391T patent/ES2320790T3/es active Active
- 2005-12-15 TW TW094144436A patent/TWI383749B/zh active
- 2005-12-15 NZ NZ555746A patent/NZ555746A/en unknown
- 2005-12-15 EA EA200701220A patent/EA013077B1/ru not_active IP Right Cessation
- 2005-12-15 EP EP08022183A patent/EP2039249A3/fr not_active Withdrawn
- 2005-12-15 AT AT05824391T patent/ATE423466T1/de not_active IP Right Cessation
- 2005-12-15 KR KR1020077013564A patent/KR101317659B1/ko active IP Right Grant
- 2005-12-15 JP JP2007545951A patent/JP5053861B2/ja active Active
- 2005-12-15 AU AU2005315777A patent/AU2005315777B2/en active Active
- 2005-12-15 AR ARP050105288A patent/AR052050A1/es active IP Right Grant
- 2005-12-15 EP EP05824391A patent/EP1827105B1/fr active Active
Non-Patent Citations (1)
Title |
---|
See references of WO2006063835A3 * |
Also Published As
Publication number | Publication date |
---|---|
PL1827105T3 (pl) | 2009-08-31 |
AU2005315777A1 (en) | 2006-06-22 |
EP2039249A3 (fr) | 2009-07-01 |
GT200500371A (es) | 2006-10-25 |
EP1827105B1 (fr) | 2009-02-25 |
JP2008524148A (ja) | 2008-07-10 |
UA89210C2 (ru) | 2010-01-11 |
EA200701220A1 (ru) | 2007-12-28 |
ATE423466T1 (de) | 2009-03-15 |
JP5053861B2 (ja) | 2012-10-24 |
DE602005012986D1 (de) | 2009-04-09 |
ES2320790T3 (es) | 2009-05-28 |
NZ555746A (en) | 2010-04-30 |
TW200637492A (en) | 2006-11-01 |
CN101080172A (zh) | 2007-11-28 |
TWI383749B (zh) | 2013-02-01 |
AR052050A1 (es) | 2007-02-28 |
MY158017A (en) | 2016-08-30 |
WO2006063835A2 (fr) | 2006-06-22 |
EA013077B1 (ru) | 2010-02-26 |
CN101080172B (zh) | 2010-05-12 |
KR20070089806A (ko) | 2007-09-03 |
KR101317659B1 (ko) | 2013-10-15 |
WO2006063835A3 (fr) | 2006-08-03 |
AU2005315777B2 (en) | 2011-03-31 |
EA200901394A1 (ru) | 2010-06-30 |
EP2039249A2 (fr) | 2009-03-25 |
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